首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 46 毫秒
1.
In the Dragon Belly cave helictites, a special type of irregular speleothem, are found, which grew on stalactites in all vertical and horizontal directions without any affinity to gravity. Microstructural and mineralogical analyses of this stalactite–helictite system indicate that its evolution is initiated by clogging of the central stalactite channel at its tip, probably when the cave was flooded by muddy water. Clogging caused the formation of secondary channels (≈0.2 mm in diameter) for water passage through the outer surface of the stalactite, where helictites start to grow. The secondary channel passes into the central channel of the helictite.The helictites consist of stacked idiomorphic calcite crystals with uniform orientation. Growth of calcite is essentially controlled by water transfer through the central channel and via canalicules (narrow channels of ≈0.05 mm in diameter) following the crystal boundaries of the calcite mesocrystal induced by capillary hydrostatic forces. At straight parts of the helictites calcite crystals are almost uniform in size, but at bended parts crystals are significantly smaller inside (≤0.1 mm in length) than outside of the bend (≤0.5 mm). It is proposed that the difference in calcite volume (larger crystals) vs. the inside of the bend leads to a helix form, which explains the origin of the term helictite.The Sr and Ba concentrations measured by laser ablation along helictites can be explained by cation incorporation during calcite precipitation close to equilibrium. Dilution effects caused by seasonality control the elemental distribution in the helictite, which result in a positive correlation between Sr and Ba. Variability of Mg is unrelated with Sr and Ba, and is probably due to the incongruent dissolution of Mg–calcite from the host rock.  相似文献   

2.
  相似文献   

3.
The geochemistry and extractability of Cd in the phosphorite deposits of Hahotoé-Kpogamé (southern Togo) have been studied using various methodologies such as Cd distribution in profiles, grain-size dependence analysis of Cd content, Cd localization using scanning electron microscopy (SEM), sequential acid extraction, and a leaching experiment with artificial seawater. Results demonstrate that in the phosphorite deposits of Hahotoe-Kpogame, Cd is enriched by a factor of 157 compared to shale and by a factor of 3 compared to average world phosphorite composition. The main carrier of Cd appears to be apatite. This is evidenced by significant high positive correlations between the Cd content and P2O5 (in bulk sedimentr = 0.7 and in the 1–0.2 mm fraction r = 0.9). The grain-size dependence of Cd contents (concentrations decreasing with decreasing grain size) and SEM analysis supports these conclusions. Secondary Cd carriers include calcite, goethite, and various bone fragments. Sequential extraction tests with acetic acid and EDTA show an extraction rate reaching up to 40%. Leaching experiments with artificial seawater show evidence of Cd release in seawater. This leads to the conclusion that the processing of phosphorite by wet sieving using seawater and dumping of phosphorite tailings into the coastal waters of Togo can be a major source of marine pollution with Cd.  相似文献   

4.
Fossil capybaras were long regarded as composed of numerous taxa, each one endemic to a particular area, a scenario completely different from the one shown by the living species. The interpretation of the record according to new criteria of ontogenetic change has demonstrated that they are useful for biocorrelation because their members have short biochrons with wide geographic distribution. The levels with capybaras of each locality would represent a short lapse within the bearing lithostratigraphic units. In turn, they would also represent short intervals within the temporal extension proposed for each Stage/Age or SALMA. All the late Miocene–Pliocene records of capybaras were analyzed and a chronological scheme was built mainly for Argentina, where records are most abundant. Numerical ages and magnetostratigraphic studies contribute to correlate this scheme with the global time scale. The Chasicoan SALMA would be correlated with part of the Tortonian Stage/Age; the Huayquerian SALMA with the late Tortonian-Messinian, and it could even extend to the earliest Zanclean. The Montehermosan SALMA would be restricted to the Zanclean. The Chapadmalalan SALMA would be correlated with the late Zanclean-early Piacenzian.  相似文献   

5.
According to the myth, ooid-rich sediments in Cleopatra Beach (Sedir Island, Turkey) were brought by ships from Alexandria Beach (Egypt) by the Roman leader, Marcus Antonius, for his lover Cleopatra. Ooids of both beaches have been compared in terms of sedimentology, mineralogy and geochemistry to determine reality of the myth of love. Sieve analyses exhibit that sediments of Cleopatra Beach are slightly better sorted than Alexandria Beach sediments, and have relatively smaller sized ooids, interpreted to represent a relatively less agitated environment. All ooids are composed mainly of aragonite characterized by high Sr contents (>8600 mg/kg). Hierarchical Cluster Analysis, the cross-plot of δ18Oaragonite versus δ13Caragonite values of ooids, and the presence of detrital grains such as gneiss and schist hint on two distinct groups of samples that correspond to the Cleopatra and Alexandria Beach ooids. These results suggest that the myth may not be realistic, and the ooids on the shore of Sedir Island were formed in-situ, e.g., during the Late Holocene.  相似文献   

6.
Batch adsorption and dissolution experiments with lepidocrocite (γ-FeOOH) and two siderophores, desferrioxamine B (DFOB) and aerobactin, were performed between pH 3 and 8 in the dark and under irradiation with UV-visible light. The increase in surface concentrations of adsorbed DFOB with increasing pH was explained in terms of electrostatic interactions between the protonated and charged terminal amine group of DFOB surface complexes and the charged lepidocrocite surface. The adsorption of aerobactin was consistent with the typical anion-like adsorption behavior of low molecular weight organic acids and indicated that the adsorption properties are strongly determined by the carboxylic acid groups. The adsorption experiments revealed furthermore that the Fe(III)-DFOB solution complex has a very low affinity for the surface, in contrast to Fe(III)-aerobactin solution complexes. In accordance with a surface-controlled mechanism of ligand-promoted dissolution, we found a linear correlation between dissolution rates of lepidocrocite and the surface concentrations of adsorbed DFOB. In the dark, 6- to 8-fold lower dissolution rate coefficients were determined for aerobactin in comparison to DFOB. These results suggested that aerobactin forms surface complexes that are less dissolution-active, characterized by a higher degree of multinuclear surface complexation and/or by less dissolution-active coordination modes of the involved iron-binding groups. For both DFOB and aerobactin, dissolution rate coefficients increased significantly under irradiation with UV-visible light. This increase was interpreted in terms of light-induced reduction of surface Fe(III), primarily by intrinsic photochemical processes of the lepidocrocite bulk phase, based on the observed photoreductive dissolution in the absence of organic ligands between pH 3 and 6. We hypothesize that the α-hydroxycarboxylate group of aerobactin may form a surface complex that additionally promotes photoreductive dissolution by a ligand-to-metal charge-transfer (LMCT) reaction, similar to citrate. However, LMCT reactions involving the α-hydroxycarboxylate group of aerobactin are rather ineffective, based on the comparison of light-induced dissolution rate coefficients determined in the presence of aerobactin and citrate.  相似文献   

7.
The paper presents original authors' data on the O, H, C, S, and Sr isotopic composition of water and sediments from the basins into which the Aral Sea split after its catastrophic shoaling: Chernyshev Bay (CB), the basin of the Great Aral in the north, Lake Tshchebas (LT), and Minor Sea (MS). The data indicate that the δ18О, δD, δ13C, and δ34S of the water correlate with the mineralization (S) of the basins (as of 2014): for CB, S = 135.6‰, δ18О = 4.8 ± 0.1‰, δD = 5 ± 2‰, δ13C (dissolved inorganic carbon, DIC) = 3.5 ± 0.1‰, δ34S = 14.5‰; for LT, S = 83.8‰, δ18О = 2.0 ± 0.1‰, δD =–13.5 ± 1.5‰, δ13C = 2.0 ± 0.1‰, δ34S = 14.2‰; and for MS, S = 9.2‰, δ18О =–2.0 ± 0.1‰, δD =–29 ± 1‰, δ13C =–0.5 ± 0.5‰, δ34S = 13.1‰. The oxygen and hydrogen isotopic composition of the groundwaters are similar to those in MS and principally different from the artesian waters fed by atmospheric precipitation. The mineralization, δ13С, and δ34S of the groundwaters broadly vary, reflecting interaction with the host rocks. The average δ13С values of the shell and detrital carbonates sampled at the modern dried off zones of the basins are similar: 0.8 ± 0.8‰ for CB, 0.8 ± 1.4‰ for LT, and –0.4 ± 0.3‰ for MS. The oxygen isotopic composition of the carbonates varies much more broadly, and the average values are as follows: 34.2 ± 0.2‰ for CB, 32.0 ± 2.2‰ for LT, and 28.2 ± 0.9‰ for MS. These values correlate with the δ18O of the water of the corresponding basins. The carbonate cement of the Late Eocene sandstone of the Chengan Formation, which makes up the wave-cut terrace at CB, has anomalously low δ13С up to –38.5‰, suggesting origin near a submarine methane seep. The δ34S of the mirabilite and gypsum (11.0 to 16.6‰) from the bottom sediments and young dried off zone also decrease from CB to MS in response to increasing content of sulfates brought by the Syr-Darya River (δ34S = 9.1 to 9.9‰) and weakening sulfate reduction. The 87Sr/86Sr ratio in the water and carbonates of the Aral basins do not differ, within the analytical error, and is 0.70914 ± 0.00003 on average. This value indicate that the dominant Sr source of the Aral Sea is Mesozoic–Cenozoic carbonate rocks. The Rb–Sr systems of the silicate component of the bottom silt (which is likely dominated by eolian sediments) of MS and LT plot on the Т = 160 ± 5 Ma, I0 = 0.7091 ± 0.0001, pseudochron. The Rb–Sr systems of CB are less ordered, and the silt is likely a mixture of eolian and alluvial sediments.  相似文献   

8.
Doklady Earth Sciences - Thermodynamic calculations on the impact of carbonate–bicarbonate fluids cooling from 500 to 100°C on a monazite + calcite association with a simultaneous...  相似文献   

9.
Lithology and Mineral Resources - The Imnyakh Formation (1500–1800 m thick), which is developed east of the Mama–Bodaibo Synclinorium (inner zone of the Patom Upland), comprises...  相似文献   

10.
  相似文献   

11.
Mainly high-K, calc-alkaline, Late Miocene to Pliocene volcanic rocks cropped out of the Konya area in Central Anatolia, Turkey. The volcanic rocks are predominantly andesitic to dacitic in composition and rarely basalt, basaltic andesite, basaltic trachyandesite and pyroclastics. Kaolinite, illite, Ca-montmorillonite, alunite, jarosite, minamiite and silica polymorphs were formed by widespread and intense hydrothermal alteration in or around the volcanic products. To investigate the effects of hydrothermal alteration on the chemistry of volcanic rocks, the whole rock chemical composition (major and trace elements, including rare-earth elements (REE) was analysed. The results of the study demonstrate notable differences in the REE behaviour in the different sample groups. REE trends of fresh parent rocks to weakly-, moderately-altered, kaolinitic and alunitic rocks are characterised by strong LREE enrichment ((La/Lu)cn = 14.57, 11,8 to 15.20, 4.54 to 13.30, 12.5 to 24.2 and 34.6 to 47.26, respectively). Most of the samples have pronounced negative and/or weakly-negative Eu anomalies ranging from 0.75 to 0.98 while three samples have weakly-positive Eu anomalies. LRE element contents are higher than those of HREE in the samples. The LRE elements were strongly enriched in the kaolinitic and alunitic alteration; in weakly- and moderately-altered rocks. LREE are nearly immobile whereas HRE elements show different behaviour in different rock groups. The HFS and TRT elements are slightly mobilised in weakly-altered rocks, but enriched in other alteration types. Elements commonly assumed to be immobile (e.g. Y, Zr, Nb, Hf, TiO2, Al2O3, REE) show variation in mass calculation. LIL elements showed enrichment over LREE and MREE, and similar behaviour, in contrast with HFSE. A clear increment of trans-transition elements (TRTE) was found mainly in alunitic and partly in kaolinitic samples.  相似文献   

12.
The F–(Ba–Pb–Zn) ore deposits of the Zaghouan District, located in NE Tunisia, occur as open space fillings or stratabound orebodies, hosted in Jurassic, Cretaceous and Tertiary layers. The chondrite-normalized rare earth element (REE) patterns may be split into three groups: (i) “Normal marine” patterns characterizing the wallrock carbonates; (ii) light REE (LREE) enriched (slide-shaped) patterns with respect to heavy REE (HREE), with small negative Ce and Eu anomalies, characteristic of the early ore stages; (iii) Bell-shaped REE patterns displaying LREE depletion, as well as weak negative Ce and Eu anomalies, characterizing residual fluids of subsequent stages. The 87Sr/86Sr ratios (0.707654–0.708127 ± 8), show that the Sr of the epigenetic carbonates (dolomite, calcite) and ore minerals (fluorite, celestite) are more radiogenic than those of the country (Triassic, Jurassic, Cretaceous, lower Miocene) sedimentary rocks. The uniformity of this ratio, throughout the District, provides evidence for the isotopic homogeneity and, consequently, the identity of the source of the mineralizing fluids. This signature strongly suggests that the radiogenic Sr is carried by Upper Paleozoic basinal fluids.The δ34S values of barite, associated to mineralizations, are close to those of the Triassic sea water (17‰). The δ34S values of sulfide minerals range from − 13.6‰ to + 11.4‰, suggesting two sulfur-reduced end members (BSR/TSR) with a dominant BSR process.Taking account of the homogeneity in the Pb-isotope composition of galenas (18.833–18.954 ± 0.001, 15.679–15.700 ± 0.001 and 38.690–38.880 ± 0.004, for the 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios respectively), a single upper crustal source for base-metals is accepted. The Late Paleozoic basement seems to be the more plausible source for F–Pb–Zn concentrated in the deposits. The genesis of the Zaghouan District ore deposits is considered as the result of the Zaghouan Fault reactivation during the Late Miocene period.  相似文献   

13.
正Columbia(Nuna)is a Paleo-Mesoproterozoic supercontinent that was assembled during global 2.0–1.8Ga collisional events,underwent long-lived,subductionrelated accretion at key continental margins in the period  相似文献   

14.
The Gurpi Formation in the southwest of Iran has been studied for microfacies and bulk organic geochemistry in order to elucidate its depositional environment and petroleum source rock characteristics. The obtained results ended up with four types of organic facies and three types of microfacies through the formation. Three microfacies types differentiated including Pelagic mudstone Wackstone, microbioclast Packstone and bioclastic Packstone reflect a distal outer ramp or basinal environment. Combination of palynofacies and organic geochemistry resulted in differentiation of four organic facies corresponding to organic facies B, BC, C and CD of Jones 1987. Detailed organic facies shows that the formation is characterized by low values of TOC, high percentages of amorphous organic matter and black phytoclasts, rare marine algae thereby representing a mixture of terrestrial and marine kerogen that confirm the formation was deposited in a distal anoxic to oxic condition. The formation shallows upward to the Microbioclast Packstone facies below the Lopha Member reaching its minimum depth in boundstones of this member in uppermost Campanian and then is followed by stagnant condition and high contents of organic matter in suboxic to anoxic condition that favoured accumulation of organic matter in early Maastrichtian. Organic geochemical and petrographical data indicate that the formation is not potentially suitable for petroleum production except for the minor interval (organic facies 2) in early Maastrichtian. Tmax values vary between 340 and 440 °C confirming immaturity trends indicated by Rock-Eval data.  相似文献   

15.
Please refer to the attachment(s) for more details  相似文献   

16.
An integrated stratigraphic analysis has been made of the Tarcău Nappe (Moldavidian Domain, Eastern Romanian Carpathians), coupled with a geochemical study of organic-rich beds. Two Main Sequence Boundaries (Early Oligocene and near to the Oligocene–Aquitanian boundary, respectively) divide the sedimentary record into three depositional sequences. The sedimentation occurred in the central area of a basin supplied by different and opposite sources. The high amount of siliciclastics at the beginning of the Miocene marks the activation of the “foredeep stage”. The successions studied are younger than previously thought and they more accurately date the deformation of the different Miocene phases affecting the Moldavidian Basin. The intervals with black shales identified are related to two main separate anoxic episodes with an age not older than Late Rupelian and not before Late Chattian. The most important organic-rich beds correspond to the Lower Menilites, Bituminous Marls and Lower Dysodilic Shales Members (Interval 2). These constitute a good potential source rock for petroleum, with homogeneous Type II oil-prone organic matter, highly lipidic and thermally immature. The deposition of black shales has been interpreted as occurring within a deep, periodically isolated and tectonically controlled basin.  相似文献   

17.
There are several source rock units in the Zagros Basin, but the Cretaceous Kazhdumi and Paleogene Pabdeh formations probably have produced the majority of the commercial hydrocarbons in this area. Among the hydrocarbon provinces of Iran, the Dezful Embayment, which is located southwest of Zagros Mountains, is one of the most prolific regions in the Middle East. Numerous studies have been made in the northern part of the Dezful Embayment, but relatively few have been done in its southern part. The present study focuses on organic matter characterization of two potential source rocks (Kazhdumi and Pabdeh formations) in southern part of the Dezful Embayment. Cuttings samples (114) were collected from 10 wells and evaluated using Rock–Eval pyrolysis and organic petrography in order to characterize the content and type of organic matter and thermal maturity. The results showed that the average total organic carbon (TOC) content of Kazhdumi and Pabdeh formations are 2.48 and 1.62 wt%, respectively. The highest TOC contents for both formations are found in the northern compartment and decreased gradually toward the south. Pyrolysis data reveal that organic matter has a fair to very good hydrocarbon generation potential and are classified as Type II–III and Type III. Rock–Eval Tmax and vitrinite reflectance show that the majority of samples are in the early mature to mature stage of the oil generation window.  相似文献   

18.
Please refer to the attachment(s) for more details.  相似文献   

19.
The Paleoproterozoic terranes (Birimian) of West Africa are well known to host numerous economic gold mineralizations. The Angovia gold mineralization is located in a brecciated and mylonitic zone within the Birimian greenstones. The sulfide–gold mineralization is mainly represented by gold associated with pyrite and chalcopyrite. A fluid inclusion study undertaken on mineralized quartz veins revealed the presence of aqueous-carbonic (CO2–H2O) fluids, the association of carbonic (CO2) and early aqueous fluids, followed by later aqueous (H2O-salt) and finally nitrogen-rich fluids. Entrapment of the initial homogeneous aqueous-carbonic fluids prior to fluid immiscibility depicts the evolution of the P–T conditions during the exhumation of the terranes after the peak of green-schist metamorphism. The CO2 rich-fluid occurs especially in gold-bearing quartz, and are considered as the main evidence of the ore-forming process in the gold-bearing quartz veins. It is considered as a product of immiscibility of the CO2–H2O parent. The volatile fraction of carbonic and aqueous-carbonic fluid inclusions is dominated by CO2, containing minor amounts of N2, even smaller amounts of CH4 and sporadically, H2S. The aqueous-carbonic fluids have moderate salinity (3–10 wt.% eq. NaCl). Late aqueous and N2 – (CH4–CO2) fluids are considered as later, unrelated to the main ore stage, and were trapped during the cooling of the hydrothermal system from 300 to 200 °C.The immiscibility has been favored by a strong pressure drop, the main trapping P–T conditions being 320–370 °C and 105–135 MPa. The mineralizing process is likely related to the immiscibility event, which was probably favored by the release of the fluid pressure after fracturing along the main shear zones. The ore process is likely to have occurred along the main shear zones or related secondary structures affected by cycling of the fluid pressure and quartz sealing–fracturing processes. The superimposed process can also explain the relative complexity of the quartz textures and fluid inclusion microfractures, and the rather wide range in the density of both parent fluid and CO2-dominated fluid.  相似文献   

20.
We consider the correlation between seismicity, variations in the length of day, and geomagnetic jerks. We found that the jerks precede with in-phase variations in the number of strong earthquakes with М > 6.5 and the rate of the length of day in the range of periods of 5–8 years.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号