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1.
The thermochemistry of several hundred compounds of twelve selected trace elements (Ge, Se, Ga, As, Te, Pb, Sn, Cd, Sb, Tl, In, and Bi) has been investigated for solar composition material along a Jupiter adiabat. The results indicate that AsF3, InBr, TlI, and SbS, in addition to CO, PH3, GeH4, AsH3, H2Se, HCl, HF, and H3BO3 proposed by Barshay and Lewis (1978), may be potential chemical tracers of atmospheric dynamics. The reported observations of GeH4 is interpreted on the basis of new calculations as implying rapid vertical transport from levels where T ? 800°K. Upper limits are also set on the abundances of many gaseous compounds of the elements investigated. 相似文献
2.
T. Encrenaz 《Earth, Moon, and Planets》1994,67(1-3):77-87
For a long time it was believed that the atmospheres of the giant planets, dominated by molecular hydrogen and helium, were similar in composition to the primordial nebula from which they formed. However, this image has strongly evolved over the past twenty years, due to new developments of ground-based infrared spectroscopy, coupled with the success of the Voyager space mission.Significant differences were measured in the abundances of helium, deuterium and carbon of the four giant planets. The variations in the C/H and D/H ratios have given support to the "nucleation" formation scenario, in which the four giant planets first accreted a nucleus of about ten terrestrial masses, big enough to bind gravitationally the surrounding gaseous nebula; the helium depletion in Saturn has been interpreted as a differentiation effect in Saturn's interior; the apparent helium excess in Neptune, coupled with the recent unexpected detection of CO and HCN in this planet, might imply the presence of molecular nitrogen. In the case of Jupiter and Saturn, disequilibrium species have been detected (CO, PH3, GeH4, AsH3), which are tracers of vertical dynamical motions.In the future, significant progress in our knowledge of the Jovian composition, including the noble gases, should be obtained with the mass spectrometer of the Galileo probe. The ISO mission is expected to provide new far-infrared spectroscopic data which should lead to the detection of new minor species and a better determination of the D/H ratio. 相似文献
3.
Spectra of Jupiter recorded in the 1900- to 2300-cm?1 range at the IRTF in Hawaii, July 1982, provide tentative evidence for variability of the Jovian atmosphere between zones and belts. It is concluded from analysis of the ν1and ν3 bands of PH3 that there is a possible enhancement of the PH3/H2 ratio in the belts when compared to the zones. There is an apparent reduction of the PH3 abundance between the IRIS Voyager 1 determinations and these spectra, implying temporal or spatial variability of PH3 on Jupiter. Interpretation of this variability in the troposphere could involve both dynamical and thermochemical processes. 相似文献
4.
The global distribution of phosphine (PH3) on Jupiter and Saturn is derived using 2.5 cm−1 spectral resolution Cassini/CIRS observations. We extend the preliminary PH3 analyses on the gas giants [Irwin, P.G.J., and 6 colleagues, 2004. Icarus 172, 37-49; Fletcher, L.N., and 9 colleagues, 2007a. Icarus 188, 72-88] by (a) incorporating a wider range of Cassini/CIRS datasets and by considering a broader spectral range; (b) direct incorporation of thermal infrared opacities due to tropospheric aerosols and (c) using a common retrieval algorithm and spectroscopic line database to allow direct comparison between these two gas giants.The results suggest striking similarities between the tropospheric dynamics in the 100-1000 mbar regions of the giant planets: both demonstrate enhanced PH3 at the equator, depletion over neighbouring equatorial belts and mid-latitude belt/zone structures. Saturn's polar PH3 shows depletion within the hot cyclonic polar vortices. Jovian aerosol distributions are consistent with previous independent studies, and on Saturn we demonstrate that CIRS spectra are most consistent with a haze in the 100-400 mbar range with a mean optical depth of 0.1 at 10 μm. Unlike Jupiter, Saturn's tropospheric haze shows a hemispherical asymmetry, being more opaque in the southern summer hemisphere than in the north. Thermal-IR haze opacity is not enhanced at Saturn's equator as it is on Jupiter.Small-scale perturbations to the mean PH3 abundance are discussed both in terms of a model of meridional overturning and parameterisation as eddy mixing. The large-scale structure of the PH3 distributions is likely to be related to changes in the photochemical lifetimes and the shielding due to aerosol opacities. On Saturn, the enhanced summer opacity results in shielding and extended photochemical lifetimes for PH3, permitting elevated PH3 levels over Saturn's summer hemisphere. 相似文献
5.
The reaction of elemental phosphorus and H atoms to form PH3 was observed and should be a major factor in the recycling of PH3 in the stratosphere of Jupiter. The formation of PH3 in this manner should predominate at high altitudes where, due to the very low temperatures, reactions that require higher activation energies than these atom reactions cannot occur. At lower altitudes, in the troposphere, the rapid formation of H atoms from the strong absorption of light by NH3 will contribute to phosphine production also in this same manner. Recent experiments have also shown that elemental phosphorus reacts readily with aqueous ammonia to form PH3. This reaction may also be important in the recycling of PH3 in the upper troposphere of Jupiter if water-ammonia clouds, as had been previously thought, exist. Considerations of the coloration of the Great Red Spot have been made based upon the nature of the phosphorus obtained by decomposition of phosphine. 相似文献
6.
Photolysis of NH3PH3 mixtures (11 Torr) at 175°K resulted in the same initial rate of P2H4 formation as when the 11 Torr of pure PH3 was photolyzed. A higher yield of P2H4 is obtained at 175°K than at 298°K because some of the P2H4 condenses on the cell wall at 175°K and is not subject to further reaction. Some reaction of P2H4 is taking place as observed by the decrease in its yield and on the formation of red phosphorus on extended photolysis of PH3 at 175°K. No NH2PH2 or (PN)x were detected as photoproducts as indicated by the absence of change in the UV spectral properties of the P2H4 and red phosphorus fraction, respectively, when NH3 is present. Although the pathway for PH3 decomposition is changed, the outcome of the photochemical process is essentially the same in the absence or presence of NH3. The formation of P2H4 and red phosphorus was not inhibited by small amounts of C2H4 and C2H2, so the low levels of hydrocarbons on Jupiter and Saturn will not have a significant effect on the course of PH3 photolysis. The ratio of products of PH3 photolysis are only slightly affected by the wavelength of light used. Use of xenon lamp, with a continuous emission in the ultraviolet where P2H4 absorbs, results in only a modest decrease in the yield of P2H4 and a modest increase in the rate of formation of red phosphorus as compared to the rates observed with a 206.2-nm light source. The quantum yield for P2H4 formation is pressure independent in the 0.5–11 Torr range. This quantum yield is not affected by lowering the temperature to 157°K or by the addition of 100 Torr of H2. It is concluded that photolysis of PH3 to P2H4 and the subsequent conversion of P2H4 to red phosphorus are likely procses on Jupiter and Saturn and that particles of P2H4 condense in the atmospheres of these planets. The conversion of some of the P2H4 to red phosphorus may take place on Jupiter. 相似文献
7.
The abundances of PH3, CH3D, and GeH4 are derived from the 2100- to 2250-cm?1 region of the Voyager 1 IRIS spectra. No evidence is seen for large-scale variations of the phosphine abundance over Jovian latitudes between ?30 and +30°. In the atmospheric regions corresponding to 170–200°K, the derived PH3/H2 value is (4.5 ± 1.5) × 10?7 or 0.75 ± 0.25 times the solar value. This result, compared with other PH3 determinations at 10 μm, suggests than the PH3/H2 ratio on Jupiter decreases with atmospheric pressure. In the 200–250°K region, we derive, within a factor of 2, CH3D/H2 and GeH4/H2 ratios of 2.0 × 10?7 and 1.0 × 10?9, respectively. Assuming a C/H value of 1.0 × 10?3, as derived from Voyager, our CH3D/H2 ratio implies a D/H ratio of 1.8 × 10?5, in reasonable agreement with the interstellar medium value. 相似文献
8.
Since the original suggestion by Gillett et al. (1969) it has generally been assumed that the region of partial transparency near 5 μm in Jupiter's atmosphere (the 5-μm window) is bounded by the v4 NH3 at 6.1 μm and the v3 CH4 band at 3.3 μm. New measurements of Jupiter and of laboratory phosphine (PH3) samples show that PH3 is a significant contributor to the continuum opacity in the window and in fact defines its short-wavelength limit. This has important implications for the use of 5-mu;m observations as a means to probe the deep atmospheric structure of Jupiter. The abundance of PH3 which results from a comparison of Jovian and laboratory spectra is about 3 to 5 cm-am. This is five to eight times less than that found by Larson et al. [Astrophys. J. (1977) 211, 972–979] in the same spectral region, but is in good agreement with the result of Tokunaga et al. [Astrophys. J. (1979) 232, 603–615] from 10-μm observations. 相似文献
9.
Observations of the water inventory as well as other chemically important species on Jupiter will be performed in the frame of the guaranteed time key project of the Herschel Space Observatory entitled “Water and related chemistry in the Solar system”. Among other onboard instruments, PACS (Photodetector Array Camera and Spectrometer) will provide new data of the spectral atlas in a wide region covering the far-infrared and submillimetre domains, with an improved spectral resolution and a higher sensitivity compared to previous observations carried out by Cassini/CIRS (Composite InfraRed Spectrometer) and by ISO (Infrared Space Observatory).In order to optimise the observational plan and to prepare for the data analysis, we have simulated the expected spectra of PACS Jupiter observations. Our simulation shows that PACS will promisingly detect several H2O emission lines. As PACS is capable of spatially resolving the Jovian disk, we will be able to discern the external oxygen sources in the giant planets by exploring the horizontal distribution of water. In addition to H2O lines, some absorption lines due to tropospheric CH4, HD, PH3 and NH3 lines will be observed with PACS. Furthermore, owing to the high sensitivity of the instrument, the current upper limit on the abundance of hydrogen halides such as HCl will be also improved. 相似文献
10.
The orbits of fictitious bodies around Jupiter’s stable equilibrium points L 4 and L 5 were integrated for a fine grid of initial conditions up to 100 million years. We checked the validity of three different dynamical models, namely the spatial, restricted three body problem, a model with Sun, Jupiter and Saturn and also the dynamical model with the Outer Solar System (Jupiter to Neptune). We determined the chaoticity of an orbit with the aid of the Lyapunov Characteristic Exponents (=LCE) and used also a method where the maximum eccentricity of an orbit achieved during the dynamical evolution was examined. The goal of this investigation was to determine the size of the regions of motion around the equilibrium points of Jupiter and to find out the dependance on the inclination of the Trojan’s orbit. Whereas for small inclinations (up to i=20°) the stable regions are almost equally large, for moderate inclinations the size shrinks quite rapidly and disappears completely for i>60°. Additionally, we found a difference in the dynamics of orbits around L 4 which – according to the LCE – seem to be more stable than the ones around L 5. 相似文献
11.
Guido Visconti 《Icarus》1981,45(3):638-652
We present computations of the photodissociation coefficients for NH3, N2H4, PH3, and H2S in the Jupiter atmosphere. The calculations take into account multiple scattering and absorption using the radiative-transfer method known as δ-Eddington approximation. The atmospheric models include two cloud layers of variable thickness and haze layers above the upper cloud and between the clouds. One of the results of the radiative computations deal with the reflectivity of the Jovian atmosphere as a function of wavelength. A comparison with available data on the albedo of the planet gives some important indications about mixing ratios and distributions of gases and aerosols. The results for the photolysis rates are compared with similar rates obtained by considering either the direct flux or the flux determined by the molecular gas absorption alone. The latter is usually the approximation used in aeronomic models. The results of this comparison show that a considerable difference exists with direct flux photodissociation but significant differences with molecular absorption flux exist only in atmospheric regions where photodissociation is relatively small. 相似文献
12.
The visible (0.3 to 1.03 μm) spectral reflectances of H2O, NH3, H2S, and NH4HS frosts and mixtures of these frosts and their uv irradiated products have been measured. These spectra are compared with the spectra of the Galilean satellites of Jupiter, Saturn's rings and Saturn's satellites to place limits on their surface composition. 相似文献
13.
W. S. Koon M. W. Lo J. E. Marsden S. D. Ross 《Celestial Mechanics and Dynamical Astronomy》2001,81(1-2):27-38
A number of Jupiter family comets such as Otermaand Gehrels 3make a rapid transition from heliocentric orbits outside the orbit of Jupiter to heliocentric orbits inside the orbit of Jupiter and vice versa. During this transition, the comet can be captured temporarily by Jupiter for one to several orbits around Jupiter. The interior heliocentric orbit is typically close to the 3:2 resonance while the exterior heliocentric orbit is near the 2:3 resonance. An important feature of the dynamics of these comets is that during the transition, the orbit passes close to the libration points L
1and L
2, two of the equilibrium points for the restricted three-body problem for the Sun-Jupiter system. Studying the libration point invariant manifold structures for L
1and L
2is a starting point for understanding the capture and resonance transition of these comets. For example, the recently discovered heteroclinic connection between pairs of unstable periodic orbits (one around the L
1and the other around L
2) implies a complicated dynamics for comets in a certain energy range. Furthermore, the stable and unstable invariant manifold tubes associated to libration point periodic orbits, of which the heteroclinic connections are a part, are phase space conduits transporting material to and from Jupiter and between the interior and exterior of Jupiter's orbit. 相似文献
14.
Spectra from the Voyager 1 IRIS experiment confirm the existence of enhanced infrared emission near Jupiter's north magnetic pole in March 1979. The spectral characteristics of the enhanced emission are consistent with a Planck source function. A temperature-pressure profile is derived for the region near the north magnetic pole, from which quantitative abundance estimates of minor species are made. Some species previously detected on Jupiter, including CH3D, C2H2 and C2H6, have been observed again near the pole. Newly discovered species, not previously observed on Jupiter, include C2H4, C3H4, and C6H6. All of these species except CH3D appear to have enhanced abundances at the north polar region with respect to midlatitudes. Upper limits are determined for C4H2 and C3H8. The quantitative results are compared with model calculations based on ultraviolet results from the IUE satellite. The plausibility of the C6H6 identification in discussed in terms of the literature on C2H2 polymerization. The relation of C6H6 to cuprene is also discussed. 相似文献
15.
Spectral observations of Saturn from the far infrared spectrometer aboard the Cassini spacecraft [Flasar, F.M., et al., 2005. Temperatures, winds, and composition in the Saturnian system. Science 307, 1247-1251] have revealed that the C/H ratio in the planet is in fact about twice higher than previously derived from ground based observations and in agreement with the C/H value derived from Voyager IRIS by Courtin et al. [1984. The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH3, PH3, C2H2, C2H6, CH3D, CH4, and the Saturnian D/H isotopic ratio. Astrophys. J. 287, 899-916]. The implications of this measurement are reanalyzed in the present report on the basis that volatiles observed in cometary atmospheres, namely CO2, CH4, NH3 and H2S may have been trapped as solids in the feeding zone of the planet. CH4 and H2S may have been in the form of clathrate hydrates while CO2 presumably condensed in the cooling solar nebula. Carbon may also have been incorporated in organics. Conditions of temperature and pressure ease the hydratation of NH3. Such icy grains were included in planetesimals which subsequently collapsed into the hydrogen envelope of the planet, then resulting in C, N and S enrichments with respect to the solar abundance. Our calculations are consistent, within error bars, with observed elemental abundances on Saturn provided that the carbon trapped in planetesimals was mainly in the form of CH4 clathrate and CO2 ice (and maybe as organics) while nitrogen was in the form of NH3 hydrate. Our approach has implications on the possible pattern of noble gases in Saturn, since we predict that contrary to what is observed in Jupiter, Ar and Kr should be in solar abundance while Xe might be strongly oversolar. The only way to verify this scenario is to send a probe making in situ mass spectrometer measurements. Our scenario also predicts that the 14N/15N ratio should be somewhat smaller in Saturn than measured in Jupiter by Galileo. 相似文献
16.
A model is presented for the photochemistry of PH3 in the upper troposphere and lower stratosphere of Saturn that includes the effects of coupling with NH3 and hydrocarbon photochemistry, specifically the C2H2 catalyzed photodissociation of CH4. PH3 is rapidly depleted with altitude (scale height ～35 km) in the upper troposphere when K～104cm2sec?1; an upper limit for K at the tropopause is estimated at ～105cm2sec?1. If there is no gas phase P2H4 because of sublimation, P2 and P4 formation is unlikely unless the rate of the spin-forbidden recombination reaction PH + H2 + M → PH3 + M is exceedingly slow. An upper limit P4 column density of ～2×1015cm?2 is estimated in the limit of no recombination. If sublimation does not remove all gas phase P2H4, P2 and P4 may be produced in potentially larger quantities, although they would be restricted almost entirely to the lowest levels of our model, where T?100°K. Potentially observable amounts of the organophosphorus compounds CH3P2H2 and HCP are predicted, with column densities of >1017 cm?2 and production rates of ～2×108cm?2sec?1. The possible importance of electronically excited states of PHx and additional PH3/hydrocarbon photochemical coupling paths are also considered. 相似文献
17.
We report measurements of the Jupiter brightness spectrum in the 850-μm and 1100-μm atmospheric windows with a spectral resolution of 125 MHz, obtained with a Fourier transform spectrometer on the James Clerk Maxwell Telescope. Three results were obtained. First, the predicted absorption features due to the rotational lines of HCN at 266 and 354 GHz were not detected within our error limits of less than 1%. We establish new upper limits for the HCN abundance in the jovian troposphere for five assumed abundance distributions and for two assumed NH3abundances. The upper limits are 1.7 to 13 times smaller than the abundance value obtained in the only reported detection of HCN in Jupiter prior to the impact of Shoemaker–Levy 9. Second, the continuum brightness temperature spectrum at 850 μm was determined and is in agreement with previous measurements, but has large error bars due to uncertainties in the photometric calibration. We estimate the ammonia abundance in the 1–2 bar region to be 1.7 times solar, but this result is tentative since scattering by NH3cloud particles and absorption by gaseous H2S were neglected in our atmospheric model. Finally, the first rotational line of PH3at 267 GHz was not detected, a result which we demonstrate is consistent with the statistical noise level in these measurements, with current values of the spectroscopic parameters, and with phosphine measurements at other wavelengths. 相似文献
18.
We propose an interpretation of the enrichments in volatiles observed in the four giant planets with respect to the solar abundance. It is based on the assumption that volatiles were trapped in the form of solid clathrate hydrates and incorporated in planetesimals embedded in the feeding zones of each of the four giant planets. The mass of trapped volatiles is then held constant with time. The mass of hydrogen and of not trapped gaseous species continuously decreased with time until the formation of the planet was completed, resulting in an increase in the ratio of the mass of trapped volatiles to the mass of hydrogen (Gautier et al., Astrophys. J. 550 (2001) L227). The efficiency of the clathration depends upon the amount of ice available in the early feeding zone. The quasi-uniform enrichment in Ar, Kr, Xe, C, N, and S observed in Jupiter is reproduced because all volatiles were trapped. The non-uniform enrichment observed in C, N and S in Saturn is due to the fact that CH4, NH3, and H2S were trapped but not CO and N2. The non-uniform enrichment in C, N and S in Uranus and Neptune results from the trapping of CH4, CO, NH3 and H2S, while N2 was not trapped. Our scenario permits us to interpret the strongly oversolar sulfur abundance inferred by various modelers to be present in Saturn, Uranus and Neptune for reproducing the microwave spectra of the three planets. Abundances of Ar, Kr and Xe in these three are also predicted. Only Xe is expected to be substantially oversolar. The large enrichment in oxygen in Neptune with respect to the solar abundance, calculated by Lodders and Fegley (Icarus 112 (1994) 368) from the detection of CO in the upper troposphere of the planet, is consistent with the trapping of volatiles by clathration. The upper limit of CO in Uranus does not exclude that this process also occurred in Uranus. 相似文献
19.
《Planetary and Space Science》1999,47(10-11):1201-1210
New models of Jupiter are based on observational data provided by the Galileo spaceprobe, which considerably improved previously existing estimates of the helium abundance in the atmosphere of Jupiter. These data yield for Jupiter’s atmosphere 20% of the solar oxygen abundance and do not agree with the results of the analysis of the collision of comet Shoemaker-Levy 9 with Jupiter (10 times the solar value). Therefore, both the models of Jupiter with water-depleted and water-enriched atmosphere are considered. By analogy with Jupiter, trial models of Saturn with a water-depleted external envelope are also developed. The molecular-metallic phase transition pressure of hydrogen Pm was taken to be 1.5, 2 and 3 Mbar. Since Saturn’s internal molecular envelope is noticeably enriched in the IR-component (its weight concentration, 0.25–0.30, being by a factor of 3–4 higher than in Jupiter), the phase transition pressure in Saturn can be lower than in Jupiter. In the constructed models, the IR-core masses are 3–3.5 M⊕ for Jupiter and 3–5.5 M⊕ for Saturn. Jupiter’s and Saturn’s IR-cores can be considered embryos onto which the accretion of the gas occurred during the formation of the planets. The mass of the hydrogen–helium component dispersed in the zone of planetary formation constitutes ≈2–5 planetary masses for Jupiter and ≈11–14 planetary masses for Saturn. 相似文献
20.
Spectroscopic remote sensing in the infrared and (sub)millimeter range is a powerful technique that is well suited for detecting minor species in planetary atmospheres (Planet Space Sci. 43(1995) 1485). Yet, only a handful of molecules in the Mars atmosphere (CO2, CO and H2O along with their isotopic species, O3, and more recently H2O2 and CH4) have been detected so far by this method. New high performance spectroscopic instruments will become available in the future in the infrared and (sub)millimeter range, for observations from the ground (infrared spectrometers on 8 m class telescopes, large millimeter and submillimeter interferometers) and from space, in particular the Planetary Fourier Spectrometer (PFS) aboard Mars Express (MEx), and the Heterodyne Instrument for the Far-Infrared (HIFI) aboard the Herschel Space Observatory (HSO). In this paper we will present results of a study that determines detectability of minor species in the atmosphere of Mars, taking into account the expected performance of the above spectroscopic instruments. In the near future, a new determination of the D/H value is expected with the PFS, especially during times of maximum H2O abundance in the martian atmosphere. PFS is also expected to place constraints on the abundance of several minor species (H2O2,CH4,CH2O, SO2, H2S, OCS, HCl) above any local outgassing sources, the hot spots. It will be possible to obtain complementary information on some minor species (O3,H2O2, CH4) from ground-based infrared spectrometers on large telescopes. In the more distant future, HIFI will be ideally suited for measuring the isotopic ratios with unprecedented accuracy. Moreover, it should be able to observe O2, which has not yet been detected spectroscopically in the IR/submm range, as well as H2O2. HIFI should also provide upper limits for several species that have not yet been detected (HCl, NH3, PH3) in the atmosphere of Mars. Some species (SO, SO2,H2S, OCS, CH2O) that may be observable from the ground could be searched for with present single-dish antennae and arrays, and in the future with the Atacama Large Millimeter Array (ALMA) submillimeter interferometer. 相似文献