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1.
We have investigated melting relations in the Fe–O–S ternary system in the pressure range of 15–27 GPa and 1873 K. Subsolidus phase relations are Fe, Fe3S2, and FeO up to 17 GPa and Fe, Fe3S, and FeO above this pressure. The eutectic temperature slightly decreases from ambient pressure to 17 GPa, whereas increases above this pressure. The eutectic temperature in this study is 100 K lower than that in the Fe–S binary system. The oxygen content in the Fe–O–S eutectic liquid drops when the coexisting solid phases changes from FeS to Fe3S2. The cotectic lines in the ternary phase diagram lie close to the Fe–FeS binary axis. The isothermal sections indicate that oxygen solubility in the Fe–O–S liquid increases with increasing temperature, and with increasing sulfur content. The solubility of sulfur in the solid Fe has a maximum value at the eutectic temperature, and decreases with increasing temperature. Our results could have important implications for formation and composition of the Martian core.  相似文献   

2.
About the observed and future changes in temperature extremes over India   总被引：1，自引：0，他引：1  
An attempt is made in the present study to analyse observed and model simulated temperature extremes over Indian region. Daily maximum and minimum temperature data at 121 well-distributed stations for the period 1970–2003 have been used to study the observed changes in objectively defined values of temperature extremes. In addition, an assessment of future scenarios of temperature extremes associated with increase in the concentration of atmospheric greenhouse gases is done using simulations of a state-of-the-art regional climate modelling system known as PRECIS (Providing Regional Climate for Impact Studies) performed to generate the climate for the present (1961–1990) and future projections for the period 2071–2100. Observational analysis done with 121 stations suggests the widespread warming through increase in intensity and frequency of hot events and also with decrease in frequency of cold events. More than 75% stations show decreasing trend in number of cold events and about 70% stations show increasing trend in hot events. Percentage of stations towards the warming through intensity indices of highest maximum temperature, lowest minimum temperature is 78 and 71% stations, respectively. Remaining stations show opposite trends, however, most of them are statistically insignificant. Observational analysis for India as a whole also shows similar results. Composite anomalies for monthly temperature extremes over two equal parts of the data period show increase (decrease) in the frequency of hot (cold) events for all months. In general, PRECIS simulations under both A2 and B2 scenarios indicate increase (decrease) in hot (cold) extremes towards the end of twenty-first century. Both show similar patterns, but the B2 scenario shows slightly lower magnitudes of the projected changes. Temperatures are likely to increase in entire calendar year, but the changes in winter season are expected to be prominent. Diurnal temperature range is expected to decrease in winter (JF) and pre-monsoon (MAM) months.  相似文献   

3.
The δ18O data obtained from an 18.7 m ice core drilled in Chongce Ice Cap at an elevation of 6,530 m a.s.l. in the West Kunlun Mountains on the northern Tibetan Plateau show a strong correlation with the summer temperature of the middle to upper troposphere over the mid-high latitudes of Eurasia. Based on this, the δ18O record can be used as a proxy of the June–September mean temperature of the mid-upper troposphere (MUT) from 1903 to 1992. The time span of the ice core record is much longer than the meteorological data available only after 1948. Using the empirical mode decomposition method (EMD), the δ18O record is decomposed into various frequency components and compared with the solar irradiance variations of the same period. The results show that (1) The June–September mean temperature of the MUT over Eurasian mid-high latitudes is completely decomposed into four IMF (intrinsic mode function) components and an increasing trend. (2) Solar irradiance is decomposed into the Schwabe cycle, the Hale cycle, the Gleissberg cycle, and an increasing trend. (3) The correlation coefficients between the June and September mean temperatures of the MUT over Eurasian mid-high latitudes and solar irradiance on the longer timescales (at least more than 11-year) show the significant correlations; their phase changes are basically identical in general, and (4) the 11-year Schwabe cycle exists in the June–September mean temperature of the MUT over Eurasian mid-high latitudes during most of the time from 1903 to 1992, and only in the two high-temperature phases (1929–1944 and from 1975 to the present) may global warming disturb this relation. A full understanding of this phenomenon would shed insight into the potential consequence of global warming on the MUT.  相似文献   

4.
Fault bound blocks of granulite and enderbite occur within upperamphibolite-facies migmatitic tonalitic–trondhjemitic–granodioritic(TTG) gneisses of the Iisalmi block of Central Finland. Theseunits record reworking and partial melting of different levelsof the Archean crust during a major tectonothermal event at2·6–2·7 Ga. Anhydrous mineral assemblagesand tonalitic melts in the granulites formed as a result ofhydrous phase breakdown melting reactions involving amphiboleat peak metamorphic conditions of 8–11 kbar and 750–900°C.A nominally fluid-absent melting regime in the granulites issupported by the presence of carbonic fluid inclusions. Thegeochemical signature of light rare earth element (LREE)-depletedmafic granulites can be modelled by 10–30 wt % partialmelting of an amphibolite source rock leaving a garnet-bearingresidue. The degree of melting in intermediate granulites isinferred to be less than 10 wt % and was restricted by the availabilityof quartz. Pressure–temperature estimates for the TTGgneisses are significantly lower than for the granulites at660–770°C and 5–6 kbar. Based on the P–Tconditions, melting of the TTG gneisses is inferred to haveoccurred at the wet solidus in the presence of an H2O-rich fluid.A hydrous mineralogy, abundant aqueous fluid inclusions andthe absence of carbonic inclusions in the gneisses are in accordancewith a water-fluxed melting regime. Low REE contents and strongpositive Eu anomalies in most leucosomes irrespective of thehost rock composition suggest that the leucosomes are not meltcompositions, but represent plagioclase–quartz assemblagesthat crystallized early from felsic melts. Furthermore, similarplagioclase compositions in leucosomes and adjacent mesosomesare not a ‘migmatite paradox’, as both record equilibrationwith the same melt phase percolating along grain boundaries. KEY WORDS: Archean continental crust; fluid inclusion; granulite; migmatite; partial melting  相似文献   

5.
The introduction of invasive bivalves such as the zebra mussel (Dreissena polymorpha) can have profound effects on aquatic ecosystems, including decreases in phytoplankton biomass and changes in the taxonomic composition of phytoplankton. Zebra mussel introductions have been associated with increased dominance of cyanobacteria, especiallyMicrocystis, but this change may depend on interacting physical, chemical, or biotic conditions. We used a 12-yr record in the Hudson River to explore the relationship between phytoplankton composition and zebra mussel filtration. During this period (1993–2005), the mean July–September filtration rate of the zebra mussel (ZMF) varied by 8-fold, and the mean biovolume of cyanobacteria, which was dominated byMicrocystis, varied from 0 to 4.2 mm3 1−1 and comprised up to 52% of total phytoplankton biovolume. There was a tendency for high cyanobacterial biomass to be associated with low rather than high ZMF. Neither the absolute nor the relative amounts of either total cyanobacteria orMicrocystis were significantly correlated to ZMF alone or in combination with total phosphorus or any other, physical or chemical parameters that we measured. Cyanobacteria dominance and abundance were both strongly correlated to temperature, and over 80% of the among year variance in cyanobacterial dominance could be explained by temperature in a linear model. Temperature in combination with dissolved SiO3 explained 90% of the variation in cyanobacterial dominance. At higher temperatures and lower dissolved SiO3, cyanobacterial abundance increased, at the expense of diatoms that dominated at lower temperatures and a higher SiO3 years. The high explanatory value of temperature is surprising as the variation in temperature among years was relatively low (24.0–26.8°C). The results suggest that event slightly increased temperatures could lead to higher biomass and dominance of cyanobacteria in some aquatic systems.  相似文献   

6.
The Legs Lake shear zone marks the southeastern boundary of an extensive region (>20,000 km2) of high-pressure (0.8–1.5+ GPa) granulite-facies rocks in the western Churchill Province, Canada. The shear zone is one of the largest exhumation-related structures in the Canadian Shield and coincides with the central segment of the ∼2,800 km long Snowbird tectonic zone. The movement history of this shear zone is critical for the development of models for the exhumation history of the high-pressure region. We used electron microprobe U–Th–Pb dating of monazite with supplemental ID-TIMS U–Pb geochronology to place constraints on the timing of shear zone activity. Combining these and other data, we suggest that regional exhumation occurred during at least three distinct phases over an ∼150 million year period. The first phase involved high temperature decompression from ∼1.0 to 0.8–0.7 GPa shortly following 1.9 Ga peak metamorphism, possibly under an extensional regime. The second phase involved rock uplift and decompression of the hanging wall to 0.5–0.4 GPa during east-vergent thrusting across the Legs Lake shear zone at ca. 1.85 Ga. This phase was likely driven by early collision-related convergence in the Trans-Hudson orogen. The final phase of regional exhumation, involving the removal of 15–20 km of overburden from both footwall and hanging wall, likely occurred after ∼1.78 Ga and may have been related to regional extensional faulting.Electronic Supplementary Material Supplementary material is available to authorised users in the online version of this article at .  相似文献   

7.
The variability in the long-term temperature and sea level over the north Indian Ocean during the period 1958–2000 has been investigated using an Ocean General Circulation Model, Modular Ocean Model version 4. The model simulated fields are compared with the sea level observations from tide-gauges, Topex/Poseidon (T/P) satellite, in situ temperature profile observations from WHOI moored buoy and sea surface temperature (SST) observations from DS1, DS3 and DS4 moored buoys. It is seen that the long (6–8 years) warming episodes in the SST over the north Indian Ocean are followed by short episodes (2–3 years) of cooling. The model temperature and sea level anomaly over the north Indian Ocean show an increasing trend in the study period. The model thermocline heat content per unit area shows a linear increasing trend (from 1958–2000) at the rate of 0.0018 × 1011 J/m2 per year for north Indian Ocean. North Indian Ocean sea level anomaly (thermosteric component) also shows a linear increasing trend of 0.31 mm/year during 1958–2000.  相似文献   

8.
The isotopic compositions of oxygen and carbon and trace concentrations of magnesium and strontium in speleothems formed in limestone caves respond to climate changes outside the caves. Measurements of these properties on a stalagmite from Shihua Cave near Beijing, China, allowed reconstruction of the regional changes in precipitation, temperature and nature of vegetation. Over the last ∼ 500 years, there were fourteen precipitation cycles with a periodicity of 30–40 years, which may well reflect fluctuations in the strength of the East Asian summer monsoons reaching northeastern China. Relative to the mean temperature of this time interval, the period 1620–1900 AD was cold and periods 1520–1620 and 1900–1994 were warm. Over the last ∼ 3000-years, about eight wet/cool-dry/warm climatic cycles of 300–400 years duration occurred, the latest wet/cool half cycle corresponding to the Little Ice Age. The δ13C record registers the anthropogenic activities of fossil fuel CO2 combustion in recent decades and regional deforestation between 13 and 16 centuries when Beijing was bustling with palatial constructions and being developed into the world’s most populated city.  相似文献   

9.
The Candamo Cave contains an important group of paleolithic paintings which have been seriously deteriorated due to mass tourism. In this work, an analysis was carried out of different climatic parameters (CO2, temperature, humidity, 222Rn) during annual cycles with the cave closed to the public and during an experimental period of controlled visits. The effect of visits on the geochemical characteristics of karstic water was also analyzed together with the cave ventilation. The natural variations in the cave air CO2 were above 3000 ppm, the increase produced through visits was only 100–110 ppm and since the humidity is almost permanently at saturation point, the critical parameter which limits the visitor capacity becomes air temperature. The temperature changes during the annual cycle are of the order of 1  °C in the external part and less than 0.5  °C in the internal part of the cave and a maximum increase of 0.13  °C was observed during the period of the visits. The 222Rn and CO2 concentration minimums in the summer period (July–October) show that this is the most propitious time for visits, since the greatest ventilation is produced in the cave at this time and, therefore, the greatest capacity for recovery. The geochemistry of the water, on the other hand, indicated that this is the period of the year in which processes of wall corrosion can be most easily introduced, although this would be of limited magnitude. The visitor capacity calculated was 29 visitors/day. Received: 29 August 1996 · Accepted: 23 June 1997  相似文献   

10.
Quantitative thermobarometry of inclusions in zoned garnet from a Franciscan eclogite block record a counter-clockwise P–T path from blueschist to eclogite and back. Garnet retains prograde zoning from inclusion-rich Alm52Grs30Pyp6Sps12 cores to inclusion-poor Alm62Grs25Pyp12Sps1 mantles, with overgrowths of highly variable composition. Barometry using the Waters–Martin version of the garnet–phengite–omphacite thermobarometer yields conditions of 7–15 kbar, 400–500°C (garnet cores), 18–22 kbar, ∼550°C (mantles), and 10–14 kbar, 350–450°C (overgrowths), in agreement with clinozoisite–sphene–rutile–garnet–quartz barometry. These pressures are ∼10–15 kbar less than those obtained using more recent, fully thermodynamic calibrations of the phengite–omphacite–garnet thermobarometer. Low early temperatures suggest that the block was subducted in a thermally mature subduction zone and not at the inception of subduction when prograde temperature is expected to be higher. Franciscan high-grade blocks likely represent crust subducted throughout the history of this convergent margin, rather than only at the inception of the subduction zone.  相似文献   

11.
The results of monitoring the flaring activity of Mrk 421 with the XMM-Newton and RXTE orbiting observatories are presented. The ASM/RXTE data show that, during most of the observational period, 2002–2006, the source was in a very active state, with a mean 1.5–12 keV flux equals ∼17 mCrab. Analysis of daily and weekly averaged data shows strong X-ray variability of Mrk 421 on time scales from days to months. The long-term light curve demonstrates a rich variety of variability patterns and a complex hierarchical flare structure, in most cases superimposed on longer trends of rising and decreasing source activity. Quantitative estimates of the variability of Mrk 421 shows evidence of correlations between the source intensity in X-rays and the variability parameters, both for separate years and epochs and for most of the observational period. The soft and hard X-ray components (according to XMM-Newton data) are correlated with each other, and spectral changes (according to ASM/RXTE data) are characterized by increasing hardness with brightening of the object in X-rays. Moderate spectral variability at individual epochs and evidence for an energy dependence of the source variability are also observed. The 2–12 keV fluxes from Mrk 421 detected by XMM-Newton are consistent with the maximum 2–10 keV flux detected by ASCA ∼10 years ago. An analysis of simultaneous day-time-scale variability of Mrk 421 in X-rays (ASM/RXTE) and very-high-energy γ-rays (GT-48 Cherenkov telescope of the Crimean Astrophysical Observatory) in periods of increased activity of the source in December 2002 and April 2004 is also presented. Published in Russian in Astronomicheskiĭ Zhurnal, 2008, Vol. 85, No. 7, pp. 589–602. The article was translated by the authors.  相似文献   

12.
Seasonal snow cover is a vital natural resource in the Himalaya. Monitoring of the areal extent of seasonal snow cover is important for both climatological studies as well as hydrological applications. In the present paper, snow cover monitoring was carried out to evaluate the region-wise accumulation and ablation pattern of snow cover in Pir Panjal and Shamshawari ranges of Kashmir valley. The study was carried out for the winter period between November and April of 2004–05, 2005–06 and 2006–07, using multi-temporal WiFS sensor data of IRS-1C/1D satellites. The study shows reduction in the areal extent of seasonal snow cover and rising trend of maximum temperature in three winters for the entire Kashmir valley. This has been validated with 20 years (1988–89 to 2007–08) climatic conditions prevailed in both ranges of Kashmir valley. Region-wise study shows the spatial and temporal variability in seasonal snow cover within Kashmir valley. Advance melting was observed in Banihal and Naugam/Tangdhar regions than Gurez and Machhal regions. Different geographical parameters of these regions were studied to evaluate the influence on snow cover and it was observed that altitude and position of region with respect to mountain range are the deciding factors for retaining the seasonal snow cover for longer duration. Such region-wise study of snow cover monitoring, can provide vital inputs for planning the hydropower projects, development in habitat areas, recreational and strategic planning in the region.  相似文献   

13.
Late Pleistocene paleoclimatic history on northeastern Qinghai–Tibetan Plateau (QTP) has been reconstructed mainly from lake sediments; however, data regarding dry–wet climate changes reported in this region are still not clear and controversial. Based on shoreline features and highstand lacustrine sediments around lakes on the QTP, high lake level histories in this paper were summarized and compared with paleoclimatic records from lake sediments, ice core and glaciation evolution surrounding mountains on the NE QTP during late Pleistocene. The results indicate that periods of high lake level occurred at MIS 5, MIS 3 and early-middle Holocene and most likely corresponding to warm and wet climate periods, while periods of low lake level existed in intervening intervals, corresponding to cold and dry climate periods, which most likely coincide with glacial advances surrounding high mountains. With an exception, no wide glacial advance in study area was found during MIS 3, possibly suggesting that effective moisture is lower than that in the other region of NE QTP in this period.  相似文献   

14.
The main objective of this study was to assess the spatial and temporal variability of groundwater level fluctuations in the Amman–Zarqa basin, during the period 2001–2005. In the year 2003, as a consequence of war, there was a sudden increase in the population in this basin. Knowing that the basin is already heavily populated and witnesses most of the human and industrial activities in Jordan, this study was prompted to help make wise water resources management decisions to cope with the new situation. Data from 31 fairly distributed wells in the upper aquifer of the basin were subjected to geostatistical treatment. Kriging interpolation techniques have indicated that the groundwater flow directions remained almost constant over the years. The two main directions are SW–NE and E–W. Kriging mapped fluctuations have also showed that drop and rise events are localized in the basin. Forecasting possibilities for management purposes were tackled using autocorrelation analysis. The constructed autocorrelograms indicated, in general, the temporal dependence of seasonal water level fluctuations, and that forecasting can be carried out within a period of 3–21 months. Several suggestions were made to mitigate the drop and rise hazards in the detected sites.  相似文献   

15.
The low-temperature heat capacity (C P) of stishovite (SiO2) synthesized with a multi-anvil device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system (PPMS) and around ambient temperature using a differential scanning calorimeter (DSC). The entropy of stishovite at standard temperature and pressure calculated from DSC-corrected PPMS data is 24.94 J mol−1 K−1, which is considerably smaller (by 2.86 J mol−1 K−1) than that determined from adiabatic calorimetry (Holm et al. in Geochimica et Cosmochimica Acta 31:2289–2307, 1967) and about 4% larger than the recently reported value (Akaogi et al. in Am Mineral 96:1325–1330, 2011). The coesite–stishovite phase transition boundary calculated using the newly determined entropy value of stishovite agrees reasonably well with the previous experimental results by Zhang et al. (Phys Chem Miner 23:1–10, 1996). The calculated phase boundary of kyanite decomposition reaction is most comparable with the experimental study by Irifune et al. (Earth Planet Sci Lett 77:245–256, 1995) at low temperatures around 1,400 K, and the calculated slope in this temperature range is mostly consistent with that determined by in situ X-ray diffraction experiments (Ono et al. in Am Mineral 92:1624–1629, 2007).  相似文献   

16.
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17.
We report the results of a study of fast variations of the H2O maser emission toward NGC 7538 IRS 1, which is associated with a star-forming region. The study is based on monitoring data in the 1.35 cm line obtained in 1996–2003 on the 22-meter radio telescope of the Pushchino Radio Astronomy Observatory (Russia). Periodic flux variations of four long-lived emission features with an average period of about 0.9 year have been detected. The flux variations of these features are correlated, suggesting that the detected variability is a consequence of pulsation of, e.g., stellar wind from the protostar in NGC 7538 IRS 1, with a period of about 0.9 year (0.87 ± 0.03 year). These pulsations are superimposed on long-term variability of the integrated maser emission with a period of 13 years.  相似文献   

18.
Aboveground and belowground biomass, density, blade length, and chlorophyll content of seagrass growing directly under docks were compared with adjacent unshaded sites. The amount of light reduction due to dock shading was measured using quantum spherical irradiance meters. Seagrasses were present under docks; they were shaded such that light levels were 19% and 16% of surface irradiance, at shallow and deep sites, respectively. Shoot density was 40–47% lower in shaded plots than in unshaded plots; total biomass was 30–33% lower in shaded plots than in unshaded plots. In contrast, blade length and chlorophyll content were increased at shaded plots relative to unshaded plots. Seagrasses were not found under docks at light levels less than 14% of surface irradiance. These results are in agreement with published in situ compensation irradiance estimates of 15–18% for Halodule wrightii in Texas coastal waters. Shading effects were most apparent between the hours of 1000 and 1500; therefore, the light received during the early morning and late afternoon hours may be critical for plants growing under docks. The north-south orientation of the docks in this study is likely an important factor contributing to the continued survival and growth of the seagrasses.  相似文献   

19.
 The P–V–T equation of state (EoS) models of Birch–Murnaghan, Vinet and Poirier–Tarantola have been compared with one another and discussed in the light of their ability to reproduce thermoelastic functions and parameters by means of fitting to pressure–volume–temperature data artificially generated for spinel, corundum and forsterite. Numerical simulations relying upon semi-empirical potentials, lattice dynamics and the quasiharmonic approximation have been used to generate P–V–T data. The results obtained indicate that all the P–V–T EoSs tested predict bulk modulus at ambient conditions with errors confined, at worst, within a few percent, and reproduce correctly its dependence on temperature. The derivatives of the bulk modulus versus P and PT are less satisfactorily modelled. The bulk thermal expansion is determined by EoSs within a few percent error, but the deviations increase significantly if the approximation of linear dependence of EoS on temperature is used (linearised thermal pressure model). Received: 30 January 2001 / Accepted: 16 June 2001  相似文献   

20.
The influence of temperature on tropospheric ozone (O3) concentrations in urban and photochemically polluted areas in the greater Athens region are investigated in the present study. Hourly values of the ambient air temperature used for studying the urban heat island effect in Athens were recorded at twenty-three experimental stations while ozone concentration values were measured at three of the above-mentioned stations and for a period of two years (1996–1997). The linear correlation between ozone concentration and air temperature values as well as the temporal variation of temperature and ozone concentration, for the above-mentioned experimental stations, were calculated and analysed. Moreover, a neural network approach was used for investigating the impact of temperature on the ozone concentration values over the greater Athens area. The neural network model used ambient air temperature as one of its input parameters and it was found that temperature is a predominant parameter, affecting considerably the ozone concentration values.  相似文献   

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