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1.
We applied the zircon evaporation method and zircon typological and compositional studies to detrital-zircon populations of quartzphyllite complexes of the Eastern Alps, including the Southalpine (Vetriolo and Recoaro) and the Austroalpine (Goldeck, Gailtal, and Thurntaler) complexes. Combined zircon morphology and geochemical and geochronological analyses (single-zircon evaporation technique) provided significant constraints for the age of the studied protoliths. The morphological study points out that zircons from Austroalpine and Southalpine quartzphyllites show substantial differences in terms of shape, colour, size, type of inclusions, cracks, and turbidity. Electron microprobe analyses (Si, Zr, Hf, P: HREE) indicate homogeneous compositions, suggesting common source areas characterized by granitoid rocks, whereas typology indicates the existence of two distinct groups. Zircon ages from the quartzphyllites are rather different, those from Austroalpine samples being younger than Southalpine ones. Pb–Pb zircon ages define two principal evolutionary sequences. The Austroalpine complexes are characterized by an older evolution typical of subduction-related magmatism. This started by 598 Ma N-MORB-type, mainly involving depleted mantle sources, and finished with 379–341 Ma acid suites typical of a crustal source. Southalpine complexes zircon ages show an evolution characterized by tholeiitic and 473 Ma alkaline within-plate basalt-type suites in both pre- and post-Early Ordovician units. It involved intraplate mantle metasomatism and an enrichment trend along multicomponent sources. These magmatic evolution lines can be related to a plate-tectonic scenario that involved terrane accretion in a progressively mature Neoproterozoic to Ordovician active margin and a subsequent Palaeo-Tethys passive margin along the north Gondwanan periphery.  相似文献   

2.
《地学前缘(英文版)》2020,11(5):1651-1667
The Spanish Central System(SCS) contains several suites of Palaeozoic mafic igneous intrusions with contrasting geochemical affinity:Ordovician tholeiitic metabasites,Variscan calc-alkaline gabbros(Gb1) and microdiorites(Gb2),shoshonitic monzogabbros(Gb3) and alkaline diabases and lamprophyres(Gb4).Not all of these rocks are accurately dated,and several aspects of their genesis are still poorly understood.We present new whole-rock geochemical data(major and trace elements,and Sr-Nd isotopes),U-Pb and Lu-Hf isotopic ratios on magmatic zircons and 40 Ar/~(39)Ar amphibole geochronology results in order to establish a precise chronology for the successive events of magmatism in the SCS,and discuss the nature of their mantle sources.Accurate ages have been determined for the Variscan gabbros(305-294 Ma),the microdiorites(299 Ma) and the accompanying felsic porphyries(292 Ma),the shoshonitic monzogabbros(285 Ma),and the alkaline diabases(274 Ma) and monzosyenites(271-264 Ma).According to this information,the Variscan mafic magmatism would be mainly concentrated in the range of 305-294 Ma,with a final manifestation represented by the minor shoshonitic dykes.The alkaline magmatism proved to be slightly older than previously thought and yielded at least two distinct pulses:diabases and lamprophyres-monzosyenites.Zircon Hf isotopes evidence the involvement of depleted and slightly enriched mantle sources.The bulk of the eHf values are in the broad range of-8 to+11,indicative of melting both depleted and enriched mantle regions.The high within-sample Hf isotope variation(up to-11 epsilon units) shown by samples from the Variscan series(gabbros,microdiorites and monzogabbros) could be explained mainly by hybridisation of magmas derived from heterogeneous lithospheric mantle sources.Pressure estimates indicate that the Variscan mafic magmas were extracted from the lithosphere.The Nd-Hf isotopic composition of these suites of rocks suggests the recycling of pelitic sediments during the Cadomian orogeny.Deeper(asthenospheric) mantle levels were involved in the generation of the alkaline suite,whose anomalous negative eHf values(moderately decoupled with respect to radiogenic Nd) could be associated with subducted oceanic components raised by mantle upwelling associated with lithosphere thinning and extension during the Permian.  相似文献   

3.
Chemical and U–Pb isotopic analyses of metaigneous rocks in the northern Oaxacan Complex in southern Mexico indicate that they form part of two granitic–gabbroic suites intruded at 1157–1130 and 1012 Ma, which were metamorphosed under granulite facies conditions between 1004 and 980 Ma. Although the older suite has both within-plate and arc geochemical signatures, the arc characteristics (enrichment of La and Ce relative to Nb, Ta, and Th) are inferred to result from crustal contamination, a conclusion consistent with their negative Nd signatures. The younger suite is spatially associated with anorthosites (from which we were unable to acquire a protolith age), suggesting that collectively it forms part of anorthosite–mangerite–charnockite–granite (AMCG) suites. The tholeiitic nature of the mafic rocks along with the within-plate character of the felsic rocks suggests that they were intruded during extension related to either farfield backarc rifting, rifting above a slab window, or anorogenic intercontinental rifting. Potentially correlative AMCG suites are widespread in Mexico, the Grenville Province of eastern Canada and northeastern USA, and the Andean massifs of Colombia, however, Pb isotopic data most closely resemble those in South America. These data are consistent with published hypotheses that suggest Oaxaquia represents an exotic terrane derived from Amazonia.  相似文献   

4.
During the Neogene, a magmatic change from calc-alkaline to alkaline types occurred in all the regions surrounding the western Mediterranean. This change has been studied in Oranie (western Algeria). In this area, potassic to shoshonitic calc-alkaline andesites (with La/Nb ratios in the range 4–6) were mainly erupted between 12 and 9 Ma. They were followed (between 10 and 7 Ma) by basalts displaying geochemical features which are transitional between calc-alkaline and alkaline lavas (La/Nb=1–1.7). After a ca. 3-Ma quiescence period, volcanic activity resumed, with the eruption of OIB-type alkaline basalts (La/Nb=0.5–0.6), from 4 to 0.8 Ma. A combined geochemical approach, using incompatible elements and Sr, Nd and O isotopes, allows us to conclude that the transitional basalts derived from the melting of a heterogeneous mantle source, at the boundary between lithosphere and asthenosphere. We propose that melting of a previously subduction-modified lithospheric mantle occurred between 12 and 10 Ma, in response to the upwelling of hot asthenosphere flowing up into an opening gap above a detached sinking slab. As a result, calc-alkaline magmas were formed. From 10 to 7 Ma, the transitional basalts were generated through melting of the boundary mantle zone between the lithosphere and the upwelling asthenosphere. During that stage, the contribution of the lithospheric source was still predominant. Then, as sinking of the oceanic slab progressed, the increasing uprise of the asthenosphere led to the formation and emplacement (from 4 to 0.8 Ma) of typical within-plate alkaline basalts derived from a plume-modified asthenospheric mantle.  相似文献   

5.
Julian A. Pearce   《Lithos》2008,100(1-4):14-48
Two geochemical proxies are particularly important for the identification and classification of oceanic basalts: the Th–Nb proxy for crustal input and hence for demonstrating an oceanic, non-subduction setting; and the Ti–Yb proxy for melting depth and hence for indicating mantle temperature and thickness of the conductive lithosphere. For the Th–Nb proxy, a Th/Yb–Nb/Yb projection demonstrates that almost all oceanic basalts lie within a diagonal MORB–OIB array with a principal axis of dispersion along the array. However, basalts erupted at continental margins and in subduction zones are commonly displaced above the MORB–OIB array and/or belong to suites with principal dispersion axes which are oblique to the array. Modelling of magma–crust interaction quantifies the sensitivity of the Th–Nb proxy to process and to magma and crustal compositions. For the Ti–Yb proxy, the equivalent Ti/Yb–Nb/Yb projection features a discriminant boundary between low Ti/Yb MORB and high Ti/Yb OIB that runs almost parallel to the Nb/Yb axis, reflecting the fact that OIB originate by melting beneath thicker lithosphere and hence by less melting and with residual garnet. In the case of volcanic-rifted margins and oceanic plume–ridge interactions (PRI), where hot mantle flows toward progressively thinner lithosphere (often becoming more depleted in the process), basalts follow diagonal trends from the OIB to the MORB field. Modelling of mantle melting quantifies the sensitivity of the Ti–Nb proxy to mantle potential temperature and lithospheric thickness and hence defines the petrogenetic basis by which magmas plot in the OIB or MORB fields. Oceanic plateau basalts lie mostly in the centre of the MORB part of that field, reflecting a high degree of melting of fertile mantle. Application of the proxies to some examples of MORB ophiolites helps them to be further classified as C (contaminated)-MORB, N (normal)-MORB, E (enriched)-MORB and P (plume)-MORB ophiolites, which may add a useful dimension to ophiolite classification. In the Archean, the hotter magmas, higher crustal geotherms and higher Th contents of contaminants all result in widespread crustal input that is easy to detect geochemically with the Th–Nb proxy. Application of this proxy to Archean greenstones demonstrates that almost all exhibit a crustal component even when reputedly oceanic. This indicates, either that some interpretations need to be re-examined or that intra-oceanic crustal input is important in the Archean making the proxy less effective in distinguishing oceanic from continental settings. The Ti–Yb proxy is not effective for fingerprinting Archean settings because higher mantle potential temperatures mean that lithospheric thickness is no longer the critical variable in determining the presence or absence of residual garnet.  相似文献   

6.
Neutron activation determination of La, Ce, Sm, Eu, Tb, Yb, Lu, Ta, Hf, Sc, Co and Th in potassic lavas from the Birunga and Toro-Ankole regions show that the rocks are characterized by high rare earth element (REE) contents (161–754 ppm) and form two groups based upon differing La/Yb ratios. One group is made up of katungite, ugandite and mafurite with La/Yb =146–312, and the other of rocks of the leucitite and phonolitic tephrite series, La/Yb =30–56. The trace element content of the ugandite group is similar to that of kimberlites. The data do not indicate any trends of differentiation or simple relationships between the two groups of rocks, although katungite is unlikely to be parental to rocks of lower La/Yb ratios. It is unlikely that in terms of La/Yb ratios that partial melting of mica-garnet-lherzolite mantle can form katungite because of the very small amounts of partial melting required (0.2%), although the La/Yb ratios of 150–200 (ugandites, mafurites) and 30–60 (leucitites, phonolitic tephrites) can be accounted for by 0.3–1.5% and 1–9% melting respectively, if the REE are then concentrated without further La and Yb fractionation. Partial melting of mantle which has been metasomatized by alkaline earths and REE bearing fluids or mixing of carbonatite and nephelenite are also compatable with the observed geochemistry of the lavas. It is considered that gas transfer processes which selectively enrich the light REE may have obscured REE evidence pertaining to early partial melting and/or differentiation processes and therefore that REE geochemistry is of little use in determining the petrogenetic processes involved in the formation of potassic lavas.  相似文献   

7.
A number of Paleoproterozoic mafic dykes are reported to intrude volcano-sedimentary sequences of the Mahakoshal supracrustal belt. They are medium to coarse-grained and mostly trend in ENE-WSW to E-W. Petrographically they are metadolerite and metabasite. Geochemical compositions classify them as sub-alkaline basalts to andesites with high-iron tholeiitic nature. Both groups, i.e. metabasites and metadolerites, show distinct geochemical characteristics; high-field strength elements are relatively higher in metadolerites than metabasites. This suggests their derivation from different mantle melts. Chemistry does not support any possibility of crustal contamination. Trace element modeling advocates that metabasite dykes are derived from a melt originated through ∼20% melting of a depleted mantle source, whereas metadolerite dykes are probably derived from a tholeiitic magma generated through <10% melting of a enriched mantle source. Chemistry also reveals that the studied samples are derived from deep mantle sources. HFSE based discrimination diagrams suggest that metabasite dykes are emplaced in tectonic environment similar to the N-type mid-oceanic ridge basalts (N-MORB) and the metadolerite dykes exhibit tectonic setting observed for the within-plate basalts. These inferences show agreement with the available tectonic model presented for the Mahakoshal supracrustal belt. The Chitrangi region experienced N-MORB type mafic magmatism around 2.5 Ga (metabasite dykes) and within-plate mafic magmatism around 1.5–1.8 Ga (metadolerite dykes and probably other alkaline and carbonatite magmatic rocks).  相似文献   

8.
Following the amalgamation of the Siberian and North China Cratons, NE China, as part of the Central Asian Orogenic Belt (CAOB), underwent Late Mesozoic lithospheric extension that was associated with volcanic activity. The Songliao Basin is the most important rift structure formed during these processes and contains voluminous volcanic rocks interlayered with sedimentary infill. Mafic-to-intermediate lavas are associated with felsic ones. This study focusses on the geochemical compositions of the less-widespread Early Cretaceous mafic-to-intermediate lavas in the Songliao Basin and compares them with the more abundant felsic rocks. Two mafic-to-intermediate magma series, one with alkaline and the other with sub-alkaline affinity, were identified. High MgO and Cr contents, low Th/Nb and La/Nb ratios, and variable but depleted Nd isotope compositions indicate that both magma suites were most likely formed by the melting of enriched upper mantle sources. Sub-alkaline mafic-to-intermediate rocks and I-type rhyolites define a co-genetic magma series. This rock suite was produced by the melting of subduction-modified lithospheric mantle and subsequent magma evolution as well as crustal melting during lithospheric extension. Alkaline mafic-to-intermediate rocks and A-type rhyolites form another co-genetic magma suite that was produced under within-plate conditions from an OIB-type mantle source, supposed to be the heterogeneous shallow asthenosphere and/or the lower lithosphere. Decompression partial melting of this mantle source requires a relatively thin lithosphere. The development of alkaline mafic rocks and A-type rhyolites as typical bimodal volcanic assemblage reflects that lithospheric thinning below the Songliao Basin reached its maximum, whereas basin rifting terminated afterwards.  相似文献   

9.
The mineralogical, petrological, geochemical and geochronological data were used to evaluate the age and petrogenesis of compositionally contrasting metamorphic rocks at the junction between Meso-Neoproterozoic Transangarian structures and Archean-Paleoproterozoic complexes of the Angara–Kan inlier of the Yenisei Ridge. The studied metabasites and metapelites provide clues for understanding the evolution of the region. The magmatic protoliths of low-Ti metabasites were derived by melting of depleted (N-MORB) upper mantle, and their high-Ti counterparts are interpreted to have originated from an enriched mantle source (E-MORB). The petrogeochemical characteristics of protoliths of the metabasite dikes resemble those of within-plate basalts and ocean island tholeiites. The Fe- and Al-rich metapelites are redeposited and metamorphosed products of Precambrian weathering crusts of kaolinite and montmorillonite-chlorite-hydromica compositions. The Р–Т conditions of metamorphism (4.9–5.5 kbar/570–650°С for metabasites; 4.1–7.1 kbar/500–630°С for metapelites) correspond to epidote–amphibolite to amphibolite facies transition. The evolution of the Angara complex occurred in two stages. The early stage (1.18–0.85 Ga) is associated with Grenville tectonics and the late stage is correlated with accretion/collision episodes of the Valhalla orogeny, with the peaks at 810–790 and 730–720 Ma, and the final stage of the Neoproterozoic evolution of the orogen on the southwestern margin of the Siberian craton. The correlation of regional crustal processes with globalscale geological events in the Precambrian evolution of the Earth supports recent paleomagnetic reconstructions that allow a direct, long-lived (1400–600 Ma) spatial and temporal connection between Siberia, Laurentia, and Baltica, which have been parts of ancient supercontinents.  相似文献   

10.
Chemical and mineralogical data from rocks dredged at six sites along plate boundaries around the Caroline Sea define at least three separate igneous suites. Three sites were located in the Sorol Trough, along the Caroline-Pacific plate boundary, and three sites were located in the Ayu Trough along the Caroline-Philippine plate boundary. Geophysical data suggest that both features have originated through processes of crustal extension.Weathered basalts with mid-ocean ridge basalt (MORB) affinities were recovered from the base of the northern margin of the Sorol Trough. Fresh transitional-to-alkalic pillow basalts from a seamount in the central part of the trough have geochemical and Sr-isotopic characteristics similar to enriched MORB or volcanics associated with off-ridge volcanism. A suite of tholeiitic rocks consisting of high-Mg basalt, ferrobasalt and a variety of mafic to ultramafic rocks dredged from the western section of the Sorol Trough has chemical and mineralogical characteristics of other intraplate tholeiitic suites like those from Hawaii. The ferrobasalts could have been derived from a high-Mg basaltic liquid through fractional crystallization of olivine, clinopyroxene and plagioclase. The geochemical data indicate that both MORB and “hot-spot” type sources have been involved in the generation of magmas beneath the Sorol Trough. Furthermore, the highly metamorphosed and tectonized mafic to ultramafic rocks recovered with the tholeiites suggest that a significant component of shear accompanied crustal accretion along “leaky” transform faults within the Sorol Trough.The chemical and isotopic characteristics of fresh to weathered pillow-lava fragments from the axial rift and eastern margin of the Ayu Trough, suggest that a MORB-type source was tapped during crustal accretion along a central spreading centre. An assemblage of metabasalts, metagabbros and silicic plutonic rocks (plagiogranites), recovered from a scarp along the western margin of the trough, have petrologic and chemical features analogous to rocks from plutonic complexes in ophiolites and some oceanic ridges. The plagiogranites could be differentiates from a relatively hydrous MORB magma, but cannot be related to the slightly LIL-enriched basalts in the Ayu Trough by crystal fractionation. Two separate mantle sources are implicated. Metamorphic features in the plutonic rocks are inferred to be the result of hydrothermal and dynamic events associated with the inception of spreading and to subsequent tectonism which exposed them.The petrochemistry of rocks from the Ayu and Sorol troughs is consistent with the hypothesis that crustal accretion occurred along the northern and western boundaries of the Caroline plate and further suggests that a variety of sub-oceanic mantle sources have been involved in the genesis of the crust in each region.  相似文献   

11.
Crustal contributions to arc magmatism in the Andes of Central Chile   总被引：52，自引：4，他引：52  
Fifteen andesite-dacite stratovolcanoes on the volcanic front of a single segment of the Andean arc show along-arc changes in isotopic and elemental ratios that demonstrate large crustal contributions to magma genesis. All 15 centers lie 90 km above the Benioff zone and 280±20 km from the trench axis. Rate and geometry of subduction and composition and age of subducted sediments and seafloor are nearly constant along the segment. Nonetheless, from S to N along the volcanic front (at 57.5% SiO2) K2O rises from 1.1 to 2.4 wt %, Ba from 300 to 600 ppm, and Ce from 25 to 50 ppm, whereas FeO*/MgO declines from >2.5 to 1.4. Ce/Yb and Hf/Lu triple northward, in part reflecting suppression of HREE enrichment by deep-crustal garnet. Rb, Cs, Th, and U contents all rise markedly from S to N, but Rb/Cs values double northward — opposite to prediction were the regional alkali enrichment controlled by sediment subduction. K/Rb drops steeply and scatters greatly within many (biotite-free) andesitic suites. Wide diversity in Zr/Hf, Zr/Rb, Ba/Ta, and Ba/La within and among neighboring suites (which lack zircon and alkali feldspar) largely reflects local variability of intracrustal (not slab or mantle) contributions. Pb-isotope data define a limited range that straddles the Stacey-Kramers line, is bracketed by values of local basement rocks, in part plots above the field of Nazca plate sediment, and shows no indication of a steep (mantle+sedimentary) Pb mixing trend. 87Sr/86Sr values rise northward from 0.7036 to 0.7057, and 143Nd/144Nd values drop from 0.5129 to 0.5125. A northward climb in basal elevation of volcanic-front edifices from 1350 m to 4500 m elevation coincides with a Bougueranomaly gradient from –95 to –295 mgal, interpreted to indicate thickening of the crust from 30–35 km to 50–60 km. Complementary to the thickening crust, the mantle wedge beneath the front thins northward from about 60 km to 30–40 km (as slab depth is constant). The thick northern crust contains an abundance of Paleozoic and Triassic rocks, whereas the proportion of younger arc-intrusive basement increases southward. Primitive basalts are unknown anywhere along the arc. Base-level isotopic and chemical values for each volcano are established by blending of subcrustal and deep-crustal magmas in zones of melting, assimilation, storage and homogenization (MASH) at the mantle-crust transition. Scavenging of mid-to upper-crustal silicic-alkalic melts and intracrustal AFC (prominent at the largest center) can subsequently modify ascending magmas, but the base-level geochemical signature at each center reflects the depth of its MASH zone and the age, composition, and proportional contribution of the lowermost crust.  相似文献   

12.
ABSTRACT

The Neoproterozoic tectonic evolution of the Jiangnan Orogen is controversial, with one of the issues being whether the ca. 850–820-Ma granitoids were generated by mantle plumes or the collision between the Yangtze and Cathaysia blocks. This paper tackles this problem by examining the age and petrogenesis of one of the granitoids, the Getengling pluton in the central Jiangnan Orogen, and through comparison with a regional geochronological–geochemical database compiled from previous studies. The Getengling pluton is characterized by high A/CNK values (~1.5), slight negative whole-rock εNd(t) values (?2.8 to ?3.4), and positive zircon εHf(t) values (0.7 ± 1.1), suggesting S-type granite affinities with juvenile contributions. Rb/Sr, Rb/Ba, and high CaO/Na2O ratios indicate psammitic sources with both clay-rich and clay-poor characters. These geochemical characteristics are distinct from those of the granitoids (typically of A type) associated with mantle plumes. The zircon laser ablation-inductively coupled plasma-mass spectrometry U–Pb age of 845 ± 4 Ma obtained in this study, together with other ca. 835–820 Ma ages of S-type granites in the Jiangnan Orogen, indicates that the felsic magmatism in the Jiangnan Orogen lasted for ca. 25 Ma, which is longer than typical plume-related felsic magmatism. In addition, the mafic rocks in the Jiangnan Orogen and elsewhere in the South China Block are geochemically distinct from the coeval mantle plume-related ones in Australia and west Laurentia. In geochemical diagrams diagnostic of tectonic settings, the Getengling pluton and other ca. 850–820 Ma intrusions plot in the syn- and post-collisional fields, whereas the pre-850 and post-820-Ma igneous rocks plot in the arc and within-plate settings, respectively. This sequential tectonic evolution from plate subduction through collision to within-plate environments further supports the hypothesis that the ca. 850–820-Ma granitoids in the Jiangnan Orogen resulted from the Yangtze–Cathaysia collision rather than from mantle pluming.  相似文献   

13.
Combined analyses of Nd isotopes from a wide range of Neoarchaean–Cretaceous igneous rocks provides a proxy to study magmatic processes and the evolution of the lithosphere. The main igneous associations include the Neoproterozoic granitoids from the southern Brazilian shield, which were formed during two tectonothermal events of the Brasiliano cycle: the São Gabriel accretionary orogeny (900–700 Ma) and the Dom Feliciano collisional orogeny (660–550 Ma). Rocks related to the formation of the São Gabriel arc (900–700 Ma) mainly have a depleted juvenile signature. For the Neoproterozoic collisional event, the petrogenetic discussion focuses on two old crustal segments and three types of mantle components. However, no depleted juvenile material was involved in the formation of the Dom Feliciano collisional belt (800–550 Ma), which implies an ensialic environment for the Dom Feliciano orogeny. In the western Neoproterozoic foreland, records of a Neoarchaean lower crust predominate, whereas a Paleoproterozoic crust does in the eastern Dom Feliciano belt. The western foreland includes two amalgamated geotectonic domains, the São Gabriel arc and Taquarembó block. In the collisional belt, the old crust was intensely reworked during the São Gabriel event. In addition to the Neoproterozoic subduction-processed subcontinental lithosphere (São Gariel arc), we recognize two old enriched mantle components, which also are identified in the Paleoproterozoic intraplate tholeiites from Uruguay and the Cretaceous potassic suites from eastern Paraguay. One end member displays the prominent influence of Trans-Amazonian (2.3–2.0 Ga) or older subduction events, whereas the other can be interpreted as a reenrichment of the first during the latest Trans-Amazonian collisional or younger events. This reenriched mantle is documented in late Neoproterozoic suites from the western foreland (605–550 Ma) and younger suites from the eastern collisional belt (600–580 Ma). The other enriched mantle component with an old subduction signature, however, appears only in older rocks of the collisional belt (800–600 Ma). The participation of the subduction-related Brasiliano mantle as an end member of binary mixing occurred in some early Neoproterozoic suites (605–580 Ma) from the western foreland, but the contribution of the Neoarchaean lower crust increased near the late igneous event (575–550 Ma).  相似文献   

14.
The meta-igneous rocks in the Piancó-Alto Brígida foldbelt, Borborema Province (northeastern Brazil) comprises, in the studied area, greenschists, amphibolite, and felsic gneisses derived from basalt to rhyolite precursors. In chemical terms, the mafic rocks are divided into three subgroups. Group-A metabasites have MgO > 6% and TiO2 > 1.8%. All samples exhibit within-plate chemical characteristics, such as high Zr/Y (6 to 8) and enriched incompatible elements. They have a sloping REE-normalized pattern [(La/Yb)N = 8 to 20]. Group-B metabasic rocks have low TiO2 (< 1.8%) and low Nb/Y and Zr/Y ratios (0.05 to 0.5 and 2.5 to 4.0, respectively), which place them within the mid-oceanic ridge basalt field, with N-MORB characteristics. They show a less differentiated REE-normalized pattern [(La/Y)N = 0.5] than Group-A metabasites. Group-C metabasites have a Nb/Y ratio that is intermediate between Groups A and B, and lower Ti and Nb contents. The metafelsic rocks of Group D show a highly differentiated REE-normalized pattern, with (La/Yb)N varying from 4 to 200, and a pronounced negative Eu anomaly. Tectonically the meta-igneous rocks of the studied area are interpreted to be the products of the back-arc evolution of part of the Piancó-Alto Brígida foldbelt.  相似文献   

15.
A new geochronological and geochemical study of the volcanic rocks of the Ponza and Palmarola Islands, Pontine Archipelago, has been carried out. This archipelago is located along the boundary between the Italian continental shelf and the opening Tyrrhenian basin. It is a key area to study volcanism related to the opening of the Tyrrhenian Sea. Ponza is the oldest felsic magmatic manifestation in the central Tyrrhenian area. Previous studies suggested that Ponza volcanic activity began before 5 Ma. Twenty-five new K–Ar ages constrain the volcanic activity (rhyolitic hyaloclastites and dykes) to the last 4.2 Ma, with two episodes of quiescence between 3.7 and 3.2 Ma and between 2.9 and 1.0 Ma. A new volcanic episode dated at 3.2–2.9 Ma has been identified on the central and southern Ponza, with emplacement of pyroclastic units. At 1.0 Ma, a trachytic episode ended the volcanic activity. The near island of Palmarola exhibits rhyolitic hyaloclastites and domes dated between 1.6 and 1.5 Ma, indicating that the island was entirely built during the Early Pleistocene in a short span of time of ca. 120 ka. Although only 6–8 km apart, the two islands display significantly different geochemical signatures. Ponza rhyolites show major and trace element compositions representative of orogenic magmas of subduction/collision zones: high-K calc-alkaline and metaluminous rhyolites (Agpaitic Index [AI] and Alumina Saturation Index [ASI] <1), high LILE/HFSE (Th/Ta=16–21) and LREE/HFSE ratios (La/Nb>3), and Nb–Ta negative anomalies. In Palmarola, the orogenic character is also present, but much less marked than in Ponza: rhyolites have a peralkaline character (AI>1), lower LILE/HFSE (Th/Ta=11–15), low LREE/HFSE ratios (La/Nb=1–2) close to those of anorogenic lavas, and the Nb–Ta negative anomalies are almost absent. Y/Nb ratios indicate different magmatic sources, one similar to island-arc or active continental margin basalts for Ponza rhyolites, and the others probably involving an OIB type component for Palmarola rhyolites and Ponza trachytes. Palmarola volcanics represent a transitional magmatism: although a preserved collisional geochemical imprint, they show geochemical features approaching those of anorogenic lavas erupted in a within-plate context. The change of magmatism evidenced in this study can be related to the tectonic evolution of the area. Indeed, Hf, Ta and Rb contents suggest that the oldest Pliocene rhyolites of Ponza would emplace in a syn- to late-collisional setting, while the younger Pleistocene rhyolites of Palmarola would be emplaced in a post-collisional setting in which the orogenic character (Th/Ta) decreases and mantle influence (Nb/Ta) increases. Geochemical modeling strongly suggests that the Palmarola rhyolites represent the waning stages of a subduction-related magmatism. The K–Ar datings allow us to estimate precisely the transition of magmatism to last less than 1.3 Ma. The transitional magmas may be the result of the upwelling of asthenospheric mantle inducing melting of a metasomatized lithospheric mantle and the mixing between these two sources. This upwelling could occur during the extension of the Tyrrhenian basin, caused by the slab retreat and steepening, or during a process of slab break-off starting in the Pliocene.  相似文献   

16.
The Qinling Mountains in Central China mark a gigantic composite orogenic belt with a complex tectonic evolution involving multiple phases of rifting and convergence. This belt separates the North China and South China Blocks and consists of the South and North Qinling terranes separated by the Shangdan suture. The suture is marked by the Grenvillian Songshugou ophiolite along the southern margin of the North Qinling terrane, which is key to understanding the Proterozoic tectonic evolution of the belt. The ophiolite consists of highly metamorphosed ultramafic and mafic rocks. Three groups of meta-basalts are present: group 1 rocks are LREE depleted and have a MORB compositional affinity. Their low Ta/Yb ratios (<0.1) are consistent with high degrees of partial melting of a depleted asthenospheric mantle. Rocks of group 2 have higher TiO2 (1.63–2.08 wt%) and Ta/Yb ratios (>0.12), and display slight enrichment of LREE, suggesting that the original magmas were derived from a depleted mantle source mixed with some enriched material. Samples from group 3 are enriched in LREE and other incompatible elements (Ti, Zr, Ta, Nb), suggesting derivation from an enriched mantle source, possibly a plume. All the basalts have high εNd(t) (+4.2 to +6.9), variable εSr(t) and high 207Pb/204Pb and 208Pb/204Pb ratios for given 206Pb/204Pb ratios. These characteristics are compatible with formation at a mid-ocean ridge system above an anomalous Dupal mantle region. The mafic rocks have a Sm–Nd whole-rock isochron age of 1030 ± 46 Ma.The Songshugou ophiolite was emplaced onto the southern margin of the North Qinling terrane, an active continental margin from the Meso-Proterozoic to Neo-Proterozoic.  相似文献   

17.
Geochemical analyses were interpreted on the dominant lithological units and on a deep crustal fluid from the Continental Deep Drilling Project (KTB) Pilot Hole, situated at the western margin of the Variscan Bohemian Massif. The biotite gneiss (from 384 m depth) shows a rare earth element pattern very similar to the European shale composite with Nd model ages of 940 Ma (CHUR) and 1.4 Ga (DM). The lamprophyre dike in the upper profile (1549 m), a nepheline and olivine normative basalt, is geochemically and isotopically similar to rocks from the Tertiary Central European Volcanic Province. The lower metabasite sequence (3575–4000 m), with an intrusion age of approximately 500 Ma, is made up primarily of highly metamorphosed subalkalic olivine basalts. The geochemical characteristics of the metabasites are a (La/Yb)N of 5–10, an La concentration of 20–50 times chondrite as well as (87Sr/86Sr)i of 0.7035–0.7038 and Nd(T) of 4–6. These values suggest a depleted mantle source for the igneous precursors, evolving by assimilation-fractional crystallization processes with up to 25% of upper crust into the ultramafic, basaltic, and intermediate rock types of the metabasite sequence. The strong geochemical and chronological similarities between the KTB metabasites and rocks from the Münchberg Massif suggest that these units belong to the same lithological complex. The high salinity as well as the radiogenic 87Sr/86Sr ratio of 0.709413 in the KTB fluid from 4000 m depth might be the result of migrating fluids reacting with the regional Permo-Mesozoic evaporite deposits, followed by extensive Sr isotopic exchange with the upper crust.  相似文献   

18.
http://www.sciencedirect.com/science/article/pii/S1674987111001125   总被引：1，自引：1，他引：0  
<正>Greenstone belts of the eastern Dharwar Craton,India are reinterpreted as composite tectonostratigraphic terranes of accreted plume-derived and convergent margin-derived magmatic sequences based on new high-precision elemental data.The former are dominated by a komatiile plus Mg-tholeiitic basalt volcanic association,with deep water siliciclastic and banded iron formation(BIF) sedimentary rocks.Plumes melted at90 km under thin rifted continental lithosphere to preserve inlraoceanic and continental margin aspects.Associated alkaline basalts record subduction-recycling of Mesoarchean oceanic crust,incubated in the asthenosphere.and erupted coevally with Mg basalts from a heterogeneous mantle plume.Together.komaliites-Mg basalts-alkaline basalts plot along the Phanerozoic mantle array in Th/Yb versus Nb/Yb coordinate space,representing zoned plumes,establishing that these reservoirs were present in the Neoarchean mantle. Convergent margin magmatic associations are dominated by tholeiitic to calc-alkaline basalts eompositionally similar to recent intraoceanic arcs.As well,boninitic flows sourced in extremely depleted mantle are present,and the association of arc basalts with Mg-andesites-Nb enriched basalts-adakites documented from Cenozoic arcs characterized by subduction of young(20 Ma),hot,oceanic lithosphere. Consequently.Cenozoic style "hot" subduction was operating in the Neoarchean.These diverse volcanic associations were assembled to give composite terranes in a subduction-accretion orogen at～2.1 Ga,coevally with a global accretionary orogen at ~2.7 Ga,and associated orogenic gold mineralization. Archean lithospheric mantle,distinctive in being thick,refractory,and buoyant,formed complementary to the accreted plume and convergent margin terranes.as migrating arcs captured thick plumeplateaus. and the refractory,low density.residue of plume melting coupled with accreted imbricated plume-arc crust.  相似文献   

19.
Two types of Neoproterozoic metabasites occur together with regionally intruded arc-related Neoproterozoic granitoids (ca. 850–830 Ma) in the Hongseong area, southwestern Gyeonggi Massif, South Korea, which is the extension of the Dabie–Sulu collision belt in China. The first type of metabasite (the Bibong and Baekdong metabasites) is a MORB-like back-arc basin basalt or gabbro formed at ca. 890–860 Ma. The Bibong and Baekdong metabasites may have formed during back-arc opening by diapiric upwelling of deep asthenospheric mantle which was metasomatized by large ion lithophile element (LILE) enriched melt or fluid derived from the subducted slab and/or subducted sediment beneath the arc axis. The second type of metabasite (the Gwangcheon metabasite) formed in a plume-related intra-continental rift setting at 763.5 ± 18.3 Ma and is geochemically similar to oceanic island basalt (OIB). These data indicate a transition in tectonic setting in the Hongseong area from arc to intra-continental rift between ca. 830 and 760 Ma. This transition is well correlated to the Neoproterozoic transition from arc to intra-continental rift tectonic setting at the margin of the Yangtze Craton and corresponds to the amalgamation and breakup of Rodinia Supercontinent.  相似文献   

20.
Seamount volcanism associated with the Xigaze ophiolite, Southern Tibet   总被引：6，自引：0，他引：6  
Basaltic lavas at Renbu, Southern Tibet are associated with the Xigaze ophiolite in the Yarlung-Zangbo suture zone. They are alkaline lavas rich in large ion lithophile elements (LILE, Ba, Rb and Sr) and high field strength elements (HFSE, Nb, Ta, Zr and Hf), but poor in Cr, Co and Ni. All of the rocks have chondrite-normalized REE patterns enriched in light rare earth elements (LREE), comparable to modern basalts of the Society Islands, Kerguelen Plateau and Broken Ridge. Abundances of some immobile or moderately immobile elements (Nb, Ta, Zr, Hf, Y, Ti and REE) are also comparable to Kerguelen alkaline basalts. The Renbu basalts are geochemically similar to oceanic island basalts (OIB) and have some elemental ratios, such as Nb/Ta ratios = 15.7–18.1, Th/Nb =  0.06–0.10, La/Nb = 0.59–0.83 and Th/Ta = 1.03–1.52, similar to the primitive mantle. Their 87Sr/86Sr ratios (0.70453–0.70602) are relatively high, similar to OIB. In the 87Sr/86Sr vs. εNd(t) diagram, the Renbu basalts plot along a trend from N-MORB to EMII (enriched mantle II), suggesting the involvement of at least two mantle sources in their generation. The Renbu basalts represent seamount volcanism associated with the Xigaze ophiolite. They formed from an OIB-type mantle source within the Neo-Tethyan Ocean that had a composition similar to the modern Indian Ocean mantle.  相似文献   

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