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宽甸万宝源斑岩型钼矿近年找矿工作取得了突破,已由小型矿山转化为中型矿山,成为辽东地区最主要的钼矿生产基地.通过对花岗闪长岩、石英斑岩、闪长玢岩、夕卡岩和大理岩的微量元素地球化学特征分析,将其按照相关富集程度通过R型聚类分析划分为5类：①Au、Bi、Cu;②Pb、As、Sn、Sb、Ag;③Co、Ni、Mn、Cr;④Mo、W;⑤Zn、Hg.因子分析也验证了以上分类的正确性.结合区域地质及矿床特征,夕卡岩中富集Au、Cu成矿元素,花岗闪长岩和石英斑岩富集Mo成矿元素,①④分类可作为寻找这些矿产资源的地球化学证据. 相似文献
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衡阳盆地北缘国庆矿区土壤地球化学特征及找矿方向 总被引：1，自引：0，他引：1
对国庆矿区开展了1∶10000地质简测,在了解矿区地质特征的基础上进行了1∶10000土壤地球化学测量工作。Cu、Pb、Zn、Au、Ag、W、Mo7种微量元素含量特征(变异系数、富集系数和浓集比率)显示,Cu、Au、W元素为区内成矿有利元素。运用统计学软件SPSS19对7种微量元素含量值进行R型聚类分析和R型因子分析,划分出Cu-Pb-Ag和Au-Mo两组主成矿元素组合。采用衬度异常法对成矿有利元素和两组主成矿元素组合进行处理成图,共圈定了2个异常靶区。经过地表工程和深部工程验证,确定了一条一定规模的工业铜矿体。 相似文献
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萨热阔布金矿是阿尔泰山南缘金一多金属矿带中与断裂变质作用有关的石英脉一蚀变岩型金矿床。本文通过电子探针的研究,在该矿区发现较多的自然铋矿物,它与金矿化关系非常密切,产出于多金属硫化物阶段,与方铅矿、黄铜矿等共生。矿区蚀变岩和矿石的微量元素R型聚类分析表明,Bi与Au相关最密切,Au、Cu、Ag、Bi是主要的成矿元素组合。Bi异常可以作为金矿化的重要指示,自然铋矿物的出现可以作为含金石英脉富矿地段的重要标志。 相似文献
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普朗斑岩铜矿床是云南中甸地区最大的斑岩型铜矿床,其成矿作用与普朗复式岩体存在密切的成因联系。对普朗复式岩体成矿的第1期石英闪长玢岩和第2期石英二长斑岩,以及不成矿的第3期闪长玢岩开展了锆石原位微量元素和磷灰石原位主量元素成分的研究。结果表明,锆石Ce/Ce~*值、Ce~(4+)/Ce~(3+)比值和Ce/Nd比值指示,不成矿的第3期闪长玢岩与成矿的第1期石英闪长玢岩的岩浆相对氧化状态大致相当,且明显高于成矿的第2期石英二长斑岩。磷灰石Cl、OH和SO3成分指示,普朗复式岩体3期斑岩具有相似的岩浆含水量,但成矿的第1期石英闪长玢岩和第2期石英二长斑岩较不成矿的第3期闪长玢岩具有更高的岩浆挥发分Cl含量和硫逸度。岩浆的高氧逸度和硫逸度、富水和富挥发分Cl均是形成斑岩铜矿床的关键因素,普朗不成矿的第3期闪长玢岩与成矿的第1期石英闪长玢岩和第2期石英二长斑岩均具有富水和高氧逸度特征,但第3期闪长玢岩较成矿的第1期石英闪长玢岩和第2期石英二长斑岩具有明显更低的岩浆挥发分Cl含量和硫逸度,这很可能是导致第1期石英闪长玢岩和第2期石英二长斑岩成矿,而第3期闪长玢岩不成矿的重要原因之一。 相似文献
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内蒙古哈达庙含金侵入杂岩体的基本地质特征及岩体成因问题 总被引：1，自引：0，他引：1
本文从岩相学、地球化学和同位素地质研究角度出发,详细论证了哈达庙含金侵入杂岩体的地质地球化学特征、成因机制及其与金矿化的关系。研究认为:侵入杂岩体内的闪长玢岩、石英闪长岩、花岗闪长岩、花岗斑岩和隐爆火山角砾岩是同源岩浆不同演化阶段的产物,成岩成矿物质来源与含基性岩成分较多的陆壳岩石深熔作用有关。从杂岩体边缘到核部,随着岩体从中基性到酸性方向的演化,碱质组分、成矿元素(Au、Ag)和挥发份的不断聚集,不仅形成了一系列隐爆火山角砾岩脉,同时也促进了金的沉淀富集。对比研究表明:流纹岩脉与侵入杂岩体是异源岩浆不同演化阶段的产物。 相似文献
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西藏谢通门县雄村铜金矿床元素地球化学特征 总被引：16，自引：6，他引：10
已经查明西藏雄村铜金矿床的Cu 、Au资源量达到超大型规模.通过对雄村铜金矿床Ⅰ号矿体详细的地质编录和测年成果,发现雄村斑岩型铜(金)矿床形成于晚侏罗世,矿体的形成与晚侏罗世侵位的、含眼球状石英斑晶的闪长玢岩(J3δομ)有关,成矿岩体呈不规则的岩枝状,全岩矿化,岩体中Au的平均品位大于1g/t,Cu含量大于0.7%.含矿围岩是早、中侏罗世的凝灰岩,近岩体部分矿化强烈.矿体被后期侵位的多种岩脉穿插,并被始新世侵位的谢通门大岩基黑云母花岗闪长岩穿插和破坏,岩脉的Cu、Au、Ag含量极低,黑云母花岗闪长岩(E2γδβ)Cu、Au、Ag的平均品位(733件样品分析结果统计)分别为0.0091%、0.0053 g/t、0.279 g/t;成矿前侵位的角闪石英闪长玢岩(J2δομ)Cu、Au、Ag的平均品位(1 414件样品分析结果统计)分别为0.0105%、0.048 g/t、0.395 g/t;穿插矿体的安山岩脉Cu、Au、Ag的平均品位(527件样品分析结果统计)分别为0.065%、0.068 g/t、0.728 g/t,穿插矿体的闪长岩脉的Cu、Au、Ag的平均品位(87件样品分析结果统计)分别为0.081%、0.091 g/t、0.818 g/t.根据167个勘探钻孔编录和化学分析(24 369件化学分析样品)资料,以及对海拔4 000 m、3 950 m、3 900 m水平面的Cu、Au、Ag、Mo、Mn、Pb、Zn、W、K、Na、Ca、Rb元素分布规律的分析,显示矿体具有斑岩型矿床的蚀变、矿化以及元素地球化学特征,主要矿化和围岩蚀变在时间上和空间上均与含眼球状石英斑晶的角闪石英闪长玢岩(J3δομ)有关.成矿期间与矿化热液活动有关的蚀变主要有:①早期钾硅酸盐化;②红柱石次生石英岩化(硅化);③黄铁绢英岩化;④青磐岩化.成矿期形成的脉体类型主要有早期石英-红柱石-硫化物脉、红柱石-黑云母-硫化物脉、磁铁矿-黑云母-硫化物脉、富黄铜矿硫化物脉、黄铁矿脉和多金属矿脉.从矿体中心向外,元素具有明显的分带特征.在矿体中心局部,由于红柱石-次生石英岩化蚀变作用强烈,致使K、Rb等元素向外迁移.矿石富K贫Na,以及K与Rb具有良好的相关性的特点均与国内外典型的斑岩铜矿床相似. 相似文献
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西藏谢通门县雄村斑岩型铜金矿床成因讨论——来自元素的空间分布特征的证据 总被引：6，自引：0，他引：6
西藏谢通门县雄村铜金矿的成矿与含眼球状石英斑晶的角闪石英闪长玢岩有关,并至少受3个玢岩岩枝控制。主成矿元素为Cu,伴生元素为Au、Ag、Zn、Pb,其他微量元素Mo、As、Ba、Bi、Cd、Co、Mn、Ni、Sb含量较高。元素在垂向上具有分带特征,即从矿体中心向外可依次划分为Cu、Au、Ag、As、Sb、(Bi)→Co、Ni→Mo→Mn→Ba→Pb、Zn、Cd、Bi、(Sb),上述元素的异常和组合是寻找和评价该类矿床的重要地球化学标志。矿床的形成经历了早期Cu—Au—Ag成矿和晚期Zn—Pb—Cu—Au—Ag成矿两个阶段:早期成矿阶段形成了Cu—Au—Ag主矿体,晚期叠加Zn—Pb—Cu—Au—Ag矿化。Cu与Au、Ag呈显著的正相关,Cu主要呈独立矿物黄铜矿产出,Au、Ag主要赋存于黄铜矿中。矿石的K/Na值为6.9、Rb/Sr值为0.8,显示出矿床矿富K、Sr和贫Na、Rb的成矿环境;而Au(平均品位0.6×10-6)0.4×10-6、Au(0.6×10-6)/Cu(0.4%)1和n(Cu)/n(Au)(为20678)40000以及Mo(19.7×10-6),说明该矿床富金而贫钼。矿床所处的大地构造位置,成矿与偏中性的斑岩有关,元素组合特征,异常元素在垂向上的分带特征,主成矿阶段的Cu—Au—Ag矿化和晚期叠加的Zn—Pb—Cu—Au—Ag矿化,富Cu、Au、Ag和贫Mo的成矿元素组合及富K、Sr和贫Na、Rb的成矿环境,均表明矿床具有产于岛弧或类似岛弧环境的斑岩型铜金矿床的特征且叠加斑岩成矿系统晚期呈脉状产出的浅成低温热液型Zn—Pb—Cu—Au—Ag矿化。 相似文献
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内蒙古敖汉旗七家金矿构造位置上处于兴蒙造山带与华北克拉通北缘的结合部位, 靠近兴蒙造山带一侧, 是近年来新发现的石英脉型金矿床.区内岩脉以闪长玢岩为主, 且与石英脉型矿体空间关系密切.根据岩脉与矿体的穿插关系, 将其分为成矿前闪长玢岩和成矿后闪长玢岩.LA-ICP-MS锆石U-Pb年代学表明, 成矿前闪长玢岩加权平均年龄为166.3±3.4 Ma, 成矿后闪长玢岩加权平均年龄为128.6±4.5 Ma, 与区域上两期构造-岩浆活动时间(分别为160 Ma左右和128 Ma左右)近似吻合.主量元素特征显示: 二者均属于准铝质, 高钾钙碱性系列; 微量元素特征显示: 二者均富集轻稀土元素、大离子亲石元素(Rb、K)和活泼的不相容元素(U、Pb), 相对亏损重稀土元素和高场强元素(Nb、Ta、Ti), 反映出岩浆来源具壳源特征.主微量元素特征均显示出二者具有岛弧岩浆岩的地球化学属性.另外, 成矿后闪长玢岩有较高的Nb/Ta(18.66~20.27)和Zr/Hf(37.16~39.23)比值, 暗示其岩浆来源具明显的幔源特征.岩石地球化学特征表明, 成矿前闪长玢岩可能起源于太平洋板块俯冲导致的下地壳部分熔融岩浆; 成矿后闪长玢岩可能起源于俯冲流体交代的地幔楔熔融岩浆, 并在其演化侵位过程中伴有地壳物质的混染.结合闪长玢岩成岩时代、岩石成因及区域构造演化, 反映出七家金矿的形成与太平洋板块的西向俯冲密切相关, 矿床在地壳由挤压增厚向伸展减薄的转换过程中形成. 相似文献
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江西相山铀矿田邹家山铀矿床蚀变特征及热液来源 总被引：1，自引：0，他引：1
对江西相山铀矿田邹家山矿床不同标高的赋矿围岩及矿石样品进行了主量元素、微量元素和稀土元素地球化学分析。结果表明,邹家山矿床不同中段的矿石经历了碱性—酸性—碱性的蚀变过程,在-85 m中段酸性蚀变达到最强,随深度增加碱性蚀变呈增强的趋势;微量元素的Q型聚类分析、不同中段U含量分析和稀土元素的配分模式表明,成矿物质可能并不来源于赋矿围岩,而是来源于流纹英安岩岩浆。进一步根据与成矿关系密切的13种元素的R型聚类分析,将邹家山矿床成矿热液系统划分为高温成矿热液系统和中低温成矿热液系统。 相似文献
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《International Journal of Coal Geology》1988,10(1):99-108
Trace-element analyses of seventy six coal samples representing all the major Lower Gondwana coal basins of India were carried out. Eighteen trace elements, viz., B, Ba, Co, Cr, Cu, Ga, Ge, La, Mn, Mo, Nb, Ni, Pb, Sn, Sr, V, Y and Zr were determined quantitatively in coal ash. An attempt was made to correlate the coals of different coalfields on the basis of multivariate analysis. In addition, the organic/inorganic affinities between the trace elements were established by the coefficients of correlation between the trace elements and ash present. A synthesis of the data reveals that there is similarity in the concentration ranges of trace elements among the coal seams of different coalfields, but the possibility of environmental differences exists due to the statistically different multivariate means of the trace-element concentrations.It is inferred that Ge, Cr, Y and La occur in these coals as organo-metallic complexes and chelates. The elements Ni, Co, Ga, V and Cu show both organic and inorganic association, whereas Mn and Ba are exclusively incorporated in the inorganic fractions. 相似文献
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传统方法不能明确揭示泥河铁矿床多阶段热液叠加蚀变过程中元素迁移的继承性特征.运用等浓度图法(the isocon diagram),根据该区晚阶段蚀变都是叠加在稍早阶段蚀变之上的实际情况,采用早期蚀变岩石为原岩与稍晚期蚀变岩石的不活动元素拟合最佳等浓度方程,定量揭示主量元素在热液蚀变过程的迁移规律.研究表明,泥河铁矿床阳离子的沉淀顺序大致为:Na→Ca、Mg、Fe、P→Ca、Fe→Al、Si.从早到晚,元素的带入和带出是连续互补的,蚀变矿化作用是一个连续的过程.钠长石的大量出现是Na质沉淀的标志,代表铁矿化的开始;膏辉岩化是Ca、Mg、Fe质沉淀的表现形式,为磁铁矿体的近矿和容矿蚀变;次生石英岩化、高岭石化是早期迁移出的Al、Si质沉淀的结果,是磁铁矿化远程指示性蚀变. 相似文献
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黔西南高砷煤的元素地球化学特征 总被引：1，自引：0，他引：1
通过分析黔西南高砷煤的元素地球化学特征,探索高砷煤中微量元素、稀土元素的地球化学行为,从而揭示了高砷煤的形成机理。分析表明,高砷煤与非高砷煤在微量元素含量方面存在较大差异,金、汞、铊矿石与龙潭煤系中的砷具有同源性,龙潭煤系页岩与峨眉山玄武岩在稀土元素组成上具有继承性。 相似文献
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G. Panagopoulos 《Environmental Geology》2009,58(5):1067-1082
The Trifilia karst aquifer presents a complex hydrochemical character due to the intricate geochemical processes that take
place in the area. Their discernment was achieved by using the chemical analyses of major, trace elements and boron isotopes.
Major ion composition indicates mixing between seawater and freshwater is occurring. Five hydrochemical zones corresponding
to five respective groundwater types were distinguished, in which the chemical composition of groundwater is influenced mainly
due to the different salinization grade of the aquifer. The relatively increased temperature of the aquifer indicates the
presence of hydrothermal waters. Boron isotopes and trace elements indicate that the intruding seawater has been hydrothermally
altered, as it is shown by the δ11B depleted signature and the increased concentrations of Li and Sr. Trace elements analyses showed that the groundwater is
enriched in various metallic elements, which derive from the solid hydrocarbons (bitumens), contained in the carbonate sediments
of the Tripolis zone. The concentration of these trace elements depends on the redox environment. Thus, in reductive conditions
As, Mn, Co and NH4 concentrations are high, in oxidized conditions the V, Se, Mo, Tl and U concentration increases while Ni is not redox sensitive
and present high concentration in both environments. 相似文献
16.
Multifractal Analysis of Element Distribution in Skarn-type Deposits in the Shizishan Orefield, Tongling Area, Anhui Province, China 总被引：3，自引：1，他引：2
Wang Qingfei Deng Jun Wan Li Zhao Jie Gong Qingjie Yang Liqiang Zhou Lei Zhang Zhijun 《《地质学报》英文版》2008,82(4):896-905
A series of element concentrations sampled from four drill cores with a length about 1000 m into different skarn-type deposits were selected from the Shizishan orefield, central Tongling, southeastern part of Anhui Province. Using the multifractal method, the distribution and migration characteristics of the major and trace elements are analyzed. The multifractal spectrum of the major elements is left-skewed, whereas the spectrum of the trace elements is right-skewed, which shows that in the process of skarn formation, the trace elements were enriched only locally, and major elements transported within a much larger range. The correlation coefficients of the multifractal parameters Aa （width of the multifractal spectrum） of the four drill cores are relatively low, but the correlation coefficients of the multifractal parameters R （spectrum symmetry parameter） and Af are relatively higher, indicating that although the non-homogeneous intensity of the distribution of elements is inconsistent, their spatial accumulation patterns are almost the same during the ore-forming process. The statistics of the mnltifractal parameters of various elements in the different locations show that the ore-forming processes and element migration pattern in the Shizishan orefield are consistent, and that the migrations of trace elements and major elements exhibit some differences. 相似文献
17.
Soil and plant composition in the Noun river catchment basin,Western Cameroon: a contribution to the development of a biogeochemical baseline 总被引：1，自引：0，他引：1
Clémentine Njofang Jörg Matschullat Akoa Amougou Jean Pierre Tchouankoué Hermann Heilmeier 《Environmental Geology》2009,56(7):1427-1436
Soils and selected edible plants of the Noun river catchment basin of western Cameroon were sampled to investigate the distribution
of trace elements, based on the preliminary idea of unusual anomalies. Analytical techniques for trace elements included ICP-AES,
GF-AAS, and ICP-MS. Further soil analyses comprised the mineralogy and contents of the biogenic elements carbon, nitrogen
and sulphur (CNS). The trace element concentrations in the soils reflect those of the lithogeochemical background of the pluto-volcanic
rocks of the region. This is consistent with the results from the mineralogical analyses and physicochemical parameters such
as pH, taken in the field, which also do not suggest any geochemical anomaly. Most trace elements analyzed in the plants showed
concentrations that reflect those of the soils (Al, Fe, Ti, and Rb). However, some trace elements were enriched in the plants
as compared to the soils, such as Zn, Cu, Cd, Mo (excluding yam), Ni (peanut), Ba (peanut), Sr (peanut, bean), and B. Trace
elements such as As, Cr, V, and Se were not bioavailable for all the analyzed plants. Besides, trace elements such as Cu,
Zn, Mo, Fe, Al, Ni, B, Ti, Rb, Cs, and Ba were in the range of phytotoxicity and reached or exceeded human food tolerance
level (Cu). The plants with seeds showed a higher absorption of trace elements compared to plants with tubercles. 相似文献
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19.
《地学前缘(英文版)》2023,14(4):101580
Due to the combined influences such as ore-forming temperature, fluid and metal sources, sphalerite tends to incorporate diverse contents of trace elements during the formation of different types of Lead-zinc (Pb-Zn) deposits. Therefore, trace elements in sphalerite have long been utilized to distinguish Pb-Zn deposit types. However, previous discriminant diagrams usually contain two or three dimensions, which are limited to revealing the complicated interrelations between trace elements of sphalerite and the types of Pb-Zn deposits. In this study, we aim to prove that the sphalerite trace elements can be used to classify the Pb-Zn deposit types and extract key factors from sphalerite trace elements that can discriminate Pb-Zn deposit types using machine learning algorithms. A dataset of nearly 3600 sphalerite spot analyses from 95 Pb-Zn deposits worldwide determined by LA-ICP-MS was compiled from peer-reviewed publications, containing 12 elements (Mn, Fe, Co, Cu, Ga, Ge, Ag, Cd, In, Sn, Sb, and Pb) from 5 types, including Sedimentary Exhalative (SEDEX), Mississippi Valley Type (MVT), Volcanic Massive Sulfide (VMS), skarn, and epithermal deposits. Random Forests (RF) is applied to the data processing and the results show that trace elements of sphalerite can successfully discriminate different types of Pb-Zn deposits except for VMS deposits, most of which are falsely distinguished as skarn and epithermal types. To further discriminate VMS deposits, future studies could focus on enlarging the capacity of VMS deposits in datasets and applying other geological factors along with sphalerite trace elements when constructing the classification model. RF’s feature importance and permutation feature importance were adopted to evaluate the element significance for classification. Besides, a visualized tool, t-distributed stochastic neighbor embedding (t-SNE), was used to verify the results of both classification and evaluation. The results presented here show that Mn, Co, and Ge display significant impacts on classification of Pb-Zn deposits and In, Ga, Sn, Cd, and Fe also have relatively important effects compared to the rest elements, confirming that Pb-Zn deposits discrimination is mainly controlled by multi-elements in sphalerite. Our study hence shows that machine learning algorithm can provide new insights into conventional geochemical analyses, inspiring future research on constructing classification models of mineral deposits using mineral geochemistry data. 相似文献
20.
Trace elements in the Merensky Reef and adjacent norites Bushveld Complex South Africa 总被引：1，自引：0，他引：1
Nicholas Arndt George Jenner Maryse Ohnenstetter Etienne Deloule Alan H. Wilson 《Mineralium Deposita》2005,40(5):550-575
Trace elements were analysed in rocks and minerals from three sections across the Merensky Reef in the Rustenburg Platinum
Mine in the Bushveld Complex of South Africa. Whole rocks and separated minerals were analysed by inductively coupled plasma-mass-spectrometer
(ICP-MS) and in situ analyses were carried out by ion microprobe and by laser-source ICP-MS. Merensky Reef pyroxenites contain
extremely high concentrations of a wide range of trace elements. These include elements incompatible with normal silicate
minerals as well as siderophile and chalcophile elements. For major elements and compatible trace elements, the measured concentrations
in cumulus phases and the bulk rock compositions are similar. For highly incompatible elements, however, concentrations in
bulk rocks are far higher than those measured in the cumulus phases. In situ analyses of plagioclase have far lower concentrations
of Th, Zr and rare earth elements than ICP-MS analyses of bulk separates of plagioclase, a difference that is attributed to
the presence of trace-element-rich accessory phases in the bulk mineral separates. We used these data to calculate the trace-element
composition of the magmas parental to the Merensky Unit and adjacent norites. We argue that there is no reason to assume that
the amount of trapped liquid in the Merensky orthopyroxenite was far greater than in the norites and we found that the pyroxenite
formed from a liquid with higher concentrations of incompatible trace elements than the liquid that formed the norites. We
propose that the Bushveld Complex was fed by magma from a deeper magma chamber that had been progressively assimilating its
crustal wall rocks. The magma that gave rise to the Merensky Unit was the more contaminated and unusually rich in incompatible
trace elements, and when it entered the main Bushveld chamber it precipitated the unusual phases that characterize the Merensky
Reef. The hybrid magma segregated sulphides or platinum-group-element-rich phases during the course of the contamination in
the lower chamber. These phases accumulated following irruption into the main Bushveld chamber to form the Merensky ore deposits. 相似文献