Phosphine photochemistry in the atmosphere of Saturn     

Jack A. Kaye  Darrell F. Strobel 《Icarus》1984,59(3):314-335

A model is presented for the photochemistry of PH₃ in the upper troposphere and lower stratosphere of Saturn that includes the effects of coupling with NH₃ and hydrocarbon photochemistry, specifically the C₂H₂ catalyzed photodissociation of CH₄. PH₃ is rapidly depleted with altitude (scale height ～35 km) in the upper troposphere when K～10⁴cm²sec^?1; an upper limit for K at the tropopause is estimated at ～10⁵cm²sec^?1. If there is no gas phase P₂H₄ because of sublimation, P₂ and P₄ formation is unlikely unless the rate of the spin-forbidden recombination reaction PH + H₂ + M → PH₃ + M is exceedingly slow. An upper limit P₄ column density of ～2×10¹⁵cm^?2 is estimated in the limit of no recombination. If sublimation does not remove all gas phase P₂H₄, P₂ and P₄ may be produced in potentially larger quantities, although they would be restricted almost entirely to the lowest levels of our model, where T?100°K. Potentially observable amounts of the organophosphorus compounds CH₃P₂H₂ and HCP are predicted, with column densities of >10¹⁷ cm^?2 and production rates of ～2×10⁸cm^?2sec^?1. The possible importance of electronically excited states of PH_x and additional PH₃/hydrocarbon photochemical coupling paths are also considered.  相似文献   

Phosphine on Jupiter and Saturn from Cassini/CIRS     

L.N. Fletcher  G.S. Orton  P.G.J. Irwin 《Icarus》2009,202(2):543-1417

The global distribution of phosphine (PH₃) on Jupiter and Saturn is derived using 2.5 cm⁻¹ spectral resolution Cassini/CIRS observations. We extend the preliminary PH₃ analyses on the gas giants [Irwin, P.G.J., and 6 colleagues, 2004. Icarus 172, 37-49; Fletcher, L.N., and 9 colleagues, 2007a. Icarus 188, 72-88] by (a) incorporating a wider range of Cassini/CIRS datasets and by considering a broader spectral range; (b) direct incorporation of thermal infrared opacities due to tropospheric aerosols and (c) using a common retrieval algorithm and spectroscopic line database to allow direct comparison between these two gas giants.The results suggest striking similarities between the tropospheric dynamics in the 100-1000 mbar regions of the giant planets: both demonstrate enhanced PH₃ at the equator, depletion over neighbouring equatorial belts and mid-latitude belt/zone structures. Saturn's polar PH₃ shows depletion within the hot cyclonic polar vortices. Jovian aerosol distributions are consistent with previous independent studies, and on Saturn we demonstrate that CIRS spectra are most consistent with a haze in the 100-400 mbar range with a mean optical depth of 0.1 at 10 μm. Unlike Jupiter, Saturn's tropospheric haze shows a hemispherical asymmetry, being more opaque in the southern summer hemisphere than in the north. Thermal-IR haze opacity is not enhanced at Saturn's equator as it is on Jupiter.Small-scale perturbations to the mean PH₃ abundance are discussed both in terms of a model of meridional overturning and parameterisation as eddy mixing. The large-scale structure of the PH₃ distributions is likely to be related to changes in the photochemical lifetimes and the shielding due to aerosol opacities. On Saturn, the enhanced summer opacity results in shielding and extended photochemical lifetimes for PH₃, permitting elevated PH₃ levels over Saturn's summer hemisphere.  相似文献   

The meridional phosphine distribution in Saturn's upper troposphere from Cassini/CIRS observations     

L.N. Fletcher  P.G.J. Irwin  G.S. Orton  S.B. Calcutt  R. de Kok  F.W. Taylor 《Icarus》2007,188(1):72-88

The Cassini Composite Infrared Spectrometer (CIRS) has been used to derive the vertical and meridional variation of temperature and phosphine (PH₃) abundance in Saturn's upper troposphere. PH₃ has a significant effect on the measured radiances in the thermal infrared and between May 2004 and September 2005 CIRS recorded thousands of spectra in both the far (10-600 cm⁻¹) and mid (600-1400 cm⁻¹) infrared, at a variety of latitudes covering the southern hemisphere. Low spectral resolution (15 cm⁻¹) data has been used to constrain the temperature structure of the troposphere between 100 and 500 mbar. The vertical distributions of phosphine and ammonia were retrieved from far-infrared spectra at the highest spectral resolution (0.5 cm⁻¹), and lower resolution (2.5 cm⁻¹) mid-infrared data were used to map the meridional variation in the abundance of phosphine in the 250-500 mbar range. Temperature variations at the 250 mbar level are shown to occur on the same scale as the prograde and retrograde jets in Saturn's atmosphere [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243-1247]. The PH₃ abundance at 250 mbar is found to be enhanced at the equator when compared with mid-latitudes. At mid latitudes we see anti-correlation between temperature and PH₃ abundance at 250 mbar, phosphine being enhanced at 45° S and depleted at 25 and 55° S. The vertical distribution is markedly different polewards of 60-65° S, with depleted PH₃ at 500 mbar but a slower decline in abundance with altitude when compared with the mid-latitudes. This variation is similar to the variations of cloud and aerosol parameters observed in the visible and near infrared, and may indicate the subsidence of tropospheric air at polar latitudes, coupled with a diminished sunlight penetration depth reducing the rate of PH₃ photolysis in the polar region.  相似文献   

A determination of the composition of the Saturnian stratosphere using the IUE     

Peter Winkelstein  John Caldwell  S.J. Kim  M. Combes  G.E. Hunt  V. Moore 《Icarus》1983,54(2):309-318

We reduced ultraviolet spectra of Saturn from the IUE satellite to produce a geometric albedo of the planet from 1500 to 3000 Å. By matching computer models to the albedo we determined a chemical composition consistent with the data. This model includes C₂H₂ and C₂H₆ with mixing ratios and distributions of (9 ± 3) × 10^?8 in the top 20 mbar of the atmosphere with none below for C₂H₂ and (6 ± 1) × 10^?6 also in the top 20 mbar with none below for C₂H₆. The C₂H₂ and C₂H₆ distributions and the C₂H₆ mixing ratio are taken directly from the Voyager IRIS model [R. Courtin et al., Bull. Amer. Astron. Soc.13, 722 (1981), and private communication]. The Voyager IRIS model also includes PH₃, which is not consistent with the uv albedo from 1800 to 2400 Å. Our model requires a previously unidentified absorber to explain the albedo near 1600 Å. After considering several candidates, we find that the best fit to the data is obtained with H₂O, having a column density of (6 ± 1) × 10^?3 cm-am.  相似文献   

The phosphine abundance on Saturn derived from new 10-micrometer spectra     

A.T. Tokunaga  H.L. Dinerstein  D.F. Lester  D.M. Rank 《Icarus》1980,42(1):79-85

Spectra of Saturn in the spectral region 10.0–10.7 μm are presented which confirm the presence of PH₃. Comparison to synthetic spectra indicates a PH₃ mixing ratio of at least 2 × 10^?6. No spectral features due to NH₃ or C₂H₄ were observed.  相似文献   

On the structure of Saturn's rings and the ‘real’ rotational period for the planet     

Ignacio Ferrín 《Astrophysics and Space Science》1975,33(2):453-457

An analysis of the Lowell Observatory photographic plates of Saturn gave the following results: (1) ring A and B show peculiar brightness distributions around the planet, from which we conclude that both are composed of particles in synchronous rotation. (2) The leading side of the particles in ring A is brighter than the trailing side by about 4%, which may indicate an interaction between such particles and the interplanetary medium. (3) Scans of the rings across the major axis show a small (～0.3″) region of enhanced brightness, from which we derive a value ofT _s =10^h13 _. ^m 8±5 _. ^m 4 for the actual planetary rotational period of Saturn. (4) In order to explain the synchronous rotation, the particles in ring A have to be at least 42 m in diameter.  相似文献   

The effect of dense cores on the structure and evolution of Jupiter and Saturn     

Allen S. Grossman  James B. Pollack  Ray T. Reynolds  Audrey L. Summers  Harold C. Graboske 《Icarus》1980,42(3):358-379

We have calculated evolutionary and static models of Jupiter and Saturn with homogeneous solar composition mantles and dense cores of material consisting of solar abundances of SiO₂, MgO, Fe, and Ni. Evolutionary sequences for Jupiter were calculated with cores of mass 2, 4, 6, and 8% of the Jovian mass. Evolutionary sequences for Saturn were calculated with cores of mass 16, 18, 20, and 22% of total mass. Two envelope mixtures, representative of the solar abundances were used: X (mass fraction of hydrogen) = 0.74, Y (mass fraction of helium) = 0.24 and X = 0.77 and Y = 0.21. For Jupiter, the observations of the temperature at 1 bar pressure (T_1bar), radius and internal luminosity were best fit by evolutionary models with a core mass of ～6.5% and chemical composition of X = 0.77, Y = 0.21. The calculated cooling time for Jupiter is approximately 4.9 × 10⁹ years, which is consistent, within our error bars, with the known age of the solar system. For Saturn, the observations of the radius, internal luminosity and T_1BAR can be best fit by evolutionary models with a core mass of ～21% and chemical composition of X = 0.77, Y = 0.21. The cooling time calculated for Saturn is approximately 2.6 × 10⁹ years, almost a factor 2 less than the present age of the solar system. Static models of Jupiter and Saturn were calculated for the above chemical compositions in order to investigate the sensitivity of the calculated gravitational moments, J₂ and J₄, to the mass of the dense core, T_1BAR and hydrogen/helium ratio. We find for Jupiter that a model having a core mass of approximately 7% gives values of J₂, J₄, and T_1BAR that are within observational limits, for the mixture X = 0.77, Y = 0.21. The static Jupiter models are completely consistent with the evolutionary results. For Saturn, the quantities J₂, J₄, and J₆ determined from the static models with the most probable T_1BAR of 140°K, using modeling procedures which result in consistent models for Jupiter, are considerably below the observed values.  相似文献   

Empirical models of pressure and density in Saturn's interior: Implications for the helium concentration, its depth dependence, and Saturn's precession rate     

Ravit Helled  Gerald Schubert 《Icarus》2009,199(2):368-377

We present ‘empirical’ models (pressure vs. density) of Saturn's interior constrained by the gravitational coefficients J₂, J₄, and J₆ for different assumed rotation rates of the planet. The empirical pressure-density profile is interpreted in terms of a hydrogen and helium physical equation of state to deduce the hydrogen to helium ratio in Saturn and to constrain the depth dependence of helium and heavy element abundances. The planet's internal structure (pressure vs. density) and composition are found to be insensitive to the assumed rotation rate for periods between 10h:32m:35s and 10h:41m:35s. We find that helium is depleted in the upper envelope, while in the high pressure region (P?1 Mbar) either the helium abundance or the concentration of heavier elements is significantly enhanced. Taking the ratio of hydrogen to helium in Saturn to be solar, we find that the maximum mass of heavy elements in Saturn's interior ranges from ∼6 to 20 M_⊕. The empirical models of Saturn's interior yield a moment of inertia factor varying from 0.22271 to 0.22599 for rotation periods between 10h:32m:35s and 10h:41m:35s, respectively. A long-term precession rate of about ^0.754″ yr⁻¹ is found to be consistent with the derived moment of inertia values and assumed rotation rates over the entire range of investigated rotation rates. This suggests that the long-term precession period of Saturn is somewhat shorter than the generally assumed value of 1.77×¹⁰⁶ years inferred from modeling and observations.  相似文献   

A Saturnian gas ring and the recycling of Titan's atmosphere     

Thomas R. McDonough  Neil M. Brice 《Icarus》1973,20(2):136-145

Atoms which escape Titan's atmosphere are unlikely to possess escape velocity from Saturn, and can orbit the planet until lost by ionization or collision with Titan. It is predicted that a toroidal ring of between ～1 and ～10³ atoms or molecules cm^?3 exists around Saturn at a distance of about 10 times the radius of the visible rings. This torus may be detectable from Earth-orbit and detection of nondetection of it may provide some information about the presence or absence of a Saturnian magnetic field, and the exospheric temperature and atmospheric escape rate of Titan. It is estimated that, if Titan has a large exosphere, ～97% or more of the escaping atoms can be recaptured by Titan, thereby decreasing the effective net atmospheric loss rate by up to two orders of magnitude. With such a reduction in atmospheric loss rates, it becomes more plausible to suggest that satellites previously thought too small to retain an atmosphere may have one. It is suggested that Saturn be examined by Lyman-α and other observations to search for the gaseous torus of Titan. If successful, these could then be extended to other satellites.The effect of a hypothetical Saturnian magnetosphere on the atmosphere of Titan is investigated. It is shown that, if Saturn has a magnetic field comparable to Jupiter's (～10 G at the planetary surface), the magnetospheric plasma can supply Titan with hydrogen at a rate comparable to the loss rates in some of the models of Trafton (1972) and Sagan (1973). A major part of the Saturnian ionospheric escape flux (～ 10²⁷ photoelectrons sec^?1) could perhaps be captured by Titan. At the upper limit, this rate of hydrogen input to the satellite could total ～0.1 atm pressure over the lifetime of the solar system, an amount comparable to estimates of the present atmospheric pressure of Titan.  相似文献   

The atmospheric composition and structure of Jupiter and Saturn from ISO observations: a preliminary review     

《Planetary and Space Science》1999,47(10-11):1225-1242

Infrared spectra of Jupiter and Saturn have been recorded with the two spectrometers of the Infrared Space Observatory (ISO) in 1995–1998, in the 2.3–180 μm range. Both the grating modes (R=150–2000) and the Fabry-Pérot modes (R=8000–30,000) of the two instruments were used. The main results of these observations are (1) the detection of water vapour in the deep troposphere of Saturn; (2) the detection of new hydrocarbons (CH₃C₂H, C₄H₂, C₆H₆, CH₃) in Saturn’s stratosphere; (3) the detection of water vapour and carbon dioxide in the stratospheres of Jupiter and Saturn; (4) a new determination of the D/H ratio from the detection of HD rotational lines. The origin of the external oxygen source on Jupiter and Saturn (also found in the other giant planets and Titan in comparable amounts) may be either interplanetary (micrometeoritic flux) or local (rings and/or satellites). The D/H determination in Jupiter, comparable to Saturn’s result, is in agreement with the recent measurement by the Galileo probe (Mahaffy, P.R., Donahue, T.M., Atreya, S.K., Owen, T.C., Niemann, H.B., 1998. Galileo probe measurements of D/H and ³He/⁴He in Jupiters atmosphere. Space Science Rev. 84 251–263); the D/H values on Uranus and Neptune are significantly higher, as expected from current models of planetary formation.  相似文献   

High-resolution spectroscopy of Saturn at 3 microns: CH₄, CH₃D, C₂H₂, C₂H₆, PH₃, clouds, and haze     

Joo Hyeon Kim  Sang J. Kim  Sungsoo S. Kim 《Icarus》2006,185(2):476-486

We report observation and analysis of a high-resolution 2.87-3.54 μm spectrum of the southern temperate region of Saturn obtained with NIRSPEC at Keck II. The spectrum reveals absorption and emission lines of five molecular species as well as spectral features of haze particles. The ν₂+ν₃ band of CH₃D is detected in absorption between 2.87 and 2.92 μm; and we derived from it a mixing ratio approximately consistent with the Infrared Space Observatory result. The ν₃ band of C₂H₂ also is detected in absorption between 2.95 and 3.05 μm; analysis indicates a sudden drop in the C₂H₂ mixing ratio at 15 mbar (130 km above the 1 bar level), probably due to condensation in the low stratosphere. The presence of the ν₃+ν₉+ν₁₁ band of C₂H₆ near 3.07 μm, first reported by Bjoraker et al. [Bjoraker, G.L., Larson, H.P., Fink, U., 1981. Astrophys. J. 248, 856-862], is confirmed, and a C₂H₆ condensation altitude of 10 mbar (140 km) in the low stratosphere is determined. We assign weak emission lines within the 3.3 μm band of CH₄ to the ν₇ band of C₂H₆, and derive a mixing ratio of 9±4×¹⁰⁻⁶ for this species. Most of the C₂H₆ 3.3 μm line emission arises in the altitude range 460-620 km (at ∼μbar pressure levels), much higher than the 160-370 km range where the 12 μm thermal molecular line emission of this species arises. At 2.87-2.90 μm the major absorber is tropospheric PH₃. The cloud level determined here and at 3.22-3.54 is 390-460 mbar (∼30 km), somewhat higher than found by Kim and Geballe [Kim, S.J., Geballe, T.R., 2005. Icarus 179, 449-458] from analysis of a low resolution spectrum. A broad absorption feature at 2.96 μm, which might be due to NH₃ ice particles in saturnian clouds, is also present. The effect of a haze layer at about 125 km (∼12 mbar level) on the 3.20-3.54 μm spectrum, which was not apparent in the low resolution spectrum, is clearly evident in the high resolution data, and the spectral properties of the haze particles suggest that they are composed of hydrocarbons.  相似文献   

Far-infrared spectrophotometry of Saturn and its rings     

M.R. Haas  E.F. Erickson  D.D. McKibbin  D. Goorvitch  L.J. Caroff 《Icarus》1982,51(3):476-490

The spectrum of Saturn was measured from 80 to 350 cm^?1 (29 to 125 μm) with ≈6-cm^?1 resolution using a Michelson interferometer aboard NASA's Kuiper Airborne Observatory. These observations are of the full disk, with little contribution from the rings. For frequencies below 300 cm^?1, Saturn's brightness temperature rises slowly, reaching ≈111°K at 100 cm^?1. The effective temperature is 96.8 ± 2.5°K, implying that Saturn emits 3.0 ± 0.5 times as much energy as it receives from the Sun. The rotation-inversion manifolds of NH₃ that are prominent in the far-infrared spectrum of Jupiter are not observed on Saturn. Our models predict the strengths to be only ≈2 to 5°K in brightness temperature because most of the NH₃ is frozen out; this is comparable to the noise in our data. By combining our data with those of an earlier investigation when the Saturnicentric latitude of the Sun was B′ = 21.2°, we obtain the spectrum of the rings. The high-frequency end of the ring spectrum (ν > 230 cm^?1) has nearly constant brightness temperature of 85°K. At lower frequencies, the brightness temperature decreases roughly as predicted by a simple absorption model with an optical depth proportional to ν^1.5. This behavior could be due to mu-structure on the surface of the ring particles with a scale size of 10 to 100 μm and/or to impurities in their composition.  相似文献   

Models of the protosatellite disk of Saturn: Conditions for Titan’s formation     

A. B. Makalkin  V. A. Dorofeeva 《Solar System Research》2006,40(6):441-455

Models of the protosatellite accretion disk of Saturn are developed that satisfy cosmochemical constraints on the volatile abundances in the atmospheres of Saturn and Titan with due regard for the data obtained with the Cassini orbiter and the Huygens probe, which landed on Titan in January 2005. All basic sources of heating of the disk and protosatellite bodies are taken into account in the models, namely, dissipation of turbulence in the disk, accretion of gaseous and solid material onto the disk from the feeding zone of Saturn in the solar nebula, and heating by the radiation of young Saturn and thermal radiation of the surrounding region of the solar nebula. Two-dimensional (axisymmetric) temperature, pressure, and density distributions are calculated for the protosatellite disk. The distributions satisfy the cosmochemical constraints on the disk temperature, according to which the temperature at the stage of the satellite formation ranged from 60–65 K to 90–100 K at pressures from 10^?7 to ?10^?4 bar in the zone of Titan’s formation (according to estimates, r = 20–35R _Sat). Variations of the basic input parameters (the accretion rate onto the protosatellite disk of Saturn from the feeding zone of the planet ?; the parameter α characterizing turbulent viscosity of the disk; and the mass concentration ratio in the solid/gas system) satisfying the aforementioned temperature constraint are found. The spectrum of models satisfying the cosmochemical constraints covers a considerable range of consistent parameters. A model with a rather small flux of ? = 10^?8 M _Sat/ yr and a tenfold depletion of Saturn’s disk in gas due to gas scattering from the solar nebula is at one side of this range. A model with a much higher flux of ? = 10^?6 M _Sat/yr and a hundredfold decrease in opacity of the disk matter owing to decreased concentration of dust particles and/or their agglomeration into large aggregates and sweeping up by planetesimals is at the other side of the range.  相似文献   

Tidal dissipation in the solid cores of the major planets     

Stanley F. Dermott 《Icarus》1979,37(1):310-321

If the orbital resonances in the Jovian and Saturnian satellite systems are the result of orbital evolution due to tidal dissipation then the present rates of energy dissipation ($\text{E}\text{dot}$) are >2 × 10²⁰ ergs sec^?1 (Jupiter) and ?2 × 10¹⁶ ergs sec^?1 (Saturn). These values of $\text{E}\text{dot}$ can be accounted for if the planets have rocky cores with volumes equal to those suggested by current models of the interiors and if the material of these cores is both solid and imperfectly elastic (Q_e ～ 34). The calculated values of Q_e are not strongly dependent on either the rigidity of the core or the densities of the core and the mantle. Thus, these quantities need not be known precisely. It may be significant that approximately the same value of Q_e is needed for all the major planets (Jupiter, Saturn, and Uranus) even though the values of $\text{E}\text{dot}$ for these planets differ by a factor greater than 10⁴.  相似文献   

A comparison of the interiors of Jupiter and Saturn     

《Planetary and Space Science》1999,47(10-11):1183-1200

Interior models of Jupiter and Saturn are calculated and compared in the framework of the three-layer assumption, which rely on the perception that both planets consist of three globally homogeneous regions: a dense core, a metallic hydrogen envelope, and a molecular hydrogen envelope. Within this framework, constraints on the core mass and abundance of heavy elements (i.e. elements other than hydrogen and helium) are given by accounting for uncertainties on the measured gravitational moments, surface temperature, surface helium abundance, and on the inferred protosolar helium abundance, equations of state, temperature profile and solid/differential interior rotation. Results obtained solely from static models matching the measured gravitational fields indicate that the mass of Jupiter’s dense core is less than 14 M_⊕ (Earth masses), but that models with no core are possible given the current uncertainties on the hydrogen–helium equation of state. Similarly, Saturn’s core mass is less than 22 M_⊕ but no lower limit can be inferred. The total mass of heavy elements (including that in the core) is constrained to lie between 11 and 42 M_⊕ in Jupiter, and between 19 and 31 M_⊕ in Saturn. The enrichment in heavy elements of their molecular envelopes is 1–6.5, and 0.5–12 times the solar value, respectively. Additional constraints from evolution models accounting for the progressive differentiation of helium (Hubbard WB, Guillot T, Marley MS, Burrows A, Lunine JI, Saumon D, 1999. Comparative evolution of Jupiter and Saturn. Planet. Space Sci. 47, 1175–1182) are used to obtain tighter, albeit less robust, constraints. The resulting core masses are then expected to be in the range 0–10 M_⊕, and 6–17 M_⊕ for Jupiter and Saturn, respectively. Furthermore, it is shown that Saturn’s atmospheric helium mass mixing ratio, as derived from Voyager, Y=0.06±0.05, is probably too low. Static and evolution models favor a value of Y=0.11−0.25. Using, Y=0.16±0.05, Saturn’s molecular region is found to be enriched in heavy elements by 3.5 to 10 times the solar value, in relatively good agreement with the measured methane abundance. Finally, in all cases, the gravitational moment J₆ of models matching all the constraints are found to lie between 0.35 and 0.38×10⁻⁴ for Jupiter, and between 0.90 and 0.98×10⁻⁴ for Saturn, assuming solid rotation. For comparison, the uncertainties on the measured J₆ are about 10 times larger. More accurate measurements of J₆ (as expected from the Cassini orbiter for Saturn) will therefore permit to test the validity of interior models calculations and the magnitude of differential rotation in the planetary interior.  相似文献   

On the origin and initial temperature of Jupiter and Saturn     

V.S. Safronov  E.L. Ruskol 《Icarus》1982,49(2):284-296

A two-stage growth of the giant planets, Jupiter and Saturn, is considered, which is different from the model of contraction of large gaseous protoplanets. In the first stage, within a time of ～3 × 10⁷ years in Jupiter's zone and ～2 × 10⁸ years in Saturn's zone, a nucleus forms from condensed (solid) material having the mass, ～10²⁸ g, necessary for the beginning of acceleration. The second stage may gravitating body, and a relatively slow accretion begins until the mass of the planet reaches ～10 m_⊕. Then a rapid accretion begins with the critical radius less than the radius of the Hill lobe, so that the classical formulae for the rate of accretion may be applied. At a mass m > m₁ ≈ 50 m_⊕ accretion proceeds slower than it would according to these formulae. When the planet sweeps out all the gas from its nearest zone of feeding (m = m₂ ≈ 130 m_⊕), the width of the exhausted zone being $\text{～}\text{built1}\text{3}$ of the whole zone of the planet) growth is provided the slow diffusion of gas from the rest of the zone (time scale increases to 10⁵?10⁶ years and more). The process is terminated by the dissipation of the remnants of gas. In Saturn's zone m₁ > m₂ ≈ 30 m_⊕. The initial mass of the gas in Jupiter's zone is estimated. Before the beginning of the rapid accretion about 90% of the gas should have been lost from the solar system, and in the planet's zone less than two Jupiter masses remain. The highest temperature of Jupiter's surface, ≈5000°K, is reached at the stage of rapid accretion, m < 100 m_⊕, when the luminosity of the planet reaches 3 × 10^?3 L_⊙. This favors an effective heating of the inner parts of the accretionary disk and the dissipation of gas from the disk. The accretion of Saturn produced a temperature rise up to 2000?2400° K (at m ≈ 20?25 m_⊕) and a luminosity up to 10^?4 L_⊙.  相似文献   

Laboratory simulations of PH₃ photolysis in the atmospheres of Jupiter and Saturn     

J.P. Ferris  Haider Khwaja 《Icarus》1985,62(3):415-424

Photolysis of NH₃PH₃ mixtures (11 Torr) at 175°K resulted in the same initial rate of P₂H₄ formation as when the 11 Torr of pure PH₃ was photolyzed. A higher yield of P₂H₄ is obtained at 175°K than at 298°K because some of the P₂H₄ condenses on the cell wall at 175°K and is not subject to further reaction. Some reaction of P₂H₄ is taking place as observed by the decrease in its yield and on the formation of red phosphorus on extended photolysis of PH₃ at 175°K. No NH₂PH₂ or (PN)_x were detected as photoproducts as indicated by the absence of change in the UV spectral properties of the P₂H₄ and red phosphorus fraction, respectively, when NH₃ is present. Although the pathway for PH₃ decomposition is changed, the outcome of the photochemical process is essentially the same in the absence or presence of NH₃. The formation of P₂H₄ and red phosphorus was not inhibited by small amounts of C₂H₄ and C₂H₂, so the low levels of hydrocarbons on Jupiter and Saturn will not have a significant effect on the course of PH₃ photolysis. The ratio of products of PH₃ photolysis are only slightly affected by the wavelength of light used. Use of xenon lamp, with a continuous emission in the ultraviolet where P₂H₄ absorbs, results in only a modest decrease in the yield of P₂H₄ and a modest increase in the rate of formation of red phosphorus as compared to the rates observed with a 206.2-nm light source. The quantum yield for P₂H₄ formation is pressure independent in the 0.5–11 Torr range. This quantum yield is not affected by lowering the temperature to 157°K or by the addition of 100 Torr of H₂. It is concluded that photolysis of PH₃ to P₂H₄ and the subsequent conversion of P₂H₄ to red phosphorus are likely procses on Jupiter and Saturn and that particles of P₂H₄ condense in the atmospheres of these planets. The conversion of some of the P₂H₄ to red phosphorus may take place on Jupiter.  相似文献   

Meridional variations of C₂H₂ and C₂H₆ in Jupiter's atmosphere from Cassini CIRS infrared spectra     

C.A. Nixon  R.K. Achterberg  P.G.J. Irwin  T. Fouchet  P.N. Romani  A. LeClair  A.A. Simon-Miller  F.M. Flasar 《Icarus》2007,188(1):47-71

Hydrocarbons such as acetylene (C₂H₂) and ethane (C₂H₆) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm⁻¹ (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm⁻¹) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν₄ band of CH₄, and in the troposphere at 150-400 mbar, via the H₂ absorption at 600-800 cm⁻¹. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C₂H₂ and C₂H₆ by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C₂H₂ν₅ and C₂H₆ν₉ bands, and also emission of the acetylene (ν₄+ν₅)−ν₄ hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼3×¹⁰⁻⁹. Additionally, the abundance gradient of C₂H₂ between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C₂H₂ and C₂H₆ by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C₂H₆ in the stratosphere (3×¹⁰¹⁰ s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5-50×¹⁰⁸ s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C₂H₂, the opposite occurs, with the relatively short photochemical lifetime (3×¹⁰⁷ s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible.  相似文献   

Interpretation of the carbon abundance in Saturn measured by Cassini     

Franck Hersant  Daniel Gautier 《Planetary and Space Science》2008,56(8):1103-1111

Spectral observations of Saturn from the far infrared spectrometer aboard the Cassini spacecraft [Flasar, F.M., et al., 2005. Temperatures, winds, and composition in the Saturnian system. Science 307, 1247-1251] have revealed that the C/H ratio in the planet is in fact about twice higher than previously derived from ground based observations and in agreement with the C/H value derived from Voyager IRIS by Courtin et al. [1984. The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH₃, PH₃, C₂H₂, C₂H₆, CH₃D, CH₄, and the Saturnian D/H isotopic ratio. Astrophys. J. 287, 899-916]. The implications of this measurement are reanalyzed in the present report on the basis that volatiles observed in cometary atmospheres, namely CO₂, CH₄, NH₃ and H₂S may have been trapped as solids in the feeding zone of the planet. CH₄ and H₂S may have been in the form of clathrate hydrates while CO₂ presumably condensed in the cooling solar nebula. Carbon may also have been incorporated in organics. Conditions of temperature and pressure ease the hydratation of NH₃. Such icy grains were included in planetesimals which subsequently collapsed into the hydrogen envelope of the planet, then resulting in C, N and S enrichments with respect to the solar abundance. Our calculations are consistent, within error bars, with observed elemental abundances on Saturn provided that the carbon trapped in planetesimals was mainly in the form of CH₄ clathrate and CO₂ ice (and maybe as organics) while nitrogen was in the form of NH₃ hydrate. Our approach has implications on the possible pattern of noble gases in Saturn, since we predict that contrary to what is observed in Jupiter, Ar and Kr should be in solar abundance while Xe might be strongly oversolar. The only way to verify this scenario is to send a probe making in situ mass spectrometer measurements. Our scenario also predicts that the ¹⁴N/¹⁵N ratio should be somewhat smaller in Saturn than measured in Jupiter by Galileo.  相似文献   

On the C/H and D/H ratios in the atmospheres of Jupiter and Saturn     

T. Encrenaz  M. Combes 《Icarus》1982,52(1):54-61

Using a method defined in a previous paper [M. Combes and T. Encrenaz, Icarus39 1–27 (1979)], we reestimated the C/H ratio in the atmospheres of Jupiter and Saturn by the measurements of the weak visible CH₄ bands, the CH₄ 3ν₃ band, and the (3-0) and (4-0) quadrupole bands of H₂. In the case of Jupiter we conclude that the C/H ratio is enriched by a factor ranging from 1.7 to 3.6 relative to the solar value. In the case of Saturn, our derived C/H value ranges from 1.2 to 3.2 times the solar value. The Jovian D/H ratio derived from this study is 1.2 × 10^?5 < D/H < 3.1 × 10^?5. The value derived for the D/H ratio on Saturn is not precise enough to be conclusive.  相似文献