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1.
Integration of calcareous nannofossil data, δ13C and δ18O values, and carbonate contents of the lower Paleocene–upper Paleocene sequence that crops out at the Misheiti section, East Central Sinai, Egypt, were used to denote the Danian/Selandian (D/S) and Selandian/Thanetian (S/T) stage boundaries. The study interval belongs to the Dakhla and Tarawan formations. Four calcareous nannofossil zones (NP4, NP5, NP6, and NP7/8) were recognized. The base of the Selandian Stage is tentatively placed at the lowest occurrences (LOs) of taxa ascribable to the second radiation of fasciculiths (i.e., Lithoptychius janii). This level is marked by a sudden drop of δ13C and δ18O values and carbonate content. No distinctive lithological changes were observed across the D/S boundary at the study section. A hiatus at the NP5/NP6 zonal boundary is indicated by the condensation of zones NP5 and NP6.The base of the Thanetian is placed at the base of Zone NP7/8 at the lithological change observed in correspondence to the boundary between the Dakhla and Tarawan formations. The δ13C and δ18O values abruptly decrease slightly above the base of Zone NP7/8. No consistent variations in the carbonate contents were recorded within Zone NP6 or across the NP6/NP7/8 zonal boundary.  相似文献   

2.
We use the evolution of river sediment characteristics and sedimentary Corg from the Himalayan range to the delta to study the transport of Corg in the Ganga-Brahmaputra system and especially its fate during floodplain transit.A detailed characterisation of both mineral and organic particles for a sampling set of river sediments allows taking into account the sediment heterogeneity characteristic of such large rivers. We study the relationships between sediment characteristics (mineralogy, grain size, specific area) and Corg content in order to evaluate the controls on Corg loading. Contributions of C3 and C4 plants are estimated from Corg stable isotopic composition (δ13Corg). We use the evolution of δ13Corg values from the Himalayan range to the delta in order to study the fate of Corg during floodplain transit.Ganga and Brahmaputra sediments define two distinct linear relations with specific area. In spite of 4-5 times higher specific area, Ganga sediments have similar Corg content, grain size and mineralogy as Brahmaputra sediments, indicating that specific area does not exert a primary control on Corg loading. The general correlation between the total Corg content and Al/Si ratio indicates that Corg loading is mainly related to: (1) segregation of organic particles under hydrodynamic forces in the river, and (2) the ability of mineral particles to form organo-mineral aggregates.Bed and suspended sediments have distinct δ13Corg values. In bed sediments, δ13Corg values are compatible with a dominant proportion of fossil Corg derived from Himalayan rocks erosion. Suspended sediments from Himalayan tributaries at the outflow of the range have low δ13Corg values (−24.8‰ average) indicating a dominant proportion of C3 plant inputs. In the Brahmaputra basin, δ13Corg values of suspended sediments are constant along the river course in the plain. On the contrary, suspended sediments of the Ganga in Bangladesh have higher δ13Corg values (−22.4‰ to −20.0‰), consistent with a significant contribution of C4 plant derived from the floodplain. Our data indicate that, during the plain transit, more than 50% of the recent biogenic Corg coming from the Himalaya is oxidised and replaced by floodplain Corg. This renewal process likely occurs during successive deposition-erosion cycles and river course avulsions in the plain.  相似文献   

3.
The stratigraphy, sedimentology and syn-depositional tectonic events (SdTEs) of the Upper Cretaceous/Paleogene (K–P) succession at four localities in north Eastern Desert (NED) of Egypt have been studied. These localities are distributed from south-southwest to north-northeast at Gebel Millaha, at North Wadi Qena, at Wadi El Dakhal, and at Saint Paul Monastery. Lithostratigraphically, four rock units have been recorded: Sudr Formation (Campanian–Maastrichtian); Dakhla Formation (Danian–Selandian); Tarawan Formation (Selandian–Thanetian) and Esna Formation (Thanetian–Ypresian). These rock units are not completely represented all over the study area because some of them are absent at certain sites and others have variable thicknesses. Biostratigrapgically, 18 planktonic foraminiferal zones have been recorded. These are in stratigraphic order: Globotruncana ventricosa Zone (Campanian); Gansserina gansseri, Contusotruncana contusa, Recimguembelina fructicosa, Pseudohastigerina hariaensis, Pseudohastigerina palpebra and Plummerita hantkenenoides zones (Maastrichtian); Praemurica incostans, Praemurica uncinata, Morozovella angulata and Praemurica carinata/Igorina albeari zones (Danian); Igorina albeari, Globanomanlina pseudomenradii/Parasubbotina variospira, Acarinina subsphaerica, Acarinina soldadoensis/Globanomanlina pseudomenardii and Morozovella velascoensis zones (Selandian/Thantian); and Acarinina sibaiyaensis, Pseudohastigerina wilcoxensis/Morozovella velascoensis zones (earliest Ypresian). Sedimentologically, four sedimentary facies belts forming southwest gently-dipping slope to basin transect have been detected. They include tidal flats, outer shelf, slumped continental slope and open marine hemipelagic facies. This transect can be subdivided into a stable basin plain plus outer shelf in the extreme southwestern parts; and an unstable slope shelf platform in the northeastern parts. The unstable slope shelf platform is characterized by open marine hemipelagic, fine-grained limestones and fine siliciclastic shales (Sudr, Dakhla, Tarawan and Esna formations). The northeastern parts are marked by little contents of planktonic foraminifera and dolomitized, slumped carbonates, intercalated with basinal facies. Tectonically, four remarkable syn-depositional tectonic events (SdTEs) controlled the evolution of the studied succession. These events took place strongly within the Campanian–Ypresian time interval and were still active till Late Eocene. These events took place at: the Santonian/Campanian (S/C) boundary; the Campanian/Maastrichtian (C/M) boundary; the Cretaceous/Paleogene (K/P) boundary; and the Middle Paleocene–Early Eocene interval. These tectonic events are four pronounced phases in the tectonic history of the Syrian Arc System (SAS), the collision of the Afro-Arabian and Eurasian plates as well as the closure of the Tethys Sea.  相似文献   

4.
Marine sedimentary phosphorites of Eocene age (Upper Ypresian) are exposed in the extreme west of Iraq within the Dammam Formation. They are associated with limestone and chert, and their deposition seems to have taken place in a shallow marine environment within a structurally controlled basin open to the sea from the northern and western sides only.The studied phosphorites are granular in texture, coarse-grained and cemented by calcite which is occasionally silicified. Bone fragments are present in small amounts. Carbonate-fluorapatite is the only phosphate mineral detected in these phosphorites, with relatively high amounts of the components SO4?2, CO3?2, F?1, H3O1 and Na1 substituting in the crystal structure.The Lower Eocene phosphorites of Iraq are part of the Tethyan phosphorite province, and are comparable in many aspects with those of Paleocene and Upper Cretaceous age in the Western Desert of the country.  相似文献   

5.
The relatively complete late Danian-initial Lutetian succession of biotic events, which are suitable to serve as biostratigraphic reference levels for interregional correlations are defined in the section of the Novouzensk reference borehole based on dinocyst and nannoplankton assemblages. The analysis of palynological and nannofossil assemblages allows dynamics of basin development and sea-level fluctuations to be traced. Three major stages reflecting different sedimentation regimes are established in the borehole section: (1) Danian with terrigenous-carbonate sedimentation regime corresponding to the Algai and Tsyganovka formations; (2) Selandian-Thanetian (initial Eocene included) characterized largely by siliceous-terrigenous sediments of the Syzran, Novouzensk, and, partly, Bostandyk formations; (3) Ypresian-Lutetian with the carbonate-terrigenous sedimentation regime corresponding to the upper part of the Ypresian Bostandyk and Lutetian Kopterek formations. The composition of dinoflagellate and nannoplankton assemblages characterizes the North Caspian basin as an internal largely shallow sea with a changeable temperature regime. The paleoecological analysis of phytocoenoses made it possible to define basin fluctuations comparable with third-order rhythms. Four Danian rhythms definable in the Algai and Tsyganovka formations indicate conditions of an open warm-water basin. Dynamics of the step-wise shoaling of the basin was characteristic of the Selandian-early Thanetian ages with subsequent restoration of the marine regime in the late Thanetian. The Syzran Formation corresponds to two Selandian rhythms, which were formed in shallower settings of the restricted sea basin. Four Thanetian rhythms are established in the Novouzensk Formation. The early Thanetian basin was characterized by the shallowest disturbed marine conditions, which were followed by the restored normal marine regime in the late Thanetian. Six Ypresian rhythms correspond to the Bostandyk Formation (Yp-0, Yp-1, Yp-5-Yp-8) reflecting transition from initial Ypresian coastal (Yp-0, Yp-1) to normal marine conditions during the Yp-5 rhythm. The early (Yp-2-Yp-4) and late (Yp-9-Yp-10) Ypresian corresponded to the sedimentation break. Most abundant and diverse microbiotic assemblages characteristic of the Yp-7 rhythm are correlative with the EECO event. The marly Kopterek Formation corresponding to the early Lutetian rhythm (Lu-1) is characterized by diverse thermophilic biota.  相似文献   

6.
As an indicator for terrestrial paleovegetation, the stable isotopic composition of total organic matter (δ13Corg) in loess sediments has been widely used for paleoclimatic reconstruction in western Europe, the Great Plains of North America and the Chinese Loess Plateau (CLP). However, little is known about the variation and paleoclimatic significance of the loess δ13Corg in arid Central Asia (ACA). We report δ13Corg data from an Axike (AXK) loess/paleosol profile from the eastern Ili Basin, eastern Central Asia. Along the profile, the δ13Corg values were more negative in the paleosol layers observed in the field and were confirmed by environmental magnetic proxies and a higher concentration of total organic carbon (TOC), consistent with results for western Europe and the northwestern CLP. Our results demonstrate that the loess δ13Corg in this region documents mainly the response of δ13C of locally predominant C3 plants to paleoclimatic variation, especially paleoprecipitation. Our results also suggest that the loess δ13Corg values in the area have the potential for quantitative paleoprecipitation reconstruction on the basis of detailed δ13Corg results from modern plants and surface soils in the future.  相似文献   

7.
During the Ordovician, huge biological revolutions and environmental changes happened in Earth’s history, including the Great Ordovician Biodiversification Event, global cooling and so on, but the cause of these events remains controversial. Herein, we conducted a paired carbon isotopic analysis of carbonate (δ13Ccarb) and organic matter (δ13Corg) through the Ordovician in the Qiliao section on the Yangtze platform of South China. Our results showed that the δ13Ccarb trend of the Qiliao section can be correlated with local and global curves. The δ13Corg trend seems is less clear than the δ13Ccarb trend for stratigraphic correlations, but some δ13Corg positive excursions in the Middle and Upper Ordovician may be used for correlation studies. These carbon isotopic records may have global significance rather than local significance, revealing several fluctuations to the global carbon cycle during the Ordovician. Several known δ13Ccarb and δ13Corg negative and positive excursions have been recognised in this study, including the early Floian Negative Inorganic Carbon (δ13Ccarb) Excursion (EFNICE), as well as the early Floian Positive Organic Carbon (δ13Ccarb) Excursion, the mid-Darriwilian Inorganic Carbon (δ13Ccarb and δ13Corg) Excursion (MDICE), and the early Katian Guttenberg Inorganic Carbon (δ13Ccarb and δ13Corg) Excursion (GICE). These positive excursions and a smooth decline trend of δ13Corg values during the early to mid-Floian may imply multiple episodes of enhanced organic carbon burial that began at the early Floian stage, probably resulting in further decline in atmospheric pCO2 and then global cooling.  相似文献   

8.
The early Aptian abrupt carbon isotope excursion in marine carbonate and sedimentary organic matter reflects a major perturbation in the global carbon cycle. However, until now almost all the evidences of this event came from marine deposits. Here we present organic-carbon isotope (δ13Corg) data from the non-marine Jehol Group in western Liaoning, China. The lacustrine δ13Corg curve is marked by a relative long-lasting δ13Corg minimum followed by two stages of positive δ13Corg excursions that are well correlated with contemporaneous marine records. The carbon isotope correlation shows that the lacustrine strata of the Jehol Group were deposited at the same time of the early Aptian Oceanic Anoxic Event (OAE1a). The relative long-lasting δ13Corg minimum supports the hypothesis that volcanic CO2 emission may have played the main role in triggering the negative δ13C excursion and global warming at the onset of this event. In addition, the onset of δ13Corg minimum is concomitant with the radiation of the Jehol Biota, implying that the evolutionary radiation of the Jehol Biota may have been closely related with the increase in atmospheric CO2 and temperature.  相似文献   

9.
The Cenomanian–Turonian boundary was characterized by distinctive positive carbon isotope excursions that were related to the formation of widespread oceanic anoxia. High-resolution geochemical proxies (TOC, CaCO3, δ13Corg, and δ13Ccarb) obtained from bulk rock, planktic foraminifers, and inoceramids from four marine marlstone-dominated stratigraphic sections in the Western Canada Sedimentary Basin (WCSB) were used to establish a regional carbon isotope stratigraphic framework and to investigate paleoenvironmental variability in four different depositional settings. Compared to background δ13Corg, (<−27‰) and δ13Ccarb (<2‰) values which were correlative to stable isotope excursions during Oceanic Anoxic Event (OAE) II worldwide, the δ13Corg (>24‰), and δ13Ccarb (>4‰) derived from inoceramid prisms in the studied sections within WCSB, were elevated during the Late Cenomanian–Early Turonian. During this interval, TOC and CaCO3 values which increased sporadically to >40% and 7%, respectively, were not consistent enough to be used for stratigraphic correlations. Based on the δ13Corg excursions, two bentonite beds were regionally correlated across this portion of the Western Interior Seaway (WIS). The eruption associated with the “Red” bentonite occurred approximately coeval with the maximum δ13Corg-excursion during OAE II in the Neocardioceras juddii Zone, whereas the “Blue” bentonite coincides with the termination of OAE II in the latest Watinoceras devonense zone. During the Late Cenomanian–Early Turonian in the WCSB, benthic foraminifers were sparse or totally absent, indicating the existence of fully anoxic bottom-water conditions. Planktic foraminifera were common in the well-oxygenated surface waters. A benthic oxic zone characterized by several agglutinated species occurs in the eastern part of the WSCB at the beginning of OAE II in the Sciponoceras gracile zone. The termination of the OAE II in the WCSB coincides with the first occurrence of small ammonites (Subprionocyclus sp.) in the western part of the basin.  相似文献   

10.
The Qreiya Beds that record the ‘mid-Paleocene event’ at Gabal Nezzazat occur within the Igorina albeari (P3b) Zone and constitute part of a 14-m thick shale succession that ranges in age from Early to Late Paleocene. They are composed of four alternating dark grey and brown shale beds, which are thinly laminated, phosphatic, organic-rich and extremely sulphidic. They are characterized by distinct enrichment and high peak anomalies in chalcophiles (Zn, Co, Ni, Cu and Pb) and organic association elements (V and Cr), especially within the brown organic-rich beds. It is concluded that these elements are incorporated into the phosphatic debris, sulphides and organic matter. In contrast, the grey beds are enriched in clay minerals and quartz. Clay mineral assemblages indicate alternating periods of warm/humid climate (high kaolinite) and dry climate (low kaolinite) during the formation of the grey and brown beds, respectively. The sediments of the Qreiya Beds yield lithological, biotic, geochemical and mineralogical data indicative of suboxic/anoxic marine environments as a result of high productivity and/or upwelling. The top metre of the succession below the Qreiya Beds is characterized by a progressive change from faunas dominated by praemurcurids to faunas dominated by Morozovilids, and by a progressive upward decrease in δ13Ccarb and δ18Ocarb values. The foraminiferal faunal change may reflect shallowing and warming preceding deposition of the Qreiya Beds. The change in isotopic values is inferred to be the result of surface weathering, fluvial input and diagenesis with no evidence of any primary change that could support presence of a hyperthermal event.  相似文献   

11.
Benthic foraminifers from borehole sections recovered by drilling in the Yamal Peninsula, West Siberia, characterize the Ceratobulimina cretacea Beds (the upper Campanian-lower Maastrichtian) and the Spiroplectammina variabilis-Gaudryina rugosa spinulosa and Spiroplectammina kasanzevi-Bulimina rosenkrantzi regional zones of the lower and upper Maastrichtian, respectively. The Danian Stage is missing from the sections, which include marine deposits of the Selandian Stage attributed to the Ceratolamarckina tuberculata Beds. Foraminiferal assemblages of the beds include the Siberian endemic species associated with Paleocene foraminifers of the Midway-type fauna of subglobal distribution range. Occurrence of the latter suggests that warm-water surface currents from the North Atlantic reached southern areas of the Kara Sea.  相似文献   

12.
A series of layers rich in organic matter (sapropelites) is known in the upper Ypresian deposits of the northeastern Peri-Tethys. Study of formainifers and quantitative analysis of their different ecological groups showed that proportion of infauna is considerably grater in sapropelic layers than in host deposits. In distinction from infauna, tests of species not burrowing into sediments (epifauna) are partially dissolved. The analyzed paleocoenoses of benthic foraminifers imply that sapropelites have been formed most likely in dysoxic environments, under conditions of the bottom waters contamination by carbon dioxide in response to a high Corg influx, weakened water circulation and low oxygen concentration. The comparison of foraminiferal assemblages with paleocoenoses studied previously in the Paleocene/Eocene boundary sapropelic interbed suggests that deposits rich in Corg originated under the same hydrogeochemical environments.  相似文献   

13.
The Late Cretaceous (Maastrichtian) to early Paleocene (Thanetian) shallow water (<100 m) agglutinated foraminifera from a section at Dakhla Oasis (Western Desert, Egypt) were analyzed for their assemblage, species and genera distribution, diversity, depositional environment, community structure and palaeobathymetry with respect to regional tectonics, climate and global eustasy. Data suggest an equitable benthic environment with low species dominance deposited in a brackish littoral and/or marsh setting. Sea level curves using characteristic benthic foraminiferal species, genera and assemblages corroborate quantitatively generated estimate and statistical analysis. Data suggests that in the absence of or of an impoverished benthic foraminiferal fauna, a high resolution agglutinated foraminiferal dataset can be as good a predictor of the benthic community structure and environment, as its calcareous counterpart, at least for shallow settings (<100 m). Present data also provides a good window in better understanding the distribution and interrelationship between the three dominant genera, Haplophragmoides, Trochammina and Ammobaculites. Faunal changes at boundaries (Cretaceous/Paleogene, Danian/Selandian and Selandian/Thanetian) are also evaluated.  相似文献   

14.
The chemical composition of organic matter (Corg, Norg, δ13C, δ15N, and n-alkanes) was studied in the top layer of bottom sediments of the East Siberian Sea. Possible ways were proposed to estimate the amount of the terrigenous component in their organic matter (OM). The fraction of terrigenous OM estimated by the combined use of genetic indicators varied from 15% in the eastern part of the sea, near the Long Strait, to 95% in the estuaries of the Indigirka and Kolyma rivers, averaging 62% over the sea area.  相似文献   

15.
Subaerial exposure and oxidation of organic carbon (Corg)-rich rocks is believed to be a key mechanism for the recycling of buried C and S back to Earth's surface. Importantly, processes coupled to microbial Corg oxidation are expected to shift new biomass δ13Corg composition towards more negative values relative to source. However, there is scarcity of information directly relating rock chemistry to oxidative weathering and shifting δ13Corg at the rock-atmosphere interface. This is particularly pertinent to the sulfidic, Corg-rich alum shale units of the Baltoscandian Basin believed to constitute a strong source of metal contaminants to the natural environment, following subaerial exposure and weathering. Consistent with independent support, we show that atmospheric oxidation of the sulfidic, Corg-rich alum shale sequence of the Cambrian-Devonian Baltoscandian Basin induces intense acid rock drainage at the expense of progressive oxidation of Fe sulfides. Sulfide oxidation takes priority over microbial organic matter decomposition, enabling quantitative massive erosion of Corg without producing a δ13C shift between acid rock drainage precipitates and shale. Moreover, 13C enrichment in inorganic carbon of precipitates does not support microbial Corg oxidation as the predominant mechanism of rock weathering upon exposure. Instead, a Δ34S = δ34Sshale − δ34Sprecipitates ≈ 0, accompanied by elevated S levels and the ubiquitous deposition of acid rock drainage sulfate minerals in deposited efflorescent precipitates relative to shales, provide strong evidence for quantitative mass oxidation of shale sulfide minerals as the source of acidity for chemical weathering. Slight δ15N depletion in the new surface precipitates relative to shale, coincides with dramatic loss of N from shales. Collectively, the results point to pyrite oxidation as a major driver of alum black shale weathering at the rock-atmosphere interface, indicating that quantitative mass release of Corg, N, S, and key metals to the environment is a response to intense sulfide oxidation. Consequently, large-scale acidic weathering of the sulfide-rich alum shale units is suggested to influence the fate and redistribution of the isotopes of C, N, and S from shale to the immediate environment.  相似文献   

16.
The contribution of soil organic matter (SOM) to continental margins is largely ignored in studies on the carbon budget of marine sediments. Detailed geochemical investigations of late Quaternary sediments (245-0 ka) from the Niger and Congo deep-sea fans, however, reveal that Corg/Ntot ratios and isotopic signatures of bulk organic matter (δ13Corg) in both fans are essentially determined by the supply of various types of SOM from the river catchments thus providing a fundamentally different interpretation of established proxies in marine sciences. On the Niger fan, increased Corg/Ntot and δ13Corg (up to −17‰) were driven by generally nitrogen-poor but 13C-enriched terrigenous plant debris and SOM from C4/C3 vegetation/Entisol domains (grass- and tree-savannah on young, sandy soils) supplied during arid climate conditions. Opposite, humid climates supported drainage of C3/C4 vegetation/Alfisol/Ultisol domains (forest and tree-savannah on older/developed, clay-bearing soils) that resulted in lower Corg/Ntot and δ13Corg (< −20‰) in the Niger fan record. Sediments from the Congo fan contain a thermally stable organic fraction that is absent on the Niger fan. This distinct organic fraction relates to strongly degraded SOM of old and highly developed, kaolinite-rich ferallitic soils (Oxisols) that cover large areas of the Congo River basin. Reduced supply of this nitrogen-rich and 12C-depleted SOM during arid climates is compensated by an elevated input of marine OM from the high-productive Congo up-welling area. This climate-driven interplay of marine productivity and fluvial SOM supply explains the significantly smaller variability and generally lower values of Corg/Ntot and δ13Corg for the Congo fan records. This study emphasizes that ignoring the presence of SOM results in a severe underestimation of the terrigenous organic fraction leading to erroneous paleoenvironmental interpretations at least for continental margin records. Furthermore, burial of SOM in marine sediments needs more systematic investigation combining marine and continental sciences to assess its global relevance for long-term sequestration of atmospheric CO2.  相似文献   

17.
Stable carbon isotopic composition of organic matter (δ13Corg) and compound-specific δ13C values of biomarkers from 15 lacustrine source rocks were analyzed to identify the original paleoenvironment and source organisms. The δ13C values of hopanes (δ13Chop) ranged from −68.7‰ to −32‰ and exhibit strongly 13C-depleted values in the lower part of Member 1 of the Nenjiang Formation (K2n1, up to −68.7‰), suggesting an origin from predominantly methanotrophic bacteria. 13C-enriched δ13CGa values and significantly 13C-depleted δ13Chop in K2n1, which coincide with water stratification and an intermittent anoxic photic zone, represents a shallow chemocline. The presence of an intermittent anoxic photic zone, which means that the anoxia expanded into the euphotic zone, is beneficial for OM preservation and results in high values of TOC and HI in this section. However, the absence of gammacerane and 13C-enrichment of δ13Chop in Member 2 of Nenjiang Formation (K2n2) reflect a deeper chemocline, corresponding to relatively oxidizing conditions and low values of TOC and HI. Moreover, the negative correlation of TOC vs δ13Corg and HI vs δ13Corg reflects the control of OM formation by sedimentary environments rather than productivity in the water column. Thus, the depth of the chemocline not only controls the abundance of OM but also affects the development of the microbial community, such as chemoautotrophic bacteria in the deep chemocline and chemoautotrophic and methanotrophic bacteria in the shallow chemocline. Moreover, δ13CGa and δ13C values for 4-methyl steranes are related to water salinity, with a higher salinity accompanied by 13C-enrichment in gammacerane and 4-methyl steranes.  相似文献   

18.
Large carbon cycle perturbations associated with the Middle Permian (Capitanian) mass extinction have been widely reported, but their causes and timing are still in dispute. Low resolution carbon isotope records prior to this event also limit the construction of a Middle Permian chemostratigraphic framework and global or local stratigraphic correlation, and hence limit our understanding of carbon cycle and environmental changes. To investigate these issues, we analyzed the 13Corg values from the Middle Permian chert-mudstone sequence (Gufeng Formation) in the Lower Yangtze deep-water basin (South China) and compared them with published records to build a chemostratigraphic scheme and discuss the underlying environmental events. The records show increased δ13Corg values from late Kungurian to early Guadalupian, followed by a decrease to the late Wordian/early Capitanian. The early-mid Capitanian was characterized by elevated δ13Corg values suggesting the presence of the “Kamura Event”: an interval of heavy positive values seen in the δ13Ccarb record. We propose that these heavy Capitanian δ13C values may be a response to a marked decline in chemical weathering rates on Pangea and associated reduction in carbonate burial, which we show using a biogeochemical model. The subsequent negative δ13C excursion seen in some carbonate records, especially in shallower-water sections (and in a muted expression in organic carbon) coincide with the Capitanian mass extinction may be caused by the input of isotopically-light carbon sourced from the terrestrial decomposition of organic matter.  相似文献   

19.
Geochemical and isotopic data for the uppermost 1.2 m of the sediments of the central Santa Monica Basin plain were examined to better understand organic matter deposition and recycling at this site. Isotopic signatures (Δ14C and δ13C) of methane (CH4) and dissolved inorganic carbon (DIC) indicate the occurrence of anaerobic oxidation of CH4 that is fueled by CH4 supplied from a relict reservoir that is decoupled from local organic carbon (Corg) degradation and methanogenesis. This finding was corroborated by a flux budget of pore-water solutes across the basal horizon of the profile. Together these results provide a plausible explanation for the anomalously low ratio between alkalinity production and sulfate consumption reported for these sediments over two decades ago. Shifts in Δ14C and δ13C signatures of Corg have previously been reported across the 20-cm depth horizon for this site and attributed to a transition from oxic to anoxic bottom water that occurred ~350 years BP. However, we show that this horizon also coincides with a boundary between the base of a hemipelagic mud section and the top of a turbidite interval, complicating the interpretation of organic geochemical data across this boundary. Radiocarbon signatures of DIC diffusing upward into surface sediments indicate that remineralization at depth is supported by relatively 14C-enriched Corg within the sedimentary matrix. While the exact nature of this Corg is unclear, possible sources are hemipelagic mud sections that were buried rapidly under thick turbidites, and 14C-rich moieties dispersed within Corg-poor turbidite sections.  相似文献   

20.
Eight zonal dinocyst assemblages and three bio stratigraphic units ranked as “beds with flora” are first distinguished in the Danian—lower Lutetian interval of the Paleogene succession, penetrated by the reference borehole Novousensk no. 1, where eight standard and one local nannoplankton zones are simultaneously recognized. The direct correlation of nannoplankton and dinocyst zones is used to refine the paleon-tological substantiation and stratigraphic position of regional lithostratigraphic units, ranges of hiatuses, and the correlation with the general stratigraphie scale. The nannoplankton of the Danian NP2 Cruciplacolithus tenuis and NP3 Chiasmolithus danicus zones is characteristic of the Algai Formation (Fm). The nannoplankton of the NP4 Coccolithus robustus Zone and dinocysts of the D3a Alterbidinium circulum Zone from the Tsyganovo Fm characterizes the Danian top. The Lower Syzran Subformation (Subfm) corresponds to the upper part of the NP4 Coccolithus robustus Zone (Neochiastizygus junctus local zone) and to the D3b (part) Cerodinium depressum Zone of the Selandian dinocysts. The latter spans part of the Upper Syzran Subformation, whose characteristic nannofossils are the nannoplankton of the NP5 Fasciculithus tympaniformis Zone and the dinocysts of the D3b (part) Isabelidinium? viborgense Zone of the Selandian. The Novouzensk Fm is represented by a succession of the dinocyst Cerodinium markovae Beds and the standard D4c Apectodinium hyperacanthum Zone of the upper Thanetian. The coccolitophorids of the lower Thanetian NP6 Heliolithus kleinpelli Zone occur at the formation base. The Bostandyk Fm includes successive bio stratigraphie units of the Ypresian. In the dinocyst scale, these are the D5a Apectodinium augustum Zone, the Pterospermella Beds (DEla Zone of the North Sea scale), and zones DBlb-c Deflandrea oebisfeldensis, D7c Dracodinium varielon-gitudum, and D8 Dracodinium politum—Charlesdowniea coleothrypta, while units of the nannoplankton scale correspond to the NP12 Martasterites tribrachiatus and NP13 Discoaster lodoensis zones. The Kopterek Fm yields Lutetian nannofossils: the nannoplankton of the NP14 Discoaster sublodoensis Zone and the dinocysts of the Wetzeliella coronata—Areosphaeridium diktyoplokum Beds. Three meaningful hiatuses are established at the Danian base, Selandian top, and in the lower Ypresian.  相似文献   

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