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1.
Tertiary volcanic rocks from the Westerwald region range frombasanites and alkali basalts to trachytes, whereas lavas fromthe margin of the Vogelsberg volcanic field consist of morealkaline basanites and alkali basalts. Heavy rare earth elementfractionation indicates that the primitive Westerwald magmasprobably represent melts of garnet peridotite. The Vogelsbergmelts formed in the spinel–garnet peridotite transitionregion with residual amphibole for some magmas suggesting meltingof relatively cold mantle. Assimilation of lower-crustal rocksand fractional crystallization altered the composition of lavasfrom the Westerwald and Vogelsberg region significantly. Thecontaminating lower crust beneath the Rhenish Massif has a differentisotopic composition from the lower continental crust beneaththe Hessian Depression and Vogelsberg, implying a compositionalboundary between the two crustal domains. The mantle sourceof the lavas from the Rhenish Massif has higher 206Pb/204Pband 87Sr/86Sr than the mantle source beneath the Vogelsbergand Hessian Depression. The 30–20 Ma volcanism of theWesterwald apparently had the same mantle source as the QuaternaryEifel lavas, suggesting that the magmas probably formed in apulsing mantle plume with a maximum excess temperature of 100°Cbeneath the Rhenish Massif. The relatively shallow melting ofamphibole-bearing peridotite beneath the Vogelsberg and HessianDepression may indicate an origin from a metasomatized portionof the thermal boundary layer. KEY WORDS: continental rift volcanism; basanites; trachytes; assimilation; fractional crystallization; partial melting  相似文献   

2.
Process identification diagrams based on trace element data show that mafic lavas from Tubuai, including alkali basalts, basanites, analcitites and nephelinites, result from different degrees of partial melting of an isotopically homogeneous mantle source. Our fractionation-corrected data are consistent with a batch melting model or a dynamic melting model involving a threshold value for melt separation close to 1% and degrees of melting ranging from 5–8% (alkali basalts) to 1.5–3% (nephelinites). The relative source concentration pattern, calculated using an inverse numerical method, shows an enrichment in highly incompatible elements. We propose that the Tubuai lava suite was derived from a two-stage partial melting process. Melting first affected the plume material located within the transition zone between garnet and spinel domains, producing alkali basalts and basanites. Then, the melting zone migrated upwards to the base of the overlying spinel-bearing lithospheric mantle, producing highly silica-undersaturated lavas. The lower lithosphere had previously been enriched by intrusion of pyroxenite veins representing plume-derived melts which percolated away from the main magma conduits. Received: 11 June 1996 / Accepted: 8 January 1997  相似文献   

3.
The Pb isotope compositions of amphiboles and clinopyroxenesin spinel peridotite and pyroxenite mantle xenoliths from theintra-plate Quaternary volcanic fields of the Eifel province(Germany) are strongly correlated with their Sr–Nd isotopeand trace element compositions. High-temperature anhydrous xenolithsfrom a depth of around 60 km have trace element and Sr–Nd–Pbisotope compositions similar to the depleted source of mid-oceanridge basalts (Depleted MORB Mantle, DMM). Amphibole-bearingxenoliths from shallower depths (<45 km) provide evidencefor three temporally distinct episodes of mantle metasomatismin the subcontinental lithosphere: (1) aqueous fluids from anisotopically enriched (EM-like) mantle reservoir caused amphiboleformation during deformation in the shallow continental lithosphericmantle and may be subduction related, probably associated withthe last major tectonic event that influenced the area (Hercynianorogeny). (2) During a second phase of mantle metasomatism theEM-like lithospheric mantle was affected by melts from an ancient,HIMU-like (high time-integrated µ = 238U/204Pb) mantlesource. The HIMU-like component introduced by these fluids hada much more radiogenic Pb isotope composition than the asthenosphericsource of the widespread Cenozoic magmatism in Europe and maybe linked to reactivation of ancient subducted crustal domainsduring the Hercynian orogeny or to early Cretaceous deep-sourcedmantle plumes. (3) During a brief final stage the heterogeneouslyenriched EM–HIMU subcontinental lithosphere was locallymodified by basaltic melts migrating along fractures and veinsthrough the upper mantle as a consequence of the Cenozoic Eifelvolcanism. Although a DMM component is completely lacking inthe metasomatic fluids of the metasomatic episodes 1 and 2,the vein melts of episode 3 and the Cenozoic Eifel lavas requiremantle sources containing three end-member components (DMM–HIMU–EM).Thus, mobilization of the more depleted mantle material occurredat the earliest in the Tertiary, contemporaneously with thedevelopment of the extensive rift system and main melt generationin Europe. Alternatively, the variety of Sr–Nd–Pbisotope signatures of the metasomatic agents may have been producedby melting of isotopically distinct mantle domains in a heterogeneousuprising mantle plume. KEY WORDS: Eifel; Europe; mantle xenoliths; metasomatism; Pb isotopes  相似文献   

4.
Major and trace element and Sr–Nd–Pb isotopic datafor mafic volcanic rocks are used to assess the number of mantleplumes contributing to the Tertiary–Holocene magmatismof the Kenya Rift Valley, current estimates of which vary fromnone to three. Rocks ranging in composition from nepheliniteto hypersthene-normative basalt have been sampled from threelithospheric zones: the Tanzanian craton, the craton marginreworked during the late Proterozoic, and the Mozambique mobilebelt. The magmas are interpreted as the products of variabledegrees of partial melting within the spinel–garnet peridotitetransition zone. Trace element and isotopic compositions fromall three zones are broadly similar to those of oceanic islandbasalts, but there is considerable compositional variation,which is related to a strong overprint from the lithosphereon plume-derived melts. Sr and Nd isotopic ratios provide theonly clear distinction between magmatic rocks from the threelithospheric domains. Within each setting, mafic magmatism hastended to become less silica undersaturated with time, and atany one locality magmatism has migrated towards the centre ofthe rift. Magmas may have formed as a result of the infiltrationof plume-derived melts into the base of the lithosphere. Theextent of interaction of inferred plume melts with the lithospherehas not varied systematically in time or space. The plume componentappears to be similar to the source of oceanic island basalts. KEY WORDS: Kenya Rift Valley; mantle plumes; geochemistry; metasomatism  相似文献   

5.
Layers of Ca-rich garnet–clinopyroxene rocks enclosedin a serpentinite body at Hujialin, in the Su–Lu terraneof eastern China, preserve igneous textures, relict spinel ingarnet, and exsolution lamellae of Ca-rich garnet, ilmenite/magnetite,Fe-rich spinel, and also amphibole in clinopyroxene. In termsof their major and trace element compositions, the studied samplesform a trend from arc cumulates towards Fe–Ti gabbros.Reconstructed augite compositions plot on the trend for clinopyroxenein arc cumulates. These data suggest that the rocks crystallizedfrom mantle-derived magmas differentiated to various extentsbeneath an arc. The Ca-rich garnet + diopside assemblage isinferred to have formed by compressing Ca-rich augite, whereasthe relatively Mg-rich cores of garnet porphyroblasts may haveformed at the expense of spinel. The protolith cumulates weresubducted from near the crust–mantle boundary (c. 1 GPa)deep into the upper mantle (4·8 ± 0·6 GPaand 750 ± 50°C). Negatively sloped P–T pathsfor the garnet–clinopyroxene rocks and the corollary ofcorner flow induced subduction of mantle wedge peridotite arenot supported by the available data. Cooling with, or without,decompression of the cumulates after the igneous stage probablyoccurred prior to deep subduction. KEY WORDS: arc cumulates; Ca-rich garnet; garnet–clinopyroxene rocks; Su–Lu terrane; UHP metamorphism  相似文献   

6.
Compositionally, high-Nb basalts are similar to HIMU (high U/Pb) ocean island basalts, continental alkaline basalts and alkaline lavas formed above slab windows. Tertiary alkaline basaltic lavas from eastern Jamaica, West Indies, known as the Halberstadt Volcanic Formation have compositions similar to high-Nb basalts (Nb > 20 ppm). The Halberstadt high-Nb basalts are divided into two compositional sub-groups where Group 1 lavas have more enriched incompatible element concentrations relative to Group 2. Both groups are derived from isotopically different spinel peridotite mantle source regions, which both require garnet and amphibole as metasomatic residual phases. The Halberstadt geochemistry demonstrates that the lavas cannot be derived by partial melting of lower crustal ultramafic complexes, metasomatised mantle lithosphere, subducting slabs, continental crust, mantle plume source regions or an upper mantle source region composed of enriched and depleted components. Instead, their composition, particularly the negative Ce anomalies, the high Th/Nb ratios and the similar isotopic ratios to nearby adakite lavas, suggests that the Halberstadt magmas are derived from a compositionally variable spinel peridotite source region(s) metasomatised by slab melts that precipitated garnet, amphibole, apatite and zircon. It is suggested that high-Nb basalts may be classified as a distinct rock type with Nb > 20 ppm, intraplate alkaline basalt compositions, but that are generated in subduction zones by magmatic processes distinct from those that generate other intraplate lavas.  相似文献   

7.
BECKER  HARRY 《Journal of Petrology》1996,37(4):785-810
Gamet-bearing high-temperature peridotite massifs in lower Austriawere exhumed during Carboniferous plate convergence in the Bohemianmassif. The peridotite massifs contain garnet pyroxenite layers,most of which are high-pressure cumulates that crystallizedin the deep lithosphere during ascent and cooling of hot asthenosphericmelts. Many of the pyroxenites have negative Eu anomalies andhigh LREE abundances in pyroxenes and bulk rocks, 87Sr/86Sr(335 Ma) as high as 0.7089, and Nd (335 Ma) as low as –4.8(leached clinopyroxenes and garnets). These pyroxenites alsoshow strong depletions in Rb, K, Ta, P and Ti compared withthe REE Equilibrium melt compositions calculated from the cumulatecompositions have very high LREE abundances (Lan = 300–600)and show strong LREEfractionation [(La/Sm)n = 7–47)].Trace element abundances, the Ca–Al-rich composition ofthe cumulates and possible Ti saturation in the melts suggestthat these melts were of primitive carbonatitic–meliliticor lamprophyrt-like composition. Other garnet pyroxenites suchas Al-rich garnet-kyanite clinopyroxemtes with positive Eu anomaliesprobably represent metamorphosed crustal rocks which were subductedand accreted to the lithospheric mantle. The high 87Sr/86Sr,low Nd (335 Ma) and negative Eu anomalies of the high-pressurecumulates can be explained if their equilibrium melts containeda component derived from subducted upper-crustal rocks. Thehigh equilibration pressures of the host peridotites (3–3.5GPa) and the high equilibration temperatures of the pyroxenites(1100–1400C) indicate that these melts are likely tobe derived from the sub-lithospheric mantle. There, meltingmay have been triggered by small amounts of melt or fluids derivedfrom a subducting slab at greater depth. KEY WORDS: garnet pyroxenites; geochemistry; lower Austria; ultramafic massifs; subduction  相似文献   

8.
We present the first data on the petrology of the mantle lithosphereof the Southeastern (SE) Slave craton, Canada. These are basedon petrographic, mineralogical and geochemical studies of mantlexenoliths in Pipe 5034 of the Cambrian Gahcho Kué kimberlitecluster. Major types of mantle xenoliths include altered eclogite,coarse garnet or spinel peridotite, and deformed garnet peridotite.The peridotites belong to the low-temperature suite and formedat T=600–1300°C and P= 25–80 kbar in a thick(at least 220–250 km), cool lithosphere. The SE Slavemantle is cooler than the mantle of other Archaean cratons andthat below other terranes of the Slave craton. The thick lithosphereand the relatively cool thermal regime provide favourable conditionsfor formation and preservation of diamonds beneath the SE Slaveterrane. Similar to average Archaean mantle worldwide, the SESlave peridotite is depleted in magmaphile major elements andcontains olivine with forsterite content of 91–93·5.With respect to olivine composition and mode, all terranes ofthe Slave mantle show broadly similar compositions and are relativelyorthopyroxene-poor compared with those of the Kaapvaal and Siberiancratons. The SE Slave spinel peridotite is poorer in Al, Caand Fe, and richer in Mg than deeper garnet peridotite. Thegreater chemical depletion of the shallow upper mantle is typicalof all terranes of the Slave craton and may be common for thesubcontinental lithospheric peridotitic mantle in general. Peridotiticxenoliths of the SE Slave craton were impregnated by kimberliticfluids that caused late-stage recrystallization of primary clinopyroxene,spinel, olivine and spinel-facies orthopyroxene, and formationof interstitial clinopyroxene. This kimberlite-related recrystallizationdepleted primary pyroxenes and spinel in Al. The kimberliticfluid was oxidizing, Ti-, Fe- and K-rich, and Na-poor, and introducedserpentine, chlorite, phlogopite and spinel into peridotitesat P < 35 kbar. KEY WORDS: kimberlite xenolith; lithosphere; mantle terrane; chemical zoning; thermobarometry; Slave craton  相似文献   

9.
A geochemical and petrological study of Miocene to recent alkalibasalts, basanites, hawaiites, mugearites, trachytes, and phonoliteserupted within the Harrat Ash Shamah volcanic field was performedto reconstruct the magmatic evolution of southern Syria. Themajor element composition of the investigated lavas is mainlycontrolled by fractional crystallization of olivine, clinopyroxene,± Fe–Ti oxides and ± apatite; feldspar fractionationis restricted to the most evolved lavas. Na2O and SiO2 variationswithin uncontaminated, primitive lavas as well as variably fractionatedheavy rare earth element ratios suggest a formation by variabledegrees of partial melting of different garnet peridotite sourcestriggered, probably, by changes in mantle temperature. The isotopicrange as well as the variable trace element enrichment observedin the lavas imply derivation from both a volatile- and incompatibleelement-enriched asthenosphere and from a plume component. Inaddition, some lavas have been affected by crustal contamination.This effect is most prominent in evolved lavas older than 3·5Ma, which assimilated 30–40% of crustal material. In general,the periodicity of volcanism in conjunction with temporal changesin lava composition and melting regime suggest that the Syrianvolcanism was triggered by a pulsing mantle plume located underneathnorthwestern Arabia. KEY WORDS: 40Ar/39Ar ages; intraplate volcanism; mantle plume; partial melting; Syria  相似文献   

10.
Major element, trace element and Sr–Nd–Pb isotopiccompositions of ultramafic xenoliths and megacrysts from thecontinental Cameroon line provide evidence for metasomatismof the upper most lithospheric mantle by enriched melts duringthe Mesozoic The megacrysts probably crystallized within thelower continental crust from melts similar to the host magmas.All the xenoliths originated as depleted residues after theextraction of basaltic melts, but some indicate evidence ofinteraction with enriched partial melts before entrainment.The U–Pb isotopic data on garnet are consistent with coolingthrough >900C at >300 Ma. The Sm–Nd isotope systematicsin constituent phases appear to have been in equilibrium ona xenolith scale at the time of entrainment, indicating derivationfrom mantle that remained at temperatures >600C until eruption.Spinel therzolies that show simple light rare earth element(LREE) depletions are characterized by isotopic compositionsthat are comparable with, but slightly more depleted than AtlanticN-MORB, suggesting that the unmetasomatized sub-continentallithosphere of the Cameroon line may be isotopically similarto that of sub-oceanic lithosphere. The Nd-depleted mantle modelages of these xenoliths are consistent with late Proterozoicdepletion, similar in age to much of the overlying continentalcrust. In contrast, samples that have LREE-enriched clinopyr-oxenes(La/Yb =4.7–9.4) contain trace amounts of amphibole, areenriched in U and have more radiogenic Pb and Sr. These xenolithsyield U–Pb and Sm–Nd model ages consistent withMesozoic enrichment, in agreement with the age of enrichmentof the source regions of the basalts, as deduced from Pb isotopiccompositions. Clinopyroxenes record three orders of magnitudeenrichment in U and LREE accompanied by progressive K depletionassociated with the growth of trace amphibole, with K/U ratiosthat range from 12000 to 1. The ratios of the trace elementsthought to have similar bulk D in mantle melting, Ce/Pb, Ba/Rband Nd/Sr ratios, display regional variations related to thetime integrated history of enrichments indicated by Nd isotopiccompositions. Mass balance calculations suggest that the meltsresponsible for the most recent enrichment of the lithospherehad higher La/Yb and U/Pb than Cameroon line host magmas, andwere probably the product of small degrees of partial meltingassociated with the earliest stages of the breakup of Pangea. KEY WORDS: Cameroon line; mantle xenoliths; megacrysts; REE; isotopic composition; trace element  相似文献   

11.
New evidence for ultrahigh‐pressure metamorphism (UHPM) in the Eastern Alps is reported from garnet‐bearing ultramafic rocks from the Pohorje Mountains in Slovenia. The garnet peridotites are closely associated with UHP kyanite eclogites. These rocks belong to the Lower Central Austroalpine basement unit of the Eastern Alps, exposed in the proximity of the Periadriatic fault. Ultramafic rocks have experienced a complex metamorphic history. On the basis of petrochemical data, garnet peridotites could have been derived from depleted mantle rocks that were subsequently metasomatized by melts and/or fluids either in the plagioclase‐peridotite or the spinel‐peridotite field. At least four stages of recrystallization have been identified in the garnet peridotites based on an analysis of reaction textures and mineral compositions. Stage I was most probably a spinel peridotite stage, as inferred from the presence of chromian spinel and aluminous pyroxenes. Stage II is a UHPM stage defined by the assemblage garnet + olivine + low‐Al orthopyroxene + clinopyroxene + Cr‐spinel. Garnet formed as exsolutions from clinopyroxene, coronas around Cr‐spinel, and porphyroblasts. Stage III is a decompression stage, manifested by the formation of kelyphitic rims of high‐Al orthopyroxene, aluminous spinel, diopside and pargasitic hornblende replacing garnet. Stage IV is represented by the formation of tremolitic amphibole, chlorite, serpentine and talc. Geothermobarometric calculations using (i) garnet‐olivine and garnet‐orthopyroxene Fe‐Mg exchange thermometers and (ii) the Al‐in‐orthopyroxene barometer indicate that the peak of metamorphism (stage II) occurred at conditions of around 900 °C and 4 GPa. These results suggest that garnet peridotites in the Pohorje Mountains experienced UHPM during the Cretaceous orogeny. We propose that UHPM resulted from deep subduction of continental crust, which incorporated mantle peridotites from the upper plate, in an intracontinental subduction zone. Sinking of the overlying mantle and lower crustal wedge into the asthenosphere (slab extraction) caused the main stage of unroofing of the UHP rocks during the Upper Cretaceous. Final exhumation was achieved by Miocene extensional core complex formation.  相似文献   

12.
Seven alkali basalt centers in the southern Canadian Cordilleracontain mantle xenolith suites that comprise spinel Cr-diopsideperidotites, spinel augite-bearing wehrlites and orthopyroxene-poorlherzolites, and minor pyroxenites. The Cr-diopside peridotitesappear to be residues of the extraction of Mg-rich basalts byup to 15% partial melting (median 5–10%) of a pyrolite-likesource in the spinel stability field. The xenoliths are similarto other mantle xenolith suites derived from beneath convergentcontinental margins, but are less depleted, less oxidized, andhave lower spinel mg-number than peridotites found in fore-arcsettings. Their dominant high field strength element depletedcharacter, however, is typical of arc lavas, and may suggestthat fluids or melts circulating through the Canadian Cordilleralithosphere were subduction related. Modeling using MELTS isconsistent with the augite-bearing xenoliths being formed byinteraction between crystallizing alkaline melts and peridotite.Assimilation–fractional crystallization modeling suggeststhat the trace element patterns of liquids in equilibrium withthe augite xenoliths may represent the initial melts that reactedwith the peridotite. Moreover, the compositions of these meltsare similar to those of some glasses observed in the mantlexenoliths. Melt–rock interaction may thus be a viablemechanism for the formation of Si- and alkali-rich glass inperidotites. KEY WORDS: Canadian Cordillera; mantle xenolith; peridotite; wehrlite; melt–rock reaction  相似文献   

13.
Amphibole pyroxenites with or without garnet and amphibolites (hydrous facies) which occur in the Lherz outcrop form monofacies or composite dykes cutting the primary schistosity of the spinel lherzolite. They coexist with monofacies or composite dykes of amphibole — free pyroxenites, with or without garnet (anhydrous facies), which are folded with the peridotite. The range of compositions, from olivine tholeiite (anhydrous facies only) to olivine basanites and nephelinites (hydrous facies) signifies a peculiar differenciation which could result from 1) fractionations closely controled by variation of the PH2O/Pt in liquids derived from partial melting of a peridotite originally containing a small amount of water. 2) tectonic features of the emplacement of the ultrabasic body up to the lower levels of the crust, during which residual liquids, increasingly undersatured and enriched in alkalies and titanium, have been segregated. The result of such a process is the formation of rocks (amphibolites) having a chemical composition close to that of some olivine melilitic nephelinites flows.  相似文献   

14.
Experimental Constraints on the Origin of the 1991 Pinatubo Dacite   总被引:12,自引:2,他引:12  
Crystallization (dacite) and interaction (dacite–peridotite)experiments have been performed on the 1991 Pinatubo dacite(Luzon Island, Philippines) to constrain its petrogenesis. Inthe dacite–H2O system at 960 MPa, magnetite and eitherclinopyroxene (low H2O) or amphibole (high H2O) are the liquidusphases. No garnet is observed at this pressure. Dacite–peridotite interaction at 920 MPa produces massive orthopyroxenecrystallization, in addition to amphibole ± phlogopite.Amphibole crystallizing in dacite at 960 MPa has the same compositionas the aluminium-rich hornblende preserved in the cores of amphibolephenocrysts in the 1991 dacite, suggesting a high-pressure stageof dacite crystallization with high melt H2O contents (>10wt %) at relatively low temperature (<950°C). The compositionsof plagioclase, amphibole and melt inclusion suggest that thePinatubo dacite was water-rich, oxidized and not much hotterthan 900°C, when emplaced into the shallow magma reservoirin which most phenocrysts precipitated before the onset of the1991 eruption. The LREE-enriched REE pattern of the whole-rockdacite demands garnet somewhere during its petrogenesis, whichin turn suggests high-pressure derivation. Partial melting ofsubducted oceanic crust yields melts unlike the Pinatubo dacite.Interaction of these slab melts with sub-arc peridotite is unableto produce a Pinatubo type of dacite, nor is a direct mantleorigin conceivable on the basis of our peridotite–daciteinteraction experimental results. Dehydration melting of underplatedbasalts requires unrealistically high temperatures and doesnot yield dacite with the low FeO/MgO, and high H2O, Ni andCr contents typical of the Pinatubo dacite. The most plausibleorigin of the Pinatubo dacite is via high-pressure fractionationof a hydrous, oxidized, primitive basalt that crystallized amphiboleand garnet upon cooling. Dacite melts produced in this way weredirectly expelled from the uppermost mantle or lower crust toshallow-level reservoirs from which they erupted occasionally.Magmas such as the Pinatubo dacite may provide evidence forthe existence of particularly H2O-rich conditions in the sub-arcmantle wedge rather than the melting of the young, hot subductingoceanic plate. KEY WORDS: Pinatubo dacite; slab melt; experimental petrology; arc magmas  相似文献   

15.
The Ueno Basalts of central Japan comprise a monogenetic volcaniccone complex that was active between 2·76 and 1·34Ma. Basalts were erupted at more than 14 centers scattered overa region 40 km in diameter. Alkali basalt was erupted first,followed by sub-alkaline basalt. Quasi-concentric expansionof eruption centers coinciding with uplift and with decreasingalkalinity of the lavas suggests that Ueno magmatism originatedfrom a mantle diapir as it mushroomed at the base of the lithosphere.Depleted asthenospheric mantle (alkali basalt), enriched lithosphericmantle (sub-alkaline basalt), and crustal components are identifiedas chemical end-members in the petrogenesis of the Ueno Basalts.Incompatible trace element abundances indicate that the Uenoalkali basalts are typical within-plate basalts, whereas thesub-alkaline basalts show strong affinities with normal arclavas. Sr–Nd–Pb isotopic compositions indicate thatthe mantle source of the alkali basalts was more depleted thanthat of the sub-alkaline basalts. About 7% melting of asthenosphericmantle in the garnet-lherzolite stability field produced theprimitive alkali basalts and 12% melting of spinel lherzolitewithin the subcontinental lithosphere produced the primitivesub-alkaline basalts. Isotopic compositions and fluid mobile/immobileelement ratios broadly covary with SiO2 contents in the sub-alkalinesuite, and increasing silica content is associated with strongerEMII (Enriched Mantle II) isotope affinities and fluid mobileelement abundances. A progressive AFC (assimilation–fractionalcrystallization) model assuming assimilation of a low-K silicicmelt reproduces the chemical variations observed in the sub-alkalinesuite. Melting of a flattening mantle diapir at the base ofthe lithosphere is the dominant cause of Ueno magmatism, accompaniedby the assimilation of older arc crust. KEY WORDS: arc basalt; crustal assimilation; mantle heterogeneity; Ueno Basalts  相似文献   

16.
Crystal fragments of pyrope from diatremes of ultramafic microbreccia in the Navajo Province of the Colorado Plateau contain inclusions of olivine, pyroxene, spinel, chlorite, amphibole, chlorapatite, and dolomite. The included suite supports earlier hypotheses that hydrous phases and carbonates were primary parts of some garnet peridotite assemblages in the Plateau lithosphere. Garnets with spinel and orthopyroxene inclusions likely all were sampled at pressures less than 36 kb and perhaps as low as 15–20 kb; no evidence was found for inclusions from greater depths. Temperature estimates are 800°–900° C for garnet-clinopyroxene equilibration, but only 500°–700° C for garnetolivine equilibration. Inherent differences between geothermometry methods account for only part of the discrepancy. Pronounced Fe-Mg zoning in garnet at olivine contacts and the lack of such zoning at clinopyroxene contacts are evidence that the difference in part relates to relative reequilibration rates with cooling. The garnet-olivine temperature estimates may be the best approximations to mantle temperatures before eruption. Our data are compatible both with the hypothesis that the garnet peridotite was emplaced in the mantle by large-scale, horizontal transport in the lithosphere and with the hypothesis that rocks were sampled from Precambrian lithosphere cooled to temperatures like those along a low heat flow geotherm. Discordances between the geothermometers here and in other lherzolite localities may be keys to evaluating tectonic histories of lherzolite masses.  相似文献   

17.
Garnet‐bearing peridotite lenses are minor but significant components of most metamorphic terranes characterized by high‐temperature eclogite facies assemblages. Most peridotite intrudes when slabs of continental crust are subducted deeply (60–120 km) into the mantle, usually by following oceanic lithosphere down an established subduction zone. Peridotite is transferred from the resulting mantle wedge into the crustal footwall through brittle and/or ductile mechanisms. These ‘mantle’ peridotites vary petrographically, chemically, isotopically, chronologically and thermobarometrically from orogen to orogen, within orogens and even within individual terranes. The variations reflect: (1) derivation from different mantle sources (oceanic or continental lithosphere, asthenosphere); (2) perturbations while the mantle wedges were above subducting oceanic lithosphere; and (3) changes within the host crustal slabs during intrusion, subduction and exhumation. Peridotite caught within mantle wedges above oceanic subduction zones will tend to recrystallize and be contaminated by fluids derived from the subducting oceanic crust. These ‘subduction zone peridotites’ intrude during the subsequent subduction of continental crust. Low‐pressure protoliths introduced at shallow (serpentinite, plagioclase peridotite) and intermediate (spinel peridotite) mantle depths (20–50 km) may be carried to deeper levels within the host slab and undergo high‐pressure metamorphism along with the enclosing rocks. If subducted deeply enough, the peridotites will develop garnet‐bearing assemblages that are isofacial with, and give the same recrystallization ages as, the eclogite facies country rocks. Peridotites introduced at deeper levels (50–120 km) may already contain garnet when they intrude and will not necessarily be isofacial or isochronous with the enclosing crustal rocks. Some garnet peridotites recrystallize from spinel peridotite precursors at very high temperatures (c. 1200 °C) and may derive ultimately from the asthenosphere. Other peridotites are from old (>1 Ga), cold (c. 850 °C), subcontinental mantle (‘relict peridotites’) and seem to require the development of major intra‐cratonic faults to effect their intrusion.  相似文献   

18.
Following previous publication of major–minor elementdata, this paper presents rare earth element (REE) data forheterogeneous (chemically zoned) garnets belonging to the peridotitesuite of mantle xenoliths from the Jagersfontein kimberlitepipe, South Africa. The rim compositions of the garnets in thehighest temperature–pressure (deepest) deformed peridotitesshow a typical megacryst-like pattern, of very low light REE(LREE) increasing through the middle REE (MREE) to a plateauof heavy REE (HREE) at c. 20 times chondrite; these compositionswould be in equilibrium with small-volume melts of the mid-oceanridge basalt (MORB) source (asthenosphere). With decreasingdepth the garnet rims show increasing LREE and decreasing HREE,eventually resulting in humped relative abundance patterns.A set of compositions is calculated for melts that would bein equilibrium with the garnet rims at different depths. Theseshow decreasing relative abundance of each REE from La to Lu,and the La/Lu ratio of the melts increases with decreasing depthof formation. Modelling of the effects of crystal fractionationshows that this process could largely generate the sequenceof garnet rim and melt compositions found with decreasing depth,including the humped REE patterns in high-level garnets. Consideringthe behaviour of major–minor elements as well as REE,a process of percolative fractional crystallization is advocatedin which megacryst source melts percolate upwards through peridotitesand undergo fractionation in conjunction with exchange withthe peridotite minerals. The initial megacryst melt probablyincludes melt of lithospheric origin as well as melt from theMORB source, and it is suggested that the process of percolativefractional crystallization may form a variety of metasomaticand kimberlitic melts from initial megacryst melts. Repeatedmetasomatism of the lower lithosphere by such differentiatingmelts is suggested by consideration of garnet core compositions.Such metasomatism would progressively convert harzburgites tolherzolites by increasing their CaO content, and this may accountfor the fact that the Cr-rich diamond–garnet harzburgiteparagenesis is commonly preserved only where it has been encapsulatedin diamonds. KEY WORDS: cratonic lithosphere; garnet zoning; mantle xenoliths; megacryst magma; metasomatic melt  相似文献   

19.
Analytical data on major elements and 31 trace elements in olivine nephelinites, nepheline basanites, basanitic alkali olivine basalts and their differentiates (tephrites, hawaiites, mugearites, benmoreites, latites, phonolites and trachytes) from Hegau, Kaiserstuhl, Rhön, Hessian Depression, Vogelsberg, Westerwald, Siebengebirge, E Eifel and Hocheifel are evaluated. They were based on 400 samples with new or unpublished data on about one third of the rocks. The Sr–Nd isotopic compositions for 78 rocks are included. The alkali basaltic volcanism is caused by adiabatic decompression of asthenospheric mantle updomed to a minimum depth of 50 km in connection with the Alpine continent collision. The chemical compositions of the primary basaltic melts from the different areas are similar containing about one hundred-fold enrichment of highly incompatible elements relative to the primitive mantle from partial melting of depleted and secondarily enriched peridotite. The elements Cs, K, Pb and Ti are specifically depleted in the basalts partly because of phlogopite being residual at partial melting. The Tertiary alkali basalts range in Nd-isotopic composition from 0.51288 to 0.51273 and in Sr-isotopic ratios from 0.7032 to 0.7042. These ranges indicate mixtures of HIMU, depleted and enriched mantle components in the metasomatically altered peridotite source which resembles that of certain ocean islands. The Nd-Sr-isotopic compositions of the Quaternary E Eifel are close to bulk Earth ratios. East and W Eifel plots differ distinctly from the Tertiary Hocheifel which is geographically intermediate. This isotopic difference, beside specific K/Na ratios, is probably caused by separate metasomatic pulses that immediately preceded the respective periods of volcanism. The metasomatically altered mantle had partly primitive mantle signatures (Nb/Ta, Zr/Sm and Th/U ratios) and partly ocean island (or MORB) source properties (Rb/Cs). A MORB source can be excluded because of the low K/Rb and high Th/U ratios. A correlation of D with 87Sr/86Sr in amphibole and phlogopite and a slightly larger 18O than in MORB is conformable with a seawater and crustal impact on the source of alkali basalts. Slightly higher than average water concentrations in the source of certain primary basaltic melts (indicated by amphibole phenocrysts in their basalts) are required for differentiation of these basalts in magma chambers of the upper crust. Model calculations are presented to explain compositions of differentiates which range from about 60% to about 20% residual melt. The latter are represented by phonolites and trachytes. The Nd- and Sr-isotopic signatures of the majority of differentiates indicate contamination by a granitic partial melt from the wall rocks of magma chambers. Olivine nephelinite magma was the common source of contaminated differentiates.  相似文献   

20.
Summary A garnet peridotite lens from Monte Duria (Adula nappe, Central Alps, Northern Italy) contains porphyroblastic garnet and pargasitic amphibole and reached peak metamorphic conditions of ∼830 C, ∼2.8 GPa. A first stage of near isothermal decompression to pressures <2.0 GPa is characterised by domains where fine grained spinel, clinopyroxene, orthopyroxene and amphibole form. The newly formed amphibole contains elevated levels of fluid mobile elements such as Rb, Ba and Pb indicating that recrystallization was assisted by infiltration of a crustal-derived fluid. Further decompression and cooling to ∼720 °C, 0.7–1.0 GPa associated with limited fluid influx is documented by the formation of orthopyroxene-spinel-amphibole symplectites around garnet. Zircon separated from this garnet peridotite exhibits two distinct zones. Domain 1 displays polygonal oscillatory zoning and high trace element contents. It contains clinopyroxene and amphibole inclusions with the same composition as the same minerals formed during the spinel peridotite equilibration, indicating that this domain formed under sub-solidus conditions during decompression and influx of crustal fluids. Domain 2 has no zoning and much lower trace element contents. It replaces domain 1 and is likely related to zircon recrystallization during the formation of the symplectites. SHRIMP dating of the two domains yielded ages of 34.2 ± 0.2 and 32.9 ± 0.3 Ma, respectively, indicating fast exhumation of the peridotite within the spinel stability field. We suggest that the Duria garnet peridotite originates from the mantle wedge above the tertiary subduction of the European continental margin and that it was assembled to the country rock gneisses between 34 and 33 Ma. Third author was Deceased  相似文献   

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