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1.
Dissolution of plagioclase under the physical conditions at shallow to intermediate burial depths is a prime candidate for secondary porosity generation in feldspathic siliciclastic sediments. The diagenetic behavior of granular aggregates of plagioclase feldspar and quartz has been investigated by experimentation performed in a Bridgeman-type pressure vessel. The experiments, each of two weeks duration, simulated pressure-temperature conditions approximating 3.5 km burial depth. By using a double-acting pore-fluid reservoir, solutions of various chemistries were cycled through samples composed of oligoclase or labradorite feldspar and quartz (90:10 wt% respectively).Scanning electron microscope analysis of the post-experiment samples reveals dissolution features and precipitated products. Dissolution voids of 10 microns occur typically in areas of maximum stress such as crack-tips and grain contacts. Dissolution on a larger scale is exemplified by topographical smoothing of grain su faces. The dissolved species are subsequently reprecipitated as Ca-enriched overgrowths (possibly zeolites) and clays. These precipitates are found individually on the scale of 10 microns and collectively as surface coatings on both feldspar and quartz grains. Atomic absorption spectroscopic analyses of the pore fluid suggest that the fluid chemistry is consistent with the observed experimental precipitates.These experiments show that clay coatings are unnecessary precursors to grain surface dissolution and that the diagenetic precipitation is not mineral selective. Also, the mass transfer of the dissolved species appears to be localized because grains displaying both dissolution and precipitation features are commonplace. Volume changes due to mineral transformation/alteration may increase secondary porosity if the dissolved species produced from dissolution are only partially involved in reprecipitation and the remaining dissolved material is flushed out by the pore fluids. However, if the mass transfer is primarily local then permeability would significantly decrease as precipitates may choke the pore throats. 相似文献
2.
3.
Jibamitra Ganguly 《Earth and Planetary Science Letters》1982,61(1):123-126
The thermodynamic relationship between the oxygen isotope fractionation properties of plagioclase and its composition has been derived by treating plagioclase as a “reciprocal solution” consisting of independent cationic and anionic substitutions, namely (NaAl)5+?(CaSi)5+and18O?16O. The results show that the logarithm of the oxygen isotope fractionation factor, α, between plagioclase and a coexisting phase varies linearly with the anorthite content of plagioclase. The proportionality constant is given by the oxygen isotope fractionation factor between albite and anorthite, and has been derived from the experimental data of two groups of workers, O'Neil and Taylor [2] and Matsuhisa et al. [3], on the isotopic fractionation between each plagioclase end-member and aqueous solutions. It is found that O'Neil and Taylor's data on isotopic exchange of plagioclase end-members with only 2–3 M chloride solution, rather than with both pure water and the chloride solution, lead essentially to zero intercept of the ln α(Ab-An) vs. 1/T2 relation, in accord with Bottinga and Javoy's [10] conclusion about the oxygen isotope fractionation between two anhydrous silicates at T<500°C. 相似文献
4.
Field studies and seismic data show that semi-brittle flow of fault rocks probably is the dominant deformation mechanism at the base of the seismogenic zone at the so-called frictional-plastic transition. As the bottom of seismogenic fault, the dynamic characteristics of the frictional-plastic transition zone and plastic zone are very important for the seismogenic fault during seismic cycles. Granite is the major composition of the crust in the brittle-plastic transition zone. Compared to calcite, quartz, plagioclase, pyroxene and olivine, the rheologic data of K-feldspar is scarce. Previous deformation studies of granite performed on a quartz-plagioclase aggregate revealed that the deformation strength of granite was similar with quartz. In the brittle-plastic transition zone, the deformation characteristics of granite are very complex, temperature of brittle-plastic transition of quartz is much lower than that of feldspar under both natural deformation condition and lab deformation condition. In the mylonite deformed under the middle crust deformation condition, quartz grains are elongated or fine-grained via dislocation creep, dynamic recrystallization and superplastic flow, plagioclase grains are fine-grained by bugling recrystallization, K-feldspar are fine-grained by micro-fractures. Recently, both field and experimental studies presented that the strength of K-feldspar is much higher than that of quartz and plagioclase. The same deformation mechanism of K-feldspar and plagioclase occurred under different temperature and pressure conditions, these conditions of K-feldspar are higher than plagioclase. The strength of granite is similar to feldspar while it contains a high content of K-feldspar. High shear strain experiment studies reveal that granite is deformed by local ductile shear zones in the brittle-plastic transition zone. In the ductile shear zone, K-feldspar is brittle fractured, plagioclase are bugling and sub-grain rotation re-crystallized, and quartz grains are plastic elongated. These local shear zones are altered to local slip-zones with strain increasing. Abundances of K-feldspar, plagioclase and mica are higher in the slip-zones than that in other portions of the samples (K-feldspar is the highest), and abundance of quartz is decreased. Amorphous material is easily formed by shear strain acting on brittle fine-grained K-feldspar and re-crystallized mica and plagioclase. Ductile shear zone is the major deformation mechanism of fault zones in the brittle-plastic transition zone. There is a model of a fault failed by bearing constant shear strain in the transition zone:local shear zones are formed along the fractured K-feldspar grains; plagioclase and quartz are fine-grained by recrystallization, K-feldspar is crushed into fine grains, these small grains and mica grains partially change to amorphous material, local slip-zones are generated by these small grains and the amorphous materials; then, the fault should be failed via two ways, 1)the local slip-zones contact to a throughout slip-zone in the center of the fault zone, the fault is failed along this slip-zone, and 2)the local slip-zones lead to bigger mineral grains that are in contact with each other, stress is concentrated between these big grains, the fault is failed by these big grains that are fractured. Thus, the real deformation character of the granite can't be revealed by studies performing on a quartz-plagioclase aggregate. This paper reports the different deformation characters between K-feldspar, plagioclase and quartz under the same pressure and temperature condition based on previous studies. Then, we discuss a mode of instability of a fault zone in the brittle-plastic transition zone. It is still unclear that how many contents of weak mineral phase(or strong mineral phase)will control the strength of a three-mineral-phase granite. Rheological character of K-feldspar is very important for study of the deformation characteristic of the granitic rocks. 相似文献
5.
H. Stel 《Pure and Applied Geophysics》1986,124(1-2):289-307
Cataclasites and mylonites, and the brittle-ductile processes that produce them, were studied at exposures along the northern rim of the Grong culmination, a transverse basement antiform in the central Scandinavian Caledonides. The rock suite studied is composed of gneisses, mylonites, and cataclasites which have a granodioritic composition. The microstructure of the rocks appears to be the result of repeated alternations of brittle faulting (associated with hydrothermal mineral growth) and ductile deformation of the crystallization products. During brittle faulting K-feldspar-chlorite veins are formed, probably by incongruent pressure solution of micas. During plastic deformation of the rocks the mineral association is transformed to white mica and green biotite, according to the reaction. $$5 biotite + 3 white mica + 9 quartz + 4 H_2 O = 8 K - feldspar + 9 chlorite$$ During this reaction plagioclase is overgrown by mica and epidote, and K-feldspar crystals are replaced by albite. The reactions which involve K-feldspars are cyclic: K-feldspar that is generated in cracks tends to be removed by albitization during ductile deformation. It is concluded that the mylonites studied represent a movement zone in the Earth's crust in which seismic and aseismic slip alternated during a large part of the deformation history. 相似文献
6.
Annadasankar Roy Hemant Mohokar Diksha Pant Uday Kumar Sinha G. N. Mendhekar 《水文科学杂志》2020,65(6):951-968
ABSTRACTMultivariate statistical analysis and inverse geochemical modelling techniques were employed to deduce the mechanism of groundwater evolution in the hard-rock terrain of Telangana, South India. Q-mode hierarchical cluster analysis (HCA) and principal component analysis (PCA) were used to extract the hydrogeochemical characteristics and classify the groundwater samples into three principal groups. Use of thermodynamic stability diagrams and inverse geochemical modelling in PHREEQC identified the chemical reactions controlling hydrogeochemistry of each of the groups obtained from statistical analysis. The model output showed that a few phases are governing the water chemistry in this area and the geochemical reactions responsible for evolution of groundwater chemistry along the flow path are (i) dissolution of evaporite minerals (dolomite, halite); (ii) dissolution of primary silicate minerals (albite, anorthite, K-feldspar, biotite); (iii) precipitation of secondary silicate minerals (kaolinite, quartz, gibbsite, Ca-montmorillonite) along with anhydrite and calcite; and (iv) reverse ion exchange processes. 相似文献
7.
O. Martins 《水文研究》1988,2(1):19-29
Water quality analyses for the Niger River for the 1980/81 hydrological year are presented. The samples were collected from the main river at Lokoja, and from two main tributaries, the Kaduna and the Benue Rivers. Different water types were distinguished by the concentrations of major ions. The type Ca > Na > Mg > K - HCO3 > SO4 > Cl was represented at all stations during at least part of the year. Chloride was found to dominate the sulphate ion in the Kaduna and Niger, while the Benue maintained a higher concentration of sulphate relative to chloride all year round. Distinct patterns of seasonal variation in the ion concentrations were observed, particularly for the samples collected at Lokoja. Low ion concentrations were prominent during periods of high discharge, while low flow periods coincided with high dissolved ion concentrations. The contribution of rainwater to the total dissolved solids in the river waters was assessed indirectly using rainwater chemistry data from the Gulf of Guinea. The estimated rainwater contribution to the Lower Niger amounts to 5.15 mg 1?1. Geochemical weathering calculations involving reactions of the four major minerals of granitic rocks - anorthite, biotite, albite, and K-feldspar - with carbon dioxide and water, can account for the average water composition of the Lower Niger. The proportion of the ionic components was also related to the occurrence of the respective element in the minerals. 相似文献
8.
D. Larsson K. Grnvold N. Oskarsson E. Gunnlaugsson 《Journal of Volcanology and Geothermal Research》2002,114(3-4)
Dissolution of igneous feldspar and the formation and occurrence of secondary feldspar in tholeiitic basalts from the Hengill volcanic centre, in SW Iceland was studied by microprobe analysis of cuttings from two ca. 2000 m deep geothermal wells. Well NG-7 in Nesjavellir represents a geothermal system in a rift zone where the intensity of young, insignificantly altered intrusions increases with depth. Well KhG-1 in Kolviðarhóll represents the margin of a rift zone where the intensity of intrusives is lower and the intensity of alteration higher. This marginal well represents altered basaltic crust in an early retrograde state. The secondary plagioclase in both wells is mainly oligoclase, occurring in association with K-feldspar and chlorite±actinolite. The texture of this assemblage depends on the lithology and intensity of alteration. In Nesjavellir (NG-7) the composition of secondary albite-oligoclase is correlated with the host-rock composition. This connection is not apparent in more intensely altered samples from Kolviðarhóll (KhG-1). The influence of temperature on composition of secondary Na-feldspar is unclear in both wells although Ca is expected to increase with temperature. Any temperature dependence may be suppressed by the influence of rock composition in Nesjavellir and by retrograde conditions at Kolviðarhóll. The absence of clear compositional gradients between igneous plagioclase and secondary feldspar and between Na-feldspar and K-feldspar suggests that secondary feldspars formed by dissolution precipitation reactions. 相似文献
9.
R.M. Prol-Ledesma C. Canet M.A. Torres-Vera M.J. Forrest M.A. Armienta 《Journal of Volcanology and Geothermal Research》2004,137(4):102
Shallow submarine hydrothermal activity has been observed in the Bahía Concepción bay, located at the Gulf coast of the Baja California Peninsula, along faults probably related to the extensional tectonics of the Gulf of California region. Diffuse and focused venting of hydrothermal water and gas occurs in the intertidal and shallow subtidal areas down to 15 m along a NW–SE-trending onshore–offshore fault. Temperatures in the fluid discharge area vary from 50 °C at the sea bottom up to 87 °C at a depth of 10 cm in the sediments.Chemical analyses revealed that thermal water is enriched in Ca, As, Hg, Mn, Ba, HCO3, Li, Sr, B, I, Cs, Fe and Si, and it has lower concentrations of Cl, Na, SO4 and Br than seawater. The chemical characteristics of the water samples indicate the occurrence of mixing between seawater and a thermal end-member. Stable isotopic oxygen and hydrogen composition of thermal samples plot close to the Local Meteoric Water Line on a mixing trend between a thermal end-member and seawater. The composition of the thermal end-member was calculated from the chemistry of the submarine samples data by assuming a negligible amount of Mg for the thermal end-member. The results of the mixing model based on the chemical and isotopic composition indicate a maximum of 40% of the thermal end-member in the submarine vent fluid.Chemical geothermometers (Na/Li, Na–K–Ca and Si) were applied to the thermal end-member concentration and indicate a reservoir temperature of approximately 200 °C. The application of K–Mg and Na/Li geothermometers for vent fluids points to a shallow equilibrium temperature of about 120 °C.Results were integrated in a hydrogeological conceptual model that describes formation of thermal fluids by infiltration and subsequent heating of meteoric water. Vent fluid is generated by further mixing with seawater. 相似文献
10.
Eiji Sasao 《Island Arc》2013,22(2):170-184
A petrographic study of sandstones from the Miocene Mizunami Group in Central Japan has been performed on core samples from a single borehole, in order to evaluate the provenance of the sedimentary rock. Evaluation of the provenance is based on bulk mineral, heavy mineral and plagioclase contents and on whole rock chemical compositions. The sandstones studied are divisible into three types; the first type is characterized by the occurrence of biotite and plagioclase ranging from albite to oligoclase, the second type is characterized by the dominance of amphibole and labradorite with pyroxene (clinopyroxene > orthopyroxene), and the third type is characterized by the dominance of pyroxene (orthopyroxene > clinopyroxene) and andesine with lesser labradorite, bytownite and anorthite. The first type is interpreted to be derived from the basement granite, whereas the others were derived mostly from volcanic ash, judging from their mineral compositions. The volcanic activity that supplied the volcanic ash to the Mizunami Basin occurred in two phases, distinguishable by variations in their mineralogical and geochemical compositions, an indication of change in character of the volcanic activity. This petrographic study of the sandstones in the Mizunami Group suggests that unrecognized volcanic activity occurred around the Mizunami Basin, even though potential provenance of the volcanic ash has not yet been identified. 相似文献
11.
Georg F. Zellmer Hetu C. Sheth Yoshiyuki Iizuka Yi-Jen Lai 《Bulletin of Volcanology》2012,74(1):47-66
Products of contrasting mingled magmas are widespread in volcanoes and intrusions. Subvolcanic trachyte intrusions hosting
mafic enclaves crop out in the Manori–Gorai area of Mumbai in the Deccan Traps. The petrogenetic processes that produced these
rocks are investigated here with field data, petrography, mineral chemistry, and whole rock major, trace, and Pb isotope chemistry.
Local hybridization has occurred and has produced intermediate rocks such as a trachyandesitic dyke. Feldspar crystals have
complex textures and an unusually wide range in chemical composition. Crystals from the trachytes cover the alkali feldspar
compositional range and include plagioclase crystals with anorthite contents up to An47. Crystals from the mafic enclaves are dominated by plagioclase An72–90, but contain inclusions of orthoclase and other feldspars covering the entire compositional range sampled in the trachytes.
Feldspars from the hybridized trachyandesitic dyke yield mineral compositions of An80–86, An47–54, Ab94–99, Or45–60, and Or96–98, all sampled within individual phenocrysts. We show that these compositional features are consistent with partial melting
of granitoid rocks by influx of mafic magmas, followed by magma mixing and hybridization of the partial melts with the mafic
melts, which broadly explains the observed bulk rock major and trace element variations. However, heterogeneities in Pb isotopic
compositions of trachytes are observed on the scale of individual outcrops, likely reflecting initial variations in the isotopic
compositions of the involved source rocks. The combined data point to one or more shallow-level trachytic magma chambers disturbed
by multiple injections of trachytic, porphyritic alkali basaltic, and variably hybridized magmas. 相似文献
12.
The Ina district of the Ryoke Belt is divided into two mineral zones, based on the mineral parageneses of the pelitic and psammitic rocks at the peak metamorphism. A biotite–muscovite zone (quartz + plagioclase + biotite + muscovite with or without K-feldspar) constitutes the northwestern part, and a biotite–cordierite–K-feldspar zone (quartz + plagioclase + biotite + cordierite + K-feldspar) comprises the central to southern and eastern parts. The isograd reaction between two mineral zones is defined by a divariant reaction: Mg-rich biotite + muscovite + quartz = Fe-rich biotite + cordierite + K-feldspar + H2 O (1), which, in the K2 O–FeO–MgO–Al2 O3 –SiO2 –H2 O (KFMASH) system, occurs at ∼ 590 °C at 0.2 GPa and 660 °C at 0.4 GPa. Fibrolite accompanied by andalusite porphyroblasts in aluminous pelitic rocks of the biotite–muscovite zone and the low-grade part of the biotite–cordierite–K-feldspar zone, suggests that sillimanite was the stable aluminosilicate at the peak metamorphic condition throughout the area. In the high-grade part of the biotite–cordierite–K-feldspar zone, fibrolite mostly occurs as inclusions in cordierite or in plagioclase. The phase relations and the compositional zoning of plagioclase in relation to fibrolite inclusions suggest that fibrolite was formed under relatively high-pressure conditions, and that partial melting took place. 相似文献
13.
Gabbroic rocks and amphibolites were collected from the KR03‐01‐D10 dredge site located on the West Arm Rise of the Godzilla Megamullion, close to the Parece Vela Rift which appears to correspond to the termination area of a detachment fault, the Philippine Sea. The gabbroic rocks and amphibolites reveal the occurrence of a high hydrothermal activity in the lower crust close to a paleo‐ridge. In the gabbroic rocks, plagioclase compositions of both porphyroclasts and matrix were transformed into sodium‐rich compositions close to albite. Amphiboles are of secondary rather than igneous origin based on their microstructural occurrences. In the amphibolites, anorthite contents of porphyroclasts and matrix plagioclase are relatively lower than those of the gabbroic rocks, whereas the chemical compositions of amphibole within the amphibolites are similar to those of amphibole within the gabbroic rocks. Amphibolites represent the product of retrograde metamorphism associated with hydrothermal alteration of the gabbroic body by the reaction: clinopyroxene + calcic plagioclase + fluid → amphibole + sodic plagioclase. The estimated temperatures of the amphibolites derived from the amphibole thermobarometer and the gabbroic rocks derived from the hornblende–plagioclase geothermometer show ～700–950°C and 650–840°C, respectively. The hydrothermal alteration recorded in the gabbroic rocks possibly occurred under high‐T conditions; the rocks were then metamorphosed to the amphibolites during a retrogressive stage. Our study indicates that amphibolitization took place with various degrees of deformation. It may imply that the hydrothermal activity increased as the Godzilla Megamullion developed as an oceanic core complex in the paleo‐ridge. 相似文献
14.
Kossitse Venyo Akpataku Shive Prakash Rai Masamaéya Dadja-Toyou Gnazou Lallébila Tampo Limam Moctar Bawa Gbandi Djaneye-Boundjou 《水文科学杂志》2019,64(8):983-1000
Hydrochemical, inverse geochemical modelling and isotopic approaches are used to assess the hydrogeochemical evolution of groundwater from the basement aquifers in the southeastern part of the Plateaux Region, Togo. Groundwater originates from present-day rainwater infiltration and is mostly fresh and slightly acidic to neutral. Hydrochemical facies are predominantly mixed cations-HCO3 associated with Ca/Mg-Cl, Na-HCO3 and Na-Cl water types in equilibrium with kaolinite and Ca/Mg-smectites. They are related to silicates hydrolysis, anthropogenic contamination, nitrification/denitrification, mixing along flowpaths and dissolution/precipitation of secondary minerals. The pattern of flow paths is in accordance with an increasing trend in total dissolved solids (TDS) toward the potentiometric depression located in the central and southern parts of the aquifer system. Inverse geochemical modelling using the NETPATH-WIN model showed the relative importance of biotite, plagioclase and amphibole weathering and dissolution of secondary carbonate minerals along the flowpath, suggesting that an abundance of minerals is not necessarily the main factor controlling the groundwater chemistry evolution. 相似文献
15.
New insights on the origin of troctolites from the breakaway area of the Godzilla Megamullion (Parece Vela back‐arc basin): The role of melt‐mantle interaction on the composition of the lower crust 
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下载免费PDF全文 The troctolites and olivine‐gabbros from the Dive 6 K‐1147 represent the most primitive gabbroic rocks collected at the Godzilla Megamullion, a giant oceanic core complex formed at an extinct spreading segment of the Parece Vela back‐arc basin (Philippine Sea). Previous investigations have shown that these rocks have textural and major elements mineral compositions consistent with a formation through multistage interaction between mantle‐derived melts and a pre‐existing ultramafic matrix. New investigations on trace element mineral compositions basically agree with this hypothesis. Clinopyroxenes and plagioclase have incompatible element signatures similar to that of typical‐MORB. However, the clinopyroxenes show very high Cr contents (similar to those of mantle clinopyroxene) and rim having sharply higher Zr/REE ratios with respect to the core. These features are in contrast with an evolution constrained by fractional crystallization processes, and suggest that the clinopyroxene compositions are controlled by melt‐rock interaction processes. The plagioclase anorthite versus clinopyroxene Mg#[Mg/(Mg + FeTot)] correlation of the Dive 6 K‐1147 rocks shows a trend much steeper than those depicted by other oceanic gabbroic sections. Using a thermodynamic model, we show that this trend is reproducible by fractionation of melts assimilating 1 g of mantle peridotite per 1 °C of cooling. This model predicts the early crystallization of high Mg# clinopyroxene, consistent with our petrological observation. The melt‐peridotite interaction process produces Na‐rich melts causing the crystallization of plagioclase with low anorthite component, typically characterizing the evolved gabbros from Godzilla Megamullion. 相似文献
16.
《Physics and Chemistry of the Earth》2004,29(1):43-54
Based on geochemical data collected by Japan Nuclear Cycle Development Institute (JNC) in the Tono uranium mine, a conceptual groundwater evolution model developed by JNC is tested to evaluate whether equilibrium-based concepts of water–rock interaction are consistent with observed variations in the mineralogy and hydrochemistry of the Tono mine area. The chemical evolution of the groundwaters is modeled assuming local equilibrium for selected mineral–fluid reactions, taking into account the rainwater origin of these solutions. Results suggest that it is possible to interpret approximately the actual groundwater chemistry (i.e., pH, Eh, total dissolved concentrations of Si, Na, Ca, K, Al, carbonate and sulfate) if the following assumptions are adopted (a) CO2 concentration in the gas phase contacting pore solutions in the overlying soil zone=10−1 atm, and (b) minerals in the rock zone that control the solubility of respective elements in the groundwater include: chalcedony (Si), albite (Na), kaolinite (Al), calcite (Ca and carbonate), muscovite (K) and pyrite (Eh and sulfate). This result helps to build confidence in the use of simplified geochemical modeling techniques to develop an understanding of dominant geochemical reactions controlling groundwater chemistry in rocks similar to those that could be used for the geological disposal of radioactive wastes. It is noted, however, that the available field data may not be sufficient to adequately constrain parameters in the groundwater evolution model. In particular, more detailed information characterizing certain site properties are needed to improve the model. For this reason, a model that accounts for ion-exchange reactions among clay minerals, and which is based on the results of laboratory experiments, has also been evaluated in the present study. Further improvement of model considering ion-exchange reactions are needed in future, however. 相似文献
17.
Thermal springs associated with normal faults in Utah have been analyzed for major cations and anions, and oxygen and hydrogen isotopes. Springs with measured temperatures averaging greater than 40°C are characterized by Na + K- and SO4 + Cl-rich waters containing 103 to 104 mg/l of dissolved solids. Lower temperature springs, averaging less than 40°C, are more enriched in Ca + Mg relative to Na + K. Chemical variations monitored through time in selected thermal springs are probably produced by mixing with non-thermal waters. During the summer months at times of maximum flow, selected hot springs exhibit their highest temperatures and maximum enrichments in most chemical constituents.Cation ratios and silica concentrations remain relatively constant through time for selected Utah thermal springs assuring the applicability of the geothermometer calculations regardless of the time of year. Geothermometer calculations utilizing either the quartz (no steam loss), chalcedony or Mg-corrected Na/K/Ca methods indicate that most thermal springs in Utah associated with normal faults have subsurface temperatures in the range of 25 to less than 120°C. This temperature range suggests fluid circulation is restricted to depths less than about three kilometers assuming an average thermal gradient of about 40°C/km.Thermodynamic calculations suggest that most thermal springs are oversaturated with respect to calcite, quartz, pyrophyllite, (Fe, Mg)-montmorillonite, microcline and hematite, and undersaturated with respect to anhydrite, gypsum, fluorite and anorthite. Chalcedony and cristobalite appear to be the only phases consistently at or near saturation in most waters. Theoretical evaluation of mixing on mineral saturation trends indicates that anhydrite and calcite become increasingly more undersaturated as cold, dilute groundwater mixes with a hot (150°C), NaCl-rich fluid. The evolution of these thermal waters issuing from faults appears to be one involving the dissolution of silicates such as feldspars and micas by CO2-enriched groundwaters that become more reactive with increasing temperature and/or time. Solution compositions plotted on mineral equilibrium diagrams trend from product phases such as kaolinite or montmorillonite toward reactant phases dominated by alkali feldspars.Isotopic compositions indicate that these springs are of local surface origin, either meteoric (low TDS, < 5000 mg/l) or connate ground water (high TDS, > 5000 mg/l). Deviations from the meteoric water line are the result of rock-water isotopic exchange, mixing or evaporation. Fluid source regions and residence times of selected thermal spring systems (Red Hill, Thermo) have been evaluated through the use of a σ D-contour map of central and western Utah. Ages for waters in these areas range from about 13 years to over 500 years. These estimates are comparable to those made for low-temperature hydrothermal systems in Iceland. 相似文献
18.
This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2 gas field of the Tarim Basin, Northwestern China. Sandstone samples and pore water samples are col-lected from well KL201 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3600 to 4000 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2SO4 type at the shallow depth (3600-3630 m), to the NaHCO3 type at the intermediate depth (3630―3695 m),and to the CaCl2 type at the greater depth (3728―3938 m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2 concen-tration, the total inorganic carbon concentration (ΣCO2), and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few key parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2] -[Ca2 ]). In the Na2SO4 water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3 water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and this intensive cementation is responsible for decreased porosity and permeability. In the CaCl2 water at the greater depth, pore water is un-der-saturated with respect to calcite, resulting in dissolution of calcite cements, as consistent with microscopic dissolution features of the samples from this depth interval. Calcite dissolution results in formation of high secondary porosity and permeability, and is responsible for the superior quality of the reservoir rocks at this depth interval. These results illustrate the importance of pore water chemis-try in controlling carbonate precipitation/dissolution, which in turn controls porosity and permeability of oil and gas reservoir rocks in major sedimentary basins. 相似文献
19.
3.5 Ga record of water-limited, acidic weathering conditions on MarsThe secondary mineral budget on Earth is dominated by clay minerals, Al-hydroxides, and Fe-oxides, which are formed under the moderate pH, high water-to-rock ratio conditions typical of Earth's near-surface environment. In contrast, geochemical analyses of rocks and soils from landed missions to Mars indicate that secondary mineralogy is dominated by Mg (± Fe, Ca)-sulfates and Fe-oxides. This discrepancy can be explained as resulting from differences in the chemical weathering environment of Earth and Mars. We suggest that chemical weathering processes on Mars are dominated by: (1) a low-pH, sulfuric acid-rich environment in which the stoichiometric dissolution of labile mineral phases such as olivine and apatite (± Fe–Ti oxides) is promoted; and (2) relatively low water-to-rock ratio, such that other silicate phases with slower dissolution rates (e.g., plagioclase, pyroxene) do not contribute substantially to the secondary mineral budget at the Martian surface. Under these conditions, Al-mobilization is limited, and the formation of significant Al-bearing secondary phases (e.g., clays, Al-hydroxides, Al-sulfates) is inhibited. The antiquity of rock samples analyzed in-situ on Mars suggest that water-limited acidic weathering conditions have more than likely been the defining characteristic of the Martian aqueous environment for billions of years. 相似文献
20.
Mineral chemistry and geothermobarometry of Moshirabad pluton,Qorveh, Kurdistan,western Iran 总被引：1，自引：0，他引：1
ALI A. SEPAHI MOHAMMAD MAANIJOU SEDDIGHEH SALAMI SARA GARDIDEH TAYEBEH KHAKSAR 《Island Arc》2012,21(3):170-187
The Moshirabad pluton is located southwest of the Sanandaj–Sirjan Metamorphic Belt, Qorveh, western Iran. The pluton is composed of diorite, monzodiorite, quartz diorite, quartz monzodiorite, tonalite, granodiorite, granite, aplite, and pegmatite. In this study 31 samples from various rocks were chosen for whole‐rock analyses and 15 samples from different lithologies were chosen for mineral chemical studies. The compositions of minerals are used to describe the nature of magma and estimate the pressure and temperature at which the Moshirabad pluton was emplaced. Feldspar compositions are near the binary systems in which plagioclase compositions range from An5 to An53 and alkali‐feldspar compositions range from Or91 to Or97. Mafic minerals in the plutonic rocks are biotite and hornblende. Based on the composition of biotites and whole‐rock chemistry, the Moshirabad pluton formed from a calc‐alkaline magma. Amphiboles are calcic amphiboles (magnesio‐hornblende or edenite). Temperatures of crystallization, calculated with the hornblende–plagioclase thermometer, range 550–750°C. These temperatures indicate that plutonic rocks have undergone some retrogressive changes in their mineral compositions. Aluminum‐in‐hornblende geobarometry indicates that the Moshirabad pluton was emplaced at pressures of 2.3–6.0 kbar, equal to depths of 7–20 km, but with consideration of regional geology, lower pressures than the above pressure range are more probable. Alteration of amphiboles can be the reason for some overestimation of pressures. 相似文献