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1.
Heavy Metal Concentrations in European Mosses: 2000/2001 Survey   总被引：3，自引：0，他引：3  
The heavy metals in mosses survey was originally established in 1980 as a joint Danish–Swedish initiative under the leadership of Åke Rühling, Sweden and has, since then, been repeated at five-yearly intervals with an increasing number of countries and individuals participating. Twenty-eight European countries, almost 7000 sites and about 100 individuals have been involved in the most recent survey in 2000/2001. The survey provides data on concentrations of 10 heavy metals (arsenic, cadmium, chromium, copper, iron, lead, mercury, nickel, vanadium, zinc) in naturally growing mosses throughout Europe. The technique of moss analysis provides a surrogate measure of the spatial patterns of heavy metal deposition from the atmosphere to terrestrial systems, and is easier and cheaper than conventional precipitation analysis. The aims of the survey are to determine patterns of variation in the heavy metal concentration of mosses across Europe, identify the main polluted areas, produce regional maps and further develop the understanding of long-range transboundary pollution.As in previous surveys, there was an east/west decrease in heavy metal concentrations in mosses, related in particular to industrial emissions. Former industrial sites and historic mines accounted for the location of some high concentrations in areas without contemporary industries. Long-range transboundary transport appears to account for elevated concentrations of heavy metals in areas without emission sources, such as lead in southern Scandinavia (presumably from emission sources elsewhere in Europe).  相似文献   

2.
The first systematic study in Romania of atmospheric pollution from heavy metals and other toxic elements based on moss analysis was undertaken as a Romanian–Russian–Norwegian collaboration, primarily in order to assess the general state of heavy metal pollution in Romania. An additional goal was to contribute to the European heavy metals in mosses survey, conducted under the auspices UNECE ICP Vegetation which reports to the Working Group of Effects of the Long-range Transboundary Air Pollution Convention. Samples of the moss species Hypnum cupressiforme, Hylocomium splendens and Brachytechium salebrosum and B. rutabulum were collected during the period 1995–2001. A total of 40 elements were determined using NAA and AAS. The total concentrations of arsenic, cadmium, copper, nickel, vanadium and zinc are presented in the form of contour maps. Generally, the observed concentrations in Romania are markedly higher than those observed in most other countries of Europe using the moss technique.  相似文献   

3.
Concentrations of the elements Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, V and Zn were measured in the moss Pleurozium schreberi from the Tatra National Park, one of the most protected regions in Poland. The moss samples were collected at different elevations between 860 and 2220 m a.s.l. P. schreberi was used as bioindicator for long range transported atmospheric pollution investigating the hypothesis that elevation influences the concentrations of elements in this moss. Principal component and classification analysis (PCCA) distinguished between mosses from the highest and the lowest elevations and mosses from West/East oriented valleys. P. schreberi from the highest elevations contained the highest concentrations of Cd, Cu, Cr, Fe, Mn, Pb, V and Zn. P. schreberi from the lowest elevation contained the highest concentration of K. P. schreberi from West/East oriented valleys contained the highest concentrations of Ni and Co. P. schreberi from the Tatra National Park, one of the most protected areas in Poland, receives metals originating from long distance aerial transport.  相似文献   

4.
The heavy metal content was investigated in meadow plants located in a cultivated area and situated along the M3 motorway (Hungary). In addition to the meadow plants used as passive bioindicators, active bioindicators were also exposed to examine the accumulation rate of air pollutants. Tortula ruralis (Hedw.) Geartn. ssp. ruralis was applied to monitor the status of the environment. Meadow plant samples were collected at distances of 5, 10, 25, 50 and 100 m from the motorway and moss samples were exposed at the same distances. The zinc, lead and cadmium content of meadow plants and moss samples were analysed by ICP spectrophotometry. It was found that the zinc, lead and cadmium contents of the meadow plants decreased as the distance increased from the motorway. There was a significant difference even between values measured at the distances of 5 m and 10 m. The heavy metal contents in the moss samples exceeded those of the meadow plants. The heavy metal content in moss samples decreased with distance from the motorway. On comparing the data with Hungarian standards, it was found that measured values did not exceed the maximum allowed concentration levels.  相似文献   

5.
Goal and Scope. The UNECE heavy metals in Mosses Surveys provide data on the accumulation of metals in naturally growing mosses throughout Europe. Using Germany as an example, this article concentrates on the elaboration and application of methods of data analysis that are necessary for a comprehensive interpretation of spatial and temporal trends in metal accumulation.Methods and Results. The sampling of mosses, and the chemical analysis of Cr, Cu, Fe, Ni, Pb, Ti, V and Zn in 1990, 1995 and 2000 are summarized briefly. The variogram analyses detect distinct autocorrelation structures in the sample data which may consequently be estimated for all sites in Germany without monitoring metal accumulation by means of ordinary kriging. A procedure for the geostatistical detection of spatial outliers was developed and applied and, after the elimination of the spatial outliers, several measurements were seen to indicate an adequate quality of the geostatistical estimations. The cluster analyses of the z-transformed estimation data result in a nominal multi-element index that indicates regional metal accumulation types over time. Percentile statistics serve for computation of an ordinal, scaled, multi-element accumulation index which is spatially differentiated over time in terms of multivariate, statistically defined ecoregions. The integrative statistical analysis reveals, from 1990 to 2000, that the metal accumulation declines up to 80% in some of the ecoregions. Hot spots of metal accumulation are mapped and interpreted by means of metadata analysis.Conclusions. Dot maps depict the spatial structure of the metal accumulation without spatial bias. This information, detailed with respect to metal species and space, should be generalized for better supporting the interpretation. The combination of geostatistical analysis and estimation, percentile and multivariate statistics is suitable for the calculation of indices that serve for a comprehensive mapping of metal accumulation in the ecoregions over time, for quantifying the bias of the surface estimation, and for mapping spatial outliers and hot spots of metal accumulation.  相似文献   

6.
Calibration of Four Species of Tillandsia as Air Pollution Biomonitors   总被引：1，自引：0，他引：1  
Many organisms have been used as bioindicators of atmospheric contamination, with moss and lichen species being the most common. However, studies using epiphytic vascular species of Tillandsia have shown a good correlation between the presence of pollutants and the bioindicator's response. Therefore, the aim of our investigation was to calibrate and compare the response of four Tillandsia species of Argentina to ascertain whether they could be used as atmospheric contamination biomonitors. For this, we analysed the correlation between the levels of heavy metals in total atmospheric deposition samples and: a) their rate of enrichment; b) the physiological response of the plant samples. Tillandsia samples collected from a non contaminated area in the province of Córdoba were transplanted to four areas in the capital city with different sources of pollution (industrial or traffic emissions). They were exposed for a period of 3 to 6 months after which the concentrations of Pb, Ni, Fe, Zn, Cu and S as well as the physiological parameters of foliar damage were determined. Simultaneously samples of total atmospheric deposition were also taken.The highest level of metal enrichment was found in T. capillaris followed by T. tricholepis, T. permutata and T. retorta. Also, the use of a foliar damage index proved to be effective and could be a useful tool to evaluate different levels of atmospheric quality in these species. The rate of heavy metal deposition was higher in the industrial area for all metals except for Zn whose values were higher in areas with high levels of traffic.  相似文献   

7.
To test the ability of Hylocomium splendens segments to retain absorbed heavy metals (Fe, V and Pb) and some physiological elements (Ca, Mg and K) over a period of some years, moss turf was cross-transplanted between polluted and background sites. Thereby it was possible to determine how quickly the concentrations in moss can reach chemical equilibrium with the atmospheric inputs. At a particular site (background or polluted), the physiological elements in transplanted material quickly reached the levels in the non-transplanted moss. For the heavy metals, the concentrations remained stable over 3 years in moss cross-transplanted from a polluted to a background site. There appeared to be inherent differences between moss at the background and polluted sites in the ability to absorb and accumulate heavy metals.  相似文献   

8.
Three different growth forms of lichens belonging to six species; Phaeophyscia hispidula, Parmotrema praesorediosum (foliose); Caloplaca subsoluta, Diploschistes candidissmus (crustose) and Peltula euploca, Phylliscum indicum (squamulose) were studied comparatively for the biomonitoring of Al, Cd, Cr, Cu, Fe, Ni and Zn in Mandav city in central India. Based on the anthropogenic activities three sites were selected for lichen collection. To identify the sources of heavy metal pollution, their concentration was analyzed in thallus as well as in their respective substrates. The thallus of studied lichens showed higher concentration of metals such as Cd, Cr, Ni and Zn, while most of the metals were absent or present in negligible amount in substrates (Fe, Al, Cu), which proves that the accumulated metals were air borne. The foliose lichens (P. hispidula and P. praesorediosum) found highly significant in metal accumulation at each sites followed by crustose and squamulose forms. Lichen samples collected from site 2, adjacent to road side accumulated maximum quantities of Zn, Ni, Cd and Cr whereas the city centre (Site 1) had maximum concentrations of Fe, Cu and Al. The site 3 situated away from the city had lowest amount of all the metals. The analysis of variance and LSD indicated that the metal concentrations among lichen species as well as between substratum is significant at p < 0.05% and P < 0.01% level respectively.  相似文献   

9.
This research is continuation of the investigation of metal accumulation in native and transplanted moss Pleurozium schreberi in the most industrialized and affected region in Poland (Upper Silesia). We tested the hypotheses that in Upper Silesia transplants of P. schreberi may be used in a 90 days bioindication experiment in case native specimens are absent; a 90 days exposure of transplanted P. schreberi was long enough for evaluation of Hg pollution of the environment. An assay was carried out with native mosses at 27 polluted sites and mosses from an uncontaminated control site transplanted to the same 27 polluted sites. P. schreberi collected from the same sites as classified for more and less polluted basing on Pb and Zn concentrations show quite different pattern of pollution with mercury; The accumulation of Hg by the transplants increased much faster in the first 45 days of the experiment (accumulation factor 1.5–6.7; mean 3.4?±?0.5) in comparison with the second period from day 45 to 90 (accumulation factor 1.0–1.6; mean 1.2?±?0.1). The 90 days exposure of transplanted P. schreberi was long enough for evaluation of Hg pollution of the environment. Transplants of P. schreberi may be used in a 90 days bioindication experiment in case native specimens are absent.  相似文献   

10.
The objective of this study was to determine the air pollution level of Ankara and to generate the air pollution map of this city by using Pseudevernia furfuracea (L.) Zopf as a biomonitor. Lichen samples were collected from unpolluted area at Yaprakli Mountains, Cankiri in November 2002 and transplanted to 27 localities in Ankara. Lichen samples were retrieved following an exposure of 3 and 6 months. Heavy metal, Cu, Mn, Ni, Pb and Zn, contents were determined by using inductively coupled plasma spectrometry (ICP). The chlorophyll a and b contents were determined by using DMSO method. The increase in Ni, Pb, Zn and chlorophyll a content of the specimens were statistically important. All the increases and decreases in the variables could be explained by the environmental stress like pollution, but it is hard to say that this is the only reason of these changes, also climatic conditions, seasons, strength of the light and the physiological status of the plant itself effective on these changes. According to the results of heavy metal analysis Pseudevernia furfuracea continued to accumulate heavy metals and worked well as a biomonitor. The air pollution level of Ankara shows great variations because of the great area of the city.  相似文献   

11.
In the year 2000, the elemental composition of mosses collected from 528 French sites has been studied as part of the 2000 European Moss Survey. Five moss species were collected: Scleropodium purum (56%), Pleurozium schreberi (18%), Hypnum cupressiforme (18%), Thuidium tamariscinum (4.5%.) and Hylocomium splendens (3.5%). Mosses were kept whole for analysis, including green and brownish parts. Summary statistics on element concentrations (Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Li, Mg, Mn, Na, Ni, P, Pb, Rb, Sr, V and Zn), and comparisons made with data from the other 27 participating European countries are shown here. The sources of these elements are identified using calculations of enrichment factors (EF) and principal component analysis (PCA). Finally, the spatial distribution in France of 10 elements is also shown, using maps underscoring areas showing highest concentration levels for each metal.  相似文献   

12.
Data of 34 elements, including heavy metals, halogens, rare earth elements, U, and Th in 139 moss samples, collected in Central Russia in 2000–2002 in the Tver and Yaroslavl regions and in the northern part of the Moscow region, are presented. Factor analysis with VARIMAX rotation was applied to identify possible sources of the elements determined in the mosses. The seven resulting factors represent crust, vegetation and anthropogenic components. Some of the factors were interpreted as being associated with ferrous smelters (Fe, Zn, Sb, Ta); combination of non-ferrous smelters and other industries (Mn, Co, Mo, Cr, Ni, W); an oil-refining plant, and oil combustion at the thermal power plant (V, Ni). The geographical distribution patterns of the factor scores are also presented. Dependency equations of elemental content in mosses versus distance from the source were derived.  相似文献   

13.
The sorption studies of Hg2+, CH3Hg+ and elemental mercury (Hg0) were carried out on lichen (Parmelia sulcata) and moss (Funaria hygrometrica) samples under laboratory conditions. Desorption studies with HCl indicate that inorganic mercury (Hg+2) and methyl mercury could be completely desorbed with 1 M HCl and 0.5 M HCl, respectively. Samples loaded with elemental mercury, however, needed 4–5 M HCl concentration for complete desorption of the adsorbed elemental mercury. When similar desorption studies were carried out with field samples collected around a thermometer factory with elevated levels of mercury (8 mg/kg), it was found that only about 10–15% of total mercury was desorbed with 1M HCl, while 4–5 M acid was required for complete desorption. We have tried to correlate this information to understand the transformations of mercury species that may occur either in the atmosphere or on the biomonitors. The results indicated that the elemental mercury, the principal form of mercury contamination around the thermometer factory, is converted into a strongly held form by some chemical binding agents on the surface of lichen/moss, or elemental mercury could diffuse into the cells of the lichen/moss, which then needs the stronger acid to release it. Sorption capacity studies suggest that the lichens and mosses can also be used as sorbent material for the decontamination of inorganic and methyl mercury from aqueous solutions.  相似文献   

14.
The results of an investigation about the vertical distribution patterns of selected trace elements in an urban environment, as reflected by their accumulation in lichen transplants, are reported. Thalli of the lichen Pseudevernia furfuracea were transplanted in 2 sites in the urban area of Thessaloniki (N Greece), subjected to very different traffic loads: 1) Tsimiski, downtown of Thessaloniki, at one of the busiest streets of the city, a street canyon 2) Toumba, far from the city centre, at the edge of the city, at an open street. In each site, thalli were suspended along a vertical transect at 3, 6, 9 and 12 m, and retrieved after one year. The results showed that while at Toumba the elemental composition of lichen samples was essentially influenced by natural occurrence, mainly airborne soil dust, at Tsimiski also anthropogenic input of pollutants determined by vehicle traffic was involved for some elements such as Cd, Cu, Ni, Pb and Zn. The vertical distribution patterns of heavy metals accumulated in lichens showed that in general elevation has no statistically significant influence on the concentration of most metals, but this was not true for Pb, whose concentrations increased with increasing elevation from ground. Residents may thus be more exposed to high concentrations of Pb than pedestrians.  相似文献   

15.
The aim of the present study was to determine the optimal size of the sampling area that should be used in the moss biomonitoring technique, in relation to the spatial variation in the concentrations of contaminants determined in samples collected within short distances (<30 m). For this, the spatial structure in the concentrations of various metals and metalloids was explored by use of semivariograms calculated by use of a robust estimator of the variance. In each of the 3 sampling sites considered in the study (one sampled on two occasions), 50 samples of the moss Pseudoscleropodium purum were collected and the tissue concentrations of As, Cd, Cu, Hg, K, Ni, Pb, Se and Zn were determined. The results obtained show that in most cases (25 out of 32), there was no spatial structure in the concentrations of the elements and that the semivariograms were subject to the nugget effect. For those elements for which spatial independence or a linear spatial structure was observed, the size of the sampling area did not affect the results, and the dimensions were irrelevant within the range studied. The existence of spatial structure, which can be fitted to a spherical model, enabled a range of autocorrelation to be defined, which corresponded to an area of diameter >16 m. The proposed method must be applied to other species and in other regions, in order to standardize the size of the sampling sites in the moss biomonitoring technique.  相似文献   

16.
The effects of growth of autoirrigated, shaded transplants of Pseudoscleropodium purum on the quantification of tissue concentrations of Cd, Cu, Hg, V and Zn, were investigated in 4 exposure periods, each of 56 days, at 7 sampling sites (contaminated and uncontaminated). Concentrations of the elements in the basal portions of the moss shoots were compared with the concentrations in the portions of the shoots that grew during the exposure period. Mercury and V were present at lower concentrations in the new portions of the shoots than in the basal portions, whereas the opposite was true for Cd, Cu and Zn. The magnitude of error introduced by growth was not negligible, and in some cases was higher than 40%, relative to the results obtained by analysis of the whole shoot. Devitalization of moss prior to its use as transplant material is recommended to avoid growth of the plant during the exposure period.  相似文献   

17.
The concentrations of heavy metals (Cd, Cr, Cu, Pb, Ni, V, Zn) in feather moss were estimated in national surveys in Latvia in 1990, 1995 and 2000. Hylocomium splendens was used as a biomonitor in 1990 and Pleurozium schreberi in the latter two years. Maps of the distributions of the metals in Latvia have been produced. The paper discusses the reasons underlying the distributions and also the temporal trends during the last ten years.  相似文献   

18.
Many lichens are very sensitive to air pollution due to their symbiotic nature. However, they are generally less sensitive to toxic effects of trace elements; therefore they can be used as accumulator organisms for estimating concentrations of these elements in the environment. Heavy metal accumulation in lichens is a commonly used bioindication method for assessing heavy metal ambient levels. An active biomonitoring method was used for the determination of short-term accumulation of zinc, lead, arsenic and cadmium by epiphytic lichens transplanted at different localities in Slovenia polluted by heavy metals. The atomic absorption spectrophotometry method was used for the determination of heavy metal content in lichen thalli. The content of heavy metals in lichens collected in the background area with clean air (Rogla, Pohorje Mountains) was used as the reference value. Lichens were transplanted from Rogla using the branch transplantation technique for a period of 6 months in the surroundings of Slovenian thermal power plants (Velenje, otanj, Zavodnje, Veliki Vrh, Vnajnarje, and Dobovec) and close to the lead and zinc ore smelter at erjav. The monthly accumulation of heavy metals was comparable within years at selected locations. Heavy metal pollution was the highest at erjav despite of remediation of lead and zinc ore smelter. The monthly accumulation of all four heavy metals was statistically significantly higher in lichens exposed at erjav than at other localities.  相似文献   

19.
The results of heavy metal measurements in monthly precipitation samples are analyzed at biological station Dal’nie Zelentsy to define the role of the atmospheric precipitation in the marine environment pollution in the Barents Sea coastal region. Peculiarities of the atmospheric processes and the genesis of air masses bringing the precipitation and the extent of their effect on the precipitation pollution with heavy metals are considered based on the data obtained in 2001–2002. Of the air masses brining the precipitation to the Kola Peninsula coast the air masses of a marine origin have significant advantage. It is shown that weight average heavy metal (except copper) concentrations in the precipitation from the marine air masses on the Kola coast are higher than in the precipitation from the continental air masses. The emissions from local metallurgic enterprises influence the extent of the precipitation pollution with copper.  相似文献   

20.
At four industrial regions, heavy metal concentrations and calculated depositions were investigated by sampling and analysing mosses. In each region, a special spatial pattern of heavy metal concentrations was detected, reflecting the industrial processes. Metals most likely originating from the industrial sites showed an exponential decrease of concentrations and depositions with increasing distance from the pollution source. The exponential deposition pattern was in some cases modified by a series of natural factors, like the main direction of winds or orographic conditions. The distance at which deposition dropped to background values was up to 20 km. Beside the fact that the moss-metho is a useful tool for deposition measurement in the vicinity of stationary sources, some improvements for using this method are discussed, highlighting factors such as a proper calculation of deposition from concentrations, or the better knowledge of correlations between heavy metal concentrations in mosses and effects on human health.  相似文献   

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