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1.
The Wahongshan fault zone in Qinghai province is one of the most important faults in westem China. In this paper, deformation and X-ray petrofabrics have been studied in the middle segment of the fault. The results show that the formation of the fault zones can be divided into two major stages: ductile shear deformation stage and brittle deformation stage. The early stage ductile shearing leads to the formation of the NW-NNW trending mylonite zones along the fault, which is intensely cut by the late-formed brittle faults. X-ray petrofabrics of rocks near the faults indicate that the minerals in the tectonites show a great degree of orientation in the alignment. The quartz, which is a very important mineral in the tectonites, is deformed by basal face gliding or near basal face gliding, and sometimes by prismatic face sliding, which indicates that the rocks are deformed in epithermal to mesothermal or mesothermal environment, and the dynamic recrystallization also plays an important role in the formation  相似文献   

2.
Under the action of tectonic stress ore fluids carrying ore-forming materials can migrate from a higher stress district to a lower one.This is a fact which has been widely accepted by geological cir-cles.However,can the components migrate in solid rocks under the action of stress?This problem has long attracted the attention of many geologists.The author has made a series of simulating experi-tal system.The results show that mylonite was produced as a consequence of shear flowage deformation in dolomite .The contents of the elements in porphyryclast and flowage deformation matrix were analyzed by means of electron microprobe,and the results show that Pb and Zn are obvi-ously concentrated in the shear-flowage deformation zone.Furthermore,Pb is concentrated in its cen-tre while Zn is concentrated on its margins .Newly-formed micro-grained galena can be detected locally.  相似文献   

3.
Potassium fertilizer is in short supply in China. However, there is a considerable resource of insoluble potassium resources in the soil mineral or potassium-baring low-degrade rocks. Most of these kinds of potassium exist in aluminous silicate minerals from which potassium cannot be absorbed directly by plants. So it is very important to study how to release potassium from soil minerals or rocks by using biological action. Recently, a large number of researches on degradation of potassic mineral by bacterial but few by fungi have been reported. In order to study the degradation of potassic mineral by fungi, we isolated a strain of thermophilic fungi TH003, which can use potassic rock as nutrient source. The strain was identified as Aspergillus fumigatus based on its morphological characters and molecular biology. In this paper, the direct and indirect processes of mineral powder degradation with the strain of TH003 were studied： mineral powder was added in medium directly for cultivation so as to investigate the direct process. For the purpose of studying indirect process, mineral powder was wrapped up in a parcel using membrane with pore size of 0.22 μm, and then the parcels were added in the medium. The interaction between mineral granules and mycelia was observed by using TEM and AFM at different stages during the whole experimental procedure. The results showed that the effect of direct process is stronger than that of indirect process. For instance, the content of K^＋ is higher in both culture media and mycelia. Direct process includes mechanical demolishment, adsorption, parceling, phagocytosis, erosion and comprehensive effect, while indirect process only refers to erosion on the surface of mineral granules by metabolic products of mycelia. The technology of fermentation engineering was employed to study the biological effects of the strain of Aspergillus fumigatus TH003 on the minerals bating low-grade potassium. Nutrition factors and culture conditions that affect the process of mineral powder degrading with the strain of TH003 were studied in this paper. The results showed that glucose and corn steep are the optimal carbon and nitrogen resources in the strain culture medium, and that pH values range from 3.0 to 9.0.  相似文献   

4.
As the two important components of shale, organic matter(OM) and clay minerals are usually thought to strongly influence the hydrocarbon generation, enrichment and exploitation. The evolution process of OM and clay minerals as well as their interrelationship over a wide range of thermal maturities are not completely clear. Taking Yanchang(T_3y), Longmaxi(S_1l) and Niutitang(?_1n) shales as examples, we have studied the microstructure characteristics of OM and clay minerals in shales with different thermal maturities. The effects of clay minerals and OM on pores were reinforced through sedimentation experiments. Using a combination of field emission scanning electron microscopy(FESEM) and low-pressure N_2 adsorption, we investigated the microstructure differences among the three shales. The results showed that both OM and clay minerals have strong effects on pores, and small mesopore(2–20 nm) is the dominant pore component for all three samples. However, the differences between the three samples are embodied in the distribution of pore size and the location. For the T_3y shale, clay minerals are loosely arranged and develop large amounts of pores, and fine OM grains often fill in intergranular minerals or fractures. Widespread OM pores distribute irregularly in S_1l shale, and most of the pores are elliptical and nondirectional. The ?_1n shale is characterized by the preferred orientational OM-clay aggregates, and lots of pores in the composites are in the mesopore range, suggesting that over maturity lead to the collapse and compaction of pores under huge pressure of strata. The results of the current research imply that with increasing thermal maturity, OM pores are absent at low maturity(T_3y), are maximized at high maturity(S_1l) and are destroyed or compacted at over-mature stage(?_1n). Meanwhile, clay minerals have gone through mineral transformation and orientational evolution. The interaction of the two processes makes a significant difference to the microstructure evolution of OM and clay minerals in shale, and the findings provide scientific foundation in better understanding diagenetic evolution and hydrocarbon generation of shale.  相似文献   

5.
The migration, accumulation and dispersion of elements caused by tectonic dynamics have always been a focus of attention, and become the basis of tectono-geochemistry. However, the effects of faulting, especially strike-slip faulting, on the adjustment of geochemical element distribution, are still not clear. In this paper, we select the West Junggar Orogenic Belt (WJOB), NW China, as a case study to test the migration behavior of elements under tectonic dynamics. The WJOB is dominated by NE-trending large-scale sinistral strike-slip faults such as the Darabut Fault, the Mayile Fault, and the Baerluke Fault, which formed during the intracontinental adjustment under N–S compression during ocean-continental conversion in the Late Paleozoic. Geochemical maps of 13 elements, Al, W, Sn, Mo, Cu, Pb, Zn, As, Sb, Hg, Fe, Ni, and Au, are analyzed for the effects of faulting and folding on element distribution at the regional scale. The results show that the element distribution in the WJOB is controlled mainly by two mechanisms during tectonic deformation: first is the material transporting mechanism, where the movement of geological units is consistent with the direction of tectonic movement; second is the diffusion mechanism, especially by tectonic pressure dissolution driven by tectonic dynamics, where the migration of elements is approximately perpendicular or opposite to the direction of tectonic movement. We conclude that the adjustment of element distributions has been determined by the combined actions of transporting and diffusion mechanisms, and that the diffusion mechanism plays an important role in the formation of geochemical Au blocks in the WJOB.  相似文献   

6.
The dolomitic rocks of the Fengcheng Formation are considered to be formed under special geologic conditions, and are significant hydrocarbon reservoir rocks in the Wu-Xia area in the Junggar Basin. Analyses of petrologic characteristics and stable isotope composition indicate that the dolomitizing host rock is volcanic and the dolomitizing fluids probably consists of brine from shore-shallow lakes with great evaporation and salinity in the Fengcheng Formation, which have formed under arid climatic conditions, as well as residual Mg-rich seawater from the underlying Jiamuhe Formation and Carboniferous. Dust tuff in the area has significant plagioclase content. Anorthite and labradorite hydrolysis by CO2 can be coupled with calcite precipitation. Late Mg-rich brine percolated and replaced calcite formed in the early time, which lead to precipitate dolostones with different occurrences, such as graniphyric, random bedded or lumpy. The diagenetic dolostones with different occurrences resulting from particular formation conditions occurred in different tectonic settings. The dolomitizing fluid has been driven by the thermal convection flow generated by volcanic eruptions. At the same time, the overthrusts of the Wu-Xia growth fault?have speeded up the flow of deep Mg-rich water upwards, and induced the water to quickly?penetrate and horizontally migrate in the strata. Fracture is the major and the most important reservoir space in dolomitic reservoir of the Fengcheng Formation. Fracture and fault plays a decisive role in controlling the formation of dolostone and the distribution of favorable reservoirs. The deliverability of oil and gas is determined by the development and match relations of dissolved pores and fractures to a certain degree.  相似文献   

7.
We investigated the weathering-pedogenesis of carbonate rocks and its environmental effects in subtropical regions of China. The investigation demonstrated that the weathering- pedogenesis of carbonate rocks is the process of a joint action of corrosion and illuviation and metasomatism in subtropical region. It is characterized by multi-stage, multi-path and multi-style. With the persisting development of weathering-pedogenesis of carbonate rocks, metasomatic pedogenesis progressively became the main process of the weathering-pedogenesis and the dominant style of formation of minerals. And it proceeds through the whole process of evolution of the weathering-pedogenesis of carbonate rocks. The stage evolution of weathering-pedogenesis of carbonate rocks and the fractionation evolution of newly produced minerals are characterized by obvious vertically zoning structures and the rules of gradation of elements geochemical characteristics in the carbonate rocks weathering profiles. The geochemical process of weathering-pedogenesis of carbonate rocks can be divided into three geochemical evolution stages, i.e., the Ca, Mg-depletion and Si, Al-enrichment stage; the Fe, Mn enrichment stage and the Si-depletion and Al-enrichment stage in the subtropical regions. Consistent with the three geochemical evolution stages, the sequence of formation and evolution of minerals can be divided into the clay mineral stage; the Fe, Mn oxide and the gibbsite stage. The influence of weathering-pedogenesis of carbonate rocks on the chemical forms of heavy elements is mainly affected via newly produced components and minerals in the process of weathering-pedogenesis, e.g., iron oxide minerals and organic matters. The important mechanism for the mobilization, transport and pollution of F and As is affected the selective adsorption and desorption of F and As on the surface of iron oxide minerals in the subtropical karst zones, i.e., the selective adsorption and desorption on mineral surfaces of newly produced minerals in the process of weath  相似文献   

8.
The Linglong-Jiaojia district is one of the most important regions containing gold deposits in China. These gold deposits can be divided into: a) the pyrite-gold-quartz vein type (Linglong type), which is controlled by brittle-ductile to ductile deformation structures, and b) the alteration-zone type (Jiaojia type), characterized by small veinlets, or the disseminated type recognized in brittle shear zones. Lode gold deposits in the Jiaojia area occur in NE brittle fracture zones, formed in a dominantly simple shear deformation regime, mainly in thrust attitude with a minor sinistral strike slip component. In the Linglong area, the lode gold deposits are located at the intersection of three types of structures: NNE and NE brittle-ductile fault zones and the ENE ductile reverse shear zone in the south of the area. The structural characteristics of these brittle shear zones are consistent with a tectonic NNW-SSE principal stress field orientation. Similar stresses explain the ENE Qixia fold axes, the Potouqing and several other ENE reverse ductile shear zones elsewhere in the region, the Tancheng-Lujiang fault zone and its subsidiaries in the vicinity of the Linglong-Jiaojia district, as well as the southern ENE suture zone north of Qingdao. Therefore these structural systems occurred as part of different major tectonic events under NNW-SSE compression principal stress fields in the area. Gold deposits are hosted in smaller-scale structures within the brittle fault zones and brittle-ductile shear zones. Although ore bodies and, on a smaller scale, quartz ore veins often seem to be randomly oriented, it is possible to explain their distribution and orientation in terms of the simple shear deformation process under which they were developed. The progressive simple shear failure is characterized by various fracture modes (tension and shear) that intervene in sequence. The tension and shear fractures are influenced by the stress level (depth of burial beneath the paleosurface) in their structural behavior, show variable dilatancy (void openings) and extend on all scales. By making use of these characteristics, a progressive failure analysis can be applied to predicting the shape and extent of ore bodies as well as the styles of mineralization at any given location.  相似文献   

9.
The seismotectonic characteristics of ten repeated earthquake swarm sequence within a seismic cluster along Jiali Fault in eastern Himalayan Syntaxis(EHS) have been analysed.The swarms are spatially disposed in and around Yigong Lake(a natural lake formed by blocking of Yigong River by landslide) and are characterized by low magnitude,crustal events with low to moderate b values.Ms:mb discriminant functions though indicate anomalous nature of the earthquakes within swarm but are considered as natural events that occurred under condition of high apparent stress and stress gradients.Composite fault plane solutions of selected swarms indicate strike-slip sense of shear on fault planes;solution parameters show low plunging compression and tensional axes along NW-SE and NE-SW respectively with causative fault plane oriented ENE-WSW.dipping steeply towards south or north.The fault plane is in excellent agreement with the disposition and tectonic movement registered by right lateral Jiali Fault.The process of pore pressure perturbation and resultant 'r—t plot' with modelled diffusivity(D = 0.12 m~2/s) relates the diffusion of pore pressure to seismic sequence in a fractured poro-elastic fluid saturated medium at average crustal depth of 15-20 km.The low diffusivity depicts a highly fractured interconnected medium that is generated due to high stress activity near the eastern syntaxial bent of Himalaya.It is proposed that hydro fracturing with respect to periodic pore pressure variations is responsible for generation of swarms in the region.The fluid pressure generated due to shearing and infiltrations of surface water within dilated seismogenic fault(Jiali Fault) are causative factors.  相似文献   

10.
The Jiangshan-Shaoxing-Pingxiang Fault(JSP Fault) is traditionally considered as the boundary between the Yangtze and Cathaysia blocks in South China. Whether the previously defined Shenshan and Kuli formations located along the JSP fault and near the Xinyu City, Jiangxi Province, are continuous strata or parts of a tectonic mélange is important for understanding the geological history of South China. A carbonaceous phyllite from the area, previously considered as part of the Neoproterozoic Shenshan and Kuli formations, is analyzed palynologically in this study. The AsteridiumComasphaeridium acritarch assemblage found in the slate can be correlated with the basal Cambrian AsteridiumHeliosphaeridium-Comasphaeridium(AHC) acritarch assemblage in Tarim and the Yangtze Block. The early Cambrian biostratigraphical age assignment for the carbonaceous phyllite indicates the presence of both Neoproterozoic and Cambrian rocks in the sedimentary package, and supports that the package is a part of tectonic mélange rather than a continuous Neoproterozoic strata. The Cambrian slate is the youngest known lithology in the mélange at present.  相似文献   

11.
Classic physical and chemical treatments applied to separating clay minerals from the host sediments are often difficult or aggressive for clay minerals. A technique using cation exchange resins (amberlite IRC-50H and amberlite IR-120) is used to separate clay minerals from the host sediments. The technique is based on the exchange of cations in the minerals that may be associated clay minerals in sediments, such as Ca and Mg from dolomite; Ca from calcite, gypsum and francolite with cations carried by resin radicals. The associated minerals such as gypsum, calcite, dolomite and francolite are removed in descending order. Separation of clay minerals using cation exchange resins is less aggressive than that by other classic treatments. The efficiency of amberlite IRC-50H in the removal of associated minerals is greater than that of amberlite IR-120.  相似文献   

12.
断裂构造研究的进展和趋势   总被引：3，自引：0，他引：3  
Fault is the most important type of tectonics in the earth crust一lithosphere. It is the faults，is a dominant elements,SVhich construct regional tectonic architecture. Fault controlled not only the evolution and the transverse inhomogenity of regional tectonics,but also the laminary structure of the earth crust-lithosphere. Three kinds of faults(compressional fault，extensional fault and strike-slip fault) may be formed by three kinds of tectionic stress-fields in the earth crust. The fault might occur individually and combine to each other as well. The recent progress and the tendency of fault research are summarized in this paper from historical review and recent analysis of study in three type fault,in orderto undertand the orentation which must be held.  相似文献   

13.
Convective heat transfer associated with the circulation of pore-fluid in porous rocks and fractures within the upper crust of the Earth is substantial when the temperature gradient is sufficiently high.In order to understand the process of Sn-polymetallic mineralization in the Dachang ore district of Guangxi,a finite element method has been used in this study to simulate both pore-fluid flow and heat transfer in this district.On the basis of related geological,tectonic and geophysical constraints,a computational model was established.It enables a computational simulation and sensitivity analysis to be carried out for investigating ore-forming pore-fluid flow and other key factors that may affect hydrothermal ore genesis in the district.The related simulation results have indicated that:(1) permeable fault zones in the Dachang ore district can serve as preferential pathways for pore-fluid flow on a regional-scale;and(2) the pore-fluid flow can affect the salinity distribution.This latter factor is part of the reason why Sn-polymetallic mineralization has taken place in this district.  相似文献   

14.
The Lower Palaeozoic system is a series of iron-bearing rocks consisting mainly of shallow sea-facies carbonates. On the basis of micrafacies analysis of the carbonate rocks,the Lower Palaeozoic sedimentary sea basin is divided into two broad sedimentary-structural regions,four sedimentary facies and nine subfacies. Original iron-rich carbonates were deposited in the restricted basins, such as salt-lake, lagoon, etc. Over the long period of geological history, the original iron formations were reconstructed by late tectonic processes to various extents. Geological observations and studies of the equilibrium mechanism of oxygen and sulfur isotope fraetionation and the composition and temperatures of fluid inclusions in the minerals indicate that thermal brines played an important role in the reworking process of the original iron-rich carbonate rocks, which thus led to the formation of sedimentary-reworked strata-bound ore deposits.  相似文献   

15.
Fault geometry, kinematics, geophysics, the tectonic stress field and tectonic evolution of the Zhouwang fault in the southern Jiangnan tectonic transition zone of the Lower Yangtze region, eastern China are examined. Field observations show the fault is composed of a series of nearly E–W trending, N–S dipping faults, and four stages of tectonism (sinistral strike-slip, thrust nappe, normal fault, and dextral strike-slip) developed in turn. Geophysical data show that the fault trends almost linearly E–W along a flat, steep gravity gradient at shallow depth, with distinct gravity anomalies to the north and south and different in the north and south. Also, the deep part is characterized by northward dip and a gradual slowing down. Tectonic stress field analysis indicates that the fault experienced four tectonic movements: NNE–SSW compression, NNW–SSE compression, NEE–SWW extension, and E–W compression. Combined with regional tectonic background and previous research results, this indicates that: (1) the Zhouwang fault experienced sinistral strike-slip movement during the Indosinian Period (260–200 Ma); (2) thrust nappes developed during the early Yanshanian Period (163–145 Ma); (3) a normal fault occurred in the late Yanshanian Period (125–65 Ma); and (4) dextral strike-slip movement occurred in the Himalayan Period (ca. 50–37 Ma). The results reveal the tectonic evolution of the fault during Mesozoic deformation in the area, and also reveal the geological evolution and tectonic transformation of the Lower Yangtze region, which is key to our understanding of intracontinental deformation in eastern China.  相似文献   

16.
The ultrahigh-pressure eclogites from the northern Dabie Mountains in central China occurred as tectonic lens or blocks within granitic gneisses or meta-peridotites. Petrologic studies suggest that the studied eclogites experienced strongly retrogressive metamorphism and produced a series of characteristic retrogressive microstructures. The retrograde structures mainly include: (1) oriented needle mineral exsolution, e. g. , quartz needles in Na-clinopyroxene and rotile, clinopyroxene and apatite exsolution in garnet formed under decreasing pressure conditions during exhumation; (2) symplectite, especially, two generations of symplectites developed outside the garnet grains, which are called ““double symplectite““ here; (3) compositional zoning of minerals such as garnet and clinopyroxene; (4) minerals with a reaction rim or retrograde rim, e.g. , omphacite with a diopside rim, diopside with an amphibole rim and rutile with a rim of ilmenite. These retrograde textures, especially mineral zoning and symplectite, provide important petrologic evidence for the exhumation process and uplift of high-grade metamorphic rocks such as eclogite in the northern Dabie Mountains, indicating a rapid exhumation process.  相似文献   

17.
The fundamental theoretical framework of the Multisphere Tectonics of the Earth System is as follows: (1) It intends to extend the geotectonic studies from the crustal and lithospheric tectonics to the multisphere tectonics of the Earth system as a whole. (2) The global dynamics driven by both the Earth system and the cosmic celestial system: solar energy, multispheric interactions of the Earth system and the combined effects of the motions of celestial bodies in the cosmos system are the driving forces of various geological processes. (3) The Continent-Ocean transformation theory: the continent and ocean are two opposite yet unified geological units, which can be transformed into each other; neither continent nor ocean will survive forever; there is no one-way development of continental accretion or ocean extinction; the simple theory of one-way continental accretion is regarded as invalid. (4) The continental crust and mantle are characterized by multiple layers, with different layers liable to slide along the interfaces between them, but corroboration is needed that continents move as a whole or even drift freely. (5) The cyclic evolution theory: the development of Earth’s tectonics is not a uniform change, but a spiral forward evolution, characterized by a combination of non-uniform, non-linear, gradual and catastrophic changes; different evolutionary stages (tectonic cycles) of Earth have distinctive global tectonic patterns and characteristics, one tectonic model should not be applied to different tectonic cycles or evolutionary stages. (6) The structure and evolution of Earth are asymmetric and heterogeneous, thus one tectonic model cannot be applied to different areas of the world. (7) The polycyclic evolution of the continental crust: the continental crust is formed by polycyclic tectonics and magmatism, rather than simply lateral or vertical accretion. (8) The role of deep faults: the deep fault zones cutting through different layers of the crust and mantle usually play important roles in tectonic evolution. For example, the present-day mid-ocean ridge fault zones, transform fault zones and Benioff zones outline the global tectonic framework. Different tectonic cycles and stages of Earth’s evolution must have their own distinctive deep fault systems which control the global tectonic framework and evolutionary processes during different tectonic cycles and stages. Starting from the two mantle superplumes Jason (Pacific) and Tuzo (Africa), the study of the evolutionary process of the composition and structure of the crust and mantle during the great transformation and reorganization of the Meso-Cenozoic tectonic framework in China and the other regions of Asia is a good demonstration of theory of Multisphere Tectonics of the Earth System.  相似文献   

18.
The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.  相似文献   

19.
Amphibole is a rock-forming mineral widely existing on the earth. It is easily dissolved and altered during the later stage of diagenesis and mineralization, and often forms chloritization, which is an important indicator for prospecting. To explore amphibole's dissolution process and alteration mechanism, dissolution experiments were carried out under acidic conditions using pargasite-rich amphibole as raw material, and the effects of temperature, p H, and experiment duration on amphibole alteration were investigated. Experimental samples and products were analyzed using X-ray diffractometer, field emission scanning electron microscope, electron probe micro analyzer, and transmission electron microscopy. It was found that many pores and erosion edges are produced after amphibole dissolution, and there is a clear interface between the dissolved residual portion and the parent. The dissolved residual portion remains in the amphibole phase, but as the temperature and time increase, the intensity of the diffraction peak of the phase in the product decreases, and the peak position shifts to a small angle. Many clay minerals such as chlorite and griffithite formed on the amphibole surface. In an environment with strong acidity(p H=3), the amount of chamosite increases with temperature(180°C→210°C→240°C), whereas clinochlore is only increased in a 150–210°C environment. Griffithite growth was observed in the acidic(p H=6) and low temperature(180°C) environments. Based on this analysis, large radius Cl– enters the amphibole lattice or cracks to promote dissolution. The Al-poor and Ca-and Fe-rich regions between the edge and core of the amphibole are caused by dynamic equilibrium in amphibole dissolution and alteration process, which is an essential indicator for the beginning of amphibole dissolution-alteration. Diffusion and the coupled dissolution-reprecipitation mechanism accomplishes the process of dissolution and alteration to form clay minerals. The energy of the system determined by temperature and p H is the key to controlling the rate of growth and nucleation of clay minerals. High temperature and strong acidity will dissolve more iron from amphibole, which is conducive to chlorite growth. Compared to chlorite, griffithite is more sensitive to temperature. Griffithite attaches on the amphibole surface with a star-like in a weak acid and low-temperature environment. The results of this study can provide a mineralogical basis for the analysis of hydrothermal alteration processes and the division of alteration zones.  相似文献   

20.
《中国地球化学学报》2006,25(B08):194-195
The immobilization conditions of heavy metals （Ni, Cu, Zn, Pb） potentially released from sewage sludge to soils were examined. Competitive adsorption experiments, sequential extraction and analytical electron microscopic studies were performed on soils with different compositional characteristics to gain information about the interaction and association of metals with soil minerals. The results showed that Cu and Pb can be characterized by a preferred adsorption in contrast to Zn and Ni independent of initial metal concentrations, ratios, and soil composition. Precipitation is the dominating retardation process in the sample containing carbonates, but it is also characteristic of metals with inhibited adsorption in samples free of carbonate. Both Cu and Pb show high affinity towards organic matter. Differences in metal affinities towards different clay minerals show the immobilization of Cu rather by specific adsorption and that of Pb rather by ion exchange. According to the sequential extraction studies the role of ion exchange is the most important process for the retardation of Zn, and in the sample containing montmorillonite. The specific adsorption is significant mostly for Cu and Pb, and primarily in samples rich in organic matter and containing vermiculite. The co-precipitation of metals with Fe-Mn oxides is significant primarily for Cu, but in some cases Pb and Zn can be also found in this fraction. In general, the strength of immobilization for the studied metals is as follows： Cu〉Pb〉Zn〉Ni. Significantly higher metal adsorption was found by the phases in the sample containing carbonates, as well as in samples characterized by the close association of clay minerals and iron oxides. Smectite and vermiculite are the most important adsorbents in soils for all of the metals. Additionally, iron-oxides immboilize significant amounts of Cu and Zn, too.  相似文献   

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