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1.
J. A. Dalziel 《Marine Chemistry》1995,49(4)
The vertical distribution of reactive mercury has been measured at two stations in the eastern North Atlantic and one station in the southeast Atlantic in conjunction with the IOC Open Ocean Baseline Survey. The average concentrations of reactive Hg in vertical profiles ranged from 0.70 to 1.07 pM with the highest values found at the northeast Atlantic stations and the lowest at the southeast station. No significant concentration gradients were found below the surface mixed layer at the two stations in the eastern North Atlantic. At station 7, in the southeast Atlantic, an increase in reactive Hg was noted in the water adjacent to the mixed layer (35–200 m) which was coincident with an oxygen depletion, down to 20% saturation at 200 m. The concentration of reactive Hg in the North Atlantic Deep Water (0.48–1.34 pM), the Antarctic Intermediate Water (0.47 pM), the Antarctic Bottom Water (0.67–1.25 pM), and the Mediterranean Outflow Water (0.83–1.06 pM) were noted. The trends in Hg concentration in the water masses between stations showed the concentration decreasing with distance from the water mass source except for Hg in the Antarctic Bottom Water. The increase noted in this water mass was attributed to mixing with North Atlantic Deep Water and or release from bottom sediments. 相似文献
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A workshop held in Halifax, Nova Scotia, Canada, brought together marine policy makers, resource users and experts to discuss spatial planning in the marine environment. Participants explored concepts of ocean zoning and learned from other jurisdictions and related integrated management initiatives. An ocean user perspectives panel featured plenary addresses on the significance of ocean zoning to various sectors. Discussions at the workshop emphasized the need for involving all key players and clearly defining terms used in the spatial planning process. 相似文献
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Samples from eleven stations in the Sargasso Sea, Slope Water, and continental shelf water of the Northwest Atlantic have been analyzed for total iron by atomic absorption spectrophotometry. Vertical profiles for iron and associated temperature and nutrient data were obtained at the five open-ocean stations. Data from six stations provided a transect across the continental shelf into the apex of the New York Bight.At open-ocean stations, iron was depleted near the surface to levels of about 1–2 nmol kg?1 and increased to levels of about 4–7 nmol kg?1 in the vicinity of the oxygen minimum. A characteristic bottom-water maximum was observed at stations where closely spaced, near-bottom sampling was conducted. This feature was due at least partially to resuspension of particulate iron associated with the nepheloid layer.Comparison of total iron concentrations (available upon digestion in concentrated nitric acid) to those of filtered samples (0.4 μm) at one Slope Water station indicated that about 40% of the available iron in the water column was associated with the particulate phase. Near the surface, in the vicinity of the chlorophyll maximum, iron was present almost totally in particulate form. The dissolved fraction increased to approximately 50% at the nutrient maximum and approached 100% in the mid-portion of the water column. In deeper waters, the particulate fraction again became important, increasing to approximately 80% of the total iron in the near-bottom maximum.In the apex of the New York Bight, iron levels in excess of 200 and 500 nmol kg?1 were observed in surface and bottom waters, respectively. In the mid-continental shelf region, the iron distribution does not appear to be greatly influenced by coastal sources; within 65 km of the coastline, iron levels approached open-ocean values. 相似文献
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《African Journal of Marine Science》2013,35(1):71-79
Surface drift in the South-East Atlantic Ocean is described using historical shipdrift data. The Benguela Current has a width of 200 km in the south and 750 km in the north. The mean speeds of the current vary from <11 cm·s?1 to a maximum of 23 cm·s?1 The highest current speeds occur during summer in the southern regions and during winter in the northern regions, and this seasonality corresponds well with seasonal wind speeds. Eddy kinetic energy is enhanced in the Subtropical Convergence zone and is highest in the general vicinity of the Agulhas Current retroflection. The Subtropical Convergence is evident as a line where northward Ekman drift terminates. 相似文献
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俄罗斯科学院海洋研究所实验室对大西洋表层水中悬浮物的物质成分及其在水中的定量分布进行了测定,以确定不同来源悬浮物的份额.研究材料来自2001-2005年间7个春季和秋季的科研船航次勘探.此外,还采集了大气中的悬浮体,作为开放性海洋中物质来源之一. 相似文献
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Dissolved and total dissolvable manganese concentrations have been measured at four stations in the western North Atlantic Ocean. Total dissolvable manganese concentrations are high in surface waters, decrease to uniformly low levels throughout the bulk of the water column, and increase in the bottom nepheloid layer. Dissolved Mn (Mnd) concentrations follow the total dissolvable concentrations throughout the surface and deep waters but do not increase in the near-bottom waters.Deep water concentrations of Mnd decrease from 30 ng l?1 in the Newfoundland Basin to 20 ng l?1 in the Sargasso Sea. This change and other features of the deep water distribution of dissolved manganese could be associated with the slow oxidation of Mn2+ to MnO2. There is also evidence at one station of scavenging of manganese from the dissolved phase in the near-bottom layer which may again be related to the kinetics of manganese oxidation. 相似文献
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Measurements of zinc and zinc complexation by natural organic ligands in the northeastern part of the Atlantic Ocean were made using cathodic stripping voltammetry with ligand competition. Total zinc concentrations ranged from 0.3 nM in surface waters to 2 nM at 2000 m for open-ocean waters, whilst nearer the English coast, zinc concentrations reached 1.5 nM in the upper water column. In open-ocean waters zinc speciation was dominated by complexation to a natural organic ligand with conditional stability constant (log KZnL′) ranging between 10.0 and 10.5 and with ligand concentrations ranging between 0.4 and 2.5 nM. The ligand was found to be uniformly distributed throughout the water column even though zinc concentrations increased with depth. Organic ligand concentrations measured in this study are similar to those published for the North Pacific. However the log KZnL′ values for the North Atlantic are almost and order of magnitude lower than those reported by Bruland [Bruland, K.W., 1989. Complexation of zinc by natural organic-ligands in the central North Pacific. Limnol. Oceanogr., 34, 269–285.] using anodic stripping voltammetry for the North Pacific. Free zinc ion concentrations were low in open-ocean waters (6–20 pM) but are not low enough to limit growth of a typical oceanic species of phytoplankton. 相似文献
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Anne Willem Omta Jorn Bruggeman Bas Kooijman Henk Dijkstra 《Journal of Sea Research》2009,62(2-3):179
The growth, sinking and remineralisation of phytoplankton constitute the soft-tissue carbon pump. Here we derive the expression for the strength of this carbon pump in terms of the nutrient utilisation and the carbon:nutrient ratio of plankton. Furthermore, we aim to determine how the physical environment affects this carbon pump. Thereto, we have used a plankton physiological model with a novel representation of the effect of temperature and light on plankton stoichiometry; it predicts that the effect of temperature on the carbon:nutrient ratio depends on the light conditions. Using this model combined with a mechanistic model for the mixed layer, we have studied the biological carbon pump at the BATS site and at various locations along a meridional transect through the Atlantic Ocean. Our results suggest that the soft-tissue carbon pump is stronger at mid-latitudes than in the (sub-)tropics and near the poles as a consequence of latitudinal variations in algal stoichiometry. 相似文献
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《Marine Chemistry》2001,73(3-4):291-303
Oxygen and phosphate measurements from two sections across the Norwegian Atlantic Current, the Gimsøy-NW section from 67.5°N 9°E to 71.5°N 1°E and the Bjørnøya-W section along 74.5°N from 7 to 15°E, are used to estimate oxygen fluxes in the surface layer and between the atmosphere and the ocean. Vertical entrainment velocities of 0.9 m day−1 for the winter season and 0.1 m day−1 for the summer season are found and applied to the upper 300 m. The resulting oxygen fluxes to the surface layer driven by this vertical mixing are 0.58±0.05 and 0.27±0.02 mol O2 m−2 year−1 at the Gimsøy-NW and Bjørnøya-W sections, respectively. Oxygen fluxes to the surface layer due to phytoplankton production are 2.6 and 3.4 mol O2 m−2 year−1, which represent the net community production at the two sections. Estimated uncertainties in these numbers are ±15%. The surface water is a sink for atmospheric oxygen during fall and winter and a source during the productive season for both sections. On an annual basis there is a net uptake of oxygen from the atmosphere, 3.4±0.4 mol O2 m−2 year−1 at the Gimsøy-NW section and 4.9±0.5 mol O2 m−2 year−1 at the Bjørnøya-W. A decrease in temperature of 1°C to 1.5°C seen between the Gimsøy-NW section and the Bjørnøya-W section is the main reason for the increased atmospheric flux of oxygen at the latter section. An oxygen budget made for the area bounded by the two sections gives a net advective flux of oxygen out of the area of approximately 10 mol O2 m−2 year−1. The increased concentration of oxygen corresponding to the decrease in surface layer temperatures going northwards in the Norwegian Atlantic Current is mainly attributed to the air–sea oxygen exchange and phytoplankton production in this area. 相似文献
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《Deep Sea Research Part II: Topical Studies in Oceanography》1999,46(5):979-990
Total (unfiltered) silver concentrations in higher latitudes of the North Atlantic (52–68°N) are reported for the second Intergovernmental Oceanographic Commission (IOC) Global Investigation of Pollutants in the Marine Environment (GIPME) baseline survey of 1993. These silver concentrations (0.69–7.2 pM) are oceanographically consistent with those (0.24–9.6 pM) previously reported for lower latitudes in the eastern North and South Atlantic (Flegal et al., 1995). However, surface (⩽200 m) water concentrations of silver (0.69–4.6 pM) in the northern North Atlantic waters are, on average, ten-fold larger than those (0.25 pM) considered natural background concentrations in surface waters of the central Atlantic. In contrast, variations in deep far North Atlantic silver concentrations are associated with discrete water masses. Consequently, the cycling of silver in the far North Atlantic appears to be predominantly controlled by external inputs and the advection of distinct water masses, in contrast to the nutrient-like biogeochemical cycling of silver observed in the central Atlantic and Pacific oceans. 相似文献
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Oceanology - Multielement chemical analysis and oxygen isotopic data has been employed for the first time to study the distribution of certain geochemical indicators in a sediment core recovered on... 相似文献
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巨大的海洋盆地是天然的大自然实验室 ,在其中根据某个海底地段的地球动力学机制特征 ,展开了成矿作用过程。对它们进行各方面和多样性的详细研究给地质学家提供了巨大的可能性来获得现在发生的成矿过程信息和利用研究陆上金属矿床时所获得的资料 ,而后者中的大部分形成于遥远的地质年代 (数百万年前 )。这个广泛应用于所有地质学科中的所谓现实主义态度 ,使专家们更深入地了解矿床的成因 ,并因此而提高了普查和预测未发现矿床的效率。无疑 ,将来海洋金属矿床本身也将成为人类生产实践的对象。在对洋底地质和矿产的综合工作中 ,应特别注意洋… 相似文献
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The areas that we studied in the North Atlantic (53 and 60°N) and in the Labrador Sea in the summer were characterized by a wide variability of the concentrations of dissolved and particulate organic matter and its elemental composition both in the surface and in the deep waters. The concentrations of dissolved and particulate Corg varied within 69–360 μM and 0.7–25.6 μM, respectively; the Norg and Porg contents varied within 1.4–22.2 μM and 0.02–0.86 μM, respectively. The maximal concentrations were registered in the photic layer and in the zones of mixing between the waters of different genesis. The particulate matter contribution to the total organic matter (OM) content varied from 0.5 to 15.4%. The waters of the photic layer contained more particulate Corg than those of the near-bottom layer. The values of the C/N molar ratios from the surface to the bottom over the entire aquatic area surveyed varied 5-to 6-fold; at that, the values of the C/P molar ratios varied more than tenfold. In the most productive waters, the values of the C/N ratios were close to the Redfield ratios (6–10). The values of the C/P molar ratios varied from 160 in the photic layer to 4831 in the deep waters. The pronounced non-uniformity in the spatial distribution of the OM and its elemental composition is caused not only by the penetration of the waters of different origins but also by the changes in the microplankton metabolism under mixing of these waters. 相似文献
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R. Chester 《Marine Chemistry》1982,11(1):1-16
The atmospheric, primary down-column and sedimentary fluxes of particulate aluminium (Alp) have been calculated for a number of regions in the Atlantic Ocean.The vertical down-column flux of Alp from Atlantic surface waters exhibits a strong geographical variation, and its magnitude is influenced by supply mechanisms, which control the surface Alp concentrations, and primary production, which affects the rate of down-column transport. Overall, the down-column transport of Alp is greatest in the marginal regions of the Atlantic. In the eastern margins the highest surface water concentrations are found in the region lying between ～30°N and ～10°N, i.e. under the general path of the northeast trades. In this region there is excellent agreement between the dry (i.e. 1 cm?1 s?1 deposition velocity) atmospheric flux (～80 000 ng Alp cm?2 y?1), the primary vertical down-column flux () and the sediment flux (～90 000 ng Alp cm?2 y?1). In the regions to the north (i.e. ～40°N to ～30°N) and to the south (i.e. ～10°N to ～5°S) the primary down-column Alp flux decreases to an average of ～19 000 μg cm?2 y?1, which makes a direct maximum contribution of ～20% of the sediment Alp requirement. In the open-ocean South Atlantic the primary down-column flux of Alp is ～3300 μg cm?2 y?1, this is similar to the dry (i.e. 1 cm?1 s?1 deposition velocity) atmospheric flux, and contributes ～20% of the Alp required by the underlying deep-sea sediment. 相似文献
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Nutrient irrigation of the North Atlantic 总被引：2，自引：1，他引：2
The North Atlantic, as all major oceans, has a remarkable duality in primary production, manifested by the existence of well-defined high and low mean primary production regions. The largest region is the North Atlantic Subtropical Gyre (NASTG), an anticyclone characterized by bowl shaped isopycnals and low production. The NASTG is surrounded at its margins by smaller cyclonic high-production regions, where these isopycnals approach the sea surface. The most extensive cyclonic regions are those at the latitudinal extremes, i.e. the subpolar and tropical oceans, though smaller ones do occur at the zonal boundaries. In this article we review historical data and present new analyses of climatological data and a selected number of hydrographic cruises in the western/northwestern and eastern/southeastern boundaries of the NASTG, with the objective of investigating the importance of upward epipycnal advection of nutrient-rich subsurface layers (irrigation) in maintaining high primary production in the euphotic layers. In the North Atlantic Subpolar Gyre (NASPG) irrigation implies intergyre exchange caused by the outcropping extension of the Gulf Stream (GS), following the formation of the deep winter mixed-layer. In the eastern boundary of the NASTG irrigation is attained through a permanent upwelling cell, which feeds the Canary Upwelling Current (CUC). In the southeastern corner irrigation occurs in fall, when the Guinea Dome (GD) is reinforced, and in winter, when the CUC reaches its southernmost extension. Other characteristics of the north/south extension of the GS/CUC are the seasonal nutrient replenishing of subsurface layers (spring restratification of NASPG and winter relaxation of the GD) and the maintenance of high levels of diapycnal mixing during the last phase of nutrient transfer to the euphotic layers. Off the Mid-Atlantic Bight the GS transports a total of about 700 kmol s−1 of nitrate, with almost 100 kmol s−1 carried in the surface (σθ < 26.8) layers and some 350 kmol s−1 in the intermediate (26.8 < σθ < 27.5) layers. A box model suggests that north of Cape Hatteras most surface and upper-thermocline nitrates are used to sustain the high levels of primary production in the NASPG. Off Cape Blanc there is winter along-shore convergence of order 10 kmol s−1 of nitrate in the near-surface layers (possibly larger in summer), with only a small fraction used to sustain local primary production in the coastal upwelling band and the remainder carried to the interior ocean. Nutrients and biomass exported from these cyclonic regions may account for the concentration levels observed within the NASTG. 相似文献
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大西洋温盐循环的演变:早渐新世北大西洋深水开始形成 总被引：1，自引：0，他引：1
气候和大洋盆地形状的急剧变化标志了新生代的开始。不断增加的证据表明了在早新生代(约55 Ma)的极端温暖时期,主要存在于南大洋的深水层形成了与现代模式根本不同的循环模式,并在北大西洋北部及南大洋形成了深水层。早新生代模式向两极模式的转变出现于何时?该转变的主要作用力如何?巴拿马地峡(4·2 Ma)的形成被认为是代表了深水循环向两极模式转变的最后作用,它使湾流将盐度较高的暖水带到北半球高纬形成北大西洋深层水(NADW),现代NADW由来自Nordic海和拉布拉多海的深水组成。然而,通常认为北大西洋的深水形成的最初阶段只有Nordic海… 相似文献