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1.
Past changes in phytoplankton assemblages in Lake Baikal over the last 4.5 Ma, both in population and composition, are inferred from the downcore profiles of the relatively stable chlorophyll derivatives steryl esters of pyropheophorbides a and b (steryl chlorine esters; SCEs) in the 0–200 m section of the BDP-98 drill core, supplemented by the data on biogenic silica (BSi) and total organic carbon (TOC) contents. SCEs-a and -b dominate among sedimentary chlorophyll derivatives in the BDP-98 sediments except for the upper few meters, indicating their high stability during diagenetic alteration of sediments. The depth (age) profiles of SCEs-a are consistent with BSi and TOC profiles and are interpreted as reflecting primary productivity of the lake in the past. Baikal proxies reveal close correlation with marine oxygen isotope records (MIS stratigraphy). These observations confirm that climate change in the northern hemisphere has been a primary factor controlling the total phytoplankton productivity in Lake Baikal during the last several million years.Among SCEs-a, C30 (dinostanol)-SCE-a, a marker of dinoflagellates was identified by GC–MS analysis. SCE-b, a marker of green algae, was identified by its UV–vis spectrum. The ratio of C30-SCE-a to total SCEs-a (TSCEs-a) was higher during 4.5–4.2 and 1.7–1.3 Ma, suggesting that dinoflagellates proliferated preferentially in those periods. The early Pleistocene maximum of this ratio corresponds to the broad minimum of diatom abundance previously suggested to have recorded a prolonged regional cooling. An abrupt increase in the SCE-b/TSCEs-a ratio was observed at 2.5–2.6 Ma, indicating that green algae containing chlorophyll b have proliferated in Lake Baikal during this period. This interval has also been suggested to contain evidence for a significant regional cooling based on minima of diatom abundance and BSi in sediments. The depth profile of C27Δ5 (cholesterol)-SCE-a relative to TSCEs-a showed a trend similar to that of BSi, suggesting that C27Δ5-SCE-a/TSCEs-a ratio is a potential marker of diatoms in Lake Baikal.Certain mismatches between the Lake Baikal profiles of biological indicators and the marine oxygen isotope records, as well as the slight temporal offsets between different Lake Baikal biological marker signals suggest that the regional component of climatic and/or lacustrine environmental changes also have played a role in determining the composition of the Lake Baikal Plio-Pleistocene phytoplankton assemblage.  相似文献   

2.
A 3-m sediment core taken from Lake Suigetsu, in which a shift from fresh to brackish water occurred about three hundred years ago, has been examined for variation with depth of organic carbon and fatty acids. From the difference in total amounts of sulphur between sediments under fresh and brackish water environments, the surface sediments above approximately 35 cm depth were deduced to be accumulated under a brackish water environment. The total contents of organic carbon and fatty acids, and percentage composition of fatty acids gave discontinuous profiles above and below the 35–40 cm sediment layer. At a depth of 12.5 cm, the distribution in chain length of the fatty acids changed from a unimodal (the predominance of C12-C18 over C20-C34) to a bimodal pattern, which was mirrored by the composition diversity index (CDI).Although the fatty acids in the surface sediments (0–40 cm) from Lake Suigetsu seemed to suffer milder degradation through microbial activity than those in a core (0–150 cm) from Lake Suwa, a freshwater eutrophic lake, both lacustrine sediments showed similar trends in the alteration of fatty acid composition with depth.  相似文献   

3.
A simple, reliable, and high-performance method has been proposed for direct determination of the isotopic composition of authigenic uranium in silica lacustrine sediments. The method is based on studying the kinetics of the selective extraction of authigenic uranium from sediments with weak solutions of ammonium hydrocarbonate followed by the ICP-MS analysis of the nuclides. To estimate the contamination of authigenic uranium by terrigenous one, the contents of 232Th and some other clastogenic elements in the extracts were measured simultaneously. The selectivity of extraction of authigenic uranium from the sediments treated with a 1% NH4HCO3 solution appeared to be no worse than 99%. The method was used to analyze the isotopic composition of authigenic uranium at several key horizons of a core dated before. The measurements directly prove that the 234U/238U values in Baikal water varied depending on climate, which contradicts the previous statements. The measured 234U/238U ratios in paleo-Baikal water match the values reconstructed from isotopic data for total uranium in the sediments on the supposition that the U/Th ratio is constant in the terrigenous part of the sediment. Direct experimental determination of total and authigenic nuclides in sediments enhances the potentiality of the method for absolute 234U-230Th dating of carbonate-barren lacustrine sediments, including those from Lake Baikal, within the intervals corresponding to the periods of glaciation, where the sediments contain a large fraction of terrigenous component. Given the fractions of terrigenous and authigenic uranium are accurately determined, we have an opportunity to study the variability of the sources of terrigenous matter and to refine the previous model for reconstructing the climate humidity in East Siberia.  相似文献   

4.
Mercury distribution was examined in the sediments of Lake Baikal that were sampled within the scope of the Baikal Drilling International Project in 1996–1999. The Hg concentrations in the ancient sediments are close to those in the modern sediments with the exception of a few peak values, whose ages coincide with those of active volcanism in adjacent areas. Mercury was demonstrated to be contained in the sediments in the adsorbed Hg0 mode, predominantly in relation with organic matter. When the organic matter of the bottom sediments is decomposed in the course of lithification, Hg is retained in the sediments adsorbed on the residual organic matter, and the concentration of this element corresponds to its initial content in the bottom sediments during their accumulation. Mercury concentrations in lithologically distinct bottom sediments of Lake Baikal and its sediments as a whole depend on the climate. Sediments that were formed during warm periods of time contain more Hg than those produced during cold periods or glaciation. Periodical variations in the Hg concentrations in the bottom sediments of Lake Baikal reflect the variations in the contents of this element in the Earth’s atmosphere in the Late Cenozoic, which were, in turn, controlled by the climatic variations on the planet and, thus, can be used for detailed reconstructions of variations in the average global temperature near the planet’s surface.  相似文献   

5.
A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO 3 − are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO2 in the water and the consequent enhancement of Ca2+ and HCO 3 − . The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO 4 3− content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake.  相似文献   

6.
High-time resolution 14C dating of Lake Baikal sediment cores indicates negative and positive anomalies of calculated linear sedimentation rate (LSR; 1.1 and 35.6 cm/ka, respectively) during the period of climate transition from the last glacial to Holocene. The timing of the Lake Baikal apparent LSR anomalies is consistent with that of the changes in the atmospheric radiocarbon concentration (Δ14C) during Younger Dryas rapid cooling event. 14C dating of lipids in the Lake Baikal surface sediments revealed that the sources of sedimentary lipids were different in each basin. In the Northern Basin of Lake Baikal, the 14C age of total lipids from the surface sediment (4.0 14C ka) was found to be older than that of TOC (1.6 14C ka). By contrast, the 14C age of total lipids in the Southern Basin was younger than that of the TOC by ca. 0.7–3.0 ka.In the Lake Hovsgol sediment cores, ages of the main lithologic boundaries during the last glacial–interglacial transition were estimated based on new 14C data sets. TOC concentration in the cores started to rapidly increase at 13.8 ± 0.3 14C ka at the base of the basinwide finely laminated layer deposited during Bølling/Allerød. The base of the layer diatomaceous mud corresponds to the end of Younger Dryas event (10.6 ± 0.1 14C ka).  相似文献   

7.
Carbon isotope ratio (δ13Corg) values of organic matter in lake sediments are commonly used to reconstruct environmental change, but the factors which influence change are varied and complex. Here we report δ13C values for sediments from Erlongwan maar lake in northeast China. In this record, changes in δ13C cannot be explained by simple changes in aquatic productivity. Instead, values were likely influenced by differences in the ratio between planktonic and benthic algae, as indicated by the remains of diatoms. This is because the variation of δ13Corg in algae from different habitats is controlled by the thickness of the diffusive boundary layer, which is dependent on the turbulence of the water. Compared with benthic algae, which grow in relatively still water, pelagic algae are exposed to greater water movement. This is known to dramatically reduce the thickness of the boundary layer and was found to cause even more severe δ13C depletion. In Erlongwan maar lake, low values were linked to the dominance of planktonic diatoms during the period commonly known as the Medieval Warm Period. Values gradually increased with the onset of the Little Ice Age, which we interpret as being driven by an increase in the proportion of benthic taxa, due to effect of the colder climate. The increase in planktonic diatoms at the end of the Little Ice Age, linked to higher temperature and a reduction in ice cover, resulted in a further decline in δ13Corg.  相似文献   

8.
New factual materials on methane eruptions into the water of Lake Baikal in August 1912 are considered. The regional press is used as the information source. The spatio-temporal relationship between the gas eruptions and earthquakes, observed in South Baikal in 1912, is revealed, which permits us to consider this effect as a consequence of seismic activity intensification. Intensive methane discharge into water is a potential danger for the lake’s ecosystem as was proved by massive death of water organisms in South Baikal in 1912 during the described phenomena.  相似文献   

9.
The component and carbon isotope compositions were studied in the hydrocabon gases from sediments of the underwater high Posolskaya Bank (Lake Baikal). It was established that sediments of this Baikal area contain methane of microbial (C1/C2 >16000; δ13C 70 ± 3‰) and thermocatalytic (C1/C2 <100; δ13C–46 ± 3‰) origin. Some samples represent a gas mixture of thermocatalytic and microbial origin. This gas is characterized by δ13C of methane varying from–60 to–70‰ and contains a significant amount of ethane. The main homolog of methane in the thermocatalytic and mixed gas is ethane. Owing to biodegradation, propane and butanes are present in trace amounts.  相似文献   

10.
We present a new palaeoenvironmental record of hydrological variability in Lake Baikal, based on re‐modelled δ18Odiatom values of diatom silica (δ18Omodelled), where the residual contaminants are identified and compensated for using electron optical imaging and whole‐sample geochemistry. δ18Omodelled interpretations are based on the balance between rivers with high δ18O values and rivers with low δ18O values. Isotopic variability is related to latitudinal differences in precipitation which feed these rivers. The δ18Omodelled record suggests that rather moist conditions prevailed in the Lake Baikal region during the latter stages of the Younger Dryas. Throughout the Holocene, episodes of low δ18Omodelled values are, in general, in good agreement with increases in percentage haematite‐stained grains in North Atlantic sediments (indicative of ice‐rafted debris events). Rivers with southerly catchments dominate fluvial input especially between c. 3.3 and 2 cal ka BP, concurrent with high precipitation in the Lake Baikal region. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

11.
We performed a thermomagnetic analysis of 91 samples and a probe microanalysis of five samples of sedimentary rocks from the lower zone of the borehole BDP-98 drilled at the bottom of Lake Baikal. The results show the scarcity of native iron: It was found only in five samples. Its concentration varies from ～10–5 to 7 × 10–4%. The distribution of native iron by content is bimodal, with a distinct “zero” mode. This scarcity of native iron in the Baikal sediments distinguishes them from continental (Eurasia) and oceanic (Atlantic) sediments of different ages. It is due to the high rate of sedimentation in the studied interval of BDP-98.  相似文献   

12.
This is a summary of new oxygen isotope record of diatoms from Lake Kotokel sediments, with implications for responses of the lake system and its environment to global change over the past 46 kyr. Fossil diatoms in all samples are free from visible contamination signatures and contain no more than 2.5% Al2O3, which ensures reliable reconstructions. The 518O values in diatoms vary between + 23.7 and + 31.2%c over the record. The results present mainly diatom assemblages of summer blooming periods, except for the time span between 36 and 32 kyr, when the isotopic signal records mainly a shift from summer to spring blooming conditions. Possible water temperature changes only partly explain the changes in the isotopic record. The observed isotopic patterns are produced mainly by isotope changes in lake water in response to variations in air temperature, hydrology, and atmospheric circulation in the region. During Marine Isotope Stage (MIS) 2 (Last Glacial maximum), high 518Odiatom resulted from rapid evaporation and low fluvial inputs. The high 518Odiatom values of about + 29 to + 30%c during the first half of MIS 1 (Holocene interglacial) suggest an increased share of summer rainfalls associated with southern/southeastern air transport. The 518Odiatom decrease to + 24%c during the second half of MIS 1 is due to the overall hemispheric cooling and increased moisture supply to the area by the Atlantic air masses. The record of Lake Kotokel sediments provides an example of complex interplay among several climatic/environmental controls of 518Odiatom during the Late Pleistocene and the Holocene.  相似文献   

13.
Interstitial water samples and sediments were collected from acidified Woods Lake (pH= 5.0) to evaluate Pb profile stability and distribution between the solid and aqueous phases. A simple equation was developed to describe the distribution coefficient for Pb(KdPb), based on the sample moisture content and analyte concentrations in bulk sediment and pore water. In Woods Lake sediment KdPb values ranged from 6.7 × 104to6.7 × 105ml/g. The affinity of Pb for the solid phase was further demonstrated by inverting a sediment core and leaving it for 10 months in situ. Upon retrieval, the Pb profile was found to have remained intact over the same depth, albeit inverted, as in the surrounding sediment. Geochemical modeling using MINTEQA2 demonstrates that Pb solids that may reasonably be expected to precipitate were all undersaturated by several orders of magnitude with respect to the interstitial water, indicating that Pb was sorbed to, rather than precipitated in, Woods Lake sediment.  相似文献   

14.
Crystallization of authigenic carbonates in mud volcanoes at Lake Baikal   总被引：1，自引：0，他引：1  
This paper presents data on authigenic siderite first found in surface sediments from mud volcanoes in the Central (K-2) and Southern (Malen’kii) basins of Lake Baikal. Ca is the predominant cation, which substitutes Fe in the crystalline lattice of siderite. The enrichment of the carbonates in the 13C isotope (from +3.3 to +6.8‰ for the Malen’kii volcano and from +17.7 to +21.9‰ for K-2) results from the crystallization of the carbonates during methane generation via the bacterial destruction of organic matter (acetate). The overall depletion of the carbonates in 18O is mainly inherited from the isotopic composition of Baikal water.  相似文献   

15.
The biomarker composition and stable isotope (C, O) ratio values of organic matter (OM) and carbonate from sediment cores from the oligotrophic Lake Brienz and the eutrophic Lake Lugano (both in Switzerland) are compared, in order to obtain information about OM sources and transformation processes. Eutrophic conditions at Lake Lugano are reflected in elevated total organic carbon (TOC) content and hydrogen index (HI) values, as well as higher lipid concentrations. Parallel down core trends in δ13C values of TOC and calcite in the Lake Lugano sediments reflect bioproductivity cycles. Variations in δ18O values of calcite are consistent with changes in mean summer temperature over the time interval covered by the core. In contrast, such a correlation does not exist for Lake Brienz and there the stable isotope composition of calcite reflects its allochthonous origin. In the sediments of both lakes, fatty acid (FA) distributions and the composition of n-alkanols and n-alkanes indicate highly variable proportions of autochthonous OM sources (algae, zooplankton, bacteria) and OM from land plants. Enhanced in situ microbial synthesis during sediment deposition in Lake Lugano is suggested by the higher TOC-normalised concentrations of branched chain FAs (C15–C17), hopanoic acids and triterpenoid alcohols (i.e. tetrahymanol, diplopterol). Variations in the concentrations of cholesterol are related to contributions from zooplankton and/or green algae, while sitosterol concentrations reflect the input of vascular plants. Periods of increased input of OM from diatoms are evidenced by high 24-methylcholesta-5,22-dien-3β-ol (either epibrassicasterol or brassicasterol) and/or highly branched isoprenoid (HBI) alkenes concentrations. High relative concentrations of diplopterol in Lake Lugano sediments are consistent with the predominance of cyanobacteria commonly observed in eutrophic lakes. The presence of archeol and hydroxyarcheol in very low concentrations in the Lugano sediments argues for the activity of methanogens and/or anaerobic methanotrophs.Differences in OM degradation processes are reflected in higher chlorin index values in the Brienz sediments but higher saturated vs. unsaturated n-FAs in the core from Lugano. Higher concentrations of branched chain FAs and 16:1ω7 n-FA, as well as enhanced 18:1ω7/18:1ω9 n-FA, are consistent with enhanced bacterial biomass in the Lugano water column or sediments. The preservation of phytol seems to be enhanced in sediments with a high relative contribution of land plant OM. Major factors affecting OM accumulation in the lakes are differences in OM sources (i.e. terrestrial OM vs. autochthonous production), extent of bacterial activity and most likely oxygen availability in the water column.  相似文献   

16.
Modeling the bulk sediment XRD patterns allows insight into the environmental and depositional histories of two neighboring rift lake basins within the Baikal watershed. Parallel 14C-dated LGM-Holocene records in Lakes Baikal and Hovsgol are used to discuss the mineralogical signatures of regional climate change. In both basins, it is possible to distinguish ‘glacial’ and ‘interglacial’ mineral associations. Clay minerals comprise in excess of 50% of layered silicates in bulk sediment.The abundance of smectite (expandable) layers in mixed-layer illite–smectites and the total illite abundance are the main paleoclimatic indices in the clay mineral assemblage. Both indices exhibit coherent responses to the Bølling–Allerød and the Younger Dryas. The smectite layer index is not equivalent to the abundance of illite–smectite, because illite–smectite tends to transform into illite. Repeated wetting–drying cycles in soils and high abundance of expandable layers in illite–smectites (>42%) favor the process of illitization. This relationship is clearly shown in both Baikal and Hovsgol records for the first time. The opposite late Holocene trends in illite abundance in Lake Baikal and Lake Hovsgol records suggest that a sensitive optimal regime may exist for illite formation in the Baikal watershed with regard to warmth and effective moisture.The Lake Hovsgol sediments of the last glacial contain carbonates, suggesting a positive trend in the lake's water budget. A progressive change towards lower Mg content in carbonates indicates lowering mineralization of lake waters. This trend is consistent with the lithologic evidence for lake-level rise in the Hovsgol basin.The pattern of mineralogical changes during the past 20 ka is used to interpret bulk sediment and carbonate mineralogy of the long 81-m Lake Hovsgol drill core (HDP-04) with a basal age of 1 Ma. The interglacial-type silicate mineral associations are confined to several thin intervals; most of the sediment record is calcareous. Carbonates are represented by six main mineral phases: calcite, low-Mg calcite, intermediate/high-Mg calcite, dolomite, excess-Ca dolomite and metastable monohydrocalcite. These mineral phases tend to form stratigraphic successions indicative of progressive changes in lake water chemistry. Five sediment layers with abundant Mg-calcites in the HDP-04 section suggest deposition in a low standing lake with high mineralization (salinity) and high Mg/Ca ratios of lake waters. Lake Hovsgol sediments contain the oldest known monohydrocalcite, found tens of meters below lake bottom in sediments as old as 800 ka. This unusual find is likely due to the conditions favorable to preservation of this metastable carbonate.  相似文献   

17.
贵州红枫湖沉积物有机质的酶及微生物降解   总被引：8，自引：1，他引：8  
文章通过DNA、α-葡萄糖苷酶和硫酸盐还原菌等的变化,研究了贵州红枫湖沉积物中有机质的酶及微生物降解.有机质在微生物及其分泌的胞外酶的作用下被降解,在沉积物深度11cm以下被降解到相对较低的含量.DNA的分布表明表层9cm的沉积物深度内微生物的活动较为强烈,是微生物降解有机质的主要位置.α-葡萄糖苷酶在悬浮层含量最高,达0.75μmol/min*g干沉积物,提示有机质中的淀粉和糖原等物质在悬浮层降解较为激烈,被大量分解;随着沉积物深度的增加α-葡萄糖苷酶活性减弱,在有机质降解明显开始变缓的11cm沉积物中,α-葡萄糖苷酶活性已降低到0.17μmol/ming干沉积物.分子生物学的研究表明红枫湖沉积物表层7cm是硫酸盐还原菌的主要分布位置,结合有机质和SO2-4含量的研究结果,提示红枫湖沉积物中SO2-4不可能成为有机质氧化的主要电子受体,硫酸盐还原的限制因素也不是有机质供应.  相似文献   

18.
Saline, 450-m-deep Lake Van (Eastern Anatolia, Turkey) is, with 576 km3, the third largest closed lake on Earth and its largest soda lake. In 1989 and 1990, we investigated the hydrochemistry of the lake’s water column and of the tributary rivers. We also cored the Postglacial sediment column at various water depths. The sediment is varved throughout, allowing precise dating back to ca. 15 ka BP. Furthermore, lake terrace sediments provided a 606-year-long floating chronology of the Glacial high-stand of the lake dating to 21 cal. ka BP. The sediments were investigated for their general mineralogical composition, important geochemical parameters, and pore water chemistry as well. These data allow reconstructing the history of the lake level that has seen several regressions and transgressions since the high-stand at the end of the Last Glacial Maximum. Today, the lake is very alkaline, highly supersaturated with Ca-carbonate and has a salt content of about 22 g kg?1. In summer, the warmer epilimnion is diluted with river water and forms a stable surface layer. Depth of winter mixing differs from year to year but during time of investigation the lake was oxygenated down to its bottom. In general, the lake is characterized by an Na–CO3–Cl–(SO4)-chemistry that evolved from the continuous loss of calcium as carbonate and magnesium in the form of Mg-silica-rich mineral phases. The Mg cycle is closely related to that of silica which in turn is governed by the production and dissolution of diatoms as the dominant phytoplankton species in Lake Van. In addition to Ca and Mg, a mass balance approach based on the recent lake chemistry and river influx suggests a fractional loss of potassium, sodium, sulfur, and carbon in comparison to chloride in the compositional history of Lake Van. Within the last 3 ka, minor lake level changes seem to control the frequency of deep water renewal, the depth of stratification, and the redox state of the hypolimnion. Former major regressions are marked by Mg-carbonate occurrences in the otherwise Ca-carbonate dominated sediment record. Pore water data suggest that, subsequent to the major regression culminating at 10.7 ka BP, a brine layer formed in the deep basin that existed for about 7 ka. Final overturn of the lake, triggered by the last major regression starting at about 3.5 ka BP, may partly account for the relative depletion in sulfur and carbon due to rapid loss of accumulated gases. An even stronger desiccation phase is proposed for the time span between about 20 and 15 ka BP following the LGM, during which major salts could have been lost by precipitation of Na-carbonates and Na-sulfates.  相似文献   

19.
Eutrophication of lakes and reservoirs has become a worldwide environmental problem, and nitrogen (N) has been recognized as one of the key factors responsible for eutrophication. Nitrogen adsorbed on sediments may be released via chemical and biological processes under changing environmental conditions. Spatial distributions of concentrations of ammonia nitrogen (NH4 +–N), nitrate nitrogen (NO3 ?–N) and total nitrogen (TN) were investigated in sediments and overlying water of Dongting Lake, the second largest freshwater lake in China. The concentration of TN in the sediments exhibited strong spatial variation with relatively high values in the eastern part and relatively low values in the southern part of the lake. The TN concentration in the water of different regions of Dongting Lake was affected by the internal load of sediment N. The vertical distribution of TN in sediment cores showed a decreasing trend with an increase in depth. Concentrations of NH4 +–N in the sediment cores decreased with the depth increase until 6–8 cm and then increased slowly. However, concentrations of NO3 ?–N in the sediment cores showed an opposite trend from those of NH4 +–N. A kinetic release experiment of NH4 +–N showed that the maximum release rate occurred in the first 5 min and the amount of NH4 +–N release reached 77.93–86.34 % of the total amount in 0–10 min. The release of NH4 +–N in the surface sediments of Dongting Lake fits a first-order kinetics function.  相似文献   

20.
Biomarker compositions of particulate organic matter (POM) from the oligotrophic Lake Brienz and the eutrophic Lake Lugano (both Switzerland) are compared, in order to obtain information about organic matter (OM) production and transformation processes in relation to water column stratification. Eutrophic conditions in Lake Lugano are reflected by enhanced alkalinity, elevated total organic carbon (TOC) and chlorin contents compared with Lake Brienz. Lower δ13C values of dissolved inorganic carbon (DIC) in Lake Lugano reflect enhanced OM respiration in the water column.Differences in OM dynamics between both lakes, as well as seasonal variations, are evidenced by TOC-normalised concentration profiles of total fatty acids (FAs) and total neutrals. In Lake Brienz, the results reflect the relative contributions of primary productivity and refractory, allochthonous OM to POM, governed by particle load and interflows due to density stratification. The depth trends at Lake Lugano are a result of high primary productivity, water column stratification and associated particle load in the upper layers, as well as microbially induced degradation close to the chemocline and greater preservation under anoxic conditions. Minor differences exist with regard to the OM composition. In both lakes, FA distributions and the composition of n-alkanols indicate a predominant autochthonous OM source (algae, zooplankton, bacteria). Inputs of OM from diatoms are reflected in highly-branched isoprenoid (HBI) alkenes, 16:1 n-FAs and 24-methylcholesta-5,22-dien-3β-ol (either epibrassicasterol or brassicasterol). Differences in relative proportions of n-C16 vs. n-C18 FAs and alkanols, respectively, as well as in the percentages of C27, C28 and C29 sterols relative to the sum of sterols are related to differences in the abundances of chrysophytes, diatoms and green algae within the euphotic zone of both lakes as well as in bacterial activity and soil in-wash. High relative proportions of cholesterol in the autumn samples, most pronounced at Lake Lugano, were attributed to an increased input from zooplankton grazing in the water column.Differences in OM degradation processes are reflected in slightly higher chlorin index values and higher relative proportions of saturated vs. unsaturated n-FAs in Lake Lugano. Higher contents of branched chain FAs, 16:1ω7 n-FA, and enhanced 18:1ω7/18:1ω9 n-FA ratios suggest enhanced bacterial biomass in the water column of Lake Lugano close to the chemocline. Increasing proportions of saturated n-FAs and n-alkanols with increasing water depth, most distinct in the autumn for both lakes, argue for intensified bacterial activity and degradation of OM during autumn. High relative contents of sterols and low n-alkanol concentrations in POM close to the chemocline at Lake Lugano during spring are interpreted to reflect higher primary productivity in the photic zone, OM export to the deeper parts and enhanced degradation rates of more labile constituents (i.e. C13–C20 n-alkanols), as compared to Lake Brienz.  相似文献   

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