首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.  相似文献   

2.
Seafloor hydrothermal alteration at an Archaean mid-ocean ridge   总被引：2，自引：0，他引：2  
A hydrothermally metamorphosed/altered greenstone complex capped by bedded cherts exposed in the North Pole, Pilbara Carton, Western Australia, is interpreted as an accretionary complex. It is distinctive in being characterised by both duplex structure and an oceanic crust stratigraphy. This complex is shown to represent an Archaean upper oceanic crust with a mid‐ocean ridge hydrothermal metamorphism that increases in grade stratigraphically downward. Three mineral zones have been defined; Zone A of the zeolite facies, the prehnite‐pumpellyite facies or the lower‐greenschist facies at high‐XCO2 condition, Zone B of the greenschist facies, and Zone C of the greenschist/amphibolite transition facies. In Zone A metabasites, Ca‐Al silicates including Ca‐zeolites, prehnite and pumpellyite are absent and epidote/clinozoisite is extremely rare. Instead, abundant carbonates are present with chlorite suggesting high‐XCO2 composition in the fluid. On the other hand, in Zones B and C metabasites, where Ca‐amphibole + epidote/clinozoisite + chlorite + Ca‐Na plagioclase are the dominant assemblages, carbonate is not identified. The metamorphic conditions boundary of Zones B/C were estimated to be about 350 °C at a pressure of <0.5 kbar. Fluid compositions coexisting with Archaean greenstones at the transition between Zones B and C were estimated by thermodynamic calculation in the CaFMASCH system (T = 350–370 °C, P = 150–1000 bar) at XCO2 of 0.012–0.140, such values are higher than present‐day vent fluids collected near mid‐ocean ridges with low‐XCO2 values, up to 0.005. The Archaean seawater depth at the mid‐ocean ridge was estimated to be 1600 m at XCO2 = 0.06 using a depth‐to‐boiling point curve for a fluid. The carbonation due to high‐XCO2 hydrothermal fluids occurred near the ridge‐axis before or was coincident with ridge metamorphism.  相似文献   

3.
Mineral paragenescs in the prehnite-pumpellyite to greenschistfades transition of the Karmutsen metabasites are markedly differentbetween amygdule and matrix, indicating that the size of equilibriumdomain is very small. Characteristic amygdule assemblages (+chlorite + quartz) vary from: (1) prehnite + pumpeUyite + epidote,prehnite + pumpellyite + calcite, and pumpellyite + epidote+ calcite for the prehnite-pumpellyite facies; through (2) calcite+ epidote + prehnite or pumpellyite for the transition zone;to (3) actinolite + epidote + calrite for the greenschist facies.Actinolite first appears in the matrix of the transition zone.Na-rich wairakites containing rare analcime inclusions coexistwith epidote or Al-rich pumpellyite in one prehnite-pumpellyitefacies sample. Phase relations and compositions of these wairakite-bearingassemblages further suggest that pumpellyite may have a compositionalgap between 0.10 and 0.15 XFe?. Although the facies boundaries are gradational due to the multi-varianceof the assemblages, several transition equilibria are establishedin the amygdule assemblages. At low Xco2, pumpellyite disappearsprior to prehnite by a discontinuous-type reaction, pumpellyite+ quartz + CO2 = prehnite + epidote + calcite + chlorite + H2O,whereas prehnite disappears by a continuous-type reaction, prehnite+ CO2 = calcite + epidote + quartz-l-H2O. On the other hand,at higher XCO2 a prehnite-out reaction, prehnite + chlorite+ H2O + CO2 = calcite + pumpellyite + quartz, precedes a pumpellyiteoutreaction, pumpellyite + CO2 = calcite + epidote + chlorite +quartz + H2O. The first appearance of the greenschist faciesassemblages is defined at both low and high XCOj by a reaction,calcite + chlorite + quartz = epidote + actinolite+ H2O + CO2.Thus, these transition equilibria are highly dependent on bothXFe3+ + of Ca-Al silicates and XH20 of the fluid phase. Phaseequilibria together with the compositional data of Ca-Al silicatesindicate that the prehnite-pumpellyite to greenschist faciestransition for the Karmutsen metabasites occurred at approximately1.7 kb and 300?C, and at very low Xco2, probably far less than0.1.  相似文献   

4.
The Heathcote Greenstone Belt is composed mainly of Lower Cambrian metavolcanic rocks and is one of three outcropping belts of the apparent basement to the Lachlan Fold Belt in SE Australia. The greenstones may be assigned to two broad magma series. A younger tholeiitic series with mid‐ocean ridge basalt (MORB) affinities has intruded through, and been erupted upon low‐Ti, intermediate SiO2 lavas. The latter were originally boninites (both clinoenstatite‐phyric and more fractionated orthopyroxene‐phyric varieties) and plagioclase‐phyric, low‐Ti andesites. They have partially re‐equilibrated to the lower greenschist facies and outcrop mainly in the central segment of the Heathcote Greenstone Belt, where deeper stratigraphic levels are exposed. Tholeiitic lavas and sills metamorphosed to the prehnite‐pumpellyite facies dominate the northern and southern segments. As the association boninite/low‐Ti lavas/MORB is known only from modern West Pacific‐type settings involving island arcs and backarc basins, the early history of the Lachlan Fold Belt is inferred to have taken place in a similar setting.  相似文献   

5.
The Ordovician volcanic rocks in the Mayaxueshan area have been pervasively altered or metamorphosed and contain abundant secondary minerals such as albite, chlorite, epidote, prehnite, pumpellyite, actinolite, titanite, quartz, and/or calcite. They were denoted as spilites or spilitic rocks in terms of their petrographic features and mineral assemblages. The metamorphic grades of the volcanic rocks are equivalent to that of the intercalated metaclastic rocks. This indicates that both the spilitic volcanic rocks and metaclastic rocks in the Mayaxueshan area have formed as a result of Caledonian regional metamorphism. We suggest that the previously denoted spilitic rocks or altered volcanic rocks should be re-denoted as metabasalts or metabasaltic rocks. The metamorphic grade of the volcanic rocks increases with their age: prehnite-pumpellyite facies for the upper part of the Middle Ordovician volcanic rocks, prehnite-pumpeilyite to lower greenschist facies for the lower part of the Middle Ordovician vol  相似文献   

6.
Coexisting primary minerals and hydrous alteration minerals in basalt lavas of the Upper Permian Broughton Formation of the Sydney Basin are indicative of the involvement of a hydrothermal fluid phase during low‐grade metamorphism. Variation and zonation of alteration phases in vesicles and vugs indicate that the alteration minerals developed in response to several episodes of precipitation, with early CO2‐rich fluids producing assemblages rich in calcite and chlorite‐smectite while later CO2‐poor fluids precipitated Ca‐zeolites, prehnite and pumpellyite. Vesicular parts of flows typically show much higher contents of alteration minerals than more massive parts of the same flow, but no systematic increase in either the style or intensity of alteration with increasing depth in the lava pile is evident. The presence of Ca‐zeolites, prehnite, pumpellyite and rare epidote suggests uppermost zeolite facies to lowermost prehnite‐pumpellyite facies metamorphism. Stability relationships of the metamorphic phases based on experimental and theoretical studies, used in conjunction with measured parameters for modern geothermal systems, indicate a peak metamorphic temperature of ～200–230°C while the extant stratigraphy indicates that the maximum depth of burial was ～ 1200 m. Alteration developed in response to circulation of hot, aqueous fluids generated by thermal convection cells associated with the Permian lavas and/or a large buried intrusion.  相似文献   

7.
Metabasalts with abundant pumpellyite have been dredged in the Vema fracture zone, Atlantic ocean, and contain prehnite+pumpellyite±epidote+chlorite+white mica. The prehnite — pumpellyite association in these rocks differs from the prehnite-epidote association for most of the prehnite — pumpellyite facies metabasalts from the ocean crust described previously. The occurrence of pumpellyite is discussed in terms of temperature conditions, and oxygen fugacity and the pumpellyiterich metabasalts are believed to be recrystallized by hydrothermal circulation of seawater at about 250° C under a very low pressure (<1 kb).The bulk composition of the rocks demonstrates a strong chemical modification during hydrothermal metamorphism, similar to what is observed under greenschist facies conditions, except for potassium which can be uptaken from seawater by the rocks.  相似文献   

8.
Abstract. The hydrothermal alteration in Ghuzayn Volcanics was associated with mineralization and accumulation of three massive sulfide deposits. The Ghuzayn Volcanics were discriminated into basaltic and andesitic lavas. The crossplots of Zr versus Nb, Y, Hf, La and Lu show that they fall in the same linear fractionation trends with more evolved affinities in the andesitic lavas compared to the less evolved affinities in the basaltic lavas. The immobile trace element contents of the Ghuzayn Volcanics show that they are of oceanic to continental tholeiitic affinity which fall in the fields of back‐arc basin basalt, N‐MORB and island arc tholeiite all meet and match with the field of the Lau‐Tonga back‐arc basin lavas. The ore‐body No. 2 is underlain by a zone of intense argillization and silicification which are so‐called alteration pipe as in some of the Cyprus‐type massive sulfide deposits. The alteration in the proximity of the ore‐body No. 2 is characterized by a zone of epidotization and slight silicification and sulfide disseminations, and surrounded by another zone of slight silicification and sulfide dissemination in the outermost rim around the ore‐body No. 2. The alteration zones in the proximity of the ore‐body No. 2 were divided into Zones I and II based on the abundance of the secondary minerals in the altered basaltic lavas. The Zone I is located in the most northern upper part of the ore‐body No. 2 and characterized by corrensite, saponite and prehnite. However, the Zone II is located in the southern part of the ore‐body No. 2 and characterized by chlorite and epidote. Both alteration zones were formed by different alteration stages. Stage 1 was formed by non to partly reacted fluids, to crystallize Mg‐chlorite and albite at temperatures ranging from 150 to 250d?C. Further, these fluids evolved with time and became Mg‐depleted, Si‐ and metal‐enriched to crystallize Fe2+‐chlorite, epidote, quartz and sulfides at temperatures ranging from 250 to 350d?C in stage 2. Later, these fluids were evolved again to be Mg‐ and Ca‐enriched in stage 3 to crystallize prehnite, laumontite, corrensite and saponite at temperatures ranging from 150 to 220d?C. Late zeolite and calcite have overgrown the previously crystallized phases and crosscutting veins along the altered basaltic lavas in stage 4. Finally, the lavas were cracked and refractured to facilitate penetration of seawater into deeper parts to heat up again and re‐leach the silica and metals in a new mineralizing event.  相似文献   

9.
The geochemistry of the metavolcanic rocks from the Granjeno Schist in northeastern Mexico indicates an origin in different tectonic environments: mid‐ocean ridge and ocean island. High ratios of Hf/Th and Th/Nb (4.4–14 and 0.08–0.15), low ratios of LaN/YbN and LaN/SmN (0.74–1.7 and 0.60–1.4) and depleted LREE patterns in metabasalt display mid‐ocean ridge characteristics. In contrast, the pattern of trace‐element ratios and REEs in metabasalt and metapillow lava 60 km to the west indicates a magma source with ocean‐island basalt characteristics. Both areas were metamorphosed during the Late Carboniferous (300 ± 4 Ma). Estimated metamorphic conditions deduced from white mica and chlorite compositions, distinguish greenschist facies (350 °C and 4 kbar) for the mid‐ocean ridge basalt, and prehnite–pumpellyite facies (250 °C and 2.5 kbar) for the ocean‐island‐type basalt. This metamorphism took place at an active continental margin during Pennsylvanian time. Our new tectonic model, which differs from earlier models, suggests that the origin of the Granjeno Schist is related to a subduction zone located at the western margin of Pangaea, active after Laurentia–Gondwana collision. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

10.
Pumpellyite from four-phase assemblages (pumpellyite + epidote + prehnite + chlorite; pumpellyite + epidote + actinolite + chlorite; pumpellyite + epidote + Na-amphibole + chlorite, together with common excess phases), considered to be low variance in a CaO-(MgO + FeO)-Al2O3-Fe2O3 (+Na2O + SiO2+ H2O) system, have been examined in areas which underwent metamorphism in the prehnite-pumpellyite, pumpellyite-actinolite and low-temperature blueschist facies respectively. The analysed mineral assemblages are compared for nearly constant (basaltic) chemical composition at varying metamorphic grade and for varying chemical composition (basic, intermediate, acidic) at constant metamorphic conditions (low-temperature blueschist facies). In the studied mineral assemblages, coexisting phases approached near chemical equilibrium. At constant (basaltic) bulk rock composition the MgO content of pumpellyite increases, and the XFe3+ of both pumpellyite and epidote decreases with increasing metamorphic grade, the Fe3+ being preferentially concentrated in epidote. Both pumpellyite and epidote compositions vary with the bulk rock composition at isofacial conditions; pumpellyite becomes progressively enriched in Fe and depleted in Mg from basic to intermediate and acidic bulk rock compositions. The compositional comparison of pumpellyites from high-variance (1–3 phases) assemblages in various bulk rock compositions (basic, intermediate, acidic rocks, greywackes, gabbros) shows that the compositional fields of both pumpellyite and epidote are wide and variable, broadly overlapping the compositional effects observed at varying metamorphic grade in low-variance assemblages. The intrinsic stability of both Fe- and Al-rich pumpellyites extends across the complete range of the considered metamorphic conditions. Element partitioning between coexisting phases is the main control on the mineral composition at different P-T conditions.  相似文献   

11.
Permian greenstones in the Jurassic Mino–Tamba accretionary complex, southwest Japan, are divided into three distinct series on the basis of their geological occurrence, mineralogy, and geochemistry. A low-Ti series (LTS) is associated with Lower Permian chert and limestone, and is the most voluminous of the three series. The LTS shows slightly more enriched geochemical and isotopic characteristics than MORB. A transition series (TS) is mainly associated with Lower Permian chert, and has more enriched geochemical signatures than MORB. Its isotopic characteristics are divided into enriched and depleted types. A high-Ti series (HTS) occurs as sills and hyaloclastites within Middle Permian chert and as dikes intruding the TS. Some HTS rocks have high MgO contents. The HTS is characterized by enrichment in incompatible trace elements and an isotopic composition comparable to HIMU-type basalt. The geochemistry of the voluminous LTS is similar to that of the oceanic basalt series of the Kerguelen plateau, suggesting production by partial melting of a shallow mantle plume head below thick oceanic lithosphere in Early Permian time. We infer that the TS formed simultaneously at the margins of the mantle plume head. In contrast, the HTS may have resulted from partial melting of a deep mantle plume tail in Middle Permian time. Permian greenstones in the Mino–Tamba belt may have thus formed by superplume activity in an intra-oceanic setting. Given the presence of two known contemporary continental flood basalt provinces (Siberia and Emeishan) and some accreted oceanic plateau basalts, the vast magmatism of the Mino–Tamba oceanic plateau suggests a large-scale superplume pulse in Permian time. Accretion of oceanic plateaux may have played an important role in the growth of continental margins and island arcs in Japan and elsewhere in the circum-Pacific region.  相似文献   

12.
The pumpellyite–actinolite facies proposed by Hashimoto is defined by the common occurrence of the pumpellyite–actinolite assemblage in basic schists. It can help characterize the paragenesis of basic and intermediate bulk compositions, which are common constituents of various low-grade metamorphic areas. The dataset of mutually consistent thermodynamic properties of minerals gives a positive slope for the boundary between the pumpellyite–actinolite and prehnite–pumpellyite facies in P–T space. In the Sanbagawa belt in Japan, the mineral parageneses of hematite-bearing and -free basic schists, as well as pelitic schists have been well documented. The higher temperature limit of this facies is defined by the disappearance of the pumpellyite+epidote+actinolite+chlorite assemblage in hematite-free basic schists with XFe3+ of epidote around 0.20–0.25 and the appearance of epidote+actinolite+chlorite assemblage with XEpFe3+≤0.20. In hematite-bearing basic schists, there is a continuous change of paragenesis to higher grade, epidote–glaucophane or epidote–blueschist facies. In pelitic schists, the albite+lawsonite+chlorite assemblage does occur but only rarely, and its assemblage cannot be used to determine the regional thermal structure. The lower temperature equivalence of the pumpellyite–actinolite assemblage is not observed in the field. The Mikabu Greenstone complex and the northern margin of the Chichibu complex, which are located to the south of the Sanbagawa belt, are characterized by clinopyroxene+chlorite or lawsonite+actinolite assemblages, which are lower temperature assemblages than the pumpellyite+actinolite assemblage. These three metamorphic complexes belong to the same subduction-metamorphic complex. The pumpellyite–actinolite facies or subfacies can be useful to help reveal the field thermal structure of metamorphic complexes  相似文献   

13.
A sequence of regional metamorphic isograds indicating a range from prehnite-pumpellyite to lower amphibolite facies was mapped in metabasites near Flin Flon, Manitoba. The lowest grade rocks contain prehnite + pumpellyite and are cut by younger brittle faults containing epidote + chlorite + calcite. Isobaric temperature- X CO2 and pressure-temperature (constant X CO2) diagrams were calculated to quantify the effects of CO2 in the metamorphic fluid on the stability of prehnite-pumpellyite facies minerals in metabasites containing excess quartz and chlorite. Prehnite and, to a lesser extent, pumpellyite are stable only in fluids with X co2 <0.002. For X co2>0.002, epidote + chlorite + calcite assemblages are stable. Our calculated phase relations are consistent with regional metamorphism in the Flin Flon area in the presence of an H2O-rich fluid and a more CO2-rich fluid in the later fault zones. We believe that the potential effects of small amounts of CO2 in the metamorphic fluid should be assessed when considering the pressure-temperature implications of mineral assemblages in low-grade metabasites.  相似文献   

14.
中国西部祁连山柴北缘地区和南阿尔金地区存在一条被阿尔金断裂错开 4 0 0km ,但构造上相连的早古生代超高压变质带。通过对柴北缘地区大柴旦、锡铁山、都兰和南阿尔金地区且末一带榴辉岩的岩石地球化学研究 ,发现榴辉岩原岩主要由玄武岩和苦橄岩两类岩石组成 ,进一步分为高Ti型 (w(TiO2 ) =2 %～ 5 % ) ,中Ti型 (1%～ 2 % )和低Ti型 (<1% ) 3种类型 ,识别出榴辉岩的原岩类型有洋脊玄武岩、岛弧拉斑玄武岩和洋岛玄武岩类等产在不同环境的岩石类型。榴辉岩的Nd同位素组成与现代洋脊玄武岩类相似 ,ε(Nd ,0 )主要为正值 ,少量为轻微负值 ,表明榴辉岩的原岩曾是海底玄武岩 ,并且经过了消减俯冲作用 ,混入了部分的地壳物质。榴辉岩的超高压变质年龄为 5 0 0～ 4 4 0Ma,原岩年龄分别为 80 0～ 75 0Ma和～ 10 0 0Ma。研究表明 ,柴北缘滩涧山群中存在两套时代不同的基性超基性岩 ,一套为产在绿梁山的新元古代时期形成的蛇绿岩组合 ,新获得的年龄值为 (76 8±39)Ma(Rb Sr)和 (780± 2 2 )Ma(Sm Nd) ,另一套主要为产在赛什腾山的晚寒武世岛弧火山岩 ,形成时代约在 5 15～ 4 86Ma。榴辉岩的岩石化学成分和Nd同位素组成 ,以及 80 0～ 75 0Ma的原岩时代与其中的新元古代基性岩类可以对比。初步认为它们是同一套岩石?  相似文献   

15.
The upper Triassic Karmutsen metabasites from northeast VancouverIsland, B.C., are thermally metamorphosed by the intrusion ofthe Coast Range Batholith. The amygdaloidal metabasites developedin the outer portion of the contact aureole show a progressivemetamorphism from zeolite to prehnite-pumpellyite facies. Thesize of an equilibrium domain is extremely small for these metabasites,and the individual amygdule assemblages are assumed to be inequilibrium. Two major calcite-free assemblages (+chlorite+quartz)are characteristic: (i) laumontite+pumpellyite+epidote in thezeolite facies and (ii) prehnite+pumpellyite+epidote in theprehnite-pumpellyite facies. The assemblages and compositionsof Ca-Al silicates are chemographically and theoretically interpretedon the basis of the predicted P-T grid for the model basalticsystem, CaO-MgO-A12O3-Fe2O3-SiO2-H2O. The results indicate:(1) local equilibrium has been approached in mineral assemblagesand compositions; (2) the XFe3+ values in the coexisting Ca-Alsilicates decrease from epidote, through pumpellyite to prehnite;(3) with increasing metamorphic grade, the Fe3+ contents ofepidotes in reaction assemblages decrease in the zeolite facies,then increase in the prehnite-pumpellyite facies rocks. Suchvariations in the assemblages and mineral compositions are controlledby a sequence of continuous and discontinuous reactions, andallow delineation of T-XFe3+ relations at constant pressure.The transition from the zeolite to prehnite-pumpellyite faciesof the Karmutsen metabasites is defined by a discontinuous reaction:0·18 laumontite+pumpellyite+0·15 quartz = 1·31prehnite+ 0·78 epidote+0·2 chlorite+ 1·72H2O, where the XFe3+ values of prehnite, pumpellyite and epidoteare 0·03, 0·10 and 0·18, respectively.These values together with available thermodynamic data andour preliminary experimental data are used to calculate theP-T condition for the discontinuous reaction as P = 1·1±0·5 kb and T = 190±30°C. The effectsof pressure on the upper stability of the zeolite facies assemblagesare discussed utilizing T-XFe3+ diagrams. The stability of thelaumontite-bearing assemblages for the zeolite facies metamorphismof basaltic rocks may be defined by either continuous or discontinuousreactions depending on the imposed metamorphic field gradient.Hence, the zeolite and prehnite-pumpellyite facies transitionboundary is multivariant.  相似文献   

16.
Abstract The Cretaceous-Eocene basic to intermediate marine volcanic rocks of the Mucuchi Formation constitute the Western Cordillera in northern Ecuador. Their chemical features mostly correspond to those of tholeiitic basalts with some calc-alkaline affinities and suggest an oceanic island arc setting. The Macuchi rocks are affected by low-grade, non-deformative metamorphism, characterized by zeolite, prehnite-pumpellyite and lower greenschist facies assemblages. Depth-zonation is suggested by the downward mineral sequence: (i) laumontite+ (pistacitic epidote, pumpellyite + prehnite); (ii) pumpellyite+ prehnite + pistacitic epidote; (iii) actinolite+biotite+ pistacitic epidote + chlorite. This broad zonation and the chemistry of individual minerals point to an interaction between the volcanic rocks and sea-water under a moderate to high thermal gradient (= 75° C/km?). Alteration appears to have been dependent primarily on fluid control (volume, pressure, composition), temperature and reaction kinetics which together partly overshadow the role of load-pressure. Compositional variations of a mineral species at the scale of a contiguous flow or even at the scale of a thin section show that intensity of alteration was spatially uneven depending on rock permeability and consequently, metastable equilibrium commonly exists. However, a progressive approximation to equilibrium as a result of P–T control is shown by the mineralogy. A high fo2 of the fluid phase is evident from the mineral chemistry. The metamorphism of the Macuchi volcanics is similar to the hydrothermal-burial type produced during the development of a volcanic arc where lavas and volcanoclastics accumulated in a shallow marine environment. However, some of its characteristics point to a transition toward systems defined by a higher T/P ratio such as those found in ocean-floor metamorphism. A model is proposed in which the Macuchi volcanics are assigned to an oceanic island arc generated contemporaneously with a marginal basin which has opened as the outcome of progressive north-south attenuation of the continental crust due to mantle diapirism.  相似文献   

17.
The major mineral assemblages of the metabasites of the Omoiji-Nagasawaarea in central Shikoku are hematite+epidote+chlorite+actinolite,riebeckitic actinolite+epidote+chlorite, epidote+chlorite+actinolite,and pumpellyite+epidote+chlorite+actinolite. The constituentminerals are often heterogeneous and assemblages in the fieldof a thin section sometimes do not obey the phase rule, butif grains apparently in non-equilibrium with others are excludedand domains of chemical equilibrium are appropriately chosenthe assemblages approximately obey the phase rule. The stability of hematite, pumpellyite, and epidote associatedwith chlorite and actinolite can be dealt with in terms of aternary system with appropriate excess phases. By fixing theFe2+/(Fe2+ +Mg) ratio of chlorite, it is dealt with in termsof stability relations in the system Ca2Al3Si3O12(OH)–Ca2AlFe2Si3O12(OH)with excess chlorite, actinolite, quartz, and controlled PH2O.The maximum and minimum Fe3+ contents of epidote in this modelsystem are determined by hematite+epidote+chlorite+actinoliteand pumpellyite+epidote+chlorite+actinolite assemblages. Themaximum Fe3+ of the three phase assemblage epidote+chlorite+actinoliteis insensitive to temperature, but the minimum Fe3+ contentof epidote is sensitive to temperature and can be used to definethe metamorphic grade by a continuous quantity related to temperature.The phase relations expected for the model system are in goodagreement with the parageneses of the Sanbagawa terrain in centralShikoku and offer an explanation to the rule of Miyashiro &Seki (1958a) that the compositional range of epidote enlargeswith increasing temperature. The model also makes it possibleto estimate semi-quantitatively the temperature range in whichthe assemblage pumpellyite+epidote+chlorite+actinolite is stable.The possible maximum range is about 120 ?C, but the assemblageis stable in metabasite only for about 90 ?C. The higher temperaturelimit of the pumpellyite-actinolite facies defined by the disappearanceof pumpellyite in metabasite corresponds to the temperatureat which epidote with Fe3+/(Fe3+ +Al) = 0.10 0.15 coexistswith pumpellyite, actinolite, and chlorite. The compositions of epidotes in the metabasites of the Omoiji-Nagasawaarea cluster around Fe3+/(Fe3+ +Al) = 0.33. The grade of thisarea is close to the lower temperature stability limit of thepumpellyite+epidote+chlorite+actinolite assemblage.  相似文献   

18.
Phase relations of pumpellyite, epidote, lawsonite, CaCO3, paragonite, actinolite, crossite and iron oxide are analysed on an Al-Ca-Fe3+ diagram in which all minerals are projected from quartz, albite or Jadeite, chlorite and fluid. Fe2+ and Mg are treated as a single component because variation in Fe2+/Mg has little effect on the stability of phases on the diagram. Comparison of assemblages in the Franciscan, Shuksan, Sanbagawa, New Caledonia, Southern Italian, and Otago metamorphic terranes reveals several reactions, useful for construction of a petrogenetic grid:
  1. lawsonite+crossite + paragonite = epidote+chlorite + albite + quartz + H2O
  2. lawsonite + crossite = pumpellyite + epidote + chlorite + albite+ quartz + H2O
  3. crossite + pumpellyite + quartz = epidote + actinolite + albite + chlorite + H2O
  4. crossite + epidote + quartz = actinolite + hematite + albite + chlorite + H2O
  5. calcite + epidote + chlorite + quartz = pumpellyite + actinolite + H2O + CO2
  6. pumpellyite + chlorite + quartz = epidote + actinolite + H2O
  相似文献   

19.
Two contrasting styles of metamorphism are preserved in the central Southern Cross Province. An early, low‐grade and low‐strain event prevailed in the central parts of the Marda greenstone belt and was broadly synchronous with the first major folding event (D1) in the region. Mineral assemblages similar to those encountered in sea‐floor alteration are indicative of mostly prehnite‐pumpellyite facies conditions, but locally actinolite‐bearing assemblages suggest conditions up to mid‐greenschist facies. Geothermobarometry indicates that peak metamorphic conditions were of the order of 250–300°C at pressures below 180 MPa in the prehnite‐pumpellyite facies, but may have been as high as 400°C at 220 MPa in the greenschist facies. A later, higher grade, high‐strain metamorphic event was largely confined to the margins of the greenstone belts. Mineral assemblages and geothermobarometry suggest conditions from upper greenschist facies at P–T conditions of about 500°C and 220 MPa to upper amphibolite facies at 670°C and 400 MPa. Critical mineral reactions in metapelitic rocks suggest clockwise P–T paths. Metamorphism was diachronous across the metamorphic domains. Peak metamorphic conditions were reached relatively early in the low‐grade terrains, but outlasted most of the deformation in the higher grade terrains. Early metamorphism is interpreted to be a low‐strain, ocean‐floor‐style alteration event in a basin with high heat flow. In contrast, differential uplift of the granitoids and greenstones, with conductive heat input from the granitoids into the greenstones, is the preferred explanation for the distribution and timing of the high‐strain metamorphism in this region.  相似文献   

20.
In this study, we have deduced the thermal history of the subducting Neotethys from its eastern margin, using a suite of partially hydrated metabasalts from a segment of the Nagaland Ophiolite Complex (NOC), India. Located along the eastern extension of the Indus‐Tsangpo suture zone (ITSZ), the N–S‐trending NOC lies between the Indian and Burmese plates. The metabasalts, encased within a serpentinitic mélange, preserve a tectonically disturbed metamorphic sequence, which from west to east is greenschist (GS), pumpellyite–diopside (PD) and blueschist (BS) facies. Metabasalts in all the three metamorphic facies record prograde metamorphic overprints directly on primary igneous textures and igneous augite. In the BS facies unit, the metabasalts interbedded with marble show centimetre‐ to metre‐scale interlayering of lawsonite blueschist (LBS) and epidote blueschist (EBS). Prograde HP/LT metamorphism stabilized lawsonite + omphacite (XJd = 0.50–0.56 to 0.26–0.37) + jadeite (XJd = 0.67–0.79) + augite + ferroglaucophane + high‐Si phengite (Si = 3.6–3.65 atoms per formula unit, a.p.f.u.) + chlorite + titanite + quartz in LBS and lawsonite + glaucophane/ferroglaucophane ± epidote ± omphacite (XJd = 0.34) + chlorite + phengite (Si = 3.5 a.p.f.u.) + titanite + quartz in EBS at the metamorphic peak. Retrograde alteration, which was pervasive in the EBS, produced a sequence of mineral assemblages from omphacite and lawsonite‐absent, epidote + glaucophane/ferroglaucophane + chlorite + phengite + titanite + quartz through albite + chlorite + glaucophane to lawsonite + albite + high‐Si phengite (Si = 3.6–3.7 a.p.f.u.) + glaucophane + epidote + quartz. In the PD facies metabasalts, the peak mineral assemblage, pumpellyite + chlorite + titanite + phengitic white mica (Si = 3.4–3.5 a.p.f.u.) + diopside appeared in the basaltic groundmass from reacting titaniferous augite and low‐Si phengite, with prehnite additionally producing pumpellyite in early vein domains. In the GS facies metabasalts, incomplete hydration of augite produced albite + epidote + actinolite + chlorite + titanite + phengite + augite mineral assemblage. Based on calculated T–M(H2O), T–M(O2) (where M represents oxide mol.%) and P–T pseudosections, peak P–T conditions of LBS are estimated at ~11.5 kbar and ~340 °C, EBS at ~10 kbar, 325 °C and PD facies at ~6 kbar, 335 °C. Reconstructed metamorphic reaction pathways integrated with the results of P–T pseudosection modelling define a near‐complete, hairpin, clockwise P–T loop for the BS and a prograde P–T path with a steep dP/dT for the PD facies rocks. Apparent low thermal gradient of 8 °C km?1 corresponding to a maximum burial depth of 40 km and the hairpin P–T trajectory together suggest a cold and mature stage of an intra‐oceanic subduction zone setting for the Nagaland blueschists. The metamorphic constraints established above when combined with petrological findings from the ophiolitic massifs along the whole ITSZ suggest that intra‐oceanic subduction systems within the Neotethys between India and the Lhasa terrane/the Karakoram microcontinent were also active towards east between Indian and Burmese plates.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号