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1.
Waters of the northern watershed of Lake Kineret, sampled during the period 1978–1983, were analyzed for their major and trace element contents. The trace element concentrations of the major water sources of the watershed (the Dan and Banias springs) represent background values. After emergence, the waters are subjected to human activity. In crossing the populated and cultivated Hula Basin in man-made canals, the major and trace element contents increase. In comparison to the trace element concentrations, those of the major elements have narrow ranges and small temporal fluctuations. Trace element concentrations varied by 3 orders of magnitude, and temporal variations were large but not neccessarily seasonal. Point sources of trace elements were urban effluents, fish pond wastes, and peat soil drainage. The trace element concentrations decrease in the waters of the last segment of the Jordan River. All measured trace elements were below the criteria levels established by regulatory agencies. Several, however, were of the same order of magnitude. Addition of wastes from enhanced recycling, and morphologic modification of the final course of the Jordan River could result in increase in the trace element concentrations in the water.  相似文献   

2.
Gough Island: Evaluation of a fractional crystallization model   总被引：3，自引：0，他引：3  
Gough Island is composed of an alkaline olivine basalt-trachyte series. A fractional crystallization model for the development of these rocks has been evaluated by correlating the geochemical trends of major and trace elements. Beginning with an alkali olivine basalt parent the major element abundances were used to determine the varying proportions of crystallizing minerals required to generate the various residual liquids. A least-squares computer model was used for this calculation. The modal proportions of cumulative minerals and trace element distribution coefficients were used to predict the trace element abundances in each rock type.Three significant trace element trends are observed in Gough Island rocks: (1) increasing rare earth (RE) abundance and relative light RE enrichment with increasing major element differentiation, (2) marked Eu, Sr, and Ba depletions in late stage trachytes, (3) Cr and M enrichment in picrite basalt.The trace element abundances predicted by the fractional crystallization model are in good agreement with these observed trends. A fractional crystallization process involving olivine, pyroxene, feldspar, and apatite accounts for all the significant major and trace element trends observed in Gough Island rocks.  相似文献   

3.
In the Taleghan area of Alborz mountain range, two distinct units of alkaline rocks are identified. Whole rock major and trace element data does not provide a clue as to their common or different parental melts. However, major and trace element geochemistry of their included clinopyroxene phenocrysts, combined with the whole rock data, helped to infer that two parental magmas were involved in the evolution of volcanic succession in the Taleghan area.  相似文献   

4.
The petrogenesis of bronzite-picrite, olivine-gabbro, norite and quartz-tholeiite dykes, which make up the 2.39 b.y. Scourie dyke swarm cutting the Archaean Lewisian gneisses of N.W. Scotland, is interpreted on the basis of their major and trace element geochemistry. Most of the dykes bear primary amphibole and/or phlogopite and, with one exception, are all hypersthene- or quartz-normative. Apart from one tholeiite dyke which shows relative light rare-earth element depletion, all the dykes show enrichment in light rare-earths and large-ion lithophile elements. They do not however show an equivalent enrichment in other incompatible high field strength ions such as Nb and Ta, and in this respect resemble island arc and calc-alkaline basalts. The different dyke types have distinctive rare-earth patterns and other trace element ratios which are maintained over a range of major element compositions.Petrogenetic modelling of the major and trace element compositions of the various dykes demonstrates that very few can be related by fractional crystallisation. Indeed, even with partial melting mechanisms at least two different mantle sources, with different major and trace element compositons, are required to explain the compositional differences between the major dyke types. The high degrees of mantle melting implied for the generation of the magnesium-rich bronzite-picrites suggests that their rare earth and other trace element patterns closely reflect those of their mantle source. Similar arguments, though less well constrained, can be advanced for the other dyke types. The results suggest that the sub-continental mantle source feeding the dykes was heterogeneous with respect to both major and trace elements, and that their mantle sources must have been enriched in lithophile elements. Enrichment at the time the Lewisian gneisses were generated (i.e. 2.92 b.y. ago) would be compatible with the initial 87Sr/86Sr ratios of the dykes and the inferred Rb/Sr ratios of their mantle sources. The sub-continental mantle sources have thus retained the geochemical signature of the crustgenerating processes some 500 m.y. earlier.  相似文献   

5.
Two clinopyroxene megacrysts, DMP-2 and DMP-3, were collected from Cenozoic alkali basalts in the Hannuoba region of China. They were characterised for major and trace element compositions for in situ microanalysis. EPMA and LA-ICP-MS analyses indicate homogeneity in the element mass fractions in both clinopyroxene samples. Bulk analyses using various techniques (XRF, ICP-OES and solution ICP-MS) also reveal good consistency in their major and trace element data. They, thus, can be used as potential reference materials for elemental in situ microanalysis. Accordingly, element mass fractions are recommended for thirty-two elements.  相似文献   

6.
广西大新县下雷锰矿床的地球化学特征及其意义   总被引：2，自引：0，他引：2  
下雷锰矿矿石和岩石的稀土元素分布形式、稀有元素和同位素组成特征的多样性,反映了锰矿形成的区域构造背景应是被动大陆边缘裂谷环境,锰矿成矿作用与区内同时代玄武岩有一定成因和物源上的联系,同时又表明下雷锰矿的物源具多源性:既有来自下地壳的物质,又有陆源物质的混入和生物作用的产物的加入。代表一种在的海相沉积条件下正常沉积的同时,有地下热水注入的多源外生成矿环境。主要元素Fe、Mn、MgO、SiO2、Al2O3、CaO的含量变化和稀有元素V/(Ni+V)、V/Cr和Fe—Mn—(Ni+Co+Cu)×10三角图解提示锰矿形成时的物理化学条件为:氧化一弱氧化环境,介质酸碱度在酸性和碱性间交替变化,成矿温度属于中低温热水范围。  相似文献   

7.
We report on the major and trace element composition and homogeneity of NIST (National Institute of Standards and Technology) glass standard reference materials 611, 612, 614, and 1834 for use as microanalytical trace element standards in laser ablation-inductively coupled plasma-mass spectrometry. The four analyzed NIST glasses were not designed as microanalytical standards, but their availability and careful preparation made them obvious candidates. Our data indicate that NIST 1834 is inhomogeneous on a scale of 100 mg with respect to several trace elements. Within analytical uncertainty, NIST 611, 612, and 614 are apparently homogeneous.  相似文献   

8.
Tholeiitic basalts dredged from the Mid-Atlantic Ridge (MAR) axis at 43 ° N are enriched in incompatible trace elements compared to the ‘ normal’ incompatible element depleted tholeiites found from 49 ° N to 59 ° N and south of 33 ° N on the MAR. The most primitive 43 ° N glasses have MgO/FeO*= 1.2 and coexist with olivine (Fo90–91) and chrome-rich spinel. The tholeiitic basalts from the MAR 43 ° N are distinct from the strongly incompatible trace element depleted tholeiities found elsewhere in the Atlantic, and have trace element features typical of island tholeiities and MAR axis tholeiites from 45 ° N. Petrographic, major, and compatible trace element trends of the axial valley tholeiites at 43 ° N are consistent with shallow-level fractionation; in particular, evolution from primitive liquids with forsteritic olivine plus chrome spinel as liquidus phases to fractionated liquids with plagioclase plus clinopyroxene as major crystallizing phases. However, each dredge haul has distinctive incompatible trace element abundances. These trace element characteristics require a hetrogeneous mantle or complex processes such as open system fractional crystallization and magma mixing. Alkali basalts (～5% normative nepheline) were dredged from a prominent fracture zone at 43 ° N. Typical of alkali basalts they are strongly enriched (compared to tholeiites) in incompatible elements. Their highly fractionated rare-earth element (REE) abundances require residual garnet during partial melting. The 43 ° N tholeiites and alkali basalts could be derived from a garnet peridotite source with REE contents equal to 2 × chondrites by ～5% and 1% melting, respectively. Alternatively, they could be derived from a moderately light REE enriched source by ～25% and 9.5% melting, respectively.  相似文献   

9.
Kimberlite magmas from the Kimberley area of South Africa have sampled two main types of phlogopite-rich mafic xenoliths which represent deep mantle segregations from highly alkaline melts. The first group corresponds to the MARID rocks characterised by the mineral association mica (phlogopite)-amphibole (K-richterite)-rutile-ilmenite-clinopyroxene and the second group consists of the PIC rocks characterised by the mineral association mica (phlogopite)-ilmenite-clinopyroxene-minor rutile. The two groups are clearly distinguished from one another by their mineral paragenesis, by the major element composition of their phlogopite and ilmenite, by the trace element content of their clinopyroxene and by their clinopyroxene and whole rock Sr and Nd isotope ratios. The combined major and trace element variations are interpreted to indicate a genetic relationship between the PIC rocks and group I kimberlite magma, and between the MARID rocks and group II kimberlite magma. The two types of parental melts percolated through, and metasomatised, the upper mantle beneath the Kimberley area as indicated by the trace element characteristics of the clinopyroxenes of the studied phlogopite-bearing peridotites.  相似文献   

10.
For the trace element analysis of gold by laser ablation ICP-MS, external calibration samples of differing matrix composition have been used in previous studies. Data presented here suggest that even for calibration samples and unknowns with closely-matched matrices, discrepancies arise due to variations in the coupling behaviour of the laser with the sample at different power deliveries, and can lead to erroneous trace element determinations. Internal standardisation for gold is complicated because Au and Ag, the most common major elements, do not have minor isotopes that can be used as internal standards. This problem was overcome for natural gold samples by using an external calibration sample only for the major elements Au and Ag, then defocussing the ion path and using 107Ag in each sample as an internal standard against which μg g-1 levels of Te, Sb, Hg, Bi, and Cu were determined. The results suggest that trace elements can occupy lattice sites in gold rather than occurring only as micro-inclusions of other phases. The analytical approach taken here may be used in trace element analysis where adequate external calibration samples are not readily available.  相似文献   

11.
Sphalerite (ZnS) is an abundant ore mineral and an important carrier of elements such as Ge, Ga and In used in high‐technology applications. In situ measurements of trace elements in natural sphalerite samples using LA‐ICP‐MS are hampered by a lack of homogenous matrix‐matched sulfide reference materials available for calibration. The preparation of the MUL‐ZnS1 calibration material containing the trace elements V, Cr, Mn, Co, Ni, Cu, Ga, Ge, As, Se, Mo, Ag, Cd, In, Sn, Sb, Tl and Pb besides Zn, Fe and S is reported. Commercially available ZnS, FeS, CdS products were used as the major components, whereas the trace elements were added by doping with single‐element ICP‐MS standard solutions and natural mineral powders. The resulting powder mixture was pressed to pellets and sintered at 400 °C for 100 h using argon as an inert gas. To confirm the homogeneity of major and trace element distributions within the MUL‐ZnS1 calibration material, measurements were performed using EPMA, solution ICP‐MS, ICP‐OES and LA‐ICP‐MS. The results show that MUL‐ZnS‐1 is an appropriate material for calibrating trace element determination in sphalerite using LA‐ICP‐MS.  相似文献   

12.
Data on the major and trace element chemistry of a suite oftwenty pantelleritic pitchstone lavas from the Quaternary Ethiopianvolcano Fantale is presented. This reveals a contrast betweenthe composition of the pre-caldera flows and the more siliceous,less peralkaline post-caldera lavas. Comparison with experimental and theoretical studies suggeststhat nearly all of the major and trace element variation withinthe two suites can be explained by assuming fractional crystallizationof alkali-feldspar, the most abundant phenocryst phase. Fractionationof the mafic phases appears to have been less significant. The trace element data strongly indicate that the lavas allbelong to a single suite. However, it is suggested that themajor element chemistry of the post-caldera flows was modifiedby the loss of volatiles at the time of the formation of thecaldera, an event which coincided with the eruption of a 2 km3welded ash-flow tuff.  相似文献   

13.
宝山-桃行榴辉岩呈透镜状包体赋存于荣成花岗质片麻岩套（Chgg）内,通过榴辉岩主量元素地球化学、微量元素及稀土元素地球化学、石榴子石矿物化学分析,确定榴辉岩原岩为壳成变质成因,具有岛弧拉斑玄武岩（IAT）特征.宝山-桃行榴辉岩是其原岩与围岩一起经过高温高压变质作用而形成.  相似文献   

14.
Fan  Jian-Jun  Li  Cai  Liu  Jin-Heng  Wang  Ming  Liu  Yi-Ming  Xie  Chao-Ming 《International Journal of Earth Sciences》2018,107(5):1755-1775
International Journal of Earth Sciences - In this paper, we present new major and trace element chemical data for the basalts and phonolites of the Nare ocean island fragment (NaOI), as well as...  相似文献   

15.
The mafic granulites from the Northern Apennines commonly containsignificant amounts of either olivine or Fe–Ti-oxide phases.On the basis of mineralogy and whole-rock major and trace elementcompositions, their protoliths are recognized as cumulus rocksderived from variably evolved tholeiitic liquids. Clinopyroxenesfrom the olivine-bearing rocks show peculiar trace element compositions(e.g. low amounts of Cr, Zr and lanthanides, coupled with relativelyhigh Sr concentrations) that record a process of granulite-faciestrace element redistribution controlled by a reaction betweenolivine and plagioclase. The trace element compositions of clinopyroxenesfrom the Fe–Ti-oxide-bearing rocks point to igneous geochemicaltrends that argue for a common igneous parentage. The  相似文献   

16.
Abstract: In the present study, the major and trace element compositions, as well as Sr, Nd isotopic compositions and K-Ar age data in mafic dikes from Hainan Island, China, have been analyzed. Whole-rock K-Ar dating yielded a magmatic duration of 61–98 Ma for mafic dikes. Mafic dikes have a very high concentration of incompatible elements, for example, Ba, Rb, Sr, K, rare earth elements, and especially light rare earth elements (LREE), and negative anomalies of Nb, Ta, and Ti in the normalized trace element patterns. The initial 87Sr/86Sr ratios and εSr(t) of the mafic dikes are 0.70634–0.71193 and +27.7 to +112.2, respectively. In the 87Sr/86Sr versus εNd(t) diagram, the Hainan Island mafic dikes plot between fields for depleted mantle and enriched mantle type 2. All these characteristics show that the mantle (source region) of mafic dikes in this area experienced metasomatism by fluids relatively enriched in LREE and large ion lithophile elements. The genesis of Hainan Island mafic dikes is explained as a result of the mixing of asthenospheric mantle with lithospheric mantle that experienced metasomatism by the subduction of the Pacific Plate. This is different from the Hainan Island Cenozoic basalts mainly derived from depleted asthenospheric mantle, and possibly, minor metasomatised lithospheric mantle. This study suggests that the Mesozoic and Cenozoic lithospheric revolutions in Hainan Island can be divided into three stages: (1) the compression orogenesis stage before 98 Ma. The dominant factor during this stage is the subduction of the ancient Pacific Plate beneath this area. The lithospheric mantle changed into enriched mantle type 2 by metasomatism; (2) the thinning and extension stage during 61–98 Ma. The dominant factor during this stage is that the asthenospheric mantle invaded and corroded the lithospheric mantle; and (3) the large-scale thinning and extension stage after 61 Ma. The large-scale asthenospheric upwelling results in the strong erupting of Cenozoic basalts, large-scale thinning of the lithosphere, the southward translating and counterclockwise rotating of Hainan Island, and the opening of the South China Sea.  相似文献   

17.
基于贵州水城小牛井田晚二叠世煤样的全硫分、微量元素、常量元素等测试数据,探讨了煤中元素富集特征及其与陆源碎屑的关系,重点是全硫分、微量元素对古海平面变化的反演。结果表明,小牛井田煤中常量元素Si、Ca、Mg、Ti、K含量高于中国煤均值,Al、Fe、Na含量低于中国煤均值;与地壳克拉克值相比,煤中微量元素只有B和Mo相对富集;煤中微量元素的富集在一定程度上受控于陆源碎屑,常量元素对陆源碎屑也有一定的继承性。煤中全硫分及微量元素B、Co、Cr、Cu、Ga、Ge、Mo、Ni、Pb、Sr、V、Zn的纵向变化规律可以用来反演古海平面变化,海退时形成的煤层全硫分及微量元素含量较低,海侵时形成的煤层全硫分及微量元素含量较高。   相似文献   

18.
In an effort to obtain information about mineral/melt trace element partitioning during the high pressure petrogenesis of basic rocks, we determined rare earth and other trace element abundances in megacrysts of clinopyroxene, orthopyroxene, amphibole, mica, anorthoclase, apatite and zircon, and in their host basalts. In general, the ranges of mineral/melt partition coefficients established from experimental partitioning studies and phenocryst/matrix measurements overlap with the ranges of megacryst/host abundance ratios. Our data for Hf, Sc, Ta and Th partitioning represent some of the only estimates available. Consideration of phase equilibria, major element partitioning and isotopic ratios indicate that most of the pyroxene and amphibole megacrysts may have been in equilibrium with their host magmas at high pressures (mostly 10–25 kb). In contrast, it is unlikely that mica, anorthoclase, apatite and zircon megacrysts formed in equilibrium with their host basalts; instead, we conclude that they were precipitated from more evolved magmas and have been mixed into their present host magmas. Consequently, the trace element abundance ratios for megacryst/host should not be interpreted as partition coefficients, but only as guides for understanding trace element partitioning during high pressure petrogenesis. With this caveat, we conclude that the megacryst/ host trace element abundance data indicate that mineral/melt partition coefficients in basaltic systems during high pressure fractionation are not drastically different from partition coefficients valid for low pressure fractionation.  相似文献   

19.
Lavas and pyroclastic rocks throughout the volcanic stratigraphy of the Tertiary-Quaternary volcanic complex of Thera in the Aegean island arc display inhomogenous plagioclase populations and phenocryst resorption textures, interpreted as indicative of magma mixing. Plagioclase zoning characteristics studied by Nomarski and laser interferometry techniques establish three main categories of plagioclase: (i) inherited plagioclase (nucleated in endmember prior to initial mixing event) (ii) in situ plagioclase (nucleated in mixed or hybrid magma) and (iii) xenocrystic plagioclase. Nomarski contrast images and linearized compositional zoning profiles reveal striking differences between calcic and sodic plagioclases, depending on the composition of the lava in which they are hosted. These differences reflect the contrasting effects of changes in physical-chemical parameters in basic vis-a-vis more acidic melts during magma mixing and/or influx of new magma into the subvolcanic magma chamber, as well as the influence of magma chamber dynamics on plagioclase equilibration. Variations in bulk major and trace element abundances of Thera volcanic products reflect the dominant overprint of crystal fractionation, but decoupling between major and trace element fractionation models and variations in incompatible trace element distributions are all indicative of magma mixing processes, consistent with compositional and textural zoning in plagioclases.  相似文献   

20.
Late Pleistocene tephras derived by large explosive volcanic eruptions are widespread in the Mediterranean and surrounding areas. They are important isochronous markers in stratigraphic sections and therefore it is important to constrain their sources. We report here tephrochronology results using multiple criteria to characterize the volcanic products of the Late Pleistocene Ciomadul volcano in eastern–central Europe. This dacitic volcano had an explosive eruption stage between 57 and 30 ka. The specific petrological character (ash texture, occurrence of plagioclase and amphibole phenocrysts and their compositions), the high-K calc-alkaline major element composition and particularly the distinct trace element characteristics provide a strong fingerprint of the Ciomadul volcano. This can be used for correlating tephra and cryptotephra occurrences within this timeframe. Remarkably, during this period several volcanic eruptions produced tephras with similar glass major element composition. However, they differ from Ciomadul tephras by glass trace element abundances, ratios of strongly incompatible trace elements and their mineral cargo that serve as discrimination tools. We used (U-Th)/He zircon dates combined with U-Th in situ rim dates along with luminescence and radiocarbon dating to constrain the age of the explosive eruptions of Ciomadul that yielded distal tephra layers but lack of identified proximal deposits.  相似文献   

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