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1.
Carbazole compounds in crude oils from the Tazhong uplift of the Tarim basin have been fractionated and detected and successfully used to study petroleum migration and trace source rocks in the study area. Alkylcarbazoles have been found in large amounts in the oil samples analyzed and alkylbenzocarbazoles detected in a small concentration only in part of the samples, but alkyldibenzocarbazoles have not been found in oils. Based on the distribution of G1, G2 and G3 of C2-alkylcarbazoles, the ratio of C3-carbazoles to C2-carbazoles and the relative amounts of alkylcarbazoles and alkylbenzocarbazoles, one can know that the vertical oil migration in the Tazhong uplift is generally from below upward, i.e. from the Ordovician through the Silurian to the Carboniferous. Evidently, source rocks in the uplift should be lower Palaeozoic strata (Ordovician and Cambrian). This study shows that carbazoles are of great importance in the study of petroleum migration and source rocks.  相似文献   

2.
Molecular data from a large set of source rock, crude oil and oil-containing reservoir rock samples from the Tarim Basin demonstrate multiple sources for the marine oils in the studied areas of this basin. Based on gammacerane/C31 hopane and C28/(C27 + C28 + C29) sterane ratios, three of the fifteen crude oils from the Tazhong Uplift correlate with Cambrian-Lower Ordovician source rocks, while the other crude oils from the Tazhong Uplift and all 39 crude oils from the Tahe oilfield in the Tabei Uplift correlate with Middle-Upper Ordovician source rocks. These two ratios further demonstrate that most of the free oils and nearly all of the adsorbed and inclusion oils in oil-containing reservoir rocks from the Tazhong Uplift correlate with Cambrian-Lower Ordovician source rocks, while the free and inclusion oils in oil-containing carbonates from the Tahe oilfield correlate mainly with Middle-Upper Ordovician source rocks. This result suggests that crude oils in the Tazhong Uplift are partly derived from the Cambrian-Lower Ordovician source rocks while those in the Ordovician carbonate reservoirs of Tahe oilfield are overwhelmingly derived from the Middle-Upper Ordovician source rocks.The scatter of C23 tricyclic terpane/(C23 tricyclic terpane + C30 17α,21β(H)-hopane) and C21/(C21 + ΣC29) sterane ratios for the free and inclusion oils from oil-containing carbonates in the Tahe oilfield possibly reflects the subtle organofacies variations in the source rocks, implying that the Ordovician reservoirs in this oilfield are near the major source kitchen. In contrast, the close and positive relationship between these two ratios for oil components in the oil-containing reservoir rocks from the Tazhong Uplift implies that they are far from the major source kitchen.  相似文献   

3.
Carbon isotopic compositions were determined by GC–IRMS for individual n-alkanes in crude oils and the free, adsorbed and inclusion oils recovered by sequential extraction from reservoir rocks in the Tazhong Uplift and Tahe oilfield in the Tabei Uplift of Tarim Basin as well as extracts of the Cambrian–Ordovician source rocks in the basin. The variations of the δ13C values of individual n-alkanes among the 15 oils from the Tazhong Uplift and among the 15 oils from the Triassic and Carboniferous sandstone reservoirs and the 21 oils from the Ordovician carbonate reservoirs in the Tahe oilfield demonstrate that these marine oils are derived from two end member source rocks. The major proportion of these marine oils is derived from the type A source rocks with low δ13C values while a minor proportion is derived from the type B source rocks with high δ13C values. Type A source rocks are within either the Cambrian–Lower Ordovician or the Middle–Upper Ordovician strata (not drilled so far) while type B source rocks are within the Cambrian–Lower Ordovician strata, as found in boreholes TD2 and Fang 1. In addition, the three oils from the Cretaceous sandstone reservoirs in the Tahe oilfield with exceptionally high Pr/Ph ratio and δ13C values of individual n-alkanes are derived, or mainly derived, from the Triassic–Jurassic terrigenous source rocks located in Quka Depression.The difference of the δ13C values of individual n-alkanes among the free, adsorbed and inclusion oils in the reservoir rocks and corresponding crude oils reflects source variation during the reservoir filling process. In general, the initial oil charge is derived from the type B source rocks with high δ13C values while the later oil charge is derived from the type A source rocks with low δ13C values.The δ13C values of individual n-alkanes do not simply correlate with the biomarker parameters for the marine oils in the Tazhong Uplift and Tahe oilfield, suggesting that molecular parameters alone are not adequate for reliable oil-source correlation for high maturity oils with complex mixing.  相似文献   

4.
The free, adsorbed and inclusion oils were recovered by sequential extraction from eleven oil and tar containing reservoir rocks in the Tazhong Uplift of Tarim Basin. The results of gas chromatography (GC) and GC–mass spectrometry analyses of these oil components and seven crude oils collected from this region reveal multiple oil charges derived from different source rocks for these oil reservoirs. The initially charged oils show strong predominance of even over odd n-alkanes in the range n-C12 to n-C20 and have ordinary maturities, while the later charged oils do not exhibit any predominance of n-alkanes and have high maturities. The adsorbed and inclusion oils of the reservoir rocks generally have high relative concentrations of gammacerane and C28 steranes, similar to the Cambrian-Lower Ordovician source rocks. In contrast, the free oils of these reservoir rocks generally have low relative concentrations of gammacerane and C28 steranes, similar to the Middle-Upper Ordovician source rocks. There are two interpretations of this result: (1) the initially charged oils are derived from the Cambrian-Lower Ordovician source rocks while the later charged oils are derived from the Middle-Upper Ordovician source rocks; and (2) both the initially and later charged oils are mainly derived from the Cambrian-Lower Ordovician source rocks but the later charged oils are contaminated by the oil components from the Silurian tar sandstones and the Middle-Upper Ordovician source rocks.  相似文献   

5.
Sequential extraction was performed on two oil sandstones from the Upper Carboniferous oil columns of TZ401 well.The free oils of these two oil sandstones and a crude oil from the Lower Carboniferous oil column of this well have low ratios of C28/C27+C28+ C29) steranes and gammacerane/C31 hopanes,ranging of 0.11-0.16 and 0.09-0.15,respectively,similar to those from the Middle-Upper Ordovician source rock.However,these two ratios for the adsorbed and inclusion oils of these two oil sandstones are relatively high,ranging of 0.29-0.31 and 0.26-0.40,respectively,similar to those of the Cambrian-Lower Ordovician source rock.This result demonstrates that the initial oil charging the reservoirs was derived from the Cambrian-Lower Ordovician source rock,whereas the later charging oil was derived from the Middle--Upper Ordovician source rock.  相似文献   

6.
塔中421井和塔中402井石炭系油层2个原油样和8个油砂样连续抽提组分甾烷、萜烷分布特征和正构烷烃单体碳同位素组成具有明显的差异,具有不同的来源。塔中421井上石炭统3个油砂样自由态组分、束缚态组分和油气包裹体具有伽马蜡烷和C28甾烷相对含量高、正构烷烃单体碳同位素组成重的特征,划分为Ⅰ类原油,对比认为主要来源于寒武系-下奥陶统烃源岩。塔中421井和塔中402井上石炭统的2个油样具有伽马蜡烷和C28甾烷相对含量低、并且正构烷烃单体碳同位素组成轻的特征,划分为Ⅱ类原油,其来源尚不明确。塔中402井石炭系上、中和下统的5个油砂样各类组分具有介于Ⅰ、Ⅱ类原油之间的特征,为Ⅰ和Ⅱ类原油的混合物。5个油砂样从自由态组分、束缚态组分至油气包裹体Ⅰ类原油含量依次增高,Ⅱ类原油含量依次降低。2口井8个油砂样从自由态组分、束缚态组分至油气包裹体C23三环萜烷/(C23三环萜烷+C30藿烷)和C21/(C21+∑C29)甾烷比值都依次降低,反映了油气充注过程中,原油成熟度不断升高。塔中4井区储层油砂不同吸附态烃类分子与碳同位素的研究结果反映塔中4油田具有多种油气来源,经历长期油气充注过程,寒武系-下奥陶统烃源岩在地史上对该区具有成烃贡献。  相似文献   

7.
1 Introduction Since the 1990’s of the 20th century, oil & gas geochemists have shifted their research focus on hydrocarbon source rocks in the past to that on reservoir rocks and oil reservoirs at present; their research field has been expanded from oil & gas exploration to the assessment of oil reservoirs and production & management. Therefore, reservoir geochemistry as a branch disciplinary of organic geochemistry is now attracting great concern of many oil & gas explorers and oilfield en…  相似文献   

8.
轮南地区油气相态分布非常复杂,奥陶系油气藏平面上具有西油东气的特点。西部轮古西油田、塔河油田和轮南1井区油族成熟度略低且有生物降解痕迹,主要以重油形式分布;东部地区油族成熟度略高,主要以轻质油、凝析油形式存在;中间地段桑塔木断垒带、中部平台区和轮南断垒带发生混合作用形成了中一高蜡油。各地区油气在垂向上变化很大,东部地区奥陶系和石炭系为凝析油气,三叠系又为正常油分布区;西部地区奥陶系为稠油,三叠系为正常油。轮南地区奥陶系在纵向上可能受控于岩溶和储层的发育程度,横向上受控于断裂作用。轮南地区油气成藏时间较早,不同物性的原油都是古油藏多期供油的结果。  相似文献   

9.
塔里木盆地塔中隆起志留系油气成藏及分布特点   总被引:7,自引:0,他引:7  
塔里木盆地塔中隆起志留系油气成藏具有两源三期的成藏特点,"两源"是指油气来源于寒武系、中、上奥陶统两套烃源岩;"三期"是指从沥青到可动油的形成经历了加里东晚期、海西晚期、燕山—喜山期三个成藏期,沥青的形成是早期油气运移聚集过程中遭破坏的结果,目前所发现的可动油是以中、上奥陶统油气源为主的晚期成藏的结果。发育三种油气藏类型,即背斜构造、地层岩性以及火山岩遮挡型。塔中隆起志留系油气聚集受三大因素控制,一是隆起构造背景,围绕古隆起构成多种圈闭类型组合的复合油气聚集区;二是有效盖层,志留系中的油气显示十分活跃,包括沥青、稠油和正常油,沥青和稠油分布在红色泥岩段以下,而可动油集中分布在灰色泥岩段之下;三是优质储层,砂岩储层分布广泛,储层储集空间有次生-原生孔隙型、原生-次生孔隙型、微孔隙型三种类型,孔隙度3.3 %~17.4 %,渗透率(0.1 ~667.97)×10-3μm2。  相似文献   

10.
塔里木盆地北部奥陶系油气相态及其成因分析   总被引:8,自引:3,他引:5  
塔里木盆地北部地区奥陶系是最重要的勘探层系,油气资源丰富;同时油气相态复杂多样,既有凝析气藏、正常油藏,也有稠油油藏、沥青等。通过对油气藏形成演化与保存过程的系统分析,结合油气地球化学和流体包裹体等分析数据,发现油气相态的多样性与油气多期次充注与次生蚀变作用有关。提出塔北隆起的东部奥陶系存在三期油气充注过程,分别发生在加里东运动晚期-海西早期、海西运动晚期、喜马拉雅运动晚期,原油主要来源于中、上奥陶统烃源岩,天然气主要来自与寒武系烃源岩有关的液态烃的裂解;塔北隆起的中西部奥陶系的油气充注主要发生在海西运动晚期。塔北奥陶系油藏形成以后,经历了三期明显的调整改造过程:海西早期构造抬升导致志留-泥盆系遭受剥蚀,东部源自寒武系油气的古油藏遭受破坏,形成沥青;三叠系沉积前的晚海西运动,使得奥陶系生源的油藏大范围遭受降解稠化;晚喜山期,来自于满加尔坳陷的天然气自东向西充注,致使隆起东部早期形成的油藏发生强烈的气侵改造,形成次生凝析气藏。而中西部奥陶系油藏在三叠系沉积前遭受降解稠化后,一直处于沉降深埋过程,油藏得到有效保存;由于成藏时间较早,轻质组分散失较多,气油比极低,油质较稠。研究认为,油气相态的多样性主要受晚海西期构造运动的抬升造成的生物降解作用和喜马拉雅晚期构造运动造成的天然气自东向西大规模充注对油藏进行气洗改造两大过程的控制。  相似文献   

11.
Petroleum migration process of Bamianhe oilfield of Dongying depression, East China is evaluated on the basis of our detailed work on geochemistry of the crude oil and the source. Molecular tracers, especially nitrogen compounds, are employed in assessing style of oil migration and accumulation. Additionally, absolute quantitative results of heteroaromatics including dibenzofuran, dibenzothiophene and fluorene with similar basic frames to pyrrolic nitrogenic compounds are also used to evaluate the quantity of petroleum migration. According to apparent migration effects of the pyrrolic nitrogen compounds, it is indicated that most of Bamianhe oil was derived from potential source kitchen-Niu-zhuang sag, migrated and accumulated at Bamianhe fault belt through selective paths according to a main filling point displayed. Generally, upward migration trend from the main point along the south slope is noted. There are observable migration effects from Guangli subsag to the north Bamianhe and Yangjiaogou oilfields showing Guangli subsag was a secondary kitchen accounting for the oils in the north portion. Significant vertical migration effects shown in several cross sections demonstrate that faults well developed in the area play an important role in oil migration and accumulation. Unformality, sandstone reservoirs distributed locally also suggest important fairways in connecting sources with traps. The tectonic and a combination of tectonic and lithological mechanism are identified as the critical mechanisms in entrapping hydrocarbons. Migration trend suggested by nitrogenic compounds agrees well with analysis of lateral compositional variety and thermal maturity gradient. This study also confirms well with our previous studies. It is the location of source rocks, tectonic and stratigraphic characteristics that have a comprehensive control on the model of hydrocarbon migration and accumulation in Bamianhe oilfield. Results also show that the oils are mostly derived from the deep parts of the Niuzhuang and Guangli sags within normal oil window.  相似文献   

12.
鄂尔多斯盆地董志—正宁地区是该盆地中生界油气勘探新区,对该地区原油的地球化学进行研究,了解原油的成因,可以为该地区石油勘探和开发提供科学依据。本研究首次对采集于董志—正宁地区原油和鄂尔多斯盆地烃源岩的烃类生物标志化合物进行了系统的分析,研究了它们的地球化学特征。原油中各类烃类生物标志化合物分布和组成特征指示了原油形成于...  相似文献   

13.
Abstract: The Ordos Basin is an important intracontinental sedimentary basin in western China for its abundant Mesozoic crude oil resources. The southern part of the Tianhuan Depression is located in the southwestern marginal area of this Basin, in which the Jurassic and Triassic Chang-3 are the main oil-bearing strata. Currently, no consensus has been reached regarding oil source and oil migration in the area, and an assessment of oil accumulation patterns is thus challenging. In this paper, the oil source, migration direction, charging site and migration pathways are investigated through analysis of pyrrolic nitrogen compounds and hydrocarbon biomarkers. Oil source correlations show that the oils trapped in the Jurassic and Chang-3 reservoirs were derived from the Triassic Chang-7 source rocks. The Jurassic and Chang-3 crude oils both underwent distinct vertical migration from deep to shallow strata, indicating that the oils generated by Chang-7 source rocks may have migrated upward to the shallower Chang-3 and Jurassic strata under abnormally high pressures, to accumulate along the sand bodies of the ancient rivers and the unconformity surface. The charging direction of the Jurassic and Chang-3 crude oils is primarily derived from Mubo, Chenhao, and Shangliyuan, which are located northeast of the southern Tianhuan Depression, with oils moving toward the west, southwest, and south. The results show that an integration of biomarker and nitrogen-bearing compound analyses can provide useful information about oil source, migration, and accumulation.  相似文献   

14.
渤海湾盆地南堡凹陷滩海地区奥陶系原油油源分析   总被引:4,自引:1,他引:3  
近年来渤海湾盆地南堡凹陷的油气勘探取得了重大突破。在滩海区奥陶系古潜山钻遇工业性高产油气流,使奥陶系古潜山成为南堡油田重要勘探目的层之一,但目前对奥陶系主要产油层中油气的来源问题仍存在着不同的认识。通过对奥陶系原油与古近系沙三段、沙一段和东三段3套烃源岩的地球化学特征进行对比研究,并结合奥陶系油气成藏特征,探讨了奥陶系原油的油源。结果表明:南堡油田奥陶系原油生物标志化合物特征和稳定碳同位素组成与沙三段烃源岩的相似,二者具有较好的亲缘关系;同时,区域性的不整合面、油源断层可以成为沟通奥陶系古潜山储层与沙三段油源的运移通道;奥陶系原油主要来源于沙三段烃源岩。  相似文献   

15.
<正>The oil source of the Tarim Basin has been controversial over a long time.This study characterizes the crude oil and investigates the oil sources in the Lunnan region,Tarim Basin by adopting compound specific isotopes of n-alkanes and biomarkers approaches.Although the crude oil has a good correlation with the Middle-Upper Ordovician(O_(2+3)) source rocks and a poor correlation with the Cambrian-Lower Ordovician((?)-O_1) based on biomarkers,theδ~(13)C data of n-alkanes of the Lunnan oils show an intermediate value between(?)-O_1 and O_(2+3) genetic affinity oils,which suggests that the Lunnan oils are actually of an extensively mixed source.A quantification of oil mixing was performed and the results show that the contribution of the Cambrian-Lower Ordovician source rocks ranges from 11%to 70%(averaging 36%),slightly less than that of the Tazhong uplift.It is suggested that the inconsistency between the biomarkers andδ~(13)C in determining the oil sources in the Lunnan Region results from multiple petroleum charge episodes with different chemical components in one or more episode(s) and different sources.The widespread marine mixed-source oil in the basin indicates that significant petroleum potential in deep horizons is possible.To unravel hydrocarbons accumulation mechanisms for the Lunnan oils is crucial to further petroleum exploration and exploitation in the region.  相似文献   

16.
近几年,在鄂尔多斯盆地上三叠统长9油层组中不断有新的油气发现,因而对长9油层组石油运移的认识对进一步的勘探开发愈发重要。本文通过对古峰庄-王洼子地区延长组长7—长9油层组流体过剩压力的计算,并结合地球化学特征分析,对该地区长9油藏形成时的油气运移的动力特征进行了研究。结果表明,古峰庄—王洼子地区延长组长9油层组石油和长7油层组烃源岩具有相似的地球化学特征,长9原油可能主要来自于其上部长7油层组源岩。长7油层组源岩层具有远远大于长9油层的过剩压力分布,二者之间具有14 MPa以上过剩压力差值,成为长7油气向长9油层组储层运移的主要动力。  相似文献   

17.
<正>The Silurian stratum in the Tazhong uplift is an important horizon for exploration because it preserves some features of the hydrocarbons produced from multi-stage tectonic evolution.For this reason,the study of the origin of the Silurian oils and their formation characteristics constitutes a major part in revealing the mechanisms for the composite hydrocarbon accumulation zone in the Tazhong area.Geochemical investigations indicate that the physical properties of the Silurian oils in Tazhong vary with belts and blocks,i.e.,heavy oils are distributed in the TZ47-15 well-block in the North Slope while normal and light oils in the No.Ⅰfault belt and the TZ16 well-block,which means that the oil properties are controlled by structural patterns.Most biomarkers in the Silurian oils are similar to that of the Mid-Upper Ordovician source rocks,suggesting a good genetic relationship. However,the compound specific isotope of n-alkanes in the oils and the chemical components of the hydrocarbons in fluid inclusions indicate that these oils are mixed oils derived from both the Mid-Upper Ordovician and the Cambrian-Lower Ordovician source rocks.Most Silurian oils have a record of secondary alterations like earlier biodegradation,including the occurrence of "UCM" humps in the total ion current(TIC) chromatogram of saturated and aromatic hydrocarbons and 25-norhopane in saturated hydrocarbons of the crude oils,and regular changes in the abundances of light and heavy components from the structural low to the structural high.The fact that the Silurian oils are enriched in chain alkanes,e.g.,n-alkanes and 25-norhopane,suggests that they were mixed oils of the earlier degraded oils with the later normal oils.It is suggested that the Silurian oils experienced at least three episodes of petroleum charging according to the composition and distribution as well as the maturity of reservoir crude oils and the oils in fluid inclusions.The migration and accumulation models of these oils in the TZ47-15 well-blocks,the No.Ⅰfault belt and the TZ16 well-block are different from but related to each other.The investigation of the origin of the mixed oils and the hydrocarbon migration and accumulation mechanisms in different charging periods is of great significance to petroleum exploration in this area.  相似文献   

18.
Up until now, it has been assumed that oil in the Palaeozoic reservoirs of the Tazhong Uplift was derived from Upper Ordovician source rocks. Oils recently produced from the Middle and Lower Cambrian in wells ZS1 and ZS5 provide clues concerning the source rocks of the oils in the Tazhong Uplift, Tarim Basin, China. For this study, molecular composition, bulk and individual n-alkane δ13C and individual alkyl-dibenzothiophene δ34S values were determined for the potential source rocks and for oils from Cambrian and Ordovician reservoirs to determine the sources of the oils and to address whether δ13C and δ34S values can be used effectively for oil–source rock correlation purposes. The ZS1 and ZS5 Cambrian oils, and six other oils from Ordovician reservoirs, were not significantly altered by TSR. The ZS1 oils and most of the other oils, have a “V” shape in the distribution of C27–C29 steranes, bulk and individual n-alkane δ13C values predominantly between −31‰ to −35‰ VPDB, and bulk and individual alkyldibenzothiophene δ34S values between 15‰ to 23‰ VCDT. These characteristics are similar to those for some Cambrian source rocks with kerogen δ13C values between −34.1‰ and −35.3‰ and δ34S values between 10.4‰ and 21.6‰. The oil produced from the Lower Ordovician in well YM2 has similar features to the ZS1 Cambrian oils. These new lines of evidence indicate that most of the oils in the Tazhong Uplift, contrary to previous interpretations, were probably derived from the Cambrian source rocks, and not from the Upper Ordovician. Conversely, the δ13C and δ34S values of ZS1C Cambrian oils have been shown to shift to more positive values due to thermochemical sulfate reduction (TSR). Thus, δ13C and δ34S values can be used as effective tools to demonstrate oil–source rock correlation, but only because there has been little or no TSR in this part of the section.  相似文献   

19.
The absolute amounts and relative distributions of neutral nitrogen compounds in the Tabei oilfield (e. G. Blocks Ln1-Ln1 1) showed remarkable migration fractionation in the vertical direction. From Ordovician reservoirs (O) to oil legs TⅢ and T Ⅰ of Triassic reservoirs in blocks LN1-LN11, the concentrations of [a] [c] decreased from 1. 59μg/g, 0.49μg/g to 0.17 μg/g (oil). The ratios of various alkylcarbazole isomers, such as 1,8-dimethylcarbazole/nitrogenpartially shielded isomers and 1,8-dimethylcarbazole/nitrogen-exposed isomers, were adopted as the indicators of petroleum migration. The ratios increased from 0.13, 0.20 to 0.67 and from going from the south to the north of the Tabei oilfield, the absolute concentrations of neutral nitrogen compounds decreased drastically, and the nitrogen-shielded isomers were enriched relative to nitrogen-exposed isomers and nitrogen-partially shielded isomers. Crude oils in the Tabei oilfield migrated laterally from the Jilake structure to the Sangtamu fault uplift and Lunnan fault uplift, and crude oils in the same fault uplift migrated and remigrated vertically from Ordovician reservoirs, to oil legs TⅢ to TⅠ of Triassic reservoirs.  相似文献   

20.
The results obtained in this paper indicate that carbazole-type compounds have high thermal stability and also show stability in oxidation and bio-degradation. This kind of compounds still has a high concentration and complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in studying petroleum migration of paleo-pool. During the basin's first-stage of oil-gas pool formation in the Silurian in Tazhong and Tabei areas of Tarim Basin (at the end of Silurian period) and the second-stage in the Awati area (in Permian), the petroleum experienced a long-distance migration. During the formation of the Silurian paleo-pools in Tazhong Uplift at the end of Silurian, the petroleum mainly came from the lower and middle Cambrian source rocks in the Manjiaer sag. The petroleum migrated towards the southwest-south entering the Silurian reservoir beds in Tazhong first. Then, it further migrated within Silurian from northwest to southeast along the highs of the Structural Belts to the region of the Silurian pinchout boundary in Tazhong. In Tabei Uplift, during the first-stage of pool formation, the petroleum was also from the lower and middle Cambrian source rocks in the Manjiaer sag. It migrated northwest entering the Silurian reservoir beds in the Tabei Uplift firstly, and then the migration continued in the same direction within the Silurian reservoirs and finally the petroleum was trapped in higher positions. During the second-stage pool formation in the Silurian beds in the areas around Awati sag, the petroleum mainly came from the lower-middle Cambrian source rocks in the Awati sag. The petroleum migrated from the generation center to Silurian reservoirs in all directions around the sag through major paths, and the petroleum was finally trapped in higher locations.  相似文献   

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