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1.
 Latest Devonian to early Carboniferous plutonic rocks from the Odenwald accretionary complex reflect the transition from a subduction to a collisional setting. For ∼362 Ma old gabbroic rocks from the northern tectonometamorphic unit I, initial isotopic compositions (εNd=+3.4 to +3.8;87Sr/86Sr =0.7035–0.7053;δ18O=6.8–8.0‰) and chemical signatures (e.g., low Nb/Th, Nb/U, Ce/Pb, Th/U, Rb/Cs) indicate a subduction-related origin by partial melting of a shallow depleted mantle source metasomatized by water-rich, large ion lithophile element-loaded fluids. In the central (unit II) and southern (unit III) Odenwald, syncollisional mafic to felsic granitoids were emplaced in a transtensional setting at approximately 340–335 Ma B.P. Unit II comprises a mafic and a felsic suite that are genetically unrelated. Both suites are intermediate between the medium-K and high-K series and have similar initial Nd and Sr signatures (εNd=0.0 to –2.5;87Sr/86Sr=0.7044–0.7056) but different oxygen isotopic compositions (δ18O=7.3–8.7‰ in mafic vs 9.3–9.5‰ in felsic rocks). These characteristics, in conjunction with the chemical signatures, suggest an enriched mantle source for the mafic magmas and a shallow metaluminous crustal source for the felsic magmas. Younger intrusives of unit II have higher Sr/Y, Zr/Y, and Tb/Yb ratios suggesting magma segregation at greater depths. Mafic high-K to shoshonitic intrusives of the southern unit III have initial isotopic compositions (εNd=–1.1 to –1.8;87Sr/86Sr =0.7054–0.7062;δ18O=7.2–7.6‰) and chemical characteristics (e.g., high Sr/Y, Zr/Y, Tb/Yb) that are strongly indicative of a deep-seated enriched mantle source. Spatially associated felsic high-K to shoshonitic rocks of unit III may be derived by dehydration melting of garnet-rich metaluminous crustal source rocks or may represent hybrid magmas. Received: 7 December 1998 / Accepted: 27 April 1999  相似文献   

2.
A detailed Sr−Nd isotopic study of primary apatite, calcite and dolomite from phoscorites and carbonatites of the Kovdor massif (380 Ma), Kola peninsula, Russia, reveals a complicated evolutionary history. At least six types of phoscorites and five types of carbonatite have been identified from Kovdor by previous investigators based on relative ages and their major and accessory minerals. Isotopic data from apatite define at least two distinct groups of phoscorite and carbonatite. Apatite from the earlier phoscorites and carbonatites (group 1) are characterized by relatively low87Sr/86Sr (0.70330–0.70349) and143Nd/144Nd initial ratios (0.51230–0.51240) with F=2.01–2.23 wt%, Sr=2185–2975 ppm, Nd=275–660 ppm and Sm=31.7–96.2 ppm. Apatite from the second group has higher87Sr/86Sr (0.70350–0.70363) and143Nd/144Nd initial ratios (0.51240–0.51247) and higher F (2.63–3.16 wt%), Sr (4790–7500 ppm), Nd (457–1074 ppm) and Sm (68.7–147.6 ppm) contents. This group corresponds to the later phoscorites and carbonatites. One apatite sample from a carbonatite from the earlier group fits into neither of the two groups and is characterized by the highest initial87Sr/86Sr (0.70385) and lowest143Nd/144Nd (0.51229) of any of the apatites. Within both groups initial87Sr/86Sr and143Nd/144Nd ratios show negative correlations. Strontium isotope data from coexisting calcite and dolomite support the findings from the apatite study. The Sr and Nd isotopic similarities between carbonatites and phoscorites indicate a genetic relationship between the two rock types. Wide variations in Sr and Nd isotopic composition within some of the earlier carbonatites indicate several distinct intrusive phases. Oxygen isotopic data from calcite and dolomite (δ18O=+7.2 to +7.7‰ SMOW) indicate the absence of any low-temerature secondary processes in phoscorites and carbonatites, and are consistent with a mantle origin for their parental melts. Apatite data from both groups of phoscorite plot in the depleted quadrant of an εNd versus εSr diagram. Data for the earlier group lie along the Kola Carbonatite Line (KCL) as defined by Kramm (1993) and data from the later group plot above the KCL. The evolution of the phoscorites and carbonatites cannot be explained by simple magmatic differentiation assuming closed system conditions. The Sr−Nd data can best be explained by the mixing of three components. Two of these are similar to the end-members that define the Kola Carbonatite Line and these were involved in the genesis of the early phoscorites and carbonatites. An additional component is needed to explain the isotopic characteristics of the later group. Our study shows that apatite from rocks of different mineralogy and age is ideal for placing constraints on mantle sources and for monitoring the Sr−Nd evolution of carbonatites. Editorial responsibility: W. Schreyer  相似文献   

3.
The major, trace (including rare earth) element abundances, and Sr-Nd-Pb isotopic compositions, have been analysed for andesitic basalt and andesitic sills and lavas of the Jurassic Ferrar Magmatic Province, Prince Albert Mountains, Antarctica. The typical “crustal signature” of the Ferrar magmatism, characterized by relatively high SiO2, LREE and LILE contents in these samples, is associated with high 87Sr/86Sr and low 143Nd/144Nd. Systematic correlations of major and trace elements indicate that fractional crystallization was important. However, increases in incompatible elements are positively correlated with initial 87Sr/86Sr, suggestive of crustal assimilation processes. The observed correlations between initial 87Sr/86Sr and LREE enrichments have been modelled by an AFC process, starting from the least evolved sample and assuming the compositions of the orthogranulites of Victoria Land as contaminants. The REE patterns of the least evolved Ferrar rocks approach those of E-type MORB, differing only by higher LREE/IREE. The enrichment in LREE, accompanying high initial 87Sr/86Sr, 207Pb/204Pb and low 143Nd/144Nd compared with E-type MORB, can be explained by interaction of “primary Ferrar basalt” with crystalline basement. We propose a petrological model whereby Ferrar magmas were generated through high degrees of melting of an E-type MORB mantle source, and subsequently these “primary” melts underwent AFC processes inheriting a crustal signature. The Sr-Nd-Pb isotopic compositions required by the AFC model for the primary Ferrar basalt are similar to those of the Dupal signature of the oceanic basalts of the Southern Hemisphere (Hart 1984). Transantarctic Mountains would have been located inside the Dupal anomaly in pre-Gondwana dispersion times. Received: 21 April 1998 / Accepted: 25 January 1999  相似文献   

4.
 Isotopic and trace element data from mantle and granulite xenoliths are used to estimate the relative contributions of mantle and crustal components to a large ignimbrite, referred to as the upper ignimbrite, that is representative of the voluminous mid-Cenozoic rhyolites of northwestern Mexico. The study also uses data from the volcanic rocks to identify deep crustal xenoliths that are samples of new crust created by the Tertiary magmatism. The isotopic composition of the mantle component is defined by mantle-derived pyroxenites that are interpreted to have precipitated from mid-Cenozoic basaltic magmas. This component has ɛNd≈+1.5, 87Sr/86Sr≈0.7043 and 206Pb/204Pb≈18.6. Within the upper ignimbrite and associated andesitic and dacitic lavas, initial 87Sr/86Sr is positively correlated with SiO2, reaching 0.7164 in the ignimbrite. Initial 206Pb/204Pb ratios also show a positive correlation with silica, whereas ɛNd values have a crude negative correlation, reaching values as low as −2. Of the four isotopically distinct crustal components identified from studies of granulite xenoliths, only the sedimentary protolith of the paragneiss xenoliths can be responsible for the high initial 87Sr/86Sr of the upper ignimbrite. The Nd, Sr, and Pb isotopic compositions of the upper ignimbrite can be modeled with relatively modest assimilation (≤20%) of the sedimentary component ± Proterozoic granulite. Gabbroic composition granulite xenoliths have distinctive Nd, Sr, and Pb isotope ratios that cluster closely within the range of compositions found in the andesitic and dacitic lavas. These mafic granulites are cumulates, and their protoliths are interpreted to have precipitated from the intermediate to silicic magmas at 32–31 Ma. These mafic cumulate rocks are probably representative of much of the deep crust that formed during mid-Cenozoic magmatism in Mexico. Worldwide xenolith studies suggest that the relatively great depth (≤20 km) at which assimilation-fractional crystallization took place in the intermediate to silicic magma systems of the La Olivina region is the rule rather than the exception. Oligocene ignimbrites of the southwestern United States (SWUS) have substantially lower ɛNd values (e.g. <−6) than the upper ignimbrite and other rhyolites from Mexico. This difference appears to reflect a greater crustal contribution to ignimbrites of the SWUS, perhaps due to a higher temperature of the lower crust prior to the emplacement of the Oligocene basaltic magmas. Received: 16 December 1994 / Accepted: 13 September 1995  相似文献   

5.
Alkalic and tholeiitic basalts were erupted in the central Arizona Transition Zone during Miocene-Pliocene time before and after regional faulting. The alkalic lava types differ from the subalkaline lavas in Sr, Nd and Pb isotopic ratios and trace element ratios and, despite close temporal and spatial relationships, the two types appear to be from discrete mantle sources. Pre-faulting lava types include: potassic trachybasalts (87Sr/86Sr = 0.7052 to 0.7055, Nd= –9.2 to –10.7); alkali olivine basalts (87Sr/ 86Sr = 0.7049 to 0.7054, Nd= –2 to 0.2); basanite and hawaiites (87Sr/86Sr = 0.7049 to 0.7053, Nd= –3.5 to –7.8); and quartz tholeiites (87Sr/86Sr = 0.7047, Nd= –1.4 to –2.6). Post-faulting lavas have lower 87Sr/86Sr (<0.7045) and Nd from –3.2 to 2.3. Pb isotopic data for both preand post-faulting lavas form coherent clusters by magma type with values higher than those associated with MORB but within the range of values found for crustal rocks and sulfide ores in Arizona and New Mexico. Pb isotopic systematics appear to be dominated by crustal contamination. Effects of assimilation and fractional crystallization are inadequate to produce the Sr isotopic variations unless very large amounts of assimilation occurred relative to fractionation. It is impossible to produce the Nd isotopic variations unless ancient very unradiogenic material exists beneath the region. Moreover the assumption that the alkalic lavas are cogenetic requires high degrees of fractionation inconsistent with major- and trace-element data. Metasomatism of the subcontinental lithosphere above a subduction zone by a slab-derived fluid enriched in Sr, Ba, P and K could have produced the isotopic and elemental patterns. The degree of metasomatism apparently decreased upward, with the alkalic lavas sampling more modified regions of the mantle than the tholeiitic lavas. Such metasomatism may have been a regional event associated with crustal formation at about 1.6 Ga. Disruption and weakening of the subcontinental lithosphere in the Transition Zone of the Colorado Plateau by volcanism probably made deformation possible.  相似文献   

6.
Strontium and Nd isotopic compositions and trace element abundances were determined for Cretaceous to late Cenozoic igneous rocks from the Japan Sea side of Southwest Japan in order to investigate the effect of the opening of the Japan Sea on igneous activity. The 87Sr/86Sr ratios for both high and low silica rocks decrease with decreasing age since the middle Miocene, when the opening occurred. Similarly, 143Nd/144Nd values for these rocks increase with decreasing age, and are negatively correlated with 87Sr/86Sr ratios. A two-component mixing process can best account for these isotopic and chemical characteristics. One end-member is likely the subcontinental lithospheric mantle (SCLM) and its derivative mafic to intermediate materials which had ɛNd values of around +3. The other endmember consists of mafic to intermediate rocks with low ɛNd values (e.g., −8), probably located in the lower crust. The mantle upwelling associated with the opening of the Japan Sea did not supply typical MORB or MORB-source materials to the crust, but did provide the heat that caused the melting of lithospheric mantle and lower crust. Received: 29 August 1996 / Accepted: 6 May 1997  相似文献   

7.
Nd- and Sr-isotopic data are reported for lavas from 23 submarine and 3 subaerial volcanoes in the northern Mariana and southern Volcano arcs. Values of Nd range from +2.4 to +9.5 whereas 87Sr/86Sr ranges from 0.70319 to 0.70392; these vary systematically between and sometimes within arc segments. The Nd-and Sr-isotopic compositions fall in the field of ocean island basalt (OIB) and extend along the mantle array. Lavas from the Volcano arc, Mariana Central Island Province and the southern part of the Northern Seamount Province have Nd to +10 and 87Sr/86Sr=0.7032 to 0.7039. These are often slightly displaced toward higher 87Sr/86Sr at similar Nd. In contrast, those lavas from the northern part of the Mariana Northern Seamount Province as far north as Iwo Jima show OIB isotopic characteristics, with Nd and 87Sr/86Sr=0.7035 to 0.7039. Plots of 87Sr/86Sr and Nd versus Ba/La and (La/Yb)n support a model in which melts from the Mariana and Volcano arcs are derived by mixing of OIB-type mantle (or melts therefrom) and a metasomatized MORB-type mantle (or melts therefrom). An alternate interpretation is that anomalous trends on the plots of Nd- and Sr-isotopic composition versus incompatible-element ratios, found in some S-NSP lavas, suggest that the addition of a sedimentary component may be locally superimposed on the two-component mixing of mantle end-members.  相似文献   

8.
The early miocene Tecuya volcanic center in the southern San Joaquin basin of California consists of flows and tuffs of basalt and rhyolite that erupted, closely spaced in time, in both submarine and subaerial conditions. The rhyolites are overlain by the basalts and constitute approximately 45% of a total of at least 180 km3 of the Tecuya volcanic rocks. The basalts have Nd(t) values of +2 to +6 and (87Sr/86Sr)i values between 0.7035 and 0.7052. These rocks show LREE enrichment [(La/Yb)N =2.4–5.5; La=28–150 times chondrite] and higher Th/U, Th/Ta, Rb/Ta, Ba/Ta, Cs/Rb but lower K/Rb ratios than MORB. Combined major- and trace-element, and Sr–Nd isotopic data suggest the involvement of subcontinental lithosphere, depleted upper mantle source (MORB), and local continental crust in the basalt petrogenesis. Nd(t) values in rhyolites vary from +1.5 to +3.7 while (87Sr/86Sr)i ratios range from 0.7051 to 0.7064. The rhyolites display LREE enrichment [(La/Yb)N=10; La=100 times chondrite] along with a distinct negative Eu anomaly (Eu/Eu*=0.75) and depletion of Ti and P. Mixing relations in (87/86Sr)i – Nd(t) space among basalts, rhyolites, and local continental crust indicate that the Tecuya rhyolites were produced by assimilation of variable amounts of continental crust by MORB-related magmas and subcontinental lithosphere-derived melts. This conclusion is supported by the synchroneity of Tecuya volcanism at 22 Ma with interaction of a segment of the East Pacific Rise along the southern California margin. The Tecuya volcanic rocks thus provide an example for the generation of rhyolitic melts owing to crustal assimilation by basaltic melts during mid-oceanic ridge-induced magmatism along a continental margin.  相似文献   

9.
The composite Oberkirch pluton consists of three compositionally different units of peraluminous biotite granite. The northern unit is relatively mafic (SiO2∼64%) and lacks cordierite. The more felsic central and southern units (SiO2=67.8 to 70.4%) can only be distinguished from each other by the occurrence of cordierite in the former. Mafic microgranular enclaves of variable composition, texture and size occur in each of these units and are concentrated in their central domains. Most abundant are large (dm to m) hornblende-bearing enclaves with dioritic to tonalitic compositions (SiO2=50.8 to 56.3 wt%; Mg#=63 to 41) and fine grained doleritic textures that suggest chilling against the host granite magma. Some of these enclaves are mantled by hybrid zones. Less common are microtonalitic enclaves containing biotite as the only primary mafic phase (SiO2=53.7 to 64.4%) and small hybrid tonalitic to granodioritic enclaves and schlieren. Synplutonic dioritic dikes (up to 6 m thick) with hybrid transition zones to the host granite occur in the southern unit of the pluton. In chemical variation diagrams, samples from unmodified hornblende-bearing mafic enclaves and dikes form continuous trends that are compatible with an origin by fractionation of olivine, clinopyroxene, hornblende and plagioclase. Chemical and initial isotopic signatures (e.g. high Mg#, low Na2O, ɛNd=−1.2 to −5.1, 87Sr/86Sr=0.7055 to 0.7080, δ18O=8.0 to 8.8‰) exclude an origin by partial melting from a mafic meta-igneous source but favour derivation from a heterogeneous enriched lithospheric mantle. Samples from the granitic host rocks do not follow the chemical variation trends defined by the diorites but display large scatter. In addition, their initial isotopic characteristics (ɛNd=−4.5 to −6.8, 87Sr/86Sr=0.7071 to 0.7115, δ18O=9.9 to 11.9‰) show little overlap with those of the diorites. Most probably, the granitic magmas were derived from metapelitic sources characterized by variable amounts of garnet and plagioclase. This is suggested by relatively high molar ratios of Al2O3/(MgO+FeOtot) and K2O/Na2O, in combination with low ratios of CaO/(MgO+FeOtot), variable values of Sr/Nd, Eu/Eu*[=Eucn/(Smcn × Gdcn)0.5] and (Tb/Yb)cn (cn=chondrite-normalized) as well as variable abundances of Sc and Y. Whole-rock initial isotopic signatures of mafic microtonalitic enclaves (ɛNd=−4.6 to −5.2; 87Sr/86Sr=0.7060 to 0.7073; δ18O ∼8.1‰) are similar to those of the low ɛNd diorites. Plagioclase concentrates from a granite sample and a mafic microtonalitic enclave are characterized by initial 87Sr/86Sr ratios that are significantly higher than those of their bulk rock systems suggesting incorporation of high 87Sr/86Sr crustal material into the magmas. Field relationships and petrographic evidence suggest that the Oberkirch pluton originated by at least three pulses of granitic magma containing mafic magma globules. In-situ hybridization between the different magmas was limited. Late injection of dioritic magma into the almost solidified granitic southern unit resulted in the formation of more or less continuous synplutonic dikes surrounded by relatively thin hybrid zones. Received: 30 April 1999 / Accepted: 6 August 1999  相似文献   

10.
This paper presents detailed mineral chemical, element geochemical and Sr–Nd–Hf isotopic data for the Late Jurassic (155?±?4 Ma) lamprophyre dikes in the Liaodong Peninsula, NE China. The lamprophyres are shoshonitic and geochemically fall into three groups: Group I has relatively high SiO2 (52.5–57.0 wt.%), low MgO (5.5–8.3 wt.%) and compatible trace element (e.g. Cr?=?128–470 ppm) contents, high initial 87Sr/86Sr ratios (0.7093–0.7117), and low εNd (T) values (?9.6 to ?12.1); Group II has relatively low SiO2 (44.8–50.0 wt.%), high MgO (10.8–14.2 wt.%) and compatible trace element (e.g. Cr?=?456–1,041 ppm) contents, low initial 87Sr/86Sr ratios (0.7073–0.7087), and high εNd (T) values (?1.4 to ?2.9); Group III is transitional between the two in all elemental and isotopic compositions. Interpretation of the elemental and isotopic data suggests that the lamprophyric melts were derived by partial melting of subcontinental lithospheric mantle (SCLM) at a depth of 60–80 km (group I), decompression melting of upwelling asthenosphere at 60–100 km (group II), and mixing between the SCLM-derived and asthenosphere-derived melts (group III). It is assumed that the local SCLM was detached at a depth of 60–80 km by the 155 Ma ago. A continental arc-rifting related to the Palaeo-Pacific plate subduction is favored as a geodynamic force for such a cratonic lithosphere detachment.  相似文献   

11.
ABSTRACT

Metatexite and diatexite migmatites are widely distributed within the upper amphibolite and granulite-facies zones of the Higo low-P/high-T metamorphic terrane. Here we report Nd–Sr isotopic and whole rock composition data from an outcrop in the highest-grade part of the granulite-facies zone, in which diatexite occurs as a 3 m-thick layer between 2 m-thick layers of stromatic-structured metatexite within pelitic gneiss. The metatexite has Nd–Sr isotopes and whole rock compositions similar to those of the gneiss, but the diatexite shows the reverse. The diatexite has a higher εNd(t) and 147Sm/144Nd ratio (εNd(t) = ?0.5; 147Sm/144Nd = 0.1636) than the gneiss (εNd(t) = ?2.1; 147Sm/144Nd = 0.1287) and metatexite (εNd(t) = ?3.1; 147Sm/144Nd = 0.1188). The (87Sr/86Sr)initial and 87Rb/86Sr of the diatexite ((87Sr/86Sr)initial = 0.70568; 87Rb/86Sr = 0.416) are lower than those of the gneiss ((87Sr/86Sr)initial = 0.70857; 87Rb/86Sr = 1.13) and metatexite ((87Sr/86Sr)initial = 0.70792; 87Rb/86Sr = 1.11). The metatexite and gneiss show enrichment of Th and depletion of P and Eu and have a similar chondrite-normalized REE pattern, which shows steep LREE–MREE-enriched and gently declining HREE patterns and negative Eu anomalies, whereas the diatexite shows enrichment of Sr and depletion of Th and Y, and exhibits gently declining LREE and steeply declining HREE pattern and weak Eu depletion. The metatexite migmatite is interpreted to have formed by in situ partial melting in which the melt did not migrate from the source, whereas the diatexite migmatite included an externally derived melt with a juvenile component. The Cretaceous high-temperature metamorphism of the Higo metamorphic terrane is interpreted to reflect emplacement of mantle-derived basalts under a volcanic arc along the eastern margin of the Eurasian continent, and mass transfer and advection of heat via hybrid silicic melts from the lower crust.  相似文献   

12.
Summary Covering a vast area of the northern Siberian platform are the Siberian flood basalts (SFB), which make up one of the world’s largest magmatic provinces. Along the northeastern margin of the SFB province lies the Maymecha-Kotuy alkaline-ultramafic complex, consisting of a large volume of alkaline lavas, numerous dykes, and the Guli massif together with numerous other, smaller alkaline plutons. The genetic link between the SFB and the Maymecha-Kotuy complex continues to be a subject of active debate. Although the rocks in both units have essentially the same age close to the Permian-Triassic boundary, questions remain as to the relative order of emplacement and the contributing source materials of each lithology. This study builds upon earlier petrologic, geochemical, and isotopic work to further an understanding of the relationship between SFB and alkaline rocks. A whole-rock U-Pb age of 250 ± 9 Ma was determined for the Guli massif, which lies within the range of ages previously reported for the SFB. The Pb isotopic composition of the Guli rocks plot mainly in the lower portion of the OIB field, and dunite and carbonatite extend downward into the MORB field suggesting for them a more depleted source than the one that produced the SFB. The combined Pb, Sr, and Nd isotopic systematics of the SFB and the Guli alkaline rocks enable the identification of several discrete source components. The first component dominates many of the Guli rocks and is characterized by low 87Sr/86Sr (0.7031 to 0.7038), high εNd (+5.35 to +3.97), and relatively unradiogenic Pb (206Pb/204Pb = 17.88–18.31; 207Pb/204Pb = 15.38–15.46; 208Pb/204Pb = 37.33–37.70), which we associate with the depleted (MORB source) mantle. The second component representing most of the SFB demonstrates a notable chemical and isotopic uniformity with 87Sr/86Sr values of 0.7046 to 0.7052, εNd values of 0 to +2.5, and an average Pb isotopic composition of 206Pb/204Pb = 18.3, 207Pb/204Pb = 15.5, and 208Pb/204Pb = 38.0. This component, making up the majority of SFB, is speculated to be a relatively primitive lower mantle plume with a near-chondritic signature. Contamination by upper and lower continental crustal material, designated as components 3 and 4, is postulated to explain the isotopic characteristics of some of the higher SiO2 Guli rocks and SFB. Finally, metasomatic processes associated with the invasion of the Siberian super-plume add a fifth component responsible for the extreme enrichment in rare-earth and related elements found in some Guli rocks and SFB.  相似文献   

13.
We provide data on the geochemical and isotopic consequences of nonmodal partial melting of a thick Jurassic pelite unit at mid-crustal levels that produced a migmatite complex in conjunction with the intrusion of part of the southern Sierra Nevada batholith at ca. 100 Ma. Field relations suggest that this pelitic migmatite formed and then abruptly solidified prior to substantial mobilization and escape of its melt products. Hence, this area yields insights into potential mid-crustal level contributions of crustal components into Cordilleran-type batholiths. Major and trace-element analyses in addition to field and petrographic data demonstrate that leucosomes are products of partial melting of the pelitic protolith host. Compared with the metapelites, leucosomes have higher Sr and lower Sm concentrations and lower Rb/Sr ratios. The initial 87Sr/86Sr ratios of leucosomes range from 0.7124 to 0.7247, similar to those of the metapelite protoliths (0.7125–0.7221). However, the leucosomes have a much wider range of initial εNd values, which range from −6.0 to −11.0, as compared to −8.7 to −11.3 for the metapelites. Sr and Nd isotopic compositions of the leucosomes, migmatites, and metapelites suggest disequilibrium partial melting of the metapelite protolith. Based on their Sr, Nd, and other trace-element characteristics, two groups of leucosomes have been identified. Group A leucosomes have relatively high Rb, Pb, Ba, and K2O contents, Rb/Sr ratios (0.15<Rb/Sr<1.0), and initial εNd values. Group B leucosomes have relatively low Rb, Pb, Ba, and K2O contents, Rb/Sr ratios (<0.15), and initial εNd values. The low Rb concentrations and Rb/Sr ratios of the group B leucosomes together suggest that partial melting was dominated by water-saturated or H2O-fluxed melting of quartz + feldspar assemblage with minor involvement of muscovite. Breakdown of quartz and plagioclase with minor contributions from muscovite resulted in low Rb/Sr ratios characterizing both group A and group B leucosomes. In contrast, group A leucosomes have greater contributions from K-feldspar, which is suggested by: (1) their relatively high K concentrations, (2) positive or slightly negative Eu anomalies, and (3) correlation of their Pb and Ba concentrations with K2O contents. It is also shown that accessory minerals have played a critical role in regulating the partitioning of key trace elements such as Sm, Nd, Nb, and V between melt products and residues during migmatization. The various degrees of parent/daughter fractionations in the Rb–Sr and Sm–Nd isotopic systems as a consequence of nonmodal crustal anatexis would render melt products with distinct isotopic signatures, which could profoundly influence the products of subsequent mixing events. This is not only important for geochemical patterns of intracrustal differentiation, but also a potentially important process in generating crustal-scale as well as individual pluton-scale isotopic heterogeneities.  相似文献   

14.
High-K mafic alkalic lavas (5.4 to 3.2 wt% K2O) from Deep Springs Valley, California define good correlations of increasing incompatible element (e.g., Sr, Zr, Ba, LREE) and compatible element contents (e.g., Ni, Cr) with increasing MgO. Strontium and Nd isotope compositions are also correlated with MgO; 87Sr/86Sr ratios decrease and ɛNd values increase with decreasing MgO. The Sr and Nd isotope compositions of these lavas are extreme compared to most other continental and oceanic rocks; 87Sr/86Sr ratios range from 0.7121 to 0.7105 and ɛNd values range from −16.9 to −15.4. Lead isotope ratios are relatively constant, 206Pb/204Pb ∼17.2, 207Pb/204Pb ∼15.5, and 208Pb/204Pb ∼38.6. Depleted mantle model ages calculated using Sr and Nd isotopes imply that the reservoir these lavas were derived from has been distinct from the depleted mantle reservoir since the early Proterozoic. The Sr-Nd-Pb isotope variations of the Deep Springs Valley lavas are unique because they do not plot along either the EM I or EM II arrays. For example, most basalts that have low ɛNd values and unradiogenic 206Pb/204Pb ratios have relatively low 87Sr/86Sr ratios (the EM I array), whereas basalts with low ɛNd values and high 87Sr/86Sr ratios have radiogenic 206Pb/204Pb ratios (the EM II array). High-K lavas from Deep Springs Valley have EM II-like Sr and Nd isotope compositions, but EM I-like Pb isotope compositions. A simple method for producing the range of isotopic and major- and trace-element variations in the Deep Springs Valley lavas is by two-component mixing between this unusual K-rich mantle source and a more typical depleted mantle basalt. We favor passage of MORB-like magmas that partially fused and were contaminated by potassic magmas derived from melting high-K mantle veins that were stored in the lithospheric mantle. The origin of the anomalously high 87Sr/86Sr and 208Pb/204Pb ratios and low ɛNd values and 206Pb/204Pb ratios requires addition of an old component with high Rb/Sr and Th/Pb ratios but low Sm/Nd and U/Pb ratios into the mantle source region from which these basalts were derived. This old component may be sediments that were introduced into the mantle, either during Proterozoic subduction, or by foundering of Proterozoic age crust into the mantle at some time prior to eruption of the lavas. Received: 28 February 1997 / Accepted: 9 July 1998  相似文献   

15.
The Saurashtra region in the northwestern Deccan continental flood basalt province (India) is notable for compositionally diverse volcano-plutonic complexes and abundant rhyolites and granophyres. A lava flow sequence of rhyolite-pitchstone-basaltic andesite is exposed in Osham Hill in western Saurashtra. The Osham silicic lavas are Ba-poor and with intermediate Zr contents compared to other Deccan rhyolites. The Osham silicic lavas are enriched in the light rare earth elements, and have εNd (t = 65 Ma) values between −3.1 and −6.5 and initial 87Sr/86Sr ratios of 0.70709-0.70927. The Osham basaltic andesites have initial εNd values between +2.2 and −1.3, and initial 87Sr/86Sr ratios of 0.70729-0.70887. Large-ion-lithophile element concentrations and Sr isotopic ratios may have been affected somewhat by weathering; notably, the Sr isotopic ratios of the silicic and mafic rocks overlap. However, the Nd isotopic data indicate that the silicic lavas are significantly more contaminated by continental lithosphere than the mafic lavas. We suggest that the Osham basaltic andesites were derived by olivine gabbro fractionation from low-Ti picritic rocks of the type found throughout Saurashtra. The isotopic compositions, and the similar Al2O3 contents of the Osham silicic and mafic lavas, rule out an origin of the silicic lavas by fractional crystallization of mafic liquids, with or without crustal assimilation. As previously proposed for some Icelandic rhyolites, and supported here by MELTS modelling, the Osham silicic lavas may have been derived by partial melting of hot mafic intrusions emplaced at various crustal depths, due to heating by repetitively injected basalts. The absence of mixing or mingling between the rhyolitic and basaltic andesite lavas of Osham Hill suggests that they reached the surface via separate pathways.  相似文献   

16.
Isotopic ratios of Nd and Sr have been measured in a suite of samples spanning most of the exposed stratigraphy of the Skaergaard intrusion in order to detect and quantify input (such as assimilated wallrock and fresh magma) into the magma chamber during crystallization. Unlike 18O and D, Nd and Sr isotope ratios do not appear to have been significantly affected by circulation of meteoric waters in the upper part of the intrusion. Variations in initial 87Sr/86Sr and Nd suggest that the Skaergaard magma chamber was affected during its crystallization by a small amount (2%–4%) of assimilation of Precambrian gneiss wallrock (high 87Sr/86Sr, low Nd) and possibly recharge of uncontaminated magma. Decreases in Nd and increases in 87Sr/86Sr during the early stages (0%–30%) of crystallization give way to approximately unchanging isotopic ratios through crystallization of the latest-deposited cumulates. Modelling of assimilation-fractional crystallization-recharge processes using these data as constraints shows that the assimilation rate must have been decreasing throughout crystallization. In addition, the isotope data allow replenishment by an amount of uncontaminated magma equal to 20%–30% of the total intrusion mass, occurring either continuously or in pulses over the first 75% of crystallization. Comparison of the recharge models with published Mg/(Mg+Fe2+) data from Skaergaard cumulates shows that the modelled replenishment rates are not inconsistent with available major element data, although significant recharge during the final 25% of crystallization can be ruled out. The isotope data show that the Skaergaard magma could have incorporated only a small amount of the gneiss that it displaced from the floor of the chamber; assimilation appears to have taken place primarily across a partially molten zone that formed at the roof from the wallrock that was dislodged during emplacement. In the latest stages of crystallization (>75% crystallized), the Skaergaard magma may have become stratified into two separately-convecting layers, effectively insulating Layered Series cumulates from further contamination.  相似文献   

17.
A detailed isotopic study of minerals and whole rocks from the Cretaceous Oka complex, Quebec, Canada, shows a very small variation in initial Nd and Sr isotopic compositions. Assuming an age of 109 Ma for the complex, apatite, calcite, garnet, melilite, monticellite, olivine and pyroxene and whole rocks yield a range for initial 87Sr/86Sr of 0.70323–0.70333; and for initial 143Nd/144Nd of 0.51271–0.51284 ( SR(T)= –14.8 to –16.2; Nd(T)=+4.1 to +6.6). The negative SR and positive Nd indicate derivation of the Nd and Sr from a source with a time-integrated depletion in the large-ion lithophile (LIL) elements. This agrees with data from other Canadian carbonatites and confirms that a large part of the Canadian Shield is underlain by a source region depleted in the LIL elements. The new data from Oka suggest that the depleted source may have remained coupled to the continental crust until recent time.  相似文献   

18.
Geochemical and Sr- and Nd-isotopic data have been determined for mafic to intermediate microgranular enclaves and host granitoids from the Early Cretaceous Gudaoling batholith in the Liaodong Peninsula, NE China. The rocks include monzogranite, porphyric granodiorite and quartz diorite. Monzogranites have relatively high 87Rb/86Sr ratios (0.672-0.853), low initial 87Sr/86Sr ratios (0.7052-0.7086) and ε Nd(t) values (−18.5 to −20.9) indicating that they were mainly derived from a newly underplated crustal source with a short crustal residence time. Quartz diorites have high initial 87Sr/86Sr ratios (0.7118-0.7120) and negative ε Nd(t) values (−13.2 to −18.1) coupled with high Al2O3 and MgO contents, indicating they were derived from enriched lithospheric mantle with contributions of radiogenic Sr from plagioclase-rich metagreywackes or meta-igneous rocks, i.e., ancient lower crust. Two groups of enclaves with igneous textures and abundant acicular apatites are distinguished: dioritic enclaves and biotite monzonitic enclaves. Dioritic enclaves have low Al2O3 (13.5-16.4 wt%) and high MgO (Mg# = ∼72.3) concentrations, low initial 87Sr/86Sr ratios (0.7058-0.7073) and negative ε Nd(t) values (∼−7.2), and are enriched in LILEs and LREEs and depleted in HFSEs, suggesting they were derived from an enriched lithospheric mantle source. Biotite monzonitic enclaves have Sr and Nd isotopic compositions similar to the monzogranites, indicating they were crystal cumulates of the parental magmas of these monzogranites. Granodiorites have transitional geochemistry and Nd- and Sr-isotopic compositions, intermediate between the monzogranites, quartz diorites and the enclaves.Geochemical and Sr- and Nd-isotopic compositions rule-out simple crystal-liquid fractionation or restite unmixing as the major genetic link between enclaves and host rocks. Instead, magma mixing of mafic mantle-derived and juvenile crustal-derived magmas, coupled with crystal fractionation and assimilation of ancient lower crust, is compatible with the data. This example shows that at least some calc-alkaline granitoids are not produced by pure intracrustal melting, but formed through a complex, multi-stage hybridization process, involving mantle- and crustal-derived magmas and several concomitant magmatic processes (crystal fractionation, crustal assimilation and crustal anatexis).  相似文献   

19.
Summary The Tyrrhenian border of the Italian peninsula has been the site of intense magmatism from Pliocene to recent times. Although calc-alkaline, potassic and ultrapotassic volcanism overlaps in space and time, a decrease of alkaline character in time and space (southward) is observed. Alkaline ultrapotassic and potassic volcanic rocks are characterised by variable enrichment in K and incompatible elements, coupled with consistently high LILE/HFSE values, similar to those of calc-alkaline volcanic rocks from the nearby Aeolian arc. On the basis of mineralogy and major and trace element chemistry two different arrays can be recognised among primitive rocks; a silica saturated trend, which resulted in formation of leucite-free mafic rocks, and a silica undersaturated trend, charactrerised by leucite-bearing rocks. Initial 87Sr/86Sr and 143Nd/144Nd values of Italian ultrapotassic and potassic mafic rocks range from 0.70506 to 0.71672 and from 0.51173 to 0.51273, respectively. 206Pb/204Pb values range between 18.50 and 19.15, 207Pb/204Pb values range between 15.63 and 15.70, and 208Pb/204Pb values range between 38.35 and 39.20. The general εSr vs. εNd array, along with crustal lead isotopic values, clearly indicates that a continental crustal component has played an important role in the genesis of these magmas. The main question is where this continental crustal component has been acquired by the magmas. Volcanological and petrologic data indicate continental crustal contamination to be a leading process along with fractional crystallisation and magma mixing. Considering, however, only the samples thought to represent primary magmas, which have been in equilibrium with their mantle source, a clearer picture emerges. A large variation of εSr vs. εNd is still observed, with εSr from −2 to +180 and εNd from + 2 to −12. A bifurcation of this array is observed in the samples that plot in the lower right quadrant, with mafic leucite-bearing Roman Province rocks buffered at εSr = + 100 whereas the mafic leucite-free potassic and ultrapotassic rocks point to strongly radiogenic Sr compositions. We may argue that mafic leucite-bearing Roman Province rocks point to εSr and εNd values similar to those of Miocene carbonate sediments whereas mafic leucite-free potassic and ultrapotassic rocks point to a silicate upper crust end-member. Lead isotopes plot well inside the field of island arcs, overlapping the values of pelagic sediments as well, but bifurcation between the samples north and south of Rome is observed. The main characteristic for the mantle source of Italian potassic and ultrapotassic magmas is the clear upper crustal signature acquired prior to partial melting through metasomatic agents released by the subducted slab. In addition, one lithospheric mantle source in the north and an asthenospheric mantle source, pointing to an HIMU reservoir, in the south were recognised. The chemical and isotopic differences observed between the northern and southern sectors of the magmatic region were possibly due to the presence of a carbonate-rich component in the crustal enriching agent in the south. One crustal component might have been generated by melting of silicate metasedimentary rocks or sediments from an ancient subducted slab. The second one might reflect the activity of mostly CO2-rich fluid released more recently by the incipient subduction of carbonate sedimentary rocks. Received February 16, 2000; revised version accepted September 6, 2001  相似文献   

20.
 Alkali basalts and nephelinites from the volcanic province of northern Tanzania contain pyroxene and nepheline that show evidence for chemical and/or isotopic disequilibria with their host magmas. Olivine, pyroxene, nepheline and plagioclase all appear to be partially xenocrystic in origin. Five whole rock/mineral separate pairs have been analyzed for Sr, Nd, and Pb isotopic compositions. The 206Pb/204Pb ratios are distinct by as much as 20.94 (whole rock) vs. 19.10 (clinopyroxene separate). The Sr and Nd isotopic disequilibria vary from insignificant in the case of nepheline, to Δ 87Sr/86Sr of 0.0002 and ΔɛNd of 0.7 in the case of clinopyroxene. The mineral chemistry of 25 samples indicates the ubiquitous presence of minerals that did not crystallize from a liquid represented by the host rock. The northern Tanzanian magmas are peralkaline and exhibit none of the xenocrystic phases expected from crustal assimilation. The disequilibria cannot be the result of mantle source variations. Rather the xenocrystic phases present appear to have been derived from earlier alkali basaltic rocks or magmas that were contaminated by the crust. Material from this earlier magma was then mixed with batches of magma that subsequently erupted on the surface. Disequilibrium in volcanic rocks has potentially serious consequences for the use of whole rock data to identify source reservoirs. However, mass balance calculations reveal that the 206Pb/204Pb isotopic compositions of the erupted lavas were changed by less than 0.25% as a result of this indirect crustal contamination. Received: 15 February 1995 / Accepted: 4 May 1996  相似文献   

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