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1.
We simulated geostationary satellite observations to assess the potential for high spatial-and temporal-resolution monitoring of air pollution in China with a focus on tropospheric ozone(O_3), nitrogen dioxide(NO_2), sulfur dioxide(SO_2), and formaldehyde(HCHO). Based on the capabilities and parameters of the payloads onboard sun-synchronous satellites, we simulated the observed spectrum based on a radiative transfer model using a geostationary satellite model. According to optimal estimation theory, we analyzed the sensitivities and retrieval uncertainties of the main parameters of the instrument for the target trace gases. Considering the retrieval error requirements of each trace gas, we determined the major instrument parameter values(e.g., observation channel, spectral resolution, and signal-to-noise ratio). To evaluate these values, retrieval simulation was performed based on the three-dimensional distribution of the atmospheric components over China using an atmospheric chemical transportation model. As many as 90% of the experiments met the retrieval requirements for all target gases. The retrieval precision of total-column and stratospheric O_3 was 2%. In addition, effective retrieval of all trace gases could be achieved at solar zenith angles larger than 70°. Therefore, the geostationary satellite observation and instrument parameters provided herein can be used in air pollution monitoring in China. This study offers a theoretical basis and simulation tool for improving the design of instruments onboard geostationary satellites.  相似文献   

2.
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3.
Three carbonate ocelli-bearing lamprophyre dykes have been found in the Laowangzhai and Beiya gold orefields in the northern sector of the Ailaoshan gold deposit zone, Yunnan Province. Ocelli in the lamprophyre dykes are carbonates composed mainly of dolomite and calcite. Their trace elements, REE and C isotopic compositions are characteristic of carbonatite and the main mineral assemblages, major elements, trace elements and REE in the matrix are similar to those in the carbonate ocelli-barren lamprophyre dykes in the orefields, which are calc-alkaline lamprophyres that derived from the fertile mantle. The results indicate that the carbonate ocelli-bearing lamprophyre dykes in this area were produced at the time when the Himalayan lamprophyre magma evolved to a relatively late stage of silicate-carbonate liquid immiscibility. In the process of magmatic evolution there took place magmatic degassing with CO2 and H2O as the dominant released gases.  相似文献   

4.
In the process of methane oxidation by nitrite ion, the latter, when in high concentration, inhibits the oxidation process. The effect of inhibition is incorporated in the proposed model, describing the dynamics of anaerobic oxidation of methane and its heavy fractions δ13CH4 and δC2H1H3 by nitrite ion. Two substrates—methane and nitrite—are considered in a modified Monod function, describing the oxidation rate. The model is calibrated against experimental data given in [8]. The dynamic behavior of the system under a deficiency of methane or nitrite ion is described. The dynamics of δ13CH4 and δC2H1H3 are shown to be governed by the oxidation dynamics of total methane CH4. By contrast to the conventional opinion that Rayleigh equation corresponds to 1st-order kinetics in terms of substrate concentration, this study shows that Rayleigh equation can be derived from dynamic equations for methane with heavy isotopes (13C and 2H), whatever the kinetic type of total methane oxidation.  相似文献   

5.
It is now well known that there is a substantial outflow of ionospheric plasma from the terrestrial ionosphere at high latitudes. The outflow consists of light thermal ions (H+, He+) as well as both light and heavy energized ions (H+, He+, O+, N+, NO+, O2+, N2+). The thermal ion outflows tend to be associated with the classical polar wind, while the energized ions are probably associated with either auroral energization processes or nonclassical polar wind processes. Part of the problem with identifying the exact cause of a given outflow relates to the fact that the ionosphere continuously convects into and out of the various high-latitude regions (sunlight, cusp, polar cap, nocturnal oval) and the time-constant for outflow is comparable to the convection time. Therefore, it is difficult to separate and quantify the possible outflow mechanisms. Some of these mechanisms are as follows. In sunlit regions, the photoelectrons can heat the thermal electrons and the elevated electron temperature acts to increase the polar wind outflow rate. At high altitudes, the escaping photoelectrons can also accelerate the polar wind as they drag the thermal ions with them. In the cusp and auroral oval, the precipitating magnetospheric electrons can heat the thermal electrons in a manner similar to the photoelectrons. Also, energized ions, in the form of beams and conics, can be created in association with field-aligned auroral currents and potential structures. The cusp ion beams and conics that have been convected into the polar cap can destabilize the polar wind when they pass through it at high altitudes, thereby transferring energy to the thermal ions. Additional energization mechanisms in the polar cap include Joule heating, hot magnetospheric electrons and ions, electromagnetic wave turbulence, and centrifugal acceleration.Some of these causes of ionospheric outflow will be briefly reviewed, with the emphasis on the recent simulations of polar wind dynamics in convecting flux tubes of plasma.  相似文献   

6.
阿尔金断裂东北段断层气体的初步研究   总被引：2，自引：0，他引：2       下载免费PDF全文
本文通过对西起安南坝,东至昌马车路口的阿尔金断裂东北段断层气体的分析,讨论了微量气体H_2、Hg、Rn、CO_2在断层上的分布特征。指出,在同一剖面上,四种气体浓度不仅对断层有同步显示规律,而且与断层的活动强度有一定的关系。另外,分析结果还显示了H_2、Hg、Rn、CO_2的浓度有西高东低的趋势。这一特征还与地质资料所表明的阿尔金山断裂东北段西部的现今活动比东部的现今活动较强的事实相吻合。文章还讨论了用对断层气体进行定点、定期观测的结果来判断断层的活动动态及进行地震短临预报的可能性。最后指出,利用断层气体来研究活动断层是一种切实可行的方法。  相似文献   

7.
He, Ne, and Ar have been measured in seven iron meteorites for which anomalous Ag isotopic compositions were reported, in order to determine if107Ag excesses could be related to galactic cosmic-ray bombardment of these meteorites. Our results show that no correlation exists between107Ag excess and either the fluence or the energy spectrum of the particles producing spallogenic rare gases. Cosmic-ray-produced107Ag estimated from38Ar concentrations can account for only about 1% of the observed excess. Elimination of cosmic-ray bombardment as a production mechanism for107Ag excess strengthens the conclusion that the excess107Ag is the decay product of short-lived107Pd (τ1/2=6.5Myr). The iron meteorite Pin?on is shown to contain trapped rare gases with4He/20Ne～600.  相似文献   

8.
Discharge from subaereal and submarine gas vents of the Baia di Levante beach gases from the Vulcano Island were sampled for major and trace gas components in May and November 1995.Chemical compositions and equilibrium calculations suggest three different groups of CO2-rich gas emissions depending on their distance from the La Fossa crater: (1) gas vents close to the Faraglione area are characterised by high H2S contents, high calculated equilibrium temperatures based on inorganic species and relatively high proportion of alkene compounds; (2) gas vents close to Vulcanello are characterised by low calculated equilibrium temperatures and low amounts of alkenes; and (3) Pontile sample has the highest equilibrium CO2 pressure (up to 68 bars) which may account for the observed absence of benzene. The relative large variability of H2S in the Baia di Levante beach gas discharge may be attributed to either different interactions between iron sulphides and weakly acid waters or catalytic effect of elemental sulphur on the de-hydrogenation of cyclo-hexane. Thermodynamic calculations suggest that the main inorganic species and CH4 may have re-equilibrated at relatively shallow depth (10–200 m b.s.l. and 30–600 m b.s.l. for a lithostatic and hydrostatic pressure, respectively). The slow kinetics of reactions in the CnH2n/CnH2n+2 systems, with respect to that of CH4–CO–CO2, may explain the observed propene/propane ratios, which can only be reached at reaction temperatures of 300–350°C. This low speed of reactions can also explain the observed disequilibrium of C1–C4 alkanes.  相似文献   

9.
通过甘东南地震危险区地震宏观异常观测实例分析,系统研究CO_2气体在地震构造活动过程中的地球化学演化过程,以及发生的一系列酸碱平衡和氧化还原化学反应。结果表明地下深部CO_2气体不仅是其他微量气体Rn等向地表方向运移的载体,而且参与酸碱平衡和氧化还原反应,是地下深部生物化学反应的重要影响条件,地震前兆及宏观异常现象的发生常伴随着CO_2的异常变化。因此CO_2气体可以作为良好的示踪气体,在地震前兆观测及重大异常落实中尤其要重视对其进行监测。  相似文献   

10.
Three techniques for obtaining soil water solutions (gravitational and matrical waters extracted using both in situ tension lysimeters and in vitro pressure chambers) and their later chemical analysis were performed in order to know the evolution of the soil‐solution composition when water moves down through the soil, from the Ah soil horizon to the BwC‐ or C‐horizons of forest soils located in western Spain. Additionally, ion concentrations and water volumes of input waters to soil (canopy washout) and exported waters (drainage solutions from C‐horizons) were determined to establish the net balance of solutes in order to determine the rates of leaching or retention of ions. A generalized process of sorption or retention of most components (even Cl?) was observed, from the soil surface to the C‐horizon, in both gravitational and matrical waters, with H4SiO4, Mn2+, Na+, and SO42? being the net exported components from the soil through the groundwater. These results enhance the role of the recycling effect in these forest soils. The net percentages of elements retained in these forest soils, considering the inputs and the outputs balance, were 68% K+, 85% Ca2+, 58% Mg2+, 7% Al3+, 5% Fe3+, 34% Zn2+, 57% Cl?, and 20% NO3?, and about 75% of dissolved organic carbon was mineralized. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

11.
Ion composition measurements on board the ACTIVE satellite during the recovery phase of a strong geomagnetic storm of 10–12 April 1990 revealed extremely high concentrations (up to 103 cm−3) of the NO+, O+2, N+2 molecular ions in the topside F2-region of the European high-latitude zone. Concentrations of O+, N+, He+, H+ light ions were slightly decreased relative to prestorm quite conditions. Theoretical calculations were used to analyze the observed variations in ion concentration. Increased neutral temperature and [O2], [N2] are shown to be the main reasons for the observed ion concentration variations.  相似文献   

12.
The isotopic composition and abundances of He, Ne and Ar have been measured in a sequence of vertically stacked gas reservoirs at Hajduszoboszlo and Ebes, in the Pannonian Basin of Hungary. The gas reservoirs occur at depths ranging from 727 to 1331 m, are CH4 dominated and occupy a total rock volume of approximately 1.5 km3. There are systematic variations in both major species abundances and rare gas isotopic composition with depth: CO2 and N2 both increase from 0.47 and 1.76% to 14.1 and 30.5%, respectively, and 40Ar/36Ar and 21Ne/22Ne increase systematically from 340 and 0.02990 at 727 m to 1680 and 0.04290 at 1331 m. A mantle-derived He component between 2 and 5% is present in all samples, the remainder is crustal-radiogenic He. The Ar and Ne isotope variations arise from mixing between atmosphere-derived components in groundwater, and crustally produced radiogenic Ar and Ne. The atmosphere-derived 40Ar and 21Ne decreases from 85 and 97% of the total 40Ar and 21Ne at 727 m to 18 and 68% at 1331 m. The deepest samples are shown to have both atmosphere-derived and radiogenic components close to the air-saturated water and radiogenic production ratios. The shallowest samples show significant fractionation of He/Ar and Ne/Ar ratios in atmosphere-derived and radiogenic rare gas components, but little or no fractionation of He/Ne ratios. This suggests that diffusive fractionation of rare gases is relatively unimportant and that rare gas solubility partitioning between CH4 and H2O phases controls the observed rare gas elemental abundances.The total abundance of atmosphere-derived and radiogenic rare gas components in the Hajduszoboszlo gas field place limits on the minimum volume of groundwater that has interacted with the natural gas, and the amount of crust that has degassed and supplied radiogenic rare gases. The radiogenic mass balance cannot be accounted for by steady state production either within the basin sediments or the basement complex since basin formation. The results require that radiogenic rare gases are stored at their production ratios on a regional scale and transported to the near surface with minimal fractionation. The minimum volume of groundwater required to supply the atmosphere-derived rare gases would occupy a rock volume of some 1000 km3 (assuming an average basin porosity of 5%), a factor of 670 greater than the reservoir volume. Interactions between groundwater and the Hajduszoboszlo hydrocarbons has been on a greater scale than often envisaged in models of hydrocarbon formation and migration.  相似文献   

13.
Imaging Differential Optical Absorption Spectroscopy (IDOAS) is an optical remote-sensing method using scattered sunlight as light source. It combines a “pushbroom” imaging spectrometer with the DOAS technique and thus allows imaging two-dimensional trace gas distributions, e.g., in volcanic plumes. The highly sensitive and specific detection of many trace gases simultaneously (specific molecules, not just elements, e.g. SO2, BrO, NO2, O3, HCHO, etc.) is possible, and the temporal and spatial variation of these gases can be measured. The IDOAS system presented here enables the taking of two-dimensional images of trace gas distributions in a volcanic plume with a spatial resolution of 100 pixels horizontally × 64 pixels vertically, each with a field of view of 0.087° in horizontal and 0.208° in vertical directions. Therefore, IDOAS provides useful information about the chemical composition and chemical variability in a volcanic plume and allows studying plume dispersal and chemical transformations. The technique was applied to map the SO2 distribution in the plume of Mt. Etna volcano for the first time in October 2003.  相似文献   

14.
The migration mechanisms of endogenous gases in the geosphere are defined in relation to the fluid-rock conditions and analyzed by basic transport equations. Upon examining the geological factors that influence the physical parameters in the equations in porous and fracture media, and considering the widespread high-permeability of deep subsurface rocks, in terms of fracture aperture, (orders of 10−2 to 101 mm at depths of thousands meters, as suggested by recent crustal surveys) advection of carrier gases, in its several forms (gas-phase flow, water displacement by gas, gas slugs and bubbles) seems to represent a major migration process. Accordingly, in contrast with early views, the role of gas diffusion and water advection in the transport of endogenous gas to the Earth surface should be strongly minimized in many contexts. In a wide range of geological settings, carrier gases (CO2, CH4) may assume a dominant role in controlling transport and redistribution toward the Earth’s surface of trace gases (Rn, He). Bubble movement in fissured rocks seems to be an effective way of rapid (gas velocities in the order of 100 to 103 m per day) and long-distance gas migration. The evolution from bubble regimes to continuous phase flow and vice versa, as gas pressure and fracture width change, is the most suitable mechanism towards determining the surface geochemical processes of seismo-tectonic, environmental and geo-exploration relevance. The transport effectiveness of trace gases by a carrier gas has yet to be studied in quantitative terms. It is already clear, however, that further studies on the distribution and behavior of trace gases approaching the Earth’s surface may not be meaningful unless accompanied by carrier gas dynamics analyses.  相似文献   

15.
Gas samples were collected by aircraft entering volcanic eruption clouds of three Guatemalan volcanoes. Gas chromatographic analyses show higher H2 and S gas contents in ash eruption clouds and lower H2 and S gases in vaporous gas plumes. H isotopic data demonstrate lighter isotopic distribution of water vapor in ash eruption clouds than in vaporous gas plumes. Most of the H2O in the vaporous plumes is probably meteoric. The data are the first direct gas analyses of explosive eruptive clouds, and demonstrate that, in spite of atmospheric admixture, useful compositional information on eruptive gases can be obtained using aircraft.  相似文献   

16.
Low-mature gases and typical low-mature gas fields in China   总被引：2，自引：0，他引：2  
No natural gas pool of industrial importance could be formed at the low-evolution stage of organic matter. In the 1980s, on the basis of the development in exploration practice, the hypotheses of bio-thermo-catalytic transitional zone gases and early thermogenic gases were proposed. The lower-limit Ro values for the formation and accumulation of natural gases of industrial importance have been expanded to 0.3%―0.4%. In the light of the two-stage model established on the basis of carbon isotope fractionation in coal-type natural gases, the upper-limit Ro values have been set at 0.8%―1.0%. In terms of the geological practice in the low-mature gas zones and China's main coal-type gas fields, it is feasible and proper to set the upper-limit Ro value of low-mature gases at 0.8%. Supper-large gas fields such as the Urengoy gas field in western Siberian Basin should belong to low-mature gas fields, of which the natural gas reserves account for more than 20% of the global proven reserves, providing strong evidence for the significance of such a type of resources. The proven natural gas reserves in the Turpan-Hami Basin of China have almost reached 1000 × 108 m3. The main source rocks in this area are the Jurassic Xishanyao Formation, which occurs as a suite of coal series strata. The corresponding thermal evolution indices (Ro ) are mainly within the range of about 0.4%―0.8%, the δ 13C1 values of methane vary between-44‰ and-39‰ (correspondingly Ro =0.6%―0.8%), and those of ethane are within the range of-29‰―-26‰, indicating that natural gases in the Turpan-Hami Basin should be designated to coal-type low-mature gases. The light hydrocarbon evolution indices of natural gases also fall within the area of low evolution while the precursor type of light hydrocarbons also shows the characteristics of the coal-type. The geological background, carbon isotopic composition and light hydrocarbon index all provide strong evidence suggesting that the proven natural gases in the Turpan-Hami Basin are low-mature gases. In China a gas field with the gas reserves reaching 300 ×108 m3 can be defined as a large gas field, and thus the proven low-mature gases in the Turpan-Hami Basin are equivalent to the reserves of three large gas fields. Its existence is of great significance in research on and exploration of low-mature gases in China.  相似文献   

17.
Gases trapped in lavas of three main flows of the Ardoukôba eruption (8 to 15 November, 1978) have been analysed by mass spectrometry. These analyses concern both plagioclase phenocrysts and microcrystalline mesostasis. Fluids are released between 500°C and 1200°C, and consist of H2O, CO2, CO, N2, SO2, HCl, H2, CH4 with traces of hydrocarbons and H2S. The total content is less than 0.3–0.4 wt. % of samples with about 0.1–0.15 wt % of H2O. No significant variation among the three flows is observed. Plagioclase phenocrysts are less abundant in fluids than the mesostasis (～2/3). The gases trapped in these phenocrysts are richer in CO and organic compounds, whereas mesostasis contain more H2O, CO2 and SO2. CO is likely produced by reduction of CO2 and H2O with carbon during either analyses or eruption itself, or is of primary origin. In the latter case, gas composition suggests an entrapment temperature of about 1200°C ± 75°C. Kinetic study of the water and carbon dioxide release allows to calculate the diffusion characteristics of these fluids. Water and carbon dioxide behave rather similarly. Plagioclase gives a single activation energy value (8 Kcal/mole), while mesostasis gives two values (8 Kcal/mole, 15 Kcal/mole). Diffusion coefficients at 20°C are estimated to fall in the range 10?13 · 10?12 cm2 · sec?1.  相似文献   

18.
This study compares the OV1-10 satellite measurements of the integral airglow intensities at 630 nm in the SAR arc regions observed in the northern and southern hemisphere as a conjugate phenomenon, with the model results obtained using the time-dependent one-dimensional mathematical model of the Earth ionosphere and plasmasphere (the IZMIRAN model) during the geomagnetic storm of the period 15–17 February 1967. The major enhancements to the IZMIRAN model developed in this study are the inclusion of He+ ions (three major ions: O+ H+ and He+ and three ion temperatures), the updated photochemistry and energy balance equations for ions and electrons, the diffusion of NO+ and O+2 ions and O(1D) and the revised electron cooling rates arising from their collisions with unexcited N2, O2 molecules and N2 molecules at the first vibrational level. The updated model includes the option to use the models of the Boltzmann or non-Boltzmann distributions of vibrationally excited molecular nitrogen. Deviations from the Boltzmann distribution for the first five vibrational levels of N2 were calculated. The calculated distribution is highly non-Boltzmann at vibrational levels v > 2 and leads to a decrease in the calculated electron density and integral intensity at 630 nm in the northern and southern hemispheres in comparison with the electron density and integral intensity calculated using the Boltzmann vibrational distribution of N2. It is found that the intensity at 630 nm is very sensitive to the oxygen number densities. Good agreement between the modeled and measured intensities is obtained provided that at all altitudes of the southern hemisphere a reduction of about factor 1.35 in MSIS-86 atomic oxygen densities is included in the IZMIRAN model with the non-Boltzm-ann vibrational distribution of N2. The effect of using of the O(1D) diffusion results in the decrease of 4–6% in the calculated integral intensity of the northern hemisphere and 7–13% in the calculated integral intensity of the southern hemisphere. It is found that the modeled intensities of the southern hemisphere are more sensitive to the assumed values of the rate coefficients of O+(4S) ions with vibrationally excited nitrogen molecules and quenching of O+(2D) by atomic oxygen than the modeled intensities of the northern hemisphere.  相似文献   

19.
Pulsating of the generalized ion and neutral polar winds   总被引：1，自引：1，他引：0  
A three-dimensional, time-dependent model of the ion and neutral polar winds was used to study their dynamic evolution during the May 4, 1998 magnetic storm. The simulation tracked the dynamics of five species (O+, H+, Hs, Os, and electrons) and covered a 9-h period. During the storm, Dst decreased to −210 nT, Ap reached 300, and Kp was elevated. The IMF Bz component was southward at the start of the storm and for several hours thereafter and then turned northward. However, the magnetospheric energy input to the ionosphere exhibited a 50-min oscillation, with the plasma convection and particle precipitation patterns expanding and contracting in a periodic manner. As a consequence, the ion and neutral polar winds pulsated with an approximate 50-min period. The H+ and O+ ions displayed cyclic upflows and downflows in the topside ionosphere as well as a highly structured spatial distribution that varied with time. The vertical flux of the neutral Hs atoms was upward at the top of the ionosphere, but the magnitude varied in a cyclic manner in response to the oscillating stormtime energy input. The vertical flux of neutral Os atoms was downward at the top of the ionosphere and varied significantly with the stormtime energy input. For H+, O+, and Hs, the maximum total (integrated) vertical flux during the storm was upward at the top of the ionosphere, with values of 8–9×1025 particles/s for H+, 2–4×1026 particles/s for O+, and 2–3×1027 particles/s for Hs. The corresponding total vertical Os flux was predominately downward, with only localized areas with positive fluxes.  相似文献   

20.
Summary The analysis is given for an improved aspiration-type mobility chamber which suppresses the growth of boundary layers and turbulence at the electrodes by employing converging-channel geometry. The distribution of small ions in air as a function of their mobility is determined from data taken with the converging-channel chamber. The results show that the distribution of positive ions is quite stable with an average mobility of about 1.35 cm2 volt–1 sec–1 (at STP). The negative-ion distribution is broader, less stable, and the average mobility shifts from about 2.1 to 1.7 cm2 volt–1 sec–1 with the addition of water vapor. The effect of Aitken nuclei upon the mobility distribution is also discussed. The results are compared with previous measurements.  相似文献   

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