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1.
Due to growing concerns regarding persistent organic pollutants (POPs) in the environment, extensive studies and monitoring programs have been carried out in the last two decades to determine their concentrations in water, sediment, and more recently, in biota. An extensive review and analysis of the existing literature shows that whilst the vast majority of these efforts either attempt to compare (a) spatial changes (to identify "hot spots"), or (b) temporal changes to detect deterioration/improvement occurring in the environment, most studies could not provide sufficient statistical power to estimate concentrations of POPs in the environment and detect spatial and temporal changes. Despite various national POPs standards having been established, there has been a surprising paucity of emphasis in establishing accurate threshold concentrations that indicate potential significant threats to ecosystems and public health. Although most monitoring programs attempt to check compliance through reference to certain "environmental quality objectives", it should be pointed out that many of these established standards are typically associated with a large degree of uncertainty and rely on a large number of assumptions, some of which may be arbitrary. Non-compliance should trigger concern, so that the problem can be tracked down and rectified, but non-compliance must not be interpreted in a simplistic and mechanical way. Contaminants occurring in the physical environment may not necessarily be biologically available, and even when they are bioavailable, they may not necessarily elicit adverse biological effects at the individual or population levels. As such, we here argue that routine monitoring and reporting of abiotic and biotic POPs concentrations could be of limited use, unless such data can be related directly to the assessment of public health and ecological risks. Risk can be inferred from the ratio of predicted environmental concentration (PEC) and the predicted no effect concentration (PNEC). Currently, the paucity of data does not allow accurate estimation of PNEC, and future endeavors should therefore, be devoted to determine the threshold concentrations of POPs that can cause undesirable biological effects on sensitive receivers and important biological components in the receiving environment (e.g. keystone species, populations with high energy flow values, etc.), to enable derivation of PNECs based on solid scientific evidence and reduce uncertainty. Using the threshold body burden of POPs required to elicit damages of lysosomal integrity in the green mussel (Perna virvidis) as an example, we illustrate how measurement of POPs in body tissue could be used in predicting environmental risk in a meaningful way.  相似文献   

2.
Climate warming, one of the main features of global change, has exerted indelible impacts on the environment, among which the impact on the transport and fate of pollutants has aroused widespread concern. Persistent organic pollutants (POPs) are a class of pollutants that are transported worldwide. Determining the impact of climate warming on the global cycling of POPs is important for understanding POP cycling processes and formulating relevant environmental policies. In this review, the main research findings in this field over the past ten years are summarized and the effects of climate warming on emissions, transport, storage, degradation and toxicity of POPs are reviewed. This review also summarizes the primary POP fate models and their application. Additionally, research gaps and future research directions are identified and suggested. Under the influence of climate change, global cycling of POPs mainly shows the following responses. (1) Global warming directly promotes the secondary emission of POPs; for example, temperature rise will cause POPs to be re-released from soils and oceans, and melting glaciers and permafrost can re-release POPs into freshwater ecosystems. (2) Global extreme weather events, such as droughts and floods, result in the redistribution of POPs through intense soil erosion. (3) The changes in atmospheric circulation and ocean currents have significantly influenced the global transport of POPs. (4) Climate warming has altered marine biological productivity, which has changed the POP storage capacity of the ocean. (5) Aquatic and terrestrial food-chain structures have undergone significant changes, which could lead to amplification of POP toxicity in ecosystems. (6) Overall, warming accelerates the POP volatilization process and increases the amount of POPs in the environment, although global warming facilitates their degradation at the same time. (7) Various models have predicted the future environmental behaviors of POPs. These models are used to assist governments in comprehensively considering the impact of global warming on the environmental fate of POPs and therefore controlling POPs effectively. Future studies should focus on the synergistic effects of global changes on the cycling of POPs. Additionally, the interactions among global carbon cycling, water cycling and POP cycling will be a new research direction for better understanding the adaptation of ecosystems to climate change.  相似文献   

3.
持久性有机污染物(POPs)在环境中分布广泛且持久存在并具有高生物富集性,通常具有致癌、致畸、致突变等危害.湖泊是POPs的主要环境归宿之一,湖泊中的POPs可被水生生物富集并通过食物网传递,对生态系统及人体健康构成极大的危害.中国是POPs生产及使用大国,也是世界上湖泊较多的国家之一.湖泊生物尤其是水产品是中国人饮食中的重要组成部分,因此POPs在中国湖泊生物体中的富集对当地的生态系统和人体健康存在很大的潜在危害.本文通过收集、分析1997年—2017年7月公开发表的中国湖泊生物体POPs数据,发现中国湖泊生物中POPs富集研究主要集中在东部平原湖区,青藏高原及云贵高原湖区有少量研究;不同POPs在不同湖区湖泊生物中富集的含量存在较大差异,DDTs和HCHs在各湖区生物中普遍检出且存在明显差异,东部平原湖区生物体内多氯联苯、多溴联苯醚含量高于其他湖区生物体内含量,其他POPs在湖泊生物体内的富集研究相对较少且主要集中在东部湖泊.中国湖泊生物中DDTs、HCHs、多环芳烃、多氯联苯、多溴联苯醚、多氯苯并二英和多氯苯并呋喃、全氟化合物、全氟辛酸、有机锡及六溴环十二烷脂肪归一化后的平均含量分别为454.56±653.40、153.57±435.99、2849.49±3092.52、118.40±20.28、18.40±20.28、17.43±19.43、147.17±192.93、1542.18±1347.64、11380.75±5316.75和2.19±1.92 ng/g.POPs在中国湖泊生物体内的含量水平与生物所处营养级、脂肪含量和年龄呈正相关,但并非完全一致,还受到生活习性、生物物种与结构、生存环境及生物量等多种因素的影响;生物不同组织对POPs的富集能力有较大差异,内脏器官对POPs的富集能力明显高于肌肉组织.  相似文献   

4.
Sediment samples from the Gomti River basin were investigated to determine and evaluate trace metal concentrations,their biological effect,and potential ecological and human health risks for adults and children.The mean concentrations of trace metals were organized in the descending order of mercury(Hg)(0.08 mg/kg)>chromium(Cr)(0.06 mg/kg)>lead(Pb)(0.05 mg/kg)>arsenic(As)(0.02 mg/kg)>cadmium(Cd)(0.01 mg/kg).The current study illustrated that metals were attributed to the area from natural sources and different anthropogenic sources especially from industries.However,the concentration levels were lower than the sediment quality guidelines(SQGs)based on the effect-range classifications of threshold effect concentration(TEC)and probable effect concentration(PEC).Therefore,the concentration of the elements showed no adverse biological effects on aquatic organisms.The evaluated potential ecological risk index also revealed the low toxicity to the aquatic environment.Moreover,the applied sediment quality indices,geo-accumulation index(Igeo),contamination factor(CF),and contamination severity index(CSI)suggested that the contamination levels of the elements were in the acceptable range,and the contamination had not notably impacted on the sediment quality.The risk index(HI)concerning age groups was significantly less than the threshold limit of 1 indicating that the contamination had no non-carcinogenic risk effect.The total carcinogenic risk(TCR)was less than a risk value of 1×104.Hence,the current study suggests that immediate remediation is not required due to an absence of alarming conditions in the study area.Proper monitoring of the attribution of the metal elements should be done for the betterment of human and environmental health。  相似文献   

5.
Complexity   总被引：1，自引：0，他引：1  
It is difficult to define complexity in modeling. Complexity is often associated with uncertainty since modeling uncertainty is an intrinsically difficult task. However, modeling uncertainty does not require, necessarily, complex models, in the sense of a model requiring an unmanageable number of degrees of freedom to characterize the aquifer. The relationship between complexity, uncertainty, heterogeneity, and stochastic modeling is not simple. Aquifer models should be able to quantify the uncertainty of their predictions, which can be done using stochastic models that produce heterogeneous realizations of aquifer parameters. This is the type of complexity addressed in this article.  相似文献   

6.
The fate of linear alkylbenzenesulponates (LAS) in estuaries and coastal areas of the North Sea has been characterized with simple environmental models. The predicted concentration range in the estuaries around the North Sea (0.9-9 microg LAS l(-1)) was validated by monitoring data (1-9 microg LAS l(-1)). In offshore sites of the North Sea, it is estimated--and experimentally verified for a few sites--that the LAS concentration is below analytical detection limit (i.e., 0.5 microg LAS l(-1)). The effects of LAS on marine organisms have been reviewed. For short-term acute tests, there was no significant difference (p = 0.83) between the mean LC50 values of freshwater and marine organisms (mainly pelagic species tested, 4.1 and 4.3 mg LAS l(-1), respectively). For longer-term chronic tests, it appeared that the sensitivity (mean no-observed effect concentration (NOEC) value) of marine and freshwater organisms (0.3 and 2.3 mg LAS l(-1), respectively) was significantly different pt-test = 0.007). The predicted no-effect-concentrations (PNEC) were 360 and 31 microg LAS l(-1), for freshwater and marine pelagic communities, respectively. Given that the maximum expected estuarine and marine concentrations are 3 to > 30 times lower than the PNEC, the risk of LAS to pelagic organisms in these environments is judged to be low.  相似文献   

7.
Microplastics in the marine environment   总被引：14，自引：0，他引：14  
This review discusses the mechanisms of generation and potential impacts of microplastics in the ocean environment. Weathering degradation of plastics on the beaches results in their surface embrittlement and microcracking, yielding microparticles that are carried into water by wind or wave action. Unlike inorganic fines present in sea water, microplastics concentrate persistent organic pollutants (POPs) by partition. The relevant distribution coefficients for common POPs are several orders of magnitude in favour of the plastic medium. Consequently, the microparticles laden with high levels of POPs can be ingested by marine biota. Bioavailability and the efficiency of transfer of the ingested POPs across trophic levels are not known and the potential damage posed by these to the marine ecosystem has yet to be quantified and modelled. Given the increasing levels of plastic pollution of the oceans it is important to better understand the impact of microplastics in the ocean food web.  相似文献   

8.
《Marine pollution bulletin》2012,65(12):2756-2760
Polyethylene pellets provide a convenient means to monitor Persistent Organic Pollutants (POPs) in marine systems. Pellets collected between 1984 and 2008 at three South African beaches were analysed for PCB, HCH and DDT. Concentrations of all three POPs decreased over the last two decades, although this signal was less clear for PCBs, and further monitoring is needed to assess trends in this family of compounds. DDT concentrations at two sites were higher than previous records for southern Africa, but there is no evidence of a link to the ongoing use of DDT for malaria control. HCHs concentrations were lower than in pellets from the east coast of southern Africa, suggesting that this pesticide was mainly used in the eastern part of the region. Our study demonstrates the potential for International Pellet Watch to track temporal as well as geographical patterns in the abundance of POPs in marine environments.  相似文献   

9.
《Marine pollution bulletin》2010,60(8-12):297-310
The ecological status of an environment should be evaluated by comparison with local “reference conditions”, here defined as the pre-industrial ecological status of the 19th century. This pilot study illustrates how micropalaeontological monitoring, using benthic foraminifera (protists) and associated geochemical parameters preserved in inner Oslofjord (Norway) sediments, characterise local reference conditions. In order to optimise the usefulness of the ecological information held by foraminifera and enable characterisation of temporal changes in environmental quality beyond time intervals covered by biological time-series, the Norwegian governmental macrofauna-based classification system is applied on fossil benthic foraminiferal assemblages. Quantitative comparisons demonstrate deteriorating ecological status in response to increased anthropogenic forcing (eutrophication, micropollutants), including a 73% loss in number of foraminiferal species. Despite reduced pollution during the past decades and, at one site, capping of polluted sediments with clean clay, the reference conditions are far from re-established. Micropalaeontological monitoring requires net sediment accumulation basins and careful considerations of taphonomic processes.  相似文献   

10.
The use of artificial substrates for monitoring environmental quality and contaminant impact has been repeatedly suggested, but little information is yet available on the applicability and the sensitivity of this approach. One of the crucial points to be addressed for using artificial substrates, as tools mirroring actual benthic community state, is assessing whether, and how, they reflect in situ conditions characterising natural sediments. In this study we investigated short-term dynamics of meiofaunal colonisation on artificial substrates (bottle brushes) deployed in impacted and "pristine" (control) sites. Meiofaunal colonisation reached a threshold level after 4-6 days in both impacted and control sites but with significantly higher densities in artificial substrates deployed in the control site. Meiofaunal parameters in artificial substrates reflected those of meiofaunal assemblages inhabiting natural sediments where artificial substrates were deployed. Colonised artificial substrates were then transplanted from impacted to control sites. This caused a significant increase of meiofaunal abundance, which after 5 days reached values indistinguishable from the non-impacted control. Given the rapid colonisation time, meiofaunal sensitivity to changing environmental conditions, it can be concluded that artificial substrates can represent an useful tool to be further developed for routine and low-cost monitoring studies aiming at integrating biological indicators of environmental quality.  相似文献   

11.
In this paper, we assess the performance of the catchment model SIMulated CATchment model (SIMCAT), to predict nitrate and soluble reactive phosphorus concentrations against four monitoring regimes with different spatial and temporal sampling frequencies. The Generalised Likelihood Uncertainty Estimation (GLUE) uncertainty framework is used, along with a general sensitivity analysis to understand relative parameter sensitivity. Improvements to model calibration are explored by introducing more detailed process representation using the Integrated Catchments model (INCA) water quality model, driven by the European hydrological predictions for the environment model. The results show how targeted sampling of headwater watercourses upstream of point discharges is essential for calibrating diffuse loads and can exert a strong influence on the whole‐catchment model performance. Further downstream, if the point discharges and loads are accurately represented, then the improvement in the catchment‐scale model performance is relatively small as more calibration points are added or frequency is increased. The higher‐order, dynamic model integrated catchments model of phosphorus dynamics, which incorporates sediment and biotic interaction, resulted in improved whole‐catchment performance over SIMCAT, although there are still large epistemic uncertainties from land‐phase export coefficients and runoff. However, the very large sampling errors in routine monitoring make it difficult to invest confidence in the modelling, especially because we know phosphorous transport to be very episodic and driven by high flow conditions for which there are few samples. The environmental modelling community seems to have been stuck in this position for some time, and whilst it is useful to use an uncertainty framework to highlight these issues, it has not widely been adopted, perhaps because there is no clear mechanism to allow uncertainties to influence investment decisions. This raises the question as to whether it might better place a cost on uncertainty and use this to drive more data collection or improved models, before making investment decisions concerning, for example, mitigation strategies. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

12.
《Marine pollution bulletin》2009,58(6-12):221-235
Deriving sediment quality guidelines (SQGs) for marine sediments is a difficult task. It will often be a trade off between reproducibility and relevance. One of the fundamental questions in ecotoxicology is to decide what one should measure to detect response in ecosystems exposed to human disturbance. In this paper we use field data to estimate threshold levels eliciting effects on soft bottom macrobenthos collected at different sediment types and depths on the Norwegian Continental Shelf and test these against natural levels occurring levels in reference conditions. SQGs are presented from multivariate analyses based on 121 gradients (represented with Ba, THC, Cd, Cu, Pb and Zn) incorporating more than 2000 species. Clear clusters with slightly disturbed communities related to contamination loadings were evident in 35% of the gradients. We found large variations in naturally occurring contamination concentrations and in the threshold levels electing effects on the fauna at different sediment types and depths. For example, an increase in depth of only 100 m can triple the Cu and Zn concentrations that elicit effects. Lowest background and threshold levels were found in shallow, sandy sediment. Our results suggest that current SQGs are too high. We hypothesised that setting a SQG of 4-times background concentrations will give sufficient protection for the fauna from metal contamination. The overall background concentration eliciting effects on metal was 3.6×.  相似文献   

13.
Analyses of sediment core samples are primary sources of historical pollution trends in aquatic systems. Determining organic compounds, such as POPs, in the dated sediments enables the estimation of their temporal concentration changes and the identification of the contaminant origin in local regions. Wars, large-scale fires, economical transitions, and bans on certain chemicals are reflected in the sediment organic compound concentrations. The high POP concentrations in surficial sediments suggest that these chemicals, even after being banned, remain in the environment. Furthermore, vertical profiles can help in understanding the sedimentation process and in estimating effective countermeasures against pollution. Moreover, studies published during the period 1991–2013 on PAHs, PCBs, OCPs, dioxins and dioxin-like compound concentrations in sediment core samples are reviewed.  相似文献   

14.
Rivers respond to environmental changes such as climate shifts, land use changes and the construction of hydro‐power dams in a variety of ways. Often there are multiple potential responses to any given change. Traditionally, potential stream channel response has been assessed using simple, qualitative frameworks based largely on professional judgement and field experience, or using some form of regime theory. Regime theory represents an attempt to use a physically based approach to predict the configuration of stable channels that can transport the imposed sediment supply with the available discharge. We review the development of regime theory, and then present a specific regime model that we have created as a stand‐alone computer program, called the UBC Regime Model (UBCRM). UBCRM differs from other regime models in that it constrains its predictions using a bank stability criterion, as well as a pattern stability criterion; it predicts both the stable channel cross‐sectional dimensions as well as the number of anabranches that the stream must have in order to establish a stable channel pattern. UBCRM also differs from other models in that it can be used in a stochastic modelling mode that translates uncertainty in the input variables into uncertainty in the predicted channel characteristics. However, since regime models are fundamentally based on the concept of grade, there are circumstances in which the model does not perform well. We explore the strengths and weaknesses of the UBCRM in this paper, and we attempt to illustrate how the UBCRM can be used to augment the existing qualitative frameworks, and to help guide professionals in their assessments. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

15.
For transitional and coastal waters the Water Framework Directive identifies 5 "General chemical and physiochemical elements supporting the biological elements". The five elements are transparency, thermal conditions, oxygenation conditions, salinity and nutrient conditions. "Supporting" in the context of the directive means that the values of the physicochemical quality elements are such as to support a biological community of a certain ecological status, recognising the fact that biological communities are products of their physical and chemical environment. Physicochemical and hydromophological aspects fundamentally determine the type of water body and habitat, and hence the type specific biological community. The directive does not intended that these supporting elements should be used as surrogates for the biological elements in monitoring. The monitoring and assessment of the physical and physicochemical quality elements will support the interpretation, assessment and classification of the results arising from the monitoring of the biological quality elements. This paper considers the challenges involved in the development of oxygen standards for the directive, their relationship to the biological elements and normative conditions of the directive and to regulatory requirements.  相似文献   

16.
《Marine pollution bulletin》2009,58(6-12):245-249
The exposure time is a variable which is usually not incorporated into models for toxicity. However, with persistent organic pollutants (POPs) exhibiting a nonspecific mode of action and lipophilic properties this variable can be modeled by the usage of the internal concentrations as a measure of the toxicity with fish. The bioconcentration process with fish is a relatively well understood and predictable process which allows the calculation of the internal lethal concentration. When the exposure time is relatively short the critical internal lethal concentrations are relatively constant for the group of POPs whereaas the LC50 measured in the ambient water is quite variable. When the exposure time is relatively long, results on the measurement of the critical internal concentration with fish over different exposure times has demonstrated that the internal lethal concentration falls with increasing exposure times in a consistent and predictable manner. This reduction in life expectancy can be described in a model which can be used to estimate the critical internal concentration for any exposure time. It also provides information useful in assessing the risk to fish and potentially other species due to the occurrence of residues of POPs in natural aquatic systems. It is suggested that these relationships can be extended to other groups of organisms and chemicals.  相似文献   

17.
The occurrence of biomarker variations linked to environmental factors makes it difficult to distinguish the effect of pollution. In an attempt to evaluate spatial and seasonal effects of environmental parameters on biomarker responses, mussels Mytilus edulis chilensis coming from an aquaculture farm were transplanted to several points within Ushuaia Bay (Beagle Channel) for 6 weeks in summer and winter. Activities of superoxide dismutase, catalase, glutathione-S-transferase and levels of lipid peroxidation were measured in gills and digestive gland. Cu, Zn, Fe, Cd and Pb concentrations were also assessed. Results indicated a significant effect of seasons on biological responses as well as in metal bioaccumulation showing the influence of natural factors such as dissolved oxygen, temperature and food availability. The interdependence of those environmental factors is important for the homeostasis of thermoconformers, especially regarding their oxidative metabolism and should also be taken into consideration to distinguish natural from pollution-induced variations.  相似文献   

18.
保护地震监测环境与经济建设快速发展的思考   总被引：1，自引：0，他引：1  
随着经济的发展,地震观测环境受到的干扰越来越严重。本文阐述了山东地区地震监测环境的现状,引述了山东省在经济建设中地震监测环境受到影响和破坏的实例,分析了产生的原因,结合山东省地震监测环境保护的实例探讨依法保护的意义,通过郯城地震台等监测环境保护实践活动,认识到法律、法规是地震监测环境得到保护的重要保障;阐述了依靠当地政府及其管理部门共同做好地震监测环境保护工作的必要性,并认为,应从加强县级地震机构建设及合理规划地震监测台网等方面入手,加强对地震监测环境的保护。进而提出了实现经济建设发展和保护地震监测环境矛盾统一的构想。地震台站工作人员要加强法律、法规的学习和运用,担负起地震台站监测环境保护的任务。同时,针对遇到的问题,提出了一些工作对策和建议。  相似文献   

19.
The exposure time is a variable which is usually not incorporated into models for toxicity. However, with persistent organic pollutants (POPs) exhibiting a nonspecific mode of action and lipophilic properties this variable can be modeled by the usage of the internal concentrations as a measure of the toxicity with fish. The bioconcentration process with fish is a relatively well understood and predictable process which allows the calculation of the internal lethal concentration. When the exposure time is relatively short the critical internal lethal concentrations are relatively constant for the group of POPs whereaas the LC50 measured in the ambient water is quite variable. When the exposure time is relatively long, results on the measurement of the critical internal concentration with fish over different exposure times has demonstrated that the internal lethal concentration falls with increasing exposure times in a consistent and predictable manner. This reduction in life expectancy can be described in a model which can be used to estimate the critical internal concentration for any exposure time. It also provides information useful in assessing the risk to fish and potentially other species due to the occurrence of residues of POPs in natural aquatic systems. It is suggested that these relationships can be extended to other groups of organisms and chemicals.  相似文献   

20.
The objective of this study was to determine the concentrations and possible sources of heavy metals and persistent organic pollutants (POPs) in water and estuarine sediments from Gao-ping River in order to evaluate the environmental quality of aquatic system in southern Taiwan. High concentrations of heavy metals including Cr, Zn, Ni, Cu and As, ranging from 10.7 to 180 mg/kg-dry weight (dw), were detected in sediments from Gao-ping River. When normalized to the principal component analysis (PCA), swinery and electroplating wastewaters were found to be the most important pollution sources for heavy metals. Of various organochlorine pesticide (OCP) residues detected, aldrin and total-hexachlorocyclohexane (HCH) were frequently found in sediments. The total concentrations of OCPs were in the range 0.47-47.4 ng/g-dw. Also, the total-HCH, total-cyclodiene, and total-dichlorodiphenyltrichloroethane (DDT) were in the range 0.37-36.3, 0.21-19.0, and 0.44-1.88 ng/g-dw, respectively. The polychlorinated biphenyl (PCB) concentrations in sediments from Gao-ping River ranged between 0.37 and 5.89 ng/g-dw. The PCB concentrations are positively correlated to the organic contents of the sediment particles. alpha-HCH was found to be the dominant compound of HCH in the sediments, showing that long-range transport may be the possible source for the contamination of HCH in sediments from Gao-ping River. In summary, trace amounts of POPs in estuarine sediments from Gao-ping River were detected, showing that there still exist a wide variety of POP residues in the river sediments in Taiwan. These POP residues may be mainly from long-range transport and weathered agricultural soils, while heavy metal contamination is primarily from the swinery and industrial wastewaters.  相似文献   

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