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1.
A critical analysis of CH, NH, OH, C2, and CN molecules/radicals has been made in twenty-four F- and early G-type dwarfs at different effective temperature as well as in new constructed model atmosphere. Molecular indices of bandheads ofA-X system of CH, NH, OH, C2, and CN have been obtained by using the data available in the literature (thirteen-colour and eight-colour photometry).Besides, some interesting plots of the molecular indices vs eff, molecular abundances and molecular indices vs dissociation energy, reduced equivalent widths and FCF's vs dissociation energy for respective molecules have also been enumerated. It is found that the molecular indices at bandheads ofA-X system of CH, NH, OH, C2, and CN are approximately constant (5810–6570 K). It is to be noted that the molecular indices decrease in the order OH, NH, CH, C2, and CN at a given temperature.The dissociation equilibrium of CH, NH, OH, C2, and CN is considered at 5810, 6570, and 7160 K phases in model atmosphere. At standard scale of abundance the molecular abundance and molecular index decrease in the order OH, NH, CH, C2, and CN at any given phase, however, CN abundance and index increase (eff=0.867-0.767). The amplitude of abundance and index variation decrease in the order NH, OH, CH, C2, and CN (eff=0.767-0.704).The reduced equivalent width decrease in the order OH, NH, CH, and C2 and FCF's decrease in the order CH, OH, NH, CN, and C2.The confrontation of models and observations of spectra of F- and early G-type dwarfs of parent molecules is of primary importance to investigate the physical conditions within atmospheres. Reliable excitation models are also requisite for interpreting spectroscopic observations of parent molecules and deriving molecular abundances.  相似文献   

2.
The contribution of exothermic ion and neutral chemistry to Titan's corona is studied. The production rates for fast neutrals N2, CH4, H, H2, 3CH2, CH3, C2H4, C2H5, C2H6, N(4S), NH, and HCN are determined using a coupled ion and neutral model of Titan's upper atmosphere. After production, the formation of the suprathermal particles is modeled using a two-stream simulation, as they travel simultaneously through a thermal mixture of N2, CH4, and H2. The resulting suprathermal fluxes, hot density profiles, and energy distributions are compared to the N2 and CH4 INMS exospheric data presented in [De La Haye, V., Waite Jr., J.H., Johnson, R.E., Yelle, R.V., Cravens, T.E., Luhmann, J.G., Kasprzak, W.T., Gell, D.A., Magee, B., Leblanc, F., Michael, M., Jurac, S., Robertson, I.P., 2007. J. Geophys. Res., doi:10.1029/2006JA012222, in press], and are found insufficient for producing the suprathermal populations measured. Global losses of nitrogen atoms and carbon atoms in all forms due to exothermic chemistry are estimated to be and .  相似文献   

3.
Spectral scans of the head of periodic Comet Halley (1982i) have been presented in the optical region (3200–7000 Å) for six nights. Emission features due to NH, CN, CH, C3, C2 and NH2 molecules have been identified. It is found that the comet exhibits night-to-night variation of emission bands. The abundances and production rates of CN and C2 species have been derived.  相似文献   

4.
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5.
The H2CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH2O)n, also called POM) into gaseous H2CO. POM decomposition can indeed explain the H2CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H2CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.  相似文献   

6.
Spectral scans of the head of periodic Comet Halley (1982i) have been presented and analysed in detail in the optical region (3200–7000 Å); for ten nights during pre-perihelion period. Emission features due to NH, CN, CH, C3, and C2 molecules have been identified. The behaviour of the variation of different emission lines strength as a function of heliocentric distance has been investigated. It is found that the comet exhibits night-to-night variation of brightness. The abundances and production rates of CN and C2 species have also been derived.  相似文献   

7.
O. Gomis  G. Strazzulla 《Icarus》2005,177(2):570-576
In this work we report on new experiments of ion irradiation of water ice deposited on top of solid carbonaceous materials to study the production of CO2 at the interface ice/refractory material and discuss the possibility that this mechanism accounts for the quantity of CO2 ice detected on the surfaces of the Galilean satellites. The used experimental technique has been in situ infrared spectroscopy. We have irradiated thin films of H2O frost on carbonaceous layers with 200 keV of He+ and Ar+, and 30 keV of He+ at 16 and 80 K. The used carbonaceous layers have been asphaltite, a natural bitumen, and solid organic residues obtained by irradiation of frozen benzene. In both cases the results show that CO2 is produced very efficiently after irradiation obtaining a maximum quantity of the order of . These results are, also quantitatively similar, to those recently obtained for water ice deposited on amorphous carbon films [Mennella, V., Palumbo, M.E., Baratta, G.A., 2004. Formation of CO and CO2 molecules by ion irradiation of water ice covered hydrogenated carbon grains. Astrophys. J. 615, 1073-1080]. Thus we suggest that, whatever is the carbonaceous residue, CO2 will be produced efficiently by the studied process. These results have interest in the context of the surfaces of the icy Galilean satellites in which CO2 has been detected mainly trapped in the non-ice material, not in the pure water ice. We suggest that radiolysis of mixtures of water ice and refractory carbonaceous materials is the primary formation mechanism responsible for the CO2 formation on the surfaces of the Galilean satellites.  相似文献   

8.
Powdered samples of carbon-nitrogen-hydrogen “tholins” that mimic Titan's atmosphere aerosols were produced under levitation conditions in the laboratory with a dusty plasma (PAMPRE experiment) using different initial N2:CH4 gas mixtures and studied using UV Raman and infrared spectroscopy, X-ray diffraction and high resolution transmission electron microscopy (HRTEM). Comparison between the tholins produced in the PAMPRE experiments and samples prepared by other techniques reveal that they form a fairly homogeneous family of hydrogenated carbon nitride materials. Wall effects during the PAMPRE deposition experiments and other were found to have little effect on the chemical structure of tholins. The first-order UV Raman bands of the disordered carbonaceous materials point to a large contribution of sp2 clusters present compared with olefinic CN or CC groupings, whereas features at 690 and 980 cm−1 suggest C3N3 rings are present as a species inserted in the macromolecular network. Diffraction techniques do not indicate the presence of large polyaromatic species in any of the tholins studied, whatever their nitrogen concentration, in disagreement with certain previous observations. This precludes the idea that the nature and degree of absorption in the visible range is controlled by the size of polyaromatic species, as has been observed in series of carbon-based materials obtained via thermal processing. Infrared spectroscopy analysis of the tholins has confirmed earlier identifications of chemical groups present including primary amines, nitriles, and alkyl moieties such as CH2/CH3, but has ruled out CH2/CH3 branches appearing on secondary or tertiary amines. Similar analyses were also performed on a polymeric (HCN)x material, which was found to present several similarities with the tholins, hence suggesting similar polymerization processes.  相似文献   

9.
David E. Woon  Jin-Young Park 《Icarus》2009,202(2):642-680
Barrierless reactions between unsaturated hydrocarbons and the ethynyl radical (C2H) can contribute to the growth of organic particulates in the haze-forming regions of Titan's atmosphere as well as in the gas giants and in the interstellar medium. We employed a combination of quantum chemistry and statistical rate theories to characterize reactions between ground state C2H and seven alkenes of the general structure R1R2C′C″R3R4 containing up to six carbons. The alkenes included ethene (C2H4); propene (C3H6); 1-butene, 2-butene, and isobutene (C4H8); trimethylethene (C5H10); and tetramethylethene (C6H12). Density functional theory calculations at the B3LYP/6-31 + G∗∗ level were used to characterize the adducts, isomers, products, and the intervening transition states for the addition-elimination reactions of all seven species. A multiple-well treatment was then employed to determine the outcome distributions for the range of temperatures and pressures relevant to Titan's atmosphere, the interstellar medium, and the outer atmospheres of the gas giants. Finally, trajectory calculations using an ROMP2 potential energy surface were used to calculate kinetic rates for the ethene + C2H reaction, where the agreement between the computed and measured values is very good. At low pressure and temperature, vinyl acetylene is a dominant product of several of the reactions, and all of the reactions yield at least one dominant product with both a double and a triple CC bond.  相似文献   

10.
The goal of this study was to explore prebiotic chemistry in a range of plausible early Earth and Mars atmospheres. To achieve this laboratory continuous flow plasma irradiation experiments were performed on N2/H2/CO/CO2 gas mixtures chosen to represent mildly reducing early Earth and Mars atmospheres derived from a secondary volcanic outgassing of volatiles in chemical equilibrium with magmas near present day oxidation state. Under mildly reducing conditions (91.79% N2, 5.89% H2, 2.21% CO, and 0.11% CO2), simple nitriles are produced in the gas phase with yield (G in molecules per 100 eV), for the key prebiotic marker molecule HCN at G∼1×10−3 (0.1 nmol J−1). In this atmosphere localized HCN concentrations possibly could approach the 10−2 M needed for HCN oligomerization. Yields under mildly oxidizing conditions (45.5% N2, 0.1% H2, 27.2% CO, 27.2% CO2) are significantly less as expected, with HCN at G∼3×10−5 (). Yields in a Triton atmosphere which can be plausibly extrapolated to represent what might be produced in trace CH4 conditions (99.9% N2, 0.1% CH4) are significant with HCN at G∼1×10−2 (1 nmol J−1) and tholins produced. Recently higher methane abundance atmospheres have been examined for their greenhouse warming potential, and higher abundance hydrogen atmospheres have been proposed based on a low early Earth exosphere temperature. A reducing (64.04% N2, 28.8% H2, 3.60% CO2, and 3.56% CH4), representing a high CH4 and H2 abundance early Earth atmosphere had HCN yields of G∼5×10−3 (0.5 nmol J−1). Tholins generated in high methane hydrogen gas mixtures is much less than in a similar mixture without hydrogen. The same mixture with the oxidizing component CO2 removed (66.43% N2, 29.88% H2, 0% CO2, and 3.69% CH4) had HCN yields of G∼1×10−3 (0.1 nmol J−1) but more significant tholin yields.  相似文献   

11.
Assuming local thermodynamic equilibrium and the same relative abundances to prevail both in photosphere and faculae, the concentration-optical depth curves for molecules CH, NH, OH, C2, CN and CO have been obtained for the four combinations of two photospheric and two facular models and the relative excesses of these molecules in the photosphere over those in faculae have been calculated. The change of photospheric model significantly affects the relationship, for a given facular model, between and D 0, the dissociation energy of the molecule concerned. Besides, the average depth of formation in the facular models and photospheric models shows a relationship with D 0.  相似文献   

12.
Ethanimine (CH3CHNH) is an important prebiotic molecule since it is a precursor of amino acid \(\alpha \)-alanine in Strecker synthesis. Two isomers (E and Z) of ethanimine were detected in the molecular cloud Sagittarius B2 north during GBT-PRIMOS survey. A possible radical-molecule reaction pathway has been proposed for the formation of ethanimine in the interstellar medium (ISM) from some previously detected interstellar molecules like methylene (both triplet CH2 (3B1) and singlet CH2 (1A1)) and methyenimine (CH2NH). The mechanism has been studied in the gas phase and in water ice with the help of density functional theory at B2PLYPD/6-311++G (2d, p) level of theory. It is observed that E-ethanimine forms efficiently in gas phase but ice reactions are favorable only in the hot core of molecular clouds. Same is true for the formation of Z-ethanimine which forms only at the surface of water cluster as the height of entrance barrier for formation of Z-ethanimine is similar to that of E-ethanimine. Isomerization from E to Z form is also studied and found to be forbidden due to large entrance barrier. Out of the two reaction system CH2 (3B1) + CH2NH and CH2 (1A1) + CH2NH, later is more favorable then the former one due to the small entrance barrier. Still, much of the detected abundance of ethanimine comes from the reaction of CH2 (3B1) with CH2NH as since CH2 (1A1) has very low abundance compared to the CH2 (3B1) in ISM. The proposed pathway seems to be a promising candidate for the ethanimine formation in ISM.  相似文献   

13.
The reaction kinetics of the butadinyl radical, C4H, with various hydrocarbons detected in the atmosphere of Titan (methane, ethane, propane, acetylene, ethene and methylacetylene) are studied over the temperature range of 39-298 K using the Rennes CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme) apparatus. Kinetic measurements were made using the pulsed laser photolysis—laser induced fluorescence technique. The rate coefficients, except for the reaction with methane, all show a negative temperature dependence and can be fitted with the following expressions over the temperature range of this study: ; ; , , . These expressions are not intended to be physically meaningful but rather to provide an easy way to introduce experimental results in photochemical models. They are only valid over the temperature range of the experiments. Possible channels of these reactions are discussed as well as possible consequences of these results for the production of large molecules and hazes in the atmosphere of Titan. These results should also be considered for the photochemistry of Giant Planets.  相似文献   

14.
Material of low geometric albedo (pV?0.1) is found on many objects in the outer Solar System, but its distribution in the saturnian satellite system is of special interest because of its juxtaposition with high-albedo ice. In the absence of clear, diagnostic spectral features, the composition of this low-albedo (or “dark”) material is generally inferred to be carbon-rich, but the form(s) of the carbon is unknown. Near-infrared spectra of the low-albedo hemisphere of Saturn's satellite Iapetus were obtained with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft at the fly-by of that satellite of 31 December 2004, yielding a maximum spatial resolution on the satellite's surface of ∼65 km. The spectral region 3-3.6 μm reveals a broad absorption band, centered at 3.29 μm, and concentrated in a region comprising about 15% of the low-albedo surface area. This is identified as the CH stretching mode vibration in polycyclic aromatic hydrocarbon (PAH) molecules. Two weaker bands attributed to CH2 stretching modes in aliphatic hydrocarbons are found in association with the aromatic band. The bands most likely arise from aromatic and aliphatic units in complex macromolecular carbonaceous material with a kerogen- or coal-like structure, similar to that in carbonaceous meteorites. VIMS spectra of Phoebe, encountered by Cassini on 11 June 2004, also show the aromatic hydrocarbon band, although somewhat weaker than on Iapetus. The origin of the PAH molecular material on these two satellites is unknown, but PAHs are found in carbonaceous meteorites, cometary dust particles, circumstellar dust, and interstellar dust.  相似文献   

15.
Twenty-seven typical binary systems have been investigated to study their power-output by gravitational radiation (P B ) and spiralling time (0) relation. It was found that these binary systems form two distinct groups. New relations have been given betweenP B and 0 for each group.  相似文献   

16.
A spectroscopic investigation of a quiescent prominence has been performed: the line profiles of the H and K lines have been carefully determined in all regions of the prominence where these emissions are likely to originate in optically thin layers. Therefore we have been able to study the electron temperature T e and the microturbulent velocity in the outer parts of the prominence. We find that on the average, T e = 5700 K (Figure 1) and = 6.7 km s-1 (Figure 2) which are in very good agreement with classical data. Figure 3 represents the radial velocity measurements and Figure 4 the ratio of the total intensity of H to K lines. Thus the prominence we have observed does not show for T e and the regular increase outward which has been described by Hirayama (1971). On the other hand increases towards the Equator, in the dynamically active part of the prominence, which could indicate that represents the effect of macroturbulence rather than microturbulence (Kawaguchi, 1966). In this part of the prominence only the K line is in emission and the average value of the microturbulence is 9.4 km s-1, the radial velocity is also generally increasing. At last, according to the absolute intensities of the H and K lines, the electron density in the outer layers of the prominence is no more than 1 × 1010 cm-3.  相似文献   

17.
The Large Angle Spectroscopic Coronagraph (LASCO)   总被引：12，自引：0，他引：12  
The Large Angle Spectroscopic Coronagraph (LASCO) is a three coronagraph package which has been jointly developed for the Solar and Heliospheric Observatory (SOHO) mission by the Naval Research Laboratory (USA), the Laboratoire d'Astronomie Spatiale (France), the Max-Planck-Institut für Aeronomie (Germany), and the University of Birmingham (UK). LASCO comprises three coronagraphs, C1, C2, and C3, that together image the solar corona from 1.1 to 30 R (C1: 1.1 – 3 R, C2: 1.5 – 6 R, and C3: 3.7 – 30 R). The C1 coronagraph is a newly developed mirror version of the classic internally-occulted Lyot coronagraph, while the C2 and C3 coronagraphs are externally occulted instruments. High-resolution imaging spectroscopy of the corona from 1.1 to 3 R can be performed with the Fabry-Perot interferometer in C1. High-volume memories and a high-speed microprocessor enable extensive on-board image processing. Image compression by a factor of about 10 will result in the transmission of 10 full images per hour.  相似文献   

18.
In this paper independent evidence in favour of the hypothesis proposed by Thakur and Sapre (1979) that a QSO consists of a bright central object embedded in an extended nebulosity has been presented. U–B and B–V , the spectral indices in (U-B) and (B-V) colours, have been calculated for a sample of 80 QSOs with redshiftz0.76. In Figure 1 = ( B–V – U–V ) has been plotted against = ( B–V + U–B )/2. In this figure the QSOs in which detectability of neubulosities has been predicted by Thakur and Sapre (1979) occupy a separate but adjacent part of the diagram as compared to those for which such a prediction has not been made. In Figure 2 (U-B)0 has been plotted against (B-V)0 for the same sample of 80 QSOs, where (U-B)0 and (B-V)0 are the (U-B) and (B-V) colours corrected for galactic extinction. In this plot also, a similar separation of the two classes of objects is discernible. Another empirical criterion—namely, (B-V)00.32 for the detectability of nebulosities around QSOs—has been suggested.  相似文献   

19.
Binary systems with their primary and secondary component masses less than 2M have been investigated to evaluate the rate of emission of gravitational energy (P B) and spiralling time (0) for them. In all twenty-two binary systems have been considered. It is found that in spite of the same mass range, these systems form two distinct groups. New relations have been given betweenP B and (0) for each group. For a few eccentric orbit systems the rate of decay of orbital periods due to the loss of energy from the system via gravitational radiation emission has also been given and compared with a short-period binary pulsar.  相似文献   

20.
Eselevich  V.G.  Fainshtein  V.G.  Eselevich  M.V. 《Solar physics》2001,200(1-2):259-281
A technique is proposed for separating the rays of the streamer belt with quasi-stationary and non-stationary solar wind (SW) flows. It is shown that the lifetime of rays with a quasi-stationary SW can exceed 20 days. A new method has been developed for measuring the relative density distribution of a quasi-stationary slow SW flowing along the streamer belt's ray of increased brightness, based on the LASCO/SOHO data. It is shown that the density n for such SW flows varies with the radius R according to the relationship nR –, where =13.3–3.9 within 4 R 0 R 6 R 0 (here R 0 is the solar radius), and decreases gradually further away. It is also shown that the V(R)-profiles in some rays of the streamer belt differ little from each other, although the value of the mass flow density, j E, at the Earth's orbit in them can vary more than by a factor of 4. This distinguishes in a crucial respect a slow SW in the streamer belt's rays from a fast SW originating in coronal holes, for which j Econstant and the dependences V(R) in different fast flows can differ greatly.  相似文献   

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