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1.
A model is presented for the photochemistry of PH3 in the upper troposphere and lower stratosphere of Saturn that includes the effects of coupling with NH3 and hydrocarbon photochemistry, specifically the C2H2 catalyzed photodissociation of CH4. PH3 is rapidly depleted with altitude (scale height ～35 km) in the upper troposphere when K～104cm2sec?1; an upper limit for K at the tropopause is estimated at ～105cm2sec?1. If there is no gas phase P2H4 because of sublimation, P2 and P4 formation is unlikely unless the rate of the spin-forbidden recombination reaction PH + H2 + M → PH3 + M is exceedingly slow. An upper limit P4 column density of ～2×1015cm?2 is estimated in the limit of no recombination. If sublimation does not remove all gas phase P2H4, P2 and P4 may be produced in potentially larger quantities, although they would be restricted almost entirely to the lowest levels of our model, where T?100°K. Potentially observable amounts of the organophosphorus compounds CH3P2H2 and HCP are predicted, with column densities of >1017 cm?2 and production rates of ～2×108cm?2sec?1. The possible importance of electronically excited states of PHx and additional PH3/hydrocarbon photochemical coupling paths are also considered. 相似文献
2.
Spectra of Saturn in the spectral region 10.0–10.7 μm are presented which confirm the presence of PH3. Comparison to synthetic spectra indicates a PH3 mixing ratio of at least 2 × 10?6. No spectral features due to NH3 or C2H4 were observed. 相似文献
3.
The abundances of PH3, CH3D, and GeH4 are derived from the 2100- to 2250-cm?1 region of the Voyager 1 IRIS spectra. No evidence is seen for large-scale variations of the phosphine abundance over Jovian latitudes between ?30 and +30°. In the atmospheric regions corresponding to 170–200°K, the derived PH3/H2 value is (4.5 ± 1.5) × 10?7 or 0.75 ± 0.25 times the solar value. This result, compared with other PH3 determinations at 10 μm, suggests than the PH3/H2 ratio on Jupiter decreases with atmospheric pressure. In the 200–250°K region, we derive, within a factor of 2, CH3D/H2 and GeH4/H2 ratios of 2.0 × 10?7 and 1.0 × 10?9, respectively. Assuming a C/H value of 1.0 × 10?3, as derived from Voyager, our CH3D/H2 ratio implies a D/H ratio of 1.8 × 10?5, in reasonable agreement with the interstellar medium value. 相似文献
4.
The formation of methylamine (CH3NH2) in the upper troposphere and lower stratosphere of Jupiter is investigated. Translationally hot hydrogen atoms are produced in the photolysis of ammonia, phosphine, and acetylene which react with methane to produce methyl (CH3) radicals; the latter recombine with NH2 to form CH3NH2. Also, methane is catalytically dissociated to CH3 + H by the species C2 and C2H produced in the photolysis of acetylene. It is shown that the combined production of CH3NH2 and subsequent photolysis to HCN is unlikely to account for the HCN observed near Jupiter's tropopause. Recombination of NH2 and C2H5N followed by photolysis to HCN is the preferred path. Production of C2H6 by these two processes is negligible in comparison to the downward flux of C2H6 from the Lyman α photolysis region of CH4. An upper limit column density on CH3PH2 is estimated to be ～1013 cm?2 as compared to 1015 cm?2 for CH3NH2. Hot H atoms account for a negligible fraction of the total ortho-para conversion by the reaction H + H2 相似文献
5.
R.F. Loewenstein D.A. Harper S.H. Moseley C.M. Telesco Harley A. Thronson R.H. Hildebrand S.E. Whitcomb R. Winston R.F. Stiening 《Icarus》1977,31(3):315-324
New broadband observations in several passbands between 30 and 500 μm of Mercury, Venus, Mars, Jupiter, Saturn, and Uranus are presented. The best agreement between the data and various thermal models of Mars, Jupiter, and Uranus is obtained with a slightly cooler absolute temperature scale than that previously adopted by Armstrong et al. (1972). The effective temperature of Uranus is 58 ± 2°K, which is in agreement with its solar equilibrium temperature. The existence of an internal energy source of Saturn has been reconfirmed and must lie within the range of 0.9 to 3.2 times the absorbed solar flux. A depression exists in the spectra of Jupiter, Saturn, and Uranus between 80 and 300 μm, which may be a result of NH3 opacity. 相似文献
6.
The reaction of elemental phosphorus and H atoms to form PH3 was observed and should be a major factor in the recycling of PH3 in the stratosphere of Jupiter. The formation of PH3 in this manner should predominate at high altitudes where, due to the very low temperatures, reactions that require higher activation energies than these atom reactions cannot occur. At lower altitudes, in the troposphere, the rapid formation of H atoms from the strong absorption of light by NH3 will contribute to phosphine production also in this same manner. Recent experiments have also shown that elemental phosphorus reacts readily with aqueous ammonia to form PH3. This reaction may also be important in the recycling of PH3 in the upper troposphere of Jupiter if water-ammonia clouds, as had been previously thought, exist. Considerations of the coloration of the Great Red Spot have been made based upon the nature of the phosphorus obtained by decomposition of phosphine. 相似文献
7.
《Planetary and Space Science》1999,47(10-11):1201-1210
New models of Jupiter are based on observational data provided by the Galileo spaceprobe, which considerably improved previously existing estimates of the helium abundance in the atmosphere of Jupiter. These data yield for Jupiter’s atmosphere 20% of the solar oxygen abundance and do not agree with the results of the analysis of the collision of comet Shoemaker-Levy 9 with Jupiter (10 times the solar value). Therefore, both the models of Jupiter with water-depleted and water-enriched atmosphere are considered. By analogy with Jupiter, trial models of Saturn with a water-depleted external envelope are also developed. The molecular-metallic phase transition pressure of hydrogen Pm was taken to be 1.5, 2 and 3 Mbar. Since Saturn’s internal molecular envelope is noticeably enriched in the IR-component (its weight concentration, 0.25–0.30, being by a factor of 3–4 higher than in Jupiter), the phase transition pressure in Saturn can be lower than in Jupiter. In the constructed models, the IR-core masses are 3–3.5 M⊕ for Jupiter and 3–5.5 M⊕ for Saturn. Jupiter’s and Saturn’s IR-cores can be considered embryos onto which the accretion of the gas occurred during the formation of the planets. The mass of the hydrogen–helium component dispersed in the zone of planetary formation constitutes ≈2–5 planetary masses for Jupiter and ≈11–14 planetary masses for Saturn. 相似文献
8.
The spectral window of Jupiter at 3 μm is analyzed and compared with previously published spectra. The two components of the spectrum, the thermal and the solar reflected contributions, are calculated at low resolution (30 cm?1) between 3300 and 3800 cm?1 for preparing the interpretation of the Galileo Near Infrared Mapping Spectrometer experiment. The calculations yield to the following conclusions: (1) NH3 is the main absorber between 3300 and 3600 cm?1 for both the thermal spectrum and the solar reflected spectrum; H2O appears only in the thermal component above 3600 cm?1. (2) The thermal component can be seen only on the dark side of Jupiter; the atmosphere is sounded down to temperature levels of about 210°K. (3) The solar reflected component can be modelized by a reflecting layer between 135 and 140°K with an albedo of 0.3; high spatial resolution maps of Jupiter at 3 μm should give access to the NH3 spatial distribution on Jupiter. 相似文献
9.
We report the detection of HCN on Jupiter. Three R-branch lines of the ν2 fundamental of HCN near 13.5 μm were observed in absorption, from which the HCN column density is inferred to be 5 × 10?3 cm-am with an uncertainty of a factor of 2. If emission from the stratosphere exists, then the derived column density is only a lowe limit. We suggest that the Jovian HCN most likely originates from the photolysis of CH4 and NH3 in the lower stratosphere and upper troposphere. In addition, an upper limit of 2.5 × 10?2 cm-am was established for the column density of HCN on Saturn. 相似文献
10.
Spectral observations of Saturn from the far infrared spectrometer aboard the Cassini spacecraft [Flasar, F.M., et al., 2005. Temperatures, winds, and composition in the Saturnian system. Science 307, 1247-1251] have revealed that the C/H ratio in the planet is in fact about twice higher than previously derived from ground based observations and in agreement with the C/H value derived from Voyager IRIS by Courtin et al. [1984. The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH3, PH3, C2H2, C2H6, CH3D, CH4, and the Saturnian D/H isotopic ratio. Astrophys. J. 287, 899-916]. The implications of this measurement are reanalyzed in the present report on the basis that volatiles observed in cometary atmospheres, namely CO2, CH4, NH3 and H2S may have been trapped as solids in the feeding zone of the planet. CH4 and H2S may have been in the form of clathrate hydrates while CO2 presumably condensed in the cooling solar nebula. Carbon may also have been incorporated in organics. Conditions of temperature and pressure ease the hydratation of NH3. Such icy grains were included in planetesimals which subsequently collapsed into the hydrogen envelope of the planet, then resulting in C, N and S enrichments with respect to the solar abundance. Our calculations are consistent, within error bars, with observed elemental abundances on Saturn provided that the carbon trapped in planetesimals was mainly in the form of CH4 clathrate and CO2 ice (and maybe as organics) while nitrogen was in the form of NH3 hydrate. Our approach has implications on the possible pattern of noble gases in Saturn, since we predict that contrary to what is observed in Jupiter, Ar and Kr should be in solar abundance while Xe might be strongly oversolar. The only way to verify this scenario is to send a probe making in situ mass spectrometer measurements. Our scenario also predicts that the 14N/15N ratio should be somewhat smaller in Saturn than measured in Jupiter by Galileo. 相似文献
11.
New far-infrared observations of the NH3 rotation-inversion manifolds in the spectrum of Jupiter have been inverted with the use oftthe detailed ammonia line opacity. A temperature of 160°K at a 1-bar pressure level and a temperature of 105°K for the minimum temperature of the inversion level at 0.15 bars have been derived for gaseous absorption due to NH3, H2, and He. The overall fit to the brightness temperature as a function of frequency σ is within ±1°K for 100 ≤ σ ≤ 400 cm?1 except for the centers of the NH3 rotation-inversion manifolds where for J ≥ 7 the fit is about 5°K too high. In the continuum for 400 ≤ σ ≤ 630 cm?1 the fit is within 2.5°K. Consideration of an ammonia ice haze, photodissociation of NH3 by uv radiation, NH3 abundance variation, different He/H2 ratios, and uncertainties in the data effect the temperatures at 1 bar and the temperature at the inversion layer by <7°K. The presently derived temperature at 1 bar of 160°K is consistent with Jovian interior models which can match the gravitational moment, J2. 相似文献
12.
13.
《Planetary and Space Science》1999,47(10-11):1225-1242
Infrared spectra of Jupiter and Saturn have been recorded with the two spectrometers of the Infrared Space Observatory (ISO) in 1995–1998, in the 2.3–180 μm range. Both the grating modes (R=150–2000) and the Fabry-Pérot modes (R=8000–30,000) of the two instruments were used. The main results of these observations are (1) the detection of water vapour in the deep troposphere of Saturn; (2) the detection of new hydrocarbons (CH3C2H, C4H2, C6H6, CH3) in Saturn’s stratosphere; (3) the detection of water vapour and carbon dioxide in the stratospheres of Jupiter and Saturn; (4) a new determination of the D/H ratio from the detection of HD rotational lines. The origin of the external oxygen source on Jupiter and Saturn (also found in the other giant planets and Titan in comparable amounts) may be either interplanetary (micrometeoritic flux) or local (rings and/or satellites). The D/H determination in Jupiter, comparable to Saturn’s result, is in agreement with the recent measurement by the Galileo probe (Mahaffy, P.R., Donahue, T.M., Atreya, S.K., Owen, T.C., Niemann, H.B., 1998. Galileo probe measurements of D/H and 3He/4He in Jupiters atmosphere. Space Science Rev. 84 251–263); the D/H values on Uranus and Neptune are significantly higher, as expected from current models of planetary formation. 相似文献
14.
Moderate-resolution spectrophotometry (Δλ/λ～0.015) has shown the effects of known atmospheric constituents (NH3, CH4, C2H6) on the 5–8 μm spectrum of Jupiter. Broadband observations of Saturn at 6.5 μm are also reported. 相似文献
15.
The spectrum of Saturn was measured from 80 to 350 cm?1 (29 to 125 μm) with ≈6-cm?1 resolution using a Michelson interferometer aboard NASA's Kuiper Airborne Observatory. These observations are of the full disk, with little contribution from the rings. For frequencies below 300 cm?1, Saturn's brightness temperature rises slowly, reaching ≈111°K at 100 cm?1. The effective temperature is 96.8 ± 2.5°K, implying that Saturn emits 3.0 ± 0.5 times as much energy as it receives from the Sun. The rotation-inversion manifolds of NH3 that are prominent in the far-infrared spectrum of Jupiter are not observed on Saturn. Our models predict the strengths to be only ≈2 to 5°K in brightness temperature because most of the NH3 is frozen out; this is comparable to the noise in our data. By combining our data with those of an earlier investigation when the Saturnicentric latitude of the Sun was B′ = 21.2°, we obtain the spectrum of the rings. The high-frequency end of the ring spectrum (ν > 230 cm?1) has nearly constant brightness temperature of 85°K. At lower frequencies, the brightness temperature decreases roughly as predicted by a simple absorption model with an optical depth proportional to ν1.5. This behavior could be due to mu-structure on the surface of the ring particles with a scale size of 10 to 100 μm and/or to impurities in their composition. 相似文献
16.
We report here the equilibrium abundances calculated for a system of over 500 compounds of 27 selected elements along a nominal Jupiter adiabat. Several species predicted to be of negligible abundance in the visible upper troposphere if chemical equilibrium is exactly attained are found to be potential tracers of rapid vertical motions. Vertical mixing of certain species, especially CO, PH3, AsH3, GeS, and GeH4, may provide detectable quantities of these species near the visible cloudtops due to quenching and incomplete equilibration of the rapidly rising, rapidly cooling gas. Observational prospects for detecting such tracers of deep circulation are discussed in the light of the spectroscopic detection of CO in the 5-μm window on Jupiter and the confirmation of PH3 on both Jupiter and Saturn. 相似文献
17.
Guido Visconti 《Icarus》1981,45(3):638-652
We present computations of the photodissociation coefficients for NH3, N2H4, PH3, and H2S in the Jupiter atmosphere. The calculations take into account multiple scattering and absorption using the radiative-transfer method known as δ-Eddington approximation. The atmospheric models include two cloud layers of variable thickness and haze layers above the upper cloud and between the clouds. One of the results of the radiative computations deal with the reflectivity of the Jovian atmosphere as a function of wavelength. A comparison with available data on the albedo of the planet gives some important indications about mixing ratios and distributions of gases and aerosols. The results for the photolysis rates are compared with similar rates obtained by considering either the direct flux or the flux determined by the molecular gas absorption alone. The latter is usually the approximation used in aeronomic models. The results of this comparison show that a considerable difference exists with direct flux photodissociation but significant differences with molecular absorption flux exist only in atmospheric regions where photodissociation is relatively small. 相似文献
18.
The global distribution of phosphine (PH3) on Jupiter and Saturn is derived using 2.5 cm−1 spectral resolution Cassini/CIRS observations. We extend the preliminary PH3 analyses on the gas giants [Irwin, P.G.J., and 6 colleagues, 2004. Icarus 172, 37-49; Fletcher, L.N., and 9 colleagues, 2007a. Icarus 188, 72-88] by (a) incorporating a wider range of Cassini/CIRS datasets and by considering a broader spectral range; (b) direct incorporation of thermal infrared opacities due to tropospheric aerosols and (c) using a common retrieval algorithm and spectroscopic line database to allow direct comparison between these two gas giants.The results suggest striking similarities between the tropospheric dynamics in the 100-1000 mbar regions of the giant planets: both demonstrate enhanced PH3 at the equator, depletion over neighbouring equatorial belts and mid-latitude belt/zone structures. Saturn's polar PH3 shows depletion within the hot cyclonic polar vortices. Jovian aerosol distributions are consistent with previous independent studies, and on Saturn we demonstrate that CIRS spectra are most consistent with a haze in the 100-400 mbar range with a mean optical depth of 0.1 at 10 μm. Unlike Jupiter, Saturn's tropospheric haze shows a hemispherical asymmetry, being more opaque in the southern summer hemisphere than in the north. Thermal-IR haze opacity is not enhanced at Saturn's equator as it is on Jupiter.Small-scale perturbations to the mean PH3 abundance are discussed both in terms of a model of meridional overturning and parameterisation as eddy mixing. The large-scale structure of the PH3 distributions is likely to be related to changes in the photochemical lifetimes and the shielding due to aerosol opacities. On Saturn, the enhanced summer opacity results in shielding and extended photochemical lifetimes for PH3, permitting elevated PH3 levels over Saturn's summer hemisphere. 相似文献
19.
New thermal profiles of Jupiter are retrieved from recent far infrared spectral measurements and for H2 mixing ratios varying from 0.8 to 0.94. The effective temperature corresponding to the inferred thermal profile is 123.15 ± 0.35°K. Far-infrared brightness temperature spectra computed from these profiles are compared to experimental data including measurements made at high spectral resolution in the NH3ν2 band at 10 μm and in NH3 pure rotational bands between 40 and 110 μm. It is found that a strong depletion of NH3 does occur in the Jovian stratosphere and that ammonia seems to be undersaturated in the upper troposphere. 相似文献
20.
Using a method defined in a previous paper [M. Combes and T. Encrenaz, Icarus39 1–27 (1979)], we reestimated the C/H ratio in the atmospheres of Jupiter and Saturn by the measurements of the weak visible CH4 bands, the CH4 3ν3 band, and the (3-0) and (4-0) quadrupole bands of H2. In the case of Jupiter we conclude that the C/H ratio is enriched by a factor ranging from 1.7 to 3.6 relative to the solar value. In the case of Saturn, our derived C/H value ranges from 1.2 to 3.2 times the solar value. The Jovian D/H ratio derived from this study is 1.2 × 10?5 < D/H < 3.1 × 10?5. The value derived for the D/H ratio on Saturn is not precise enough to be conclusive. 相似文献