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1.
A simple kinetic mechanism of nitrate radicals uptake on dry sea-salt NaCl, NaBr surfaces is proposed. The mechanism includes adsorption/desorption equilibrium and unimolecular decomposition of the adsorbed complex: NO3(g) + NaX(s) (NO3-NaX)(s); (NO3-NaX)(s) NaNO3 + X(s) Two techniques were used: the matrix isolation ESR and mass spectrometry. The uptake coefficient () is found to be dependent on exposure time of salt to NO3 for raw coating. The initial (t0) is higher than the observable steady-state obs. At room temperature obs is independent of [NO3] at low [NO3] = 3 × 109 - 1011 cm-3, but it is inversely proportional to [NO3] at concentrations higher than 1012 cm-3. At temperatures above 100 °C, obs becomes independent of [NO3] in a wider range of [NO3]. An increased number of dislocations is supposed to exist in the case of raw coating. Due to a wide spread of the surface sites binding energy with the ionic lattice near dislocations, the part of surface complexes has lower binding energy and "burns" more rapidly. That burning determines the transition from (t0) down to obs.The kinetic parameters and elementary rate coefficients are obtained. The recommended for low atmospheric NO3 concentration are in the range of 0.002 ± 0.04 for NaCl and 0.1-0.3 for NaBr depending on a mechanism of the (t) relaxation.  相似文献   

2.
Flux densities of carbon dioxide were measured over an arid, vegetation-free surface by eddy covariance techniques and by a heat budget-profile method, in which CO2 concentration gradients were specified in terms of mixing ratios. This method showed negligible fluxes of CO2, consistent with the bareness of the experimental site, whereas the eddy covariance measurements indicated large downward fluxes of CO2. These apparently conflicting observations are in quantitative agreement with the results of a recent theory which predicts that whenever there are vertical fluxes of sensible or latent heat, a mean vertical velocity is developed. This velocity causes a mean vertical convective mass flux (= cw for CO2, in standard notation). The eddy covariance technique neglects this mean convective flux and measures only the turbulent flux c w. Thus, when the net flux of CO2 is zero, the eddy covariance method indicates an apparent flux which is equal and opposite to the mean convective flux, i.e., c w = – c w. Corrections for the mean convective flux are particularly significant for CO2 because cw and c w are often of similar magnitude. The correct measurement of the net CO2 flux by eddy covariance techniques requires that the fluxes of sensible and latent heat be measured as well.  相似文献   

3.
Local Similarity Relationships In The Urban Boundary Layer   总被引：5，自引：3，他引：2  
To investigate turbulent structures in an urban boundary layer (UBL) with many tallbuildings, a number of non-dimensional variable groups based on turbulent observationsfrom a 325-m meteorological tower in the urban area of Beijing, China, are analyzedin the framework of local similarity. The extension of surface-layer similarity to localsimilarity in the stable and unstable boundary layer is also discussed. According to localsimilarity, dimensionless quantities of variables: e.g., velocity and temperature standarddeviations i/u*l (i=u,v,w) andT/T*l,correlation coefficients of uw and wT covariance, gradients of wind and temperaturem and h, and dissipation rates of turbulent kinetic energy (TKE) andtemperature variance and N can be represented as a functiononly of a local stability parameter z/, where is the local Obukhovlength and z is the height above ground. The average dissipation rates of TKE andtemperature variance are computed by using the u spectrum, and the uw and wTcospectra in the inertial subrange. The functions above were found to be in a goodagreement with observational behaviour of turbulence under unstable conditions, butthere were obvious differences in the stable air.  相似文献   

4.
E- turbulence model predictions of the neutralatmospheric boundary layer (NABL) are reinvestigated to determine thecause for turbulence overpredictions found in previous applications. Analytical solutions to the coupled E and equations for the case of steady balance between transport and dissipation terms, the dominant balance just below the NABL top, are derived. It is found that analytical turbulence profiles laminarizeat a finite height only for values of closure parameter ratio c 2 /e equal toor slightly greater than one, with laminarization as z for greater . The point = 2 is additionally foundthat where analytical turbulent length scale (l) profilesmade a transition from ones ofdecreasing ( < 2) to increasing ( > 2)values with height. Numerically predicted profiles near the NABL topare consistent with analytical findings. The height-increasingvalues of l predicted throughout the NABL with standard values ofclosure parameters thus appear a consequence of 2.5(> 2), implied by these values (c 2 = 1.92, = 1.3, e = 1). Comparison of numericalpredictions with DNS data shows that turbulence overpredictions obtained with standard-valued parameters are rectifiedby resetting and e to 1.1 and 1.6, respectively, giving, with c 2 = 1.92, 1.3, and laminarization of the NABL's cappingtransport-dissipation region at a finite height.  相似文献   

5.
Analytical solutions for the Ekman layer   总被引：1，自引：0，他引：1  
The PBL equation that governs the transition from the constant-stress surface layer to the geostrophic wind in a neutrally stratified atmosphere for which the eddy viscosityK(z) is assumed to vary smoothly from the surface-layer value U *z (0.4,U *=friction velocity,z=elevation) to the geostrophic asymptoteK GU *d forzd is solved through an expansion in fd/U *1 (f=Coriolis parameter). The resulting solution is separated into Ekman's constant-K solution an inner component that reduces to the classical logarithmic form forzd and isO() relative to the Ekman component forzd. The approximationKU *d is supported by the solution of Nee and Kovasznay's phenomenological transport equation forK(z), which yieldsK–U *d exp(–z/d), where is an empirical constant for which observation implies, 1. The parametersA andB in Kazanskii and Monin's similarity relation forG/U * (G=geostrophic velocity) are determined as functions of . The predicted values ofG/U * and the turning angle are in agreement with the observed values for the Leipzig wind profile. The predicted value ofB based on the assumption of asymptotically constantK is 4.5, while that based on the Nee-Kovasznay model is 5.1; these compare with the observed value of 4.7 for the Leipzig profile. A thermal wind correction, an asymptotic solution for arbitraryK(z) and 1, and an exact (unrestricted ) solution forK(z)=U *d[1–exp(–z/d)] are developed in appendices.  相似文献   

6.
The aerodynamic classification of the resistance laws above solid surfaces is based on the use of a so-called Reynolds roughness number Re s =h s u */, whereh s is the effective roughness height, -viscosity,u *-friction velocity. The recent experimental studies reported by Toba and Ebuchi (1991), demonstrated that the observed variability of the sea roughness cannot be explained only on the basis of the classification of aerodynamic conditions of the sea surface proposed by Kitaigorodskii and Volkov (1965) and Kitaigorodskii (1968) even though the latter approach gains some support from recent experimental studies (see for example Geernaertet al. 1986). In this paper, an attempt is made to explain some of the recently observed features of the variability of surface roughness (Toba and Ebuchi, 1991; Donelanet al., 1993). The fluctuating regime of the sea surface roughness is also described. It is shown that the contribution from the dissipation subrange to the variability of the sea surface can be very important and by itself can explain Charnock's (1955) regime.  相似文献   

7.
Turbulence measurements performed in a stable boundary layer over the sloping ice surface of the Vatnajökull in Iceland are described. The boundary layer, in which katabatic forces are stronger than the large-scale forces, has a structure that closely resembles that of a stable boundary layer overlying a flat land surface, although there are some important differences. In order to compare the two situations the set-up of the instruments on an ice cap in Iceland was reproduced on a flat grass surface at Cabauw, the Netherlands. Wind speed and temperature gradients were calculated and combined with flux measurements made with a sonic anemometer in order to obtain the local stability functions m and h as a function of the local stability parameter z/L. Unlike the situation at Cabauw, where m was linear as a function of z/L, in the katabatically forced boundary layer, the dependence of m on stability was found to be non-linear and related to the height of the wind maximum. Thermal stratification and the depth of the stable boundary layer however seem to be rather similar under these two different forcing conditions.Furthermore, measurements on the ice were used to construct the energy balance. These showed good agreement between observed melt and components contributing to the energy balance: net radiation (supplying 55% of the energy), sensible heat flux (30%) and latent heat flux (15%).Local sources and sinks in the turbulent kinetic energy budget are summed and indicate a reasonable balance in near-neutral conditions but not in more stable situations. The standard deviation of the velocity fluctuations u, v, and w, can be scaled satisfactorily with the local friction velocity u* and the standard deviation of the temperature fluctuation with the local temperature scale *.  相似文献   

8.
For the thermal stability function h used to calculate heat and moisture fluxes in the surface layer, we choose a formulation which has the theoretically correct free convection limit % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaeikaiabgk% HiTGqaciaa-PhacaqGVaGaamitaiaabMcadaahaaWcbeqaaiabgkHi% TiaaigdacaGGVaGaaG4maaaaaaa!3DFE!\[{\rm{(}} - z{\rm{/}}L{\rm{)}}^{ - 1/3} \]. We then use the experimental result that z/L Ri to deduce a formulation with an exponent -1/6 for the momentum stability function m. This formulation also resolves the matching problem at the interface between the surface and Ekman layers. The proposed functions are found to remain reasonably close to another formulation that is well supported by observations and has exponents -1/2 for h and -1/4 for m. The intent of the proposals is mainly to clarify and simplify the parameterization of the convective boundary layer in present day atmospheric models, without significantly altering the results.  相似文献   

9.
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10.
Stability correction functions which combine the exponent of z/L, and a linear term in z/L, are proposed for the unstable case. The functions provide a reasonably close fit to the m and h results of Dyer and Hicks (1970) for 0 < –z/L 1, but they cannot be extended to cases of strong instability. Attractive features are the ability to integrate the expressions directly in terms of z/L, and a particularly close fit of the integrated result to experimentally derived m values.  相似文献   

11.
Previous results of non-dimensional wind and temperature profiles as functions of ( = z/L) show systematic deviations between different experiments. These discrepancies are generally believed not to reflect real differences but rather instrumental shortcomings. In particular, it is clear that flow distortion has not been adequately treated in most previous experiments. In the present paper, results are presented from a surface-layer field experiment where great care was taken to remove any effects from this kind of error and also to minimize other measuring errors. Data from about 90 30-min runs with turbulence measurements at three levels (3, 6, and 14 m) and simultaneous profile data have been analysed to yield information on flux-gradient relationships for wind and temperature.The flux measurements themselves show that the fluxes of momentum and sensible heat are constant within ± 7% on average for the entire 14 m layer in daytime conditions and when the stratification is slightly stable. For more stable conditions, the flux starts to decrease systematically somewhere in the layer 6 to 14 m. From a large body of data for near-neutral conditions (¦¦ 0.1), values are derived for von Kármán's constant: 0.40 ± 0.01 and for h at neutrally, 0.95 ± 0.04. The range of uncertainty indicated here is meant to include statistical uncertainty as well as the effect of possible systematic errors.Data for m and h for an extended stability range (1 > > – 3) are presented. Several formulas for m and h appearing in the literature have been used in a comparative study. But first all the formulas have been modified in accordance with the following assumptions: = 0.40 and ( h ) = 0 = 0.95; deviations from this result in the various studies are due to incomplete correction for flow distortion. After new corrections are introduced, the various formulas were compared with the present measurements and with each other. It is found that after this modification, the most generally used formulas for m and h for unstable conditions, i.e., those of Businger et al. (1971) and Dyer (1974) agree with each other to within ± 10% and with the present data. For stable conditions, the various formulas still disagree to some extent. The conclusion in relation to the present data is not as clear as for the unstable runs, because of increased scatter. It is, however, found that the modified curve of Businger et al. (1971) for h fits the data well, whereas for m , Dyer's (1974) curve appears to give slightly better agreement.  相似文献   

12.
Summary During an expedition to the high Andes of Southern Peru in June–July 1977, measurements of direct solar radiation in four spectral bands (0.270–0.530–0.630–0.695–2.900 ) were conducted at six sites in elevations ranging from sea level to 5645 m. These measurements were evaluated in Langley plots to determine total optical depths () and irradiances at the top of the atmosphere. In addition, water vapor optical depths (wv) were calculated from the mean radiosounding over Lima during the expedition, and Rayleigh (ray) and ozone (oz) optical depths were obtained from published tabulations. Subtracting ray, oz, and wv from yielded estimates of aerosol optical depth aer. The components ray and oz decrease from the shorter towards the longer wavelength bands and from the lower towards the higher elevation sites; aer also decreases towards the higher elevations. Particularly pronounced is the decrease of aer and from the lowlands of the Pacific coast to the highlands of the interior, reflecting the effect of a persistent lower-tropospheric inversion and the contrast from the marine boundary layer to the clear atmosphere of the high Andes.With 4 Figures  相似文献   

13.
Summary First, the Group Method of Data Handling (GMDH) algorithm, a self-organizing method for constructing higher order regression, is applied to build a model for long-term forecasting. Then, the Group Method of Phase Space Component (GMPSC) model is set up based on chaos theory and GMDH. Several case studies show that both GMDH and GMPSC provide an efficient and potentially useful tool for non-linear time series modeling.Supported by the NKPFR Climate Dynamics and Climate Prediction Theory.  相似文献   

14.
In this paper, we lay the foundations of a systematic mathematical formulation for the governing equations for flow through an urban canopy (e.g., coarse-scaled building array) where the effects of the unresolved obstacles on the flow are represented through a distributed mean-momentum sink. This, in turn, implies additional corresponding terms in the transport equations for the turbulence quantities. More specifically, a modified k-- model is derived for the simulation of the mean wind speed and turbulence for a neutrally stratified flow through and over a building array, where groups of buildings in the array are aggregated and treated as a porous medium. This model is based on time averaging the spatially averaged Navier--Stokes equations, in which the effects of the obstacle--atmosphere interaction are included through the introduction of a volumetric momentum sink (representing drag on the unresolved buildings in the array).The k-- turbulence closure model requires two additional prognostic equations, namely one for the time-averaged resolved-scale kinetic energy of turbulence,, and another for the dissipation rate, , of . The transport equation for is derived directly from the transport equation for the spatially averaged velocity, and explicitly includes additional sources and sinks that arise from time averaging the product of the spatially averaged velocity fluctuations and the distributed drag force fluctuations. We show how these additional source/sink terms in the transport equation for can be obtained in a self-consistent manner from a parameterization of the sink term in the spatially averaged momentum equation. Towards this objective, the time-averaged product of the spatially averaged velocity fluctuations and the distributed drag force fluctuations can be approximated systematically using a Taylor series expansion. A high-order approximation is derived to represent this source/sink term in the transport equation for . The dissipation rate () equation is simply obtained as a dimensionally consistent analogue of the equation. The relationship between the proposed mathematical formulation of the equations for turbulent flow within an urban canopy (where the latter is treated as a porous medium) and an earlier heuristic two-band spectral decomposition for parameterizing turbulence in a plant canopy is explored in detail.  相似文献   

15.
We propose a simple model for esimating the average number of occurrences per unit time (c o) that a threshold concentration c o is exceeded. It is based on the joint probability density of the observed concentration c(t) and its time derivative (t) under the assumption that c(t) is a stationary time series; this assumption leads to the hypothesis that c(t) and (t) are statistically independent. Adopting plausible forms of the frequency distributions of c and , we apply the model to diffusion from an infinite area source and from an elevated point source, both in the neutral boundary layer, and obtain simple results for (c o) and the average duration of one excursion above c o as functions of c o, the mean and the standard deviation of the concentration, and surface-layer variables.The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   

16.
Turbulence mechanisms at an agricultural site   总被引：8，自引：0，他引：8  
An extensive set of turbulence data from the 3- and 12-m heights taken over an agricultural site (Marsta, Sweden) are analyzed and compared with data from ideal sites.In unstable air, Monin-Obukhov similarity is found to be valid for the non-dimensional gradients of wind, m , temperature, h , and humidity, e , for (only a few data), for T /|T *|,/ E /|E *| and for the non-dimensionalized inertial subrange spectra of temperature and humidity. Where comparison is possible, the unstable data also agree with those found in the Kansas study, with one remarkable exception, the inertial subrange constant of the temperature spectrum, 1, being only 0.39, compared to the value 0.80 found at the Kansas site.On the stable side, most similarity predictions break down, with most of the data differing systematically from the corresponding Kansas results, the only exception being . The inertial subrange constants for temperature, 1, and for humidity, 1 are found to have the same values, 0.39 and 0.30, respectively, as they do on the unstable side. Remarkable similarity is found for the shape of the stable u- and - and e-spectra. In addition, this shape is found to be identical with that found in Kansas. The peak wavelength of the stable u-, and -spectra is found to be about four times larger than it is for the corresponding Kansas spectra. This is interpreted to be a result of the increased macro-roughness at the Marsta site as compared with that at the Kansas site. A possible explanation for the low 1-value is discussed, suggesting that 1 is not a universal constant, but instead dependent on the turbulent structure.  相似文献   

17.
Several formulations and proposals to determine the value of the radiometric scalar roughness for sensible heatz 0h,r are tested with respect to their performance in the estimation of the sensible heat flux by means of the profile equations derived from Monin-Obukhov similarity theory. The equations are applied to the data set of spatially averaged surface skin temperature and profiles of wind speed and temperature observed in a pasture field during a growing season. The use of a physical model developed for a dense canopy to estimate scalar roughness for sensible heatz 0h,r produced sensible heat fluxH with a correlation coefficientr=0.884, the ratio of means being H s /H=1.19 in a comparison with reference values ofH s . In comparison, a proposal for a fixed value ofz 0h yieldedr=0.887, H s /H=0.879. In both cases, the validity ofz 0h =z 0h,r was assumed. All expressions derived to estimatez 0h,r from a multiple linear regression with such predictors as leaf area index, solar radiation and the ratio of solar radiation to extraterrestrial radiation, were found to produce a better result, withr better than 0.90 and H s /H around 1.0. However, when the constantsc andf of a linear regression equationHs=cH+f are used to evaluate the equations, a marked difference in performance of each formulation appeared. In general, equations with smaller numbers of predictors tend to produce a biased result, i.e., an overestimation ofH at largeH s . These values ofH are used in conjunction with the energy balance equation to derive values of the latent heat fluxLE, which are shown to be in good agreement with the reference valuesLE s , withr greater than 0.97.  相似文献   

18.
Careful micrometeorological measurements on an empty parking lot allowed determination of the surface fluxes of sensible heatH and of momentum by applying profile equations derived from Monin-Obukhov similarity theory with two sets of the stability correction function for momentum m and sensible heat h . These fluxes were compared with reference values ofH independently determined by means of an eddy correlation technique. In general, better agreement was found betweenH values derived from profiles with the stability functions of Brutsaert (1992) and referenceH values, than when the Businger-Dyer functions were used to deriveH. The disagreement in the latter comparison was especially serious under strongly unstable conditions, with the value ofy=–z/L (wherez is the height andL is the Obukhov length) larger than 10. A closer look at the procedure for calculatingH from the profiles revealed that the large differences between theH values derived with these two different versions of the stability correction functions were caused by the small differences of the h values, and not by the larger differences of the m values. This result stems from the strong sensitivity of the resultingH values on the choice of h .  相似文献   

19.
Summary The effect of the Alpine orography on prototype cold fronts approaching from the west is investigated by three-dimensional numerical model simulations. The numerical experiments cover a range of parameter constellations which govern the prefrontal environment of the front. Especially, the appearance and intensity of prefrontal northern Alpine foehn varies from case to case.The behaviour of a cold front north of the Alps depends much on the prefrontal condition it encounters. It is found that prefrontal foehn can either accelerate or retard the approaching front.An important feature is the pressure depression along the northern Alpine rim that results from the southerly foehn flow. In cases where this depression compensates the eastward directed pressure gradient associated with the largescale flow, the front tends to accelerate and the foehn breaks down as soon as the front passes. In contrast, the foehn prevents the front from a rapid eastward propagation if it is connected with a strong southerly wind component.No-foehn experiments are performed for comparison, where either the mountains are removed, or the static stability is set to neutral. Also shown are effects of different crossfrontal temperature contrasts.List of Symbols c F propagation speed of a front - x, y horizontal grid spacing (cartesian system) - , horizontal grid spacing (geographic system) - t time step - z vertical grid spacing (cartesian system) - cross-frontal potential temperature difference - i potential temperature step at an inversion - E turbulent kinetic energy - f Coriolis parameter - FGP frontogenesis parameter (see section 2.2) - g gravity acceleration (g=9.81 m s–2) - vertical gradient of potential temperature - h terrain elevation (above MSL) - h i height of an inversion (h i =1000 m MSL) - H height of model lid (H=9000 m MSL) - K M exchange coefficient of momentum - K H exchange coefficient of heat and moisture - longitude - N Brunt-Väisäla-frequency - p pressure - Exner function (=T/) - latitude - q v specific humidity - R d gas constant of dry air (R d =287.06 J kg–1 K–1) - density of dry air - t time - T temperature - potential temperature - TFP thermal front parameter (see section 2.2) - u, v, w cartesian wind components - u g ,v g geostrophic wind components - horizontal wind vector - x, y, z cartesian coordinates Abbreviations GND (above) ground level - MSL (above) mean sea level - UTC universal time coordinated With 20 Figures  相似文献   

20.
Plume dispersion in the convective boundary layer (CBL) is investigated experimentally in a laboratory convection tank. The focusis on highly-buoyant plumes that loft near or become trapped in the CBL capping inversion and resistdownward mixing. Such plumes are defined by dimensionless buoyancy fluxes F* 0.1, where F* = Fb/(U w* 2 zi), Fb is the stack buoyancy flux,U is the mean wind speed, w* is the convective velocity scale, and zi is the CBL depth. The aim is to obtain statistically-reliable mean (C) and root-mean-square (rms, c) concentration fields as a function of F* and the dimensionless distance X = w*x/(U zi), where x is the distance downstream of the source.The experiments reveal the following mainresults: (1) For 3 X 4and F* 0.1, the crosswind-integrated concentration (CWIC) fields exhibit distinctly uniform profiles below zi with a CWIC maximum aloft, in contrast to the nonuniform profiles obtained earlier by Willis and Deardorff. (2) The lateral dispersion (y) variation with X is consistent with Taylor's theory for * 0.1 and a buoyancy-enhanced dispersion, y/zi F* 1/3X2/3, forF* = 0.2 and 0.4. (3) The entrapment, the plume fraction above zi, has a mean (E) that follows a systematic variationwith X and F*, and a variability (e/E) that is broad ( 0.3 to 2) near the source but subsides to 0.25 far downstream. (4) Vertical profiles of the concentration fluctuation intensity (c/C) are uniform for z < zi and X > 1.5, but exhibit significant increases: (a) at the surface and close to the source (X 1.5), and(b) in the entrainment zone. (5) The cumulative distribution functions (CDFs) of the scaled concentration fluctuations (c/c) separate into mixed-layer and entrainment-layer CDFs for X 2, with the mixed-layer group collapsing to a single distribution independent of z.These are the first experiments to obtain all components of the lateral and vertical dispersion parameters (rms meander, relative dispersion, total dispersion) for continuous buoyant releases in a convection tank. They also are the first tank experiments to demonstrate agreement with field observations of: (1) the scaled ground-level concentration along the plume centreline, and (2) the dimensionless lateral dispersion _y/z_i of buoyant plumes.  相似文献   

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