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1.
We investigate the growth of the northern Tibetan Plateau and associated climate change by applying oxygen and carbon isotopic compositions in Cenozoic strata in the southwestern Qaidam basin. The X-ray diffraction and isotopic studies reveal that the carbonate minerals are mainly authigenic and they do not preserve any evidence for detrital carbonate and diagenesis. The isotope data show large fluctuations in the δ18O and δ13C values in the middle–late Eocene, indicating relatively warm and seasonal dry climate. The positive correlation of the δ18O and δ13C values in the Oligocene and the positive shift of the δ13C values from the Eocene to Oligocene suggest that the climate changed to arid in the Oligocene. However, the δ18O values show negative shift, which is closely related to the global cooling event. During the Miocene, the δ13C values vary between –2‰ and –4‰, whereas the δ18O values show continuous negative shift. The mean δ18O values decrease from –8.5‰ in the early Miocene to –10.0‰ in the late Miocene. The stable isotope-based paleoaltimetry results suggest that the elevation of the southwestern Qaidam basin was approximately 1500 m in the middle–late Eocene and Oligocene. Subsequently, during Miocene the crustal uplift process started and the elevation reached approximately 2000 m in the early Miocene and 2500 m in the late Miocene, which suggests large-scale growth of the northern Tibet Plateau during the Miocene.  相似文献   

2.
The regional geologic setting of the Adycha-Taryn metallogenic zone, one of the areas most productive for noble-metal mineralization in northeastern Russia, is discussed. The intricate metallogenic history of the zone and the prolonged geodynamic activity of its ore-hosting structures are documented. Different types of mineralization, such as hydrothermal-metamorphogenic, gold-bismuth, gold-quartz, gold-antimony, and silver-antimony, are described. New data on the isotopic compositions of oxygen in quartz, sulfur in sulfides, and oxygen and carbon in carbonates from different mineralization types are presented. The early metamorphogenic quartz beyond the ore zones has δ18O = + 20.1 ± 2.0‰. At the gold-bismuth deposits, the δ18O values of quartz are within the narrow range of + 12.5 ± 0.4‰. Quartz from the gold-quartz mineralization shows much wider variation in δ18O values, from + 14.2 to + 19.5‰. A similar range (δ18O = + 16.1 to + 19.2‰) is observed for the gold-antimony mineralization. Cryptograined quartz from the silver-antimony mineralization is enriched in light oxygen isotopes (δ18O = -3.2 to + 4.7‰). The following δ34S values (‰) have been established in sulfides of mineralization of different types: gold-bismuth -3.7 to -2.2 (Apy) and -6.7 to -6.8 (Py); gold-quartz -2.1 to + 2.4 (Apy), -6.6 to + 5.4 (Py), and -6.1 to + 4.2 (St); gold-antimony -2.0 to + 1.6 (Apy), -3.5 to + 2.1 (Py), and -5.3 to + 0.2 (St); and silver-antimony -2.0 to -1.9 (Apy), -2.2 ± 0.1 (Py), and -5.7 to -5.6 (St). The δ13C and δ18O values are contrasting in the studied types of mineralization, varying respectively from -6.9 to -5.9‰ and from + 2.1 to + 5.7‰ (gold-bismuth), from -9.1 to -6.1‰ and from + 12.4 to 18.7‰ (gold-quartz), from -12.1 to -9.5‰ and from + 15.0 to + 16.3‰ (gold-antimony), from -11.6 to -11.1‰ and from + 1.5 to + 4.7‰ (silver-antimony). Metamorphogenic calcites are rich in both heavy C (-1.1 to -1.7‰) and heavy O (+ 20.3 to + 20.5‰) isotopes. Microthermometric study and crush-leach analysis of fluid inclusions have revealed differences in the composition of ore-forming fluids and formation conditions for different types of mineralization. The isotopic compositions of O, C, and S of mineral-forming fluids suggest a significant input of magmatic fluids to the formation of gold-bismuth and gold-antimony deposits, the contribution of metamorphic fluids increases at gold-quartz deposits, and meteoric water is involved in the formation of silver-antimony deposits.  相似文献   

3.
The fluid composition, δD of channel H2O, and δ18O of lattice oxygen have been determined in beryl and emerald from a variety of geological environments and used to constrain the origin of the parental fluids from which beryl has grown. Step-heating analyses performed by quadrupolar mass spectrometry were used to quantify the composition of the fluid phases in beryl from granitic pegmatites and greisens and emerald from Brazil, Colombia, and Afghanistan. An important conclusion is that beryl and emerald have a similar fluid composition, with concentrations of H2O being greater than 90% of the total water in the mineral irrespective of the age of formation (2.0 Ga to 32 Ma) and tectonic settings. However, the Brazilian Santa Terezinha shear-zone emerald deposit contains abundant CO2, up to 13 wt% of the total fluid. A second conclusion is that the channel H2O content for some Brazilian emeralds is higher than the range defined for beryl in the literature, especially for those related to the shear-zone type (2.99 lt; H2O < 3.16 wt%) and the pegmatite type from the Pombos, Pela Ema, and Pirenopolis deposits (2.78 < H2O < 3.01 wt%). Colombian emeralds have very low H2O contents (1.30 < H2O < 1.96 wt%), among the lowest in the world.

Brazilian, Colombian, and Afghanistani emeralds have contrasting and restricted ranges of δ18O values. In Brazil, emeralds related to pegmatites have a systematic δ18O inter-deposit variability (+6.3 < δ18O < +12.4‰). The calculated δ18O of the fluid was buffered by the host ultrabasic rocks during fluid-rock interaction. Emerald and cogenetic phlogopite related to shear-zone-type deposits have a quite restricted δ18O range (+12.0 < δ18O 7lt; +12.4‰); the calculated is interpreted to represent the original isotopic composition of the hydrothermal fluid. Relative to Brazil, the δ18O of Colombian and Afghanistani emeralds shows strong enrichment in 18O (+13.4 < δ18O < +23.6‰), and the high calculated δ18O of the fluid suggests extensive reaction with 18O-rich sedimentary or metasedimentary rocks.

In Brazil, the δD composition of channels in emerald and the calculated δ18OH2O for phlogopite are compatible with both magmatic and metamorphic origins. A magmatic origin is supported for emeralds associated with the pegmatitic Socotó and Carnaiba deposits (mean δD = ?37.8 ± 8‰) and a metamorphic origin is suggested for the Santa Terezinha shear-zone type (mean δD = ?32.4 ± 3‰). A metamorphic origin is proposed for Colombian emeralds. Afghanistani emeralds have a δD composition of channels (mean δD = ?46.3 ± 1.3‰) that is compatible with both magmatic and metamorphic origins.  相似文献   

4.
The Panzhihua intrusion in southwest China is part of the Emeishan Large Igneous Province and host of a large Fe-Ti-V ore deposit.During emplacement of the main intrusion,multiple generations of mafic dykes invaded carbonate wall rocks,producing a large contact aureole.We measured the oxygen-isotope composition of the intrusions,their constituent minerals,and samples of the country rock.Magnetite and plagioclase from Panzhihua intrusion haveδ18O values that are consistent with magmatic equilibrium, and formed from magmas withδ18O values that were 1-2‰higher than expected in a mantle-derived magma.The unmetamorphosed country rock has highδ18O values,ranging from 13.2‰（sandstone） to 24.6-28.6‰（dolomite）.The skarns and marbles from the aureole have lowerδ18O andδ13C values than their protolith suggesting interaction with fluids that were in exchange equilibrium with the adjacent mafic magmas and especially the numerous mafic dykes that intruded the aureole.This would explain the alteration ofδ18O of the dykes which have significantly higher values than expected for a mantle-derived magma.Depending on the exactδ18O values assumed for the magma and contaminant, the amount of assimilation required to produce the elevatedδ18O value of the Panzhihua intrusion was between 8 and 13.7 wt.%,assuming simple mixing.The exact mechanism of contamination is unclear but may involve a combination of assimilation of bulk country rock,mixing with a melt of the country rock and exchange with CO2-rich fluid derived from decarbonation of the marls and dolomites.These mechanisms,particularly the latter,were probably involved in the formation of the Fe-Ti-V ores.  相似文献   

5.
This study was conducted on recent desert samples—including (1) soils, (2) plants, (3) the shell, and (4) organic matter from modern specimens of the land snail Eremina desertorum—which were collected at several altitudes (316–360 m above sea level) from a site in the New Cairo Petrified Forest. The soils and shellE. desertorum were analyzed for carbonate composition and isotopic composition (δ18O, δ13C). The plants and organic matterE. desertorum were analyzed for organic carbon content and δ13C. The soil carbonate, consisting of calcite plus minor dolomite, has δ18O values from −3.19 to −1.78‰ and δ13C values −1.79 to −0.27‰; covariance between the two values accords with arid climatic conditions. The local plants include C3 and C4 types, with the latter being dominant. Each type has distinctive bulk organic carbon δ13C values: −26.51 to −25.36‰ for C3-type, and −13.74 to −12.43‰ for C4-type plants.The carbonate of the shellE. desertorum is composed of aragonite plus minor calcite, with relatively homogenous isotopic compositions (δ18Omean = −0.28 ± 0.22‰; δ13Cmean = −4.46 ± 0.58‰). Most of the δ18O values (based on a model for oxygen isotope fractionation in an aragonite-water system) are consistent with evaporated water signatures. The organic matterE. desertorum varies only slightly in bulk organic carbon δ13C values (−21.78 ± 1.20‰) and these values suggest that the snail consumed more of C3-type than C4-type plants. The overall offset in δ13C values (−17.32‰) observed between shellE. desertorum carbonate and organic matterE. desertorum exceeds the value expected for vegetation input, and implies that 30% of carbon in the shellE. desertorum carbonate comes from the consumption of limestone material.  相似文献   

6.
Serpentinites are widespread in the Arabian-Nubian Shield (ANS) of the Eastern Desert of Egypt and usually enclose a tremendous carbonate alteration. Combined investigation of the stable isotope compositions of both O-H in serpentines and O-C in the whole-rock and the chemistry of the fluid-mobile elements (FMEs) in whole-rock serpentinites from Wadi (W.) Alam, Gabal (G.) El-Maiyit, and W. Atalla (Eastern Desert of Egypt) allowed to better understand the subsequent fluid sources of serpentinization and carbonation, as well as impact of these processes on the geochemistry of protolith ultramafic rocks. δ 18O values of W. Alam and W. Atalla serpentine minerals are close to the unaltered mantle and propose a lower temperature serpentinization if compared with those of G. El-Maiyit rocks. Moreover, δD values of W. Alam and W. Atalla serpentines (? 94 to ? 65‰) correspond to an igneous source that might be hydrothermal solutions mixed with the seawater in the mid-ocean ridge-arc transition setting. On the other hand, G. El-Maiyit serpentine is more depleted in 18O (with lower δ 18O values = 4.08–4.85‰), and its δD values (? 73 to 56 ‰) are most probably caused by an interaction with metamorphic fluids, acquired during on-land emplacement of oceanic peridotites or during burial in fore-arc setting. In addition, the oceanic oxygen isotope composition of most studied ophiolitic serpentinites points to the preservation of the pre-obduction δ 18O signatures and thus local-scale fluid flow at low water/rock ratios. Serpentinization fluids were CO2-poor and the carbonation of the serpentinites resulted from infiltration of externally derived fluids. δ 18OVSMOW values of carbonates in the studied serpentinites vary between heavier oxygen isotope composition in G. El-Maiyit samples (av. = 25.32‰) to lighter composition in W. Alam samples (av. = 19.43‰). However, δ 13C values of all serpentinites point mantle source of carbon. This source might have been evolved in mid-ocean ridge (W. Atalla) and subduction zone (W. Alam and G. El-Maiyit) settings. The studied serpentinites are usually enriched in FMEs, particularly Pb, Sr, Cs, and U. These enrichments were most probably the result of serpentinization and/or carbonation.  相似文献   

7.
Using the clumped isotope method, the temperature of dolomite and calcite formation and the oxygen isotopic composition (δ18Ow) of the diagenetic fluids have been determined in a core taken from the Arab‐D of the Ghawar field, the largest oil reservoir in the world. These analyses show that while the dolomites and limestones throughout the major zones of the reservoir recrystallized at temperatures between ca 80°C and 100°C, the carbonates near the top of the reservoir formed at significantly lower temperatures (20 to 30°C). Although the δ18O values of the diagenetic fluids show large variations ranging from ca <0‰ to ca +8‰, the variations exhibit consistent downhole changes, with the highest values being associated with the portion of the reservoir with the highest permeability and porosity. Within the limestones, dolomites and dolomites associated with the zone of high permeability, there are statistically significant different trends between the δ18Ow values and recrystallization temperature. These relationships have different intercepts suggesting that fluids with varying δ18Ow values were involved in the formation of dolomite and limestone compared to the formation of dolomite associated with the zone of high permeability. These new data obtained using the clumped isotope technique show how dolomitization and recrystallization by deep‐seated brines with elevated δ18Ow values influence the δ18O values of carbonates, possibly leading to erroneous interpretations unless temperatures can be adequately constrained.  相似文献   

8.
The oxygen isotope compositions of diagenetic carbonate minerals from the Lower Jurassic Inmar Formation, southern Israel, have been used to identify porewater types during diagenesis. Changes in porewater composition can be related to major geological events within southern Israel. In particular, saline brines played an important role in late (Pliocene-Pleistocene) dolomitization of these rocks. Diagenetic carbonates included early siderite (δ18OSMOW=+24.4 to +26.5‰δ13CPDB=?1.1 to +0.8‰), late dolomite, ferroan dolomite and ankerite (δ18OSMOW=+18.4 to +25.8‰; δ13CPDB=?2.1 to +0.2‰), and calcite (δ18OSMOW=+21.3 to +32.6‰; δ13CPDB=?4.2 to + 3.2‰). The petrographic and isotopic results suggest that siderite formed early in the diagenetic history at shallow depths. The dolomitic phases formed at greater depths late in diagenesis. Crystallization of secondary calcite spans early to late diagenesis, consistent with its large range in isotopic values. A strong negative correlation exists between burial depth (temperature) and the oxygen isotopic compositions of the dolomitic cements. In addition, the δ18O values of the dolomitic phases in the northern Negev and Judea Mountains are in isotopic equilibrium with present formation waters. This behaviour suggests that formation of secondary dolomite post-dates the tectonic activity responsible for the present relief of southern Israel (Upper Miocene to Pliocene) and that the dolomite crystallized from present formation waters. Such is not the case in the Central Negev. In that locality, present formation waters have much lower salinities and δ18O values, indicating invasion of freshwater, and are out of isotopic equilibrium with secondary dolomite. Recharge of the Inmar Formation by meteoric water in the Central Negev occurred in the Pleistocene, and halted formation of dolomite.  相似文献   

9.
Carbonate concretions in the Lower Carboniferous Caton Shale Formation contain diagenetic pyrite, calcite and barite in the concretion matrix or in different generations of septarian fissures. Pyrite was formed by sulphate reduction throughout the sediment before concretionary growth, then continued to form mainly in the concretion centres. The septarian calcites show a continuous isotopic trend from δ13C=?28·7‰ PDB and δ18O=?1·6‰ PDB through to δ13C=?6·9‰ PDB and δ18O=?14·6‰ PDB. This trend arises from (1) a carbonate source initially from sulphate reduction, to which was added increasing contributions of methanogenic carbonate; and (2) burial/temperature effects or the addition of isotopically light oxygen from meteoric water. The concretionary matrix carbonates must have at least partially predated the earliest septarian cements, and thus used the same carbonate sources. Consequently, their isotopic composition (δ13C=?12·0 to ?10·1‰ PDB and δ18O=?5·7 to ?5·6‰ PDB) can only result from mixing a carbonate cement derived from sulphate reduction with cements containing increasing proportions of carbonate from methanogenesis and, directly or indirectly, also from skeletal carbonate. Concretionary growth was therefore pervasive, with cements being added progressively throughout the concretion body during growth. The concretions contain barite in the concretion matrix and in septarian fissures. Barite in the earlier matrix phase has an isotopic composition (δ34S=+24·8‰ CDT and δ18O=+16·4‰ SMOW), indicating formation from near‐surface, sulphate‐depleted porewaters. Barites in the later septarian phase have unusual isotopic compositions (δ34S=+6 to +11‰ CDT and δ18O=+8 to +11‰ SMOW), which require the late addition of isotopically light sulphate to the porewaters, either from anoxic sulphide oxidation (using ferric iron) or from sulphate dissolved in meteoric water. Carbon isotope and biomarker data indicate that oil trapped within septarian fissures was derived from the maturation of kerogen in the enclosing sediments.  相似文献   

10.
Upper Visean limestones in the Campine Basin of northern Belgium are intensively fractured. The largest and most common fractures are cemented by non-ferroan, dull brown-orange luminescent blocky calcite. First melting temperatures of fluid inclusions in these calcites are around -57°C, suggesting that precipitation of the cements occurred from NaCl-CaCl2-MgCl2 fluids. The final melting temperatures (Tmice) are between -5 and -33°C. The broad range in the Tmice data can be explained by the mixing of high salinity fluids with meteoric waters, but other hypotheses may also be valid. Homogenization temperatures from blocky calcite cements in the shelf limestones are interpreted to have formed between 45 and 75°C. In carbonates which were deposited close to and at the shelf margin, precipitation temperatures were possibly in the range 70-85°C and 72-93°C, respectively. On the shelf, the calcites have a δ18O around -9.3‰ PDB and they are interpreted to have grown in a fluid with a δ18O between −3.5 and +1.0‰ SMOW. At the shelf margin, blocky calcites (δ18O∼ - 13.5‰ PDB) could have precipitated from a fluid with a δ18O betweenn -4.0 and -1.1‰ SMOW. The highest oxygen isotopic compositions are comparable to those of Late Carboniferous marine fluids (δ18O= - 1‰ SMOW). The lowest values are more positive than a previously reported composition for Carboniferous meteoric waters (δ18O= -7‰ SMOW). Precipitation is likely to have occurred in marine-derived fluids, which mixed with meteoric waters sourced from near the Brabant Massif. Fluids with a similar negative oxygen isotopic composition and high salinity are actually present in Palaeozoic formations. The higher temperature range in the limestones near the shelf margin is explained by the upward migration of fluids from the ‘basinal’ area along fractures and faults into the shelf.  相似文献   

11.
Carbonatites host some of the largest and highest grade rare earth element (REE) deposits but the composition and source of their REE-mineralising fluids remains enigmatic. Using C, O and 87Sr/86Sr isotope data together with major and trace element compositions for the REE-rich Kangankunde carbonatite (Malawi), we show that the commonly observed, dark brown, Fe-rich carbonatite that hosts REE minerals in many carbonatites is decoupled from the REE mineral assemblage. REE-rich ferroan dolomite carbonatites, containing 8–15 wt% REE2O3, comprise assemblages of monazite-(Ce), strontianite and baryte forming hexagonal pseudomorphs after probable burbankite. The 87Sr/86Sr values (0.70302–0.70307) affirm a carbonatitic origin for these pseudomorph-forming fluids. Carbon and oxygen isotope ratios of strontianite, representing the REE mineral assemblage, indicate equilibrium between these assemblages and a carbonatite-derived, deuteric fluid between 250 and 400 °C (δ18O + 3 to + 5‰VSMOW and δ13C ? 3.5 to ? 3.2‰VPDB). In contrast, dolomite in the same samples has similar δ13C values but much higher δ18O, corresponding to increasing degrees of exchange with low-temperature fluids (< 125 °C), causing exsolution of Fe oxides resulting in the dark colour of these rocks. REE-rich quartz rocks, which occur outside of the intrusion, have similar δ18O and 87Sr/86Sr to those of the main complex, indicating both are carbonatite-derived and, locally, REE mineralisation can extend up to 1.5 km away from the intrusion. Early, REE-poor apatite-bearing dolomite carbonatite (beforsite: δ18O + 7.7 to + 10.3‰ and δ13C ?5.2 to ?6.0‰; 87Sr/86Sr 0.70296–0.70298) is not directly linked with the REE mineralisation.  相似文献   

12.
The Pongkor gold–silver deposit is the largest low‐sulfidation epithermal precious metal deposit in Indonesia, and is of Pliocene age. The deposit consists of nine major subparallel quartz–adularia–carbonate veins with very low sulfide content. Vein infill records five paragenetic sequences, dominated by calcite in the early stage and quartz in the later stage of the hydrothermal evolution. Fluid inclusions in hydrothermal calcite and quartz of all stages indicate a temperature ranging from 180 to 220°C and a meteoric water origin (very low salinity close to 0 wt% NaCl equivalent). Carbon isotope data on calcite display a narrow range from ?6.5 to ?3.0‰δ13C. The oxygen isotope values have a wider range of +4.6 to +10.1‰δ18O. The broadly positive correlation of the δ13C versus δ18O plot suggests that the carbon species, which equilibrated during the formation of calcite, is dominated by H2CO3 not far from equilibrium with HCO3?. The abundance of rare earth and yttrium (REY) in carbonate samples is very low (>REY mostly <2 ppm). However, there is always a positive Eu anomaly, which indicates a deeper fluid reservoir at >250°C.  相似文献   

13.
Few global syntheses of oxygen and carbon isotope composition of pedogenic carbonates have been attempted,unlike marine carbonates.Pedogenic carbonates represent in-situ indicators of the climate conditions prevailing on land.The δ~(18)O and δ~(13)C values of pedogenic carbonates are controlled by local and global factors,many of them not affecting the marine carbonates largely used to probe global climate changes.We compile pedogenic oxygen and carbon isotopic data(N= 12,167) from Cretaceous to Quaternary-aged paleosols to identify potential trends through time and tie them to possible controlling factors.While discrete events such as the PaleoceneEocene Thermal Maximum are clearly evidenced,our analysis reveals an increasing complexity in the distribution of the δ~(18)O vs δ~(13)C values through the Cenozoic.As could be expected,the rise of C_4 plants induces a shift towards higher δ~(13)C values during the Neogene and Quaternary.We also show that the increase in global hypsometry during the Neogene plays a major role in controlling the δ~(18)O and δ~(13)C values of pedogenic carbonates by increasing aridity downwind of orographic barriers.Finally,during the Quaternary,an increase of 3‰ inδ~(18)O values is recorded both by the pedogenic carbonates and the marine foraminifera suggesting that both indicators may be used to track global climate signal.  相似文献   

14.
The recharge altitude estimation of thermal springs from northern and eastern Morocco using 18O and 2H contents requires the definition of regional isotopic altitudinal gradients (?0.25‰ for 100 m for the Rif and ?0.30‰ for the East) and the calculation of residence time using 14C. The altitudes of emergence vary widely between 170 and 1040 m under the altitude of the recharge areas. The 18O and 2H compositions of palaeowaters (>10000 yr BP) indicate two effects, altitude and palaeoclimate. To cite this article: A. Winckel et al., C. R. Geoscience 334 (2002) 469–474.  相似文献   

15.
The Triassic Dehnow pluton of NE Iran is a garnet-bearing I-type calc-alkaline metaluminous diorite-tonalite-granodiorite intrusion. The parental magma formed as the result of partial melting of intermediate to felsic rocks in the lower crust. Petrological and geochemical evidence, which indicates a magmatic origin for the garnet, includes: large size (~10–20 mm) of crystals, absence of reaction rims, a distinct composition from garnet in adjacent metapelitic rocks, and similarity in the composition of mineral inclusions (biotite, hornblende) in the garnet and in the matrix. Absence of garnet-bearing enclaves in the pluton and lack of sillimanite (fibrolite) and cordierite inclusions in magmatic garnet suggests that the garnet was not produced by assimilation of meta-sedimentary country rocks. Also, the δ18O values of garnet in the pluton (8.3–8.7‰) are significantly lower than δ18O values of garnet in the metapelitic rocks (12.5–13.1‰). Amphibole-plagioclase and garnet-biotite thermometers indicate crystallization temperatures of 708°C and 790°C, respectively. A temperature of 692°C obtained by quartz-garnet oxygen isotope thermometry points to a closure temperature for oxygen diffusion in garnet. The composition of epidote (Xep) and garnet (Xadr) indicates ~800°C for the crystallization temperature of these minerals. Elevated andradite content in the rims of garnet suggests that oxygen fugacity increased during crystallization.  相似文献   

16.
Ice core from Greenland was melted, filtered, homogenised, loaded into glass ampoules, sealed, autoclaved to eliminate biological activity, and calibrated by dual‐inlet isotope‐ratio mass spectrometry. This isotopic reference material (RM), USGS46, is intended as one of two secondary isotopic reference waters for daily normalisation of stable hydrogen (δ2H) and stable oxygen (δ18O) isotopic analysis of water with a mass spectrometer or a laser absorption spectrometer. The measured δ2H and δ18O values of this reference water were ?235.8 ± 0.7‰ and ?29.80 ± 0.03‰, respectively, relative to VSMOW on scales normalised such that the δ2H and δ18O values of SLAP reference water are, respectively, ?428 and ?55.5‰. Each uncertainty is an estimated expanded uncertainty (U = 2uc) about the reference value that provides an interval that has about a 95‐percent probability of encompassing the true value. This reference water is available in cases containing 144 glass ampoules that are filled with either 4 ml or 5 ml of water per ampoule.  相似文献   

17.
《Applied Geochemistry》2003,18(7):997-1009
The δ18O and δD values in the deep confined aquifer beneath the North China Plain which is located at 112°30′E–119°30′E and 34°46′N–40°25′N, reflect differences in paleoclimatic conditions between the Holocene and the late Pleistocene. Groundwater samples whose 14C ages are between 12 and 25 ka B.P have ranges of −9.4 to −11.7‰ for δ18O and −76‰ to −85‰ for δD values. These very negative δ18O and δD values reflect the cold and arid climate in the last glacial period. The temperature estimated in this period is 6–9 °C cooler than that of the present. The entire ranges of δ18O and δD values for samples with 14C dating from 7 ka B.P to present are −7.7‰ to −10.2‰ and −63‰ to −73‰, respectively. The greater δ18O and δD enrichments of these samples indicate a period of relatively humid and warm climate in the Holocene. However, the wide ranges of δ18O (−9.0‰ to −11.1‰) and δD (−66‰ to −80‰) values for samples with 14C age ranging from 12 to 7 ka B.P. imply an unstable climatic condition of rapidly increasing temperature, which marks the transition from the Pleistocene to the Holocene.  相似文献   

18.
《Geochimica et cosmochimica acta》1999,63(11-12):1825-1836
Oxygen isotope data have been obtained for silicate inclusions in diamonds, and similar associated minerals in peridotitic and eclogitic xenoliths from the Finsch kimberlite by laser-fluorination. Oxygen isotope analyses of syngenetic inclusions weighing 20–400 μg have been obtained by laser heating in the presence of ClF3. 18O/16O ratios are determined on oxygen converted to CO2 over hot graphite and, for samples weighing less than 750 μg (producing <12 μmoles O2) enhanced CO production in the graphite reactor causes a systematic shift in both δ13C and δ18O that varies as a function of sample weight. A “pressure effect” correction procedure, based on the magnitude of δ13C (CO2) depletion relative to δ13C (graphite), is used to obtain corrected δ18O values for inclusions with an accuracy estimated to be ±0.3‰ for samples weighing 40 μg.Syngenetic inclusions in host diamonds with similar δ13C values (−8.4‰ to −2.7‰) have oxygen isotope compositions that vary significantly, with a clear distinction between inclusions of peridotitic (+4.6‰ to +5.6‰) and eclogitic paragenesis (+5.7‰ to +8.0‰). The mean δ18O composition of olivine inclusions is indistinguishable from that of typical peridotitic mantle (5.25 ± 0.22‰) whereas syngenetic purple garnet inclusions possess relatively low δ18O values (5.00 ± 0.33‰). Reversed oxygen isotope fractionation between olivine and garnet in both diamond inclusions and diamondiferous peridotite xenoliths suggests that garnet preserves subtle isotopic disequilibrium related to genesis of Cr-rich garnet and/or exchange with the diamond-forming fluid. Garnet in eclogite xenoliths in kimberlite show a range of δ18O values from +2.3‰ to +7.3‰ but garnets in diamondiferous eclogites and as inclusions in diamond all have values >4.7‰.  相似文献   

19.
The Early Jurassic period was characterized by extreme environmental changes, as reflected by major global carbon isotope anomalies and abrupt changes in oxygen isotope and elemental records of marine organisms. Available data suggest an overall warm Early Jurassic climate interrupted by periods of severe cooling, with a climatic optimum during the early Toarcian. Available geochemical studies, however, have mainly focused on the northern margin of the Tethys Ocean, so that the palaeogeographic extent of these environmental perturbations, latitudinal palaeotemperature gradients and climate belt boundaries remain poorly constrained. Here we report the first stable isotope records of brachiopod shells (δ13C and δ18O values) from the Upper Sinemurian-Middle Toarcian interval in the southern margin of the Tethys Ocean (northwest Algeria). These data were used to better constrain the palaeoenvironmental evolution of the North Gondwana margin during the Early Jurassic, which likely played an important role on supra-regional climate. The diagenetic history of the analysed brachiopod shells was monitored using scanning electron microscopy, and elemental (manganese and strontium) compositions. The brachiopod δ13C and δ18O data show very similar trends as those reported for various Tethyan regions, and record negative carbon and oxygen isotope excursions near the Sinemurian–Pliensbachian and Pliensbachian–Toarcian transitions and during the Toarcian oceanic anoxic event (T-OAE). Despite these similarities, the carbon and oxygen isotope records are systematically offset towards more positive δ13C values (average +0.5‰) and more negative δ18O values (−1.0‰) compared to those obtained from sites of higher palaeolatitudes in the northern Tethyan margin. These offsets suggest a spatial heterogeneity in the stable isotope composition of dissolved inorganic carbon in the Early Jurassic Ocean and a marked latitudinal temperature gradient between the southern and northern margins of the Tethys.  相似文献   

20.
The oxygen isotope composition of 56 Hercynian granites and 42 pre-Hercynian gneisses has been investigated. In addition some mineral δ 18O data and 5 δD values of whole rocks have been obtained. The granites from the N-Schwarzwald show, in general, relatively uniform δ 18O values between 11.5 and 13.5‰, those from the S-Schwarzwald are less uniform and lighter in 18O and range from 2.3 to 11.5‰. The gneisses from the pre-Hercynian basement exhibit more or less the same variation and range from 1.7 to 10.4‰. δ 18O values <6‰ only occur in the S-Schwarzwald and obviously indicate hydrothermal interactions of meteoric waters, which probably took place after the emplacement and solidification of the granites and which equally affected granites and gneisses. Due to the nearly identical 18O/16O ratios of S-Schwarzwald granites and gneisses, it is proposed that such gneisses in the pre-Hercynian basement qualify as the precursor rocks of the S-Schwarzwald, granites whereas for the N-Schwarzwald granites crustal rocks with heavier δ 18O values, unknown from the present surface, have to be postulated. This distribution is also reflected on a 87Sr/86Sr-18O/16O diagram.  相似文献   

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