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1.
The sediment at the interface immediately beneath the water column is distinct from deeper-lying sediments in its properties and, at least quantitatively, in the processes driving diagenesis. Progress in understanding the sediment-water interface can be based on consideration of fundamentals of biogeochemical particle / fluid interactions and on application of certain biological techniques especially suited to this challenging portion of the sediment column. This article reports results achieved by combining theoretical fundamentals and specialized experimental techniques in the study of the interface from selected depositional environments. For fine-grained and sandy deposits from fresh-water to coastal marine environments, the interface is characterized by exaggerated microrelief, great porosity, and significant biological alteration. Additional application of this research approach is poised to further our understanding of engineering, and acoustic and xenochemical responses of sedimentary materials, with special emphasis on the influence of the bio-organic phase of the interface upon its fabric and physical properties.  相似文献   

2.
The paleomagnetic records and mineral-magnetic properties of unconsolidated core sediment from the east Mariana Basin of the western Pacific have been analyzed to trace the time-dependent variations in sedimentary environments. Progressive alternating field demagnetization effectively extracts a stable remanent magnetization showing both normal and reverse polarities. Comparison of successive polarity changes, recorded in the sediment core, with reference magnetic polarity time-scale, reveals that the recovered sediment column was deposited since the late Pliocene. From the sediment age model, calculated sedimentation rate during the late Pliocene was 9.8 times higher than that during the Pleistocene. Considering the oceanic environments and geologic setting in the study area, the anomalous high sediment flux during the late Pliocene was probably caused by enhanced current flows, such as North Equatorial Current, associated with atmospheric circulation as well as by debris flows from adjacent sea mounts. In addition, the systematic variation of mineral-magnetic properties indicates periodical fluxes of coarse and magnetically stable particles, on the fine-grained dominant sedimentary environments. Such influxes, however, would not be related to syn-volcanic activities, because the summits of seamounts were totally blanketed by biogenic Pliocene-Pleistocene sediments. It is, hence, reasonable to interpret that paleomagnetic and mineral-magnetic data probably reflect drastic paleoenvironmental changes at the boundary between the Pliocene and Pleistocene, where strong current and atmospheric circulations decreased.  相似文献   

3.
Pore pressures in the seabed are extremely sensitive to any imposed stress because of the low permeabilities commonly exhibited by marine sediments. Consequently, the measurement of sediment pore pressures can be used to infer either the nature of the imposed stress (if the sediment properties are known) or the physical properties of the sediment (if the imposed stresses are known). Stresses of many different types may be exerted on the seabed either through hydrostatic forces (e.g. tidal and wave effects), or directly by lithospheric forces (e.g. tectonic and thermal forces). Several techniques for measuring in situ pore pressures in the upper few metres of sediments have been developed, and one instrument, the PUPPI, will operate autonomously in water depths up to 6000 m. Basic sediment properties and processes can already be inferred from pore pressure responses using this technique. However, further application and development could greatly enhance its capability, especially for long-term monitoring of sediment conditions. In this Chapter, pore pressure measurement techniques are briefly reviewed and problems are highlighted. An outline is given of some of the many ways in which pore pressure measurements could be used to gain further insight into geological processes and to determine some of the pertinent sediment properties more accurately for engineering applications.  相似文献   

4.
Acoustics have the promise of being able to have a significant impact on our understanding of coastal sedimentary processes, which play such an important role in the dynamics of the coastal and shallow water environment. Due to this, the application of acoustics for remotely measuring suspended sediments, over ranges from metres to tens of metres, is gaining acceptance within the sediment community. This recognition of the use of acoustics to the area of sediment processes is based on advances which have been made decade in the understanding of the interaction of sound with marine suspended sediments, and also due to ongoing field observations which have shown the unique ability of the acoustic technique to measure suspended sediment profiles. In the present work acoustic measurements of suspended sediments have been conducted at 1, 2.5, 3, and 5 MHz in a number of different shallow water environments. The interpretation of the acoustic data to obtain suspended sediment concentration is presented, and some of the difficulties when inverting the acoustic information to obtain the suspended load are considered. Some discussion is also given to future uses of acoustics for studying sediment processes, and how one may utilize the application of underwater sound to manage our coastal environment more effectively  相似文献   

5.
长江粘土矿物示踪标记稳定性的初步研究   总被引：8，自引：0，他引：8       下载免费PDF全文
选择物质来源相对单一、区域较广的浙江沿岸东海内陆架区，以4种主要粘土矿物(伊利石、蒙皂石、高岭石、绿泥石)为研究对象，以探讨长江粘土矿物作为示踪标记的稳定性问题。研究区5组沉积物样品中粘土矿物的X射线衍射实验及含量分析结果表明，伊利石、蒙皂石和高岭石的相对含量较稳定，具有作为长江物源示踪标记的价值．而各区域的绿泥石含量之间不具有显著的统计相似性。现有资料还不能完全解释长江口及邻近东海内陆架区内粘土矿物组合的相对稳定状态，今后应对絮凝作用、沉积分异作用、海底生物地球化学作用等因素的效府做进一步的研究。  相似文献   

6.
Seabed sediment microstructure has an influence on its acousto-physical properties, and the properties in a length of the sediment column reflect an aspect of the macroscopic behavior of the microstructure. An original measurement method of the sound attenuation within small distance cross sections in a sediment column, and the corresponding approach in data processing to attain an attenuation factor are detailed in the paper. This method was used to measure the compressional wave in series of points with a small distance in the sediment column, and it is shown that exponential attenuation is a type of compressional wave attenuation model for a sediment column in its full length. It indicates that there are various models of compressional wave attenuation in seabed sediments in the South China Sea after comparison of data from other literature. The method of measuring sound attenuation satisfies the sampling space interval in the acoustical forward and inverse problems in seabed sediments, and the original method provides a new approach for finding out sound attenuation mechanism in seabed sediments on small length scale.  相似文献   

7.
The characteristics of shallow-water reverberation are often controlled by scattering from the seabed. While scattering mechanisms are understood in general, the state-of-the-art falls far short of predicting the correct angular and frequency dependence of scattering in a given region. A series of acoustic and supporting geoacoustic measurements were conducted over a large area in the Straits of Sicily in order to study seabed scattering in a complex littoral environment. The hypothesis was that exploiting direct path reflection coefficient measurements, in conjunction with the scattering measurements, could help illuminate the underlying scattering mechanisms. The sediment at the seabed interface was found to be a fine silty clay with nearly uniform properties across the area. Notwithstanding this spatial homogeneity, 1-6-kHz reflection and scattering measurements showed significant spatial variability. The coupled reflection-scattering approach resolved this apparent discrepancy, revealing that the reflection and scattering processes are largely controlled by the sediment properties below, rather than at, the water sediment interface. Measurements at 3600 Hz show that site-to-site variability is in part controlled by the thickness of the silty-clay layer. Layers up to 10 m below the water sediment interface contribute to the scattering at 3600 Hz.  相似文献   

8.
1. (1) The nature of sediment—sea interactions depends on the time scale considered. At a time scale commensurate with human life, one can define a water—sediment interface, and the main exchanges are solutes exchanges through this interface by concentration diffusion. This condition will be termed as “Short time-scale equilibrium interaction”.
On the other hand, at a geological time scale, there is a continuous accretion to the “sediment” of suspended particulate matter, bottom-current borne materials and sometimes precipitates of previously dissolved salts; to this sediment build-up corresponds a flux of water of reverse sense, from the sediment to the water column, due to the compaction of muds and oozes which reduce their porosity (their water content) under their own load. The concept of interface is then of limited utility, since physically it is constantly changing, and since the material balance of the exchanges does not depend on its characteristics at a first order of approximation. This condition will be termed “long time-scale geological interaction”.
These situations are extreme ones. In areas of present important detrital sedimentation, even for short time spans it is doubtful if the definition of an interface has some utility: we are in a situation close to “geological time scale”. On the contrary, in abyssal zones remote from continents, the rate of sedimentation is so low that even for eons an interface separating two environments in physico-chemical equilibrium exists.
2. (2) If there were no internal sources of dissolved species in the sediment, the only concentration changes to occur would be due to the decrease in porosity (in water content) following gravitational compaction of sediments. But this phenomenon is the same as sedimentation, thus transfer of matter would be unappreciable within short time spans. The fact that this transfer can be measured at human time scale shows therefore that dissolved species are actually produced in the sediment. Some of these can originate from possible inorganic chemical reactions, but all the organic molecules, and an important part of the inorganic (such as phosphates, nitrates, NH4+, S2-) require processing of organic matter for their production. Whether or not this reworking is of biological origin remains controversial. On the whole, the quantities of matter thus transferred are very minute compared to the quantities present in oceanic waters. They cannot be considered in general as a significant input. But they may be important locally (nearshore restricted water bodies, or manganese nodules formation).
3. (3) At geological time scale, sedimentation, which adds solid material to the preexisting sediment, results also in the compaction of this sediment. At every depth in the sediment there exists an equilibrium value of the porosity, i.e. the fluids content, of the sediment; it tends to this value by expelling the corresponding quantity of fluids, with a rate determined by its permeability. This input may be important, but it is mainly water, and water formerly oceanic: therefore it is not a true input, but simply a delayed return. The transfer of other fluids (mainly oil and gas) is unsignificant generally speaking. Once more, it may be locally important (submarine seepages).
4. (4) On the whole, the processes of water—sediment interaction appear not to add any new matter into the oceanic pool, but rather to regulate the restitution by the sediment to the water of substances which were already present in ocean, in particulate or dissolved form, either free or combined. One can trace out two main processes, which differ in their rates and yields:
4.1. (a) the short time scale diffusion—high rate low yield restitution of organics and inorganics in dissolved state:
4.2. (b) the long time scale compaction: low rate high yield restitution of entrapped fluids, essentially water (devoid of dissolved species).
Not only do these processes not bring any new matter to the ocean, but even the absolute quantities involved are modest compared either to the quantities present in the ocean or to the quantities generated by the photosynthetic primary production or brought by the rivers.In contrast to the insignificance of the water—sediment interaction in the oceanic material balance, this same interaction is one of the main sources for the material sedimented and especially the organic one, and therefore it is a fundamental key for all the subsequent sedimentary history.The significant inputs at the limit “bottom”-water come from the regions of deep tectonic activity, volcanism, creation of new oceanic crust etc… There tremendous amounts of substances can be brought into solution, changing at least locally the concentration equilibrium values of seawater. They are of course inorganic ions, but they can have important biological consequences. The buffering capacity of the world ocean is so high that only cosmic events can influence its composition.  相似文献   

9.
From the distribution of dissolved and solid arsenic species in a contaminated estuarine sediment and measured rates of flux of the various arsenic species we propose an empirical model for the cycling of arsenic between sediments and water column. The chemical form of arsenic in the sediment was largely determined by the redox state of the sediment. Arsenite was the dominant dissolved and solid species in the deeper reduced sediment, and arsenate was dominant in the oxidized surface layer. Arsenite in the interstitial water diffused toward the surface layer, where it was mostly oxidized to arsenate prior to leaving the sediments. Some arsenate adsorbed to the surface sediments and produced a surface layer enriched in arsenic. Small concentrations of methyl and dimethyl arsenic were produced in the sediments, and these also diffused into the overlying water.Nereis succinea, a burrowing polychaete, affected distribution and flux of arsenic from the sediments by its production of irrigated burrows. These burrows increased both the effective surface area of the sediment and the diffusion of arsenic by a factor of five. When the relative effects of the activities of Nereis succinea and physical resuspension are compared, results indicate that although physical resuspension can produce large pulses of materials from contaminated sediments, continuous biological activity is likely to be more important in the mobilization of contaminants from sediments in many estuarine environments.  相似文献   

10.
Deep-sea benthic ecosystems are mainly sustained by sinking organic materials that are produced in the euphotic zone. “Benthic-pelagic coupling” is the key to understanding both material cycles and benthic ecology in deep-sea environments, in particular in topographically flat open oceanic settings. However, it remains unclear whether “benthic-pelagic coupling” exists in eutrophic deep-sea environments at the ocean margins where areas of undulating and steep bottom topography are partly closely surrounded by land. Land-locked deep-sea settings may be characterized by different particle behaviors both in the water column and in relation to submarine topography. Mechanisms of particle accumulation may be different from those found in open ocean sedimentary systems. An interdisciplinary programme, “Project Sagami”, was carried out to understand seasonal carbon cycling in a eutrophic deep-sea environment (Sagami Bay) with steep bottom topography along the western margin of the Pacific, off central Japan. We collected data from ocean color photographs obtained using a sea observation satellite, surface water samples, hydrographic casts with turbidity sensor, sediment trap moorings and multiple core samplings at a permanent station in the central part of Sagami Bay between 1997 and 1998. Bottom nepheloid layers were also observed in video images recorded at a real-time, sea-floor observatory off Hatsushima in Sagami Bay. Distinct spring blooms were observed during mid-February through May in 1997. Mass flux deposited in sediment traps did not show a distinct spring bloom signal because of the influence of resuspended materials. However, dense clouds of suspended particles were observed only in the spring in the benthic nepheloid layer. This phenomenon corresponds well to the increased deposition of phytodetritus after the spring bloom. A phytodetrital layer started to form on the sediment surface about two weeks after the start of the spring bloom. Chlorophyll-a was detected in the top 2 cm of the sediment only when a phytodetritus layer was present. Protozoan and metazoan meiobenthos increased in density after phytodetritus deposition. Thus, “benthic-pelagic coupling” was certainly observed even in a marginal ocean environment with undulated bottom topography. Seasonal changes in features of the sediment-water interface were also documented.  相似文献   

11.
Microresistivity imaging and X-radiography of 3-cm-thick sediment core slabs collected by divers from Eckernförde Bay, Germany, indicate subtle delineations and features created by hydrodynamic and biological processes within the top 20 cm of the sediment. Variations in the images of both techniques are controlled by the physical properties of the sediment. The X-radiographs record attenuation by solids throughout the 3-cm thickness of the sediment slab, while microresistivity images depend on pore water in terms of amount, salinity, and distribution. The microresistivity method is shown to detect layered structures and the presence of shells within the highporosity sediment.  相似文献   

12.
An overview of SAX99: acoustic measurements   总被引：5，自引：0，他引：5  
A high-frequency acoustic experiment was performed at a site 2 km from shore on the Florida Panhandle near Fort Walton Beach in water of 18-19 m depth. The goal of the experiment was, for high-frequency acoustic fields (mostly In the 10-300-kHz range), to quantify backscattering from the seafloor sediment, penetration into the sediment, and propagation within the sediment. In addition, spheres and other objects were used to gather data on acoustic detection of buried objects. The high-frequency acoustic interaction with the medium sand sediment was investigated at grazing angles both above and below the critical angle of about 30°. Detailed characterizations of the upper seafloor physical properties were made to aid in quantifying the acoustic interaction with the seafloor. Biological processes within the seabed and the water column were also investigated with the goal of understanding their impact on acoustic properties. This paper summarizes the topics that motivated the experiment, outlines the scope of the measurements done, and presents preliminary acoustics results  相似文献   

13.
The use of dissolved Al as a tracer for oceanic water masses and atmospheric dust deposition of biologically important elements, such as iron, requires the quantitative assessment of its sources and sinks in seawater. Here, we address the relative importance of oceanic versus atmospheric inputs of Al, and the relationship with nutrient cycling, in a region of high biological productivity in coastal Antarctica. We investigate the concentrations of dissolved Al in seawater, sea ice, meteoric water and sediments collected from northern Marguerite Bay, off the West Antarctic Peninsula, from 2005 to 2006. Dissolved Al concentrations at 15 m water depth varied between 2 and 27 nM, showing a peak between two phytoplankton blooms. We find that, in this coastal setting, upwelling and incorporation of waters from below the surface mixed layer are responsible for this peak in dissolved Al as well as renewal of nutrients. This means that changes in the intensity and frequency of upwelling events may result in changes in biological production and carbon uptake. The waters below the mixed layer are most likely enriched in Al as a result of sea ice formation, either causing the injection of Al-rich brines or the resuspension of sediments and entrainment of pore fluids by brine cascades. Glacial, snow and sea ice melt contribute secondarily to the supply of Al to surface waters. Total particulate Al ranges from 93 to 2057 mg/g, and increases with meteoric water input towards the end of the summer, indicating glacial runoff is an important source of particulate Al. The (Al/Si)opal of sediment core top material is considerably higher than water column opal collected by sediment traps, indicative of a diagenetic overprint and incorporation of Al at the sediment–water interface. Opal that remains buried in the sediment could represent a significant sink of Al from seawater.  相似文献   

14.
The relationship between acoustic backscatter, sediment characteristics and benthic habitat is examined using high-resolution sidescan sonar data collected at the Loch Linnhe artificial reef site on the west coast of Scotland. The site is typical for the continental shelf of NW Europe, with a mix of seabed environments from muddy to coarse, stony substrata on a 10–100 m length scale. A sidescan sonar mosaic was produced and classified according to derived backscatter parameters (mean, median and standard deviation of the backscatter values) using an unsupervised classification procedure. The accuracy of the final classified map was assessed by comparison with a ground-truthing survey in which the biological habitat was derived from underwater video footage. The sidescan correctly predicted seabed surface characteristics of observed biological habitat with 78% accuracy. A second, and more challenging test of the acoustic data to correctly predict biological habitat was made by comparing it with data from 21 grab sampling stations. These stations were divided into three groups using multivariate statistical techniques based on their backscatter properties. Benthic assemblage structure was found to be significantly distinct between the high and low, and the medium and low backscatter stations. There was a low to moderate but significant correlation between the multivariate patterns of acoustic backscatter, benthic assemblage structure, and particle size distribution. The work shows that even in areas with subtle and gradational changes in substratum, the sidescan was able to predict biological community with an acceptable accuracy.  相似文献   

15.
The interdependence between the seismo-acoustic properties of a marine sediment and its geotechnical/physical parameters has been known for many years, and it has been postulated that this should allow the extraction of geotechnical information from seismic data. Though in the literature many correlations have been published for the surficial layer, there is a lack of information for greater sediment depths. In this article, a desktop study on a synthetic seafloor model illustrates how the application of published near-surface prediction equations to subsurface sediments (up to several tens of meters burial depth) can lead to spurious predictions. To test this further, acoustic and geotechnical properties were measured on a number of sediment core samples, some of which were subjected to loading in acoustically-equipped consolidation cells (oedometers) to simulate greater burial depth conditions. For low effective pressures (representing small burial depths extending to around 10 meters subsurface), the general applicability of established relationships was confirmed: the prediction of porosity, bulk density, and mean grain size from acoustic velocity and impedance appears generally possible for the investigated sedimentary environments. As effective pressure increases through, the observed relationships deviate more and more from the established ones for the near-surface area. For the samples tested in this study, in some instances increasing pressure even resulted in decreasing velocities. There are several possible explanations for this abnormal behavior, including the presence of gas, overconsolidation, or bimodal grain size distribution. The results indicate that an appropriate depth correction must be introduced into the published prediction equations in order to obtain reliable estimates of physical sediment properties for greater subsurface depths.  相似文献   

16.
This paper proposes a method, based on the Biot model, for estimating the physical and acoustic properties of surficial ocean sediments from normal incidence reflection data acquired by a chirp sonar. The inversion method estimates sediment porosity from reflection coefficient measurements and, using the estimated porosity and the measured change in fast wave attenuation with frequency, estimates the permeability of the top sediment layer. The spectral ratio of echoes from the interface at the base of the upper sediment layer and from the sediment-water interface provides a measure of the change in attenuation with frequency. Given the porosity and permeability estimates, the Kozeny-Carman equation provides the mean grain size and the inversion method yields the acoustic properties of top sediment layer. The inversion technique is tested using chirp sonar data collected at the 1999 Sediment Acoustics Experiment (SAX-99) site. Remote estimates of porosity, grain size, and permeability agree with direct measurements of those properties.  相似文献   

17.
The interdependence between the seismo-acoustic properties of a marine sediment and its geotechnical/physical parameters has been known for many years, and it has been postulated that this should allow the extraction of geotechnical information from seismic data. Though in the literature many correlations have been published for the surficial layer, there is a lack of information for greater sediment depths. In this article, a desktop study on a synthetic seafloor model illustrates how the application of published near-surface prediction equations to subsurface sediments (up to several tens of meters burial depth) can lead to spurious predictions. To test this further, acoustic and geotechnical properties were measured on a number of sediment core samples, some of which were subjected to loading in acoustically-equipped consolidation cells (oedometers) to simulate greater burial depth conditions. For low effective pressures (representing small burial depths extending to around 10 meters subsurface), the general applicability of established relationships was confirmed: the prediction of porosity, bulk density, and mean grain size from acoustic velocity and impedance appears generally possible for the investigated sedimentary environments. As effective pressure increases through, the observed relationships deviate more and more from the established ones for the near-surface area. For the samples tested in this study, in some instances increasing pressure even resulted in decreasing velocities. There are several possible explanations for this abnormal behavior, including the presence of gas, overconsolidation, or bimodal grain size distribution. The results indicate that an appropriate depth correction must be introduced into the published prediction equations in order to obtain reliable estimates of physical sediment properties for greater subsurface depths.  相似文献   

18.
The importance of interstitial pore water as a vehicle for transport of dissolved ions between sediment at depth and the overlying ocean reservoir may be overestimated. The major cause of this overestimation is the assumption that the rate of ionic diffusion through the sediment is of a similar magnitude to the rate of reaction occurring within the sediment column. Examples are given to indicate that the above assumption may not be correct, at least for diagenetic sulfate reduction. Closed-system modeling, although approximate, is shown to be consistent, both qualitatively and isotopically, with measured changes that are observed for several sedimentary environments.  相似文献   

19.
The detailed investigation of organic carbon cycling in estuarine and marine environments has stimulated the development of multidisciplinary concepts, research and sampling strategies as well as analytical tools in the last 10 years. Among other approaches, the molecular biomarker one has also undergone significant improvements. Some examples dealing with specific markers including sterols, alkenes and fatty acids are discussed in this paper in terms of source identification and transformation processes.Although some limitations exist for the elucidation of their stereochemistry, sterols have been used extensively to study biochemical processes affecting the organic matter in the water column and at the ocean/sediment interface. Sterols also appear as promising tracers of terrestrial vs. marine inputs in complex estuarine systems. The specificity of individual fatty acids or groups of acids has also been used to assess the origins and transformation processes of organic matter in marine samples. New approaches are presented including the investigation of intact lipid classes and the elucidation of the position of double bonds of unsaturated fatty acids and alkenes. Finally, we discuss the use of che-mometric techniques due to increasing chemical information and the interest of combining molecular-level and stable isotope approaches.  相似文献   

20.
The concentration profiles of nitrate plus nitrite, ammonium, and redox potential in sediment and water column were determined in late winter and summer at a sampling site off Norrbyn, northern Sweden, in the Gulf of Bothnia. The sediment had an oxidized surface layer during winter and spring, and nitrification occurred. Nitrate but not ammonium was present in the water column at this time. During summer a layer of planktonic detritus was deposited onto the sediment and led to its deoxygenation and reduction. Ammonium was then the predominant form of inorganic nitrogen in the water column.Laboratory experiments confirmed that nitrification in the surface layer of sediment prevented ammonium export during winter. Enhanced temperature or organic detritus deoxygenated the surface sediment and inhibited nitrification, and export of ammonium from the sediment increased. Although nitrification was important in determining the flow of nitrogen in the sediment it accounted for at most only 5% of the total oxygen uptake by the sediment.  相似文献   

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