首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
In the history of Mars exploration its atmosphere and planetary climatology aroused particular interest. In the study of the minor gases abundance in the Martian atmosphere, water vapour became especially important, both because it is the most variable trace gas, and because it is involved in several processes characterizing the planetary atmosphere. The water vapour photolysis regulates the Martian atmosphere photochemistry, and so it is strictly related to carbon monoxide. The CO study is very important for the so-called “atmosphere stability problem”, solved by the theoretical modelling involving photochemical reactions in which the H2O and the CO gases are main characters.The Planetary Fourier Spectrometer (PFS) on board the ESA Mars Express (MEX) mission can probe the Mars atmosphere in the infrared spectral range between 200 and 2000 cm?1 (5–50 μm) with the Long Wavelength Channel (LWC) and between 1700 and 8000 cm?1 (1.2–5.8 μm) with the Short Wavelength Channel (SWC). Although there are several H2O and CO absorption bands in the spectral range covered by PFS, we used the 3845 cm?1 (2.6 μm) and the 4235 cm?1 (2.36 μm) bands for the analysis of water vapour and carbon monoxide, respectively, because these ranges are less affected by instrumental problems than the other ones. The gaseous concentrations are retrieved by using an algorithm developed for this purpose.The PFS/SW dataset used in this work covers more than two and a half Martian years from Ls=62° of MY 27 (orbit 634) to Ls=203° of MY 29 (orbit 6537). We measured a mean column density of water vapour of about 9.6 pr. μm and a mean mixing ratio of carbon monoxide of about 990 ppm, but with strong seasonal variations at high latitudes. The seasonal water vapour map reproduces very well the known seasonal water cycle. In the northern summer, water vapour and CO show a good anticorrelation most of the time. This behaviour is due to the carbon dioxide and water sublimation from the north polar ice cap, which dilutes non-condensable species including carbon monoxide. An analogous process takes place during the winter polar cap, but in this case the condensation of carbon dioxide and water vapour causes an increase of the concentration of non-condensable species. Finally, the results show the seasonal variation of the carbon monoxide mixing ratio with the surface pressure.  相似文献   

2.
This work presents an algorithm for the scientific analysis of individual calibrated measurements from the Planetary Fourier spectrometer (PFS).The instrument, included in the scientific payload of the ESA Mars Express mission to Mars, acquires spectra in the range between 250 and 8200 cm−1, with a sampling step of ∼1 cm−1 and an effective resolution of ∼2 cm−1. The observed radiance depends on several parameters of the atmosphere and surface of Mars as described by the radiative transfer equation. Adopting the very general formalism of Bayesian analysis, we determined which quantities are actually retrievable from individual measurements. Namely, they are: the surface temperature, the column density of dust and water ice aerosols in the atmosphere, the air temperature as a function of altitude (in the indicative range 5-45 km above the surface), the surface pressure, and the column density of water vapor and carbon monoxide. These evaluations are carried out taking into account the noise equivalent radiance (NER) of the instrument and the natural variabilities of the investigated parameters in the Martian environment, as estimated from the expectations of the European Martian Climate Dataset v3.1 (EMCD). Other parameters included in the radiative transfer equation shall be assumed as known, because they are not retrievable from individual measurements due to the instrumental NER or an underconstrained inverse problem: the surface emissivity in the thermal infrared, the optical properties of suspended dust and the analytical shape of dust concentration vs. altitude.During the development of the algorithm devoted to these studies, different approaches were evaluated on the basis of formal, computational and scientific considerations, with the aim to develop the general design of an integrated software package.The resulting code was extensively tested on a wide set of simulated PFS spectra. These spectra were computed from the atmospheric and surface conditions extracted from the EMCD, assumed to be representative of the Martian environment for different values of latitude, local time and season. Their comparison with the retrievals from simulated observations allowed us to evaluate the systematic and random errors affecting the procedures with respect to the different quantities involved. The code evaluates the surface temperature with an error in the order of 1 K, while the vertical air temperature profile is computed with an uncertainty less than 2 K from in the region between 5 and 20 km above the surface, increasing up to 7 K at 50 km. The column opacity of dust, measured in terms of integrated optical thickness at 1100 cm−1, is computed with an error of around 0.13. The surface pressure determination is carried out with a typical uncertainty of 0.2-0.3 millibar. Several auxiliary tests allowed us to study the correlations between the different retrieval errors and the possible causes of incorrect PFS data interpretation. The choice of a suitable model for the dust optical properties is demonstrated to be particularly critical.This paper also presents the first discussion about application of the procedure to actual PFS Martian data. Despite the calibration issues still affecting the determination of absolute radiance in the near-infrared, the algorithm is able to achieve a satisfactory modeling of observations in a wide range of situations.  相似文献   

3.
Despite the fact that microbial cells are unlikely to be found in the Martian soil in the near future, this paper is written on the assumption that some of the seasonally varying concentration of Martian methane is due to ongoing methanogenesis. It is first pointed out that life might have arisen on Mars first and been transported to Earth later. A case is made that an icy origin of life is more likely than a hot origin, especially if biomolecules take advantage of the high encounter rates and stability against hydrolysis, and that microorganisms feed on the ions that comprise eutectic solutions in ice. Although certain difficulties are avoided if RNA and DNA grow while adsorbed on clay grains, double strand-breaks of microbial DNA due to alpha radioactivity are a far greater threat to microbial survival on clay or other rock types than in ice. Developing a relation between the rate of microbial metabolism in ice and the experimentally determined rate of production of trapped gases of microbial origin, one can estimate the concentration of methanogens that could account for the methane production rate as a function of temperature of their habitat. The result, of order 1 cell cm−3 in the Martian subsurface, seems an attainable goal provided samples are taken from at least 1 or 2 m below the hostile surface of Mars. Instruments on NASA’s 2011 Mars Science Lab will measure stable isotopes for methane, water, and carbon dioxide, which on Earth served to distinguish abiotic, thermogenic, and microbial origins. Future measurements of chirality of biomolecules might also provide evidence for Martian life.  相似文献   

4.
The Mars Atmosphere-Ice Coupler MAIC-2 is a simple, latitudinal model, which consists of a set of parameterisations for the surface temperature, the atmospheric water transport and the surface mass balance (condensation minus evaporation) of water ice. It is driven directly by the orbital parameters obliquity, eccentricity and solar longitude (Ls) of perihelion. Surface temperature is described by the Local Insolation Temperature (LIT) scheme, which uses a daily and latitude-dependent radiation balance. The evaporation rate of water is calculated by an expression for free convection, driven by density differences between water vapor and ambient air, the condensation rate follows from the assumption that any water vapour which exceeds the local saturation pressure condenses instantly, and atmospheric transport of water vapour is approximated by instantaneous mixing. Glacial flow of ice deposits is neglected. Simulations with constant orbital parameters show that low obliquities favour deposition of ice in high latitudes and vice versa. A transient scenario driven by a computed history of orbital parameters over the last 10 million years produces essentially monotonically growing polar ice deposits during the most recent 4 million years, and a very good agreement with the observed present-day polar layered deposits. The thick polar deposits sometimes continue in thin ice deposits which extend far into the mid latitudes, which confirms the idea of “ice ages” at high obliquity.  相似文献   

5.
John E. Moores  Peter H. Smith 《Icarus》2011,211(2):1129-1149
A chamber was constructed to simulate the boundary between the ice table, regolith and atmosphere of Mars and to examine fractionation between H2O and HDO during sublimation under realistic martian conditions of temperature and pressure. Thirteen experimental runs were conducted with regolith overlying the ice. The thickness and characteristic grain size of the regolith layer as well as the temperature of the underlying ice was varied. From these runs, values for the effective diffusivity, taking into account the effects of adsorption, of the regolith were derived. These effective diffusivities ranged from 1.8 × 10−4 m2 s−1 to 2.2 × 10−3 m2 s−1 for bare ice and from 2.4 × 10−11 m2 s−1 to 2.0 × 10−9 m2 s−1 with an adsorptive layer present. From these, latent heats of adsorption of 8.6 ± 2.6 kJ mol−1 and 9.3 ± 2.8 kJ mol−1 were derived at ice-surface temperatures above 223 ± 8 K and 96 ± 28 kJ mol−1 and 104 ± 31 kJ mol−1 respectively for H2O and HDO were derived at colder temperatures. For temperatures below 223 K, the effective diffusivity of HDO was found to be lower than the diffusivity of H2O by 40% on average, suggesting that the regolith was adsorptively fractionating the sublimating gas with a fractionation factor of 1.96 ± 0.74. Applying these values to Mars predicts that adsorbed water on the regolith is enriched in HDO compared to the atmosphere, particularly where the regolith is colder. Based on current observations, the D/H ratio of the regolith may be as high as 21 ± 8 times VSMOW at 12°S and LS = 357° if the regolith is hydrated primarily by the atmosphere, neglecting any hydration from subsurface ice.  相似文献   

6.
Mid- and far-infrared spectra from the Composite InfraRed Spectrometer (CIRS) have been used to determine volume mixing ratios of nitriles in Titan's atmosphere. HCN, HC3N, C2H2, and temperature were derived from 2.5 cm−1 spectral resolution mid-IR mapping sequences taken during three flybys, which provide almost complete global coverage of Titan for latitudes south of 60° N. Three 0.5 cm−1 spectral resolution far-IR observations were used to retrieve C2N2 and act as a check on the mid-IR results for HCN. Contribution functions peak at around 0.5-5 mbar for temperature and 0.1-10 mbar for the chemical species, well into the stratosphere. The retrieved mixing ratios of HCN, HC3N, and C2N2 show a marked increase in abundance towards the north, whereas C2H2 remains relatively constant. Variations with longitude were much smaller and are consistent with high zonal wind speeds. For 90°-20° S the retrieved HCN abundance is fairly constant with a volume mixing ratio of around 1 × 10−7 at 3 mbar. More northerly latitudes indicate a steady increase, reaching around 4 × 10−7 at 60° N, where the data coverage stops. This variation is consistent with previous measurements and suggests subsidence over the northern (winter) pole at approximately 2 × 10−4 m s−1. HC3N displays a very sharp increase towards the north pole, where it has a mixing ratio of around 4 × 10−8 at 60° N at the 0.1-mbar level. The difference in gradient for the HCN and HC3N latitude variations can be explained by HC3N's much shorter photochemical lifetime, which prevents it from mixing with air at lower latitude. It is also consistent with a polar vortex which inhibits mixing of volatile rich air inside the vortex with that at lower latitudes. Only one observation was far enough north to detect significant amounts of C2N2, giving a value of around 9 × 10−10 at 50° N at the 3-mbar level.  相似文献   

7.
The infrared AOTF spectrometer is a part of the SPICAM experiment onboard the Mars-Express ESA mission. The instrument has a capability of solar occultations and operates in the spectral range of 1-1.7 μm with a spectral resolution of ∼3.5 cm−1. We report results from 24 orbits obtained during MY28 at Ls 130°-160°, and the latitude range of 40°-55° N. For these orbits the atmospheric density from 1.43 μm CO2 band, water vapor mixing ratio based on 1.38 μm absorption, and aerosol opacities were retrieved simultaneously. The vertical resolution of measurements is better than 3.5 km. Aerosol vertical extinction profiles were obtained at 10 wavelengths in the altitude range from 10 to 60 km. The interpretation using Mie scattering theory with adopted refraction indices of dust and H2O ice allows to retrieve particle size (reff∼0.5-1 μm) and number density (∼1 cm−3 at 15-30 km) profiles. The haze top is generally below 40 km, except the longitude range of 320°-50° E, where high-altitude clouds at 50-60 km were detected. Optical properties of these clouds are compatible with ice particles (effective radius reff=0.1-0.3 μm, number density N∼10 cm−3) distributed with variance νeff=0.1-0.2 μm. The vertical optical depth of the clouds is below 0.001 at 1 μm. The atmospheric density profiles are retrieved from CO2 band in the altitude range of 10-90 km, and H2O mixing ratio is determined at 15-50 km. Unless a supersaturation of the water vapor occurs in the martian atmosphere, the H2O mixing ratio indicates ∼5 K warmer atmosphere at 25-45 km than predicted by models.  相似文献   

8.
David Andrew Fisher 《Icarus》2007,187(2):430-441
A time varying stable isotope model for the D/H history of Mars water cycle is developed with variable atmosphere, space loss rate, ground and ice cap flux rates. It considers coupled ground reservoirs and traces D/H in the air and reservoirs secularly and over obliquity cycles. The various flux rates are prescribed time variables that simulate surface flux, and solar driven space loss rates. Predicted bulk averages for the ice cap, ground ice reservoirs and atmosphere span the observed ranges reported by Mumma et al. [Mumma, M.J., Novak, R.E., DiSanti, M.A., Bonev, B., Dello Russo, N., Magee-Sauer, K., 2003. The Martian Atmosphere. Conference Reports of “Sixth International Conference on Mars Atmosphere,” No. 3186]. When the dominant obliquity cycle variations are scaled so that the model delivers present seasonal variations, the present long term bulk D/H average for the ice cap is ∼+2.7 (equivalent to +1700‰ in δ(D) wrt SMOW). The obliquity driven D/H cycle in the ice cap's layers varies between 3 and 6. The smaller more accessible reservoirs have larger bulk averages with the smallest being able to reach D/H values over 9 within ∼105 years. Small hypothetical solar activity driven variations in the escape rate to space and in the fractionation constant [Krasnopolsky, V.A., Feldman, P.D., 2001. Science 294, 1914-1917] for the escape process can produce a “solar wiggle” whose D/H amplitude can reach 0.1 (δ(D) amplitude of 100‰). Because of the temporal variability, a single modern measured atmospheric D/H ratio at a particular Ls cannot tell very much about the total water inventory of Mars. A bulk average for the Northern Ice Cap and better still a dated vertical profile of D/H from the ice cap would, however, go a long way towards illuminating the “modern” water history of Mars. The age and stability of the Northern Ice Cap and the D/H history locked in the layering is discussed. An ice cap that is very young and exchanges its mass through the atmosphere often will necessarily have a large D/H.  相似文献   

9.
An AOST Fourier spectrometer of the Phobos-Soil project is intended for studying Mars and Phobos by means of measurements of IR radiation spectra of the Martian surface and atmosphere, the Phobos surface, and the spectrum of solar radiation passing through the Martian atmosphere on its limb. The main scientific problems to be solved with the spectrometer on Mars are measurements of methane content, search for minor constituents, and study of diurnal variations in the temperature and atmospheric aerosol. The spectrometer will also study the Martian and Phobos surface both remotely and after landing. The spectral range of the instrument is 2.5?C25 ??m, the best spectral resolution (without apodization) is 0.6 cm?1, and the instantaneous field of view is 2.5°. The recording time of one spectrum is equal to 5 s in solar observations and 50 s in observations of Mars and Phobos. The instrument has self-thermal stabilization and two-axis pointing systems, as well as a built-in radiation source for flight calibration. The spectrometer mass is 4 kg, and power consumption is up to 13 W. Scientific problems, measurement modes, and, briefly, engineering implementation of the experiment are discussed in this work.  相似文献   

10.
Takeshi Imamura  Yuko Ito 《Icarus》2011,211(1):498-503
A Hovmöller diagram analysis of the dust optical depth measured by the Mars Global Surveyor Thermal Emission Spectrometer shows the occurrence of quasi-periodic westwardly-propagating disturbances with timescales of 10-20 sols during summer in the south polar region of Mars. Dust clouds emerge repeatedly around the region with a latitude of around 70-80°S and a longitude of 240-300°E, move westward at speeds of 3-6 m s−1, reach the region with a longitude of 60-120°E, and finally disappear. This longitude range coincides with elevated terrains in the south polar region, and in this region an increase of dust optical depth encircling the south pole is also observed. This implies that the quasi-periodic dust events will contribute to the enhancement of the atmospheric dust loading in this region. These dust events might be related to baroclinic instability caused by the thermal contrast across the CO2 cap edge, or the horizontal advection or vertical convection with radiative-dynamical feedback. The westward movement of the dust clouds suggests steady westward winds blowing in the near-surface layer, where the quasi-periodic dust lifting is expected to occur. Such a westward cap-edge flow will be created by the Coriolis force acting on the flow from the ice side to the regolith side.  相似文献   

11.
Valles Marineris offers a deep natural insight into the upper crust of Mars. The morphology of its slopes reflects the properties of the wall materials, thus constraining in models of composition and evolution of the upper layers of the Martian crust. Hence, knowledge about the lithological composition of these wall rocks is of major interest to the understanding of the geological and climatic history of Mars. This study investigates mechanical rock mass parameters of the northern wall of eastern Candor Chasma (between 290°E and 296°E longitude, −8° to −5° latitude). These are inferred from its present-day morphology and a proposed slope-forming history, applying a distinct element code to simulate the stability and the tectonic history of this slope within a parameter study. Additionally, a mathematical denudation model is applied to take into account the effect of exogenic processes on the slope. The study results show that two periods of normal faulting in conjunction with massive interim denudational scarp recess is a valid model for the evolution of the northern wall of eastern Candor Chasma. The estimated rate of scarp recess of 60 m Myr−1 is comparable with certain terrestrial scarp retreat rates. The best-fit models yield a homogenous distribution of low-level rock mass strength and deformability properties distributed over the entire stratigraphic column of the northern wall of eastern Candor Chasma. The values are 5.0 (±0.7) MPa for the uniaxial compressive strength, 1.6 (±0.2) MPa for the Brazilian tensile strength, 4.7 (±1.5) GPa for the Young's modulus, 0.2 (±0.15) for the Poisson's ratio, 22 (±2)° for the internal friction angle, 1.6 (±0.2) MPa for the cohesion and 2200 (±500) kg m−3 for the density. This study favors columnar jointed basalt as the material that builds up the northern wall of eastern Candor Chasma and other walls within central Valles Marineris. The best-fit denudational model of the upper slope section of the northern wall of eastern Candor Chasma indicates a distinct cap rock unit of lesser susceptibility to denudation than the wall rock below.  相似文献   

12.
Helium concentrations in the Martian atmosphere are estimated assuming that the helium production on Mars, comparable to its production on Earth, via the radioactive decay of uranium and thorium, is in steady state equilibrium with its thermal escape. Although non-thermal losses would tend to reduce the estimated concentrations, these concentrations are not necessarily an upper limit since higher production rates and/or a possibly lower effective exospheric temperature over the solar activity cycle could increase them to even higher values. The computed helium concentration at the Martian exobase (200 km) is 8 × 106 atoms cm?3. Through the lower exosphere, the computed helium concentrations are 30–200 times greater than the Mariner-measured atomic hydrogen concentrations. It follows that helium may be the predominant constituent in the Martian lower exosphere and may well control the orbital lifetime of Mars-orbiting spacecraft. The estimated helium mixing ratio is greater at the Martian turbopause than at the terrestrial turbopause, and the helium column density in the lower Martian atmosphere may be comparable to that on Earth.  相似文献   

13.
Mars was observed near the peak of the strongest SO2 band at 1364-1373 cm−1 with resolving power of 77,000 using the Texas Echelon Cross Echelle Spectrograph on the NASA Infrared Telescope Facility. The observation covered the Tharsis volcano region which may be preferable to search for SO2. The spectrum shows absorption lines of three CO2 isotopomers and three H2O isotopomers. The water vapor abundance derived from the HDO lines assuming D/H = 5.5 times the terrestrial value is 12±1.0 pr. μm, in agreement with the simultaneous MGS/TES observations of 14 pr. μm at the latitudes (50° S to 10° N) of our observation. Summing of spectral intervals at the expected positions of sixteen SO2 lines puts a 2σ upper limit on SO2 of 1 ppb. SO2 may be emitted into the martian atmosphere by seepage and is removed by three-body reactions with OH and O. The SO2 lifetime, 2 years, is longer than the global mixing time 0.5 year, so SO2 should be rather uniformly distributed across Mars. Seepage of SO2 is less than 15,000 tons per year on Mars which is smaller than the volcanic production of SO2 on the Earth by a factor of 700. Because CH4/SO2 is typically 10−4-10−3 in volcanic gases on the Earth, our results show seepage is unlikely to be the source of the recently discovered methane on Mars and therefore strengthen its biogenic origin.  相似文献   

14.
Recent geological observations in the northern mid-latitudes of Mars show evidence for past glacial activity during the late Amazonian, similar to the integrated glacial landsystems in the Dry Valleys of Antarctica. The large accumulation of ice (many hundreds of meters) required to create the observed glacial deposits points to significant atmospheric precipitation, snow and ice accumulation, and glacial flow. In order to understand the climate scenario required for these conditions, we used the LMD (Laboratoire de Météorologie Dynamique) Mars GCM (General Circulation Model), which is able to reproduce the present-day water cycle, and to predict past deposition of ice consistent with geological observations in many cases. Prior to this analysis, however, significant mid-latitude glaciation had not been simulated by the model, run under a range of parameters.In this analysis, we studied the response of the GCM to a wider range of orbital configurations and water ice reservoirs, and show that during periods of moderate obliquity (? = 25-35°) and high dust opacity (τdust = 1.5-2.5), broad-scale glaciation in the northern mid-latitudes occurs if water ice deposited on the flanks of the Tharsis volcanoes at higher obliquity is available for sublimation. We find that high dust contents of the atmosphere increase its water vapor holding capacity, thereby moving the saturation region to the northern mid-latitudes. Precipitation events are then controlled by topographic forcing of stationary planetary waves and transient weather systems, producing surface ice distribution and amounts that are consistent with the geological record. Ice accumulation rates of ∼10 mm yr−1 lead to the formation of a 500-1000 m thick regional ice sheet that will produce glacial flow patterns consistent with the geological observations.  相似文献   

15.
The LIDAR instrument operating from the surface of Mars on the Phoenix Mission measured vertical profiles of atmospheric dust and water ice clouds at temperatures around −65 °C. An equivalent lidar system was utilized for measurements in the atmosphere of Earth where dust and cloud conditions are similar to Mars. Coordinated aircraft in situ sampling provided a verification of lidar measurement and analysis methods and also insight for interpretation of lidar derived optical parameters in terms of the dust and cloud microphysical properties. It was found that the vertical distribution of airborne dust above the Australian desert is quite similar to what is observed in the planetary boundary layer above Mars. Comparison with the in situ sampling is used to demonstrate how the lidar derived optical extinction coefficient is related to the dust particle size distribution. The lidar measurement placed a constraint on the model size distribution that has been used for Mars. Airborne lidar measurements were also conducted to study cirrus clouds that form in the Earth’s atmosphere at a similar temperature and humidity as the clouds observed with the lidar on Mars. Comparison with the in situ sampling provides a method to derive the cloud ice water content (IWC) from the Mars lidar measurements.  相似文献   

16.
High-resolution infrared imaging spectroscopy of Mars has been achieved at the NASA Infrared Telescope Facility (IRTF) on June 19-21, 2003, using the Texas Echelon Cross Echelle Spectrograph (TEXES). The areocentric longitude was 206°. Following the detection and mapping of hydrogen peroxide H2O2 [Encrenaz et al., 2004. Icarus 170, 424-429], we have derived, using the same data set, a map of the water vapor abundance. The results appear in good overall agreement with the TES results and with the predictions of the Global Circulation Model (GCM) developed at the Laboratory of Dynamical Meteorology (LMD), with a maximum abundance of water vapor of 3±1.5×10−4(17±9 pr-μm). We have searched for CH4 over the martian disk, but were unable to detect it. Our upper limits are consistent with earlier reports on the methane abundance on Mars. Finally, we have obtained new measurements of CO2 isotopic ratios in Mars. As compared to the terrestrial values, these values are: (18O/17O)[M/E] = 1.03 ± 0.09; (13C/12C)[M/E] = 1.00 ± 0.11. In conclusion, in contrast with the analysis of Krasnopolsky et al. [1996. Icarus 124, 553-568], we conclude that the derived martian isotopic ratios do not show evidence for a departure from their terrestrial values.  相似文献   

17.
Laboratory spectra of methane-nitrogen mixtures have been recorded in the near-infrared range (1.0-1.65 μm) in conditions similar to Titan's near surface, to facilitate the interpretation of the DISR/DLIS (DISR—Descent Imager/Spectral Radiometer) spectra taken during the last phase of the descent of the Huygens Probe, when the surface was illuminated by a surface-science lamp. We used a 0.03 cm−1 spectral resolution, adequate to resolve the lines at high pressure (pN2∼1.5 bar). By comparing the laboratory spectra with synthetic calculations in the well-studied ν2+2ν3 band (7515-7620 cm−1), we determine a methane absorption column density of 178±20 cm atm and a temperature of 118±10 K in our experiment. From this, we derive the methane absorption coefficients over 1.0-1.65 μm with a 0.03 cm−1 sampling, allowing for the extrapolation of the results to any other methane column density under the relevant pressure and temperature conditions. We then revisit the calibration and analysis of the Titan “lamp-on” DLIS spectra. We infer a 5.1±0.8% methane-mixing ratio in the first 25 m of Titan's atmosphere. The CH4 mixing ratio measured 90 s after landing from a distance of 45 cm is found to be 0.92±0.25 times this value, thus showing no post-landing outgassing of methane in excess of ∼20%. Finally, we determine the surface reflectivity as seen between 25 m and 45 cm and find that the 1500 nm absorption band is deeper in the post-landing spectrum as compared to pre-landing.  相似文献   

18.
This paper reports on mapping of water frost and ice on Mars, in the range of latitudes between 30°S and 30°N. The study has been carried out by analysing 2485 orbits acquired during almost one martian year by the Mars Express/OMEGA imaging spectrometer. Water frost/ice is identified by the presence of ∼1.5 μm, ∼2 μm and ∼3.0 μm absorptions. Although the orbits analysed in this study cover all seasons, water frost/ice is observed only near the aphelion seasons, at Ls = 19° and at Ls = 98-150°. Water frost/ice is detected mainly on the southern hemisphere between 15°S and 30°S latitude while it has not been identified within 15°S-15°N. In the northern hemisphere, the water frost/ice detection is complicated by the presence of clouds. Usually, water frost/ice is found in shadowed areas, while in few cases it is exposed to the sunlight. This indicates a clear relationship with the local illumination conditions on the slopes which favour the water frost/ice deposition on the surface when the temperatures are very low. OMEGA observations span from 10 to 17 LT and the frost/ice is detected mainly between 15 and 16 LT, with practically no detection before 13 LT. We think this is due to the fact that the 10-12 LT observations occur at large distances and it is not a local time effect. A thermal model is used to determine the deposition conditions on the sloped surfaces where water frost/ice has been found. There, daily atmospheric saturation does not occur on pole facing 10-25° slopes with current water vapour abundances but only by assuming values greater than 40 pr μm. Moreover, the water frost/ice is not detected during the northern winter, even if the thermal model foresees daily saturation on 25° slopes.  相似文献   

19.
Eric Chassefière 《Icarus》2009,204(1):137-271
The observations of methane made by the PFS instrument onboard Mars Express exhibit a definite correlation between methane mixing ratio, water vapor mixing ratio, and cloud optical depth. The recent data obtained from ground-based telescopes seem to confirm the correlation between methane and water vapor. In order to explain this correlation, we suggest that the source of gaseous methane is atmospheric, rather than at the solid surface of the planet, and that this source may consist of metastable submicronic particles of methane clathrate hydrate continuously released to the atmosphere from one or several clathrate layers at depth, according to the phenomenon of “anomalous preservation” evidenced in the laboratory. These particles, lifted up to middle atmospheric levels due to their small size, and therefore filling the whole atmosphere, serve as condensation nuclei for water vapor. The observed correlation between methane and water vapor mixing ratios could be the signature of the decomposition of the clathrate crystals by condensation-sublimation processes related to cloud activity. Under the effect of water condensation on crystal walls, metastability could be broken and particles be eroded, resulting in a subsequent irreversible release of methane to the gas phase. Using PFS data, and according to our hypothesis, the lifetime of gaseous methane is estimated to be smaller than an upper limit of 6 ± 3 months, much smaller than the lifetime of 300 yr calculated from atmospheric chemical models. The reason why methane has a short lifetime might be the occurrence of heterogeneous chemical decomposition of methane in the subsurface, where it is known since Viking biology experiments that oxidants efficiently decompose organic matter. If true, it is shown by using existing models of H2O2 penetration in the regolith that methane could prevent H2O2 from penetrating in the subsurface, and further oxidizing the soil, at depths larger than a few millimeters. The present source of methane clathrate, acting over the last few hundred thousand or million years, could have given rise to the thin CO2-ice layer covering the permanent water ice south polar cap. The hypothesis proposed in this paper requires, to be validated, a number of laboratory experiments studying the stability of methane clathrates in martian atmospheric conditions, and the kinetics and amplitude of clathrate particle erosion in presence of condensing water vapor. Detailed future observations of methane, and associated modeling, will allow to more accurately quantify the production rate of methane clathrate, its temporal variability at seasonal scale, and possibly to locate the source(s) of clathrates at the surface.  相似文献   

20.
The near-infrared reflectance spectra of the martian surface present strong absorption features attributed to hydration water present in the regolith. In order to characterize the relationships between this water and atmospheric vapor and decipher the physical state of water molecules in martian regolith analogs, we designed and built an experimental setup to measure near-IR reflectance spectra under martian atmospheric conditions. Six samples were studied that cover part of the diversity of Mars surface mineralogy: a hydrated ferric oxide (ferrihydrite), two igneous samples (volcanic tuff, and dunite sand), and three potential water rich soil materials (Mg-sulfate, smectite powder and a palagonitic soil, the JSC Mars-1 regolith stimulant). Sorption and desorption isotherms were measured at 243 K for water vapor pressure varying from 10−5 to ∼0.3 mbar (relative humidity: 10−4 to 75%). These measurements reveal a large diversity of behavior among the sample suite in terms of absolute amount of water adsorbed, shape of the isotherm and hysteresis between the adsorption and desorption branches. Simultaneous in situ spectroscopic observations permit a detailed analysis of the spectral signature of adsorbed water and also point to clear differences between the samples. Ferric (oxy)hydroxides like ferrihydrite or other phases present in palagonitic soils are very strong water adsorbent and may play an important role in the current martian water cycle by allowing large exchange of water between dust-covered regions and atmosphere at diurnal and seasonal scales.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号