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1.
Numerical models of atmosphere–ocean circulation are widely used to understand past climate and to project future climate change. Although the same laws of physics, chemistry, and fluid dynamics govern any general circulation model, each model’s formulations and parameterizations are different, yielding different projections. Notwithstanding, models within an ensemble will have varying degrees of similarity for different outputs of interest. Multi-model ensembles have been used to increase forecast skill by using simple or weighted averages where weights have been obtained by considering factors such as estimated model bias and consensus with other models (Giorgi and Mearns, J. Clim. 15:1141–1158, 2002, Geophys. Res. Lett. 30:1629–1632, 2003; Tebaldi et al., Geophys. Res. Lett. 31:L24213, 2004, J. Clim. 18:1524–1540, 2005). This paper considers an alternative view of multi-model ensembles. For use with the North American Regional Climate Change Assessment Program (NARCCAP), multivariate statistical models are employed to characterize modes of similarity within the members of an ensemble. Specifically, we propose a spatially-correlated latent variable model which facilitates the exploration of when, where, and how regional climate models are similar, and what factors best predict observed locations of model convergence.  相似文献   

2.
Criteria of ecological estimation of temperature conditions for functioning of land ecosystems are examined in this work. It has been shown that soil climate has a key influence on the spatial distribution of phytocenosises of the East European Plain. To characterize the temperature regime of soils, it is proposed, together with active temperatures (>10°C), to use ecologically sufficient (5–10°C) and ecologically optimal (10–22°C) temperatures. Some parameters concerning the different depths of the root layer (20 cm, 40 cm, 80 cm, 160 cm, and 320 cm) are proposed for use as the criteria of ecological estimation of the temperature regime. On the basis of the mentioned criteria, the main regularities of the temperature regime of East European Plain soils have been examined.  相似文献   

3.
Hydrological impacts from climate change are of principal interest to water resource policy-makers and practicing engineers. Predictive climatic models have been extensively investigated to quantify the impacts. Palaeoclmatic investigations, on the other hand, show unequivocal and strong periodicity of climate variations in proxy evidence. Yet how to use the periodicity in future hydroclimatic timing and forecasting has received less attention. This paper examines the periodicity in Pleistocene–Holocene glacial–interglacial events and in modern precipitation records, and discusses a way in which the periodicity is used for hydroclimatic predictions. The analysis, based on published CO2, ΔT2H) and δ18O proxy data of polar ice cores and deep oceanic benthic fossils, shows a periodicity in a ~100, ~40 or 25 kyear duration consistent with Milankovitch orbital regulations during the glacial–interglacial periods. On a fine time scale, millennium and multi-decadal periodicity is observed in high-resolution proxy variations of Greenland ice cores and in instrumental precipitation records of the contiguous USA. A basic periodicity of decadal and multi-decadal changes in ~20 and ~10–15 year duration is apparent in wavelet frequency analysis of both ice core proxy and precipitation data. While the kyear-scale periodicity is found of global prevalence, the millennium and decadal variations vary in space and are region-specific. Based on these findings, a generalized time-downscaling hierarchy of periodicity is proposed as a potential approach for timing and forecasting future hydroclimatic conditions at a resolution relevant to the water resources engineering and management.  相似文献   

4.
The standard thermodynamic properties at 25°C, 1 bar (ΔG fo, ΔH fo, S o, C Po, V o, ω) and the coefficients of the revised Helgeson–Kirkham–Flowers equations of state were evaluated for several aqueous complexes formed by dissolved metals and either arsenate or arsenite ions. The guidelines of Shock and Helgeson (Geochim Cosmochim Acta 52:2009–2036, 1988) and Sverjensky et al. (Geochim Cosmochim Acta 61:1359–1412, 1997) were followed and corroborated with alternative approaches, whenever possible. The SUPCRT92 computer code was used to generate the log K of the destruction reactions of these metal–arsenate and metal–arsenite aqueous complexes at pressures and temperatures required by the EQ3/6 software package, version 7.2b. Apart from the AlAsO4o and FeAsO4o complexes, our log K at 25°C, 1 bar are in fair agreement with those of Whiting (MS Thesis, Colorado School of Mines, Golden, CO, 1992). Moreover, the equilibrium constants evaluated in this study are in good to fair agreement with those determined experimentally for the Ca–dihydroarsenate and Ca–hydroarsenate complexes at 40°C (Mironov et al., Russ J Inorg Chem 40:1690, 1995) and for Fe(III)–hydroarsenate complex at 25°C (Raposo et al., J Sol Chem 35:79–94, 2006), whereas the disagreement with the log K measured for the Ca–arsenate complex at 40°C (Mironov et al., Russ J Inorg Chem 40:1690, 1995) might be due to uncertainties in this measured value. The implications of aqueous complexing between dissolved metals and arsenate/arsenite ions were investigated for seawater, high-temperature geothermal liquids and acid mine drainage and aqueous solutions deriving from mixing of acid mine waters and surface waters. Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users.  相似文献   

5.
The Beer–Lambert law is traditionally used to determine water and carbon concentrations in glasses from their infrared (IR) spectra. In practice, this method requires estimation of the thickness and density of the glass as well as the calibration of the molecular absorptivities of the species concerned. All of these parameters can be sources of practical difficulties and analytical uncertainty. These weaknesses in the application of the Beer–Lambert law have been overcome by an empirical analysis of the infrared spectra. Using a set of 292 spectra obtained on 113 natural and experimental tholeiitic glasses (SiO2 48.5–51 wt%; water contents 0–4000 ppm H2O), it can be shown that the thickness–density (ρ d) product of a glass sample can be directly and reliably inferred from its IR spectrum. This allows the Beer–Lambert law to be rewritten. The new form no longer requires thickness or density estimations to determine volatile contents. Moreover, if needed, the thickness of the glass slab can also be accurately determined from the IR spectra. This new method is developed for quantitative determination of water concentrations in MORB glasses but can also be applied to any minor species (carbon, sulfur, etc.) provided it is active in the IR domain and that a suitable independent frequency of IR absorption can be identified. Precision is about 60 ppm H2O on O–H contents. This method, tested on natural and experimental MORB-type glasses, can be applied to any chemical composition provided a set of reference spectra is available. Received: 16 September 1999 / Accepted: 18 February 2000  相似文献   

6.
A temperature–time path was constructed for high-temperature low-pressure (HT–LP) migmatites of the Bayerische Wald, internal zone of the Variscan belt, Germany. The migmatites are characterised by prograde biotite dehydration melting, peak metamorphic conditions of approximately 850 °C and 0.5–0.7 GPa and retrograde melt crystallisation at 800 °C. The time-calibration of the pressure–temperature path is based on U–Pb dating of single zircon and monazite grains and titanite separates, on 40Ar/39Ar ages obtained by incremental heating experiments on hornblende separates, single grains of biotite and K-feldspar, and on 40Ar/39Ar spot fusion ages of biotite determined in situ from sample sections. Additionally, crude estimates of the duration of peak metamorphism were derived from garnet zoning patterns, suggesting that peak temperatures of 850 °C cannot have prevailed much longer than 2.5 Ma. The temperature–time paths obtained for two areas approximately 30 km apart do not differ from each other considerably. U–Pb zircon ages reflect crystallisation from melt at 850–800 °C at 323 Ma (southeastern area) and 326 Ma (northwestern area). The U–Pb ages of monazite mainly coincide with those from zircon but are complicated by variable degrees of inheritance. The preservation of inherited monazite and the presence of excess 206Pb resulting from the incorporation of excess 230Th in monazite formed during HT–LP metamorphism suggest that monazite ages in the migmatites of the Bayerische Wald reflect crystallisation from melt at 850–800 °C and persistence of older grains at these temperatures during a comparatively short thermal peak. The U–Pb ages of titanite (321 Ma) and 40Ar/39Ar ages of hornblende (322–316 Ma) and biotite (313–309 Ma) reflect cooling through the respective closure temperatures of approximately 700, 570–500 and 345–310 °C published in the literature. Most of the feldspars' ages (305–296 Ma) probably record cooling below 150–300 °C, while two grains most likely have higher closure temperatures. The temperature–time paths are characterised by a short thermal peak, by moderate average cooling rates and by a decrease in cooling rates from 100 °C/my at temperatures between 850–800 and 700 °C to 11–16 °C/my at temperatures down to 345–310 °C. Further cooling to feldspar closure for Ar was probably even slower. The lack of decompressional features, the moderate average cooling rates and the decline of cooling rates with time are not easily reconciled with a model of asthenospheric heating, rapid uplift and extension due to lithospheric delamination as proposed elsewhere. Instead, the high peak temperatures at comparatively shallow crustal levels along with the short thermal peak require external advective heating by hot mafic or ultramafic material. Received: 7 July 1999 / Accepted: 28 October 1999  相似文献   

7.
To estimate the behavior of Au, Pd, REE, and Y in magmatic and postmagmatic processes, a series of experimental studies on the solubility of noble metals and REE in magma, magmatic fluid, and hydrothermal solutions has been performed in wide temperature and pressure ranges (300–400°C, 860–1350°C; 1–14 kbar). The coefficients of Au and Pd partitioning (D F/L) between fluid and tholeiitic melt have been determined. Depending on P, T, and the composition of the system, they vary from 1 to 11 for Au and 0.02 to 1 for Pd. The phase solubility technique was used to determine Au and Pd solubility in hydrothermal fluid. The effects of temperature, composition, and fluid acidity on Au and Pd solubility have been estimated. The high solubility of these metals in aqueous chloride solutions has been established for both Au (28–803 mg/kg at T = 300°C, 305–1123 mg/kg at T = 350°C, and 330–1400 mg/kg at T = 400°C) and Pd (40–126 mg/kg at T = 300°C, 62–152 mg/kg at T = 350°C, and 20–210 mg/kg at T = 400°C). The coefficients of REE and Y partitioning (D F/L) between fluid and tholeiitic or alkaline melts have been determined. They vary from 0.00n to 2 depending on P, T, and fluid composition. The experimental data on Au and Pd solubility in solutions and magmatic fluids and the wide variation of REE D F/L between fluid and melt show that magmatic and hydrothermal fluids are efficient agents of Au, Pd, and REE transfer and fractionation. The obtained experimental data were used for elucidating sources of fluids and their role in the genesis of Au-Pd-REE occurrences in the Subpolar Urals.  相似文献   

8.
New U–Pb, Re–Os, and 40Ar/39Ar dates are presented for magmatic and hydrothermal mineral phases in skarn- and porphyry-related ores from the Nambija and Pangui districts of the Subandean zone, southeastern Ecuador. Nambija has been one of the main gold-producing centers of Ecuador since the 1980s due to exceptionally high-grade ores (average 15 g/t, but frequently up to 300 g/t Au). Pangui is a recently discovered porphyry Cu–Mo district. The geology of the Subandean zone in southeastern Ecuador is dominated by the I-type, subduction-related, Jurassic Zamora batholith, which intrudes Triassic volcanosedimentary rocks. The Zamora batholith is in turn cut by porphyritic stocks, which are commonly associated with skarn formation and/or porphyry-style mineralization. High precision U–Pb and Re–Os ages for porphyritic stocks (U–Pb, zircon), associated prograde skarn (U–Pb, hydrothermal titanite), and retrograde stage skarn (Re–Os, molybdenite from veins postdating gold deposition) of the Nambija district are all indistinguishable from each other within error (145 Ma) and indicate a Late Jurassic age for the gold mineralization. Previously, gold mineralization at Nambija was considered to be Early Tertiary based on K–Ar ages obtained on various hydrothermal minerals. The new Jurassic age for the Nambija district is slightly younger than the 40Ar/39Ar and Re–Os ages for magmatic–hydrothermal minerals from the Pangui district, which range between 157 and 152 Ma. Mineralization at Nambija and Pangui is associated with porphyritic stocks that represent the last known episodes of a long-lived Jurassic arc magmatism (∼190 to 145 Ma). A Jurassic age for mineralization at Nambija and Pangui suggests that the Northern Andean Jurassic metallogenic belt, which starts in Colombia at 3° N, extends down to 5° S in Ecuador. It also adds a new mineralization style (Au-skarn) to the metal endowment of this belt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

9.
The Antarctic Ice Sheet plays a major role in the global system, and the large ice streams discharging into the circumpolar sea represent its gateways to the world’s oceans. Satellite radar altimeter data provide an opportunity for mapping surface elevation at kilometerresolution with meteraccuracy. Geostaristical methods have been developed for the analysis of these data. Applications to Seasat data and data from the Geosat Exact Repeat Mission indicate that the grounding line of Lambert Glacier/Amery Ice Shelf, the largest ice stream in East Antarctica, has advanced 10–12 km between 1978 and 1987–89. The objectives of this paper are to explore possibilities and limitations of satellite-altimetry-based mapping to capture changes for shorter time windows and for smaller areas, and to investigate some methodological aspects of the data analysis. We establish that one season of radar altimeter data is sufficient for constructing a map. This allows study of interannual variation and is the key for a limeseries analysis approach to study changes in ice streams. Maps of the lower Lambert Glacier and the entire Amery Ice Shelf are presented for austral winters 1978, 1987, 1988, and 1989. As a first step toward understanding the dynamics of the ice-stream/iceshelf system, elevation changes are calculated for grounded ice, the grounding zone, and floating ice. In the absence of (sufficient) surface gravity control for the Lambert Glacier/Amery Ice Shelf area, altimetry-based maps may facilitate improvement of geoid models as they provide constraints on the terrain correction in the inverse gravimetric problem.  相似文献   

10.
In order to characterize the post-Svecofennian tectonothermal evolution of the Fennoscandian Shield, 40Ar–39Ar biotite and some 40Ar–39Ar muscovite geochronological data are reported from a total of 30 surface outcrop and 1,000 m long borehole samples at Forsmark, central Sweden. The 13 surface samples were collected across 3 branches of a major WNW to NW trending system of deformation zones, whereas the boreholes were drilled within a tectonic lens, in between two of these zones. The 40Ar–39Ar biotite ages indicate that the present erosion surface, in central Sweden, cooled below c. 300°C at 1.73–1.66 Ga, and that the rocks could have accommodated strain in a brittle manner between 1.8 and 1.7 Ga. The variation in surface ages is suggested to be due to fault along the large WNW to NW trending deformation zones, following the establishment of a sub-Cambrian peneplain. The minor variation of ages within a single crustal block may be due to disturbance along ENE to NNE trending fracture zones. Possible cooling paths, derived from 40Ar–39Ar hornblende, muscovite and biotite ages, were calculated for the time interval from 1.80 to 1.67 Ga, when the area cooled from c. 500 to 300°C. Cooling rates of 1.9–4°C/m.y. have been attained. Between 1.68 and 1.64 Ga, uplift rates of c. 22 m/m.y. were calculated from borehole 40Ar–39Ar biotite data. Tectonothermal histories, inferred from the combined cooling and uplift rates, are related to simple cooling after the Svecofennian orogeny, to crustal movement in response to far-field effects of c. 1.7 Ga orogenic activities further to the west or to a combination of these possibilities.  相似文献   

11.
Application of multiple chronometers (including U–Pb and 40Ar/39Ar geochronology and zircon and apatite (U–Th)/He thermochronology) to porphyry intrusions at the Bajo de la Alumbrera porphyry copper–gold deposit, Argentina, reveals a complex history of reheating that spans millions of years. Previous U–Pb geochronology, combined with our new 40Ar/39Ar data, shows that the multiple porphyritic intrusions at Bajo de la Alumbrera were emplaced during two episodes, the first at about 8.0 Ma (P2 and associated porphyries) and the second about a million years later (Early and Late P3 porphyries). Complex overprinting alteration events have obscured the earliest hydrothermal history of the deposit. By contrast, 40Ar/39Ar data reveal the close temporal relationship of ore-bearing potassic alteration assemblages (7.12 ± 0.13 Ma; biotite) to the emplacement of the P3 intrusions. Consistent with low closure temperatures, younger ages have been determined for associated hydrothermal alkali feldspar (6.82 ± 0.05 Ma and 6.64 ± 0.09 Ma). The temperature-sensitive Ar data also record an unexpected prolonged cooling history (to below 200°C) extending to 5.9 Ma. Our data suggest that the Bajo de la Alumbrera system underwent protracted cooling, after the collapse of the main hydrothermal system, or that one or more low-temperature (~100–200°C) reheating events occurred after emplacement of the porphyritic intrusions at Bajo de la Alumbrera. These have been constrained in part by our new 40Ar/39Ar data (including multidomain diffusion modeling) and (U–Th)/He ages. Single-grain (U–Th)/He ages (n = 5) for phenocrystic zircon from P2 and P3 intrusive phases bracket these thermal events to between 6.9 (youngest crystallization of intrusion) and 5.1 Ma. Multidomain modeling of alkali feldspar data (from both igneous and hydrothermal crystals) is consistent with the deposit cooling rapidly from magmatic temperatures to below about 300°C, with a more protracted history down to 150°C. We conclude that the late-stage low-temperature (150 to 200°C) thermal anomaly localized at Bajo de la Alumbrera resulted from radiation of heat and/or fluids sourced from deeper-seated magma bodies, emplaced beneath the deposit. To produce the observed thermal longevity of the porphyry system, magma bodies underlying the Bajo de la Alumbrera deposit must have been repeatedly replenished by new magma batches. Without replenishment, crystallization of the source magma will occur, and heat release will stop, leading to rapid cooling (in less than ten thousand years). The influx of deep-seated magma may have caused the development of late low-temperature hydrothermal alteration assemblages at Bajo de la Alumbrera, at the same time that mineralization formed at Agua Rica, some 25 km away. All available chronologic data for the Bajo de la Alumbrera deposit suggest that the hydrothermal system was active episodically over at least a three-million and possibly up to a four-million-year period. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

12.
A state-of-the-art regional climate modelling system, known as PRECIS (Providing REgional Climates for Impacts Studies) developed by the Hadley Centre for Climate Prediction and Research, UK is applied over the Indian domain to investigate the impact of global warming on the cyclonic disturbances such as depressions and storms. The PRECIS simulations at 50 × 50 km horizontal resolution are made for two time slices, present (1961–1990) and the future (2071–2100), for two socioeconomic scenarios A2 and B2. The model simulations under the scenarios of increasing greenhouse gas concentrations and sulphate aerosols are analysed to study the likely changes in the frequency, intensity and the tracks of cyclonic disturbances forming over north Indian Ocean (Bay of Bengal and Arabian Sea) and the Indian landmass during monsoon season. The model overestimates the frequency of cyclonic disturbances over the Indian subcontinent in baseline simulations (1961–1990). The change is evaluated towards the end of present century (2071–2100) with respect to the baseline climate. The present study indicates that the storm tracks simulated by the model are southwards as compared to the observed tracks during the monsoon season, especially for the two main monsoon months, viz., July and August. The analysis suggests that the frequency of cyclonic disturbances forming over north Indian Ocean is likely to reduce by 9% towards the end of the present century in response to the global warming. However, the intensity of cyclonic disturbances is likely to increase by about 11% compared to the present.  相似文献   

13.
According to records of 17 meteorological stations distributed in the study area, climate change of the middle Inner Mongolia in northern China was analyzed in this paper. Based on SPOT VGT data, combined with field investigation, local vegetation change was detected in the last 10 years. The results show that annual mean air temperature obviously rose, while precipitation slightly decreased in fluctuation in the study area during the last 50 years. Air temperature increasing rates are +0.318°C 10 year−1 during 1960-2009 and +0.423°C 10 year−1 during 1980–2009, while precipitation decreasing rates are −2.91 mm 10 year−1 during 1960–2009. There were five different dry or wet periods from the 1960s to the 2000s in order, and the wetter 1990s and the drier 2000s changed dramatically in the study area. Local climate totally tend to warm–dry conditions during the last 50 years. According to coefficient of variation (Cv) of yearly growing-season cumulative NDVI value and yearly NDVI maximum in pixel scale, vegetation had experienced huge temporal and spatial variation during the last 10 years. Recently, frequent droughts and dust storms seriously affected local agriculture and grazing activities, and resulted in heavy economic loss, especially over the drought period of 1999–2001. Faced with those drought disasters accompanied with strong dust storms, the local authorities proposed the enclosing-transferring strategy and made great efforts to adapt overt climate change and improve environment, including making selective emigration, decreasing livestock numbers, fencing grasslands and building forage production bases with irrigation instruments and actively adjusting industry structure. However, some effects and potential problems of this adaptation strategy still need to be comprehensively assessed further in longer time scales and aimed at different sub-regions.  相似文献   

14.
A series of global actions have been made to address climate change. As a recent developed climate policy, Intended Nationally Determined Contributions (INDC) have renewed attention to the importance of exploring temperature rise levels lower than 2 °C, in particular a long-term limit of 1.5 °C, compared to the preindustrial level. Nonetheless, achieving the 2 °C target under the current INDCs depends on dynamic socioeconomic development pathways. Therefore, this study conducts an integrated assessment of INDCs by taking into account different Shared Socioeconomic Pathways (SSPs). To that end, the CEEP-BIT research community develops the China’s Climate Change Integrated Assessment Model (C3IAM) to assess the climate change under SSPs in the context of with and without INDCs. Three SSPs, including “a green growth strategy” (SSP1), “a more middle-of-the-road development pattern” (SSP2) and “further fragmentation between regions” (SSP3) form the focus of this study. Results show that after considering INDCs, mitigation costs become very low and they have no evident positive changes in three SSPs. In 2100, a temperature rise would occur in SSP1-3, which is 3.20, 3.48 and 3.59 °C, respectively. There are long-term difficulties to keep warming well below 2 °C and pursue efforts toward 1.5 °C target even under INDCs. A drastic reduction in greenhouse gas emissions is needed in order to mitigate potentially catastrophic climate change impacts. This work contributes on realizing the hard link between the earth and socioeconomic systems, as well as extending the economic models by coupling the global CGE model with the economic optimum growth model. In C3IAM, China’s energy consumption and emissions pattern are investigated and refined. This study can provide policy makers and the public a better understanding about pathways through which different scenarios could unfold toward 2100, highlights the real mitigation and adaption challenges faced by climate change and can lead to formulating effective policies.  相似文献   

15.
Recent trends in pre-monsoon daily temperature extremes over India   总被引:6,自引:0,他引:6  
Extreme climate and weather events are increasingly being recognized as key aspects of climate change. Pre-monsoon season (March–May) is the hottest part of the year over almost the entire South Asian region, in which hot weather extremes including heat waves are recurring natural hazards having serious societal impacts, particularly on human health. In the present paper, recent trends in extreme temperature events for the pre-monsoon season have been studied using daily data on maximum and minimum temperatures over a well-distributed network of 121 stations for the period 1970–2005. For this purpose, time series of extreme temperature events have been constructed for India as a whole and seven homogeneous regions, viz., Western Himalaya (WH), Northwest (NW), Northeast (NE), North Central (NC), East coast (EC), West coast (WC) and Interior Peninsula (IP).  相似文献   

16.
High-alumina basalts from seven High-Andean stratovolcanoes (37 °30′S to 41 °S) have major and trace element (including rare earth elements, REE) that are consistent with derivation by partial melting (typically 10–15%) of garnet-free peridotite followed by fractional crystallization of olivine and pyroxene. High-alumina basalts from two stratovolconoes require significantly lower degrees of melting (<5%) or melting of an incompatible, element-enriched source. However, a poorly understood feature of all of these basalts-and calc-alkaline rocks in general-is the mechanism for causing their low TiO2 and heavy REE content relative to oceanic basalts. Further north in Chile (33 °–34 °S and 21 °–22 °S) amphibole-bearing andesites have REE abundances consistent with derivation from a garnet-bearing source such as incompatible, element-rich eclogite (e.g., Franciscan eclogites) or garnet peridotite. The marked petrological and geochemical changes along strike of the Andes are probably related to the varying nature of the subduction process; e.g., dips of the downgoing slab varying from 10 to 30 °.  相似文献   

17.
18.
Air pollution has been a major transboundary problem and a matter of global concern for decades. Climate change and air pollution are closely coupled. Just as air pollution can have adverse effects on human health and ecosystems, it can also impact the earth’s climate. As we enter an era of rapid climate change, the implications for air quality need to be better understood, both for the purpose of air quality management and as one of the societal consequences of climate change. In this study, an attempt has been made to estimate the current air quality to forecast the air quality index of an urban station Kolkata (22.65°N, 88.45°E), India for the next 5 years with neural network models. The annual and seasonal variability in the air quality indicates that the winter season is mostly affected by the pollutants. Air quality index (AQI) is estimated as a geometric mean of the pollutants considered. Different neural network models are attempted to select the best model to forecast the AQI of Kolkata. The meteorological parameters and AQI of the previous day are utilized to train the models to forecast the AQI of the next day during the period from 2003 to 2012. The selection of the best model is made after validation with observation from 2013 to 2015. The radial basis functional (RBF) model is found to be the best network model for the purpose. The RBF model with various architectures is tried to obtain precise forecast with minimum error. RBF of 5:5-91-1:1 structure is found to be the best fit for forecasting the AQI of Kolkata.  相似文献   

19.
Permian granulites associated with noritic intrusions and websterites are a common feature of the post-Variscan European crust. Such granulites are common in the Southern Alps (e.g. Ivrea Zone), but occur only in the Gruf Complex in the Central Alps. To understand the geotectonic significance of these granulites, in particular in the context of Alpine migmatisation, zircons from 15 high-grade samples have been U–Pb dated by SHRIMP II analysis. Oscillatory zoned zircons from charnockite sheets, interpreted as melts generated through granulite facies fluid-absent biotite melting at 920–940°C, yield ages of 282–260 Ma. Some of these zircons contain inclusions of opx, unequivocally attributable to the granulite facies, thus confirming a Permian age for the charnockites and associated granulites. Two samples from an enclave-rich orthogneiss sheet yield Cambrian and Ordovician zircon cores. Two deformed leucogranites and six ortho- and augengneisses, which compose two-thirds of the Gruf Complex, give zircon ages of 290–260 Ma. Most zircons have milky rims with ages of 34–29 Ma. These rims date the Alpine amphibolite facies migmatisation, an interpretation confirmed by directly dating a leucosome pocket from upper amphibolite facies metapelites. The Gruf charnockites associated with metre-scale schlieren and boudins of opx–sapphirine–garnet–granulites, websterites and gabbronorites can thus be identified as part of the post-Variscan European lower crust. A geotectonic reconstruction reveals that this piece of lower crust stranded in the (European) North upon rifting of the Neotethys, such contrasting the widespread granulite units in the Southern Alps. Emplacement of the Gruf lower crust into its present-day position occurred during migmatisation and formation of the Bergell Pluton in the aftermath of the breakoff of the European slab.  相似文献   

20.
This paper discusses the largest electrum units precipitated in calcite of the final (“nonproductive”) stage of ore formation. Notably, during examination of the chemical composition of these gold grains, sphalerite and other minerals belonging to the early (“productive”) association have been found. The results of thermo- and cryometric investigations of fluid inclusions in calcite of the Agatovskoe deposit have indicated that in the composition of two-phase fluid solutions of admixtures, NaCl, KCl, and MgCl dominated. This is evidenced by chloride eutectics of the admixture solutions in the temperature interval from −35 to −39°C. The complete homogenization of the fluid admixtures takes place in a narrow temperature interval (from 206 to 213°C) and concentration of salts is 3.7–6.0 mass % in NaCl equivalent. The density of the fluid changes starting from 0.88–0.89 g/cm3. The derived homogenization temperatures correspond to the temperatures of gold deposition, since the pressure during formation of gold veins in the deposit was small.  相似文献   

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