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1.
Abstract— Crystal‐bearing lunar spherules (CLSs) in lunar breccia (14313, 14315, 14318), soil (68001, 24105), and impact‐melt rock (62295) samples can be classified into two types: feldspathic and olivine‐rich. Feldspathic CLSs contain equant, tabular, or acicular plagioclase grains set in glass or a pyroxene‐olivine mesostasis; the less common olivine‐rich CLSs contain euhedral or skeletal olivine set in glass, or possess a barred‐olivine texture. Bulk‐chemical and mineral‐chemical data strongly suggest that feldspathic CLSs formed by impact melting of mixtures of ferroan anorthosite and Mg‐suite rocks that compose the feldspathic crust of the Moon. It is probable that olivine‐rich CLSs also formed by impact melting, but some appear to have been derived from distinctively magnesian lunar materials, atypical of the Moon's crust. Some CLSs contain reversely‐zoned “relic” plagioclase grains that were not entirely melted during CLS formation, thin (≤5 μm thick) rims of troilite or phosphate, and chemical gradients in glassy mesostases attributed to metasomatism in a volatile‐rich (Na‐K‐P‐rich) environment. Crystal‐bearing lunar spherules were rimmed and metasomatized prior to brecciation. Compound CLS objects are also present; these formed by low‐velocity collisions in an environment, probably an ejecta plume, that contained numerous melt droplets. Factors other than composition were responsible for producing the crystallinity of the CLSs. We agree with previous workers that relatively slow cooling rates and long ballistic travel times were critical features that enabled these impact‐melt droplets to partially or completely crystallize in free‐flight. Moreover, incomplete melting of precursor materials formed nucleation sites that aided subsequent crystallization. Clearly, CLSs do not resemble meteoritic chondrules in all ways. The two types of objects had different precursors and did not experience identical rimming processes, and vapor fractionation appears to have played a less important role in establishing the compositions of CLSs than of chondrules. However, the many detailed similarities between CLSs and chondrules indicate that it is more difficult to rule out an origin for some chondrules by impact melting than some have previously argued. Differences between CLSs, chondrules, and their host rocks possibly can be reconciled with an impact‐melt origin for some chondrules when different precursors, the higher gravity of the Moon compared to chondrite parent bodies, and the likely presence of nebular gas during chondrule formation are taken into account.  相似文献   

2.
Abstract— Mafic, Th-rich impact-melt breccias, most of which are identified with the composition known as low-K Fra Mauro (LKFM), are the most common rock type in the nonmare regoliths of the Apollo lunar landing sites. The origin of mafic impact-melt breccias bears on many lunar problems: the nature of the late meteoroid bombardment (cataclysm); the spatial distribution of KREEP, both near the surface and at depth; the ages of the major basins; and the composition of the early crust of the nearside lunar highlands. Thus, it is crucial that the origin of mafic impact-melt breccias be accurately understood. Because of both intra- and intersite differences in compositions of mafic impact-melt breccia samples, apparent differences in crystallization age, and differences in siderophile-element ratios, previous studies have argued that either (1) most mafic impact-melt breccias are the products of several large craters local to the site at which they were found but that some are of basin origin or that (2) they are all from the Imbrium (Apollos 14 and 15), Nectaris (Apollo 16), and Serenitatis (Apollo 17) basins. Here, we reconsider the hypothesis that virtually all of the Th-rich, mafic impact-melt breccias from the Apollo missions are products of the Imbrium impact. Ejecta deposit modeling based on modern crater scaling indicates that the Imbrium event produced ejecta deposits that average hundreds of meters thick or more at all Apollo highland sites, which is thicker than some previous estimates. Substantial amounts of Imbrium ejecta should have been sampled at every Apollo highland site. We suggest that the mafic impact-melt breccias may be the principal form of those ejecta. The Imbrium projectile impacted into Th-rich material that we regard as part of a unique, mafic, lunar geochemical province we call the High-Th Oval Region. Based on the surface distribution of Th, only basins within the High-Th Oval Region excavated Th-rich material; the Th concentrations of the highlands as observed by the Apollo orbiting γ-ray experiments are consistent with the estimates from ejecta modeling. Of the younger basin-forming impacts, only Imbrium was large enough to produce the copious amount of melt required by the ubiquitous presence of mafic impact-melt breccias in the Apollo-sampled regolith. The High-Th Oval Region still may have been molten or hot at shallow depths ～4 Ga ago when the Imbrium projectile struck. We reason that compositional heterogeneity of ejected melt breccia is to be expected under these circumstances. We argue that siderophile-element “fingerprints” of mafic impact-melt breccias are not inconsistent with production of all common types by a single projectile. We suggest that the narrow range of ages of 3.7–4.0 Ga for all successfully dated mafic impact-melt breccias may reflect a single event whose age is difficult to measure precisely, rather than a number of discrete impact events closely spaced in time, such that reported age variations among mafic impact-melt breccias reflect the ability to measure 40Ar/39Ar ages with greater precision than the accuracy with which measured portions of mafic impact-melt breccias have recorded the time of their formation.  相似文献   

3.
Impact-generated silicate spherules from the Lonar Crater, India and from all Apollo sites are analogous to meteoritic chondrules (and some microtektites). Thus, the impact origin of chondrules, first proposed by Urey (1952) is a mechanism strongly supported by physical evidence from both the Moon and the Earth. Chondrites appear to be essentially impact breccias similar to lunar and Lonar microbreccias. The implications of this with regard to size and composition of the meteorite parent bodies are reviewed as well as the possible variations of element fractionation by volatilization-condensation.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.  相似文献   

4.
Feldspar in ordinary chondrites (OCs) is often associated with thermal metamorphism, as a secondary mineral that forms from the crystallization of matrix and chondrule mesostasis. However, studies of feldspar in equilibrated OCs show that there is a range of plagioclase compositions within chondrules, some of which may be primary products of chondrule crystallization. It is important to recognize primary feldspar within chondrules because it can be used to help understand the secondary effects of thermal metamorphism and aqueous alteration. The presence of primary feldspar also provides important petrologic constraints on chondrule formation time scales. We undertook a careful study of Semarkona (LL3.00) and observed feldspar in 18% of chondrules. The feldspar is plagioclase covering a wide range of compositions (An2–An99) with little K‐feldspar component (<Or3). We show that plagioclase is a primary igneous phase, based on grain morphology and compositions consistent with growth from a melt having the bulk compositions of the host chondrules. Based on experimental studies, the presence of plagioclase suggests chondrules cooled slowly at temperatures close to the solidus. We also observed several secondary features consistent with the aqueous alteration. These features include zoning of Na and Ca in plagioclase, heterogeneity in plagioclase compositions in altered chondrules, development of porosity from the dissolution of chondrule glass, and alteration of glass to phyllosilicates. Alteration of major Al‐bearing phases, like plagioclase and glass, has important implications for interpretations of ages derived from Al‐Mg dating of chondrules, if they have been affected by secondary processes.  相似文献   

5.
Abstract– We have carried out a study of feldspar compositions in a suite of H and LL ordinary chondrites, of petrologic types 4, 5, and 6, in order to examine the process of recrystallization and equilibration of feldspar as the degree of metamorphism increases. In the H chondrites, there is little variation in feldspar compositions among the petrologic types, suggesting that homogenization of chondrule mesostasis, from which feldspar is presumed to have crystallized, occurred before feldspar crystallization began. The LL chondrites we studied are more complex. In Bjurböle (L/LL4), plagioclase in individual relict chondrules has distinct compositions, with a range of An/Ab ratios and low Or contents. This heterogeneity is most likely attributable to original compositional heterogeneity among chondrule mesostases: localized recrystallization of mesostasis must have occurred before diffusional equilibration took place. In Tuxtuac (LL5), the An/Ab ratio of plagioclase is more homogeneous, and plagioclase includes a significant Or component. In addition, we observe what appears to be exsolution of K‐feldspar from albitic host grains. In Saint Séverin (LL6), the An/Ab ratio of plagioclase is homogeneous, but plagioclase compositions show a range of Or contents, corresponding to a patchy distribution of K in individual feldspar grains. The observations in these LL chondrites are difficult to interpret with a simple model of progressive equilibration with increasing petrologic type. We suggest that the current criteria for assigning petrologic types are poorly defined: it is possible that the assigned petrologic types of these chondrites do not correlate with their peak temperatures. We propose that feldspar compositions might record conditions during the heating stage of metamorphism, and that the early stages of metamorphism may have occurred in the presence of fluids, rather than under the dry conditions that are commonly assumed.  相似文献   

6.
Previous age estimates of the Imbrium impact range from 3770 to 3920 Ma, with the latter being the most commonly accepted age of this basin‐forming event. The occurrence of Ca‐phosphates in Apollo 14 breccias, interpreted to represent ejecta formed by this impact, provides a new opportunity to date the Imbrium event as well as refining the impact history of the Moon. We present new precise U‐Pb analyses of Ca‐phosphates from impact breccia sample 14311 that are concordant and give a reliable weighted average age of 3938 ± 4 Ma (2σ). Comparison with previously published U‐Pb data on phosphate from Apollo 14 samples indicate that all ages are statistically similar and suggest phosphates could have been formed by the same impact at 3934 Ma ± 3 Ma (2σ). However, this age is older than the 3770 to 3920 Ma range determined for other samples and also interpreted as formed during the Imbrium impact. This suggests that several impacts occurred during a 20–30 Ma period around 3900 Ma and formed breccias sampled by the Apollo missions.  相似文献   

7.
Abstract There are two types of glass-rich chondrules in unequilibrated ordinary chondrites (OC): (1) porphyritic chondrules containing 55–85 vol% glass or microcrystalline mesostasis and (2) nonporphyritic chondrules, containing 90–99 vol% glass. These two types are similar in mineralogy and bulk composition to previously described Al-rich chondrules in OC. In addition to Si-, Al- and Na-rich glass or Ca-Al-rich microcrystalline mesostasis, glass-rich chondrules contain dendritic and skeletal crystals of olivine, Al2O3-rich low-Ca pyroxene and fassaite. Some chondrules contain relict grains of forsterite ± Mg-Al spinel. We suggest that glass-rich chondrules were formed early in nebular history by melting fine-grained precursor materials rich in refractory (Ca, Al, Ti) and moderately volatile (Na, K) components (possibly related to Ca-Al-rich inclusions) admixed with coarse relict forsterite and spinel grains derived from previously disrupted type-I chondrules.  相似文献   

8.
Sixteen samples of Boulder 1 from Station 2 at the Apollo 17 site were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, Ir, Ni, Rb, Re, Sb, Te, Tl, U, and Zn. Two clast samples contam no meteoritic material and appear to consist of relatively pristine igneous rocks: an unusual, KREEP-rich pigeonite basalt of very high Ge content, and an alkali-poor coarse norite. Nine grey or black breccia samples contain a unique, Group 3 meteoritic component of Ir/Au ratio 0.65–0.82, which appears to separate into subgroups 3H and 3L on the basis of Ni, Ge, and Re content. It is quite distinct from the Group 2 component (Ir/Au - 0.46–0.54) that dominates at the Apollo 17 site.The unique black-rimmed clasts from this boulder show striking compositional zoning. The cores of anorthositic breccia are very low in Rb, Cs, and U, and have a distinctive 5L meteoritic component (Ir/Au1.1). The black rinds are 5- to 10-fold richer in Rb, Cs, and U and have a Group 3 meteoritic component. The cores may represent breccias formed in an earlier impact that became coated with alkali-rich ejecta during the event that produced the boulder.Because of the rarity of the Group 3 meteoritic component at the Apollo 17 site, this boulder cannot represent ordinary Serenitatis ejecta, with their characteristic admixture of the Group 2 Serenitatis projectile. It may represent pre-Serenitatis material excavated from the fringes of the crater during late stages of the Serenitatis impact, but only lightly shocked and hence uncontaminated by the Serenitatis projectile.  相似文献   

9.
Abstract— The study of chondrules provides information about processes occurring in the early solar system. In order to ascertain to what extent these processes played a role in determining the properties of the enstatite chondrites, the physical and chemical properties of chondrules from three EL3 chondrites and three EH3 chondrites have been examined by optical, cathodoluminescence (CL), and electron microprobe techniques. Properties examined include size, texture, CL, and composition of both individual phases and bulk chondrules. The textures, distribution of textures, and composition of silicates of the EL3 chondrules resemble those of EH3 chondrules. However, the chondrules from the two classes differ in that (1) the size distribution of the EL chondrules is skewed to larger values than EH chondrules, (2) the enstatite in EL chondrules displays varying shades of red CL due to the presence of fine‐grained sulfides and metal in the silicates, and (3) the mesostasis of EH chondrules is enriched in Na relative to that of EL chondrules. The similarities between the chondrules of the two classes suggest similar precursor materials, while the differences suggest that there was not a single reservoir of meteoritic chondrules, but that their origin was fairly local. The differences in the size distribution of chondrules in EH and EL chondrites may be explained by aerodynamic and gravitational sorting during accumulation of the meteoric material, while differences in CL and mesostasis properties may reflect differences in formation conditions and cooling rate following chondrule formation. We argue that our observations are consistent with the formation of enstatite chondrites in a thick dynamic regolith on their parent body.  相似文献   

10.
Secondary ion mass spectrometry (SIMS) U‐Pb ages of Ca‐phosphates from four texturally distinct breccia samples (72255, 76055, 76015, 76215) collected at the Apollo 17 landing site were obtained in an attempt to identify whether they represent a single or several impact event(s). The determined ages, combined with inferences from petrologic relationships, may indicate two or possibly three different impact events at 3920 ± 3 Ma, 3922 ± 5 Ma, and 3930 ± 5 Ma (all errors 2σ). Searching for possible sources of the breccias by calculating the continuous ejecta radii of impact basins and large craters as well as their expected ejecta thicknesses, we conclude that Nectaris, Crisium, Serenitatis, and Imbrium are likely candidates. If the previous interpretation that the micropoikilitic breccias collected at the North Massif represent Serenitatis ejecta is correct, then the average 207Pb/206Pb age of 3930 ± 5 Ma (2σ) dates the formation of the Serenitatis basin. The occurrence of zircon in the breccias sampled at the South Massif, which contain Ca‐phosphates yielding an age of 3922 ± 5 Ma (2σ), may indicate that the breccia originated from within the Procellarum KREEP terrane (PKT) and the Imbrium basin appears to be the only basin that could have sourced them. However, this interpretation implies that all basins suggested to fall stratigraphically between Serenitatis and Imbrium formed within a short (<11 Ma) time interval, highlighting serious contradictions between global stratigraphic constraints, sample interpretation, and chronological data. Alternatively, the slightly older age of the two micropoikilitic breccias may be a result of incomplete resetting of the U‐Pb system preserved in some phosphate grains. Based on the currently available data set this possibility cannot be excluded.  相似文献   

11.
Abstract— We report measurements of K isotope ratios in 28 Semarkona chondrules with a wide range of petrologic types and bulk compositions as well as the compositions of CPX‐mesostasis pairs in 17 type I Semarkona chondrules, including two chondrules with radial alkali zonation and 19 type II chondrules. Despite the wide range in K/Al ratios, no systematic variations in K isotopic compositions were found. Semarkona chondrules do not record a simple history of Rayleigh‐type loss of K. Experimentally determined evaporation rates suggest that considerable alkali evaporation would have occurred during chondrule formation. Nevertheless, based on Na CPX‐mesostasis distribution coefficients, the alkali contents of the cores of most chondrules in Semarkona were probably established at the time of final crystallization. However, Na CPX‐mesostasis distribution coefficients also show that alkali zonation in type I Semarkona chondrules was produced by entry of alkalis after solidification, probably during parent body alteration. This alkali metasomatism may have gone to completion in some chondrules. Our preferred explanation for the lack of systematic isotopic enrichments, even in alkali depleted type I chondrule cores, is that they exchanged with the ambient gas as they cooled.  相似文献   

12.
In this paper, we compare the U‐Pb zircon age distribution pattern of sample 14311 from the Apollo 14 landing site with those from other breccias collected at the same landing site. Zircons in breccia 14311 show major age peaks at 4340 and 4240 Ma and small peaks at 4110, 4030, and 3960 Ma. The zircon age patterns of breccia 14311 and other Apollo 14 breccias are statistically different suggesting a separate provenance and transportation history for these breccias. This interpretation is supported by different U‐Pb Ca‐phosphate and exposure ages for breccia 14311 (Ca‐phosphate age: 3938 ± 4 Ma, exposure age: ~550–660 Ma) from the other Apollo 14 breccias (Ca‐phosphate age: 3927 ± 2 Ma, compatible with the Imbrium impact, exposure age: ~25–30 Ma). Based on these observations, we consider two hypotheses for the origin and transportation history of sample 14311. (1) Breccia 14311 was formed in the Procellarum KREEP terrane by a 3938 Ma‐old impact and deposited near the future site of the Imbrium basin. The breccia was integrated into the Fra Mauro Formation during the deposition of the Imbrium impact ejecta at 3927 Ma. The zircons were annealed by mare basalt flooding at 3400 Ma at Apollo 14 landing site. Eventually, at approximately 660 Ma, a small and local impact event excavated this sample and it has been at the surface of the Moon since this time. (2) Breccia 14311 was formed by a 3938 Ma‐old impact. The location of the sample is not known at that time but at 3400 Ma, it was located nearby or buried by hot basaltic flows. It was transported from where it was deposited to the Apollo 14 landing site by an impact at approximately 660 Ma, possibly related to the formation of the Copernicus crater and has remained at the surface of the Moon since this event. This latter hypothesis is the simplest scenario for the formation and transportation history of the 14311 breccia.  相似文献   

13.
Abstract— Characteristics of the regolith of Cayley plains as sampled at the Apollo 16 lunar landing site are reviewed and new compositional data are presented for samples of <1 mm fines (“soils”) and 1–2 mm regolith particles. As a means of determining which of the many primary (igneous) and secondary (crystalline breccias) lithologic components that have been identified in the soil are volumetrically important and providing an estimate of their relative abundances, more than 3 × 106 combinations of components representing nearly every lithology that has been observed in the Apollo 16 regolith were systematically tested to determine which combinations best account for the composition of the soils. Conclusions drawn from the modeling include the following. At the site, mature soil from the Cayley plains consists of 64.5% ± 2.7% components representing “prebasin” materials: anorthosites, feldspathic breccias, and a small amount (2.6% ± 1.5% of total soil) of nonmare, mafic plutonic rocks, mostly gabbronorites. On average, these components are highly feldspathic, with average concentrations of 31–32% Al2O3 and 2–3% FeO and a molar Mg/(Mg + Fe) ratio of 0.68. The remaining 36% of the regolith is syn- and postbasin material: 28.8% ± 2.4% mafic impact-melt breccias (MIMBs, i.e., “LKFM” and “VHA basalts”) created at the time of basin formation, 6.0% ± 1.4% mare-derived material (impact and volcanic glass, crystalline basalt) with an average TiO2 concentration of 2.4%, and 1% postbasin meteoritic material. The MIMBs are the principal (80–90%) carrier of incompatible trace elements (rare earths, Th, etc.) and the carrier of about one-half of the siderophile elements and elements associated with mafic mineral phases (Fe, Mg, Mn, Cr, Sc). Most (71%) of the Fe in the present regolith derives from syn- and postbasin sources (MIMBs, mare-derived material, and meteorites). Thus, although the bulk composition of the Apollo 16 regolith is nominally that of noritic anorthosite, the noritic part (the MIMBs) and the anorthositic part (the prebasin components) are largely unrelated. There is compositional evidence that 3–4% of the soil is Th-rich material such as that occurring at the Apollo 14 site, and one fragment of this type was found among the small regolith particles studied here. If regolith such as that represented by the Apollo 16 ancient regolith breccias was a protolith of the present regolith, such regolith cannot exceed ～71% of the present regolith; the rest must be material added or redistributed since closure of the ancient regolith breccias. The postclosure material includes the mare-derived material and the Apollo-14-like component. Compositions of all mature surface soils from Apollo 16, even those collected 4 km apart on the Cayley plains, are very similar, which is in stark contrast to the wide compositional range of the lithologies of which the soil is composed. This uniformity indicates that the ratio of MIMBs to feldspathic prebasin components is not highly variable in the megaregolith over distances of a few kilometers, that there are no large, subsurface concentrations of “pure” mafic impact-melt breccia, and that the intimate mixing is inherent to the Cayley plains at a gross scale. Thus, the mixing of mafic impact-melt breccias and feldspathic prebasin components must have occurred during formation and deposition of the Cayley plains; such uniformity could not have been achieved by small postdeposition impacts into a stratified megaregolith. Using this conclusion as one constraint, and the known distribution of Th on the lunar surface as another, and the assumption that the Imbrium impact is primarily responsible for formation of the Cayley plains, arguments are presented that the Apollo 16 MIMBs derive from the Imbrium region, and, consequently, that one-fourth of the Apollo 16 regolith is primary Imbrium ejecta in the form of mafic impact-melt breccias.  相似文献   

14.
Analysis of terrain in the Apollo 16 Descartes landing region shows a series of features that form a stratigraphic sequence which dominates the history and petrogenesis at the site. An ancient 150 km diam crater centered on the Apollo 16 site is one of the earliest recognizable major structures. Nectaris ejecta was concentrated in a regional low at the base of the back slope of the Nectaris basin to form the Descartes Mountains. Subsequently, a 60 km diam crater formed in the Descartes Mountains centered about 25 km to the west of the site. This crater dominates the geology and petrogenetic history of the site. Stone and Smoky Mountains represent the degraded terraced crater walls, and the dark matrix breccias and metaclastic rocks derived from North and South Ray craters represent floor fallback breccias from this cratering event. Subsequent major cratering occurred in the region (Dollond B, etc.) prior to the Imbrium and Orientale basin-forming events but had minor effect on the site. Based on this interpretation, contributions from Imbrium at the Apollo 16 site are minor and those from Orientale negligible. The petrology of the Apollo 16 rocks supports this stratigraphic and process model of a local crater-dominated history for this region.  相似文献   

15.
Abstract— An important and poorly understood group of rocks found in the ancient lunar highlands is called “feldspathic granulitic impactites.” Rocks of the granulite suite occur at most of the Apollo highlands sites as hand samples, rake samples, clasts in breccias, and soil fragments. Most lunar granulites contain 70–80% modal plagioclase, but they can range from anorthosite to troctolite and norite. Previous studies have led to different interpretations for the thermal history of these rocks, including formation as igneous plutons, long-duration metamorphism at high temperatures, and short-duration metamorphism at low temperatures. This paper reports on a study of 24 polished thin sections of lunar granulites from the Apollo 15, 16, and 17 missions. We identify three different textural types of granulitic breccias: poikilitic, granoblastic, and poikilitic-granoblastic breccias. These breccias have similar equilibration temperatures (1100 ± 50 °C), as well as common compositions. Crystal size distributions in two granoblastic breccias reveal that Ostwald ripening took place during metamorphism. Solid-state grain growth and diffusion calculations indicate relatively rapid cooling during metamorphism (0.5 to 50 °C/year), and thermal modeling shows that they cooled at relatively shallow depths (<200 m). In contrast, we conclude that the poikilitic rocks formed by impact melting, whereas the poikilitic-granoblastic rocks were metamorphosed and may have partially melted. These results indicate formation of lunar granulites in relatively small craters (30–90 km in diameter), physically associated with the impact-melt breccia pile, and possibly from fine-grained fragmental precursor lithologies.  相似文献   

16.
Abstract The major‐ and minor‐element abundances were determined by electron microprobe in 1039 glasses from regoliths and regolith breccias to define the compositional topology of lunar glasses at the Apollo 16 landing site in the central highlands of the Moon. While impact glasses with chemical compositions similar to local materials (i.e., Apollo 16 rocks and regoliths) are abundant, glasses with exotic compositions (i.e., transported from other areas of the Moon) account for up to ?30% of the population. A higher proportion of compositionally exotic, angular glass fragments exists when compared to compositionally exotic glass spherules. Ratios of non‐volatile lithophile elements (i.e., Al, Ti, Mg) have been used to constrain the original source materials of the impact glasses. This approach is immune to the effects of open‐system losses of volatile elements (e.g., Si, Na, K). Four impact glasses from one compositionally exotic group (low‐Mg high‐K Fra Mauro; lmHKFM) were selected for 40Ar/39 Ar dating. The individual fragments of lmHKFM glass all yielded ages of ?3750 ± 50 Ma for the time of the impact event. Based on the petrography of these individual glasses, we conclude that the likely age of the impact event that formed these 4 glasses, as well as the possible time of their ballistic arrival at the Apollo 16 site from a large and distant cratering event (perhaps in the Procellarum KREEP terrain) (Zeigler et al. 2004), is 3730 ± 40 Ma, close to the accepted age for Imbrium.  相似文献   

17.
Abstract— We report secondary ion mass spectrometry (SIMS) U‐Pb analyses of zircon and apatite from four breccia samples from the Apollo 14 landing site. The zircon and apatite grains occur as cogenetic minerals in lithic clasts in two of the breccias and as unrelated mineral clasts in the matrices of the other two. SIMS U‐Pb analyses show that the ages of zircon grains range from 4023 ± 24 Ma to 4342 ± 5 Ma, whereas all apatite grains define an isochron corresponding to an age of 3926 ± 3 Ma. The disparity in the ages of cogenetic apatite and zircon demonstrates that the apatite U‐Pb systems have been completely reset at 3926 ± 3 Ma, whereas the U‐Pb system of zircon has not been noticeably disturbed at this time. The apatite U‐Pb age is slightly older than the ages determined by other methods on Apollo 14 materials highlighting need to reconcile decay constants used for the U‐Pb, Ar‐Ar and Rb‐Sr systems. We interpret the apatite age as a time of formation of the Fra Mauro Formation. If the interpretation of this Formation as an Imbrium ejecta is correct, apatite also determines the timing of Imbrium impact. The contrast in the Pb loss behavior of apatite and zircon places constraints on the temperature history of the Apollo 14 breccias and we estimate, from the experimentally determined Pb diffusion constants and an approximation of the original depth of the excavated samples in the Fra Mauro Formation, that the breccias experienced an initial temperature of about 1300–1100 °C, but cooled within the first five to ten years.  相似文献   

18.
Abstract Two types of texturally and compositionally similar breccias that consist largely of fragmental debris from meteorite impacts occur at the Apollo 16 lunar site: Feldspathic fragmental breccias (FFBs) and ancient regolith breccias (ARBs). Both types of breccia are composed of a suite of mostly feldspathic components derived from the early crust of the Moon and mafic impact-melt breccias produced during the time of basin formation. The ARBs also contain components, such as agglutinates and glass spherules, indicating that the material of which they are composed occurred at the surface of the Moon as fine-grained regolith prior to lithification of the breccias. These components are absent from the FFBs, suggesting that the FFBs might be the protolith of the ARBs. However, several compositional differences exist between the two types of breccia, making any simple genetic relationship implausible. First, clasts of mafic impact-melt breccia occurring in the FFBs are of a different composition than those in the ARBs. Also the feldspathic “prebasin” components of the FFBs have a lower average Mg/Fe ratio than the corresponding components of the ARBs; the average composition of the plagioclase in the FFBs is more sodic than that of the ARBs; and there are differences in relative abundances of rare earth elements. The two breccia types also have different provenances: the FFBs occur primarily in ejecta from North Ray crater and presumably derive from the Descartes Formation, while the ARBs are restricted to the Cayley plains. Together these observations suggest that although some type of fragmental breccia may have been a precursor to the ARBs, the FFBs of North Ray crater are not a significant component of the ARBs and, by inference, the Cayley plains. The average compositions of the prebasin components of the two types of fragmental breccia are generally similar to the composition of the feldspathic lunar meteorites. With 30–31% Al2O3, however, they are slightly richer in plagioclase than the most feldspathic lunar meteorites (～29% Al2O3), implying that the crust of the early central nearside of the Moon contained a higher abundance of highly feldspathic anorthosite than typical lunar highlands, as inferred from the lunar meteorites. The ancient regolith breccias, as well as the current surface regolith of the Cayley plains, are more mafic than (1) prebasin regoliths in the Central Highlands and (2) regions of highlands presently distant from nearside basins because they contain a high abundance (～30%) of mafic impact-melt breccias produced during the time of basin formation that is absent from other regoliths.  相似文献   

19.
Abstract– Two suites of lunar impact melt samples have been measured in NASA’s Reflectance Experiment Laboratory (RELAB) at Brown University. Suite 1 comprises seven Apollo 17 crystalline impact melt breccias and seven quenched glass equivalents. Suite 2 is made up of 15 additional impact melt samples (from Apollo 12, 15, 16, and 17) which exhibit a range of textures and compositions related to cooling conditions and glass abundance. A few of these samples have cooled slowly and fully crystallized, and thus have the same spectral properties as igneous rocks of similar texture and composition; they cannot be uniquely distinguished without geologic context. However, most of the impact melts and melt breccias contain either quantities of quenched glass and/or have developed microcrystalline nonequilibrium textures with well‐defined, diagnostic spectral properties. The microcrystalline textures are associated with a distinctive 600 nm absorption feature, apparently due to submicroscopic ilmenite inclusions in a transparent host (typically fine‐grained plagioclase). The reflectance properties of these lunar sample suites contribute to and constrain the identification and characterization of impact melts in remote sensing data.  相似文献   

20.
Micrometeorites that pass through the Earth's atmosphere undergo changes in their chemical compositions, thereby making it difficult to understand if they are sourced from the matrix, chondrules, or calcium–aluminum‐rich inclusions (CAIs). These components have the potential to provide evidence toward the understanding of the early solar nebular evolution. The variations in the major element and trace element compositions of 155 different type (scoriaceous, relict bearing, porphyritic, barred, cryptocrystalline, and glass) of S‐type cosmic spherules are investigated with the intent to decipher the parent sources using electron microprobe and laser ablation inductively coupled plasma‐mass spectrometry. The S‐type cosmic spherules appear to show a systematic depletion in volatile element contents, but have preserved their refractory trace elements. The trends in their chemical compositions suggest that the S‐type spherules comprise of components from similar parent bodies, that is, carbonaceous chondrites. Large fosteritic relict grains observed in this investigation appear to be related to the fragments of chondrules from carbonaceous chondrites. Furthermore, four spherules (two of these spherules enclose spinels and one comprised entirely of a Ca‐Al‐rich plagioclase) show enhanced trace element enrichment patterns that are drastically different from all the other 151 cosmic spherules. The information on the chemical composition and rare earth elements (REEs) on cosmic spherules suggest that the partially to fully melted ones can preserve evidences related to their parent bodies. The Ce, Eu, and Tm anomalies found in the cosmic spherules have similar behavior as that of chondrites. Distinct correlations observed between different REEs and types of cosmic spherules reflect the inherited properties of the precursors.  相似文献   

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