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1.
We have investigated Pb concentrations and isotopic compositions in settling particles collected by sediment traps experiments over a period of two years, from May 2005 to April 2007, at two depths, 770 and 5100 m, at station KNOT in the Northwestern Pacific Ocean (44°N, 155°E). To the identify provenances of Pb, the samples were separated into two fractions by chemical leaching techniques, with the leachate expected to contain Pb of anthropogenic origin. Isotopic compositions of Pb and concentrations of Pb, Sc, Mn, La, Yb, and Th were measured by quadrupole ICP-MS. The isotope ratios of leachable Pb in settling particles were 207Pb/206Pb = 0.860 ± 0.001; 208Pb/206Pb = 2.116 ± 0.002 (mean ± 95% confidence intervals), which are similar to those of aerosols in China that are greatly affected by pollution from coal combustion. We estimated the mean contribution from anthropogenic Pb sources to the Pb in settling particles, using the conventional binary (anthropogenic and natural Pb) mixing equation for Pb isotopes, as 90% in the upper trap and 78% in the lower trap. Furthermore, we found a significant negative correlation between the isotope ratios of Pb and concentrations of leachable Mn, normalized to those of leachable Pb, suggesting that manganese oxides play an important role in transporting Pb from the upper layers of the ocean to the deeper layers. Our results support the speculation published in a previous study that Pb might be scavenged by Mn oxides in the Northwestern Pacific Ocean.  相似文献   

2.
Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for 207Pb/206Pb and 208Pb/206Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for 207Pb/206Pb (208Pb/206Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for 207Pb/206Pb and 208Pb/206Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.  相似文献   

3.
Submarine canyons represent natural conduits for preferential transport of particulate material, including anthropogenic contaminants, from coastal zones directly to the deep sea. To assess related dispersal of natural and anthropogenic lead (Pb), we analyzed Pb concentrations and stable isotope ratios in surface sediments and sediment trap particulate material from the Portuguese margin Nazaré and Setúbal/Lisbon canyons. Geochemical data are integrated with previously obtained data on near-bottom hydrodynamics and processes and pathways of sediment transport. The two canyon systems are located in close geographic proximity to each other, but represent contrasting settings in terms of sediment input and down-canyon sediment transport processes.Concentration–isotope diagrams and three-isotope plots (206Pb/207Pb vs. 208Pb/206Pb) suggest binary mixing between natural and anthropogenic end members. The inferred isotopic signature of pollutant Pb (206Pb/207Pb=1.143 [1.134–1.149, 95% confidence interval]) is most consistent with industrial Pb; ongoing influence from gasoline Pb additives is at most of minor importance. Two proposed natural end members most likely bracket the isotopic signature of natural Pb. Accordingly, binary mixing calculations indicate that on average 20–45% vs. 35–55% of total Pb is derived from anthropogenic sources in the Nazaré and Setúbal–Lisbon canyon systems, respectively. Enhanced anthropogenic influence in the latter area is consistent with its proximity to heavily populated and industrialized areas and with sediment input from the Tagus and Sado rivers, potential major carriers of pollutant particles. In both canyon systems, the anthropogenic component generally decreases with increasing water depth.Isotopic signatures of sediment trap particulate material are generally consistent with surface sediment data at similar water depth, but show large variability in the upper Nazaré canyon and major deviations from surface sediments in the lower canyon. In the lower canyon, Pb isotopic ratios of sediment trap particulate material mostly reflect low pelagic fluxes from the overlying water column, whereas surface sediment signatures are dominated by episodic down-canyon mass transport events. Such gravity flows appear to incorporate older (pre-industrial) material masking the isotopic signature of pollutant Pb. Large variability in the upper canyon reflects continuous sediment resuspension by bottom currents. Stronger average bottom currents are associated with higher 206Pb/207Pb ratios of sediment trap particulate material and hence decreased influence of pollutant Pb. This may reflect preferential resuspension of natural Pb at the canyon floor and/or additional remobilization of older, less-polluted sediment in adjacent areas such as the canyon walls.  相似文献   

4.
To investigate the factors controlling lead (Pb) concentration and identify the sources of Pb in Yellow Sea sediments along the Korean coast, the concentration of Pb and Pb isotopes in 87 surface and 6 core sediment samples were analyzed. The 1 M HCl leached Pb concentrations had a similar geographic distribution to those of fine-grained sediments, while the distribution of residual Pb concentrations resembled that of coarse-grained sediments. Leached Pb was presumed to be associated with manganese (Mn) oxide and iron (Fe) oxy/hydroxide, while residual Pb was associated with potassium (K)-feldspar, based on good linear relationships between the leached Pb and the Fe/Mn concentrations, and the residual Pb and K concentrations. Based on a ratio–ratio plot with three isotopes (207Pb/206Pb and 208Pb/206Pb) and the geographic location of each sediment, sediments were categorized into two groups of samples as group1 and group2. Group 1 sediments, which were distributed in Gyeonggi Bay and offshore (north of 36.5°N), were determined to be a mixture of anthropogenic and natural Pb originating from the Han River, based on a 208Pb/206Pb against a Cs/Pbleached mixing plot of core and surface sediments. Group 2 sediments, which were distributed in the south of 36.5°N, also showed a two endmembers mixing relationship between materials from the Geum River and offshore materials, which had very different Pb concentrations and isotope ratios. Based on the isotopes and their concentrations in core and surface sediments, this mixing relationship was interpreted as materials from two geographically different origins being mixed, rather than anthropogenic or natural mixing of materials with the same origin. Therefore, the relative percentage of materials supplied from the Geum River was calculated using a two endmembers mixing model and estimated to be as much as about 50% at 35°N. The spatial distribution of materials derived from the Geum River represented that of fine-grained sediments originating from the Geum River. It was concluded that Pb isotopes in sediments could be used as a tracer in studies of the origin of fine-grained sediments along the Korean Yellow Sea coast.  相似文献   

5.
Measurements of the concentration of thallium in seawater collected from numerous ocean locations ranged from 12 to 16 ng kg−1. Variations between the Atlantic and Pacific Oceans, between the northern and southern hemispheres of the Pacific Ocean, and between surface and deep waters of both the Pacific and Atlantic oceans were comparable with the precision of the analyses. This relatively constant distribution indicates that the element's cycle in seawater may be similar to those of the alkali metals which are its principal biogeochemical analogues.  相似文献   

6.
The concentrations of total lead were determined in both ordinary coastal seawater and in coastal waters highly polluted with sewage. The average concentration of total lead ranged from about 25 ng/kg in surface samples of the former type to an average of 150 ng/kg in the latter type. 0.4−μm filtrate lead was found to be equivalent to lead extracted from untreated seawater by dithizone in chloroform. In highly polluted waters, particle lead ranged from 56 to 39% of the total lead, with the proportion increasing as the amount of sewage in the seawater increased. Virtually all of the lead in sewage is contained in the particle phase before it enters the ocean but about 11% is made freely available by cation exchange when the sewage is mixed with seawater. In ordinary coastal waters that are not highly polluted with sewage lead, particle lead ranged from 90 to > 20%, and most of this lead was associated with plankton. About one-third of total lead, or one-half of particle lead, in untreated seawater adheres to the walls of the water container within the first day. Upon prolonged standing (> 3 months) most of the remaining particle lead can be collected on the surface of algal colonies growing on the walls of the water container. The concentrations of freely available lead in seawater do not seem to be significantly affected by wall adsorption. The 206Pb/207Pb ratio of total lead in coastal surface seawater collected near Los Angeles was 1.194, and a day earlier was 1.188 near La Jolla. It is believed that this shows lack of mixing of contributions from two different sources of lead pollution: a pulse of rain-storm runoff of gasoline lead(206Pb/207Pb 1.197) from paved surfaces added to Los Angeles waters; and sewage lead (206Pb/207Pb 1.188) from San Diego added to La Jolla waters.  相似文献   

7.
We conducted full-depth hydrographic observations between 8°50′ and 44°30′N at 165°W in 2003 and analyzed the data together with those from the World Ocean Circulation Experiment and the World Ocean Database, clarifying the water characteristics and deep circulation in the Central and Northeast Pacific Basins. The deep-water characteristics at depths greater than approximately 2000 dbar at 165°W differ among three regions demarcated by the Hawaiian Ridge at around 24°N and the Mendocino Fracture Zone at 37°N: the southern region (10–24°N), central region (24–37°N), and northern region (north of 37°N). Deep water at temperatures below 1.15 °C and depths greater than 4000 dbar is highly stratified in the southern region, weakly stratified in the central region, and largely uniform in the northern region. Among the three regions, near-bottom water immediately east of Clarion Passage in the southern region is coldest (θ<0.90 °C), most saline (S>34.70), highest in dissolved oxygen (O2>4.2 ml l?1), and lowest in silica (Si<135 μmol kg?1). These characteristics of the deep water reflect transport of Lower Circumpolar Deep Water (LCDW) due to a branch current south of the Wake–Necker Ridge that is separated from the eastern branch current of the deep circulation immediately north of 10°N in the Central Pacific Basin. The branch current south of the Wake–Necker Ridge carries LCDW of θ<1.05 °C with a volume transport of 3.7 Sv (1 Sv=106 m3 s?1) into the Northeast Pacific Basin through Horizon and Clarion Passages, mainly through the latter (～3.1 Sv). A small amount of the LCDW flows northward at the western boundary of the Northeast Pacific Basin, joins the branch of deep circulation from the Main Gap of the Emperor Seamounts Chain, and forms an eastward current along the Mendocino Fracture Zone with volume transport of nearly 1 Sv. If this volume transport is typical, a major portion of the LCDW (～3 Sv) carried by the branch current south of the Wake–Necker and Hawaiian Ridges may spread in the southern part of the Northeast Pacific Basin. In the northern region at 165°W, silica maxima are found near the bottom and at 2200 dbar; the minimum between the double maxima occurs at a depth of approximately 4000 dbar (θ～1.15 °C). The geostrophic current north of 39°N in the upper deep layer between 1.15 and 2.2 °C, with reference to the 1.15 °C isotherm, has a westward volume transport of 1.6 Sv at 39–44°30′N, carrying silica-rich North Pacific Deep Water from the northeastern region of the Northeast Pacific Basin to the Northwest Pacific Basin.  相似文献   

8.
渤海中部沉积物铅来源的同位素示踪   总被引：1，自引：1，他引：0  
本研究对渤海中部表层和柱状沉积物中Pb的含量和同位素进行了分析,研究了其时空分布规律,并探讨了其物质来源。结果表明,表层沉积物中Pb的含量为14.54×10-6~59.42×10-6,其含量在渤海湾近岸、黄河口附近、研究区的东北部较高,而在研究区的中部和渤海湾北部含量较低;Pb同位素207Pb/206Pb的值为0.8341~0.8489,208Pb/206Pb的值为2.0828~2.0980。岩心沉积物中Pb含量、同位素组成与表层沉积物相似,整体上较为稳定,但在1990s以来呈现增大的趋势。渤海中部沉积物中Pb以自然来源为主,黄河沉积物是其主要物质来源,但渤海湾北端则与滦河源物质或沿岸侵蚀相关;人类活动影响主要出现在1990s以后,与中国含Pb矿石的燃烧等工业活动相关,但影响微弱,仅在黄河口西北近岸海域、渤海湾等个别站位得到体现。  相似文献   

9.
We deployed hydroponic eelgrass, Zostera marina L., to test its use as a sentinel accumulator and indicator of the source of water-borne lead (Pb) contamination in the marine environment. Eelgrass was deployed unrooted in the water column in the vicinity of the Portsmouth Naval Shipyard, located on Seavey Island in Portsmouth Harbor of New Hampshire and Maine, offshore from seepage sites near the Jamaica Island landfill (JIL). Deployed eelgrass, water samples from seepage sites, and sediment from the deployment sites were analyzed for Pb concentration and stable Pb isotopic composition. Isotopic composition was used to distinguish recent anthropogenic Pb inputs from background Pb in the estuary. Isotope ratios indicated that two groundwater seeps were a source of recent anthropogenic Pb (i.e. industrial Pb from the landfill) to Jamaica Cove. The eelgrass that showed the strongest presence of industrial Pb (having the lowest 206Pb/207Pb) was closest to a high volume seep that drained from the JIL and had a similar isotope signature as well as elevated Pb concentrations. These data confirm a source of water-borne industrial Pb in the estuary and show that eelgrass can function as a sentinel accumulator of Pb from anthropogenic sources.  相似文献   

10.
The 210Pb geochronology, heavy metal concentrations (Zn, Cu, and Pb), and stable Pb isotope ratios (206Pb/207Pb) of three sediment cores collected from Jakarta Bay were analyzed to decipher the history of heavy metal contamination in the period 1900–2006. The chemical and isotopic analyses clearly suggest that anthropogenic metal accumulation in the sediments began in the 1920s and increased greatly from the 1970s until the end of the 1990s. From the end of the 1990s to 2006, accumulation rates were constant or decreased for Zn and Pb near the coastal industrialized area. Comparison of economic data and sociological information suggests that the decline in the concentrations of heavy metals could be attributed to the stricter environmental regulations which were enforced at the end of 1990s. However, metal contamination is currently still an important cause of concern in dealing with environmental preservation and protection in Jakarta Bay.  相似文献   

11.
Lead concentrations and isotopic composition have been measured in bone and teeth of small cetaceans belonging to three species (Delphinus delphis, Phocoena phocoena and Stenella coeruleoalba), to evaluate the toxicological risk and to determine sources of lead in the European waters. Lead concentrations, far lower than threshold value inducing toxic effects in human, were higher in teeth than in bones, but highly correlated between the two tissues (r=0.92, p<0.001). Large variations of 206Pb/207Pb values in bone tissue showed that cetaceans must be submitted to various atmospheric influences. No geographical differences appeared which is consistent with studies on their distribution indicating seasonal movements between Brittany waters and the Bay of Biscay. The negative correlation between 206Pb/207Pb ratios and age of the individuals reflected the decrease in the production of alkyl lead in Europe, i.e., the increasing use of unleaded gasoline.  相似文献   

12.
Abstract

The geochemical characteristics and Pb isotope variations in Fe-Mn deposits collected from the South China Sea (SCS) were studied in this paper. The mineralogical and chemical composition data indicate that the deposits are almost all hydrogenetic in origin. Compared with the Fe-Mn deposits in other oceans, the SCS Fe-Mn deposits have a significantly higher Pb content because of higher material supply in addition to a lower growth rate of the deposits. Pb isotope ratios in the surface of the SCS Fe-Mn deposits are relatively uniform, with a characteristic of relatively lower 206Pb/204Pb ratio. The Pb isotopic compositions of the SCS Fe-Mn deposits are controlled by the Pacific Deep Water and local inputs, which include eolian dust from the Asian continent and weathering products from Taiwan, Luzon and SCS submarine volcanic rocks. The continuously increasing 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios along the transect of nodule D581 over the past 3.5?Ma are affected by the stepwise closure of the Luzon Strait that reduced volcanic material supply and the deep current strengthen at the same time.  相似文献   

13.
《Oceanologica Acta》1998,21(4):533-542
Seawater samples collected in the northeast Pacific from 112° 50′W to 126° 36′W along a latitudinal band (21–25° N) have been analysed for 228RA and 226Ra. Both nuclides exhibit their characteristic distributions. In the surface water, the exponential-like decrease of 228 Ra away from Baja California can be interpreted by horizontal water mixing with eddy diffusion coefficients (Kx) of 1 × 106 cm2 s−1 and 5 × 107 cm2 S−1 for scale lengths of 200 km and 1000 km, respectively. In the bottom waters, the decrease of 228Ra away from bottom sediments can be modeled by vertical eddy diffusivities (Kz) of 15–30 cm2 s−1 except at one station (24° 16.9′ N, 115° 8.9′ W) where a value of 120 cm2 s−1 is obtained. The 228Ra-derived diffusivities were used to compute the mass balance of 226Ra using a two-box model. The model results show a mean mixing coefficient of 3.8 cm2 s−1 for the thermocline and a mean upwelling velocity of 7.7 m y−1 in the study area, both are about two or three times higher than those generally quoted for the Pacific.  相似文献   

14.
《Journal of Sea Research》2007,57(2-3):171-179
We examined the relationship between body size and maturation in male Japanese flounder Paralichthys olivaceus, and whether spatial variation in the occurrence of mature fish between southern (Fukushima and Miyagi prefectures, 38° N) and northern (Aomori Prefecture, 41° N) waters could be explained by variation in growth rates and somatic body condition. Male flounder in southern and northern waters matured sexually at two years of age; however, the probability of 2-y-old males being mature differed between the two waters. In southern waters, almost all 2-y-old males had mature testes during the spawning season (May–September), whereas the majority of 2-y-old males in northern waters remained immature during the same period. Males in southern waters had grown faster than those in northern waters by summer, two years after birth, but the length range of males in the two regions largely overlapped during the spawning season. The somatic condition of 2-y-old males in June was significantly higher in southern waters than in northern waters, but there was no significant difference in condition between immature and mature specimens in each region. The length-growth increments of 2-y-old males in southern waters during the growing season, just after the spawning season, were similar to those in northern waters. These discrepancies in fish between northern and southern waters did not appear to be explained by the theory of growth and energy allocation strategies. Our findings show that life-history traits of male Japanese flounder may vary on a small geographical scale off the Pacific coast of northern Japan.  相似文献   

15.
The seasonal and interannual changes in surface nutrients, dissolved inorganic carbon (DIC) and total alkalinity (TA) were recorded in the North Pacific (30–54°N) from 1995 to 2001. This study focuses on the region north of the subarctic boundary (∼40°N) where there was extensive monthly coverage of surface properties. The nutrient cycles showed large interannual variations in the eastern and western subarctic gyres. In the Alaska Gyre the seasonal depletion of nitrate (ΔNO3) increased from 8–14 μmol kg−1 in 1995–1999 to 21.5 μmol kg−1 in 2000. In the western subarctic the shifts were similar in amplitude but more frequent. The large ΔNO3 levels were associated with high silicate depletions, indicating enhanced diatom production. The seasonal DIC:NO3 drawdown ratios were elevated in the eastern and central subarctic due to calcification. In the western subarctic and the central Bering Sea calcification was significant only during 1997 and/or 1998, two El Ni?o years. Regional C/N stoichiometric molar ratios of 5.7 to 7.0 (>40°N) were determined based on the years with negligible or no calcification. The annual new production (NPa) based on ΔNO3 and these C/N ratios showed large interannual variations. NPa was usually higher in the western than in the eastern subarctic. However, values of 84 gC m−2yr−1 were found in the Alaska Gyre in 2000 which is similar to that in the most productive provinces of the northern North Pacific. There were also large increases in NPa around the Alaska Peninsula in 1997 and 1998. Finally, the net removal of carbon by the biological pump was estimated as 0.72 Gt C yr−1 in the North Pacific (>30°N). This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

16.
We analyzed the stable nitrogen isotope composition of an extensive set of samples of particulate matter (PM) and seawater nitrate collected during October/November 1997 along the Mexican coastline from 24° to 11.5°N. At the northern and southern end of our study area, the δ15N of PM ranged between 5 and 7‰ in the upper 200 m of the water column with higher values at intermediate depths. These data are very similar to those reported from other parts of the open ocean. In the oxygen minimum zone (OMZ), we found significantly higher δ15N values for suspended particles. Furthermore, the δ15N of nitrate (NO3) was elevated within the OMZ and we found a strong relationship between the oxygen concentration, nitrate deficit and the 15N content of the nitrate. The core of the OMZ between 22°N, 105°W and 15°N, 110°W coincided with higher nitrate deficits and δ15N values relative to the stations near the boundaries. The δ15N of nitrate was highest, with values up to 18.7‰, where oxygen concentrations were below 1–2 μmol/l. This pattern is consistent with an overall nitrogen isotopic enrichment factor of 22.5‰ for denitrification in the core of the OMZ using the Rayleigh equation (closed-system approach). Results from a diffusion model (open-system approach), however, gave a fractionation factor of 30±7.5‰, implying that the Rayleigh formula only gives a lower estimate of the fractionation factor ε. The vertical flux of particles collected in short-term deployments (ca. 35 h) of a drifting sediment trap was not significantly correlated with the water column nitrate deficit. The isotopic signature of the nitrate within the gradient is very similar to the δ15N value of sedimenting particles, suggesting that there might be a strong link between the production and sedimentation of particles. Upward flux of nitrate across the thermocline can account for less than half of the particle flux leaving the mixed layer. Mixing and transport of nitrate across the lower boundary of the OMZ can lead to significant enrichment in the 15N content of deep waters, and our isotopic data imply that at least 14% of the nitrate in the waters below the OMZ originates from this source.  相似文献   

17.
This study quantifies diapycnal mixing and vertical heat transfer in the Pacific side of the Arctic Ocean, where sea-ice cover has disappeared between July and September in the last few decades. We conducted microstructure measurements in the open water region around the Canada Basin from late summer to fall in 2009 and 2010 using R/V Mirai. In the study domain, the dissipation rate of turbulent kinetic energy, ε, is typically as low level as O(10?10) W kg?1, resulting in vertical heat diffusivity of O(10?7) m2 s?1, which is close to the molecular diffusivity of heat, suggesting comparatively little predominance of mechanical turbulent mixing. An exception is the case at the Barrow Canyon, where the strong baroclinic throughflow generates substantial vertical mixing, producing ε > O(10?7) W kg?1, because of the shear flow instability. Meanwhile, in the confluence region, where the warm/salty Pacific water and the cold/fresh Arctic basin water encounter, the micro-temperature profiles revealed a localized enhancement in vertical diffusivity of heat, reaching O(10?5) m2 s?1 or greater. In this region, an intrusion of warm Pacific water creates a horizontally interleaved structure, where the double-diffusive mixing facilitates vertical heat transfer between the intruding Pacific water and the surrounding basin waters.  相似文献   

18.
We have measured helium isotopic ratios of thirty-seven Pacific water samples from various depths collected in adjacent regions of Honshu, Japan. The 3He/4He ratios vary significantly from 0.989 R atm to 1.208 R atm where R atm is the atmospheric ratio of 1.39 × 10−6. The mid-depth (750–1500 m) profile of 3He/4He ratios at ST-1 located Northwestern Pacific Ocean east of Japan (Off Joban; 37°00′ N, 142°40′ E) is significantly different from that at ST-2 of the Northern Philippine Sea south of Japan (Nankai Trough; 33°07′ N, 139°59′ E), suggesting that these waters were separated by a topographic barrier, the Izu-Ogasawara Ridge. Taking 3He/4He data of the Geosecs expeditions in the western North Pacific, an extensive plume of 15% excess 3He relative to the air may be traced at ST-1 over 12,000 kilometers to the northwest of the East Pacific Rise where the mantle helium may originate. The 20% excess found at ST-2 may be attributable to the additional source of the subduction-type mantle helium in the Okinawa Trough. A 15% excess of 3He has also been discovered at a depth of about 1000∼1500 m at ST-3 adjacent to Miyakejima Island (33°57′ N, 139°22′ E) and ST-4 of Sagami Bay (35°00′ N, 139°22′ E). It is confirmed that mid-depth all over the western North Pacific water is affected by the mantle helium with a high 3He/4He ratio. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

19.
The results of determinations of cadmium, copper and lead in western Mediterranean waters collected during the PHYCEMED 81 cruise are discussed in this paper. The analyses were carried out according to two different methods: flameless atomic absorption and anodic stripping voltammetry. Very strict conditions of sampling and treatment were maintained in order to reduce the chance of contamination. The concentrations found are considerably lower than those usually reported for Mediterranean waters. The distributions are homogeneous, both vertically and from one station to another. The average concentrations are 8 ng 1?1 for Cd, 90 ng 1?1 for Cu and 30–40 ng?1 for Pb. This homogeneity, as well as the concentrations of cadmium and lead, may be explained by the hydrological conditions of the Mediterranean Sea.  相似文献   

20.
Stable nitrogen isotopic ratios were measured in sinking particles and surface sediments from the South China Sea (SCS) in order to study recent nitrogen sources and degradation. Average δ15N values of 16 sediment traps deployed at seven locations in the northern, central and southern SCS were uniformly low, ranging between 2.7 and 4.5‰ with a winter minimum in the northern and central SCS. Enhanced nitrogen contents and δ15N values were noted in samples affected by swimmers, comprising between 5 and 20% of total nitrogen fluxes. Nitrate sources were subsurface waters from the western Pacific, which were isotopically depleted due to the remineralization of nitrogen from nitrogen fixation in surface waters. Nitrogen fixation in the SCS contributed up to 20% to the settling particles. In the southern SCS, resuspended matter close to the shelf added to the sinking particulates. The long-term trap record from the central SCS revealed decreasing δ15N values during the 1990s, which correspond with findings from the North Pacific Subtropical Gyre and may be attributable to increased nitrogen fixation due to global warming-related stratification. This trend may be restricted to the 1990s but could also persist due to the projection of more frequent occurrence of El Niño conditions.The δ15N increase from swimmer-free trap averages of 2.7–3.6‰ to values of 5–6‰ in underlying deep-sea sediments was in the same range as in other deep ocean areas. Similar to results from the northern Indian Ocean, this increase could be related to isotopic enrichment during amino acid degradation. The lowest sedimentary δ15N values characterize the Pinatubo ash layer deposited off Luzon in an event of mass sedimentation in 1991. The fast deposition of organic matter drawn from the surface waters with the ash in the form of vertical density currents evidently preserved the planktonic δ15N signal.  相似文献   

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