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1.
In order to study the stability of martian climate, we constructed a two-dimensional (horizontal-vertical) energy balance model. The long-term CO2 mass exchange process between the atmosphere and CO2 ice caps is investigated with particular attention to the effect of planetary ice distribution on the climate stability. Our model calculation suggests that high atmospheric pressure presumed for past Mars would be unstabilized if H2O ice widely prevailed. As a result, a cold climate state might have been achieved by the condensation of atmospheric CO2 onto ice caps. On the other hand, the low atmospheric pressure, which is buffered by the CO2 ice cap and likely close to the present pressure, would be unstabilized if the CO2 ice albedo decreased. This may have led the climate into a warm state with high atmospheric pressure owing to complete evaporation of CO2 ice cap. Through the albedo feedback mechanisms of H2O and CO2 ices in the atmosphere-ice cap system, Mars may have experienced warm and cold climates episodically in its history. 相似文献
2.
The 362.156 GHz absorption spectrum of H2O2 in the Mars atmosphere was observed on September 4 of 2003, employing the James Clerk Maxwell Telescope (JCMT) sub-millimeter facility on Mauna Kea, Hawaii. Radiative transfer analysis of this line absorption yields an average volume mixing ratio of 18±0.4 ppbv within the lower (0-30 km) Mars atmosphere, in general accordance with standard photochemical models (e.g., Nair et al., 1994, Icarus 111, 124-150). Our derived H2O2 abundance is roughly three times greater than the upper limit retrieved by Encrenaz et al. (2002, Astron. Astrophys. 396, 1037-1044) from infrared spectroscopy, although part of this discrepancy may result from the different solar longitudes (Ls) of observation. Aphelion-to-perihelion thermal forcing of the global Mars hygropause generates substantial (>200%) increases in HOx abundances above ∼10 km altitudes between the Ls=112° period of the Encrenaz et al. upper limit measurement and the current Ls=250° period of detection (Clancy and Nair, 1996, J. Geophys. Res. 101, 12785-12590). The observed H2O2 line absorption weakens arguments for non-standard homogeneous (Encrenaz et al., 2002, Astron. Astrophys. 396, 1037-1044) or heterogeneous (Krasnopolsky, 2003a, J. Geophys. Res. 108; 2003b, Icarus 165, 315-325) chemistry, which have been advocated partly on the basis of infrared (8 μm) non-detections for Mars H2O2. Observation of Mars H2O2 also represents the first measurement of a key catalytic specie in a planetary atmosphere other than our own. 相似文献
3.
We present near-IR spectra of solid CO2 in H2O and CH3OH, and find they are significantly different from that of pure solid CO2. Peaks not present in either pure H2O or pure CO2 spectra become evident when the two are mixed. First, the putative theoretically forbidden CO2 (2ν3) overtone near 2.134 μm (4685 cm−1), that is absent from our spectrum of pure solid CO2, is prominent in the spectra of H2O/CO2=5 and 25 mixtures. Second, a 2.74-μm (3650 cm−1) dangling OH feature of H2O (and a potentially related peak at 1.89 μm) appear in the spectra of CO2-H2O ice mixtures, but are probably not diagnostic of the presence of CO2. Other CO2 peaks display shifts in position and increased width because of intermolecular interactions with H2O. Warming causes some peak positions and profiles in the spectrum of a H2O/CO2=5 mixture to take on the appearance of pure CO2. Absolute strengths for absorptions of CO2 in solid H2O are estimated. Similar results are observed for CO2 in solid CH3OH. Since the CO2 (2ν3) overtone near 2.134 μm (4685 cm−1) is not present in pure CO2 but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO2 is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies. 相似文献
4.
In this work we consider when and how much liquid water during present climate is possible within the gullies observed on the surface of Mars. These features are usually found on poleward directed slopes. We analyse the conditions for melting of H2O ice, which seasonally condenses within the gullies. We follow full annual cycle of condensation and sublimation of atmospheric CO2 and H2O, accounting for the heat and mass transport in the soil. During the summer, once the facets of the gullies are exposed to the Sun the water ice can melt and evaporate. Two mid latitude locations in both hemispheres are considered. The model includes both the rough geometry of the gullies as well as the slope of the surface where the gullies appear. It is an extension of the model developed to calculate condensation of CO2 ice in troughs of different sizes, including polygonal features on Mars (Kossacki and Markiewicz, 2002, Icarus 160, 73; Kossacki et al., 2003, Planet. Space Sci. 51, 569). We have found, that water ice accumulated during winter can undergo transition to the liquid phase after complete sublimation of CO2 ice. The amount of liquid water depends on water content in the atmosphere and on the local wind speed. It is probably not enough to destabilise the slope and cause flow of the surface material. However, even the small amounts of liquid water predicted, can play an important role in surface chemistry, in increasing the cohesive strength of the soil's surface layer and possibly may have some exobiological implications. 相似文献
5.
It has been suggested that inclusions of CO2 or CO2 clathrate hydrates may comprise a portion of the polar deposits on Mars. Here we present results from an experimental study in which CO2 molecules were trapped in water ice deposited from CO2/H2O atmospheres at temperatures relevant for the polar regions of Mars. Fourier-Transform Infrared spectroscopy was used to monitor the phase of the condensed ice, and temperature programmed desorption was used to quantify the ratio of species in the generated ice films. Our results show that when H2O ice is deposited at 140-165 K, CO2 is trapped in large quantities, greater than expected based on lower temperature studies in amorphous ice. The trapping occurs at pressures well below the condensation point for pure CO2 ice, and therefore this mechanism may allow for CO2 deposition at the poles during warmer periods. The amount of trapped CO2 varied from 3% to 16% by mass at 160 K, depending on the substrate studied. Substrates studied were a tetrahydrofuran (C4H8O) base clathrate and Fe-montmorillonite clay, an analog for Mars soil. Experimental evidence indicates that the ice structures are likely CO2 clathrate hydrates. These results have implications for the CO2 content, overall composition, and density of the polar deposits on Mars. 相似文献
6.
Current evidence indicates that the Martian surface is abundant with water presently in the form of ice, while the atmosphere was at one time more massive with a past surface pressure of as much as 1 atm of CO2. In an attempt to understand the Martian paleoclimate, we have modeled a past CO2H2O greenhouse and find global temperatures which are consistent with an earlier presence of liquid surface water, a finding which agrees with the extensive evidence for past fluvial erosion. An important aspect of the CO2H2O greenhouse model is the detailed inclusion of CO2 hot bands. For a surface pressure of 1 atm of CO2, the present greenhouse model predicts a global mean surface temperature of 294°K, but if the hot bands are excluded, a surface temperature of only 250°K is achieved. 相似文献
7.
The role of CO2 permafrost as an erosive agent on Mars is considered. In the CO2H2O system, with a CO2 triple point at 217°K and 5.1-bar pressure, carbon dioxide solid, liquid, or gas, CO2 clathrate, and ice are possible stable phases in the range of temperatures and pressures likely to be encountered in the Martian regolith. It is argued that conditions may exist in which CO2 permafrost is extensive on Mars, provided that adequate CO2 is available: the maximum ratio of H2O:CO2 required in the subsurface pore space system is 17:3. Erosional processes likely to result from such permafrost are block slumping, leading to canyon development; pit chains along faults; chaotic terrain where massive permafrost destruction has occured; large-scale flows of slurry; and perhaps even the flash floods which create channels. 相似文献
8.
Konrad J. KossackiWojciech J. Markiewicz 《Icarus》2002,160(1):73-85
The Mars Orbiter Camera onboard the Mars Global Surveyor has obtained several images of polygonal features in the southern polar region. In images taken during the end of the southern spring, when the surrounding surface is free of the seasonal frost, CO2 ice still appears to be present within the polygonal troughs. In Earth's polar regions, polygons such as these are indicative of water ice in the ground below. We analyzed the seasonal evolution of the thermal state and the CO2 content of these features. Our 2-D model includes condensation and sublimation of the CO2 ice, a self consistent treatment of the variations of the thermal properties of the regolith, and the seasonal variations of the local atmospheric pressure which we take from the results of a general circulation model. We find that the residence time of seasonal CO2 ice in troughs depends not only on atmospheric opacity and albedo of the CO2 ice, but also and most significantly on the distribution of water ice in the regolith. Optical properties of the atmosphere and surface CO2 ice can be independently obtained from observations. To date this is not true about the distribution of water ice below the surface. Our analysis quantifies the dependence of the seasonal cycle of the CO2 ice within the troughs on the assumed distribution of the water ice below the surface. We show that presence of water ice in the ground at a depth smaller than the depth of the troughs reduces winter condensation rate of CO2 ice. This is due to higher heat flux conducted from the water ice rich regolith toward the facets of the troughs. 相似文献
9.
Models are developed to describe the photochemistry of ozone on Mars. Catalytic reactions involving H, OH and HO2 play a major role at low latitudes where they ensure a vertical column density for O3 of less than 2 × 10?4 cm atm. The source for odd hydrogen (H + OH + HO2) is relatively smaller at high latitudes in winter due to the small concentrations of H2O present there at that time. Odd hydrogen is also efficiently removed from the high-latitude winter atmosphere by condensation of H2O2. The role of catalytic chemistry is reduced accordingly and the vertical column density of O3 may be as large as 5.7 × 10?3 cm atm in accord with earlier observations carried out by Barth and co-workers with instruments on Mariner 9. 相似文献
10.
A detailed theoretical study of the potential energy surface of H2CO3 is explored at the CCSD(T)//B3LYP/aug-cc-pVTZ level. On the potential energy surface, 12 isomers of H2CO3 are located. Their molecular properties such as geometries, vibrational frequencies, rotational constants, dipole moments, gas-phase acidities, and relative energies are calculated. Various reaction pathways and decomposition products have also been discussed. Among these products, CO2 and H2O are definitely the most favorable products with predominant abundance. Large energy barriers are predicted for other dissociation channels leading to the formation of oxygen, formaldehyde, and so on. These high energy channels are not important thermodynamically and kinetically, but they might occur in the presence of cosmic rays in astronomic environments. From the present work we suggest that chemical reactions between CO2 and H2O at the polar ice caps could be a potential source of H2CO and O2, in addition to the previously proposed mechanisms, i.e., the oxidation of methane and cosmic-ray-mediated production through the intermediate H2CO3. The results of the present work may provide useful data to improve our understanding of icy chemistry at the polar caps on Mars. 相似文献
11.
Stephen D. Wall 《Icarus》1981,47(2):173-183
A thin light-colored ground covering appeared on the surface of Mars near the Viking 2 lander from Ls = 230° to Ls = 16°, a total of 249 Mars days, during the lander's first winter on the surface. This paper presents a reduction of applicable lander imagery during the period. Imaging sequences, relative surface albedo, spectral reflectance estimates, and limited photometric data are presented and compared with previous laboratory measurements. Photometric data are best fit by an average Minnaert k = 1.1 (blue), k = 1.0 (green), and k = 0.95 (red). Appearance and disappearance rates, spectral reflectance, and photometric data all tend to confirm an earlier proposal that the covering was a combination of H2O and CO2, which fell already condensed onto dust particles brought northward by the season's first major dust storm. Under this assumption, the covering thickness is estimated to be between 0.5 and a few millimeters. 相似文献
12.
It has been suggested that the residual polar caps of Mars contain a reservoir of permanently frozen carbon dioxide which is controlling the atmospheric pressure. However, observational data and models of the polar heat balance suggest that the temperatures of the Martian poles are too high for solid CO2 to survive permanently. On the other hand, the icelike compound carbon dioxide-water clathrate (CO2 · 6H2O) could function as a CO2 reservoir instead of solid CO2, because it is stable at higher temperatures. This paper shows that the permanent polar caps may contain several millibars of CO2 in the form of clathrate, and discusses the implications of this permanent clathrate reservoir for the present and past atmospheric pressure on Mars. 相似文献
13.
G. Hansen M. Giuranna S. Fonti H. Hirsh A. Maturilli G. Piccioni B. Saggin 《Planetary and Space Science》2005,53(10):1089-1095
The Mars Express spacecraft has a highly inclined orbit around Mars and so has been able to observe the south pole of Mars in illuminated conditions at the end of the southern summer (Ls=330). Spectra from the planetary Fourier spectrometer (PFS) short wavelength (SW) channel were recorded over the permanent ice cap to study its composition in terms of CO2 ice and H2O ice. Models are fitted to the observed data, which include a spatial mixture of soil (not covered by ice) and CO2 frost (with a specific grain size and a small amount of included dust and H2O ice). Two different kinds of spectra were observed: those over the permanent polar cap with almost pure CO2 ice, negligible water ice, no soil fraction required, and bright; and those over mixed terrain (at the edge of the cap or near troughs) containing a significant soil spatial fraction, more water ice and smaller CO2 grain size. The amount of water ice given by fits to scaled albedo models is less than 10 ppm by weight. When using multi-stream reflectance models with the appropriate lighting geometry, the water amount must be 2-5 times greater than the albedo fit (less than 50 ppm). At the periphery of the residual polar cap, we found a region almost completely covered by water frost, modeled as a mixture of micron-sized and sub-mm sized grains. Our result using a granular mixture of micron-sized grains of water ice and dust with the CO2 grains is different from the modeling of OMEGA polar cap observations using molecular mixtures. 相似文献
14.
The flow law determined experimentally for solid CO2 establishes that a hypothesis of glacial flow of CO2 at the Martian poles is not physically unrealistic. Compression experiments carried out under 1 atm pressure and constant strain rate demonstrate that the strength of CO2 near its sublimation point is considerably less than the strength of water ice near its melting point. The data fit a power law “creep” equation of the form , where ? is compressive strain rate (sec?1), σ is compressive stress (bars), R is the gas constant in calories per mole, and T is absolute temperature. The exponent of σ of 3.9 contrasts with a value near 3.1 for water ice, and indicates that the strain rate is somewhat more sensitive to stress for CO2 than for water. Likewise, the low activation energy for creep, 12 200 cal mole?1, illustrates that CO2 is not highly sensitive to temperature and is thus likely to flow over a broad range of temperatures below its melting point. Strength values for CO2 are of the order of one-tenth to one-third the strength of ice under equivalent conditions.A plausible glacial model for the Martian polar caps can be constructed and is helpful in explaining the unique character of the polar regions. CO2-rich layers deposited near the pole would have flowed outward laterally to relieve high internal shear stresses. The topography of the polar caps, the uniform layering of the layered deposits, and the general extent of the polar “sediments” could all be explained using this model. Flow of CO2 rather than water ice greatly reduces the problems with Martian glaciation. Nevertheless, problems do remain, in particular the large amounts of CO2 necessary, the need to increase vapor pressure and temperature with depth in the polar deposits, and the lack of good observational evidence of flor features. Within the limits of the present knowledge of surface conditions of Mars, CO2 glaciation appears to be a realistic alternate working hypothesis for the origin of the polar features. 相似文献
15.
Joel S. Levine 《Icarus》1976,28(2):165-169
The presence of 28% argon on Mars as calculated by Levine and Riegler and indirectly inferred from Soviet Mars-6 lander data has important implications for the outgassing history of H2O, CO2, and N2 on Mars. Even if the terrestrial volatile outgassing ratio is only approximately valid for Mars, then large quantities of H2O [of the order of 105 gcm?2 (about 108 more H2O than is currently present in the Martian atmosphere)] and about 104 gcm?2 of CO2 (about 103 times more CO2 than found at present in the Martian atmosphere) and some 450 gcm?2 of N2 may have outgassed over the history of Mars. 相似文献
16.
Robert M. Haberle Francois Forget James Schaeffer Nora J. Kelly 《Planetary and Space Science》2008,56(2):251-255
The mostly carbon dioxide (CO2) atmosphere of Mars condenses and sublimes in the polar regions, giving rise to the familiar waxing and waning of its polar caps. The signature of this seasonal CO2 cycle has been detected in surface pressure measurements from the Viking and Pathfinder landers. The amount of CO2 that condenses during fall and winter is controlled by the net polar energy loss, which is dominated by emitted infrared radiation from the cap itself. However, models of the CO2 cycle match the surface pressure data only if the emitted radiation is artificially suppressed suggesting that they are missing a heat source. Here we show that the missing heat source is the conducted energy coming from soil that contains water ice very close to the surface. The presence of ice significantly increases the thermal conductivity of the ground such that more of the solar energy absorbed at the surface during summer is conducted downward into the ground where it is stored and released back to the surface during fall and winter thereby retarding the CO2 condensation rate. The reduction in the condensation rate is very sensitive to the depth of the soil/ice interface, which our models suggest is about 8 cm in the Northern Hemisphere and 11 cm in the Southern Hemisphere. This is consistent with the detection of significant amounts of polar ground ice by the Mars Odyssey Gamma Ray Spectrometer and provides an independent means for assessing how close to the surface the ice must be. Our results also provide an accurate determination of the global annual mean size of the atmosphere and cap CO2 reservoirs, which are, respectively, 6.1 and 0.9 hPa. They also indicate that general circulation models will need to account for the effect of ground ice in their simulations of the seasonal CO2 cycle. 相似文献
17.
The recent discovery of methane on Mars has led to much discussion concerning its origin. On Earth, the isotopic signatures of methane vary with the nature of its production. Specifically, the ratios among 12CH4, 13CH4, and 12CH3D differ for biotic and abiotic origins. On Mars, measuring these ratios would provide insights into the origins of methane and measurements of water isotopologues co-released with methane would assist in testing their chemical relationship. Since 1997, we have been measuring HDO and H2O in Mars’ atmosphere and comparing their ratio to that in Earth’s oceans. We recently incorporated a line-by-line radiative transfer model (LBLRTM) into our analysis. Here, we present a map for [HDO]/[H2O] along the central meridian (154°W) for Ls=50°. From these results, we constructed models to determine the observational conditions needed to quantify the isotopic ratios of methane in Mars’ atmosphere. Current ground-based instruments lack the spectral resolution and sensitivity needed to make these measurements. Measurements of the isotopologues of methane will likely require in situ sampling. 相似文献
18.
Recent detection of methane (CH4) on Mars has generated interest in possible biological or geological sources, but the factors responsible for the reported variability are not understood. Here we explore one potential sink that might affect the seasonal cycling of CH4 on Mars - trapping in ices deposited on the surface. Our apparatus consisted of a high-vacuum chamber in which three different Mars ice analogs (water, carbon dioxide, and carbon dioxide clathrate hydrates) were deposited in the presence of CH4 gas. The ices were monitored for spectroscopic evidence of CH4 trapping using transmission Fourier-Transform Infrared (FT-IR) spectroscopy, and during subsequent sublimation of the ice films the vapor composition was measured using mass spectrometry (MS). Trapping of CH4 in water ice was confirmed at deposition temperatures <100 K which is consistent with previous work, thus validating the experimental methods. However, no trapping of CH4 was observed in the ice analogs studied at warmer temperatures (140 K for H2O and CO2 clathrate, 90 K for CO2 snow) with approximately 10 mTorr CH4 in the chamber. From experimental detection limits these results provide an upper limit of 0.02 for the atmosphere/ice trapping ratio of CH4. If it is assumed that the trapping mechanism is linear with CH4 partial pressure and can be extrapolated to Mars, this upper limit would indicate that less than 1% is expected to be trapped from the largest reported CH4 plume, and therefore does not represent a significant sink for CH4. 相似文献
19.
The evolution of the martian atmosphere with regard to its H2O inventory is influenced by thermal loss processes of H, H2, nonthermal atmospheric loss processes of H+, H2+, O, O+, CO2, and O2+ into space, as well as by chemical weathering of the surface soil. The evolution of thermal and nonthermal escape processes depend on the history of the intensity of the solar XUV radiation and the solar wind density. Thus, we use actual data from the observation of solar proxies with different ages from the Sun in Time program for reconstructing the Sun's radiation and particle environment from the present to 3.5 Gyr ago. The correlation between mass loss and X-ray surface flux of solar proxies follows a power law relationship, which indicates a solar wind density up to 1000 times higher at the beginning of the Sun's main sequence lifetime. For the study of various atmospheric escape processes we used a gas dynamic test particle model for the estimation of the pick up ion loss rates and considered pick up ion sputtering, as well as dissociative recombination. The loss of H2O from Mars over the last 3.5 Gyr was estimated to be equivalent to a global martian H2O ocean with a depth of about 12 m, which is smaller than the values reported by previous studies. If ion momentum transport, a process studied in detail by Mars Express is significant on Mars, the water loss may be enhanced by a factor of about 2. In our investigation we found that the sum of thermal and nonthermal atmospheric loss rates of H and all nonthermal escape processes of O to space are not compatible with a ratio of 2:1, and is currently close to about 20:1. Escape to space cannot therefore be the only sink for oxygen on Mars. Our results suggest that the missing oxygen (needed for the validation of the 2:1 ratio between H and O) can be explained by the incorporation into the martian surface by chemical weathering processes since the onset of intense oxidation about 2 Gyr ago. Based on the evolution of the atmosphere-surface-interaction on Mars, an overall global surface sink of about 2×1042 oxygen particles in the regolith can be expected. Because of the intense oxidation of inorganic matter, this process may have led to the formation of considerable amounts of sulfates and ferric oxides on Mars. To model this effect we consider several factors: (1) the amount of incorporated oxygen, (2) the inorganic composition of the martian soil and (3) meteoritic gardening. We show that the oxygen incorporation has also implications for the oxidant extinction depth, which is an important parameter to determine required sampling depths on Mars aimed at finding putative organic material. We found that the oxidant extinction depth is expected to lie in a range between 2 and 5 m for global mean values. 相似文献
20.
A sensitive search for SO2 in the martian atmosphere: Implications for seepage and origin of methane
Vladimir A. Krasnopolsky 《Icarus》2005,178(2):487-492
Mars was observed near the peak of the strongest SO2 band at 1364-1373 cm−1 with resolving power of 77,000 using the Texas Echelon Cross Echelle Spectrograph on the NASA Infrared Telescope Facility. The observation covered the Tharsis volcano region which may be preferable to search for SO2. The spectrum shows absorption lines of three CO2 isotopomers and three H2O isotopomers. The water vapor abundance derived from the HDO lines assuming D/H = 5.5 times the terrestrial value is 12±1.0 pr. μm, in agreement with the simultaneous MGS/TES observations of 14 pr. μm at the latitudes (50° S to 10° N) of our observation. Summing of spectral intervals at the expected positions of sixteen SO2 lines puts a 2σ upper limit on SO2 of 1 ppb. SO2 may be emitted into the martian atmosphere by seepage and is removed by three-body reactions with OH and O. The SO2 lifetime, 2 years, is longer than the global mixing time 0.5 year, so SO2 should be rather uniformly distributed across Mars. Seepage of SO2 is less than 15,000 tons per year on Mars which is smaller than the volcanic production of SO2 on the Earth by a factor of 700. Because CH4/SO2 is typically 10−4-10−3 in volcanic gases on the Earth, our results show seepage is unlikely to be the source of the recently discovered methane on Mars and therefore strengthen its biogenic origin. 相似文献