共查询到19条相似文献，搜索用时 171 毫秒
1.
对陕西紫阳屈家山等锰矿床中蜡硅锰矿的下，物理光深沉性质，化学成分，Ｘ－射线衍射数据及晶胞参数，红外光谱特征进行了比较详细的研究，提供了精确的测试数据。 相似文献
2.
云南鹤庆蜡硅锰矿的矿物学特征 总被引：1，自引：0，他引：1
对云南省鹤庆锰矿的物质组成及工艺矿物学研究中首次发现,也是国内第一次发现的锰矿物—蜡硅锰矿[Mn_5Si_4O_(10)(OH)_6],进行了大量研究工作。现就蜡硅锰矿的矿物学特征作简要报道。 相似文献
3.
我国现有锰矿资源状况，不能满足钢铁工业发展的需要。寻找低磷低铁低硅富锰矿，是解决锰矿资源短缺的重要途径。城口锰矿具有较大的找矿前景，锰矿层产出稳定，锰含量高，铁含量低，烧失量大。加强城口矿区勘查，扩大矿床规模，可望成为我国锰矿的重要生产基地。 相似文献
4.
冶金地质部门为了保障冶金工业的可持续发展，制订出“优质锰矿”质量标准，把优质锰作为主要勘查对象，对扬子地台周边优质锰矿成矿规律开展研究，并对优质锰矿资源前景进行了科学评价，取得了突破性进展。优质锰矿科研与勘查的密切结合，尤其在新一轮国土资源大调查中，取得重大进展。文章还对我国优质锰矿科研及勘查工作提出了若干建议。 相似文献
5.
北祁连山缝合带是一条典型的早古生代大洋型俯冲带,其中发育两条蓝片岩带:含硬柱石的低级蓝片岩带和含榴辉岩的高级蓝片岩带。在清水沟地区含榴辉岩的高级蓝片岩带中的高压变质富锰硅质岩中发现稀有的砷硅锰矿,这是国内首次发现砷硅锰矿。利用光学显微镜、扫描电镜、电子探针、拉曼光谱、透射电镜等方法对其进行了详细的矿物学研究。研究发现,砷硅锰矿密度为3. 69～3. 75 g/cm3,硬度为6～7,与石英、红帘石、蓝闪石、多硅白云母和赤铁矿等矿物共生,二轴晶,正光性,(010)解理完全,从淡黄色到金黄色,多色性强烈;砷硅锰矿的主要成分是Si、Al、Mn,富含As,并含有少量的F、V、P;在拉曼图谱上,砷硅锰矿具有许多明显的特征峰,且显示出砷酸根、钒酸根以及MnO键和Si O3基团的存在;在晶体结构上,砷硅锰矿为斜方晶系,空间群为Pnmm,晶轴参数为a=8. 934、b=5. 817、c=19. 005。这些矿物学特征可以作为砷硅锰矿的鉴定和研究依据。 相似文献
6.
棠甘山锰矿床属于典型的沉积-岩浆气液叠加型层控锰矿床。根据矿床产状、矿物组合、元素地球化学、同位素地球化学、有机质和气液包体特点表明，棠甘山锰矿是受岩浆气液叠加形成的一个新的层控锰矿类型。大部分成矿物质来自矿床本身，而少量成矿物质来自岩浆气液。 相似文献
7.
人工合成锰矿物实验及其产物 总被引：2，自引：1，他引：1
通过在蒸馏水中0～10℃条件下,在含Cu、Co、Ni和有机质溶液以及不同底质的合成海水中（常温常压）合成锰矿物。结果得出,初始锰矿物是黑锰矿;控制锰矿物形成的条件是,除必要的物质来源外,起决定作用的是形成环境的酸碱度和氧化还原电位。在含硅质粘土和钙质软泥的试管中产生三层沉淀物：上部层主要是菲细粒（粒径0．5～1.5μm）黑锰矿,中间层为菲细粒黑锰矿和黑锰矿微结核（粒径5.8～43.5μm）,下部层分别为含黑锰矿微结核的硅质粘土和钙质软泥。有的实验中在硅质粘土或钙质软泥上面形成一层厚度为20～33μm黑锰矿结壳。这种结壳上表面的突起和埋藏型结核的表面相似,下表面的小突起里定向排列。 相似文献
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10.
本文阐明了我国优质锰矿分布的区域构造特征,成矿的岩相和古地理环境,磷锰和磷铁分离的地球化学机制及后期改造对优质锰矿形成的作用。 相似文献
11.
A. I. Brusnitsyn 《Geology of Ore Deposits》2006,48(3):193-214
The mineralogy of slightly metamorphosed manganese ore at the South Faizulino hydrothermalsedimentary deposit in the southern Urals has been studied; 32 minerals were identified. Quartz, hausmannite, rhodochrosite, tephroite, ribbeite, pyroxmangite, and caryopilite are major minerals; calcite, kutnahorite, alleghanyite, spessartine, rhodonite, clinochlore, and parsettensite are second in abundance. This mineralic composition was formed in the process of gradual burial of ore beneath the sequence of Middle Devonian-Lower Carboniferous rocks. The highest parameters of metamorphism are T ≈ 250°C and P ≈ 2.5 kbar. The relationships between minerals and their assemblages made it possible to reconstruct the succession of ore transformation with gradually increasing temperature and pressure. Manganese accumulated in the initial sediments as oxides and a gel-like Mn-Si phase. Rhodochrosite and neotocite were formed at the diagenetic stage. In the course of a further increase in temperature and pressure, neotocite was replaced with caryopilite; ribbeite, tephroite, pyroxmangite, and other silicates crystallized afterwards. In addition to the PT parameters, the formation of various metamorphic mineral assemblages was controlled by the Mn/(Mn + Si) ratio in ore and X CO2 in pore solution. The latter parameter was determined by the occurrence of organic matter in the ore-bearing rocks. Ore veinlets as products of local hydrothermal redistribution of Mn, Si, and CO2 were formed during tectonic deformations in the Middle Carboniferous and Permian. 相似文献
12.
The results of geological-mineralogical study of stratificated manganese ores in Famennian rocks of the Lemva facies in Pai-Khoi are presented. Carbonate manganese ores make up conformable stratified and lenticular bodies (up to 0.6 m thick) in the interval between the Gromashor and Silovayakha formations that are composed of jasperoids and carbonate-siliceous rocks. Ores are characterized by fine wavy bedding and development of transverse quartz veinlets. The ores are mainly composed of kutnahorite. Secondary minerals are represented by dolomite, calcite, pyrite, ransayite, and cryptomelane (?). Mn-muscovite, micro-cline, pyrophanite, galena, barite, apatite, and monazite are accessory minerals. The average MnO content is 23.81 wt %. The interval also includes a long (up to 40 m) lens of rhodonite rocks (Silovayakha occurrence) that replace carbonate ores along the strike. The major minerals in these rocks are represented by rhodochrosite, rhodonite, pyroxmangite, and quartz. Secondary minerals are observed as tephroite, alleghanyite, friedelite, caryopilite, neotocite, sussexite, pyrite, and supergene manganese oxides. Spessartine, albandine, barite, and apatite are accessory minerals. Based on the analysis of factual material, we suggest that ore material was derived from hydrothermal paleoceanic systems associated with Devonian volcanism. Ore concentration in the sedimentation zone was related to the stagnant reduced setting of bottom water. Ore deposition was promoted by the delivery of fresh portions of ocean water. Ore matter was accumulated mainly by chemogenic mechanism and partly with the’ participation of bacteria. It is suggested that boundary between the Gromashor and Silovayakha formations should be corrected to unite rocks of the Famennian manganiferous association into a single formation. 相似文献
13.
Jürgen Abrecht 《Contributions to Mineralogy and Petrology》1989,103(2):228-241
Mn-rich members of the pyrosmalite-family [(Mn, Fe)8Si6O15(OH, Cl)10], friedelite and schallerite have been identified as rock-forming minerals together with caryopilite, in several metamorphosed carbonate Mn-deposits. The phase assemblages and mineral compositions are described for eight of these localities each of which represents a distinct geologic situation. Friedelite is always Cl-bearing and occurs both as a prograde phase in low-grade metamorphic rocks (Pyrenees, Haute-Maurienne) and as a secondary phase formed by retrogressive replacement of primary anhydrous phases in higher-grade rocks. Schallerite, an Asbearing relative of friedelite, occurs in the greenschist metamorphic deposit of the Ködnitztal (Austria) together with other As-minerals. In these deposits, caryopilite is typically formed during retrograde metamorphism by alteration of, generally anhydrous, Mn-silicates. Based upon these occurrences, a qualitative petrogenetic grid for the system MnO-SiO2-CO2-H2O with the phases friedelite, caryopilite, pyroxmangite/rhodonite, tephroite, rhodochrosite, quartz, CO2, and H2O is proposed. The phase relations imply that Cl- (or As-) free friedelite is not stable in hydrous systems with respect to caryopilite. From the mineral assemblages containing hydrous Mn silicates, waterrich fluids are inferred during the retrograde metamorphic evolution of the investigated deposits. Chemical data for Mn-rich chlorites, which are basically members of the clinochlore-pennantite series which coexist with the pyrosmalite minerals, show the absence of intermediate Mn/Mg ratios. This supports the existence of a miscibility gap as previously hypothesized by other authors. 相似文献
14.
A. I. Brusnitsyn 《Geology of Ore Deposits》2010,52(7):551-565
A mineralogical investigation of metamorphosed manganese rocks was carried out at ore deposits related to the Devonian volcanic
complexes of the Magnitogorsk paleovolcanic belt of the South Urals. The mineralogical appearance of these rocks is determined
by three consecutively formed groups of mineral assemblages: (1) assemblages occupying the main volume of orebodies and formed
during low-grade regional metamorphism (T = 200−250°C, P = 2–3 kbar); (2) assemblages of segregated and metasomatic veinlets that fill the systems of late tectonic fractures; and
(3) assemblages of near-surface supergene minerals. Sixty-one minerals have been identified in orebodies and crosscutting
hydrothermal veinlets. The major minerals are quartz, hematite, hausmannite, braunite, tephroite, andradite, epidote, rhodonite,
caryopilite, calcite, and rhodochrosite. The mineral assemblages of metamorphosed manganese rocks (metamanganolites) are characterized.
Chemical compositions of braunite, epidote-group minerals, piemontite, pyroxenes, rhodonite, pyroxmangite, and winchite are
considered. The bibliography on geology and mineralogy of the South Ural manganese deposits is given. 相似文献
15.
The paper describes mineralogy of the low grade metamorphosed manganese sediments, which occur in sedimentary complexes of the Pai Khoi Ridge and the Polar Urals and volcanosedimentary complexes of the Central and South Urals. The degree of metamorphism of the rocks studied corresponds to PT conditions of the prehnite–pumpellyite (deposits of Pai Khoi and Polar and South Urals) and green schist (deposits of the Central Urals) facies. One hundred and nine minerals were identified in the manganese-bearing rocks on the basis of optical and electron microscopy, X-ray diffraction, and microprobe analysis. According to the variations in the amount of major minerals of the manganese rocks of the Urals, they are subdivided on carbonate (I), oxide–carbonate–silicate (II), and oxide–silicate (III) types. Carbonates, various Mn2 +-bearing silicates associated with oxides and carbonates, and braunite (Mn3 +-bearing silicate) are the major Mn hosts in types I, II, and III, respectively. Because of the different oxidation state of Mn, the rocks of types I and II are termed as “reduced” and the rocks of type III, as “oxidized”. The formation of a certain mineralogical type of metamorphic assemblage is controlled by the content of organic matter in the primary sediments. The sequence type I → type II → type III reflects the decrease in the amount of organic matter in metalliferous sediments. Mineralogical data indicate that manganese in the primary sediments accumulated in a silicate form (MnSi gel, glass, etc). During diagenesis, the Mn–Si phase was transformed to neotokite with subsequent formation of caryopilite and further crystallization of pyroxmangite, rhodonite, tephroite, and other silicates due to reactions involving caryopilite. The hydrated Mn-silicates (caryopilite and/or friedelite) and the spatially associated parsettensite, stilpnomelane, and other minerals are the index minerals of the low grade metamorphism. Under PT conditions of prehnite–pumpellyite facies, nearly 70% of silicate minerals are hydrous. The metamorphosed Mn-bearing sediments are characterized by the low-temperature caryopilite (or tephroite-caryopilite-pyroxmangite ± rhodonite) and the high-temperature caryopilite-free (or tephroite-pyroxmangite ± rhodonite) facies. Their PT conditions correspond to zeolite and prehnite-pumpellyite (the low-temperature) and green schist and higher grade (the high-temperature) facies. 相似文献
16.
从地洼成矿作用看中国某些优质锰矿的成因与远景 总被引：2，自引：0，他引：2
何知礼 《大地构造与成矿学》1990,14(3):203-210
研究发现中国某些优质锰矿,属复成矿床,它们都是地洼成矿作用的产物。福建连城锰矿就是典型实例,类似矿床特别是复成风化锰矿,还见于闽西南-粤东北及湖南。滇东南一些锰矿,例如著名的斗南锰矿与白显锰矿的成因,也可能与地洼成矿作用有一定联系。分析对比了一些优质复成锰矿和一些较贫的复成锰矿的成矿地质条件。从地洼成矿作用可以看出中国某些优质锰矿的成因与远景。提出在中国东南地洼区、南北地洼区南端及云贵地洼区某些地方,寻找优质复成风化锰矿与复成菱锰矿—硫锰矿矿床是较有希望的。 相似文献
17.
Ibrahim A. Salem Mohamed E. Ibrahim Mohamed Abd El Monsef 《Arabian Journal of Geosciences》2012,5(3):385-406
The present work deals with the geology, mineralogy, geochemistry, and origin of the metagabbroic-hosted manganese deposits at Wadi Maliek in the southern Eastern Desert of Egypt. The manganese veins are found in the shear zones and channel ways of the fault planes within the metagabbroic rocks pointing to those hydrothermal solutions carrying manganese and iron load penetrating along these fractures. These faults are striking N 80° E?CS 80° W with dipping 65°. These veins vary in thickness from 15?cm up to 125?cm wide; each vein may show difference in thickness from bottom to top. Microscopic examinations, X-ray diffraction, infrared spectral, differential thermal (DTA), thermogravimetric (TGA), and ESEM-EDAX analyses revealed that the manganese minerals consist mainly of pyrolusite, psilomelane, and ramsdellite. Goethite and hematite are the common iron minerals. Petrographically, the manganese deposits can be classified into three ore types based on the predominance of manganese and iron minerals: manganese, manganese?Ciron, and iron ore types. The geochemistry of Maliek deposits indicated that the total averages of some major oxides in manganese, manganese?Ciron, and iron ore types are respectively as follows: SiO2 (15.64%, 11.52%, and 20.58%), MnO (39.9%, 17.81%, and 0.77%), FeO* (7.13%, 33.31%, and 37.08%), CaO (5.89%, 5.82%, and 5.32%), and Na2O (1.04%, 1.61%, and 1.53%). With regard to trace elements, the Maliek manganese deposits are rich in Zn, Ba, Pb, Sr, and V. Based on the geological, mineralogical, and geochemical results, the studied manganese deposits are considered to be precipitated from hydrothermal solution. 相似文献
18.
本文在前人研究的基础上,概述了地层、构造和岩浆岩对我国银矿产出和分布的控制特点和规律:银矿赋矿地层以泥盆系最多,其次是中元古界、石炭系等,按赋矿岩性则以碳酸盐岩最多,变质岩次之;古老地块边缘裂陷槽和增生带、区域性深大断裂及多组构造汇聚部位及陆相断陷盆地是我国银矿产出和分布的重要控制因素;海相火山岩、陆相火山岩、侵入岩控制着我国不同地区和类型的银矿产出。分析了我国大型、超大型银矿的找矿前景和方向,提出川西义敦岛弧带、川滇黔接壤地区和大兴安岭成矿带是大型、超大型银矿的重要找矿区,继续加强我国陆相火山岩型大型、超大型银矿的寻找和研究;重视在萤石矿床分布区、黑色岩系分布区找银矿及火山岩地区找银锰型矿床;充分利用银矿找钨、锡等其他矿种。 相似文献