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1.
Orozco Miguel Molina José Miguel Crespo-Blanc Ana Alonso-Chaves Francisco Manuel 《Geologie en Mijnbouw》1999,78(1):103-117
The rauhwackes near Serón in the northern Sierra de los Filabres (S Spain), previously considered as true tectonic breccias, are reinterpreted on the basis of sedimentological, geomorphological and geometrical evidence as subaerial or nearly subaerial sedimentary deposits. Channel fills, parallel lamination, cross-lamination, graded bedding, sedimentary clastic dykes and other sedimentary structures and features occur in the rauhwacke body. These sedimentary rocks correspond to continental deposits of alluvial and karstic origin deposited over a karstified erosional surface of Nevado–Filabride marbles. Although no fossils have been found in the rauhwackes, a Tortonian age for these rocks is suggested on the basis of structural arguments and lithostratigraphic data from the nearby Almanzora basin. The rauhwackes were buried by slabs of Alpujarride rocks that gravitationally slid over them during the uplifting of the Sierra de los Filabres. 相似文献
2.
The major chemical components of bauxite deposits of Belgaum (76° 24′E : 15° 54′N) and Yercaud (78° 14′E : 11° 48′N) areas
have been determined. A chemical continuity between parent rocks (zone I) to bauxites (zone IV) via clay (zone II) and laterites
(zone III) clearly indicates that bauxites have been derived byin situ weathering of the respective parent rocks. 相似文献
3.
桂西地区铝土矿为典型喀斯特型,包括二叠系沉积型和第四系堆积型两亚类。堆积型铝土矿是沉积型铝土矿经抬升、破碎、风化,最后堆积于喀斯特洼地中形成。以平果教美铝土矿为研究对象,探索堆积型铝土矿形成过程中矿物的变化与元素迁移。沉积型矿石的矿物组成包括硬水铝石、鲕绿泥石、锐钛矿及少量针铁矿、金红石和高岭石;堆积型矿石的矿物组成主要为硬水铝石、锐钛矿、高岭石及少量三水铝石和鲕绿泥石。转化过程中堆积型矿石中的硬水铝石含量明显增加,鲕绿泥石含量明显减少。沉积型铝土矿的主要化学组成为Al2O3、SiO2、FeO和TiO2;堆积型为Al2O3、SiO2、TiO2和Fe2O3。两类矿石中元素Zr 、Ba、Nb、V含量均较高,稀土总量变化大,富集轻稀土。质量平衡计算表明堆积型铝土矿形成过程中Al、Ba、Sr、Y等元素增加,而Si、Fe、Ti、Nb、V、Ce等元素减少,其余元素变化不明显。 相似文献
4.
Subaerial leaching process of sedimentary bauxite and the discussion on classifications of bauxite deposits 
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下载免费PDF全文 Bauxite is the ultimate fine-grained products of chemical weathering,and thus it is closely linked with the intense chemical weathering. Based on variations of parent rock and weathering processes,the weathering products can be subdivided into laterite and terra rossa,of which the former is formed by weathering of aluminosilicates and the latter is produced by the weathering of carbonates. During the intense chemical weathering,minerals in original subaerial sediments(parent rocks)would suffer a series of processes(dissolution,hydrolyzation,hydration,carbonation,and oxidation)and be destroyed or transformed,leading to formation of new minerals. In the favorable environment,continuously intense chemical weathering would cause the loss of most mobile elements(e.g., K,Na,Ca,Mg,Si)and the enrichment of Al,resulting in the formation of bauxite. Although sedimentary bauxites are closely linked with the weathering curst,they show obvious differences in formation processes. Sedimentary bauxites are composed of intense chemical weathering products that are transported from outside of the basin and re-deposited in the basin,while most weathering crusts are transformed from saprolite and/or deluvium in-situ,and they can only form low-grade bauxites. Sedimentary environments also differ in bauxite ore layers and bauxitic claystone layers. Bauxite ore layers are formed in the subaerial environment and controlled by the leaching process of groundwater in the vadose zone. Based on the analysis of bauxitization,this study proposes to use multiple parameters,such as provenance,sedimentation and mineralization,to build the new classification of Chinese bauxite deposits. In this classification,lateritic and karstic types of bauxite deposits are autochthonous or parautochthonous saprolite and/or deluvium,while sedimentary type is dominated by heterochthonous provenance. 相似文献
5.
Karstic bauxite deposits are widespread in Central Guizhou Province, SW China, and high-grade ores are frequently sandwiched with overlying coal and underlying iron-rich layers and form a special “coal–bauxite–iron” structure. The Lindai deposit, which is one of the most representative karstic bauxite deposits in Central Guizhou Province, was selected as a case study. Based on textural features and iron abundances, bauxite ores in the Lindai deposit are divided into three types of ores, i.e., clastic, compact, and high-iron. The bauxite ores primarily comprise diaspore, boehmite, kaolinite, illite, and hematite with minor quartz, smectite, pyrite, zircon, rutile, anatase, and feldspar. The Al2O3 (53–76.8 wt.%) is the main chemical contents of the bauxite ore samples in the Lindai district, followed by SiO2, Fe2O3, TiO2, CaO, MgO, S, and P etc. Our geological data on the Lindai deposit indicated that the ore-bearing rock series and its underlying stratum have similar rare earth elements distribution pattern and similar Y/Ho, Zr/Hf, and Eu/Eu1 values; additionally, all ore-bearing rock samples are rich in MgO (range from 0.16 wt.% to 0.68 wt.%), and the plots of the dolomites and laterites lie almost on or close to the weathering line fit by the Al-bearing rocks in Zr vs. Hf and Nb vs. Ta diagrams; suggesting that the underlying Middle Cambrian Shilengshui Formation dolomite is the parent rock of bauxite resources in the Lindai district.Simulated weathering experiments on the modern laterite from the Shilengshui Formation dolomite in the Lindai bauxite deposit show that hydrogeological conditions are important for karstic bauxite formation: Si is most likely to migrate, its migration rate is several magnitudes higher than those of Al and Fe under natural conditions; the reducing inorganic acid condition is the most conducive to Al enrichment and Si removal; Fe does not migrate easily in groundwater, Al enrichment and Fe removal can occur only in acidic and reducing conditions with the presence of organic matter.The geological and experimental studies show that “coal–bauxite–iron” structure in Lindai deposit is formed under certain hydrogeological conditions, i.e., since lateritic bauxite or Al-rich laterite deposited upon the semi-closed karst depressions, Si can be continuously removed out under neutral/acidic groundwater conditions; the coal/carbonaceous rock overlying the bauxitic materials were easily oxidized to produce acidic (H2S, H2SO4, etc.) and reductant groundwater with organic materials that percolated downward, resulting in enrichment of Al in underlying bauxite; it also reduced Fe3+ to its easily migrating form Fe2+, moving downward to near the basal carbonate culminated in precipitating of ferruginous (FeS2, FeCO3, etc.) strata of the “coal–bauxite–iron” structure. Thus, the bauxitic materials experienced Al enrichment and Si and Fe removal under above certain hydrogeological conditions forming the high-quality bauxite. 相似文献
6.
M.N. Oti 《Chemical Geology》1987,60(1-4):63-72
Laterites of southeastern Nigeria developed on rocks of the crystalline Basement Complex and on sedimentary rocks of the lower Benue Trough were studied in order to characterize them geochemically and texturally. In the sedimentary basin, rocks of each major stratigraphic formation were analyzed.
It is found that the laterites are mature with Al2O3/(Fe2O3 + SiO2) ratios of <1, and that lithology rather than stratigraphy exerts the main control on the laterization process in SE Nigeria. Zn, Cr and Mn appear to be relatively more concentrated in these laterites than the other elements analyzed; the affinity between Mn and Fe is reflected well but not that between Pb and Zn, although this was expected in view of the occurrence of galena and sphalerite in the area. Most of the laterites are pisolitic and/or vermiform in texture. There are no essential geochemical differences between laterites formed on the Precambrian Basement Complex and those formed on Cretaceous and Younger sediments. 相似文献
7.
A brief characteristic of three genetic groups of large and superlarge (lateritic, sedimentary, and karstic) bauxite deposits is presented. Their structure, composition, formation conditions, and localization patterns in the Earth’s Phanerozoic history are unraveled. Climatic, tectonic, geomorphological, hydrogeological, and other major factors favorable for bauxite formation are scrutinized. It is shown that only the combination of these factors produces large deposits that can make up productive bauxite ore districts and provinces. 相似文献
8.
《Journal of African Earth Sciences》2006,44(5):525-536
The studied serpentinites occur as isolated masses, imbricate slices of variable thicknesses and as small blocks or lenses incorporated in the sedimentary matrix of the mélange. They are thrusted over the associated island arc calc-alkaline metavolcanics and replaced by talc-carbonates along shear zones. Lack of thermal effect of the serpentinites upon the enveloping country rocks, as well as their association with thrust faults indicates their tectonic emplacement as solid bodies. Petrographically, they are composed essentially of antigorite, chrysotile and lizardite with subordinate amounts of carbonates, chromite, magnetite, magnesite, talc, tremolite and chlorite. Chrysotile occurs as cross-fiber veinlets traversing the antigorite matrix, which indicate a late crystallization under static conditions. The predominance of antigorite over other serpentine minerals indicates that the serpentinites have undergone prograde metamorphism or the parent ultramafic rocks were serpentinized under higher pressure. The parent rocks of the studied serpentinites are mainly harzburgite and less commonly dunite and wehrlite due to the prevalence of mesh and bastite textures. The serpentinites have suffered regional metamorphism up to the greenschist facies, which occurred during the collisional stage or back-arc basin closure, followed by thrusting over a continental margin. The microprobe analyses of the serpentine minerals show wide variation in SiO2, MgO, Al2O3, FeO and Cr2O3 due to different generations of serpentinization. The clinopyroxene relicts, from the partly serpentinized peridotite, are augite and similar to clinopyroxene in mantle-derived peridotites. The chromitite lenses associated with the serpentinites show common textures and structures typical of magmatic crystallization and podiform chromitites. The present data suggest that the serpentinites and associated chromitite lenses represent an ophiolitic mantle sequence from a supra-subduction zone, which were thrust over the continental margins during the collisional stage of back-arc basin. 相似文献
9.
黔中—渝南成矿带石炭纪铝土矿含矿岩系,分别形成于修文、息烽—遵义和黔北—渝南三个沉积区,大多数铝土矿属产于碳酸盐岩侵蚀面上的、少数为产于泥页岩侵蚀面上的硬水铝石沉积型铝土矿床。修文沉积区铝土矿中Zr、RE2O3含量最多,息烽—遵义沉积区铝土矿中Ga含量最多,黔北—渝南沉积区Li含量最多,各有特色。修文沉积区铝土矿含矿岩系的母岩,是其下伏寒武系碳酸盐岩与下奥陶统页岩、灰岩、白云岩;息烽—遵义沉积区含矿岩系的母岩为下伏下奥陶统页岩、灰岩及白云岩;黔北—渝南沉积区含矿岩系的母岩,是下伏下志留统泥、页岩和上石炭统石灰岩。碳酸盐岩中Al2O3与稳定的微量元素含量甚少,要演变成大面积铝土矿,必须要配以足够的含Al2O3和微量元素较多的泥、页岩,才可能满足形成大规模铝土矿的物质需求。 相似文献
10.
Mineralogical-geochemical features of different facies types of sedimentary iron ore deposits are described. Particular attention is paid to deposits associated with the weathering crusts of ultramafic igneous rocks and to marine oolitic iron ores. The multistage formation of their geochemical properties is proved available geochemical models are considered. 相似文献
11.
The studied serpentinites occur as isolated masses, imbricate slices of variable thicknesses and as small blocks or lenses incorporated in the sedimentary matrix of the mélange. They are thrusted over the associated island arc calc-alkaline metavolcanics and replaced by talc-carbonates along shear zones. Lack of thermal effect of the serpentinites upon the enveloping country rocks, as well as their association with thrust faults indicates their tectonic emplacement as solid bodies. Petrographically, they are composed essentially of antigorite, chrysotile and lizardite with subordinate amounts of carbonates, chromite, magnetite, magnesite, talc, tremolite and chlorite. Chrysotile occurs as cross-fiber veinlets traversing the antigorite matrix, which indicate a late crystallization under static conditions. The predominance of antigorite over other serpentine minerals indicates that the serpentinites have undergone prograde metamorphism or the parent ultramafic rocks were serpentinized under higher pressure. The parent rocks of the studied serpentinites are mainly harzburgite and less commonly dunite and wehrlite due to the prevalence of mesh and bastite textures. The serpentinites have suffered regional metamorphism up to the greenschist facies, which occurred during the collisional stage or back-arc basin closure, followed by thrusting over a continental margin. The microprobe analyses of the serpentine minerals show wide variation in SiO2, MgO, Al2O3, FeO and Cr2O3 due to different generations of serpentinization. The clinopyroxene relicts, from the partly serpentinized peridotite, are augite and similar to clinopyroxene in mantle-derived peridotites. The chromitite lenses associated with the serpentinites show common textures and structures typical of magmatic crystallization and podiform chromitites. The present data suggest that the serpentinites and associated chromitite lenses represent an ophiolitic mantle sequence from a supra-subduction zone, which were thrust over the continental margins during the collisional stage of back-arc basin. 相似文献
12.
An attempt is made to reveal a geochemical compatibility with paleoenvironment to understand the genesis of bauxite deposits that are derived from two different parent rocks. For this purpose two in situ bauxite profiles, one developed over basalt and another over sandstone, have been taken. Gibbsite is the major mineral in all these bauxites with minor occurrences of goethite, hematite, anatase, kaolinite, etc. From the study it is evident that the paleoenvironment and geochemical processes are vital factors that could lead to the formation of bauxites. The significance of this is fully discussed. 相似文献
13.
华北克拉通在中奥陶世至晚石炭世期间一直出露地表,经历了长期的风化作用,形成大规模的铁-铝黏土矿,其成矿物源一直是研究的热点,尤其是本溪组底部铁矿和铁质黏土矿与上部铝黏土矿是否为同一来源尚未查清。本研究选取克拉通南缘大安铝黏土矿床作为研究对象,展开微区矿物及元素地球化学组成分析,进一步探讨铁-铝黏土矿物质来源。大安矿床内含矿岩系自下而上包括铁质黏土岩、铝土矿、铝质黏土矿;局部喀斯特高地缺失铝土矿,铝质黏土矿直接覆盖于铁质黏土岩之上。铁质黏土岩在洼地以菱铁矿、黄铁矿和伊利石为主,在隆起区以赤铁矿、伊利石和高岭石为主。铝土矿以硬水铝石、伊利石和锐钛矿为主;铝质黏土矿主要矿物为伊利石。矿物微区分析在黏土矿底部发现大量的碳化硅和少量自然硅、硅铁矿、铬铁矿;区域对比揭示北秦岭造山带内商丹缝合带和二郎坪群中的蛇绿岩为铝黏土矿形成提供了成矿物质。本溪组底部铁质黏土与上部铝黏土矿稳定元素比率(例如Zr/TiO2、Hf/TiO2、Nb/TiO2、Ta/TiO2)存在明显差异,揭示二者为不同来源: 底部铁质黏土岩和铁矿层为底板碳酸盐岩原地风化的产物;而上部铝黏土矿是异地搬运物,北秦岭造山带在晚石炭世的整体抬升为华北铝黏土矿形成提供了重要的成矿物质。 相似文献
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Through a systematic study on trace elements and REE geochemistry of mudstone deposited in the basin and lower slope environments during Upper Proterozoic to Triassic in the Southwest Yangtze Mssif,three geochemical abnormal horizons of which the geochemical characteristics are quite different from those of other horizons have been established for the first time.They are the Lower Cambrian,the Upper Devonian and the Upper Permian,As compared with the crustal evolution in this area.these three geochemical abnormal horizons are corresponding to the pulling-apart periods of geotectonic cycles.which illustrates that uncommon depositional sources puring into the basin from the earth‘s interior may be one of the most important causes to originate the geochemical anomalies in these lhrizons.Thus it can be realized that the geochemistry of post-Archean sedimentary rocks has a great deal to do with the crustal evolution and it can be used as a tracer to analyze the crustal evolution.The elements in this area are mainly concentrated in these geochemical abnormal horizons,and the degree of enrichment and deficiency of trace elements in other horizons is very limited.A series of research on mineralization indicates that the main strata-bound ore deposits discovered in the Southwest Yangtze Massif occur in the Cambrian,Devonian and Permian-Trassic strata.The results of isotope tracer resarch have also proved that most of the metallogenic elements in these ore deposits came from the host strata.which illustrates that the geochemical abnormal horizons may have made great contributions to these ore-forming processes.Thus it can be concluded that it is only the particular horizons corresponding to the particular periode of earth‘s evolution that can they be the significant source beds because only in these uncommon horizons there can be highly enriched metallogeinc elements.which may be one of the most important reasons for explaining the time-bound nature of mineralization. 相似文献
16.
W. E. Petrascheck 《Mineralium Deposita》1989,24(2):77-81
Some Mediterranean bauxite deposits in karst, considered to be allochthonous originating from neighboring silicate rocks, reveal the following common features of fluvial transport and sedimentation: (1) The SiO2 content increases in the direction of the transport; (2) the trace elements indicate the area of origin; (3) the bauxite was deposited in depressions of a slightly karstified coastal plain in a lagoonal or estuarine environment; (4) the karst relief became accentuated after the bauxite was covered by sediments; and (5) the depth of the karstic depressions was controlled by the former groundwater level. Therefore, the thickness of the orebodies increases with the distance from the former shoreline. These factors have an implication on the strategy of exploration. The following examples are taken from central Greece and Montenegro and comparisons are made with the bauxite districts of France, Italy, and Jamaica. 相似文献
17.
Prof. A. J. Bernard 《International Journal of Earth Sciences》1974,63(1):41-51
The author summarizes the main arguments in the debate between syngenetic and epigenetic deposits and then underlines the importance of the arguments which prove that the formation of the sediments and of the metalliferous concentrations which they bear are contemporaneous. This is strongly suggested by very early syn-sedimentary reworking of the mineralization. This approach leads to a consideration of metallogenesis of syngenetic sedimentary concentrations both as a supply of metal and a sedimentary trap. The exploitability of mineralized rocks is presently such that only the coincidence of an outstanding supply of metal and a receptive sedimentary environment will yield a workable ore deposit. Reviewing all metalliferous sources which could be contemporaneous with sedimentation (terrigenous, exhalative, marine and possibly also fluidogenic) the author stresses the geological and geochemical characteristic of the surrounding sediments. At the same time, the examination of traps in sandy, shaly and carbonate environments permits to the identification of the main characteristics of the concentration on the scale of the deposit and of the ore itself. The search for an understanding of metalliferous concentrations in the sedimentary cycle becomes a question of defining criteria for the quality of supplies and traps. On the level of the trap these would be the duration and the regulation of parameters which govern the efficiency of the concentrating system: the sedimentary features which result from these concentrating processes must be recognized within the lithologic column during tactical exploration. On the level of the metallogenetic province it is the purpose of strategic exploration to search among the available geological and geochemical data for features which favor each type of supply. These are the basic principles of the indirect method of exploration for sedimentary ore deposits. 相似文献
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《International Geology Review》2012,54(2):179-193
The Chadobets uplift is located in the southwestern part of the Siberian platform (Lat. 59° 10′ N, Long. 99°29′–100° 11′ E). It is a brachyanticline with two domes, the Terinovskiy (19 × 16 km) and the Chuktukon (7 × 6 km). The Central and Chuktukon deposits situated on the domes were derived from laterized Proterozoic quartz-mica-feldspar slates and sandstones and Triassic alkaline ultramafic rocks (picrite, pyroxenite, kimberlite, and carbonatite). The laterite profiles attain a thickness of 600 m on slates, 300 m on carbonatites, and 80 km on kimberlites. The final weathering products are bauxites, Al-Ti-Fe laterites, and Fe-Mn ochres enriched in REE (up to 50% Ln2O3 and 1% Y2O3), Nb (up to 5% Nb2O5), Ti (up to 32% TiO2), Th (0.1–0.4% ThO2), as well as Ba, P., Zn, and V. The laterites contain gibbsite; goethite; hematite; anatase after perovskite; oxyhydroxides of Mn; supergene monazite; rhabdophane; florencite; churchite; Ce-, Ba-, and Sr-pyrochlores; cerianite; barite; francolite; etc. Cretaceous-Paleogene sedimentary bauxites accumulated all these minerals, plus boehmite, diaspore, corundum, berthierine, siderite, calcite, marcasite, and pyrite. The bauxites contain 9.5% TiO2, up to 4% TR2O3 (LREE), 0.8% Nb2O5, and 0.31% ThO2. Because of their geologic setting, number of parent rocks, and mineral and chemical composition, the Central and Chuktukon deposits are unique complex deposits of bauxite, rare elements, and rare-earth elements. 相似文献