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1.
Mariner 9 has provided a refutation or reinterpretation of several historical claims for Martian biology, and has permitted an important further characterization of the environmental constraints on possible Martian organisms. Four classes of conceivable Martian organisms are identified, depending on the environmental temperature, T, and water activity, aw: Class I, high T, high aw; Class II, low T, high aw; Class III, high T, low aw; and Class IV, low T, low aw. The Viking lander biology experiments are essentially oriented toward Class I organisms, although arguments are given for the conceivable presence on Mars of organisms in any of the four classes. Organisms which extract their water requirements from hydrated minerals or from ice are considered possible on Mars, and the high ultraviolet flux and low oxygen partial pressure are considered to be negligible impediments to Martian biology. Large organisms, possibly detectable by the Viking lander cameras, are not only possible on Mars; they may be favored. The surface distribution of Martian organisms and future search strategies for life on Mars are discussed.  相似文献   

2.
Hf‐W isotopic systematics of Martian meteorites have provided evidence for the early accretion and rapid core formation of Mars. We present the results of numerical simulations performed to study the early thermal evolution and planetary scale differentiation of Mars. The simulations are confined to the initial 50 Myr (Ma) of the formation of solar system. The accretion energy produced during the growth of Mars and the decay energy due to the short‐lived radio‐nuclides 26Al, 60Fe, and the long‐lived nuclides, 40K, 235U, 238U, and 232Th are incorporated as the heat sources for the thermal evolution of Mars. During the core‐mantle differentiation of Mars, the molten metallic blobs were numerically moved using Stoke's law toward the center with descent velocity that depends on the local acceleration due to gravity. Apart from the accretion and the radioactive heat energies, the gravitational energy produced during the differentiation of Mars and the associated heat transfer is also parametrically incorporated in the present work to make an assessment of its contribution to the early thermal evolution of Mars. We conclude that the accretion energy alone cannot produce widespread melting and differentiation of Mars even with an efficient consumption of the accretion energy. This makes 26Al the prime source for the heating and planetary scale differentiation of Mars. We demonstrate a rapid accretion and core‐mantle differentiation of Mars within the initial ~1.5 Myr. This is consistent with the chronological records of Martian meteorites.  相似文献   

3.
Geologic evidence of the prior existence of liquid water on Mars suggests surface temperatures Ts were once considerably warmer than at present; and that such a condition may have arisen from a larger atmospheric greenhouse. Here we develop a simple climate model for a CO2/H2O Mars atmosphere including water vapor-longwave opacity feedback in the atmosphere and temperature-albedo feedback at surface icecaps, under the assumption that once the Martian surface pressure was ps ≥ 1 atm CO2. Longwave flux to space is computed as a function of Ts and ps using band-absorption models for the effect of the 15-μm fundamental, and the 10- and 15-μm hot bands, of the CO2 molecule; as well as the pure rotation bands and e continuum of H2O. The derived global radiative balance predicts a global mean surface temperature of 283°K at 1 atm CO2. When the emission model is coupled to a latitudinally resolved energy balance climate model, including the effect of poleward heat transfer by atmospheric baroclinic eddies, the solutions vary, depending on ps. We considered two cases: (1) the present Mars (ps ? 0.007 atm) with pressure-buffering by solid CO2 icecaps, and limited poleward heat flux by the atmosphere; and (2) a hypothetical “hot Mars” (ps ? 1.0 atm), whose much higher CO2 amount augmented by H2O evaporative feedback yields a theoretical Ts distribution with latitude admitting liquid water over 95% of the surface, water icecaps at the poles, and a diminished equator-to-pole temperature gradient relative to the present.  相似文献   

4.
Nonthermal emission occurs in the cores of the 9.4- and 10.4-μm CO2 bands on Mars, and has been recently identified as a natural atmospheric laser. This paper presents observations of the total flux and center-to-limb dependence of this emission for Mars and Venus. The emission is believed to be excited by absorption of solar flux in the near-ir CO2 bands, followed by collisional transfer to the 00°1 state of CO2. A comparison is made between the observations and a detailed theoretical model based on this mechanism. It is found that the theoretical model successfully reproduces the observed center-to-limb dependence of this emission, to within the limits imposed by the spatial resolution of the observations. A comparison is also made between the observed fluxes and the predictions of the theoretical models. The observed flux from Mars agrees closely with the prediction of the model; the flux observed from Venus is 74% of the flux predicted by the model. This emission is utilized to obtain the kinetic temperatures of the Martian and Venusian mesospheres. For Mars near 70 km altitude, a rotational temperature analysis using five lines gives T = 135 ± 20°K. The frequency width of the emission is also analyzed to derive a temperature of 126 ± 6°K. In the case of the Venusian mesosphere near 109 km, the frequency width of the emission gives T = 204 ± 10°K.  相似文献   

5.
We present the results of extensive numerical modeling of the Martian interior. Yoder et al. in 2003 reported a mean moment of inertia of Mars that was somewhat smaller than the previously used value and the Love number k2 obtained from observations of solar tides on Mars. These values of k2 and the mean moment of inertia impose a strong new constraint on the model of the planet. The models of the Martian interior are elastic, while k2 contains both elastic and inelastic components. We thoroughly examined the problem of partitioning the Love number k2 into elastic and inelastic components. The information necessary to construct models of the planet (observation data, choice of a chemical model, and the cosmogonic aspect of the problem) are discussed in the introduction. The model of the planet comprises four submodels—a model of the outer porous layer, a model of the consolidated crust, a model of the silicate mantle, and a core model. We estimated the possible content of hydrogen in the core of Mars. The following parameters were varied while constructing the models: the ferric number of the mantle (Fe#) and the sulfur and hydrogen content in the core. We used experimental data concerning the pressure and temperature dependence of elastic properties of minerals and the information about the behavior of Fe(γ-Fe ), FeS, FeH, and their mixtures at high P and T. The model density, pressure, temperature, and compressional and shear velocities are given as functions of the planetary radius. The trial model M13 has the following parameters: Fe#=0.20; 14 wt % of sulfur in the core; 50 mol % of hydrogen in the core; the core mass is 20.9 wt %; the core radius is 1699 km; the pressure at the mantle-core boundary is 20.4 GPa; the crust thickness is 50 km; Fe is 25.6 wt %; the Fe/Si weight ratio is 1.58, and there is no perovskite layer. The model gives a radius of the Martian core within 1600–1820 km while ≥30 mol % of hydrogen is incorporated into the core. When the inelasticity of the Martian interior is taken into account, the Love number k2 increases by several thousandths; therefore, the model radius of the planetary core increases as well. The prognostic value of the Chandler period of Mars is 199.5 days, including one day due to inelasticity. Finally, we calculated parameters of the equilibrium figure of Mars for the M13 model: J 2 0 = 1.82 × 10?3, J 4 0 = ?7.79 × 10?6, e c-m D = 1/242.3 (the dynamical flattening of the core-mantle boundary).  相似文献   

6.
Shortly after the occurrence of the impulsive spikes of the two-ribbon flare of May 21, 1980, a temperature analysis of the X-ray emitting flare plasma showed the presence of a low-temperature component [n = 15 × 1010 cm#X2212;3; T = 20 × 106 K] and a high-temperature component [n = 2 × 1010 cm#X2212;3; T = 40 × 106 K]. The mean free path of an electron in the hot component is comparable to the size of the source (≈ 104 km). Heat losses from the hot source can therefore not be described with classical formulae. Theoretical arguments show that most likely the electron to ion temperature ratio T e/Ti in the hot plasma is close to unity. This implies the presence of a hot ion component (T i ≈ 40 × 106 K) as well. Under these conditions (T eT i) heat flux limitation by electrostatic turbulence is ineffective. However, reduction of the heat flux is still possible due to the breakdown of classical theory. It is demonstrated that only non-classical current dissipation processes can sustain a hot source against cooling by a saturated heat flux. Investigation of the collisionality as a function of position along a magnetic loop shows that the breakdown of classical theory should be expected to occur first near the base of the loop. We conclude that the newly discovered hot source is important for the energy budget of the flare, even if the heat losses are considerably reduced. It is estimated that for the May 21, 1980 flare a total of about 1031 ergs were necessary to maintain the hot source against heat losses over the time period that it was observed (≈ 10 min).  相似文献   

7.
Of the terrestrial planets, Earth and probably Mercury possess substantial intrinsic magnetic fields generated by core dynamos, while Venus and Mars apparently lack such fields. Thermal histories are calculated for these planets and are found to admit several possible present states, including those which suggest simple explanations for the observations; whule the cores of Earth and Mercury are continuing to freeze, the cores of Venus and Mars may still be completely liquid. The models assume whole mantle convection, which is parameterized by a simple Nusselt-Rayleigh number relation and dictates the rate at which heat escapes from the core. It is found that completely fluid cores, devoid of intrinsic heat sources, are not likely to sustain thermal convection for the age of the solar system but cool to a subadiabatic, conductive state that can not maintain a dynamo. Planets which nucleate an inner core continue to sustain a dynamo because of the gravitational energy release and chemically driven convection that accompany inner core growth. The absence of a significant inner core can arise in Venus because of its slightly higher temperature and lower central pressure relative to Earth, while a Martian core avoids the onset of freezing if the abundance of sulfur in the core is ?15% by mass. All of the models presented assume that (I) core dynamos are driven by thermal and/or chemical convection; (ii) radiogenic heat production is confined to the mantle; (iii) mantle and core cool from initially hot states which are at the solidus and superliquidus, respectively; and (iv) any inner core excludes the light alloying material (sulfur or oxygen) which then mixes uniformly upward through the outer core. The models include realistic pressure and composition-dependent freezing curves for the core, and material parameters are chosen so that the correct present-day values of heat outflow, upper mantle temperature and viscosity, and inner core radius are obtained for the earth. It is found that Venus and Mars may have once had dynamos maintained by thermal convection alone. Earth may have had a completely fluid core and a dynamo maintained by thermal convection for the first 2 to 3 by, but an inner core nucleates and the dynamo energetics are subsequently dominated by gravitational energy release. Complete freezing of the Mercurian core is prohibited if it contains even a small amount of sulfur, and a dynamo can be maintained by chemical convection in a thin, fluid shell.  相似文献   

8.
Terrestrial and Martian atmospheres are both characterised by a large variety of mesoscale meteorological events, occurring at horizontal scales of hundreds of kilometres and below. Available measurements from space exploration and recently developed high-resolution numerical tools have given insights into Martian mesoscale phenomena, as well as similarities and differences with their terrestrial counterparts. The remarkable intensity of Martian mesoscale events compared to terrestrial phenomena mainly results from low density and strong radiative control. This is exemplified in the present paper by discussing two mesoscale phenomena encountered in the lowest atmospheric levels of both planets with notable differences: nighttime katabatic winds (drainage flow down sloping terrains) and daytime boundary layer convection (vertical growth of mixed layer over heated surfaces). While observations of katabatic events are difficult on Earth, except over vast ice sheets, intense clear-cut downslope circulations are expected to be widespread on Mars. Convective motions in the daytime Martian boundary layer are primarily driven by radiative contributions, usually negligible on Earth where sensible heat flux dominates, and exhibit turbulent variances one order of magnitude larger. Martian maximum heat fluxes are not attained close to the surface as on Earth but a few hundreds of metres above, which implies generalised definitions for mixing layer scales such as vertical velocity w?. Measurements on Mars of winds in uneven topographical areas and of heat fluxes over flat terrains could be useful to assess general principles of mesoscale meteorology applicable to both terrestrial and Martian environments.  相似文献   

9.
《Icarus》1987,71(2):203-224
Theoretical arguments are presented in support of the idea that Mars possessed a dense CO2 atmosphere and a wet, warm climate early in its history. Calculations with a one-dimensional radiative-convective climate model indicate that CO2 pressures between 1 and 5 bars would have been required to keep the surface temperature above the freezing point of water early in the planet's history. The higher value corresponds to globally and orbitally averaged conditions and a 30% reduction in solar luminosity; the lower value corresponds to conditions at the equator during perihelion at times of high orbital eccentricity and the same reduced solar luminosity.The plausibility of such a CO2 greenhouse is tested by formulating a simple model of the CO2 geochemical cycle on early Mars. By appropriately scaling the rate of silicate weathering on present Earth, we estimate a weathering time constant of the order of several times 107 years for early Mars. Thus, a dense atmosphere could have persisted for a geologically significant time period (109years) only if atmospheric CO2 was being continuously resupplied. The most likely mechanism by which this might have been accomplished is the thermal decomposition of carbonate rocks induced directly and indirectly (through burial) by intense, global-scale volcanism. For plausible values of the early heat flux, the recycling time constant is also of the order of several times 107 years. The amount of CO2 dissolved in standing bodies of water was probably small; thus, the total surficial CO2 inventory required to maintain these conditions was approximately 2 to 10 bars. The amount of CO2 in Mars' atmosphere would eventually have dwindled, and the climate cooled, as the planet's internal heat engine ran down. A test for this theory will be provided by spectroscopic searches for carbonates in Mars' crust.  相似文献   

10.
The thermo-mechanical properties of planetary surface and subsurface layers control to a high extent in which way a body interacts with its environment, in particular how it responds to solar irradiation and how it interacts with a potentially existing atmosphere. Furthermore, if the natural temperature profile over a certain depth can be measured in situ, this gives important information about the heat flux from the interior and thus about the thermal evolution of the body. Therefore, in most of the recent and planned planetary lander missions experiment packages for determining thermo-mechanical properties are part of the payload. Examples are the experiment MUPUS on Rosetta's comet lander Philae, the TECP instrument aboard NASA's Mars polar lander Phoenix, and the mole-type instrument HP3 currently developed for use on upcoming lunar and Mars missions. In this review we describe several methods applied for measuring thermal conductivity and heat flux and discuss the particular difficulties faced when these properties have to be measured in a low pressure and low temperature environment. We point out the abilities and disadvantages of the different instruments and outline the evaluation procedures necessary to extract reliable thermal conductivity and heat flux data from in situ measurements.  相似文献   

11.
Mars is thought to have hosted large amounts of water and carbon dioxide at primitive epochs. The morphological analysis of the surface of Mars shows that large bodies of water were probably present in the North hemisphere at late Noachian (3.7–4 Gyr ago). Was this water solid or liquid? For maintaining liquid water at this time, when the Sun was (likely) less bright than now, a CO2 atmosphere of typically 2 bars is required. Can sputtering, still presently acting at the top of the Martian atmosphere, have removed such a dense atmosphere over the last 3.5–4 Gyr? What was the fate of the 100–200 m global equivalent layer of water present at late Noachian? When did Martian magnetic dynamo vanish, initiating a long period of intense escape by sputtering? Because sputtering efficiency is highly non-linear with solar EUV flux, with a logarithmic slope of ≈7:ΦsputΦEUV7, resulting in enhanced levels of escape at primitive epochs, when the sun was several times more luminous than now in the EUV, there is a large uncertainty on the cumulated amount of volatiles removed to space. This amount depends primarily on two factors: (i) the exact value of the non-linearity exponent (≈7 from existing models, but this value is rather uncertain), (ii) the exact time when the dynamo collapsed, activating sputtering at epochs when intense EUV flux and solar wind activity prevailed in the solar system. Both parameters are only crudely known at the present time, due the lack of direct observation of sputtering from Martian orbit, and to the incomplete and insufficiently spatially resolved map of the crustal magnetic field. Precise timing of the past Martian dynamo can be investigated through the demagnetisation signature associated with impact craters. A designated mission to Mars would help in answering this crucial question: was water liquid at the surface of Mars at late Noachian? Such a mission would consist of a low periapsis (≈100 km) orbiter, equipped with a boom-mounted magnetometer, for mapping the magnetic field, as well as adequate in situ mass and energy spectrometers, for a full characterization of escape and of its response to solar activity variations. Surface based observations of atmospheric noble gas isotopic ratios, which keep the signatures of past escape processes, including sputtering for the lightest of them (Ne, Ar), would bring a key constraint for escape models extrapolated back to the past.  相似文献   

12.
The thermal emission spectrometer (TES) and the radio science (RS) experiment flying on board the Mars Global Surveyor (MGS) spacecraft have made observations of atmospheric temperatures below the saturation temperature of carbon dioxide (CO2). This supersaturated air provides a source of convective available potential energy (CAPE), which, when realized may result in vigorous convective mixing. To this point, most Mars atmospheric models have assumed vertical mixing only when the dry adiabatic lapse rate is exceeded. Mixing associated with the formation of CO2 clouds could have a profound effect on the vertical structure of the polar night, altering the distribution of temperature, aerosols, and gasses.Presented in this work are estimates of the total planetary inventory of CAPE and the potential convective energy flux (PCEF) derived from RS and TES temperature profiles. A new Mars Global Circulation Model (MGCM) CO2 cloud model is developed to better understand the distribution of observed CAPE and its potential effect on Martian polar dynamics and heat exchange, as well as effects on the climate as a whole. The new CO2 cloud model takes into account the necessary cloud microphysics that allow for supersaturation to occur and includes a parameterization for CO2 cloud convection. It is found that when CO2 cloud convective mixing is included, model results are in much better agreement with the observations of the total integrated CAPE as well as total column non-condensable gas concentrations presented by Sprague et al. [2005a, GRS measurements of Ar in Mars’ atmosphere, American Astronomical Society, DPS meeting #37, #24.08, and 2005b, Distribution and Abundance of Mars’ Atmospheric Argon, 36th Annual Lunar and Planetary Science Conference, #2085] When the radiative effects of water ice clouds are included the agreement is further improved.  相似文献   

13.
Petr Chýlek  G.W. Grams 《Icarus》1978,36(2):198-203
Ultraviolet spectral reflectance data obtained from the Mariner 9 during the 1971 Mars dust storm were analyzed at two wavelengths to deduce the complex index of refraction of Martian dust. Martian dust particles were considered to be irregularly shaped and randomly oriented nonspherical particles. The analysis shows that the Mariner 9 data are consistent with the scattering by irregular particles with an index of refraction m = 1.59 ? 0.0015i at λ = 0.305 μm and m = 1.55 ? 0.004i at λ = 0.268 μm. Both the real and the imaginary parts of refractive index found are considerably smaller than previously reported results using a spherical shape model for Martian dust particles.  相似文献   

14.
A theoretical thermal evolution model of Mars is constructed, utilizing as constraints the available geophysical and geological data, including those provided by the Viking missions. The calculation includes conduction and subsolidus mantle convection. Calculated models indicate that Martian evolution can be roughly characterized by four different stages. (1) Core formation and crust differentiation: this stage starts from the planet formation to about 1 by thereafter. During this period, Martian core is separated and the initial crust is differentiated. (2) Heating, expansion, and mantle differentiation: this stage begins after the core separation and extends to about 3 by. First, mantle temperatures rise and reach partial melting. Between 2 and 3 by, extensive melting, differentiation, and outgassing occur. Planetary radius increases and extensional features observed at the surface are most likely generated at this stage. (3) Mature phase: after 3 by, the planet reaches maturity. Between 3 and 4 by slow and sustained evolution continues. Lithosphere thickens and partial melt zone deepens. (4) Cooling period: this stage represents the last phase of Martian history. The planet is cooling slowly. The partial melting zone shrinks and volcanic activity tapers off. At present, Martian lithosphere is about 200 km thick and the mantle is convecting slowly. The models suggest that the core is molten, and the calculated surface heat flux is 35 erg cm?2 sec?1.  相似文献   

15.
The processes of kinetics and transport of hot oxygen and hydrogen atoms in the transition (from the thermosphere to the exosphere) region of the upper Martian atmosphere are studied. The reaction of dissociative recombination of the principal ionospheric ion O 2 + with thermal electrons in the ionosphere of Mars served as the source of hot oxygen atoms. The process of momentum and energy transfer in elastic collisions between hot oxygen atoms and atmospheric hydrogen atoms with thermal energies was regarded as the source of hot hydrogen atoms. The kinetic energy distribution functions are determined for suprathermal oxygen and hydrogen atoms. It is shown that the exosphere is populated with a significant number of suprathermal oxygen atoms with kinetic energies ranging up to the escape energy of 2 eV (i.e., the hot oxygen Martian corona is formed). The transfer of energy from hot oxygen atoms to thermal hydrogen atoms creates an additional nonthermal flux of atomic hydrogen escaping from the Martian atmosphere.  相似文献   

16.
We have used and extended Roosbeek’s tidal potential for Mars to calculate tidal displacements, gravity variations, and external gravitational potential variations. The tides on Mars are caused by the Sun, and to a lesser degree by the natural satellites Phobos (8%, relative to the Sun) and Deimos (0.08%, relative to the Sun). To determine the reaction of Mars to the tidal forcing, the Love numbers h, l, and k and the gravimetric factor δ were calculated for interior models of Mars with different state, density, and radius of the core and for models which include mantle anelasticity. The latitude dependence and frequency dependence of the Love numbers have been taken explicitly into account. The Love numbers are about three times smaller than those for the Earth and are very sensitive to core changes; e.g., a difference of about 30% is found between a model with a liquid core and an otherwise similar model with a solid core. Tidal displacements on Mars are much smaller than on Earth due to the smaller tidal potential, but also due to the smaller reaction of Mars (smaller Love numbers). For both the tidal diplacement and the tidal external potential perturbations, the tidal signal is at the limit of detection and is too small to permit properties of Mars’s interior to be inferred. On the other hand, the Phobos tidally induced gravity changes, which are subdiurnal with typical periods shorter than 12 h, can be measured very precisely by the very broad band seismometer with thermal control of the seismological experiment SEIS of the upcoming NetLander mission. It is shown that the Phobos-induced gravity tides could be used to study the Martian core.  相似文献   

17.
We have systematically surveyed the effects of the ion temperature anisotropy on the peak reconnected flux level of the tearing instability excited in a thick current sheet (its half-thickness D equal to the ion inertial length). A series of two- and three-dimensional (2-D and 3-D) simulations have been performed for a magnetotail-like situation, where the ion perpendicular temperature is fixed to balance the magnetic pressure of the lobe while the ion parallel temperature can be varied to give rise to the temperature anisotropy αi=Ti,perp/Ti,para. Focusing on the behavior of the fastest growing mode (wavelength λ=12D), the results are summarized as follows: (1) The peak levels are larger when the initial αi is larger and lobe reconnection is obtained only when αi>1.5. (2) 3-D effects do speed-up the reconnection process but do not change the peak level substantially. (3) The time-scale of gas pressure build-up at the center of magnetic islands relative to the time-scale of reconnected flux growth is identified to be the key issue in determining the peak level. Based on these results for the fastest growing mode with λ=12D, discussion is given on the larger-scale development, that is, what happens when longer wavelength modes are allowed to develop.  相似文献   

18.
The thermal history of Mars during accretion and differentiation is important for understanding some fundamental aspects of its evolution such as crust formation, mantle geochemistry, chronology, volatile loss and interior degassing, and atmospheric development. In light of data from new Martian meteorites and exploration rovers, we have made a new estimate of Martian mantle siderophile element depletions. New high pressure and temperature metal–silicate experimental partitioning data and expressions are also available. Using these new constraints, we consider the conditions under which the Martian mantle may have equilibrated with metallic liquid. The resulting conditions that best satisfy six siderophile elements—Ni, Co, W, Mo, P, and Ga—and are consistent with the solidus and liquidus of the Martian mantle phase diagram are a pressure of 14 ± 3 GPa and temperature of 2100 ± 200 K. The Martian mantle depletions of Cr and V are also consistent with metal–silicate equilibration in this pressure and temperature range if deep mantle silicate phases are also taken into account. The results are not consistent with either metal–silicate equilibrium at the surface or at the current‐day Martian core–mantle boundary. Recent measurements and modeling have concluded that deep (~17 GPa or 1350 km) mantle melting is required to explain isotopic data for Martian meteorites and the nature of differentiation into core, mantle, and crust. This is in general agreement with our estimates of the conditions of Martian core formation based on siderophile elements that result in an intermediate depth magma ocean scenario for metal–silicate equilibrium.  相似文献   

19.
Theoretical physical models of the Martia interior are presented in the light of new and revised data and constraints. These models include thermal evolution, densities, and seismic wave velocities. The interior of Mars appears to be Earth-like in many respects. Although thermal models indicate that Mars has passed its peak of evolution it may still have an asthenosphere and may be moderately active tectonically. Mars has an Fe-FeS core with a radius of and may be moderately active tectonically. Mars has an Fe-FeS core with a radius of 1500–2000 km. The mantle is enriched in FeO with an olivine composition of about Fo75. Theoretically determined seismic wave velocities are relatively well constrained in the mantle with upper-mantle Pn velocities ranging from 7.64 to 7.80 km/sec. However, there are wide variations in VP in the core dependent on composition. The shadow zone due to the core is larger than the Earth's.  相似文献   

20.
Abstract— Pyroxene structural data, along with analyses of titanomagnetite, fayalite and mesostasis of the new nakhlite Miller Range (MIL) 03346, define equilibration near 1 bar, 1100 °C, and oxygen fugacity near the FMQ buffer. There is a clear progression of oxygen fugacity (fO2) in Martian meteorites from reduced Allan Hills (ALH) 84001 to intermediate shergottites to oxidized nakhlites. This trend can be explained by polybaric graphite‐CO‐CO2 equilibria in the Martian mantle. Shergottites would have formed at pressures between 1.2 and 3.0 GPa, and nakhlite parent liquids formed at pressures >3.0 GPa, consistent with geochemical and petrologic data for the shergottites and nahklites. Carbon buffering in the Martian mantle could be responsible for variation in fO2 in Martian meteorites (rather than assimilation or crustal interaction), as well as C‐H‐O fluids that could be the source of ˜30 ppb CH4 detected by recent spacecraft missions. The conundrum of an oxidized current mantle and basalts, but reduced early mantle during core‐mantle equilibrium exists for both the Earth and Mars. A polybaric buffering role for graphite can explain this discrepancy for Mars, and thus it may not be necessary to have an oxidation mechanism like the dissociation of MgFe‐perovskite to account for the oxidized terrestrial mantle.  相似文献   

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