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1.
Abstract The Rand and Pelona Schists consist of eugeoclinal rock types overlain by continental basement along the Vincent-Chocolate Mountains (VCM) faults. Both schists display inverted metamorphic zonation, defined in part by a systematic variation in composition of calcic to sodic-calcic amphibole in mafic schist structurally upward. The compositional progressions include increase of total A1, A1IV and Ti, but decrease in the ratios of Na/(Na + Ca) to A1/(A1 + Si), and NaM4 to (A1VI+ Fe3++ Ti). These variations imply that structurally high rocks belong to a lower-pressure metamorphic fades series than those at depth. This result is consistent with previous views that the inverted metamorphic zonations represent intact structural sequences.
Amphibole composition is dependent not only on structural position (i.e. P-T ), but also upon bulk-rock composition. The important controls are whole-rock Mg/(Mg + Fe2++ Mn) and Fe3+/Fe2+. The greatest impact of these factors, however, is on the absolute values of Na and Al, rather than their ratio. Thus, interpretation of facies series is not seriously hindered by compositional variability.
Sodic amphibole in epidote blueschists from the Rand Schist is extensively replaced by sodic-calcic amphibole. Sodic-calcic amphibole in the Rand Schist and Pelona Schist is, itself, rimmed by actinolitic amphibole. Similar blueschist to greenschist transitions in other metamorphic terranes are typically attributed to exhumation. In the Rand and Pelona Schists, the sequence probably formed during burial.  相似文献   

2.
Blue-green hornblendes are observed in metabasite assemblages throughout the chlorite, biotite and garnet zones of the southwest Scottish Highlands. Actinolites are common in more Mg-rich metabasites in these zones. At low grade, hornblendes are relatively edenite-rich, and may sometimes occur together with a more Mg-rich, Al-poor actinolite. Within the garnet zone, hornblendes are pargasitic, showing extensive tschermakite substitution. Textural and chemical evidence do not indicate the presence of any miscibility gap between hornblende and actinolite within the chlorite to garnet zones in the southwest Highlands. The occurrence of hornblende-actinolite pairs in metabasites of the Scottish Dalradian, and perhaps also in other metamorphic terrains, is considered to reflect the incomplete chemical equilibration of lower grade actinolitic amphibole during prograde metamorphism, rather than a miscibility gap. The paucity of amphibole compositions intermediate between hornblende and actinolite in many metamorphic terrains is thought to reflect the rapid but continuous change of stable amphibole compositions in metabasites over a small range of increased metamorphic grade.  相似文献   

3.
The Pelona Schist, which forms the lower plate of the Vincent thrust in the San Gabriel Mountains of southern California, has undergone a complex history of folding. The youngest folds in the schist (style 2 folds) range in shape from open to tight and fold both compositional layering and schistosity. These are superposed upon isoclinal folds with axial-plane schistosity (style 1 folds) that, in turn, overprint older isoclinal folds (also called style 1 folds). Samples from the hinges of style 2 folds contain two generations of muscovite. Muscovites of the older generation are parallel to the folded (style 1) schistosity. The newer muscovites recrystallized during and/or after style 2 folding. Microprobe analysis indicates that the two generations of muscovite are very similar in composition, although the new muscovites tend to have slightly higher paragonite and celadonite contents than the old muscovites. From the gross similarity of the two groups of muscovite, it is concluded that the style 1 and style 2 folds were produced during a single progressive deformation. The slightly higher paragonite and celadonite contents of the new muscovites are thought to indicate that both pressure and temperature were increasing during the deformation. This is consistent with the deformation being due to underthrusting of the Pelona Schist beneath the upper plate of the Vincent thrust.  相似文献   

4.
Regional variation in the P–T path of the Sambagawa metamorphic rocks, central Shikoku, Japan has been inferred from compositional zoning of metamorphic amphibole. Rocks constituting the northern part (Saruta River area) exhibit a hairpin type P–T path, where winchite/actinolite grew at the prograde stage, the peak metamorphism was recorded by the growth of barroisite to hornblende and sodic amphibole to winchite/actinolite grew at the retrograde stage. In the southern part (Asemi River area), rocks exhibit a clockwise type P–T path, where barroisite to hornblende core is rimmed by winchite to actinolite. The difference in P–T path could suggest a faster exhumation rate (i.e. more rapid decompression) in the southern than in the northern part. On the other hand, physical conditions of deformation during the exhumation stage have been independently inferred from microstructures in deformed quartz. Recrystallized quartz grains in rocks from the low‐grade (chlorite and garnet) zones are much more stretched in the southern part (aspect ratio ≥ 4.0) than in the northern part (aspect ratio< 4.0), indicating a higher strain rate in the former than in the latter. These facts may indicate that the exhumation and strain rates are correlated (i.e. the exhumation rate increases with increasing the strain rate). The difference in the exhumation rate inferred from amphibole zoning between the northern and southern parts could be explained by an extensional model involving normal faulting, where the lower plate can be exhumed faster than the upper plate due to the displacement along the fault. Furthermore, the model may explain the positive correlation between the exhumation and strain rates, because the lower plate tended to support more stress than the upper plate.  相似文献   

5.
Hydration reactions are direct evidence of fluid–rock interaction during regional metamorphism. In this study, hydration reactions to produce retrograde actinolite in mafic schists are investigated to evaluate the controlling factors on the reaction progress. Mafic schists in the Sanbagawa belt contain amphibole coexisting with epidote, chlorite, plagioclase and quartz. Amphibole typically shows two types of compositional zoning from core to rim: barroisite → hornblende → actinolite in the high‐grade zone, and winchite → actinolite in the low‐grade zone. Both types indicate that amphibole grew during the exhumation stage of the metamorphic belt. Microstructures of amphibole zoning and mass‐balance relations suggest that: (1) the actinolite‐forming reactions proceeded at the expense of the preexisting amphibole; and (2) the breakdown reaction of hornblende consumed more H2O fluid than that of winchite, when one mole of preexisting amphibole was reacted. Reaction progress is indicated by the volume fraction of actinolite to total amphibole, Yact, with the following details: (1) reaction proceeded homogeneously in each mafic layer; (2) the extent of the hornblende breakdown reaction is commonly low (Yact < 0.5), but it increases drastically in the high‐grade part of the garnet zone (Yact > 0.7); and (3) the extent of the winchite breakdown reaction is commonly high (Yact > 0.7). Many microcracks are observed within hornblende, and the extent of hornblende breakdown reaction is correlated with the size reduction of the hornblende core. Brittle fracturing of hornblende may have enhanced retrograde reaction progress by increasing of influx of H2O and the surface area of hornblende. In contrast to high‐grade rocks, the winchite breakdown reaction is well advanced in the low‐grade rocks, where reaction progress is not associated with brittle fracturing of winchite. The high extent of the reaction in the low‐grade rocks may be due to small size of winchite before the reaction.  相似文献   

6.
Abstract Compositions of actinolite, hornblende and cummingtonite, together with pyroxene and plagioclase, are studied in basic intrusions in the Dalradian of north-east Scotland, and the Glen Scaddle complex in the West Moine. Amphibolitization is due to influx of water from the country rocks. Pyroxene compositions are found to have adjusted to the regional metamorphic environment. Owing to the difficulty of diffusion of Al and Si, calcic amphiboles are zoned and commonly contain quartz blebs. Discontinuities in zoning give rise to actinolite-hornblende pairs. Compared with north-east Scotland, disequilibrium is less strong in the Glen Scaddle area: in the latter, plagioclase compositions have been greatly changed, Na partition between hornblende and plagioclase is close to equilibrium, the maximum Al content of hornblende is lower and zoning patterns are more consistent. The Fe/Mg ratio in calcic amphiboles varies with Al content, while approaching equilibrium partition with other minerals. Both zoning patterns and Fe/Mg partition with cummingtonite suggest that Fe/Mg of the calcic amphiboles increases more strongly with increasing (Alvi+Fe3+) than can be explained simply by substitution of Al,Fe3+ for Mg on M2. Model reactions for amphibole formation are constructed. Cummingtonite formed at lower chemical potential of CaO than actinolite: Ca was exchanged for Mg,Fe between orthopyroxene-derived and clinopyroxene-derived local systems. Both cummingtonite and actinolite were formed because of kinetic constraints, as intermediate reaction products: actinolite-hornblende pairs represent disequilibrium. This work suggests that many occurrences of actinolite with hornblende, where the minerals are zoned, may also be due to diffusion kinetics.  相似文献   

7.
Abstract Metre-scale amphibolite boudins in the Cheyenne Belt of south-eastern Wyoming are cut and deformed by shear zones which preserve a full strain transition across 7 cm, from relatively undeformed amphibolite with a relict igneous texture to mylonitic amphibolite with an L-S tectonic fabric. The strain transition is marked by the progressive rotation of amphibole + plagioclase aggregates into parallelism with the shear-zone boundary. An increase in strain magnitude is indicated by development of the tectonic fabric and progressive reduction of amphibole and plagioclase grain size as a result of cataclasis. Bulk chemistry of five samples across a single strain transition shows no significant or systematic variation in major element chemistry except for a minor loss of SiO2, which indicates that the shear zone was a system essentially closed to non-volatile components during metamorphism and deformation. Amphibolites throughout the shear zone consist of amphibole and plagioclase with only minor amounts of quartz, chlorite, epidote, titanite and ilmenite. Within the relatively undeformed amphibolite, amphibole and plagioclase have wide compositional ranges in single thin sections. Amphibole compositions vary from actinolitic hornblende to magnesio-hornblende with increases in Al, Fe, Na and K contents and decreases in Si and Mg that can be modelled as progress along tschermakite, edenite and FeMg-1 exchange vectors from tremolite. Plagioclase ranges from An60 in cores to An30 within grain-boundary domains. With increasing strain magnitude, local variation of amphibole composition decreases as amphibole becomes predominantly magnesio-hornblende. Plagioclase composition range also decreases, although grain-boundary domains still have higher albite content. These petrological data indicate that shear-zone metamorphism was controlled by the magnitude of strain during synmetamorphic deformation. SEM and microprobe imaging indicate that chemical reactions occurred by a dissolution and reprecipitation process during or after cataclastic deformation. This suggests that grain-boundary formation was an important process in the petrological evolution of the shear zone, possibly by providing zones for fluid ingress to facilitate metamorphic reactions. These results highlight the necessity for conducting detailed microstructural evaluation of rocks in order to interpret petrological, isotopic and geochronological data.  相似文献   

8.
 The Middle Miocene Tobe hornfels in the Sanbagawa metamorphic belt, western Shikoku, southwest Japan, is characterized by an abnormally steep metamorphic gradient compared with other hornfelses associated with intrusive bodies. The basic hornfels, originally Sanbagawa greenschist rocks, is divided into the following three metamorphic zones: plagioclase, hornblende, and orthopyroxene. The plagioclase zone is defined by the appearance of calcic plagioclase, the hornblende zone by the assemblage of hornblende+calcic plagioclase+quartz, and the orthopyroxene zone is characterized by the assemblage of orthopyroxene + clinopyroxene + plagioclase + quartz. Calcic amphibole compositions change from actinolite to hornblende as a result of the continuous reactions during prograde metamorphism. Petrographical and thermometric studies indicate a metamorphic temperature range of 300–475°C for the plagioclase zone, 475–680°C for the hornblende zone, and 680–730°C for the orthopyroxene zone. The temperature gradient based on petrological studies is approximately 5°C/m, which is unusually high. Geological and petrological studies demonstrate that the hornfelses were formed by the focusing of high-temperature fluids through zones of relatively high fracture permeability. The steep thermal gradient in the Tobe hornfels body is consistent with a large fluid flux, greater than 8.3 × 10–7 m3 m–2S–1, over the relatively short duration of metamorphism, approximately 100 years. Received: 10 October 1995 / Accepted: 28 May 1996  相似文献   

9.
赣东北高压变质岩的岩石类型、矿物组成与变质过程   总被引：6，自引：1，他引：6  
赣东北高压变质岩包括含硬玉霓辉石钠长角闪片岩、含硬玉霓辉石石英钠长石岩、含霓辉石角闪石英钠长石岩、含霓辉石钠长角闪片岩、蓝透闪石石英钠长石岩、镁钠闪石石英钠长石岩等岩石类型，主要组成脏矿物为硬玉、霓辉石、镁钠闪石、蓝透闪石、镁角闪石、阳起石、石英、钠长石、金红石和榍石。研究表明，高压变质峰期后经历了近等温降压退变质过程。  相似文献   

10.
Abstract A garnet–hornblende Fe–Mg exchange geothermometer has been calibrated against the garnet–clinopyroxene geothermometer of Ellis & Green (1979) using data on coexisting garnet + hornblende + clinopyroxene in amphibolite and granulite facies metamorphic assemblages. Data for the Fe–Mg exchange reaction between garnet and hornblende have been fitted to the equation. In KD=Δ (XCa,g) where KD is the Fe–Mg distribution coefficient, using a robust regression approach, giving a thermometer of the form: with very satisfactory agreement between garnet–hornblende and garnet–clinopyroxene temperatures. The thermometer is applicable below about 850°C to rocks with Mn-poor garnet and common hornblende of widely varying chemistry metamorphosed at low aO2. Application of the garnet–hornblende geothermometer to Dalradian garnet amphibolites gives temperatures in good agreement with those predicted by pelite petrogenetic grids, ranging from 520°C for the lower garnet zone to 565–610°C for the staurolite to kyanite zones. These results suggest that systematic errors introduced by closure temperature problems in the application of the garnet–clinopyroxene geothermometer to the ‘calibration’data set are not serious. Application to ‘eclogitic’garnet amphibolites suggests that garnet and hornblende seldom attain Fe–Mg exchange equilibrium in these rocks. Quartzo-feldspathic and mafic schists of the Pelona Schist on Sierra Pelona, Southern California, were metamorphosed under high pressure greenschist, epidote–amphibolite and (oligoclase) amphibolite facies beneath the Vincent Thrust at pressures deduced to be 10±1 kbar using the phengite geobarometer, and 8–9kbar using the jadeite content of clinopyroxene in equilibrium with oligoclase and quartz. Application of the garnet–hornblende thermometer gives temperatures ranging from about 480°C at the garnet isograd through 570°C at the oligoclase isograd to a maximum of 620–650°C near the thrust. Inverted thermal gradients beneath the Vincent Thrust were in the range 170 to 250°C per km close to the thrust.  相似文献   

11.
Metabasaltic rocks in the Klamath Mountains of California with ‘komatiitic’ major element concentrations were investigated in order to elucidate the origin of the magnesian signature. Trace-element concentrations preserve relict igneous trends and suggest that the rocks are not komatitic basalts, but immature arc rocks and within-plate alkalic lavas. Correlation of ‘excess’ MgO with the volume per cent hornblende (±clinopyroxene) suggests that the presence of cumulus phases contributes to the MgO-rich compositions. Early submarine alteration produced regional δ18O values of +10±1.5%° and shifts in Al2O3, Na2O, and K2O concentrations. Regional metamorphic grade in the study area varies from biotite-zone greenschist facies (350–550°C, c. 3 kbar) southward to prehnite–actinolite facies (200–400°C, ≤3 kbar), but little isotopic or elemental change occurred during the regional recrystallization. The greenschist facies assemblage is actinolitic hornblende + phengite + epidote + sodic plagioclase + microcline + chlorite + titanite + hematite + quartz in Ti-poor metabasaltic rocks; in addition to these phases biotite is present in Ti-rich analogues. Lower grade greenstones contain prehnite and more nearly stoichiometric actinolite. The moderate to low pressures of regional metamorphism are compatible with P–T conditions in a magmatic arc. Later contact metamorphism at 2–2.9±0.5 kbar and at peak temperatures approaching 600° C around the English Peak and Russian Peak granodiorites produced 3–4–km-wide aureoles typified by gradual, systematic increases in the pargasite content of amphibole, muscovite content of potassic white mica, and anorthite content of plagioclase compositions. Metasomatism during contact metamorphism produced further increases in bulk-rock δ18OSMOW of as much as +6%°. Thus, the unusually MgO-rich nature of the Sawyers Bar rocks may be attributed at least partly to metasomatism and the presence of magnesian cumulus phases.  相似文献   

12.
Retrograde coronas of Caledonian age, between clinopyroxene and plagioclase in the Jotun Nappe Complex, Norway, illustrate the effects of diffusion kinetics on mineral distributions among layers and on the compositions of hornblende-actinolite. One corona type comprises a symplectite of epidote + quartz adjacent to plagioclase, and a less well-organized intergrowth of amphibole + quartz replacing clinopyroxene. The observed mineral proportions imply an open-system reaction, but the similarity of Al/Si ratios in reactant plagioclase and product symplectite indicates approximate conservation of Al2O3 and SiO2. The largest inferred open-system flux is a loss of CaO, mostly derived from consumption of clinopyroxene. The approximate layer structure, Pl|Ep + Qtz|Hbl + Qtz|Act±Hbl + Qtz|Cpx, is modelled using the theory of steady-state diffusion-controlled growth with local equilibrium. To obtain a solution, it is necessary to use a reactant plagioclase composition which takes into account aluminous (epidote) inclusions. The results indicate that, in terms of Onsager diffusion coefficients L ii , Ca is more mobile than AL (L CaCa/L AlAl3.) (where means greater than or approximately equal to). This behaviour of Ca is comparable with that of Mg in previously studied coronas around olivine. Si is non-diffusing in the present modelling, because of silica saturation. Oxidation of some Fe2+ to Fe3+ occurs within the corona. Mg diffuses towards its source (clinopyroxene) to maintain local equilibrium. Other coronas consist of two layers, hornblende adjacent to plagioclase and zoned amphibole + quartz adjacent to clinopyroxene. In the zoned layer, actinolitic hornblende forms relict patches, separated from quartz blebs by more aluminous hornblende. A preliminary steady-state, local-equilibrium model of grain-boundary diffusion explains the formation of low-Al and high-Al layers as due to Al immobility. Zoning and replacement are qualitatively explained in terms of evolution of actinolite to more stable aluminous compositions. This is modelled by a non-steady-state modification of the theory, retaining local equilibrium in grain boundaries while relatively steep zoning profiles develop in grain interiors through slow intracrystalline diffusion. Replacement of actinolite by hornblende does not require a change in P–T conditions if actinolite is a kinetically determined, non-equilibrium product. The common preservation of a sharp contact between hornblende and actionolite layers may be explained by ineffectiveness of intracrystalline diffusion: according to the theory, given sufficient grain-boundary Al flux, a metastable actinolite + quartz layer in contact with hornblende may be diffusionally stable and may continue to grow in a steady state.  相似文献   

13.
吴新伟  徐仲元 《岩石学报》2016,32(9):2901-2911
色尔腾山岩群是华北克拉通西部陆块阴山地块早前寒武纪变质基底的主要组成部分,对探讨华北克拉通早前寒武纪基底构造演化有着十分重要的意义。本文根据对营盘湾-东五分子一带的色尔腾山岩群的地质填图、剖面测量、地球化学分析和SHRIMP测年,对色尔腾山岩群的组成、原岩建造、形成环境和形成时代进行了讨论。认为色尔腾山岩群由陈三沟岩组、柳树沟岩组和东五分子岩组组成,陈三沟岩组由灰黑色细粒斜长角闪岩、浅灰色细粒黑云斜长片麻岩夹角闪斜长片麻岩组成;东五分子岩组下段由细粒含石英黑云斜长角闪岩、黑云角闪斜长片麻岩、黑云斜长片麻岩呈韵律产出,顶部为灰白色细粒黑云斜长片麻岩夹薄层磁铁黑云斜长片麻岩,上段为由细粒黑云角闪片岩与浅肉红色黑云长英片麻岩互层,顶部有薄层白色透闪石大理岩;柳树沟岩组以角闪片岩、二云母片岩、二云石英片岩、石榴黑云片岩、黑云母片岩为特征。其原岩总体构成表现为:下部以火山岩为主,上部以碎屑沉积岩和化学沉积岩为主的火山-碎屑沉积建造。火山岩明显富碱,其中酸性火山岩明显富铝、贫镁;具有较高的大离子亲石元素含量、较低的Y和重稀土元素含量;具有轻稀土富集、重稀土亏损的稀土分布形式。地球化学特征与埃达克岩类似,形成于活动大陆边缘的构造环境下。通过对东五分子岩组上部互层产出的细粒长英片麻岩和黑云母片岩分别取样,进行锆石U-Pb SHRIMP测年,分别获得1980±9Ma、1946±16Ma的成岩年龄和1901±15Ma、1893±66Ma的变质年龄。综上所述可以得出,色尔腾山岩群的形成于1.95~1.98Ga之间,是在类似埃达克岩的活动大陆边缘岛弧环境下沉积的,在1.9Ga左右发生碰撞造山而发生变质。  相似文献   

14.
《International Geology Review》2012,54(12):1055-1115
The Isua supracrustal belt (～3.8 Ga) constitutes the oldest accretionary complex in the world. Petrochemical and geothermobarometric studies of more than 1500 rock samples of the Isua belt have enabled us to estimate the extent of regional metamorphism, the petrotectonic environment, and the subduction-zone geothermal gradient in the Archean. The following line of evidence indicates progressive, prograde metamorphism from greenschist (Zone A) through albite-epidote-amphibolite (Zone B) to amphibolite facies (Zones C and D) in the northeastern part of the Isua supracrustal belt: (1) the systematic change of mineral paragenesis in metabasites and metapelites; (2) progressive change of the composition of major metamorphic minerals, including plagioclase, amphibole, chlorite, epidote, and garnet; (3) normal zoning of amphibole and garnet; and (4) the absence of relict minerals of high-grade amphibolitic metamorphism even in the lowest metamorphic zone. Metabasites of the Isua belt vary extremely in Mg#, causing a complex mineral paragenesis throughout the area. For example, a high FeO content of metabasites expands the stability field of hornblende to both lower and higher grades. The compositional and mineralogical characteristics above also indicate that the Isua supracrustal belt underwent a single regional metamorphic event, involving minor contact metamorphism and mylonitization; however, weak ocean-floor metamorphism and low-grade regional metamorphism during accretion cannot be ruled out.

Metamorphic pressures and temperatures are estimated to be 5–7 kbar from garnet-hornblende-plagioclase-quartz geobarometry and 380–550°C from garnet-biotite geothermometry in Zones B to D. These P-T estimates indicate an intermediate P/T ratio metamorphic facies series. Geological investigations and chronological constraints of the Isua metamorphic belt indicate that the regional metamorphism was related to the subduction of Archean lithosphere, and records a geothermal gradient for the Archean subduction zone that is much higher than geotherms for Phanerozoic subduction zones. The high geothermal gradient may have resulted from the young age of subducted lithosphere and high potential temperature of the mantle. The Archean high geothermal gradient led to melting of thick oceanic crust in a thin, descending oceanic plate, creating many huge granitic (tonalite-trondhjemite-granodiorite [TTG]) batholiths. Slab melting changed the oceanic crust (density = 3.07) to denser garnet-bearing assemblages (density = 3.55), implying that TTG melt extraction provided a potential driving force for Archean plate tectonics.  相似文献   

15.
相山地区变质岩划分为４个变质岩带，由南往北依次分布，构成典型的递增变质带。十字石的出现表明变质作用已达到低角闪岩相。获得十字石云母片岩及斜长角闪片岩ＲｂＳｒ等时年龄分别为７１９．７、７２７．６Ｍａ。首次厘定相山变质岩形成于新元古代，而非加里东期变质。其原岩的成岩时代应为前震旦纪  相似文献   

16.
周文孝  葛梦春 《地球科学》2013,38(4):715-724
通过大比例尺填图和剖面研究, 将内蒙古锡林浩特地区的"锡林郭勒杂岩"解体分为3大部分: 一套表壳岩、晚元古代基性-超基性侵入岩和早古生代酸性侵入岩.在此基础上根据变质岩的岩性组合和变形变质特点, 可将其中的表壳岩化分为4个岩性段: 黑云(石榴石)斜长片麻岩, 间夹多层条纹状斜长角闪岩, 在其顶部多见薄层含磁铁石英岩; 中粗粒黑云斜长片麻岩和细粒长英质片麻岩; 混合岩化条带状黑云(角闪)斜长片麻岩, 含石榴石黑云二长片麻岩夹条纹状斜长角闪岩组合; 夕线石黑云斜长片麻岩, 条纹状黑云斜长片麻岩, 间夹含石榴石黑云母石英片岩.通过对比区域内宝音图群、艾勒格庙组、白乃庙群等古老地块的岩石组合, 发现在原岩建造、变质级别、沉积环境等特征上均有区别, 应将这套表壳岩单独厘定为锡林浩特岩群, 它们组成了锡林郭勒微陆块前寒武变质基底岩系, 其地质特征的研究对锡林郭勒微陆块基底的形成和演化及华北板块与西伯利亚板块的构造关系演化有重要意义.   相似文献   

17.
The Hongtoushan copper–zinc deposit is the only large Archean volcanogenic massive sulfide (VMS) deposit in China. This paper presents new information on the timing of metallogenesis and metamorphism of the deposit, including new cathodoluminescence (CL) images, and Th U?1 and LA–ICP–MS U–Pb dating on zircons of the biotite–plagioclase gneiss and plagioclase–amphibole gneiss that host the deposit. The CL images and Th U?1 ratios indicate that the zircons within the gneiss are of metamorphic origin. LA–ICP–MS dating of the plagioclase–amphibole gneiss yielded the upper intercept ages of 2549 Ma, and the biotite–plagioclase gneiss yielded the upper intercept ages of 2552 Ma and 2550 Ma correspondingly, indicating that the mineralization of the deposit occurred at around 2550 Ma. The rims of zircons within these host rocks yielded younger U–Pb ages at 2529, 2520 and 2515 Ma, identical to the age of felsic intrusive rocks in the study area. This suggests that the Hongtoushan VMS deposit underwent initial metamorphism and deformation at around 2520 Ma by the intrusion of granite magmas.  相似文献   

18.
The San Emigdio and related Pelona, Orocopia, Rand and Sierra de Salinas schists of southern California were underplated beneath the southern Sierra Nevada batholith and adjacent southern California batholith along a shallow segment of the subducting Farallon plate in Late Cretaceous to early Tertiary time. These subduction accretion assemblages represent a regional, deeply exhumed, shallowly dipping domain from an ancient slab segmentation system and record the complete life cycle of the segmentation process from initial flattening and compression to final extensional collapse. An important unresolved question regarding shallow subduction zones concerns how the thermal structure evolves during the slab flattening process. New field relationships, thermobarometry, thermodynamic modelling and garnet diffusion modelling are presented that speak to this issue and elucidate the tectonics of underplating and exhumation of the San Emigdio Schist. We document an upsection increase in peak temperature (i.e. inverted metamorphism), from 590 to 700 °C, peak pressures ranging from 8.5 to 11.1 kbar, limited partial melting, microstructural evidence for large seismic events, rapid cooling (825–380 °C Myr?1) from peak conditions and an ‘out and back’P–T path. While inverted metamorphism is a characteristic feature of southern California schists, the presence of partial melt and high temperatures (>650 °C) are restricted to exposures with maximum depositional ages between 80 and 90 Ma. Progressive cooling and tectonic underplating beneath an initially hot upper plate following the onset of shallow subduction provide a working hypothesis explaining high temperatures and partial melting in San Emigdio and Sierra de Salinas schists, inverted metamorphism in the schist as a whole, and the observed P–T trajectory calculated from the San Emigdio body. Lower temperatures in Pelona, Orocopia and Rand schists are likewise explained in the context of this overarching model. These results are consistent with an inferred tectonic evolution from shallow subduction beneath the then recently active Late Cretaceous arc to exhumation by rapid trench‐directed channelized extrusion in the subducted schist.  相似文献   

19.
The prograde amphibole that coexists with chlorite, epidote, muscovite, albite, quartz and hematite in Sanbagawa schists was examined to investigate the relationship between the prograde P-T paths of individual rocks and the metamorphic field gradient in the Sanbagawa metamorphic belt, central Shikoku. The amphibole changes from actinolite, through ferri-winchite and crossite, to barroisite and hornblende with increasing grade along the metamorphic field gradient. However, the sequence of prograde amphibole compositions in each sample varies in different mineral zones. The general scheme can be summarized as: magnesioriebeckite-riebeckite crossite in the upper chlorite zone of lower-grade rocks; crossite or glaucophane barroisite in the garnet zone of medium-grade rocks; and actinolite or winchite barroisite hornblende in the albite-biotite zone of higher-grade rocks. Changes of amphibole composition indicate that the prograde P-T path recorded in the higher-grade rocks was situated on the higher-temperature side of that of the lower-grade rocks and on the lower-pressure side of the metamorphic field gradient. The systematic change of P-T paths implies an increasing d P /d T during continuous subduction. These features can be interpreted as documenting prograde metamorphism within a young subduction zone that has a non-steady-state geotherm.  相似文献   

20.
The Darvel Bay ophiolite consists of a conformable sequence of mantle harzburgite, a gabbro layer of about 2 km thickness, a basalt layer and associated chert-spilite association of Late Cretaceous to Eocene age, and overlying Miocene melange and olistostrome deposits. The ophiolite is an extension into Borneo of the recently inactive Sulu Archipelago non-volcanic arc. Generally the gabbro layer has been converted to banded plagioclase-amphibole gneisses and the basalt layer to crudely foliated epidote amphibolite. Igneous relicts occur sporadically, especially in the lower gabbro horizons. They have either cumulus granular or gabbroic textures and contain diopsidic augite, bronzite, and a dark brown pargasitic hornblende. The labradorite is occasionally clouded. The partitioning of Fe/Mg between the two pyroxenes and the hornblende suggests an igneous paragenesis and the former allocation of these pyroxene-bearing rocks to the granulite facies is now rejected.The basites have undergone metamorphic re-equlibration, frequently sporadic and imperfec, through amphibolite facies, characterized by hornblende, to greenschist facies, characterized by actinolite. Igneous labradorite frequently persists to the lower grades. The partitioning of Ca/Na between amphibole and plagioclase may be correlated with metamorphic grade.Sub sea-floor retrogressive metamorphism, combined with large scale metasomatism resulting from the circulation of hot brine, appears to be the most appropriate mechanism to explain the sodium enrichment in the basalt layer and the imperfect metamorphic re-equilibration of the ophiolite generally.  相似文献   

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