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1.
Gabbro is selected as a sample for experimental deformation to investigate and validate the migration of dements during rock deformation. Samples are deformed for 3 h under a strain of about 5% at T=700℃, p=100 MPa, σ=50 MPa. It is shown that there are 4 areas with different colors in the section of the samples paralld to σ1 : the extensional, contractional, and strongly compressional areas and a ductile shear zone, respectively on the basis of the stress states and the direction of material movement. The chemical components such as K, Na, AI and Fe from materials in different areas have changed. The four elements mentioned above in pyroxene grains decrease in content from the extensional area through the ductile shear zone, the contractional area, to the strongly compressional area. The contents of the same elements in feldspar grain vary in a reverse direction.  相似文献   

2.
This study dealt with the distribution characteristics of soil organic carbon （SOC） and the variation of stable carbon isotopic composition （δ^13C values） with depth in six soil profiles, including two soil types and three vegetation forms in the karst areas of Southwest China. The δ^13C values of plant-dominant species, leaf litter and soils were measured using the sealed-tube high-temperature combustion method. Soil organic carbon contents of the limestone soil profiles are all above 11.4 g/kg, with the highest value of 71.1 g/kg in the surface soil. However, the contents vary between 2.9 g/kg and 46.0 g/kg in three yellow soil profiles. The difference between the maximum and minimum δ^13C values of soil organic matter （SOM） changes from 2.2‰ to 2.9‰ for the three yellow soil profiles. But it changes from 0.8‰ to 1.6‰ for the limestone soil profiles. The contrast research indicated that there existed significant difference in vertical pattems of organic carbon and δ^13C values of SOM between yellow soil and limestone soil. This difference may reflect site-specific factors, such as soil type, vegetation form, soil pH value, and clay content, etc., which control the contents of different organic components comprising SOM and soil carbon turnover rates in the profiles. The vertical variation patterns of stable carbon isotope in SOM have a distinct regional character in the karst areas.  相似文献   

3.
With the aim of better understanding the tight gas reservoirs in the Zizhou area of east Ordos Basin, a total of222 samples were collected from 50 wells for a series of experiments. In this study, three pore-throat combination types in sandstones were revealed and confirmed to play a controlling role in the distribution of throat size and the characteristics of gas-water relative permeability. The type-Ⅰ sandstones are dominated by intercrystalline micropores connected by cluster throats, of which the distribution curves of throat size are narrow and have a strong single peak(peak ratio 30%). The pores in the type-Ⅱ sandstones dominantly consist of secondary dissolution pores and intercrystalline micropores, and throats mainly occur as slice-shaped throats along cleavages between rigid grain margins and cluster throats in clay cement.The distribution curves of throat size for the type-Ⅱ sandstones show a bimodal distribution with a substantial low-value region between the peaks(peak ratio 15%). Primary intergranular pores and secondary intergranular pores are mainly found in type-Ⅲ samples, which are connected by various throats. The throat size distribution curves of type-Ⅲ sandstones show a nearly normal distribution with low kurtosis(peak ratio 10%), and the micro-scale throat radii(0.5 μm) constitute a large proportion. From type-Ⅰ to type-Ⅲ sandstones, the irreducible water saturation(Swo) decreased; furthermore, the slope of the curves of Krw/Krg in two-phase saturation zone decreased and the two-phase saturation zone increased,indicating that the gas relative flow ability increased. Variations of the permeability exist in sandstones with different porethroat combination types, which indicate the type-Ⅲ sandstones are better reservoirs, followed by type-Ⅱ sandstones and type-Ⅰ sandstones. As an important factor affecting the reservoir quality, the pore-throat combination type in sandstones is the cumulative expression of lithology and diagenetic modifications with strong heterogeneity.  相似文献   

4.
The aim of the present study is to locate and decipher the groundwater quality,types,and hydrogeochemical reactions,which are responsible for elevated concentration of fluoride in the Chhindwara district in Madhya Pradesh,India.Groundwater samples,quality data and other ancillary information were collected for 26 villages in the Chhindwara District,M.P.India during May 2006.The saturation index was computed for the selected samples in the region,which suggest that generally most of the minerals are saturated with respect to water.The concentration of fluoride in the region varies from 0.6 to 4.74 mg/l,which is much higher as per the national and international water quality standards.The study also reveals that the fluoride bearing rock formations are the main source of the higher concentration of fluoride in groundwater along with the conjuncture of land use change.Moreover,the area is a hard rock terrain and consists of fractured granites and amygdaloidal and highly jointed compact basalt acting as good aquifer,which is probably enriching the high content of fluoride in groundwater.High concentration of fluoride is found in deeper level of groundwater and it is possible due to rock-water interaction,which requires further detailed investigation.The highly alkaline conditions indicate fluorite dissolution,which works as a major process for higher concentration of fluoride in the study area.The results of this study will ultimately help in the identification of risk areas and taking measures to mitigate negative impacts related to fluoride pollution and toxicity.  相似文献   

5.
Micropores of shale are significant to the gas content and production potential of shale, which has been verified in the research of marine shale gas; while, few studies have been conducted on lacustrine shales. This study collected 42 samples from three wells in the Late Cretaceous Qingshankou Formation of the southern Songliao Basin, NE China, and investigated these samples by the focused ion beam-scanning electron microscope (FIB–SEM) and nitrogen adsorption analysis techniques. Four types of micropores were identified in the samples, i.e., intergranular pore, intracellular pore, organic matter pore and microfracture. The pore structure type is characterized by open slit pores and “ink type” pores which are mainly 1.5–5 nm in diameter with mesopores as the main pores. The mesopores account for 74.01% of the pore volume and 54.68% of the pore surface area. Compared with the lacustrine shales from the Triassic Yanchang Formation in the Ordos Basin and Xujiahe Formation in the Sichuan Basin, the intergranular clay mineral interlayer pores are considered to be the main reservoir space for shale gas storage in the study area, followed by intraparticle pores, organic matter pores and microfractures. Maturity and micropore are the key controlling factors which affect the shale gas content of the Qingshankou Formation in southern Songliao Basin.  相似文献   

6.
A study on the potential and kinetics of hydrocarborn(HC) generation of 30 source-rock samples from a certain depression has been made by means of ROCK-EVAL technique .In the pyrolysis experiment, the source material types, maturation and hydrocarbon-generating potential of source rocks from three Upper Jurassic horizons of that area have been evaluated in terms of such indicators as the type-index, hydrocarbon-generating potential and maximum pyrolysis temperaturw(Tmax) .The results show that the pyrolysis HC yield of immature source rocks is much higher than that of mature rocks in case that the source mateuial is of high quantity and organic matter is abundant, which suggests that it is important for evaluating the HC-generating potential to use immature samples for pyrolysis.In the pyrolytic simulation experiments on other two immature samples,it was found that the hydrocarbon yield is temperature-dependent, and thereafter the kinetical parameters for source rocks, such as reactional grade, appearant activation energy and frequency factor were calculated.  相似文献   

7.
The Distrbution of Various Mercury Species in Soil   总被引：2，自引：0，他引：2  
According to the mercury species with different solubilities,the analytical procedure involving sequential chemical extraction has been applied to partitioning the mercury species in soils into seven fractions.Soil samples collected from five localities in different areas (the high-mercury ares.the man-made mercury-polluted area and the reference area)were an alyzed for the seven mercury species.It is found that high mercury contents of soils can be attributed to both man-made pollution and geological processes,but the two kinds of solis show obvious differences in the distribution of their mercury species.  相似文献   

8.
The Carboniferous system in the Xiaohaizi area, Bachu County, Xinjiang Uygur Autonomous Region, composed of typical mixed terrigenous clastic, carbonate and sulphate sediments, was mainly deposited in the tidal flat and lagoon environments. The mixed sediments occur as the following eleven types: 1. limestone intercalated with siltstone; 2. interbeds of shale and limestone; 3. gypsolyte interbedded with limestone; 4. gypsolyte intercalated with siltstone; 5. gypsolyte interbedded with shale; 6. gypsolyte intercalated with siltstone, limestone and dolomite; 7. siltstone interbedded with gypsolyte and limestone; 8. terrigenous detritus scattered in carbonate matrix; 9. carbonate as cement in clastic rocks; 10. mixed sediments of carbonate and terrigenous mud; 11. mixed sediments of carbonate grains with terrigenous sand. Based on the analysis of the dynamic mechanism of mixed sediments, it is believed that these types of mixed sediments in the study area were controlled by climate, sea level change and so  相似文献   

9.
Effects of mercury on ecosystems and human health are well documented. Human activities have significant impacts on transport, transformation, and fate of mercury in the natural environment. In this study, a gold mining area （Tongchuan）, an urban area （Xi＇an）, and a historical site （Qinshihuan Tomb） in Shaanxi Province, China, was chosen to study the effects of human activities on the transport, transformation, and fate of mercury in the area. Samples of atmospheric precipitate, soil, sediment, pomegranate, corn and those from wells and the rivers that flow through or flow by the city and from the mining area were collected. The EPA methods were used for sample preparation and analysis of these samples. These methods combine acid digestion, chemical reduction, purge and trap with Cold Vapor Atomic Fluorescence Spectrometry （CVAFS）. Preliminary results showed high total mercury concentrations in the water samples collected from a river in Tongguan County. The total mercury concentrations ranged from 133 to 188 ng/L in the water samples collected from the rivers flowing through Xi＇an City. The amount of total mercury in the soil/sediment samples which were collected in the vicinity of Xi＇an ranged from 31.8 to 83.2 ng/g. The total mercury concentrations in the samples of atmospheric precipitate （including rain and snow collected from Sep. 2005 to Jan. 2006） ranged from 106-298 ng/L.  相似文献   

10.
Highly elevated cadmium concentrations in paddy soil in the Mae Sod District, Tak Province, Thailand, was detected and widely reported in 2003. This emergence provoked public interest and demands for responsibility and remedial actions. As zinc mines and concentrator were located in the upstream area, mining activities were proclaimed a contamination source. Department of Primary Industries and Mines （DPIM）, a governmental organization responsible for mining and mineral processing, was thus challenged to verify the reliability of post monitoring data displaying consistently low heavy metal concentrations in compliance with the standard limits for over 15 years. Detailed survey and deep-going research on the causes, boundary and severity of cadmium contamination as well as the environmental impact alleviation were consequently conducted. Environmental samples were accumulated systematically for 2 years throughout the areas of upstream and downstream mining sites. A total of 259 soil samples from 53 spots at the depths of 0-20, 20-40, 40-60 and 60-200 cm were drilled with hand auger. Samples of water, stream sediment and mine tailing were also collected. Chemical analysis for cadmium （Cd）, zinc （Zn） and lead （Pb） concentrations with AAS and ICP were undertaken. The contaminated area was finally defined to spread over approximately 18 square kilometer mainly of mountainous mineralizing land and colluvium.  相似文献   

11.
This paper covers the detailed version of the potential raw material deposits at Darukhula and the adjacent areas of Nizampur, the manufacturing of high-strength Portland cement samples from the same material and comparison of the physical and chemical parameters for resulting cement with British and Pakistan standard specifications, which include compressive strength, setting time, consistency, lechatelier expansion, Blaine and insoluble residue. It was found that the raw material available in the study area meets the standard specifications and the area is feasible for the cement plant installation. The area can provide raw material which is quite sufficient for the running of a cement plant.  相似文献   

12.
In this investigation local clay from Cherat mines, Nowshera District, NWFP, Pakistan, has been tested as a pozzolanic material in high strength Portland cement. Thermal treatments were performed as a means of activation of the clay. It was found that thermal treatment of the clay can increase its pozzolanic activity. Different blended mortars, containing different amounts of clay, activated at different temperatures were studied for compressive strength, consistency, and setting times. It was concluded that the mechanical properties of the blended cements were mainly governed by the percentage of incorporation of the calcined clay. Blended cement composition has been formulated, with optimal results of 20% calcined clay at a temperature of 600℃.  相似文献   

13.
Limestone beds of the Late Cretaceous Abiod formation (Campanian-Maastrichtian system) are fundamentally important for the economic growth of the raw material sector in Tunisia. However, little attention has been paid to the detailed physical and chemical properties of the Abiod limestone. Nine limestone samples collected from the Abiod formation outcropping in the areas of Bizerte, Gafsa and Gabes, Tunisia, as well as their separated clay fractions, were characterized using different techniques, such as XRF, XRD, FTIR and TG/DTA. XRF showed the chemical composition of the limestone in which calcium carbonate was the main constituent, and silica, iron and magnesium were the impurities. XRD also confirmed the presence of small amounts of clay minerals and quartz along with sharp peaks of calcite. FTIR spectra indicated that the limestone was mainly composed of CaCO3 in the form of calcite, as identified by its main characteristic absorption bands. These data were in agreement with XRD and XRF analysis data. The TG/DTA curves of the limestone samples, showing a close similarity to that of pure calcium carbonate, exhibited an endothermic peak between 600 and 760°C, with the maximum near 750°C. Moreover, FTIR spectra of clay fraction samples indicated high silica content in some samples. Especially the samples SD1 and SD2 collected in the northern area showed higher amounts of silica compared with those of AS1, AS2, CHB, ZNC, SND, MKM and GBS collected from southern districts. However, among the latter seven samples, one could recognize two groups based on the clay mineral investigations: (1) limestone with minor amounts of smectite and mixed layer minerals of smectite/illite (AS1 and 2, CHB, ZNC, SND and GBS) and (2) limestone with smectite, kaolinite and apatite (SND and MKM). Differences in these mineralogical and chemical characteristics should be considered when limestone from the Abiod formation is utilized as a medium for heavy metal removal from wastewater.  相似文献   

14.
贵州紫云县猴场镇扁平村的上石炭统叶状藻礁及其周边灰岩中广泛发育大量的各类胶结物。通过对胶结物的形态、结构和阴极发光特征以及胶结物间的接触关系的研究,可以确定成岩作用的先后并识别成岩环境。浅海海底同生成岩阶段大的孔隙中形成等厚环边针状胶结物、葡萄状胶结物,小的孔隙里形成微晶胶结物。早成岩阶段形成微亮晶和斑块状亮晶方解石胶结物和放射纤维扇状胶结物,表生成岩阶段的溶蚀作用和胶结作用强烈,胶结物类型有斑块状或等粒的方解石胶结物和等厚环壁柱状胶结物,等厚环壁柱状胶结物在所有胶结物中体积是较大的。早期胶结作用使叶状藻礁灰岩孔隙度大为降低。中、晚成岩阶段,孔隙被等厚环壁刃状胶结物和晶簇或斑块状亮晶方解石所充填,有些先成的胶结物被热液改造。后生作用阶段发生的主要是构造破裂作用,其中少数裂隙被红褐色含Fe2O3微晶层和晶体粉砂及渗流豆粒充填。叶状藻礁灰岩的孔隙在晚成岩阶段前或中被胶结而之后没有创造出大且连通的孔隙,是它没能成为油气储集层的原因之一。  相似文献   

15.
左洪发 《安徽地质》2010,20(1):42-48
安徽省含山县柱山—项家山水泥石灰岩矿床矿位扬子准地台与华北地台、大别山造山带的结合部位,属扬子板块西北缘,大别造山带的前陆带,郯庐断裂带的东侧,属丘陵地貌,山体走向为北东向,地形起伏变化较大,区域内矿产主要为沉积矿产,有石膏、水泥用石灰岩、石英砂岩、耐火粘土及陶瓷粘土、砖瓦用粘土等。另外有铜、铅、锌、铁、铀、高岭土、煤等矿(化)点。本文对含山县柱山—项家山水泥石灰岩矿床特征、成因以及开采技术条件进行探讨。  相似文献   

16.
贵州紫云县猴场镇扁平村的上石炭统中的叶状藻礁及其周边灰岩中发育强烈的成岩作用和胶结物,这些胶结物在猴场研究区内是显著的和有代表性的。通过观察、分析野外露头、光片、薄片、薄片的阴极发光和染色,来研究礁体岩石的成岩作用,确定了成岩作用序列、成岩环境、成岩阶段。成岩作用类型主要有泥晶化、溶蚀、胶结、新生变形、机械压实、剪切或...  相似文献   

17.
Limestones in the Palmers Oakey District, N.S.W., range in age from Middle Silurian to Early Devonian. They occur as sheet‐like, bioclastic beds and/or isolated clasts in three facies: a volcaniclastic facies, a mudstone‐limestone facies, and a limestone‐mudstone breccia facies. Multielement conodont taxa, not previously reported from Australia, include Kockelella absidata, Kockelella stauros, Ozarkodina asymmetrica, Ozarkodina stygia, Ozarkodina transitans, Pseudooneotodus bicornis, and Pseudooneotodus tricornis.  相似文献   

18.
张建 《江苏地质》1997,21(1):22-26
系统了介绍了生产水泥的石灰石，下蜀粘土，硫酸渣三组分配料的工艺性能试验成果，提供了一套有关采用现代水泥工艺生产出符合ＡＳＴＭ的Ｉ型水泥的试验数据，同时，其试验成果可代同类矿床勘探借鉴。  相似文献   

19.
The flanks of Middle Triassic carbonate buildups in the Dolomites show well‐developed clinostratification, with typical angles of 30–40°. This paper focuses on the metre‐scale fabric of these clinoforms and sets these within the context of their large‐scale and microscopic features. Clinoform stratification is caused by fibrous cement crusts, by stylolites paralleling a vague stratification and by pelagic limestone interbedded with the lower portions of the clinoforms. These parts of the clinoforms locally exhibit a boulder fabric. A fracture system, subvertical to clinostratification, is filled by fibrous cements and marine internal sediment. The analysis of clinoform fabric indicates that parts consist of in situ automicrite. Other parts of the clinoforms are made up of breccia. The breccias occur as isolated pockets and lenses with random orientation and dimensions ranging from a few square decimetres to hundreds of square metres. The breccias have gradual contacts with the unbrecciated host rock. Breccia components are mostly angular, show a microfacies similar to that of the unbrecciated host rock and are composed of millimetre‐ to decimetre‐sized particles that generally float in radiaxial‐fibrous cement. Matching grain boundaries are common. Calcite cement typically makes up 20 and 40 vol.% of the brecciated areas. Clinostratification, the fracture system, brecciation and boulder fabric point to gravity induced deformation of in situ flank deposits rather than gravity induced depositional processes. Brecciation appears to result from translational sliding (millimetres to metres) on the steep buildup flanks, which caused fracturing of the vaguely stratified automicrite, followed by displacive growth of fibrous cement. Cementation occurred in a (shallow) burial, marine phreatic environment, because cement clasts are virtually absent from the flank‐derived gravity flows in the adjoining basinal sediments. Displacive cement growth indicates a volume increase of the clinoforms during diagenesis of up to 20–40 vol.% and can account for the local drag of buildup interior limestones. Similarly, the boulder fabric appears to be a diagenetic feature, which resulted from differential settling of incompletely lithified boundstone and grainstone, and the interbedded pelagic limestone.  相似文献   

20.
Monitoring general variability of soil attributes is a fundamental requirement from the point of view of understanding and predicting how ecosystems yield. In order to monitor impact of different land use types on the combination of morphological, clay mineralogical and physicochemical characterizes, 42 soil samples (0–30 cm) were described and analyzed. Soil samples belonging to Cambisols and Vertisols reference soil groups collected from three neighboring land use types included cropland (under long-term continuous cultivation), grassland, and forestland. The soils were characterized by high pH (mean of 7.1–7.5) and calcium carbonate equivalent (CCE) (mean of 35–97 g kg?1) in the three land use types. The weakening in soil structure, hardening of consistency, and lighting of soil color occurred for the cropland under comparable condition with grassland and forest. Changes in land use types produced a remarkable change in the XRD patterns of clay minerals containing illite and smectite due the dynamic and removal of potassium. Continuous cultivation resulted in an increase in sand content up to 35 % while silt and clay content decreased up to 22 and 18 %, respectively, as compared to the adjoining grassland and forest mainly as a result of the difference of dynamic alterational and erosional process in the different land use. Long-term cultivation caused a negative and degradative aspects on soil heath as is manifested by the increasing in soil pH (a rise of 0.3–0.46 unit), electrical conductivity (EC) (a rise of 1.78–5.5 times), sodium absorption ration (SAR) (a rise of 10–51 %), exchangeable sodium percentage (ESP) (a rise of 3–46 %), and the decrease in soil organic C (a drop of 12–41 %), along with soil fertility attributes. Overall, the general distribution of soil organic C, total N, available P and K, cation exchange capacity (CEC), and exchangeable cations (Ca, Mg, and K) followed the order: forestland > grassland > cropland. The general distribution of EC, SAR, ESP, and exchangeable Na, however, followed the order: cropland > grassland > forestland. Soil quality index (SQI), calculated based on some physicochemical properties, specified that cultivation led to a negative effect in SQI for both Cambisols (a drop of 10–17 %) and Vertisols (a drop of 17 %) as compared to those of under grassland and forestland.  相似文献   

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