共查询到20条相似文献，搜索用时 15 毫秒
1.
《Journal of Asian Earth Sciences》2002,20(2):151-155
The Qianlishan granite complex, situated 16 km southeast of Chenzhou City, Hunan Province, China, hosts the Shizhuyuan W–Sn–Bi–Mo deposit. This complex, which intruded the Protozoic metasedimentary rocks and the Devonian clastic sedimentary and carbonate rocks, consists of mainly medium- to coarse-grained biotite granites and minor amounts of fine-grained biotite granite in addition to granite and quartz porphyry. K–Ar ages suggest three episodes of plutonism: the medium- to coarse-grained biotite granite (before 152 Ma), the fine-grained biotite granite (137 Ma), and the granite porphyry (129–131 Ma). Muscovite ages of the greisen are 145–148 Ma, suggesting that the W–Sn–Bi–Mo mineralization was related to the main, medium- to coarse-grained biotite granites. The K–Ar age of the hydrothermal vein mineralization is 92 Ma and is probably related to the porphyries. 相似文献
2.
The Weilasituo and Bairendaba Zn–Pb–Ag–Cu–(Sn–W) sulphide deposits are located in the southern part of Great Xing'an Range of Inner Mongolia in China. The deposits are located at shallow depths in the newly discovered Weilasituo porphyry hosting Sn–W–Rb mineralization. The mineralization at Weilasituo and Bairendaba consist of zoned massive sulphide veins within fractures cutting the Xilinhot Metamorphic Complex and quartz diorite. The Weilasituo deposit gradually zones from the Cu-rich Zn–Cu sulphide mineralization in the west to Zn-rich Zn–Cu sulphide mineralization in the east. The Bairendaba deposit has a Cu-bearing and Zn-rich core through a transitional zone devoid of copper to an outer zone of Zn–Pb–Ag mineralization. Three main veins contain more than 50 wt.% of the contained metal in the two deposits with their metal ratios displaying a systematic and gradual increase in Zn/Cu, Pb/Zn and Ag/Zn ratios from the western part of Weilasituo to the eastern part of Bairendaba.Three stages of vein-type mineralization are recognized. Early, sub-economic mineralization consists of a variable proportion of euhedral arsenopyrite, pyrite, quartz, and rare wolframite, scheelite, cassiterite, magnetite and cobaltite. This was succeeded by main stage mineralization with economic concentration of zoned Cu, Zn, Pb and Ag sulphide minerals along strike within the veins. The zones consist of the assemblages: (1) pyrrhotite–Fe-rich sphalerite–chalcopyrite(–quartz–fluorite) at west Weilasituo; (2) pyrrhotite–Fe-rich sphalerite–chalcopyrite(–galena–tetrahedrite–quartz–fluorite) at east Weilasituo; (3) pyrrhotite–Fe-rich sphalerite–chalcopyrite(–galena–tetrahedrite–quartz–fluorite) in the centre of Bairendaba; (4) pyrrhotite–Fe-rich sphalerite–galena(–chalcopyrite–tetrahedrite–quartz–fluorite) in the transition zone of Bairendaba; and (5) pyrrhotite–Fe-rich sphalerite–galena–tetrahedrite(–chalcopyrite–falkmanite–argentite–pyrargyrite–quartz–fluorite) in the outer zone at Bairendaba. Post-main ore stage is devoid of sulphides and characterized overprinting of fluorite, sericite, chlorite, illite, kaolinite and calcite.Zircon SHRIMP U–Pb dating, Zircon LA–ICP–MS U–Pb dating, molybdenite Re–Os isochron dating, and muscovite Ar–Ar dating indicate the Beidashan granitic batholith was intruded at 140 ± 3 Ma (MSWD = 3.3), the porphyritic monzogranite from marginal facies of the Beidashan batholith was intruded at 139 ± 2 Ma (MSWD = 0.75), the mineralized quartz porphyry was intruded at 135 ± 2 Ma (MSWD = 0.91), the greisen mineralization occurred at 135 ± 11 Ma (MSWD = 7.2), and the post-main ore stage muscovite deposited at 129.5 ± 0.9 Ma. The new geochronology data show the porphyry Sn–W–Rb and vein-type sulphide mineralization are contemporaneous with granitic magmatism in the region.The metal zonation at the Weilasituo and Bairendaba deposits is a result of progressive metal deposition. This was during the evolution of a metal-bearing fluid along the strike of the veins and during the main stage of ore formation at the upper part of the deep-seated porphyry Sn–W–Rb system. This progressive zonation indicates that the deposits represent end-numbers formed from one ore-forming fluid, which moved from west to east from the porphyry. The metal zonation patterns of the major veins are consistent with metal-bearing fluid entering the system with the precipitation of chalcopyrite proximally and sphalerite, galena and Ag-bearing minerals more distally. We show that the mechanism of metal deposition is therefore controlled by thermodynamic conditions resulting in the progressive separation of sulphides from the metal-bearing fluid. The temperature gradient between the inflow zone and the outflow zone appears to be one of the key parameters controlling the formation of the metal zonation pattern. The sulphide precipitation sequence is consistent with a low fS2 and low fO2 state of the acidic metal-bearing fluid. The metal zonation pattern provides helpful clues from which it is possible to establish the nature of fluid migration and metal deposition models to locate a possible porphyry mineralization at depth in the Great Xing'an Range, which is consistent with the geology of the newly discovered porphyry Sn–W–Rb system. 相似文献
3.
The Taoxihu deposit (eastern Guangdong, SE China) is a newly discovered Sn polymetallic deposit. Zircon U-Pb dating yielded 141.8 ± 1.0 Ma for the Sn-bearing granite porphyry and 145.5 ± 1.6 Ma for the biotite granite batholith it intruded. The age of the granite porphyry is consistent (within error) with the molybdenite Re–Os isochron age (139.0 ± 1.1 Ma) of the Sn mineralization, indicating a temporal link between the two. Geochemical data show that the granite porphyry is weakly peraluminous, contain high Si, Na and K, low Fe, Mg, Ca and P, and relatively high Rb/Sr and low K/Rb values. The rocks are enriched in Rb, Th, U, K, and Pb and depleted in Ba, Sr, Ti and Eu, resembling highly fractionated I-type granites. They contain bulk rock initial 87Sr/87Sr of 0.707371–0.707730 and εNd(t) of −5.17 to −4.67, and zircon εHf(t) values from −6.67 to −2.32, with late Mesoproterozoic TDM2 ages for both Nd and Hf isotopes. This suggests that the granite porphyry was likely formed by the partial melting of the crustal basement of Mesoproterozoic overall residence age with minor mantle input.δ34SCDT values of the Taoxihu chalcopyrite and pyrite range from 0.1 to 2.1‰ (average: 0.9‰), implying a dominantly magmatic sulfur source. The 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios of the Taoxihu sulfide ores are 18.497–18.669, 15.642–15.673 and 38.764–38.934, respectively, indicating a mainly upper continental crustal lead source with minor mantle contribution. The highly fractionated and reduced (low calculated zircon Ce4+/Ce3+ and EuN/EuN1 values) nature of the ore-forming granitic magma may have facilitated the Sn enrichment and played a key role in the Sn mineralization. We propose that the ore-forming fluids at Taoxihu were of magmatic-hydrothermal origin derived from the granite porphyry, and that both the granite porphyry and the Sn mineralization were likely formed in an extensional setting, possibly related to the subduction slab rollback of the Paleo-Pacific Plate. 相似文献
4.
The Sierras Pampeanas orogen, in northwestern Argentina, hosts significant Sn–W mineralization in a variety of mostly epizonal granite stocks emplaced in variably metamorphosed country rocks. The San Blas, Huaco and El Durazno granite stocks in the Sierra de Velasco, the La Quebrada granite in the Sierra de Mazán, the Cerro Colorado granite in the Cerro Negro, and the Los Mudaderos and Sauce Guacho granite stocks in the Sierra de Ancasti, are largely peraluminous (ASI between 1.05 and 1.38) and represent S-type granites, are strongly fractionated (i.e., high Rb–Sr ratio), have a low oxidation state (low Fe2O3/Fe2O3 ratio) and are geotectonically linked to syncollisional magmatism. The U–Pb SHRIMP analyses on zircons from the Cerro Colorado and La Quebrada granites, located in the Cerro Negro and Sierra de Mazán, respectively, revealed ages from Lower Ordovician (Tremadocian) to Carboniferous. All granites display elevated LREE values, low HREE values and negative Eu anomalies. With regards to total REE values, two groups of granite stocks can be recognized. The granites with lower REE contents are highly evolved granites and are related to Sn–W mineralization. The mineralized granites display higher values of Sn, W and Rb, and lower values of Sr and Ba compared to barren granites. These trace element characteristics appear to be diagnostic for Sn–W mineralized granite stocks in the western Sierras Pampeanas. The western Sierras Pampeanas contains locally geochemically evolved Carboniferous granites, which are interpreted to be the main control of significant Sn–W mineralization. The Carboniferous age of western Sierras Pampeanas Sn–W mineralization sets it apart from the Triassic age of the Sn–W mineralization in the Eastern Tin belt of Bolivia. 相似文献
5.
6.
Sami Hamed Abd El Nabi 《Arabian Journal of Geosciences》2011,5(5):971-983
A geophysical signature associated with Nb–Ta–Sn mineralization of G. (G. : abbreviation to word Gebel which means mountain in Arabic) Nuweibi area, located the Central Eastern Desert of Egypt is presented. This signature was established by an integration of airborne gamma ray spectrometric and magnetic data. Variations seen in the gamma ray spectrometric data are used as a base to study the three granitic suites: younger-, albite-, and older granites in G. Nuweibi area. Graphical techniques such as frequency histograms and box-plots are used to visualize the shape of the distribution and determine the anomaly thresholds of the three radioelements eU, eTh, and K% data in these granitic suites. The box-plot graphical representations and calculations made on data sets indicate that no samples have eU values above the thresholds, i.e., no outliers representing values of the box-plots. Nuweibi albite granite is associated with a gamma ray response that includes the strongest eU, eTh, K%, and eTh/K ratio anomalies in the study area. K–eTh plot shows that the albite granite has a higher eTh concentration than the older and younger granites. The increase in K concentration and raise in Th/K ratio of Nuweibi albite granite points to unusual geological processes leading to mineralization and reflects the highly fractionated nature of the magma which results in thorium enrichment. This also reflects that K alteration associated with Nb–Ta–Sn mineralization is both poorly focused spatially and very much weaker than observed in any other mineralizing districts. The distribution of magnetic sources and their locations and depths in the study region are determined by Euler deconvolution and analytical signal techniques. Good clustering of Euler solutions were obtained using SI?=?0.5 and SI?=?1.0 for most of the features in the area under consideration. The solutions obtained have shown magnetic sources which can be related to the impact structure whose depths varies between ground surface to 1.66 km. The analytical signal revealed that the metamorphosed basic rocks (mainly olivine metagabbro), serpentinite and dyke bodies are the main sources of high magnetic anomalies, particularly within the area east G. Nuweibi region. 相似文献
7.
The Horní Slavkov–Krásno Sn–W ore district is hosted by strongly altered Variscan topaz–albite granite (Krudum granite body) on the northwestern margin of the Bohemian Massif. We studied the fluid inclusions on greisens, ore pockets, and ore veins from the Hub Stock, an apical expression of the Krudum granite. Fluid inclusions record almost continuously the post-magmatic cooling history of the granite body from ～500 to <50°C. Rarely observed highest-temperature (～500°C) highest-salinity (～30?wt.% NaCl eq.) fluid inclusions are probably the result of secondary boiling of fluids exsolved from the crystallizing magma during pressure release which followed hydraulic brecciation of the gneissic mantle above the granite cupola. The greisenization was related to near-critical low-salinity (0–7?wt.% NaCl eq.) aqueous fluids with low amount of CO2, CH4, and N2 (≤10?mol% in total) at temperatures of ～350–400°C and pressures of 300–530 bar. Crush-leach data display highly variable and negatively correlated I/Cl and Br/Cl values which are incompatible with both orthomagmatic and/or metamorphic origin of the fluid phase, but can be explained by infiltration of surficial and/or sedimentary fluids. Low fluid salinity indicates a substantial portion of meteoric waters in the fluid mixture that is in accordance with previous stable isotope data. The post-greisenization fluid activity associated with vein formation and argillitization is characterized by decreasing temperature (<350 to <50°C), decreasing pressure (down to ～50–100 bar), and mostly also decreasing salinity. 相似文献
8.
The Carris orebody consists of two partially exploited W–Mo–Sn quartz veins formed during successive shear stages and multipulse fluid fillings. They cut the Variscan post-D3 Gerês I-type granite. The most important ore minerals are wolframite, scheelite, molybdenite and cassiterite. There are two generations of wolframite. The earlier generation of wolframite is rare and has the highest WO4Mn content (91 mol%) and the most common wolframite contains 26–57 mol% WO4Mn. Re–Os dating of molybdenite from the ore quartz veins and surrounding granite yields ages of 279 ± 1.2 Ma and 280.3 ± 1.2 Ma, respectively which are in very good agreement with the previous ID-TIMS U–Pb zircon age for the Carris granite (280 ± 5 Ma).3He/4He ratio of pyrite ranging between 0.73 and 2.71 Ra (1 Ra = 1.39 × 10− 6) and high 3He/36Ar (0.8–5 × 10− 3) indicate a mixture of a crustal radiogenic helium fluid with a mantle derived-fluid.The fluid inclusion studies on quartz intergrown with wolframite and scheelite, beryl and fluorite reveal that two distinct fluid types were involved in the genesis of this deposit. The first was a low to medium salinity aqueous carbonic fluid (CO2 between 4 and 14 mol%) with less than 1.95 mol% N2, which was only found in quartz associated with wolframite. The other was a low salinity aqueous fluid found in all the four minerals. The homogenization temperatures indicate minimum entrapment temperatures of 226–310 °C (average 280 °C) for the H2O–CO2–N2–NaCl fluid and average temperatures of 266 °C for scheelite and 242 °C, 190 °C and 160 °C for the last generations of beryl, fluorite and quartz, respectively. It was estimated that wolframite was deposited ~ 7 km depth, assuming a lithostatic pressure, probably due to strong pressure fluctuation caused by seismic events triggered by brittle tectonics during the exhumation event. Precipitation of scheelite and sulphides took place later, at the same depth, but under a hydrostatic or suprahydrostatic pressure regime, and probably caused by mixing between the magmatic–hydrothermal fluid and meteoric waters that deeply penetrated the basement during post-Variscan decompression. 相似文献
9.
10.
The newly discovered large-scale Baiganhu W–Sn orefield, consisting of the Kekekaerde, Baiganhu, Bashierxi, and Awaer deposits, is located in Ruoqiang County, southeastern Xinjiang, China. These deposits comprise mainly three types of W–Sn mineralization: early-stage skarn-type, middle-stage greisen-type, and late-stage quartz-vein-type. In this study, we classified seven major vertical zones on the basis of petrographic characteristics, roughly from the bottom of the parental granitic intrusions upward, as (A) fresh syenogranite, (B) argillic alteration, (C) muscovite-dominated greisenization, (D) tourmaline-dominated greisenization, (E) marginal facies (including K-feldspar pegmatite and fine-grained granite), (F) aplitic apophysis, and (G1) skarn or (G2) infilled silification zones. According to the alteration–mineralization assemblages and cross-cutting relationships, five stages of mineralization are recognized in the orefield (I, skarn stage; II, greisen stage; III, quartz vein stage; IV, argillic alteration stage; and V, supergene stage), and reverse alteration zonation in the altered intrusion is also observed.The W–Sn deposits are spatially associated with syenogranite, which is part of the Caledonian Bashierxi magmatic series. Laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) zircon U–Pb dating of the syenogranite yields a weighted mean 206Pb/238U age of 413.6 ± 2.4 Ma (MSWD = 0.36, n = 30). Hydrothermal muscovite from three samples associated with W–Sn mineralization yields plateau 40Ar/39Ar ages of 411.7 ± 2.6 Ma (MSWD = 0.21), 412.8 ± 2.4 Ma (MSWD = 0.22), and 413.8 ± 2.6 Ma (MSWD = 0.22), which is consistent with the zircon U–Pb age, thus indicating a temporal link between the emplacement of the syenogranite and the W–Sn mineralization. Our age data and previously published ages, along with geochemical data, for the granitoids in the Bashierxi magmatic series show a nearly contemporaneous evolution of A- and S-type granites, which were emplaced in a post-orogenic setting at ca. 432–413 Ma. As compared with the A-type granites, the syenogranites with S-type affinities probably resulted from a lower degree of partial melting of metagreywackes, which was more likely to be enriched in the ore-forming elements W and Sn, as well as volatiles such as B and H2O. In addition, the syenogranites exhibit low oxidation states and underwent high degrees of factional crystallization, both of which favor post-magmatic W–Sn mineralization. We suggest that more attention should be given to buried syenogranites of S-type affinities during mineral exploration in this area, and that the proposed model of a vertical alteration zoning can act as a guide to the targeting of similar ore systems. 相似文献
11.
The Xitian tungsten–tin (W–Sn) polymetallic deposit, located in eastern Hunan Province, South China, is a recently explored region containing one of the largest W–Sn deposits in the Nanling W–Sn metallogenic province. The mineral zones in this deposit comprise skarn, greisen, structurally altered rock and quartz-vein types. The deposit is mainly hosted by Devonian dolomitic limestone at the contact with the Xitian granite complex. The Xitian granite complex consists of Indosinian (Late Triassic, 230–215 Ma) and Yanshanian (Late Jurassic–Early Cretaceous, 165–141 Ma) granites. Zircons from two samples of the Xitian granite dated using laser ablation-inductively coupled mass spectrometer (LA-ICPMS) U–Pb analysis yielded two ages of 225.6 ± 1.3 Ma and 151.8 ± 1.4 Ma, representing the emplacement ages of two episodic intrusions of the Xitian granite complex. Molybdenites separated from ore-bearing quartz-veins yielded a Re–Os isochron age of 149.7 ± 0.9 Ma, in excellent agreement with a weighted mean age of 150.3 ± 0.5 Ma. Two samples of muscovites from ore-bearing greisens yielded 40Ar/39Ar plateau ages of 149.5 ± 1.5 Ma and 149.4 ± 1.5 Ma, respectively. These isotopic ages obtained from hydrothermal minerals are slightly younger than the zircon U–Pb age of 151.8 ± 1.4 Ma of the Yanshanian granite in the Xitian area, indicating that the W–Sn mineralization is genetically related to the Late Jurassic magmatism. The Xitian deposit is a good example of the Early Yanshanian regional W–Sn ore-forming event (160–150 Ma) in the Nanling region. The relatively high Re contents (8.7 to 44.0 ppm, average of 30.5 ppm) in molybdenites suggest a mixture of mantle and crustal sources in the genesis of the ore-forming fluids and melts. Based upon previous geochemical studies of Early Yanshanian granite and regional geology, we argue that the Xitian W–Sn polymetallic deposit can be attributed to back-arc lithosphere extension in the region, which was probably triggered by the break-off of the flat-slab of the Palae-Pacific plate beneath the lithosphere. 相似文献
12.
The Xishan deposit, located in the western Guangdong Province in South China, is a quartz-vein type W-Sn deposit with an average Sn grade of 0.1–0.4 wt%. The deposit is temporally and spatially associated with Xishan alkali feldspar granite. The W–Sn mineralization is present mainly as veins that are hosted by the granite. In this paper we present new zircon U–Pb age, whole-rock geochemical data, Sr–Nd–Pb–Hf isotopic data and Re–Os age in order to constrain the nature and timing of magmatism and mineralization in the Xishan mining district with implications on geodynamic settings. LA–ICP–MS zircon U–Pb analyses yielded an age of 79.14 ± 0.31 Ma for the alkali feldspar granite, consistent with the molybdenite Re–Os age of 79.41 ± 1.11 Ma. The alkali feldspar granite shows high contents of SiO2 (71.52–76.25 wt%), high total alkalis (Na2O + K2O = 9.35–13.51 wt%), high field strength elements (e.g. Zr = 95.4–116 ppm, Y = 97.1–138 ppm, Nb = 36.1–55.5 ppm, Ga = 97.1–138 ppm), and rare earth elements (total REE = 171.8–194.0 ppm) as well as high Ga/Al ratios (10,000 × Ga/Al = 3.23–3.82) suggesting that it has the geochemical characteristics of A-type granite and shows an A2 subtype affinity. Sr–Nd isotopes of the alkali feldspar granite show that (87Sr/86Sr)i values range from 0.7111 to 0.7183, and the εNd(t) values and Nd model ages (T2DM) vary from −6.8 to −6.5 and 1414 to 1433 Ma, respectively. The Pb isotopic compositions are variable, with 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values ranging from 18.783 to 18.947, 15.709 to 15.722 and 38.969 to 39.244, respectively, indicating that the alkali feldspar granite was derived from a mantle-crust mixed source. In situ Hf isotopic analyses reveal that the alkali feldspar granite has εHf(t) values ranging from −9.69 to −0.04 and two-stage Hf model ages from 1145 Ma to 1755 Ma, indicating that the alkali feldspar granite was formed by the partial melting of Mesoproterozoic crusts of the Cathaysia Block with additions of mantle-derived materials. These results, together with previously presented regional geological relationships, suggest that the formation of the Xishan granite and associated W–Sn mineralization is related to lithospheric extension and asthenospheric upwelling that are attributed to a directional change of Pacific plate motion. 相似文献
13.
Hartmut Beurlen Marcelo R. R. Da Silva Rainer Thomas Dwight R. Soares Patrick Olivier 《Mineralium Deposita》2008,43(2):207-228
The Borborema Pegmatitic Province (BPP), northeastern Brazil, is historically important for tantalum mining and also famous
for top-quality specimens of exotic Nb–Ta oxides and, more recently, for the production of gem quality, turquoise blue, ‘Paraíba
Elbaite.’ With more than 750 registered mineralized rare-element granitic pegmatites, the BPP extends over an area of about
75 by 150 km in the eastern part of the Neoproterozoic Seridó Belt. The Late Cambrian pegmatites are mostly hosted by a sequence
of Neoproterozoic cordierite–sillimanite biotite schists of the Seridó Formation and quartzites and metaconglomerates of the
Equador Formation. The trace-element ratios in feldspar and micas allow to classify most pegmatites as belonging to the beryl–columbite
phosphate subtype. Electron microprobe analyses (EMPA) of columbite, tapiolite, niobian–tantalian rutile, ixiolite and wodginite
group minerals from 28 pegmatites in the BPP are used to evaluate the effectiveness of Nb–Ta oxide chemistry as a possible
exploration tool, to trace the degree of pegmatite fractionation and to classify the pegmatites. The columbite group mineral
composition allows to establish a compositional trend from manganoan ferrocolumbite to manganocolumbite and on to manganotantalite.
This trend is typical of complex spodumene- and/or lepidolite-subtype pegmatites. It clearly contrasts with another trend,
from ferrocolumbite through ferrotantalite to ferrowodginite and ferrotapiolite compositions, typical of pegmatites of the
beryl–columbite phosphate subtype. Large scatter and anomalous trends in zoned crystals partially overlap and conceal the
two main evolution patterns. This indicates that a large representative data set of heavy mineral concentrate samples, collected
systematically along cross-sections, would be necessary to predict the metallogenetic potential of individual pegmatites.
Other mineral species, e.g. garnets and/or tourmaline, with a more regular distribution than Nb–Ta oxides, would be more appropriate
and less expensive for routine exploration purposes. The currently available Nb–Ta oxide chemistry data suggest the potential
for highly fractionated Ta–Li–Cs pegmatites in the BPP, so far undiscovered, and encourages further, more detailed research. 相似文献
14.
LA-ICPMS Zircon U–Pb and Molybdenite Re–Os Isotopic Dating of the Tungsten Deposits in the Dengfuxian W–Sn Orefield, Eastern Hunan Province, South China, and Their Geological Implications 
下载免费PDF全文
下载免费PDF全文 Please refer to the attachment(s) for more details. 相似文献
15.
16.
The Nanling Range in South China is well known for its rich granite-related W–Sn deposits. To elucidate the controls of different granite-related W–Sn metallogenesis in the region, we chose five representative ore-related granites (Yanbei, Mikengshan, Tieshanlong, Qianlishan, and Yaogangxian intrusions) in the Hunan–Jiangxi region, and studied their magmatic zircon ages and trace element geochemistry. Our new zircon data showed the differences in ages, temperatures and oxygen fugacity of the ore-forming magmas. Zircon U–Pb ages of the Yanbei and Mikengshan intrusions are characterized by 142.4 ± 2.4 and 143.0 ± 2.3 Ma, respectively, whereas the Tieshanlong and Qianlishan intrusions are 159.5 ± 2.3 and 153.2 ± 3.3 Ma, respectively. The Sn-related intrusions were younger than the W-related intrusions. The Ti-in-zircon thermometry showed that there was no systematic difference between the Sn-related Yanbei (680–744 °C) and Mikengshan (697–763 °C) intrusions and the W-related Tieshanlong (730–800 °C), Qianlishan (690–755 °C) and Yaogangxian (686–751 °C) intrusions. However, the zircon Ce4+/Ce3+ ratios of the Yanbei (averaged at 18.3) and Mikengshan (averaged at 18.8) intrusions are lower than those of the Tieshanlong (averaged at 36.9), Qianlishan (averaged at 38.4) and Yaogangxian (averaged at 37) intrusions, indicating that the Sn-related granitic magmas might have lower oxygen fugacities than those of the W-related. This can be explained by that, in more reduced magmas, Sn is more soluble than W and thus is more enriched in the residual melt to form Sn mineralization. The difference in source materials between the Sn-related and the W-related granites seems to have contributed to the different redox conditions of the melts.
相似文献17.
Chengyang Wang Jianfeng Li Keyong Wang Qi Yu Guanghu Liu 《Arabian Journal of Geosciences》2018,11(5):88
In recent decades, several skarn-related deposits have been found and explored in the southern Great Xing’an Range of China. To get a clear understanding of the characteristics and genetics of this type of deposit in this area, three of the largest, most typical, and most famous skarn-related deposits (Haobugao Pb–Zn deposit, Huanggang Sn–Fe polymetallic deposit, and Baiyinnuoer Pb–Zn deposit) are selected for systematically metallogenic study in this paper. The results of ore geology, fluid inclusion, and stable isotopes indicate that (1) most of the ore bodies of each deposit, occurred in the outer contact zone of the magma intrusion and Permian strata, fine vein disseminated mineralization within the intrusions were also found in this study. Mineralization of these deposits all show closely temporal, spatial, and genetic relationships with skarns. (2) Fluid inclusion petrography and microthermometry results show that the fluid inclusion assemblages developed in the different mineralization stages of each deposit changed from Type-S (daughter mineral-bearing three-phase fluid inclusions) + Type-V (vapor-rich fluid inclusions) + Type-L (liquid-rich fluid inclusions) to Type-V + Type-L and eventually evolved into L-Type. Correspondingly, the ore-forming fluids changed from medium to a high-temperature, high-salinity, and boiling fluid system and then to a low-temperature, low-salinity, and uniform fluid system. The types of fluid inclusions in garnets are consistent with those in quartz phenocrysts of Mesozoic granites, indicating that the formation of skarns is directly related to Mesozoic magmatic activity. (3) The δ34S values of ores from the above three deposits all exhibit a narrow variation range (changes are mainly around 0‰) and greatly differ from the SEDEX-type deposits in China. The lead isotope compositions of the sulfide minerals are also consistent with those of Mesozoic granites. These previous characteristics suggest that both of the ore-forming fluids and the ore-forming materials were of magmatic origin. Consequently, the Haobugao, Baiyinnuoer, and Huanggang deposits are all skarn-type deposits, which are related to Mesozoic magmatic activities in terms of ore geology features, ore-forming fluids, and ore-forming material. 相似文献
18.
Yan-Jun Li Jun-Hao Wei Hua-Yong Chen Jun Tan Le-Bing Fu Gang Wu 《Mineralium Deposita》2012,47(7):763-780
The Maoduan Pb–Zn–Mo deposit is in hydrothermal veins with a pyrrhotite stage followed by a molybdenite and base metal stage. The Re–Os model ages of five molybdenite samples range from 138.6 ± 2.0 to 140.0 ± 1.9 Ma. Their isochron age is 137.7 ± 2.7 Ma. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb dating of the nearby exposed Linggen granite porphyry gave a 206Pb/238U age of 152.2 ± 2.2 Ma and the hidden Maoduan monzogranite yielded a mean of 140.0 ± 1.6 Ma. These results suggest that the intrusion of the Maoduan monzogranite and Pb–Zn–Mo mineralization are contemporaneous. δ 34S values of sulfide minerals range from 3.4‰ to 4.8‰, similar to magmatic sulfur. Four sulfide samples have 206Pb/204Pb = 18.252–18.432, 207Pb/204Pb = 15.609–15.779, and 208Pb/204Pb = 38.640–39.431, similar to the age-corrected data of the Maoduan monzogranite. These isotope data support a genetic relationship between the Pb–Zn–Mo mineralization and the Maoduan monzogranite and probably indicate a common deep source. The Maoduan monzogranite has geochemical features similar to highly fractionated I-type granites, such as high SiO2 (73.7–75.2 wt.%) and alkalis (K2O + Na2O = 7.8–8.9 wt.%) and low FeOt (0.8–1.3 wt.%), MgO (~0.3 wt.%), P2O5 (~0.03 wt.%), and TiO2 (~0.2 wt.%). The granitic rocks are enriched in Rb, Th, and U but depleted in Ba, Sr, Nb, Ta, P, and Ti. REE patterns are characterized by marked negative Eu anomalies (Eu/Eu* = 0.2–0.4). The Maoduan monzogranite, having (87Sr/86Sr) t = 0.7169 to 0.7170 and εNd(t) = −13.8 to −13.7, was probably derived from mixing of partial melts from enriched mantle and the Paleoproterozoic Badu group in an extensional tectonic setting. 相似文献
19.
对土壤中的银、硼、锡测定通常用光谱法,以焦硫酸钾、氟化钠、三氧化二铝和碳粉为缓冲剂,改善各元素的蒸发行为,采用较短的摄谱时间,大大降低光谱背景,以锗作为内标元素,实现了试样中银、硼、锡的同时定量测定,方法应用于岩石、土壤等地质样品测试中并取得了满意的结果。 相似文献
20.