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1.
Thermodynamic modeling of the hydrothermal exposure of the rocks of the Bazhenov Formation resulted in revealing the equilibrium mineral associations at 50–350°C and the pressure of saturated water vapor. The calculation results show that mineral parageneses varied slightly with the increase of temperature. Thus, zeolites were characterized by the stilbite–laumontite–wairakite series; kaolinite, pyrite, dolomite, and brannerite were replaced by montmorillonite and/or albite, pyrrhotite, calcite, and uraninite, respectively. The modeling results were confirmed in experiments.  相似文献   

2.
In this review, we describe the geological characteristics and metallogenic–tectonic origin of Fe deposits in the Altay orogenic belt within the Xinjiang region of northwestern China. The Fe deposits are found mainly within three regions (ordered from northwest to southeast): the Ashele, Kelan, and Maizi basins. The principal host rocks for the Fe deposits of the Altay orogenic belt are the Early Devonian Kangbutiebao Formation, the Middle to Late Devonian Altay Formation, with minor occurrences of Lower Carboniferous and Early Paleozoic metamorphosed volcano-sedimentary rocks. The principal mineral-forming element groups of the deposits are Fe, Fe–Cu, Fe–Mn, Fe–P, Fe–Pb–Zn, Fe–Au, and Fe–V–Ti. The Fe deposits are associated with distinct formations, such as volcanic rocks, skarn deposits, pegmatites, granite-related hydrothermal vein mineralization, and mafic pluton-related V–Ti-magnetite deposits. The Fe deposits are most commonly associated with volcanic rocks in the upper Kangbutiebao Formation, in the volcano-sedimentary Kelan Basin, and in skarn deposits at several localities, including the lower Kangbutiebao Formation in the volcano-sedimentary Maizi Basin, and the Altay Formation at Jiaerbasidao–Kekebulake region. Homogenization temperatures of fluid inclusions in the prograde, retrograde and sulfide stages of the skarn type deposit are mainly medium- to high-temperature (cluster between 200 and 500 °C), medium-temperature (cluster between 200 and 340 °C) and low- to medium temperature (cluster between 160 and 300 °C), respectively. Ore fluids in the sedimentation period in the volcano-sedimentary type deposit are characterized by low- to medium temperature (with a peak around 190 °C), low to moderate salinity (3.23 to 22.71 wt.% NaCl equiv). Ore fluids in the pegmatite type deposit are characterized by low- to medium temperature (with a peak at 240 °C), low salinity (with a peak around 9 wt.% NaCl equiv). An analysis of the isotopic data for Fe deposits from the Altay orogenic belt indicates that the sulfur was derived from several sources, including volcanic rocks and granite, as well as bacterial reduction of sulfate from seawater. The present results indicate that different deposit types were derived from various sources. The REE geochemistry of rocks and ores from the Fe deposits in the Altay orogenic belt suggests that the ore-forming materials were derived from mafic volcanic rocks. Based on isotopic age data, the timing of the mineralization can be divided into four broad intervals: Early Devonian (410–384 Ma), Middle Devonian (377 Ma), Early Permian (287–274 Ma), and Early Triassic (c. 244 Ma). The ore-forming processes of the Fe deposits are closely related to volcanic activity and the emplacement of intermediate and felsic intrusions. We conclude that Fe deposits within the Altay orogenic belt developed in a range of tectonic settings, including continental arc, post-collisional extensional settings, and intracontinental settings.  相似文献   

3.
In the central West-Siberian basin, fractured and cavernous carbonate rocks that are often oilbearing, which are referred to as correlation layer 1 (CL1), are frequently present at the top of the Abalak formation and/or at the bottom of the Bazhenov formation. They are sporadically distributed over the profile and the area; their genesis is still not completely clear. The structural features and oil-bearing capacity of carbonate rocks have been studied, as well at the distributions of carbon and oxygen stable isotopes from bulk rocks and calcite filling fractures in the CL1 layer that was penetrated by six wells. The spherolitic microstructure of limestones together with the carbon and oxygen isotope distributions (δ13C =–14 to–26‰ VPDB; δ18O = 0 to–5‰ VPDB) indicate the precipitation of carbonate material due to microbial activity on the surface and/or in the upper part of sediments at high methane concentrations. The fractures and caverns in limestones are frequently oil-bearing; they contain coarse crystals of calcite, pyrite, quartz, and, more rarely, barite. This degree of mineralization and the isotope composition of calcite oxygen (up to–18‰ VPDB) indicate that calcite precipitates at elevated temperature (up to 120°C) from the hydrothermal fluids that could migrate from underlying strata.  相似文献   

4.
A great volume of original information on the formation of the ultrabasic rocks of the Siberian Platform has been accumulated owing to the study of melt inclusions in Cr-spinels. The inclusions show the general tendencies in the behavior of the magmatic systems during the formation of the ultrabasic massifs of the Siberian Platform, tracing the main evolution trend of decreasing Mg number with SiO2 increase in the melts with subsequent transition from picrites through picrobasalts to basalts. The compositions of the melt inclusions indicate that the crystallization conditions of the rocks of the concentrically zoned massifs (Konder, Inagli, Chad) sharply differ from those of the Guli massif. Numerical modeling using the PETROLOG and PLUTON softwares and data on the composition of inclusions in Cr-spinels yielded maximum crystallization temperatures of the olivines from the dunites of the Konder (1545–1430°C), Inagli (1530–1430°C), Chad (1460–1420°C), and Guli (1520–1420°C) massifs, and those of Cr-spinels from the Konder (1420–1380°C), Inagli (up to 1430°C), Chad (1430–1330°C), and Guli (1410–1370°C) massifs. Modeling of the Guli massif with the PLUTON software using the compositions of the melt inclusions revealed the possible formation of the alkaline rocks at the final reverse stage of the evolution of the picritic magmas (with decrease of SiO2 and alkali accumulation) after termination of olivine crystallization with temperature decrease from 1240–1230°C to 1200–1090°C. Modeling with the PLUTON software showed that the dunites of the Guli massif coexisted with Fe-rich (with moderate TiO2 contents) melts, the crystallization of which led (beginning from 1210°C) to the formation of pyroxenes between cumulate olivine. Further temperature decrease (from 1125°C) with decreasing FeO and TiO2 contents provided the formation of clinopyroxenes of pyroxenites. For the Konder massif, modeling with the PLUTON software indicates the possible formation of kosvites from picrobasaltic magmas beginning from 1350°C and the formation of clinopyroxenites and olivine–diopside rocks from olivine basaltic melts from 1250°C.  相似文献   

5.
The mineralization area (Altınpınar, Torul–Gümüşhane) is situated in the Southern Zone of the Eastern Pontides Orogenic Belt (EPOB), which is one of the important metallogenic provinces in the Alpine–Himalayan belt and is intruded by the late Carboniferous granitic rocks (Gümüşhane Granitoid), an early to middle Jurassic volcano-sedimentary unit consisting mainly of basaltic–andesitic volcanic and pyroclastic rocks (Şenköy Formation) and Eocene basaltic–andesitic volcanic rocks (Alibaba Formation). The studied Pb–Zn ± Au mineralizations are related to silica veins ranging from a few millimeters to a maximum of 40 cm in thickness and are localized within fracture zones developed along the contact between the Gümüşhane Granitoid and Şenköy Formation. Silicic, sulfidic, hematitic, argillic, intense chloritic and carbonate alteration are the most common types from the fault lines toward the outer zones. Cavity filling and banded structures are widely observed. The mineral paragenesis comprises galena, sphalerite, pyrite, chalcopyrite, tennantite and quartz. Mineral chemistry studies indicate that ion exchange occurs between Zn and Fe in sphalerites, and the Zn/Cd ratio of sphalerites varies between 50.65 and 144.64. The homogenization temperatures measured from fluid inclusions vary between 170 °C and 380 °C, especially between 250 °C and 300 °C, and the wt.% NaCl eqv. salinity of ore-forming fluids is between 2.4 and 7.3 (4.7 on average), supporting an epithermal system in their origin. The values of sulfur isotopes, which are obtained from pyrite and galena minerals, range between − 8.3‰ and − 2.3‰, indicating that sulfur, which enables mineral formation, originates from magmatic genesis. The average formation temperature of the ore is 317 °C as determined with a sulfur isotope geothermometer. The values of oxygen and hydrogen isotopes vary between 8.5‰ and 10.2‰ and − 91‰ and −73‰, respectively. With regard to the compositions of oxygen and hydrogen isotopes, fluids comprising the mineralization are formed by the mixture of magmatic water and meteoric water. This situation is supported by the fact that the increase in the homogenization temperature indicates dilution with surface water but depends on the increase in the salinity of fluid inclusions. Considering all the data, it is clear that the studied mineralization is an epithermal vein-type mineralization that is related to granitic magmas.  相似文献   

6.
A close relation of the organic carbon (Corg) content with major has been established for rocks of the Upper Jurassic–Lower Cretaceous Bazhenov Formation. Applying the method of multiple linear regression, it has been demonstrated that the Corgcontent in rocks of the Bazhenov Formation is stringently controlled by its bulk chemical composition. This inference is consistent with the existing ideas regarding a close interrelation between the following main components of rocks: organic carbon and authigenic quartz formed on remains of Radiolaria; pyrite formed in a highly reducing medium of Corg-rich sediments; and terrigenous clayey material diluting the authigenic siliceous–carbonaceous–pyritic matrix. These components chiefly determine the spectrum of major elements in the Bazhenov Formation. The establishment of the close relation between the Corgcontent and the group of major elements refutes the suggestion of some authors that siliceous material was supplied to nonlithified sediments of the Bazhenov sea by hydrothermal solutions, because this mechanism would have inevitably upset geochemical relations between elements in the studied rocks.  相似文献   

7.
The metamorphic conditions of the Upper Permian Yangjiagou Formation in eastern Changchun, China, were evaluated based on the mineral assemblage, illite crystallinity, illite polytypism,the b dimension of illite, and the chemical composition of chlorite. The pelitic rocks in the Yangjiagou Formation are characterized by illite + kaolinite + chlorite ± mixed-layer chlorite/smectite and detrital quartz + plagioclase. Illite in the formation has a crystallinity of 0.38-0.55 and comprises mixed 2 M_1 and1 M_d polytypes, indicating a metamorphic temperature of 200℃. Based on the chemical composition of chlorite and the chlorite geothermometer, we estimated diagenetic to very low-grade metamorphic conditions with temperatures of 185℃~204℃. The b dimension of illite varies from 8.992 A to 9.005 A.We used a mathematical algorithm to extend Guidotti and Sassi's(1986) diagram relating illite b dimension with temperature and pressure, and used this diagram, together with illite crystallinity and chlorite chemical composition, to semi-quantitatively estimate the formation pressure at1.2 kbar. These reveal that the Yangjiagou Formation has experienced very low-grade metamorphism.  相似文献   

8.
It was shown that the contents of Ni, Mo, and Co in the siliceous clay black shale rocks of the normal sections of the Bazhenov Formation are several times higher than the global mean contents of these elements in black shales. These rocks have the highest contents of pyrite and organic carbon and show evidence for strongly reducing formation conditions at the slowest background rate of sedimentation of their material. A transition from the siliceous clay rocks to the mudstones of normal section, which are considered as turbidites, and further to the mudstones and clayey silt rocks of the so-called anomalous sections (deposits of submarine deltas and canyons) is accompanied by sequential depletion in pyrite and organic carbon, a decrease in indicators of the reduction level of the sedimentation environment, and an increase in sedimentation rate and clay material content. Simultaneously, the contents of the elements of interest decreases in the sequence Mo > Ni > Co. In the rocks of anomalous sections, the contents of these elements decrease to the level of their mean abundances in clays.  相似文献   

9.
Phase equilibrium modelling and monazite microprobe dating were used to characterize the polymetamorphic evolution of metapelites from the northern part of the Vepor Unit, West Carpathians. Three generations of garnet and associated metamorphic assemblages found in these rocks correspond to three distinct metamorphic events related to the Variscan orogeny, a Permian phase of crustal extension and the Alpine orogeny. Variscan staurolite‐bearing and Alpine chloritoid‐bearing assemblages record medium‐temperature and medium‐pressure regional metamorphisms reaching 540–570 °C/5–7.5 kbar and 530–550 °C/5–6.5 kbar respectively. The Permian metamorphic assemblage involves garnet, andalusite, sillimanite, biotite, muscovite, plagioclase and corundum and locally forms silica‐undersaturated andalusite‐biotite‐spinel coronas around older staurolite. The transition from andalusite to sillimanite indicates a prograde low‐pressure and medium‐temperature metamorphism characterized by temperature increase from 500 to 650 °C at ~3 kbar. As accessory monazite is abundant in the rocks, an attempt was made to derive its age of formation by means of electron microprobe‐based Th‐U‐Pb chemical dating. Despite the polymetamorphic nature of the metapelites, the monazite yielded uniform Permian ages. Microstructures confirm that monazite was formed in relation to the low‐pressure and medium‐temperature paragenesis, and the weighted average ages obtained for two different samples are 278 ± 5 and 275 ± 12 Ma respectively. The virtual lack of Variscan and Alpine monazite populations points to interesting aspects concerning the growth systematics of monazite in metamorphic rocks.  相似文献   

10.
The gneisses of the Makuti Group in north-west Zimbabwe are characterized by complex geometries that resulted from intense non-coaxial deformation in a crustal scale high-strain zone that accommodated extensional deformation along the axis of the Zambezi Belt at c. 800 Ma. Within low-strain domains in the Makuti gneisses, undeformed metagabbroic lenses preserve eclogite and granulite facies assemblages, which record a part of the metamorphic history that predates Pan-African events. Eclogitic rocks can be subdivided into: (1) corona-textured metagabbros that preserve igneous textures, and (2) garnet–omphacite rocks in which primary textures are destroyed. The lenses of eclogitic rocks are enveloped in a mantle of garnet–clinopyroxene–hornblende gneiss, which is a common rock type in the Makuti gneisses. The eclogites preserve multi-staged, domainal, symplectic reaction textures that developed progressively as the rocks experienced loading followed by decompression–heating. In the metagabbros, the original clinopyroxene, plagioclase and olivine domains acted separately during the peak of metamorphism, with plagioclase being replaced by garnet and kyanite, and olivine being replaced by orthopyroxene and possibly omphacite. The peak assemblage was overprinted by: (1) the multi-mineralic corona assemblage pargasite–orthopyroxene–spinel–plagioclase replacing garnet–kyanite–clinopyroxene (possibly at c. 19 kbar, 760±25 °C); (2) orthopyroxene–pargasite–plagioclase–scapolite coronas replacing orthopyroxene (15±1.5 kbar, 750±50 °C); and (3) moats of orthopyroxene–plagioclase replacing garnet (10±1 kbar, 760±50 °C). The garnet–omphacite rocks record similar peak conditions (15±1.1 kbar, 760±60 °C). Garnet–clinopyroxene–hornblende–plagioclase gneisses envelop the eclogites and record matrix conditions of 11±1.5 kbar at 730±50 °C using assemblages that are oriented in the regional fabric. These rocks are characterized by decompression-heating textures, reflecting temperature increases during exhumation of the Makuti gneisses. The eclogite facies rocks formed during a collisional event prior to 850 Ma. Their formation could be related to a suture zone that developed along the axis of the Zambezi Belt during the formation of Rodinia (between 1400 and 850 Ma). The main deformation-metamorphism in the Makuti gneisses occurred around 800 Ma and involved extension and exhumation of the high-P rocks (break-up of Rodinia), which experienced a high-T metamorphic overprint. Around 550–500 Ma, a collisional event associated with the formation of Gondwana resulted in renewed burial and metamorphic recrystallization of the Makuti gneisses.  相似文献   

11.
ABSTRACT The northern Dabie terrane consists of a variety of metamorphic rocks with minor mafic-ultramafic blocks, and abundant Jurassic-Cretaceous granitic plutons. The metamorphic rocks include orthogneisses, amphibolite, migmatitic gneiss with minor granulite and metasediments; no eclogite or other high-pressure metamorphic rocks have been found. Granulites of various compositions occur either as lenses, blocks or layers within clinopyroxene-bearing amphibolite or gneiss. The palaeosomes of most migmatitic gneisses contain clinopyroxene; melanosomes and leucosomes are intimately intermingled, tightly folded and may have formed in situ. The granulites formed at about 800–830 °C and 10–14 kbar and display near-isothermal decompression P–T paths that may have resulted from crust thickened by collision. Plagioclase-amphibole coronae around garnets and matrix PI + Hbl assemblages from mafic and ultramafic granulites formed at about 750–800 °C. Partial replacement of clinopyroxene by amphibole in gneiss marks amphibolite facies retrograde metamorphism. Amphibolite facies orthogneisses and interlayered amphibolites formed at 680–750 °C and c. 6 kbar. Formation of oligoclase + orthoclase antiperthite after plagioclase took place in migmatitic gneisses at T ≤ 490°C in response to a final stage of retrograde recrystallization. These P–T estimates indicate that the northern Dabie metamorphic granulite-amphibolite facies terrane formed in a metamorphic field gradient of 20–35 °C km-1 at intermediate to low pressures, and may represent the Sino-Korean hangingwall during Triassic subduction for formation of the ultrahigh- and high-P units to the south. Post-collisional intrusion of a mafic-ultramafic cumulate complex occurred due to breakoff of the subducting slab.  相似文献   

12.
13.
We compare frictional strengths in the temperature range 25–250 °C of fault gouge from SAFOD (CDZ and SDZ) with quartzofeldspathic wall rocks typical of the central creeping section of the San Andreas Fault (Great Valley sequence and Franciscan Complex). The Great Valley and Franciscan samples have coefficients of friction, μ > 0.35 at all experimental conditions. Strength is unchanged between 25° and 150 °C, but μ increases at higher temperatures, exceeding 0.50 at 250 °C. Both samples are velocity strengthening at room temperature but show velocity-weakening behavior beginning at 150 °C and stick-slip motion at 250 °C. These rocks, therefore, have the potential for unstable seismic slip at depth. The CDZ gouge, with a high saponite content, is weak (μ = 0.09–0.17) and velocity strengthening in all experiments, and μ decreases at temperatures above 150 °C. Behavior of the SDZ is intermediate between the CDZ and wall rocks: μ < 0.2 and does not vary with temperature. Although saponite is probably not stable at depths greater than ∼3 km, substitution of the frictionally similar minerals talc and Mg-rich chlorite for saponite at higher temperatures could potentially extend the range of low strength and stable slip down to the base of the seismogenic zone.  相似文献   

14.
Rare-earth elements abundance in black shales of the Upper Jurassic (Tithonian Stage)–Lower Cretaceous (Berriassian Stage) Bazhenov Formation is discussed. This formation is the principal oil source rocks of West Siberia. The deposits within the formation can be subdivided into two main marine groups: (a) moderately hemipelagic deposits (clayey-siliceous, including phosphatic and carbonate rocks) and low-density distal clayey turbidites (argillites), both are considered as normal and (b) silty argillites and clayey-silt rocks, which are channel deposits and considered as anomalous. The hemipelagic rocks of normal sections, which are enriched in the rare-earth elements (REE), accumulated under both slow rates of sedimentation (clayey-siliceous rocks) and faster rates of sedimentation (argillites). The channel deposits of anomalous sections, which are impoverished in the REE, accumulated exclusively under fast rates of sedimentation.Within the hemipelagic group the rate of sedimentation of the argillites was faster than of the clayey-siliceous rocks, but the REE concentration in the former rocks (140.4 ppm) is higher than in the latter group (97.4 ppm). The argillites are more than twice enriched in clayey material than clayey-siliceous rocks. It is likely that the clay fraction was the main carrier of REE in these rocks. In the channel group of rocks, the REE abundance in clayey-silt rocks (21.2 ppm) is lower than in the silty argillite (84.6 ppm), in which the clay content is elevated.With respect to redox potential the Bazhenov Formation rocks can be subdivided further into three groups, based on the degree of pyritization index (DOP): (1) the highly reducing clayey-siliceous rocks of normal sections, with high DOP; (2) the substantially reducing argillites and carbonate rocks of normal sections, with intermediate DOP; (3) the moderately reducing rocks of anomalous sections with low DOP. The rocks with the high DOP (group 1) are characterized by ΣLREE/Σ(M+H)REE ratios between 7.37 and 7.5, whereas the rocks with the lower DOP (group 2 and 3) are characterized by ΣLREE/Σ(M+H)REE ratios between 12.8 and 13.5. Negative Ce anomalies are either small or absent in all deposits, which is typical for reducing conditions.Thus, the Bazhenov Formation exemplifies the complex depositional conditions that influence the REE concentration in black shale. However, it is this very complexity that has contributed to the development of six separate depositional models (REE contents in ppm are given in brackets). (1) Phosphatic clayey-siliceous rocks of normal sections (367.95); (2) argillites of normal sections (130.73); (3) clayey-siliceous rocks of normal sections (85.97); (4) carbonate rocks, largely dolomites of normal sections (23.23); (5) silty argillites of anomalous sections (78.7) and (6) clayey-silt rocks of anomalous sections (19.66).  相似文献   

15.
This diagenetic study (including fieldwork, petrographic, fluid inclusion, and stable isotope investigations) deals with the outcrop of Upper Permian–Lower Triassic carbonate rocks, which are equivalent to the Khuff Formation. The studied succession, which outcrops in the Ras Al Khaimah region, northern United Arab Emirates, comprises three formations, including the Bih, the Hagil, and the Ghail formations. The study focuses on unraveling the conditions and fluid compositions encountered during diagenesis of the succession. Emphasize is also made on linking diagenesis to major stratigraphic surfaces and to highlight reservoir property evolution and heterogeneity of the studied rocks. The evolution of fluids and related diagenetic products can be summarized as follows: (1) formation of near-surface to shallow burial, fine-crystalline dolomite (dolomite matrix) through pervasive dolomitization of carbonate sediments by modified marine pore waters; (2) formation of coarse-crystalline dolomite cement by highly evolved marine pore waters (13–23 wt.% NaCl eq.) at elevated temperatures (120–208°C), and (3) calcite cementation by highly saline fluid (20–23 wt.% NaCl eq.) at high temperature (170–212°C). A final calcite cement generation has been formed by the percolation of meteoric fluids during uplift. Fracture- and vug-filling diagenetic minerals are mainly restricted to the mid-Bih breccia marker level, suggesting preferential focused fluid flow through specific stratigraphic surfaces as well as along tectonic-related structures. Reservoir properties have been evolved as result of the interplay of the original sedimentary texture and the diagenetic evolution. Porosity is higher in the Bih Formation, which is dominated by dolomitized packstones and grainstones, than in the Hagil and Ghail formations, consisting mainly of dolomitized mudstones and wackestones. Image analyses were used to quantify the visual porosity in thin sections. The highest porosity values were measured in the Bih Formation, which is characterized by significant amounts of vug- and fracture-filling cements. This feature is attributed to the increase of porosity owing to substantial dissolution of abundant intergranular and vug-filling cements. In contrast, the Hagil and Ghail formations, which consist of finer-grained rock than the Bih Formation, were less cemented, and thus, the porosity enhancement by cement dissolution was insignificant.  相似文献   

16.
The Sabzevar ophiolites mark the Neotethys suture in east-north-central Iran. The Sabzevar metamorphic rocks, as part of the Cretaceous Sabzevar ophiolitic complex, consist of blueschist, amphibolite and greenschist. The Sabzevar blueschists contain sodic amphibole, epidote, phengite, calcite ± omphacite ± quartz. The epidote amphibolite is composed of sodic-calcic amphibole, epidote, albite, phengite, quartz ± omphacite, ilmenite and titanite. The greenschist contains chlorite, plagioclase and pyrite, as main minerals. Thermobarometry of a blueschist yields a pressure of 13–15.5 kbar at temperatures of 420–500 °C. Peak metamorphic temperature/depth ratios were low (~12 °C/km), consistent with metamorphism in a subduction zone. The presence of epidote in the blueschist shows that the rocks were metamorphosed entirely within the epidote stability field. Amphibole schist samples experienced pressures of 5–7 kbar and temperatures between 450 and 550 °C. The presence of chlorite, actinolite, biotite and titanite indicate greenschist facies metamorphism. Chlorite, albite and biotite replacing garnet or glaucophane suggests temperatures of >300 °C for greenschist facies. The formation of high-pressure metamorphic rocks is related to north-east-dipping subduction of the Neotethys oceanic crust and subsequent closure during lower Eocene between the Central Iranian Micro-continent and Eurasia (North Iran).  相似文献   

17.
In the Western Alps, the Piemont-Ligurian oceanic domain records blueschist to eclogite metamorphic conditions during the Alpine orogeny. This domain is classically divided into two “zones” (Combin and Zermatt-Saas), with contrasting metamorphic evolution, and separated tectonically by the Combin fault. This study presents new metamorphic and temperature (RSCM thermometry) data obtained in Piemont-Ligurian metasediments and proposes a reevaluation of the P–T evolution of this domain. In the upper unit (or “Combin zone”) temperatures are in the range of 420–530 °C, with an increase of temperature from upper to lower structural levels. Petrological evidences show that these temperatures are related to the retrograde path and to deformation at greenschist metamorphic conditions. This highlights heating during exhumation of HP metamorphic rocks. In the lower unit (or “Zermatt-Saas zone”), temperatures are very homogeneous in the range of 500–540 °C. This shows almost continuous downward temperature increase in the Piemont-Ligurian domain. The observed thermal structure is interpreted as the result of the upper and lower unit juxtaposition along shear zones at a temperature of ~500 °C during the Middle Eocene. This juxtaposition probably occurred at shallow crustal levels (~15–20 km) within a subduction channel. We finally propose that the Piemont-Ligurian Domain should not be viewed as two distinct “zones”, but rather as a stack of several tectonic slices.  相似文献   

18.
The metamorphic history of the Southern Marginal Zone (SMZ) of the Limpopo Belt, South Africa, possibly provides insight into one of the oldest preserved continental collision zones. The SMZ consists of granitoid gneisses (the Baviaanskloof Gneiss) and subordinate, infolded metasedimentary, metamafic and meta‐ultramafic lithologies (the Bandelierkop Formation) and is regarded as the c. 2700 Ma granulite facies reworked equivalent of the Kaapvaal craton basement. The granulite facies metamorphism is proposed to have occurred in response to collision between the Kaapvaal and Zimbabwe cratons. Previous studies have proposed a wide variety of P–T loops for the granulites, with considerable discrepancy in both the shapes of the retrograde paths and the magnitude of the peak P–T conditions. To date, the form of the prograde path and the timing of the onset of metamorphism remain unknown. This study has used a range of different metasedimentary rocks from a large migmatitic quarry outcrop to better constrain the metamorphic history and the timing of metamorphism in the SMZ. Detrital zircon ages reveal that the protoliths to the metasedimentary rocks were deposited subsequent to 2733 ± 13 Ma. Peak metamorphic conditions of 852.5 ± 7.5 °C and 11.1 ± 1.3 kbar were attained at 2713 ± 8 Ma. The clockwise P–T path is characterized by heating in the sillimanite field along a P–T trajectory which approximately parallels the kyanite to sillimanite transition, followed by near‐isothermal decompression at peak temperature and near‐isobaric cooling at ~6.0 kbar. These results support several important conclusions. First, the sedimentary rocks from the Bandelierkop Formation are not the equivalent of any of the greenstone belt sedimentary successions on the Kaapvaal craton, as has been previously proposed. Rather, they post‐date the formation of the Dominion and Witwatersrand successions on the Kaapvaal craton. From the age distribution of detrital zircon, they appear to have received significant input from various origins. Consequently, at c. 2730 Ma, the Baviaanskloof Gneiss most likely acted as basement onto which the sedimentary succession represented by the Bandelierkop Formation metapelites was deposited. Second, the rocks of the SMZ underwent rapid evolution from sediment to granulite facies anatexis, with a burial rate of ~0.17 cm yr?1. Peak metamorphism was followed by an isothermal decompression to 787.5 ± 32.5 °C and 6.7 ± 0.5 kbar and isobaric cooling to amphibolite facies conditions, below 640 °C prior to 2680 ± 6 Ma. This age for the end of the high‐grade metamorphic event is marked by the intrusion of crosscutting, undeformed pegmatites that are within error the same age as the crosscutting Matok intrusion (2686 ± 7 Ma). Collectively, the burial rate of the sedimentary rocks, the shape of the P–T path, the burial of the rocks to in excess of 30 km depth and the post‐peak metamorphic rapid decompression argue strongly that the SMZ contains sediments deposited along an active margin during lateral convergence, and that the SMZ was metamorphosed as a consequence of continental collision along the northern margin of the Kaapvaal craton at c. 2700 Ma.  相似文献   

19.
Lithology and Mineral Resources - A complex of lithological-geochemical studies was carried out in rocks of the Upper Jurassic–Lower Cretaceous Bazhenov Formation and their transition zones...  相似文献   

20.
Based on comprehensive studies of fluid inclusions in quartz formed at different stages of hydrothermal process, we consider the physicochemical conditions of formation of epithermal ores (K1) in the Balei ore field. The limiting parameters of hydrothermal process have been established: 353–131 °C, 150–30 bars, and salt concentrations of 7.6–0.5 wt.%-NaCl equiv. A specific feature of the ore-forming process at the Balei deposits is a rapid drop in temperature and pressure, which is typical of open hydrothermal systems. The temperature increase at the beginning of each stage evidences pulse-like ore formation. The productive stage coincides with the initiation of a drastic decrease in temperature (<225 °C) and salt concentration in the solution. The deposits resulted from the functioning of the common Balei ore-magmatic system at shallow depths with a high permeability of the host rocks. High-K calc-alkalic magmas might have been sources of gold mineralization. The ore formation zone is localized above intrusive bodies near their roof. It is not ruled out that the Balei gold was partly borrowed from the products of the early cycles (J2-3) of gold mineralization and from the host rocks.  相似文献   

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