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1.
Early stage of critical clusters growth in phenomenological and molecular dynamics simulation models
Romuald Puzyrewski Jaros&#x;aw Rybicki Micha&#x; Bia&#x;oskrski 《Atmospheric Research》2006,82(3-4):465
The growth of critical clusters is discussed in the paper according to the classical and molecular dynamics (MD) approaches. A new formula for molecule numbers in critical clusters has been derived within the framework of the classical approach. A set of equations controlling the early stage of growth in a neighborhood of a critical size is presented. As far as molecular dynamics simulation is concerned, a computational technique based on the DL_POLY code is described in brief. Computation results are presented concerning cluster formation of H2O vapor, distribution of clusters versus time, cluster growth and radial density distribution of isolated clusters. A comparison with the classical results is made for a case of dense vapor, where the mechanism of strong condensation is predominant. The Hertz–Knudsen formula seems to be verified by the molecular dynamics results. 相似文献
2.
Study of tropical cyclogenesis using satellite data 总被引：1，自引：1，他引：0
Summary Satellite data are used to study the cloud development and water vapor supply during the genesis of Typhoon Nina (November 1987). Using satellite microwave and infrared data, the following physical parameters are retrieved and analyzed: water vapor path, surface wind, sea surface evaporation, precipitation, and cloud type.During the week prior to the genesis of Nina, several cloud clusters were observed in the region of the subsequent genesis (near 5° N, 170° E). Cloud type studies showed that several clusters had similar structures. By examining the sea surface evaporation and precipitation in the cloud clusters, we found that the precipitation exceeded evaporation by several times in the precipitating areas of the cluster that evolved into a tropical storm, indicating that local evaporation alone could not supply enough water vapor, and that horizontal transfer of water vapor from surrounding areas is required for the tropical cyclogenesis. Surface wind fields indicated that there was a constant increase of cyclonic wind in the area of the cloud cluster that finally led to the tropical storm, while no apparent increase of wind was found in the other cloud clusters. In addition, water vapor amount did not decrease for several days until the disturbance was upgraded to a tropical storm, while it was found to decrease after the mature stage for the other cloud clusters that did not evolve into tropical storms.From consideration of the water vapor balance, the cyclogenesis can be interpreted as a transition from an unbalanced cluster to a balanced cluster. Horizontal transfer of water vapor in a water vapor-unbalanced cloud cluster is not large enough to overcome the deficit caused by precipitation over evaporation. The shortage of water vapor in the unbalanced cluster results in a short-lived cloud cluster. When the sum of evaporation and horizontal transfer can provide enough water vapor supply to balance the removal by precipitation (balanced cluster), the precipitation does not dry up the atmosphere. This is the necessary condition for the cyclogenesis. The increase in horizontal transfer of water vapor is found in this study to be associated with the increase of the surface cyclonic wind.With 5 Figures 相似文献
3.
Antti Lauri Joonas Merikanto Evgeni Zapadinsky Hanna Vehkamki 《Atmospheric Research》2006,82(3-4):489
We compare two molecular Monte Carlo simulation methods, the discrete summation method and the growth/decay method, which calculate the vapor-liquid nucleation free energy barrier by simulating isolated clusters of fixed size without the surrounding vapor. The methods are applied to calculations of nucleation barriers of Lennard–Jones argon at 60 K and 80 K. Both of these methods are computationally efficient, as only isolated clusters without the surrounding vapor are simulated, and the methods can be applied with any given cluster definition. They give equivalent results to other methods where the vapor phase is also included. The discrete summation method is based on the calculation of the difference in free energies between two systems containing an n-cluster and an (n − 1)-cluster plus one non-interacting (free) molecule. We show that the configurational space is not equivalent in the two systems. Hence, there has to be an additional term in the free energy calculation that accounts for several kT in magnitude. In contrast to previous studies we also show that it is not correct to prevent the overlap of the non-interacting molecule and another molecule by a zero or an arbitrarily small repulsive potential, but with a small excluded space around the free molecule. 相似文献
4.
《Atmospheric Research》2007,83(3-4):489-502
We compare two molecular Monte Carlo simulation methods, the discrete summation method and the growth/decay method, which calculate the vapor-liquid nucleation free energy barrier by simulating isolated clusters of fixed size without the surrounding vapor. The methods are applied to calculations of nucleation barriers of Lennard–Jones argon at 60 K and 80 K. Both of these methods are computationally efficient, as only isolated clusters without the surrounding vapor are simulated, and the methods can be applied with any given cluster definition. They give equivalent results to other methods where the vapor phase is also included. The discrete summation method is based on the calculation of the difference in free energies between two systems containing an n-cluster and an (n − 1)-cluster plus one non-interacting (free) molecule. We show that the configurational space is not equivalent in the two systems. Hence, there has to be an additional term in the free energy calculation that accounts for several kT in magnitude. In contrast to previous studies we also show that it is not correct to prevent the overlap of the non-interacting molecule and another molecule by a zero or an arbitrarily small repulsive potential, but with a small excluded space around the free molecule. 相似文献
5.
分析1980~2002年主汛期(5~7月)广西锋面型大范围暴雨期间孟加拉湾对流云团演变及与之相应高低空环流变化,结果表明:孟加拉湾强对流在广西暴雨发生前3天发展最为旺盛,受孟加拉湾低槽引导,对流云团爬上中南半岛进入广西,当其与高原东移的云团相结合时再次发展,造成广西大范围暴雨。分析200 hPa高度场和流场结果表明:当广西暴雨发生时,孟加拉湾、中南半岛及广西受200 hPa南亚高压控制。分析850 hPa水汽通量矢量场结果表明:广西锋面型暴雨发生时,从孟加拉湾到广西上空有一西南气流的水汽输送带,广西暴雨水汽主要来源于孟加拉湾。 相似文献
6.
The incorporation of additional information on free energies of small clusters in a cluster distribution based on the capillarity approximation is considered in relation with self-consistency (SC). The concept of fictitious average monomers is applied to expand the self-consistent form of a unary size distribution to cover also the distribution of a binary system. The experimental data on the free energies of monohydrates and dihydrates of sulfuric acid are used to obtain the partially self-consistent size distribution of clusters. Using these distributions, the concentrations of sulfuric acid and water, required for obtaining a unit nucleation rate, are calculated and compared among themselves and with experimental concentrations. Free energies of cluster formation are estimated by the thermodynamically consistent classical theory taking into account the difference between interior and surface compositions of a cluster. The partially self-consistent size distribution gives the best agreement with experimental data. The self-consistent distribution of the proposed form overestimates hydration and, therefore, largely underestimates nucleation rates compared to experimental rates. 相似文献
7.
《Atmospheric Research》2009,91(2-4):303-312
Nucleation phenomena have a great importance in many areas of science. However, the main theoretical tool to analyse these phenomena, the classical nucleation theory (CNT), has known weaknesses. A decade ago a nucleation theorem based correction to CNT was developed [McGraw, R., Laaksonen, A., 1996. Scaling properties of the critical nucleus in classical and molecular-based theories of vapor–liquid nucleation. Phys. Rev. Lett. 76, 2754–2757]. We have analysed experimental nucleation rate data of two homologous series of molecular fluids in terms of this scaling relation. Our first results suggest possible universal functional form for correction to the temperature dependence of CNT. 相似文献
8.
The rainfall distribution within the rainy season has crucial implications on a variety of disciplines. According to one approach of analyzing the intraseasonal rainfall distribution, it is essential to examine the date of different accumulated percentage (DAP hereafter), as presented in Paz and Kutiel (Isr J Earth Sci 52:47–63, 2003). The present study identifies various intraseasonal temporal distributions of rainfall, in 41 stations within the Mediterranean basin. Furthermore, classifications of these distributions according to their time, yield, and length are presented. The accumulated percentage was calculated for each Julian day for every available year in all stations. A correlation matrix between every possible pair of years, in each station, was calculated, and a cluster analysis (average linkage method) was performed. Finally, the averages of the entire dataset and the average of every cluster were compared in order to classify the clusters by using three parameters: timing represented by DAP(25%, 50%, 75%) annual rainfall total and the rainy season length (RSL). Between 2 and 5 different types of clusters, with various probabilities, were defined for every station. Out of 132 overall clusters, which were found in 41 stations, the most frequent type (cluster 1) was the median in all three parameters. There were 16 clusters identified as short in their RSL, and 18 were identified as having a long classification. There were 19 dry clusters, and only eight were identified as wet. As for the parameter of timing, 39 clusters were classified as early and 38 as late. One conclusion of this study was that the probability of a dry year is higher than a wet one, and likewise, the probability of a long year is higher than of a short one. 相似文献
9.
《Atmospheric Research》2007,83(3-4):605-609
This article presents the results of an experimental investigation on gas-phase coating of nanometer-sized NaCl aerosol particles with a condensing vapor of ZnCl2. The coating process has been carried out in a commercially available Venturi aspirator, where the NaCl at ambient temperature is mixed with the supersaturated ZnCl2 vapor. The operating conditions (ZnC12 vapor temperature, and ZnCl2/NaCl flow rate ratio) at which the ZnCl2 vapor preferentially nucleates onto the surface of the seed NaCl particles forming a coating layer on them, have been determined. Particle size growth as a function of the original seed diameter has also been determined. Smaller particles undergo a larger relative size growth ratio. It has also been shown that the presence of a coating layer does not affect the charge distribution of the original seed particles. 相似文献
10.
This article presents the results of an experimental investigation on gas-phase coating of nanometer-sized NaCl aerosol particles with a condensing vapor of ZnCl2. The coating process has been carried out in a commercially available Venturi aspirator, where the NaCl at ambient temperature is mixed with the supersaturated ZnCl2 vapor. The operating conditions (ZnC12 vapor temperature, and ZnCl2/NaCl flow rate ratio) at which the ZnCl2 vapor preferentially nucleates onto the surface of the seed NaCl particles forming a coating layer on them, have been determined. Particle size growth as a function of the original seed diameter has also been determined. Smaller particles undergo a larger relative size growth ratio. It has also been shown that the presence of a coating layer does not affect the charge distribution of the original seed particles. 相似文献
11.
12.
This paper describes a diagnostic study of the feedback mechanism in greenhouse effects of increased CO_2 and oth-er trace gases(CH_4,N_2O and CFCs),simulated by general circulation model.The study is based on two sensitivity exper-iments for doubled CO_2 and the inclusion of other trace gases,respectively,using version one of the community climatemodel(CCM1)developed at the National Centre for Atmospheric Research.A one-dimensional(1-D)and atwo-dimensional(2-D)radiative-convective models are used to diagnose the feedback effect.It shows that thefeedback factors in global and annual mean conditions are in the sequence of surface albedo,water vapor amount,watervapor distribution,cloud height,critical lapse rate and cloud cover,while in zonal and annual mean conditions in thetropical region the above sequence does not change except the two water vapor terms being the largest feedback compo-nents.Among the feedback components,the total water vapor feedback is the largest(about 50%).The diagnosis alsogives a very small feedback of either the cloud cover or the lapse rate,which is substantially different from the 1-Dfeedback analysis by Hansen et al.(1984).The small lapse rate feedback is considered to be partly caused by theconvective adjustment scheme adopted by CCM1 model.The feedback effect for doubled CO_2 is very different from that of the addition of other trace gases because of theirdifferent vertical distributions of radiative forcing although the non-feedback responses of surface air temperature forboth cases are almost the same.For instance,the larger forcing at surface by the addition of other trace gases can causestronger surface albedo feedback than by doubled CO_2.Besides,because of the negative forcing of doubled CO_2 in thestratosphere,cloud height feedback is more intense.The larger surface forcing in the case of other trace gases can also in-fluence atmospheric water vapor amount as well as the water vapor distribution,which will in turn have strongerfeedback effects.All these indicate that it is incorrect to use“effective CO_2”to replace other trace gases in the generalcirculation model. 相似文献
13.
A.-K. Viitanen T. Mattila J.M. Mkel M. Marjamki O. Anttalainen J. Keskinen 《Atmospheric Research》2008,90(2-4):115-ICNAA07
Ion mobility spectrometry offers a robust and effective technique to study ion clusters in ambient conditions. Here, we have experimentally studied the influence of temperature on the positive ion cluster formation of 2-propanol vapor in air, along with parallel measurements for n-butyl acetate vapor in air. For both of these low proton affinity compounds in the ppm concentration range, temperatures below 0 °C tend to favor formation of dimers and trimers. The measurements indicate that approximate estimations for the fractions of these n-mers (n > 1) in the ion spectra, can be obtained by classical theory for ion induced nucleation. Presence of natural background vapors however slightly blurs the data, especially for the fraction of monomers, so that accurate prediction of the fractions of n-mers in the spectra would require more accurate information on the gas composition. The findings concerning thermal behavior of ions help to understand better ion phenomena also in field conditions. 相似文献
14.
Kinematics, cloud microphysics and spatial structures of tropical cloud clusters: A two-dimensional cloud-resolving modeling study 总被引：4，自引：1，他引：3
Kinematics, cloud microphysics and spatial structures of tropical cloud clusters are investigated using hourly outputs from a two-dimensional cloud-resolving model simulation. The model is forced by the large-scale vertical velocity, zonal wind and horizontal advections obtained from Tropical Ocean Global Atmosphere Coupled Ocean–Atmosphere Response Experiment (TOGA COARE). A period of 1600–2300 LST 21 December 1992 is selected for this study when the zonal-mean westerly winds in the lower troposphere intensify while the zonal-mean easterly winds above weaken. Under the vertical-shear environment, there are a westward-propagating cloud cluster, a newly-formed cloud cluster, and four eastward-moving cloud clusters. Two weak eastward-moving cloud clusters merge into strong westward-moving cloud clusters. Merged clouds display notable growth in the eastern edge, indicating that merging processes enhance convection. The development of the new cloud at the western edge of the existing cloud cluster before merging may account for the westward propagation of cloud cluster group, while the advection of the maximum total hydrometeor mixing ratio by the westerly winds after merging may cause the eastward propagation of individual cloud clusters. 相似文献
15.
The Indian landmass has been divided into homogeneous clusters by applying the cluster analysis to the probability density function of a century-long time series of daily summer monsoon (June through September) rainfall at 357 grids over India, each of approximately 100 km × 100 km. The analysis gives five clusters over Indian landmass; only cluster 5 happened to be the contiguous region and all other clusters are dispersed away which confirms the erratic behavior of daily rainfall over India. The area averaged seasonal rainfall over cluster 5 has a very strong relationship with Indian summer monsoon rainfall; also, the rainfall variability over this region is modulated by the most important mode of climate system, i.e., El Nino Southern Oscillation (ENSO). This cluster could be considered as the representative of the entire Indian landmass to examine monsoon variability. The two-sample Kolmogorov-Smirnov test supports that the cumulative distribution functions of daily rainfall over cluster 5 and India as a whole do not differ significantly. The clustering algorithm is also applied to two time epochs 1901–1975 and 1976–2010 to examine the possible changes in clusters in a recent warming period. The clusters are drastically different in two time periods. They are more dispersed in recent period implying the more erroneous distribution of daily rainfall in recent period.
相似文献16.
Cluster analysis of post-landfall tracks of landfalling tropical cyclones over China 总被引：1，自引：0，他引：1
In this paper, we apply finite-mixture-model-based clustering algorithms to cluster post-landfall tracks of tropical cyclones (TCs) making landfall over China. Because existing studies find that landfall surfaces or elevations affect post-landfall TC movements, we also take account of elevations in addition to time orders in this model. Our study reveals three clusters, with cluster 1 making landfall in Hainan province and moving across the western coast of Guangdong province. Most of the TC tracks in cluster 1 move over the ocean and make secondary landfalls over Yunnan province of China and Vietnam. Cluster 1 finally dissipates inland and moves westward as a result of the westward-shift subtropical high, westward steering flow, easterly vertical wind shear and strong mountainous blocking. Cluster 2 makes landfall over Guangdong and Fujian provinces. TCs in cluster 2 subsequently move inland and disappear due largely to westward-shift subtropical high, easterly steering flow, easterly vertical wind shear and relatively strong mountainous blocking. Cluster 3 makes landfall along the Fujian and Zhejiang coast and sustains a long period of time, recurving mostly to the mid-latitude region owing to the surrounding eastward-shift subtropical high, westerly vertical wind shear, weak mountainous blocking and westerly steering flow. Because cluster 2 is significantly associated with La Niña events, TCs more likely make landfall over southeastern China coast and move westward or northwestward without recurving. Cluster 3 sustains a longer time than clusters 1 and 2 in spite of its weak horizontal and vertical water vapor supply. TCs in cluster 3 interact actively with westerlies during the post-landfall period. However, we cannot observe any analogous interactions with the mid-latitude westerlies in clusters 1 and 2. TCs of clusters 1 and 2 are influenced by summer monsoon flows. Moreover, summer monsoon exerts a greater influence on cluster 1 than cluster 2. The composite 200 hPa divergence of cluster 3 is stronger than that of clusters 1 and 2. This explains to some degree why cluster 3 sustains longer than clusters 1 and 2 after making landfall. 相似文献
17.
In the first part of this study, results of a computational fluid dynamics simulation over an array of cubes have been validated
against a set of wind-tunnel measurements. In Part II, such numerical results are used to investigate spatially-averaged properties
of the flow and passive tracer dispersion that are of interest for high resolution urban mesoscale modelling (e.g. non resolved
obstacle approaches). The results show that vertical profiles of mean horizontal wind are linear within the canopy and logarithmic
above. The drag coefficient, derived from the numerical results using the classical formula for the drag force, is height
dependent (it decreases with height). However, a modification of the formula is proposed (accounting for subgrid velocity
scales) that makes the drag coefficient constant with height. Results also show that the dispersive fluxes are similar in
magnitude to the turbulent fluxes, and that they play a very important role within the canopy. Vertical profiles of turbulent
length scales (to be used in k–l closure schemes, where k is the turbulent kinetic energy and l a turbulent length scale) are also derived. Finally the distribution of the values around the mean over the reference volumes
are analysed for wind and tracer concentrations. 相似文献
18.
该文根据中国高空气候标准值 (1971—2000年) 逐月数据集124个探空站资料,计算出各站的整层大气水汽含量,并绘制出年水汽含量分布,除青藏高原地区外,其余地区基本上呈纬向分布。继而配合我国地面气候标准值逐月数据集的水汽压和地面气压数据,在对水汽压进行相应的订正后,将其与整层水汽含量进行相关分析,拟合出全国普遍适用的、统一的或分月的线性经验表达式。拟合结果与实测值之间的均方根误差为0.25 cm。文中还详细讨论了多项式不同次数对拟合结果的影响,结果表明:与数据点走向拟合较好的多项式,次数高其结果并非误差最小。利用经地面气压订正的地面水汽压 (x) 与整层水汽含量 (y) 的拟合公式为y=0.185x+0.093,其最大优点是站点无论高低、不分地域普遍适用。 相似文献
19.
“0811”暴雨过程中MCC与一般暴雨云团的对比分析 总被引：3，自引：0，他引：3
利用T639 1°×1°分析场、FY-2红外云图、红外辐射亮温(TBB)、闪电定位和气柱水汽总量等资料,对2010年8月11日发生在山西南部暴雨过程(即"0811"暴雨过程)中的中尺度对流复合体(MCC)和其北部的一般暴雨云团进行了对比分析,结果表明,(1)山西北部暴雨带主要由6个β中尺度对流云团生成、发展及合并造成;山西南部区域性暴雨则由MCC的生成、发展、东移所引发。(2)山西北部的暴雨云团在850hPa暖切变线南部生成和发展,并在地面切变线附近合并;山西南部的MCC由3个β中尺度对流云团发生、发展及合并形成,该对流云团在700hPa次天气尺度切变线上触发生成;MCC发展、成熟阶段,α中尺度云团沿925hPa暖切变线东移;减弱阶段,随西太平洋副热带高压的南退而南压。(3)在西太平洋副热带高压西进北抬的背景下,同一次暴雨过程中,MCC发生在5 880gpm边缘弱的斜压环境中,高层则出现在高压北侧的反气旋环流中;一般暴雨云团发生在5 840gpm边缘较强的斜压环境中,高层则出现在急流入口区的右侧。(4)MCC作为大型的中尺度对流系统,不但对低层高温高湿能量的需求比一般暴雨云团更多,而且在垂直方向上,要求湿层、高能舌及暖温结构更深厚。(5)山西南部MCC影响区和5 880gpm线边缘为负地闪覆盖区,正地闪主要出现在其北部一般暴雨云团影响区和5 840gpm线附近。与MCC相比,一般暴雨云团影响下,局地闪电开始及闪电峰值的出现较降水的开始及降水峰值的出现有更多的提前量。(6)山西北部暴雨云团出现在气柱水汽总量梯度的大值区及水汽锋上;山西南部MCC则出现在水汽锋南侧气柱水汽总量的大值区。气柱水汽总量对"0811"暴雨过程有36h的提前量,对暴雨的落区有很好的指示意义。 相似文献
20.
本文根据大气中NO_2形成HNO_3的主要化学反应求解带有化学反应的扩散方程而得到HNO_3生成量的空间分布。HNO_3气体形成后边扩散边被降水清洗带至地面。我们又求解了HNO_3气体的扩散方程,考虑降水清洗从而得到HNO_3被降水带至地面的湿沉降量,得到水平面上HNO_3在24h内的分布,可用来大致估计HNO_3污染程度及范围。 相似文献