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1.
正1 Introduction China has very abundant liquid mineral resources.Especially,the brine resources in the west of Sichuan Basin are pushed into the first place in China,whose K and B contents are unusually high.These rare liquid mineral resources have very good exploitation prospect(Lin,2001;2006).Generally speaking,phase equilibrium  相似文献   

2.
Deposition of Potash-Magnesium Salts in the Qarhan Playa, Qaidam Basin   总被引：1，自引：0，他引：1  
The Qarhan potash-magnesium salt deposit, which consists from east to west of four playa districts, namely Huobuxun, Qarhan, Dabuxun and Bieletan, may be divided from bottom to top into three salt beds(S_1, S_2 and S_3), with potash salts mainly occurring in S_3. The paper lays emphasis on the evolutionary history of the deposition of Salt Bed S_3 and the modes of formation of potash salts in the Qarhan playa.The analysis of the data obtained from more than 170 boreholes and the geochemical studies on bromine, magnesium and calcium reveal the existence of four concentration stages and three dilution stages during the ormation of the Upper Salt Bed S_3. In the process of concentration, evaporation of brine and precipitation of salt minerals dominated, which obeyed the regularity indicated by the phase diagram of the quaternary system Mg-Na-K/Cl~-H_2O. In the dilution stages, however, mixing of brines, dissolution of salts(especially the playa) and mechanical clastic deposition played the leading role. The prerequisite for mixing in the Qarhan salt deposit lies in that chloride type brine of the northeastern part coexists with magnesium sulfate type brine of the southwestern part in the same salt lake. The appearance of bassanite has verified the process of mixing. The dissolution refers to the partial dissolution of the salt beds originally deposited. Particularly in the last dilution process, approximately 200 km~2 of the playa north of the Tuanjie Lake had been dissolved before a new-born lake took form.Solid potash salts were formed in three ways:(1) The surficial brine of the Dabuxun lake coexistent with the playa had an intercompensational relationship with the intercrystalline brine in the playa. As a result, K~+ ions were collected into the lake, and layered Carnallite precipitated from lake brine during the seasons of evaporation, which was accelerated by the action of wind.(2) Disseminated potash-magnesium salts were formed by further concentration of intercrystalline brine.(3) Dissolution and reformation of the playa resultedin the formation of a new-born salt lake, in the drying of which brine collected the potash-magnesium salts originally dispersed over the playa into local low-lying areas, forming finally stratoid potash-magnesium salts.  相似文献   

3.
Located in the eastern part of the Tarim basin, Xinjiang, the Lop Nur was an ultimate water catchment area of the Tarim basin during the Quaternary. Through nearly ten years of investigation and research, the authors have found a superlarge brine potash deposit in the Luobei subbasitv—a secondary basin of the Lop Nur depression. The deposit has been mined now. On that basis, the authors propose new theories on the genesis of the potash rock deposit. In the tectonic and geomorphologic contexts, the Tarim basin lies in a “high mountain-deep basin” environment. At the beginning of the Quaternary, influenced by the neotectonic movement, the Lop Nur evolved into a “deep basin” in the Tarim basin. At the end of the middle Pleistocene, neotectonic migration began to take place in the interior of the Lop Nur and a new secondary deep basin—the Luobei subbasin—formed gradually. Despite its small area, it is actually the deepest subbasin in the Lop Nur depression, where brines of the Lop Nur Salt Lake gather and evaporate, thus providing materials for the formation of a superlarge brine potash rock deposit. With respect to the phenomenon of brine concentration and change with deepening of the lake, the authors propose a model of “high mountain-deep basin” tectonic migration for potash concentration. In the sedimentological context, the honeycomb-shaped voids developed in glauberite rock in the subbasin are good space for potash-rich brine accumulation. Study indicates that the deposition of glauberite requires recharge of calcium-rich water.In the Tarim area the calcium-rich water might come from deep formation water or oilfield water, and the river water recharging the Lop Nur Salt Lake was rich in sulfate radicals and other components; in addition, the climate in the area was very dry and the brine evaporated steadily, thus resulting in deposition of substantial amount of glauberite, potash accumulation in intercrystal brine and final formation of the potash deposit. Generally, potash formation in a salt lake undergoes a three-stage process of “carbonates→sulfates (gypsum and glauberite)→chlorides (halite etc.)”, but in the study area there only occurred a two-stage process of “carbonates→sulfates (gypsum and glauberite)”. The authors call this new geological phenomenon the “two-stage potash formation” model. In conclusion, the superlarge Lop Nur potash deposit is the result of combined “high mountain-deep basin” tectonism and “two-stage potash formation”.  相似文献   

4.
Potassium-rich brine in the Sichuan Basin has been much studied in recent years, but few studies have focused on the distribution and migration of salt basin and the differences of potassium formation mechanisms. This work examined the salt-gathering and potassium formation of potassium-rich brine during the Triassic in the Sichuan Basin using lithofacies palaeogeographic depiction and geochemical analyses. (1) The favorable sedimentary facies controlling the formation of potassium-rich brine during the Triassic in the Sichuan Basin are evaporation platform and restricted platform, whereas the salt basin is one of the main factors controlling the poly-salt center. (2) The distribution and migration of this salt basin were affected by certain factors. The salt basin of the Jialingjiang Formation was mainly distributed in the east and central Sichuan Basin, whereas that of the Leikoupo Formation was mainly distributed in the central and west Sichuan Basin. The sedimentary centers have gradually moved westward and become smaller. (3) Three main formation mechanisms were identified for the potassium-rich brine during the Triassic in the Sichuan Basin, i.e., evaporation and concentration of seawater, surface fresh water leaching, and deep water-rock reaction. Fresh water leaching was characterized by low anomaly δ18O and δ13C values. Water-rock reaction was mainly related to temperature, and high temperature environment (caused by burial depth, overthrust and deep hydrothermal fluids) was beneficial to water-rock reaction. The characteristics of water-rock reaction do not correspond to the increase ratio of K?103/Cl and Br?103/Cl in brine, and the Rb+ content of the brine was high. (4) The formation mechanisms of potassium-rich brine differed between different areas of the Sichuan Basin. In east Sichuan, the evaporation and concentration of seawater, together with meteoric fresh water leaching, was the main formation factor, whereas the evaporation and concentration of seawater and water–rock reaction predominated in west Sichuan. This study of the sedimentary environment and formation mechanisms is of significance to the exploration and exploitation of potassium-rich brine in the Sichuan Basin.  相似文献   

5.
正The underground brine resource along the coast of Laizhou Bay is the world’s rare shallow underground brine resource,which occurs in the Laizhou city in the east,and extends to the coastal area of the Binzhou city in  相似文献   

6.
正Salt Lake brine pump is one of the key equipment in salt lake brine extraction device.As the salt lake brine is a kind of high concentration solution with a variety of chemical constituents,the flow and agitation of saturated  相似文献   

7.
Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer （salt deposit） in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system （salt deposits） was developed by using the Pitzer theory. Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarhan Salt Lake.  相似文献   

8.
Sichuan Basin is one of the most important marine–salt forming basins in China. The Simian and Triassic have a large number of evaporites. The Triassic strata have found a large amount of polyhalite and potassium-rich brine. However, no soluble potassium salt deposit were found. In this study, the halite in well Changping 3 which is located at the eastern part of the Sichuan basin was studied using the characteristics, hydrogen and oxygen isotopes of the fluid inclusion in halite to reconstruct the paleoenvironment. The salt rocks in well Changping 3 can be divided into two types: grey salt rock and orange salt rock. The result shows that the isotopic composition of the halite fluid inclusion is distinct from the global precipitation line reflecting that the salt formation process is under strong evaporation conditions and the climate is extremely dry. At the same time, compared with the hydrogen and oxygen isotopes of brine in the Sichuan Basin and the hydrous isotope composition of the inclusions in the salt inclusions of other areas in China, it is shown that the evaporation depth of the ancient seawater in the Sichuan Basin was high and reached the precipitation of potassium and magnesium stage.  相似文献   

9.
Firstly,the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory.The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented,which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake.And secondly,with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference,a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile,the model was applied to model potassium/magnesium transport in Qarban Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarban Salt Lake.  相似文献   

10.
孙大鹏 《地球化学》1974,(4):230-248
The purpose of this paper is to discuss from a hydrechemieal and physieochemieal view point the formation of reeent potash deposits in a salt lake lying in a Quarternary depression of a certain basin in China. Its surface brine, which varies seasonally and annually in composition, is of MgSO4 subtype and is highly mineralized with a low metamorphic eoefficient (MgSO4/MgCl2= 0.029). These deposits are distributed at the northern and northeastern banks of the lake, far away from riverwater supply. Mineralogical composition of the deposits is quite simple, eonsisting mainly of halits and earnallites. The formation of natural potash took place as the eoncentration of surface brine reached a certain point during evaporation. Rate of precipitation, eomposition and grain size of the carnallite sediment are largely dependent upon ebanges in brine concentration. The presenee of these recent potash deposits in present-day basins and continental salt lakes demonstrates that continental salt-bearing basins should likewise be taken as promising areas for aneient potassium salt prospecting.  相似文献   

11.
Direct current resistivity and ground penetrating radar surveys were employed to obtain the value of the resistivity and dielectric constant in the brine near the Barrow, Alaska. The geophysical surveys were undertaken together with the permafrost drilling program for the measuring of the ground temperature regime and for the core sampling. The sampled cores were measured for their physical and chemical properties in the laboratory under different temperature conditions (-60 to 20 ℃). Laboratory results support field observations and led to the development of a technique for distinguishing freshwater taliks and brine layers in permafrost. These methods were also employed in freshwater taliks near Council,Alaska. The electrical resistivity is a powerful and sensitive parameter for brine detection. However, the resistivity is a less sensitive indicator of the soil type or water content under highly saline conditions.High frequency dielectric constant is an ideal second parameter for the indication of the soil type, liquid water content and other physical properties. The imaginary part of the dielectric constant and resistivity have a significant dependence upon salinity, i.e. upon freezing temperature. The ground temperature regime and the freezing point of the brine layer are important parameters for studying the electric properties of permafrost terrain.  相似文献   

12.
We report new petrological, phase equilibria modeling, and fluid inclusion data for pelitic and mafic granulites from Rundv?gshetta in the highest-grade region of the Neoproterozoic Lützow-Holm Complex(LHC),East Antarctica, and provide unequivocal evidence for fluid-rock interaction and high-temperature metasomatism in the presence of brine fluid. The studied locality is composed dominantly of well-foliated pelitic granulite(K-feldspar+quartz+sillimanite+garnet+ilmenite) with foliation-parallel bands and/or layers of mafic granulite(plagioclase+orthopyroxene+garnet+ilmenite+quartz+biotite). The boundary between the two lithologies is defined by thin(about 1 -20 cm in thick) garnet-rich layers with a common mineral assemblage of garnet+plagioclase+quartz+ilmenite+biotite ? orthopyroxene. Systematic increase of grossular and decrease of pyrope contents in garnet as well as decreasing Mg/(Fe+Mg) ratio of biotite from the pelitic granulite to garnet-rich rock and mafic granulite suggest that the garnet-rich layer was formed by metasomatic interaction between the two granulite lithologies. Phase equilibria modeling in the system NCKFMASHTO demonstrates that the metasomatism took place at 850 -860℃, which is slightly lower than the peak metamorphism of this region, and the modal abundance of garnet is the highest along the metapeliteemetabasite boundary(up to 40%), which is consistent with the field and thin section observations. The occurrence of brine(7.0 -10.9 wt.% Na Cleqfor ice melting or 25.1 -25.5 wt.% NaC leqfor hydrohalite melting) fluid inclusions as a primary phase trapped within plagioclase in the garnet-rich layer and the occurrence of Cl-rich biotite(Cl = 0.22 -0.60 wt.%) in the metasomatic rock compared to that in pelitic(0.15 -0.24 wt.%) and mafic(0.06-0.13 wt.%) granulites suggest infiltration of brine fluid could have given rise to the high-temperature metasomatism. The fluid might have been derived from external sources possibly related to the formation of major suture zones formed during the Gondwana amalgamation.  相似文献   

13.
<正>Zabuye Salt Lake in Tibet,China is a carbonate-type salt lake,which has some unique characteristics that make it different from other types of salt lakes.The lake is at the latter period in its evolution and contains liquid and solid resources.Its brine is rich in Li,B,K and other useful minor elements that are of great economic value.We studied the concentration behavior of these elements and the crystallization paths of salts during isothermal evaporation of brine at 15℃and 25℃.The crystallization sequence of the primary salts from the brine at 25℃is halite(NaCl)→aphthitalite (3K_2SO_4·Na_2SO_4)→zabuyelite(Li_2CO_3)→trona(Na_2CO_3·NaHCO_3·2H_2O)→thermonatrite (Na_2CO_3·H_2O)→sylvite(KCl),while the sequence is halite(NaCl)→sylvite(KCl)→trona (Na_2CO_3·NaHCO_3·2H_2O)→zabuyelite(Li_2CO_3)→thermonatrite(Na_2CO_3·H_2O)→aphthitalite (3K_2SO_4·Na_2SO_4) at 15℃.They are in accordance with the metastable phase diagram of the Na~+,K~+-Cl~-, CO_3~(2-),SO_4~(2-)-H_2O quinary system at 25℃,except for Na_2CO_3·7H_2O which is replaced by trona and thermonatrite.In the 25℃experiment,zabuyelite(Li_2CO_3) was precipitated in the early stage because Li_2CO_3 is supersaturated in the brine at 25℃,in contrast with that at 15℃,it precipitated in the later stage.Potash was precipitated in the middle and late stages in both experiments,while boron was concentrated in the early and middle stages and precipitated in the late stage.  相似文献   

14.
The Gas Hure Salt Lake(GHSL) in the northwestern Qaidam Basin, western China, is rich in boron(B)resources, but its B-resource origin is hardly known. Hydrochemical compositions and B isotope characteristics of different waters were collected around the GHSL, including the river water, stream water, spring water, salt-lake brine,intercrystalline brine, well water, drilling brine, and solar pond brine. The hydrochemical signatures suggest that silicates,carbonates and evaporates are the main B-bearing rocks during the water dynamic. The reservoir estimation of B resources shows that the Kulamulekesay River(KLMR) and the Atekan River(ATKR) contribute annually 18.3 tons and 22.84 tons of B, respectively, with a total amount of 11.72 × 10~4 tons of B during the past 5.7 ka. In comparison with the known B reservoir(32.96 × 10~4 tons) in the GHSL, a significant amount of B in the GHSL was probably recharged from deep fluids and sediments around the GHSL. The B concentration and B-enrichment degree are shaped by the evaporation process,which are highly elevated at the carnallite and bischofite stages.  相似文献   

15.
正Objective Lop Nur is one of the world's largest Quaternary salt lakes and is currently a playa. In this lake, unique giant glauberite deposits occur, of which the intercrystalline pores host super-large liquid potash deposits. Recently, it has been thought that the potassium-rich brine was formed when the enormous quantity of glauberite deposited. To clarify this issue 14 C dating for brine is used to provide new evidence of chronology illustrating the relationship of potassium-rich brine with the host glauberite rock and improve our understanding of the formation mechanism of the brine in Lop Nur playa.  相似文献   

16.
Marine sedimentary strata are widely distributed in the coastal zone of the study area, and are rich in brine resources. The exploitation of underground water resources often first caused the intrusion of salt water in the marine strata. Based on the analysis of sea-salt water intrusion feature, the sea-salt water intrusion is divided into four stages: The occurrence and development stage(1976–1985), the rapid development stage(1986–1990), the slow development stage(1990–2000) and the stable development stage(2000–2015). Based on the comparative analysis of the relationship between seawater intrusion and influencing factors, this paper presents that the groundwater exploitation and the brine resources mining are the main control factors of sea-salt water intrusion. On this basis, we have established a numerical model of the sea-salt water intrusion. Using this model, we predicted the development trend of the sea-salt water intrusion. The results show that if the current development of groundwater and brine is maintained, the sea-salt water intrusion will gradually withdraw; once development of brine stops, sea-salt water will invade again. This provides the scientific basis for the rational exploitation of groundwater and the prevention of sea-salt water intrusion.  相似文献   

17.
Cu and Fe skarns are the world’s most abundant and largest skarn type deposits, especially in China, and Au-rich skarn deposits have received much attention in the past two decades and yet there are few papers focused on schematic mineral deposit models of Cu–Fe–Au skarn systems. Three types of Au-rich deposits are recognized in the Edongnan region, Middle–Lower Yangtze River metallogenic belt: ~140 Ma Cu–Au and Au–Cu skarn deposits and distal Au–Tl deposits; 137–148 Ma Cu–Fe; and 130–133 Ma Fe skarn deposits. The Cu–Fe skarn deposits have a greater contribution of mantle components than the Fe skarn deposits, and the hydrothermal fluids responsible for formation of the Fe skarn deposits involved a greater contribution from evaporitic sedimentary rocks compared to Cu–Fe skarn deposits. The carbonate-hosted Au–Tl deposits in the Edongnan region are interpreted as distal products of Cu–Au skarn mineralization. A new schematic mineral deposit model of the Cu–Fe–Au skarn system is proposed to illustrate the relationship between the Cu–Fe–Au skarn mineralization, the evaporitic sedimentary rocks, and distal Au–Tl deposits. This model has important implications for the exploration for carbonate–hosted Au–Tl deposits in the more distal parts of Cu–Au skarn systems, and Fe skarn deposits with the occurrence of gypsum-bearing host sedimentary rocks in the MLYRB, and possibly elsewhere.  相似文献   

18.
正Introduction The amount of the total dissolved salts(TDS)in most of the salt brines on northern Tibet is relatively lower.So the effective brine concentration technique is needed for lithium,boron and potassium extraction from these brine  相似文献   

19.
In the Triassic marine sediments, an obvious enrichment of lithium has been found. The source and enrichment mechanism of lithium is unknown. Here, we report trace and rare earth element and isotope analyses for Triassic sedimentary samples from core ZK601, recovered from the Huangjinkou anticline in the Xuanhan basin. Lithium concentrations from the Leikoupo and Jialingjiang formations are much higher than the average concentrations in the crust of eastern China and in other marine sediments. Lithium concentrations are highest at depths of 3300–3360 m (in argillaceous marine sediments), and Li is positively correlated with Rb, Ga, Zr, Nb and other trace elements. The range of δ7Li values in our samples is consistent with that in other Triassic marine carbonate rocks. Lithium concentrations and isotope ratios are negatively correlated in the argillaceous dolomite samples at depths of 3300–3360 m. We compared the results in this study with trace and rare earth elements in the clay from Sichuan and Chongqing, and propose that the clay in the argillaceous marine evaporites from Huangjinkou formed via the hydrolysis of volcanic ash during Early–Middle Triassic volcanic eruptions into brine basins, during which clay adsorbed Li from the brine and formed Li-rich argillaceous dolomites. The addition and hydrolysis of volcanic ash in the evaporative brine is also related to the formation of a new type of polyhalite.  相似文献   

20.
Zabuye Salt Lake in Tibet, China is a carbonate-type salt lake, which has some unique characteristics that make it different from other types of salt lakes. The lake is at the latter period in its evolution and contains liquid and solid resources. Its brine is rich in Li, B, K and other useful minor elements that are of great economic value. We studied the concentration behavior of these elements and the crystallization paths of salts during isothermal evaporation of brine at 15°C and 25°C. The crystallization sequence of the primary salts from the brine at 25°C is halite (NaCl) → aphthitalite (3K2SO4·Na2SO4) → zabuyelite (Li2CO3)→ trona (Na2CO3·NaHCO3·2H2O) → thermonatrite (Na2CO3·H2O) → sylvite (KCl), while the sequence is halite (NaCl) → sylvite (KCl) → trona (Na2CO3·NaHCO3·2H2O) → zabuyelite (Li2CO3) → thermonatrite (Na2CO3·H2O) → aphthitalite (3K2SO4·Na2SO4) at 15°C. They are in accordance with the metastable phase diagram of the Na+, K+-Cl?, CO32?, SO42?-H2O quinary system at 25°C, except for Na2CO3·7H2O which is replaced by trona and thermonatrite. In the 25°C experiment, zabuyelite (Li2CO3) was precipitated in the early stage because Li2CO3 is supersaturated in the brine at 25°C, in contrast with that at 15°C, it precipitated in the later stage. Potash was precipitated in the middle and late stages in both experiments, while boron was concentrated in the early and middle stages and precipitated in the late stage.  相似文献   

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