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1.
Assessing soil erosion and control factors by radiometric technique in the source region of the Yellow River,Tibetan Plateau 总被引：1，自引：0，他引：1
《Quaternary Research》2014,81(3):538-544
Measurements of 137Cs concentration in soils were made in a representative catchment to quantify erosion rates and identify the main factors involved in the erosion in the source region of the Yellow River in the Tibetan Plateau. In order to estimate erosion rates in terms of the main factors affecting soil loss, samples were collected taking into account the slope and vegetation cover along six selected transects within the Dari County catchment. The reference inventory for the area was established at a stable, well-preserved, site of small thickness (value of 2324 Bq·m− 2). All the sampling sites had been eroded and 137Cs inventories varied widely in the topsoil (14.87–25.56 Bq·kg− 1). The effective soil loss values were also highly variable (11.03–28.35 t·km− 1·yr− 1) in line with the vegetation cover change. The radiometric approach was useful in quantifying soil erosion rates and examining patterns of soil movement. 相似文献
2.
《Quaternary Science Reviews》2005,24(10-11):1217-1222
Tide gauge data at seven sites of the Permanent Service for Mean Sea Level (PSMSL), with information for relative sea-level during the past 140–200 yr, were analyzed to examine the rates and causes of the global sea-level rise (GSLR) during the twentieth century. By subtracting linear trends for relative sea-level rise during the past 100 yr from the observed data, we get the apparent GSLRs of ∼1 mm yr−1 for five sites around the Baltic Sea and Brest. The rate for San Francisco is significantly larger than this, with an optimum value ∼2 mm yr−1. The spatial difference of ∼1 mm yr−1 between these sites is reasonably explained by the recent melting of the Greenland ice sheet with an equivalent sea-level rise of ∼1 mm yr−1. The predicted relative sea-level change for this melting scenario is 0.5 mm yr−1 at sites around the Baltic Sea and Brest, and 1.5 mm yr−1 for San Francisco. The residuals between observations and predictions, ∼0.5 mm yr−1 at all sites, may be contributed by thermal expansion of seawater and/or other melting sources. These results suggest the rate of twentieth-century GSLR to be 1.5 mm yr−1. 相似文献
3.
Sediment samples (213 sites) collected from the tectonic-active continental margin, offshore southwestern Taiwan were analyzed for grain sizes, organic carbon, nitrogen and carbon isotopic composition to obtain mass accumulation rate of terrestrial organic carbon and carbon budget to evaluate fate of terrestrial organic carbon from small mountainous rivers on the continental margin offshore southwestern Taiwan. Terrestrial organic carbon accumulation rates range from 0.29 to 45.6 g C m−2 yr−1 with a total accumulation budget of 0.063 Mt yr−1, which accounts for less than 13% of total river particulate organic carbon loads exported from the adjacent rivers, the Gaoping (a.k.a., Kaoping), Erhjen and Tsengwen rivers. This low burial efficiency of terrestrial organic carbon demonstrated that a majority of river-borne particles together with organic materials was moved away from the study area.For the river-borne particles from the Gaoping river, a pair of depocenters in the upper slope flanking the Gaoping submarine canyon are the locations where the maximum TCorg accumulation rate were observed which hold up to 45% (0.016 Mt yr−1) of the calculated accumulation found in the study region. On the other hand, the occurrence of higher-fraction terrestrial organic carbon in the upper and middle Gaoping submarine canyon suggests that a majority of particulate organic carbon of the Gaoping river was transported directly into the deep-sea basin through the Gaoping submarine canyon. Our results demonstrated that active margin with narrow shelf and slope is not an efficient sink for the large amount of terrigenous organic carbon supplied by the small rivers, but, a transient environment for these river derived particles. 相似文献
4.
《Earth》2007,80(1-2):75-109
The soil's resistance to concentrated flow erosion is an important factor for predicting rill and (ephemeral) gully erosion rates. While it is often treated as a calibration parameter in process-based soil erosion models, global change studies require the estimation of erosion resistance from measurable soil properties. Several laboratory and field experiments have been conducted to determine the erosion resistance of various types of soils, but no attempts have been made hitherto to summarize all these data and to explore them for general trends. In this study, all available data on the resistance of topsoils to concentrated flow erosion in terms of channel erodibility (Kc) and critical shear stress (τcr) has been collected together with all soil and environmental properties reported in literature to affect the soil erosion resistance. Reported Kc values for cropland topsoils range between 0.002 10− 3 s m− 1 and 250 10− 3 s m− 1 (n = 470), whereas τcr values range between 0 and 15 Pa (n = 522). It is demonstrated that so far, the heterogeneity of measurement methods, the lack of standardized definitions and the shortcomings of the flow shear stress model hamper the comparability of soil erosion resistance values from different datasets. Nevertheless, combining Kc and τcr data from different datasets, a general soil erosion resistance ranking for different soil textures can be proposed. The compiled dataset also reveals that tillage practices clearly affect Kc (Kc for conventional tillage > Kc for reduced tillage > Kc for no tillage) but not τcr.It was concluded that Kc and τcr are not related to each other and that soil and macro-environmental properties affecting the foremost do not necessarily affect the latter as well and vise versa. Often Kc seems to be a more appropriate parameter than τcr to represent the differences in soil erosion resistance under various soil and environmental conditions (e.g. bulk density, moisture content, consolidation, tillage). The two parameters represent different quantities and are therefore both needed to characterize the soil's resistance to concentrated flow erosion. 相似文献
5.
Glaciers erode bedrock but are also efficient conveyors of debris supplied during a cycle of glaciation by processes other than basal erosion. In this dual capacity as both an eroding and a transporting agent lies the ambiguity of ‘glacial erosion’ as a geomorphic process, with implications for methods of measuring the removal of rock mass by glaciers in the geological past, and for interpreting what exactly the consequences have been on topography and elevation change. A global review of ～400 Quaternary glacial denudation rates estimated from five different measurement techniques provides values ranging between 10?4 and 10 mm yr?1. We investigate the causes of such wide variability by examining the respective influences of environmental setting and methodological bias. A reference frame chosen for assessing these issues is the Massif du Carlit (Pyrenees, France), where a quantified mass balance of the well preserved glacial, periglacial and paraglacial deposits was made possible by detailed geomorphological mapping and terrestrial cosmogenic nuclide dating of extant erosional and depositional landform sequences. Resulting age brackets helped to define three main episodes of ice-cap growth and decline, each characterized by a volume of debris and a mappable source area. Erosion rates were expressed in two ways: (i) as spatially averaged denudation rates (D) during the successive stages of glacial advance to the line of maximum ice extent (MIE), post-MIE ice recession, and Lateglacial cirque readvance, respectively; and (ii) as cirque-wall recession rates (R) where moraine facies criteria indicated a supraglacial provenance of debris. Results indicate low erosion (D ≈ 0.05 mm yr?1) during the ice advance phase, probably because of thin or passive ice covering the low-gradient subglacial topography that occurs just above the late Pleistocene equilibrium line altitude (2.2–2.4 km). Erosion rates peaked (D ≈ 0.6 mm yr?1 and R ≈ 2.4–4.5 mm yr?1) during the main transition to ice-free conditions, when deglacial debuttressing promoted the rapid response of freshly exposed slope systems to new equilibrium conditions in the steep crest zone. Lateglacial D- and R-values declined to 0.2–0.3 mm yr?1, with indications of spatially variable R controlled by lithology. In this environment glaciers overall behaved more as conveyors of debris supplied by supraglacial rock exposures in the mountain crest zone than as powerful modifiers of subglacial topography. This explains the widespread preservation of deep, in situ preglacial weathering profiles on relict Cenozoic land surfaces in the deglacierized part of the Eastern Pyrenees. When plotted on the global data set analyzed and discussed in the review, the East Pyrenean erosion rates stand out as being amongst the lowest on record. 相似文献
6.
In the Patía River delta, the best-developed delta on the western margin of South America, a major water diversion started in 1972. The diversion of the Patía flow to the Sanquianga River, the latter a small stream draining internal lakes from the Pacific lowlands, shifted the active delta plain from the south to the north and changed the northern estuarine system into an active delta plain. The Sanquianga Mangrove National Park, a mangrove reserve measuring 800 km2, lies in this former estuary, where major hydrologic and sedimentation changes are occurring. Overall, major environmental consequences of this discharge diversion in terms of geomorphic changes along distributary channels and ecological impacts on mangrove ecosystems are evidenced by: (1) distributary channel accretion by operating processes such as sedimentation, overbank flow, increasing width of levees, sedimentation in crevasses, interdistributary channel fill, and colonization of pioneer mangrove; (2) freshening conditions in the Sanquianga distributary channel, a hydrologic change that has shifted the upper estuarine region (salinity <1%) downstream; (3) downstream advance of freshwater vegetation, which is invading channel banks in the lower and mixing estuarine zones; (4) die-off of approximately 5200 ha of mangrove near the delta apex at Bocas de Satinga, where the highest sediment accumulation rates occur; and (5) recurrent periods of mangrove defoliation due to a worm plague. Further analyses indicate strong mangrove erosion along transgressive barrier islands on the former delta plain. Here tectonic-induced subsidence, relative sea-level rise, and sediment starving conditions due to the channel diversion, are the main causes of the observed retreating conditions of mangrove communities. Our data also indicate that the Patía River has the highest sediment load (27 × 106 t yr−1) and basin-wide sediment yield (1500 t km−2 yr−1) on the west coast of South America. Erosion rates from the Patía catchment have been more pronounced during the decades of 1970–1980 and 1990–2000, as a result of land degradation and deforestation. The high sediment and freshwater inputs into the mangrove ecosystem create additional stress (both at ongoing background levels and, occasionally, at dramatic levels), which may periodically push local environmental parameters beyond the thresholds for mangrove survival. The future environmental state of the Sanquianga Mangrove National Reserve deserves more scientific and governmental attention. 相似文献
7.
300 MW Baspa II is India’s largest private hydroelectric facility, located at the Baspa River which is an important left-hand tributary to the Sutlej River in the NW Himalaya (India). In this valley the Sangla palaeo-lake has been dammed around 8200 yr BP behind a rock-avalanche dam and Baspa II is located exactly on top of this palaeo-lake. This special location represents a very rare possibility to evaluate the short-term, river load and hydrological parameters measured during the planning and operational stages of Baspa II with the long-term parameters gained from the palaeo-lake sediments from the catchment. Sedimentological and geomorphological investigations of the lacustrine sediments have been used to reconstruct environmental changes during >2500 years of its existence. The Mid-Holocene erosion rates of the Baspa catchment estimated from the volume and duration of deposition of the exposed lake sediments are at 0.7–1.0 mm yr−1, almost identical with the modern erosion rates calculated from river gauge data from Baspa II. Several charcoal layers and charcoal pieces from the uppermost palaeo-lake levels around 5000 cal yr BP might be related to woodland clearance and they possibly represent one of the oldest evidences for human presence in the Baspa Valley during Neolithic time. 相似文献
8.
《Quaternary Science Reviews》2007,26(15-16):1951-1964
On the basis of lake-level data, the period of the Preboreal oscillation (PBO) at 11 300–11 150 cal yr BP as defined by the GRIP oxygen-isotope record appears to correspond to wetter climatic conditions in west-central Europe and to a marked drying in north-central Italy. Additional short-lived phases of higher lake level have been identified before the PBO at ca 11 450–11 400 and 11 350 cal yr BP in west-central Europe, and at ca 11 500 cal yr BP in Italy. Such multiple climatic oscillations around the PBO have been observed in various records in northwestern Europe. On the basis of various proxies, a map of changes in moisture over western Europe during the PBO indicates a mid-latitude zone between 58 and 43°N characterised by wetter conditions, while a drier climate developed in southern and northern Europe. This wet middle zone shows a larger extension and suggests a more meandering, weaker Atlantic Westerly Jet during the PBO than during the 8.2 kyr event. A comparison of lake-level records in west-central Europe with (1) outbursts from North American and north-European proglacial lakes, and (2) variations in solar activity as reflected by 14C and the 10Be records supports the hypothesis that the PBO was a response to successive meltwater pulses at 11 300, 11 250, 11 200 and 11 170 cal yr BP and to a sudden decrease in solar activity at 11 250 cal yr BP. This study points to the necessity of developing integrated multi-proxy approaches to construct more robust regional event stratigraphies, and of better documenting palaeohydrological changes in the Mediterranean area. 相似文献
9.
《Quaternary Science Reviews》2005,24(1-2):211-222
Determinations of cosmogenic 3He exposure ages and erosion rates in volcanic rocks older than a few hundred thousand years are complicated by the presence of radiogenic He in addition to the magmatic and cosmogenic He, in phenocryst minerals. However, by analysing microphenocrysts (that crystallised on or immediately prior to eruption) that have not trapped magmatic He, the three-component problem can be eliminated and accurate determinations of cosmogenic 3He made. In this study, we perform three experiments using pyroxene microphenocrysts in basaltic clasts in the Pliocene Ayacata Formation breccias, Gran Canaria, that demonstrate they are free of magmatic He. Exposure ages and erosion rates calculated from the cosmogenic 3He concentrations are combined with a geomorphological study, to produce a tentative interpretation of landscape evolution in the mountainous interior of Gran Canaria. Long-term steady-state erosion rates of 14–24 mm ka−1 are recorded from bedrock erosional surfaces on a high plateau. Headwall retreat rates for a major drainage system of 1.6 m ka−1 have been constrained from the ca 225 ka exposure age of a boulder emplaced on slopes beneath the headwall. Strath terraces and boulders in a small canyon system yield much younger exposure ages of 47–43 ka. 相似文献
10.
《Applied Geochemistry》2006,21(11):1955-1968
Elemental Hg–Au amalgamation mining practices are used widely in many developing countries resulting in significant Hg contamination of surrounding ecosystems. The authors examined for the first time Hg contamination in air, water, sediment, soil and crops in the Tongguan Au mining area, China, where elemental Hg has been used to extract Au for many years. Total gaseous Hg (TGM) concentrations in ambient air in the Tongguan area were significantly elevated compared to regional background concentrations. The average TGM concentrations in ambient air in a Au mill reached 18,000 ng m−3, which exceeds the maximum allowable occupational standard for TGM of 10,000 ng m−3 in China. Both total and methyl-Hg concentrations in stream water, stream sediment, and soil samples collected in the Tongguan area were elevated compared to methyl-Hg reported in artisanal Au mining areas in Suriname and the Amazon River basin. Total Hg concentrations in vegetable and wheat samples ranged from 42 to 640 μg kg−1, all of which significantly exceed the Chinese guidance limit for vegetables (10 μg kg−1) and foodstuffs other than fish (20 μg kg−1). Fortunately, methyl-Hg was not significantly accumulated in the crops sampled in this study, where concentrations varied from 0.2 to 7.7 μg kg−1. 相似文献
11.
《Quaternary Research》2014,81(3):445-451
Some scholars have argued that the formation and outburst of an ancient dammed lake in the Jishi Gorge at ca. 3700 cal yr BP resulted in the destruction of Lajia, the site of a famous prehistoric disaster in the Guanting Basin, upper Yellow River valley, China. However, the cause of the dammed lake and the exact age of the dam breaching are still debated. We investigated ancient landslides and evidence for the dammed lake in the Jishi Gorge, including dating of soil from the shear zone of an ancient landslide, sediments of the ancient dammed lake, and loess above lacustrine sediments using radiocarbon and optically stimulated luminescence (OSL) dating methods. Six radiocarbon dates and two OSL dates suggested that the ancient landslides and dammed lake events in the Jishi Gorge probably occurred around 8100 cal yr BP, and the ancient dammed lake was breached between 6780 cal yr BP and 5750 cal yr BP. Hence, the outburst of the ancient dammed lake in the Jishi Gorge was unrelated to the ruin of the Lajia site, but likely resulted in flood disasters in the Guanting Basin around 6500 cal yr BP. 相似文献
12.
Dissolved and particulate Zn and Ni concentrations were determined at 76 locations along the Yangtze River basin from the headwaters to the estuary during flood and dry seasons. Spatial and temporal variations of Zn and Ni were investigated and six major source zones were identified. The Three Gorges Dam (TGD) blocked most of the suspended loads and extremely low concentration of Zn and Ni were observed downstream of the dam. Dissolved (ranging from 0.062 to 8.0 μg L−1) and particulate (ranging from 12 to 110 mg kg−1) Ni showed similar levels of concentrations during flood and dry seasons, whereas dissolved (ranging from 0.43 to 49 μg L−1) and particulate (ranging from 54 to 1100 mg kg−1) Zn were slightly and much lower in the flood season than dry season, respectively. This was attributed to the increased water discharge during the flood season causing a dilution effect and sediment resuspension. In the flood season, average concentrations of Zn and Ni were higher in the main channel than in tributaries, due to soil erosion and mining activities providing the dominant inputs. The situation was opposite in the dry season, attributed to the contribution of municipal sewage, industrial activities, and waste disposal. During the flood season, dissolved Zn and Ni concentrations were negatively correlated with pH. Water and suspended particulate matter (SPM) from the upper reaches, middle reaches, and lower reaches of the Yangtze River were characterized by their Zn and Ni concentrations. The Panzhihua, Nanling and Tongling mining areas were considered as the most important source zones of particulate Zn and Ni. The Chongqing region, Wuhan region and the Yangtze River Delta provided most of the dissolved Zn and Ni inputs into the river. Annual net flux of Zn (10–72 × 105 kg a−1) and Ni (5.0–19 × 105 kg a−1) in each source zone were estimated according to their respective influent and effluent fluxes. Contributions of the source zones to Zn and Ni transport decreased from the upper reaches to the lower reaches. 相似文献
13.
The Alaknanda and Bhagirathi rivers flow through the Higher and Lesser Himalayas and confluence at Devprayag, which represents the origin of the Ganga (or Ganges) river. In the present study, a vast number of temporal and spatial samples of the river waters were collected and analyzed for major cations and anions. In addition, more recent and time series water flow data have been obtained and based on these inputs, a more refined dissolved flux rates have been estimated. The Alaknanda and Bhagirathi rivers show significant variations in chemical compositions during different seasons. Carbonate rock weathering is responsible for more than 70% of the chemical compositions in the river waters. The chemical weathering rates show seasonal variations and are much higher during non-monsoon season. The dissolved flux of Alaknanda river is much higher (1.80 × 106 tons yr?1) as compared to the Bhagirathi river (0.34 × 106 tons yr?1). The chemical weathering rates in the basin vary between 85 and 155 tons km?2 yr?1, which is significantly higher compared to the global average of ～24 tons km?2 yr?1. 相似文献
14.
《Applied Geochemistry》2006,21(10):1733-1749
The Tinto and Odiel rivers are heavily affected by acid mine drainage (AMD). However, the exact quantities of contaminants transported into the Huelva estuary and the Gulf of Cadiz are unknown. The existing previous investigations are, in general, based on studies with few data or incorrect methodology, and are therefore unreliable. This study aims to present a reliable estimation of the dissolved contaminant load transported by both rivers for the periods 1995/96 to 2002/03. The methodology used is based principally on the correlation between contaminant concentration and flow rate. The results show that both rivers transport enormous quantities of dissolved contaminants: 7900 t a−1 of Fe, 5800 t a−1 Al, 3500 t a−1 Zn, 1700 t a−1 Cu, 1600 t yr−1 Mn and minor quantities of other metals. These values represent 60% of the global gross flux of dissolved Zn transported by rivers in to the ocean, and 17% of the global gross flux of dissolved Cu. 相似文献
15.
《Gondwana Research》2014,25(2):464-493
We discuss possible scenarios of continental collision, and their relation to mechanisms of exhumation of HP and UHP rocks, inferred from thermo-mechanical numerical models accounting for thermo-rheological complexity of the continental lithosphere. Due to this complexity, mechanisms of continental convergence are versatile and different, in many aspects from those that control oceanic subduction. Elucidating these mechanisms from conventional observations is difficult, and requires additional constraints such as those derived from petrological data. Indeed, exhumation of HP/UHP rocks is an integral part of convergent processes, and burial/exhumation dynamics inferred from metamorphic P–T–t paths provides strong constraints on the collision scenarios. Metamorphic rocks also play an active role due to their contrasting physical properties (rheology, density, fluid transport capacity). Numerical thermo-mechanical experiments suggest that HP/UHP exhumation can only be produced in subduction contexts, as well as that long-lasting (> 10 Myr) continental subduction can only occur in case of cold strong lithospheres (TMoho < 550 °C, the equivalent elastic thickness Te > 50 km) and of relatively high convergence rates (> 3–5 cm yr− 1 ). In this case, high density UHP material in the crustal part of subduction interface provides additional pull on the slab and is not always exhumed to the surface. In case of slower convergence and/or weaker lithosphere (Te < 40 km), continental subduction is a transient process that takes a limited time span in the evolution of collision zone. Under these conditions, hot mechanically weak UHP rocks enhance decoupling between the upper and lower plate while their exhumation may be rapid (faster than convergence rate) and abundant. Therefore, the UHP exhumation paths can be regarded as sensitive indicators of subduction. Rheological changes and fluid exchanges associated with low-to-middle pressure phase transitions along the subduction interface, such as serpentinization during the oceanic phase and schisting, play a major role producing necessarily mechanical softening of the subduction interface and of the hydrated mantle wedge. The oceanic UHP rocks are exhumed thanks to mixing with low-density continental crustal units during transition from oceanic to continental subduction. At the continental phase, the UHP exhumation occurs as a result of a multi-stage process: at the deep stage (< 40 km depth) the exhumation is rapid and is driven by buoyancy of partly metamorphosed (or partly molten) UHP material often mixed with non-metamorphosed crustal volumes. At final stages, exhumation takes common slow path through the accretion prism mechanism and the erosional denudation. The experiments suggest that formation of UHP rocks requires that continental subduction starts at higher oceanic subduction rate. It then may progressively slow down until the lockup of the subduction interface and/or slab-break-off. A rate of ~ 1–2 cm yr− 1 is generally sufficient to drive continental subduction during the first several Myr of convergence, but pertinent subduction requires faster convergence rates (> 3–5 cm yr− 1). We suggest that most continental orogenic belts could have started their formation from continental subduction but this process has been generally limited in time. 相似文献
16.
A field experiment is being carried out at the Diavik diamond mine in northern Canada to investigate the influence of unsaturated flow behavior on the quality of drainage from mine waste rock piles in a region of continuous permafrost. This paper is part of a series describing processes affecting the weathering of waste rock and transport of reaction products at this site; here the focus is on unsaturated water flow and its role in mass loading. Two 15 m-high instrumented test piles have been built on 60 m by 50 m collection systems, each consisting of lysimeters and a large impermeable high-density polyethylene (HDPE) liner. Collection lysimeters are installed nearby to investigate infiltration in the upper 2 m of the waste rock. Porosity, water retention curves, and hydraulic conductivity functions are estimated from field measurements and for samples ranging in size from 200 cm3 to 16 m3. Net infiltration in 2007 is estimated to have been 37% of the rainfall for mean annual rainfall conditions. Early-season infiltration freezes and is remobilized as the waste rock thaws. Wetting fronts migrate at rates of 0.2–0.4 m d−1 in response to common rainfall events and up to 5 m d−1 in response to intense rainfall. Pore water and non-reactive solutes travel at rates of <10−2 to 3 × 10−2 m d−1 in response to common rainfall events and up to 0.7 m d−1 in response to intense rainfall. Time-varying SO4 mass loading from the base of the test piles is dictated primarily by the flow behavior, rather than by changes in solute concentrations. 相似文献
17.
《Applied Geochemistry》2006,21(11):1855-1867
Methylmercury (MeHg) and total Hg (THg) concentrations in soil profiles were monitored in the Thur River basin (Alsace, France), where a chlor-alkali plant has been located in the city of Vieux-Thann since the 1930s. Three soil types were studied according to their characteristics and location in the catchment: industrial soil, grassland soil and alluvial soil. Contamination of MeHg and THg in soil was important in the vicinity of the plant, especially in industrial and alluvial soil. Concentrations of MeHg reached 27 ng g−1 and 29,000 ng g−1 for THg, exceeding the predictable no effect concentration. Significant ecotoxicological risk exists in this area and remedial actions on several soil types are suggested. In each type of soil, MeHg concentrations were highest in topsoil, which decreased with depth. Concentrations of MeHg were negatively correlated with soil organic matter and total S, particularly when MeHg concentrations exceeded 8 ng g−1. Under these conditions, MeHg concentrations in soil seemed to be influenced by THg, soil organic matter and total S concentrations. It was found that high MeHg/THg ratios (near 2%) in soil were mainly related to the combined soil environmental conditions such as low THg concentrations, low organic C/N ratios (<11) and relatively low pH (5–5.5). Nevertheless, even when the MeHg/THg ratio was low (∼0.04%), MeHg and THg concentrations were elevated, up to 13 ng g−1 and to 29,000 ng g−1, respectively. Thus, both THg and MeHg concentrations should be taken into account to assess potential environmental risks of Hg. 相似文献
18.
《Quaternary Science Reviews》2007,26(22-24):2897-2912
The Late Cenozoic development of the River Tana in Kenya has been reconstructed for its central reach near its confluence with the River Mutonga, which drains the Mount Kenya region. Age control for this system has been provided by K–Ar and Ar–Ar dating. Between 3.21 and 2.65 Ma a major updoming occurred, in relation to the formation of the Kenyan rift valley. The tilting related to this doming has been reconstructed from lava flows that preserve former river gradients. Linear projection of these trends to the current rift valley rim suggests a net updoming of the eastern Gregory Rift valley by at least ∼1 km during 3.21–2.65 Ma. In contrast, since 2.65 Ma the Tana system has been mainly subject to relatively minor epeirogenic uplift. Changing climatic conditions combined with continuing uplift yielded a typical staircase of strath terraces with at least 10 distinct levels. A more detailed reconstruction of the incision rates since 215 ka has been made, by correlating mineralogically fingerprinted volcaniclastic Tana deposits with dated tephras in a lake record. These volcaniclastic sediments were deposited during glacial periods, contemporaneous with lahars. The reconstructed incision rates for the three youngest terraces are ∼0.1–0.2 mm a−1, thus considerably faster than the overall average rate of valley incision since the Mid-Pliocene, of 0.06 mm a−1. A plausible uplift history has been reconstructed using the estimated ages of the Tana terraces and marine terraces on the Indian Ocean coastline. The result suggests an increase in the rate of incision by the River Tana at ∼0.9 Ma, an observation typical in most European river terrace staircases. The reconstructed Late Quaternary development of Tana valley indicates that a similar Quaternary uplift mechanism has operated in both Europe and East Kenya, suggesting a globally applicable process. 相似文献
19.
《Applied Geochemistry》2004,19(8):1217-1232
Laboratory experiments were conducted with volcanic ash soils from Mammoth Mountain, California to examine the dependence of soil dissolution rates on pH and CO2 (in batch experiments) and on oxalate (in flow-through experiments). In all experiments, an initial period of rapid dissolution was observed followed by steady-state dissolution. A decrease in the specific surface area of the soil samples, ranging from 50% to 80%, was observed; this decrease occurred during the period of rapid, initial dissolution. Steady-state dissolution rates, normalized to specific surface areas determined at the conclusion of the batch experiments, ranged from 0.03 μmol Si m−2 h−1 at pH 2.78 in the batch experiments to 0.009 μmol Si m−2 h−1 at pH 4 in the flow-through experiments. Over the pH range of 2.78–4.0, the dissolution rates exhibited a fractional order dependence on pH of 0.47 for rates determined from H+ consumption data and 0.27 for rates determined from Si release data. Experiments at ambient and 1 atm CO2 demonstrated that dissolution rates were independent of CO2 within experimental error at both pH 2.78 and 4.0. Dissolution at pH 4.0 was enhanced by addition of 1 mM oxalate. These observations provide insight into how the rates of soil weathering may be changing in areas on the flanks of Mammoth Mountain where concentrations of soil CO2 have been elevated over the last decade. This release of magmatic CO2 has depressed the soil pH and killed all vegetation (thus possibly changing the organic acid composition). These indirect effects of CO2 may be enhancing the weathering of these volcanic ash soils but a strong direct effect of CO2 can be excluded. 相似文献
20.
Arsenic concentrations are reported for the <2 mm fraction of ca. 2200 soil samples each from agricultural (Ap horizon, 0–20 cm) and grazing land (Gr, 0–10 cm), covering western Europe at a sample density of 1 site/2500 km2. Median As concentrations in an aqua regia extraction determined by inductively coupled plasma emission mass spectrometer (ICP-MS) were 5.7 mg/kg for the Ap samples and 5.8 mg/kg for the Gr samples. The median for the total As concentration as determined by X-ray fluorescence spectrometry (XRF) was 7 mg/kg in both soil materials. Maps of the As distribution for both land-use types (Ap and Gr) show a very similar geographical distribution. The dominant feature in both maps is the southern margin of the former glacial cover seen in the form of a sharp boundary between northern and southern European As concentrations. In fact, the median As concentration in the agricultural soils of southern Europe was found to be more than 3-fold higher than in those of northern Europe (Ap: aqua regia: 2.5 vs. 8.0 mg/kg; total: 3 vs. 10 mg/kg). Most of the As anomalies on the maps can be directly linked to geology (ore occurrences, As-rich rock types). However, some features have an anthropogenic origin. The new data define the geochemical background of As in agricultural soils at the European scale. 相似文献