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1.
Abstract— Detailed laboratory studies have been carried out in order to simulate the interaction between nanometer‐sized kamacite metal particles and different gas mixtures consisting of H2:H2S (250:0.1), H2:CO (250:1), and H2:CO:H2S (250:1:0.1) under nebular‐type conditions (5 × 10?4 atm and 473 K). Reaction of H2 + H2S with kamacite particles for 1000 h leads to the formation of pyrrhotite. Incorporation of CO into the gaseous reactant mixture results in the formation of both sulfide and carbide phases. At the same time, amorphous C is deposited onto the metal particles and organic molecules are evolved, namely hydrocarbons and thiols in the C1‐C5 and C1‐C2 range, respectively. Carbon deposition and production of organics are enhanced with respect to experiments performed with H2 + CO, where a carbide phase is formed. There is no evidence for the existence of S‐poisoning effects on the metal‐catalysed hydrogenation of CO through Fischer‐Tropsch‐type reactions in nebular environments. In fact, it is experimentally demonstrated that S‐containing organic species could be synthesized by such reactions from nebular gas.  相似文献   

2.
A global-mean model of coupled neutral and ion chemistry on Titan has been developed. Unlike the previous coupled models, the model involves ambipolar diffusion and escape of ions, hydrodynamic escape of light species, and calculates the H2 and CO densities near the surface that were assigned in some previous models. We tried to reduce the numbers of species and reactions in the model and remove all species and reactions that weakly affect the observed species. Hydrocarbon chemistry is extended to C12H10 for neutrals and C10H+11 for ions but does not include PAHs. The model involves 415 reactions of 83 neutrals and 33 ions, effects of magnetospheric electrons, protons, and cosmic rays. UV absorption by Titan's haze was calculated using the Huygens observations and a code for the aggregate particles. Hydrocarbon, nitrile, and ion chemistries are strongly coupled on Titan, and attempt to calculate them separately (e.g., in models of ionospheric composition) may result in significant error. The model densities of various species are typically in good agreement with the observations except vertical profiles in the stratosphere that are steeper than the CIRS limb data. (A model with eddy diffusion that facilitates fitting to the CIRS limb data is considered as well.) The CO densities are supported by the O+ flux from Saturn's magnetosphere. The ionosphere includes a peak at 80 km formed by the cosmic rays, steplike layers at 500-700 and 700-900 km and a peak at 1060 km (SZA = 60°). Nighttime densities of major ions agree with the INMS data. Ion chemistry dominates in the production of bicyclic aromatic hydrocarbons above 600 km. The model estimates of heavy positive and negative ions are in reasonable agreement with the Cassini results. The major haze production is in the reactions C6H + C4H2, C3N + C4H2, and condensation of hydrocarbons below 100 km. Overall, precipitation rate of the photochemical products is equal to 4-7 kg cm−2 Byr−1 (50-90 m Byr−1 while the global-mean depth of the organic sediments is ∼3 m). Escape rates of methane and hydrogen are 2.9 and 1.4 kg cm−2 Byr−1, respectively. The model does not support the low C/N ratio observed by the Huygens ACP in Titan's haze.  相似文献   

3.
C/2006 P1 McNaught is a dynamically new comet from the Oort cloud that passed very close to the Sun, driving overall volatile production rates up to about 1031 molecules s−1. Post-perihelion observations were obtained in a target-of-opportunity campaign using the CSHELL instrument at the NASA Infrared Telescope Facility atop Mauna Kea, Hawaii, on UT 2007 January 27 and 28. Eight parent volatiles (H2O, CH4, C2H2, C2H6, HCN, CO, NH3, H2CO) and two daughter fragments (OH and NH2) were detected, enabling the determination of a rotational temperature and production rate for H2O on UT January 27 and absolute and relative production rates for all the detected parent species on UT January 28. The chemical composition measured in the coma suggests that this close perihelion passage stripped off processed outer surface layers, likely exposing relatively fresh primordial material during these observations. The post-perihelion abundances we measure for CO and CH4 (relative to H2O) are slightly depleted while C2H2, NH2 and possibly NH3 are enhanced when compared to the overall comet population. Measured abundances for other detected molecular species were within the range typically observed in comets.  相似文献   

4.
Experimental results on the spectral identification of new infrared absorption features and the changes of their absorbances produced through vacuum ultraviolet-extreme ultraviolet (VUV-EUV) photon-induced chemical reactions in the C2H2-H2O mixed ices at 10 K are obtained. To the best of our knowledge, this is the first time that EUV photons have been employed in the study of the photolysis of ice analogues. Two different compositions, i.e., C2H2:H2O=1:4 and 1:1, were investigated in this work. A tunable intense synchrotron radiation light source available at the Synchrotron Radiation Research Center, Hsinchu, Taiwan, was employed to provide the required VUV-EUV photons. In this study, the photon wavelengths selected to irradiate the icy samples corresponded to the prominent solar hydrogen, helium, and helium ion lines at 121.6 nm, 58.4 nm, and 30.4 nm, respectively. The photon dosages used were typically in the range of 1×1015 to 2×1017 photons. Molecular species produced and identified in the ice samples at 10 K resulting from VUV-EUV photon irradiation are mainly CO, CO2, CH4, C2H6, CH3OH, and H2CO. In addition to several unidentified features, we have tentatively assigned several absorption features to HCO, C3H8, and C2H5OH. While new molecular species were formed, the original reactants, i.e., H2O and C2H2, were detectably depleted due to their conversion to other species. The new chemical species produced by irradiation of photons at 30.4 nm and 58.4 nm can be different from those produced by the 121.6-nm photolysis. In general, the product column density of CO reaches saturation at a lower photon dosage than that of CO2. Furthermore, the production yield of CO is higher than that of CO2 in the photon irradiation. In the present study, we also observe that the photon-induced chemical reaction yields are high using photons at 30.4 and 58.4 nm. The results presented in this work are essential to our understanding of chemical synthesis in ice analogues, e.g., the cometary-type ices and icy satellites of planetary systems.  相似文献   

5.
Abstract— Fischer‐Tropsch catalysis, by which CO and H2 are converted to CH4 on the surface of transition metals, has been considered to be one of the most important chemical reactions in many planetary processes, such as the formation of the solar and circumplanetary nebulae, the expansion of vapor clouds induced by cometary impacts, and the atmospheric re‐entry of vapor condensate due to asteroidal impacts. However, few quantitative experimental studies have been conducted for the catalytic reaction under conditions relevant to these planetary processes. In this study, we conduct Fischer‐Tropsch catalytic experiments at low pressures (1.3 times 10?4 bar ≤ P ≤ 5.3 times 10?1 bar) over a wide range of H2/CO ratios (0.25–1000) using pure iron, pure nickel, and iron‐nickel alloys. We analyze what gas species are produced and measure the CH4 formation rate. Our results indicate that the CH4 formation rate for iron catalysts strongly depends on both pressure and the H2/CO ratio, and that nickel is a more efficient catalyst at lower pressures and lower H2/CO ratios. This difference in catalytic properties between iron and nickel may come from the reaction steps concerning disproportionation of CO, hydrogenation of surface carbon, and the poisoning of the catalyst. These results suggest that nickel is important in the atmospheric re‐entry of impact condensate, while iron is efficient in circumplanetary subnebulae. Our results also indicate that previous numerical models of iron catalysis based on experimental data at 1 bar considerably overestimate CH4 formation efficiency at lower pressures, such as the solar nebula and the atmospheric re‐entry of impact condensate.  相似文献   

6.
T.Y Brooke  H.A Weaver  G Chin  S.J Kim 《Icarus》2003,166(1):167-187
High resolution infrared spectra of Comet C/1995 O1 (Hale-Bopp) were obtained during 2-5 March 1997 UT from the NASA Infrared Telescope Facility on Mauna Kea, Hawaii, when the comet was at r≈1.0 AU from the Sun pre-perihelion. Emission lines of CH4, C2H6, HCN, C2H2, CH3OH, H2O, CO, and OH were detected. The rotational temperature of CH4 in the inner coma was Trot=110±20 K. Spatial profiles of CH4, C2H6, and H2O were consistent with release solely from the nucleus. The centroid of the CO emission was offset from that of the dust continuum and H2O. Spatial profiles of the CO lines were much broader than those of the other molecules and asymmetric. We estimate the CO production rate using a simplified outflow model: constant, symmetric outflow from the peak position. A model of the excitation of CO that includes optical depth effects using an escape probability method is presented. Optical depth effects are not sufficient to explain the broad spatial extent. Using a parent+extended-source model, the broad extent of the CO lines can be explained by CO being produced mostly (∼90% on 5 March) from an extended source in the coma. The CO rotational temperature was near 100 K. Abundances relative to H2O (in percent) were 1.1±0.3 (CH4), 0.39±0.10 (C2H6), 0.18±0.04 (HCN), 0.17±0.04 (C2H2), 1.7±0.5 (CH3OH), and 37-41 (CO, parent+extended source). These are roughly comparable to those obtained for other long-period comets also observed in the infrared, though CO appears to vary.  相似文献   

7.
The neutral gas environment of a comet is largely influenced by dissociation of parent molecules created at the surface of the comet and collisions of all the involved species. We compare the results from a kinetic model of the neutral cometary environment with measurements from the Neutral Mass Spectrometer and the Dust Impact Detection System onboard the Giotto spacecraft taken during the fly-by at Comet 1P/Halley in 1986. We also show that our model is in good agreement with contemporaneous measurements obtained by the International Ultraviolet Explorer, sounding rocket experiments, and various ground based observations.The model solves the Boltzmann equation with a Direct Simulation Monte Carlo technique (Tenishev, V., Combi, M., Davidsson, B. [2008]. Astrophys. J. 685, 659-677) by tracking trajectories of gas molecules and dust grains under the influence of the comet’s weak gravity field with momentum exchange among particles modeled in a probabilistic manner. The cometary nucleus is considered to be the source of dust and the parent species (in our model: H2O, CO, H2CO, CO2, CH3OH, C2H6, C2H4, C2H2, HCN, NH3, and CH4) in the coma. Subsequently our model also tracks the corresponding dissociation products (H, H2, O, OH, C, CH, CH2, CH3, N, NH, NH2, C2, C2H, C2H5, CN, and HCO) from the comet’s surface all the way out to 106 km.As a result we are able to further constrain cometary the gas production rates of CO (13%), CO2 (2.5%), and H2CO (1.5%) relative to water without invoking unknown extended sources.  相似文献   

8.
A radiative seasonal model which incorporates a multilayer radiative transfer treatment at wave-lengths longward of 7 μm is presented and applied to Saturn's stratosphere. Opacities due to H2-He, CH4, C2H2, and C2H6 are included. Season-dependent insolation is shown to produce a strong hemispheric asymmetry decreasing with depth at the Voyager encounter times, and seasonal amplitudes of 30°K at the poles are predicted in the high stratosphere. The ring-modulated dependence of the insolation and the orbital eccentricity are shown to have a significant effect. Calculations agree closely with the Voyager 1 and 2 radio occultation ingress profiles recorded at 76°S and 36.5°S for CH4/H2 = 3.5 + 1.4/? 1.0 × 10?3;the estimated errors include modeling systematic errors and uncertainties in the occultations profiles. The possible role of aerosols in the stratospheric heating is analyzed. The Voyager 2 egress profile recorded at 31°S cannot be reproduced by calculations. Some constraints on the C2H2 and C2H6 abundances are derived. The upper portion of the occultation profiles (p < 3mbar) can be matched for C2H2/H2 = 1.0 + 1.3/?0.6 × 10?7, C2H6/H2 = 1.5 + 1.8/?0.9 × 10?6 at 76°S and C2H2/H2 = 4 + 6/?4 × 10?8, C2H6/H2 = 6 + 9/?6 × 10?7 at 36.5°N. At the northern occultation latitude, the discrepancy with the concentrations derived from analysis of IRIS spectra by R. Courtin, D. Gautier, A. Marten, B. Bézard, and R. Hanel (1984, Astrophys. J.287) can be explained by a sharp variation of the mixing ratios of these gases with altitude in the upper stratosphere. Other interpretations are discussed.  相似文献   

9.
The formation of methylamine (CH3NH2) in the upper troposphere and lower stratosphere of Jupiter is investigated. Translationally hot hydrogen atoms are produced in the photolysis of ammonia, phosphine, and acetylene which react with methane to produce methyl (CH3) radicals; the latter recombine with NH2 to form CH3NH2. Also, methane is catalytically dissociated to CH3 + H by the species C2 and C2H produced in the photolysis of acetylene. It is shown that the combined production of CH3NH2 and subsequent photolysis to HCN is unlikely to account for the HCN observed near Jupiter's tropopause. Recombination of NH2 and C2H5N followed by photolysis to HCN is the preferred path. Production of C2H6 by these two processes is negligible in comparison to the downward flux of C2H6 from the Lyman α photolysis region of CH4. An upper limit column density on CH3PH2 is estimated to be ～1013 cm?2 as compared to 1015 cm?2 for CH3NH2. Hot H atoms account for a negligible fraction of the total ortho-para conversion by the reaction H + H2  相似文献   

10.
Using pseudo-time-dependent models and three different reaction networks, a detailed study of the dominant reaction pathways for the formation of cyanopolyynes and their abundances in TMC-1 is presented. The analysis of the chemical reactions show that for the formation of cyanopolyynes there are two major chemical regimes. First, early times of less than ～104 yrs when ion-molecule reactions are dominant, the main chemical route for the formation of larger cyanopolyynes is $$C_n H^ + \xrightarrow{N}C_n N^ + \xrightarrow{{H_2 }}HC_n N^ + \xrightarrow{{H_2 }}H_2 C_n N^ + \xrightarrow{{e^ - }}HC_n N$$ wheren=5, 7, and 9. Second, at times greater than 104 yrs, when neutral-neutral reactions become dominant, two major reaction routes for the formation of cyanopolyynes are (a), $$HCN\xrightarrow{{C_2 H}}HC_3 N\xrightarrow{{C_2 H}}HC_5 N\xrightarrow{{C_2 H}}HC_7 N\xrightarrow{{C_2 H}}HC_9 N$$ and (b) $$C_n H_2 + CN \to HC_{n + 1} N + H,{\text{ }}n = 4,6, and 8$$ depending on the reaction network used. The results indicate that for route (a) large abundances ofC 2 H (fractional abundances of ～10?7), and for route (b) large abundances ofC 2 H 2 are required in order to reproduce the observed abundances of cyanopolyynes. The calculated abundances of cyanopolyynes show great sensitivity to the value of extinction particularly att?5×105 yrs (i.e. photochemical timescale). The effect of other physical parameters, such as the cosmic-ray ionization abundances are also examined. In general, the model calculations show that the observed abundances of cyanopolyynes can be achieved by pseudo-time-dependent models at late times of several million years.  相似文献   

11.
Ethane (C2H6), methylacetylene (CH3C2H or C3H4) and diacetylene (C4H2) have been discovered in Spitzer 10-20 μm spectra of Uranus, with 0.1-mbar volume mixing ratios of (1.0±0.1)×10−8, (2.5±0.3)×10−10, and (1.6±0.2)×10−10, respectively. These hydrocarbons complement previously detected methane (CH4) and acetylene (C2H2). Carbon dioxide (CO2) was also detected at the 7-σ level with a 0.1-mbar volume mixing ratio of (4±0.5)×10−11. Although the reactions producing hydrocarbons in the atmospheres of giant planets start from radicals, the methyl radical (CH3) was not found in the spectra, implying much lower abundances than in the atmospheres of Saturn or Neptune where it has been detected. This finding underlines the fact that Uranus' atmosphere occupies a special position among the giant planets, and our results shed light on the chemical reactions happening in the absence of a substantial internal energy source.  相似文献   

12.
The reactivity of C2(X1Σ+g) with simple saturated (CH4, C2H6 and C3H8) and unsaturated (C2H2 and C2H4) hydrocarbons has been studied in the gas phase over the temperature range 24-300 K using the CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme or Reaction Kinetics in a Uniform Supersonic Flow) technique. All reactions have been found to be very rapid in this temperature range and the rate coefficients are typically ?10−10 cm3 molecule−1 s−1 with the exception of methane for which the rate coefficient is one order of magnitude lower: ∼10−11 cm3 molecule−1 s−1. These results have been analyzed in terms of potential destruction sources of C2(X1Σ+g) in the atmospheres of Titan and the Giant Planets. It appears that the rate coefficient of the reaction 1C2 + CH4 should be updated with our new data and that reactions with C2H2, C2H4 and C2H6 should also be included in the existing photochemical models.  相似文献   

13.
We present near-IR (2.2-2.4 μm) reflectance and transmittance spectra of frozen (16 and 77 K) methanol (CH3OH) and water-methanol (1:1) mixtures before and after irradiation with 30 keV He+ and 200 keV H+ ions. Spectra of other simple hydrocarbons (CH4, C2H2, C2H4, C2H6) and CO have also been obtained both to help in the identification of the new molecules formed after ion irradiation of methanol-rich ices, and to get insight into the question of the presence of simple frozen hydrocarbons on the surface of some objects in the outer Solar System. The results confirm what obtained by studies performed in different spectral ranges, namely the ion-induced formation of CO and CH4, and, for the first time, evidence a strong decrease of the intensity of the methanol band at about 2.34 μm in comparison with that at 2.27 μm. The results are discussed in view of their relevance for icy objects in the Solar System (namely comets, Centaurs, and Kuiper belt objects) where CH3OH has been observed or suggested to be present.  相似文献   

14.
We have theoretically studied the influence of a far-infrared radiation (FIR) field from Hπ region on the cooling by C and O atoms, C+ ion and CO molecule in a photodissociation region, and a molecular cloud associated with Hπ region (hereinafter referred as HI region) at low temperatures (T k≤200 K). Comparisons have been made for cooling with and without FIR for two extreme abundances (10−4 and 10−7) of the mentioned species for temperatures ranging between 10 and 200K and an hydrogen particle density range 10 cm−3≤n o≤ 107 cm3. The cooling by the species with low line-splitting (CI, Cπ and CO) is significantly influenced by the radiation field for temperaturesT k < 100 K while the effect of radiation field on cooling by OI is significant even at higher temperatures (T k > 100 K). The effect of FIR field on the cooling of CO from low rotational transitions is negligibly small, whereas it is considerable for higher transitions. In general, the cooling terms related to the short-wavelength transitions are more affected by FIR than those related to longer wavelengths. It is also demonstrated here that in the determination of thermal structure of an HI region the dust grains play an important role in the heating of gas only through photoelectron emission following irradiation by far-ultraviolet (FUV) radiation, as the infrared radiation from the dust is too small to have substantial effect on the cooling. It is found that in the Hπ /HI interface the FIR field from grains in the Hπ region is not capable of modifying the temperature of the warmest regions but does so in the inner part where the temperature is low enough.  相似文献   

15.
We have studied the possible synthesis of organic molecules by the absorption of galactic cosmic rays in an N2CH4H2 Titan model atmosphere. The cosmic-ray-induced ionization results in peak electron densities of 2 × 103 cm?3, with NH4+, C3H9+, and C4H9+ being among the important positive ions. Details of the ion and neutral chemistry relevant to the production of organic molecules are discussed. The potential importance of N(2D) reactions with CH4 and H2 is also demonstrated. Although the integrated production rate of organic matter due to the absorption of the cosmic ray cascade is much less than that by solar ultraviolet radiation, the production of nitrogen-bearing organic molecules by cosmic rays may be greater.  相似文献   

16.
M.H. Moore  R.L. Hudson 《Icarus》2003,161(2):486-500
Infrared spectra and radiation chemical behavior of N2-dominated ices relevant to the surfaces of Triton and Pluto are presented. This is the first systematic IR study of proton-irradiated N2-rich ices containing CH4 and CO. Experiments at 12 K show that HCN, HNC, and diazomethane (CH2N2) form in the solid phase, along with several radicals. NH3 is also identified in irradiated N2 + CH4 and N2 + CH4 + CO. We show that HCN and HNC are made in irradiated binary ice mixtures having initial N2/CH4 ratios from 100 to 4, and in three-component mixtures have an initial N2/(CH4 + CO) ratio of 50. HCN and HNC are not detected in N2-dominated ices when CH4 is replaced with C2H6, C2H2, or CH3OH.The intrinsic band strengths of HCN and HNC are measured and used to calculate G(HCN) and G(HNC) in irradiated N2 + CH4 and N2 + CH4 + CO ices. In addition, the HNC/HCN ratio is calculated to be ∼1 in both icy mixtures. These radiolysis results reveal, for the first time, solid-phase synthesis of both HCN and HNC in N2-rich ices containing CH4.We examine the evolution of spectral features due to acid-base reactions (acids such as HCN, HNC, and HNCO and a base, NH3) triggered by warming irradiated ices from 12 K to 30-35 K. We identify anions (OCN−, CN−, and N3−) in ices warmed to 35 K. These ions are expected to form and survive on the surfaces of Triton and Pluto. Our results have astrobiological implications since many of these products (HCN, HNC, HNCO, NH3, NH4OCN, and NH4CN) are involved in the syntheses of biomolecules such as amino acids and polypeptides.  相似文献   

17.
David E. Woon  Jin-Young Park 《Icarus》2009,202(2):642-680
Barrierless reactions between unsaturated hydrocarbons and the ethynyl radical (C2H) can contribute to the growth of organic particulates in the haze-forming regions of Titan's atmosphere as well as in the gas giants and in the interstellar medium. We employed a combination of quantum chemistry and statistical rate theories to characterize reactions between ground state C2H and seven alkenes of the general structure R1R2C′C″R3R4 containing up to six carbons. The alkenes included ethene (C2H4); propene (C3H6); 1-butene, 2-butene, and isobutene (C4H8); trimethylethene (C5H10); and tetramethylethene (C6H12). Density functional theory calculations at the B3LYP/6-31 + G∗∗ level were used to characterize the adducts, isomers, products, and the intervening transition states for the addition-elimination reactions of all seven species. A multiple-well treatment was then employed to determine the outcome distributions for the range of temperatures and pressures relevant to Titan's atmosphere, the interstellar medium, and the outer atmospheres of the gas giants. Finally, trajectory calculations using an ROMP2 potential energy surface were used to calculate kinetic rates for the ethene + C2H reaction, where the agreement between the computed and measured values is very good. At low pressure and temperature, vinyl acetylene is a dominant product of several of the reactions, and all of the reactions yield at least one dominant product with both a double and a triple CC bond.  相似文献   

18.
The evolution of the different chemical species are followed in a model of contracting interstellar cloud. The central density increases from n = 10 cm–3 diffuse initial cloud model to a dense cloud with central density number of n >- 105 cm–3 after a time of 1.2 × 107 yr. A network of 622 reactions has been involved. The chemistry of the cloud is integrated simultaneously with the hydrodynamic equations of contraction.The results predict that the different molecular species increase in abundance as the contraction proceeds. The species which enhance significantly are CO, HCO, CS and NO. The fractional abundances of many of the other molecular species increase distinctly with contraction, e.g. CH, C2H, CN, SO2, CO2, H2O, C2, NH3, HCN, SO, OCS and SN. The transformation of the initial diffuse cloud model with small abundances of molecular species to a dense molecular cloud with enhancement of the different molecular species is confirmed. The results predict good agreements of our results with both the observations and other theoretical studies.  相似文献   

19.
Since gas-phase reactions alone cannot account for the observed abundances of H2 in the typical interstellar cloud, one or more surface reactions are probably involved. Of the three possible candidates, only the catalytic production of H2 on transition metal grains is supported by laboratory evidence. Using the rate equations developed in a previous paper for this process, the steady-state equilibrium abundances of H, H2,e –, H+, H–, H2 +, and H3 + are calculated for large (r>10 pcs;M102 M ), tenuous (n=102–104 cm–3) hydrogen dust clouds under a wide variety of conditions. In addition to the four rate equations involved in the catalytic reactions, 18 gas-phase and one additional surface reaction—the physical adsorption of H-atoms on cold, dielectric surfaces and their subsequent recombination and desorption as H2 molecules—are included in the calculations. It is found that metal grains can produce as much interstellar H2 as the best physical adsorption mechanism under optimum conditions if the extinction in the visible is less than 5m.0. The three critical parameters for efficient catalysis (activation energy of desorption, grain temperature, and the number density of available sites) are examined, and it is shown that catalytic reactions are efficient producers of H2 under all but the most unfavorable conditions.  相似文献   

20.
Radiation synthesis has been proposed as a mechanism for changing the nature of the outer few meters of ice in a comet stored 4.6 billion years in the Oort cloud and may explain some of the differences observed between new and more evolved comets. Cometary-type ice mixtures were studied in a laboratory experiment designed to approximately simulate the expected temperature, pressure, and radiation environment of the interstellar Oort cloud region. The 2.5- to 15-μm infrared absorption features of thin ice films were analyzed near 20°K before and after 1 MeV proton irradiation. Various ice mixtures included the molecules H2O, NH3, CH4, N2, C3H8, CO, and CO2. All experiments confirm the synthesis of new molecular species in solid phase mixtures at 20°K. The synthesized molecules, identified by their infrared signatures, are C2H6, CO2, CO, N2O, NO, and CH4 (weak). Synthesized molecules, identified by gas chromatographic (GC) analysis of the volatile fraction of the warmed irradiated ice mixture, are C2H4 or C2H6, and C3H8. When CH4 is present in the irradiated ice mixture, long-chained volatile hydrocarbons and CO2 are synthesized along with high-molecular-weight carbon compounds present in the room temperature residue. Irradiated mixtures containing CO and H2O synthesize CO2 and those CO2 and H2O synthesize CO. Due to radiation synthesis, ～1% of the ice was converted into a nonvolatile residue containing complicated carbon compounds not present in blank samples. These results suggest that irrespective of the composition of newly accreted comets, initial molecular abundances can be altered and new species created as a result of radiation synthesis. Irradiated mixtures exhibited thermoluminescence and pressure enhancements during warming; these phenomena suggest irradiation synthesis of reactive species. Ourbursts in new comets resulting from similar radiation induced exothermic activity would be expected to occur beginning at distances of the order of 100 AU.  相似文献   

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