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1.
The effect of land reclamation on the migration and accumulation of heavy metals and some pollutants in small rivers is determined. The study was conducted in the Middle Amur lowland in different phases of hydrological regime and at different extent of floodplain inundation. The formation of the hydrological regime in small rivers in this area is governed by the irregular annual runoff distribution. The seasonal character of flood periods requires water samples to be taken before spring flood (April) and after floods have passed (September–October), and at various extent of floodplain inundation. The field studies of water-courses were carried out in 2009–2014. The water samples were analyzed to determine the concentrations of heavy metals (iron, manganese, copper, nickel, cobalt, lead and zinc), suspended substances, organic carbon (total, dissolved, and suspended), humic and fulvic acids, and volatile organic compounds. The mobility of heavy metals in surface watercourses was shown to reflect the effect of drainage and surface runoff from soil horizons, an increase in the concentrations of suspended and organic compounds, especially, fulvic acids, which enhance their geochemical mobility. During floods, an increase in heavy metals washout from floodplain soils and the dilution of their concentrations causes the formation of a single-type concentration series of heavy metals. In addition, the processes of pollutants migration show an effect of changes in the geomorphological characteristics of floodplain–channel complexes and a decrease in flow velocity in watercourses in the areas where land reclamation was applied. Thus, all factors mentioned above lead to a decrease in water pollution index in the river.  相似文献   

2.
Frequent heavy rainfalls during the East Asian summer monsoon drastically increase water flow and chemical loadings to surface waters. A solid understanding of hydroclimatic controls on watershed biogeochemical processes is crucial for water quality control during the monsoon period. We investigated spatio‐temporal variations in the concentrations and spectroscopic properties of dissolved organic matter (DOM) and the concentrations of trace metals in Hwangryong River, Korea, during a summer period from the relatively dry month of June through the following months with heavy rainfall. DOM and its spectroscopic properties differed spatially along the river, and also depended on storm and flow characteristics around each sampling time. At a headwater stream draining a forested watershed, the concentrations (measured as dissolved organic carbon (DOC)), aromaticity (measured as specific UV absorbance at 254 nm), and fulvic acid‐ and protein‐like fluorescence of DOM were higher in stormflow than in baseflow waters. DOC concentrations and fluorescence intensities increased along the downstream rural and urban sites, in which DOC and fluorescence were not higher in stormflow waters, except for the ‘first flush’ at the urban site. The response of DOM in reservoir waters to monsoon rainfalls differed from that of stream and river waters, as illustrated by storm‐induced increases in DOM aromaticity and fulvic‐like fluorescence, and no significant changes in protein‐like fluorescence. The results suggest that surface water DOM and its spectroscopic properties differentially respond to changes in hydroclimatic conditions, depending on watershed characteristics and the influence of anthropogenic organic matter loadings. DOC concentrations and intensities of spectroscopic parameters were positively correlated with some of the measured trace metals (As, Co, and Fe). Further research will be needed to obtain a better understanding of climate effects on the interaction between DOM and trace metals. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

3.
The Salt-water River watershed is one of the major river watersheds in the Kaohsiung City, Taiwan. Water quality and sediment investigation results show that the river water contained high concentrations of organics and ammonia-nitrogen, and sediments contained high concentrations of heavy metals and organic contaminants. The main pollution sources were municipal and industrial wastewaters. Results from the enrichment factor (EF) and geo-accumulation index (Igeo) analyses imply that the sediments can be characterized as heavily polluted in regard to Cd, Cr, Pb, Zn, and Cu. The water quality analysis simulation program (WASP) model was applied for water quality evaluation and carrying capacity calculation. Modeling results show that the daily pollutant inputs were much higher than the calculated carrying capacity (1050 kg day(-1) for biochemical oxygen demand and 420 kg day(-1) for ammonia-nitrogen). The proposed watershed management strategies included river water dilution, intercepting sewer system construction and sediment dredging.  相似文献   

4.
Concentrations of ten metals were measured in waters and sediments at 14 sites during four sampling periods (1996–1997). These sites include various marine ecosystems that are highly influenced by industry, tourism and river discharges, nine of which are within the Morrocoy National Park. Spatially, metal concentrations in water were homogenous, whereas in sediments their distributions were related to grain size. Maximum concentrations of cadmium (Cd) and mean concentrations of copper (Cu), nickel (Ni), lead (Pb) and zinc (Zn) in water were above the guideline values proposed by NOAA, indicating the potential of these metals for producing chronic effects in marine biota. Sheltered sites showed the highest metal concentrations in sediments; with Cd and Zn above these guidelines. Enrichment factors and geo-accumulation indexes suggested that metals in sediments were largely of natural origin except for Pb, Cd and vanadium (V), which were apparently associated with industrial effluents. A disruption of the spatial distribution of metals after heavy rainfall, when exposed sites reached concentrations as high as those in sheltered sites, showed the influence of nearby rivers. The potential increase of such climatic events could represent additional stress for natural protected areas in the Caribbean.  相似文献   

5.
天津中心城区河网氮磷污染与富营养化特征   总被引：1，自引：0，他引：1  
2013年底天津中心城区河道全部连通,形成中心城区河网.为了掌握河网形成后的水质状况,于2014年3月-2015年2月进行了为期1年的定点水质监测,并对其水体氮、磷时空分布及富营养化特征进行分析.结果表明,河网水体氮污染严重,以铵态氮(NH+4-N)为主;磷污染程度较轻,主要形态为磷酸盐(PO3-4-P);河网水体中氮、磷浓度顺水流方向均呈上游高、下游低的空间分布特征;氮、磷各项指标浓度时间变化趋势基本一致,3月均最高,10月均最低,冬季处于相对较低水平;与河网形成前相比,海河干流NH+4-N、总磷(TP)和PO3-4-P浓度年平均值分别下降6.5%、14.7%和16.4%,津河总氮、NH+4-N、硝态氮、TP和PO3-4-P浓度年平均值分别降低18.6%、34.5%、12.9%、31.6%和32.5%,表明河网形成后氮、磷污染程度较之前有所改善,其中津河改善较为明显;河网水体全年处于中度富营养状态,主要为磷限制性状态;河网富营养化防治应遵循以控制营养盐为主的控源、截污、水环境增容和生态补水策略.  相似文献   

6.
Interaction between groundwater and surface water in watersheds has significant impacts on water management and water rights, nutrient loading from aquifers to streams, and in‐stream flow requirements for aquatic species. Of particular importance are the spatial patterns of these interactions. This study explores the spatio‐temporal patterns of groundwater discharge to a river system in a semi‐arid region, with methods applied to the Sprague River Watershed (4100 km2) within the Upper Klamath Basin in Oregon, USA. Patterns of groundwater–surface water interaction are explored throughout the watershed during the 1970–2003 time period using a coupled SWAT‐MODFLOW model tested against streamflow, groundwater level and field‐estimated reach‐specific groundwater discharge rates. Daily time steps and coupling are used, with groundwater discharge rates calculated for each model computational point along the stream. Model results also are averaged by month and by year to determine seasonal and decadal trends in groundwater discharge rates. Results show high spatial variability in groundwater discharge, with several locations showing no groundwater/surface water interaction. Average annual groundwater discharge is 20.5 m3/s, with maximum and minimum rates occurring in September–October and March–April, respectively. Annual average rates increase by approximately 0.02 m3/s per year over the 34‐year period, negligible compared with the average annual rate, although 70% of the stream network experiences an increase in groundwater discharge rate between 1970 and 2003. Results can assist with water management, identifying potential locations of heavy nutrient mass loading from the aquifer to streams and ecological assessment and planning focused on locations of high groundwater discharge. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

7.
Suspended sediment adsorbs pollutants from flowing water in rivers and deposits onto the bed. However, the pollutants accumulated in the river bed sediment may affect the bio-community through food chain for a long period of time. To study the problem the concentration of heavy metals （Cr, Cd, Hg, Cu, Fe, Zn, Pb and As） in water, sediment, and fish/invertebrate were investigated in the middle and lower reaches of the Yangtze River during 2006-2007. The concentrations of heavy metals were 100-10,000 times higher in the sediment than in the water. Benthic invertebrates had relatively high concentrations of heavy metals in their tissues due to their proximity to contaminated sediments. Benthic invertivore fish had moderately high concentrations of heavy metals whereas phytoplanktivore fish, such as the silver carp, accumulated the lowest concentration of heavy metals. The concentrations of Cu, Zn, and Fe were higher than Hg, Pb, Cd, Cr, and As in the tissue samples. The concentration of heavy metals was lower in the river sediments than in the lake sediments. Conversely, the concentration of heavy metals was higher in river water than in lake water. While a pollution event into a water body is often transitory, the effects of the pollutants may be long-lived due to their tendency to be absorbed in the sediments and then released into the food chain. The heavy metals were concentrated in the following order： bottom material 〉 demersal fish and benthic fauna 〉 middle-lower layer fish 〉 upper-middle layer fish 〉 water.  相似文献   

8.
The natural and anthropogenic sources of iron, copper, and zinc in water streams in the Republic of Bashkortostan are considered. Statistical analysis of long-term hydrochemical monitoring data was used to establish the spatial year-to-year and annual regularities in metal concentrations in water streams. The acceptability of river water quality for different types of water use was estimated. The exceedance probabilities of metal MAC values in streams were evaluated.  相似文献   

9.
《Marine pollution bulletin》2012,64(5-12):528-534
The Salt-water River watershed is one of the major river watersheds in the Kaohsiung City, Taiwan. Water quality and sediment investigation results show that the river water contained high concentrations of organics and ammonia–nitrogen, and sediments contained high concentrations of heavy metals and organic contaminants. The main pollution sources were municipal and industrial wastewaters. Results from the enrichment factor (EF) and geo-accumulation index (Igeo) analyses imply that the sediments can be characterized as heavily polluted in regard to Cd, Cr, Pb, Zn, and Cu. The water quality analysis simulation program (WASP) model was applied for water quality evaluation and carrying capacity calculation. Modeling results show that the daily pollutant inputs were much higher than the calculated carrying capacity (1050 kg day−1 for biochemical oxygen demand and 420 kg day−1 for ammonia–nitrogen). The proposed watershed management strategies included river water dilution, intercepting sewer system construction and sediment dredging.  相似文献   

10.
ABSTRACT

With the rapid economic development and urbanization in Taihu Basin (eastern China), the river system has decayed and the connectivity of rivers and lakes has weakened, resulting in frequent floods. The impact of changes in river system structure on hydrological processes in the plain river network area was analysed against a background of urbanization. An indicator system was built to describe the quantitative, morphological and spatial structure of the river system. Analysis of the change in annual average and extreme water levels revealed the influencing mechanism of the changes in river system structure on the hydrological processes. The results indicate a decreasing tendency in the density of the river system in the study area, with a reduction in water surface ratio by about 20% in the past 50 years. Since the 1960s, the maximum and annual average water levels have increased. The degree of change in the mean monthly, annual lowest and annual highest water levels was great, with that in the non-flood season being higher than in the flood season. The decrease in the number of rivers directly reduced the storage and adjustable capacity of the basin.  相似文献   

11.
The presence of metals, including manganese (Mn) and iron (Fe), adversely impacts water quality. In seasonally stratified reservoirs, Mn and Fe can accumulate in the water column due to reducing conditions in sediments and be released to downstream rivers through dam discharge. In addition to reservoir stratification influences, the release of metals downstream is influenced by hydrologic conditions in the river. We examined the seasonal and spatial variability of Mn and Fe concentrations in a eutrophic, hydropower reservoir and the downstream river over a two‐year period. Overall, we found that reservoir stratification was a strong predictor of tailrace Mn and Fe concentrations but that tailrace Fe concentrations were also influenced by dam discharge. Downgradient of the tailrace, river discharge and suspended sediment were the dominant predictors of both Mn and Fe concentrations. Using our data, we develop a conceptual model of seasonal and hydrologic drivers of metal concentrations. The model can be modified for other systems aiding drinking water utilities and other water users in forecasting under what seasonal and hydrologic conditions that Mn and Fe concentrations in river systems are likely to be elevated.  相似文献   

12.
The closed-form analytical stormwater quality models are developed for simulating urban catchment pollutant buildup and washoff processes. By integrating the rainfall–runoff transformation with pollutant buildup and washoff functions, stormwater quality measures, such as the cumulative distribution functions (CDFs) of pollutant loads, the expected value of pollutant event mean concentrations (EMCs) and the average annual pollutant load can be derived. This paper presents methodologies and major procedures for the development of urban stormwater quality models based on derived probability distribution theory. In order to investigate the spatial variation in model parameters and its impact on stormwater pollutant buildup and washoff processes as well as pollutant loads to receiving waters, an extended form of the original rainfall–runoff transformation which is based on lumped runoff coefficient approach is proposed to differentiate runoff generation mechanisms between the impervious and pervious areas of the catchment. In addition, as a contrast to the aggregated pollutant buildup models formulated with a single lumped buildup parameter, the disaggregated form of the pollutant buildup model is proposed by introducing a number of physically-based parameters associated with pollutant buildup and washoff processes into the pollutant load models. The results from the case study indicate that analytical urban stormwater management model are capable of providing results in good agreement with the field measurements, and can be employed as alternatives to continuous simulation models in the evaluation of long-term stormwater quality measures.  相似文献   

13.
流域场镇式发展是三峡地区城乡统筹发展的重要模式,通常形成河流两岸串珠状的场镇分布格局,这种人类活动的点状聚集特征对入库河流水环境的综合影响并不清楚.选择三峡库区流域场镇发展特征明显的黑水滩河及主要支流为研究对象,于2014年9月至2015年6月期间对流域内分布的主要场镇前后的水体进行碳、氮、磷浓度的监测分析,探讨场镇分布对流域水体生源要素时空格局的影响.研究结果表明,黑水滩河干、支流水体总有机碳(TOC)和溶解性有机碳浓度为4.5~39.2和3.2~31.4 mg/L,总氮(TN)、铵态氮和硝态氮浓度范围为1.12~6.96、0.87~5.00和0.073~0.881 mg/L,总磷(TP)、溶解性总磷和正磷酸盐浓度范围为0.078~0.454、0.049~0.310和0.025~0.222 mg/L,不同形态的碳、氮、磷含量变化幅度较大;黑水滩河干、支流流经不同场镇区前后,水体各形态碳、氮、磷浓度均不同程度增加(其中TOC、TN和TP的增幅范围分别为4.7%~61.3%、26.7%~144.7%和12.8%~50.7%),而在无场镇分布的干流河段,水体碳浓度变化不大,氮、磷浓度明显降低,表明水体生源要素的空间变异特征受到流域场镇分布格局与河流自净能力的双重影响,导致黑水滩河干流自上游向下游碳浓度呈“阶梯式”增长,氮、磷浓度呈“波动式”增长;相关分析显示,流域水体碳、氮、磷浓度均呈极显著的正相关关系,即场镇发展模式下河流水体污染物呈同步变化的趋势,表明山地河流流域内串珠状场镇发展模式导致从上游向下游水体污染物呈明显的累积效应,并进一步超出水体自净能力,造成下游水体恶化.河流碳、氮、磷浓度的季节变化主要受径流稀释作用影响,表现为夏秋季低、春季高的模式;富营养化综合指数表明,黑水滩河各监测断面全年属于富营养状态以上,表层水体氮污染严重,磷污染较轻;初步估算黑水滩河每年向三峡水库输入TOC、TN、TP通量达4057、1001和47 t,对三峡水库水环境安全具有严重威胁.三峡库区沿河串珠状场镇式发展形成了一种“点面”双重特征的污染模式,未来河流水环境污染防控中应予以关注.  相似文献   

14.
The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.  相似文献   

15.
The surface water and groundwater are important components of water cycle, and the interaction between surface water and groundwater is the important part in water cycle research. As the effective tracers in water cycle research, environmental isotope and hydrochemistry can reveal the interrelationships between surface water and groundwater effectively. The study area is the Huaisha River basin, which is located in Huairou district, Beijing. The field surveying and sampling for spring, river and well water were finished in 2002 and 2003. The hydrogen and oxygen isotopes and water quality were measured at the laboratory. The spatial characteristics in isotope and evolution of water quality along river lines at the different area were analyzed. The altitude effect of oxygen isotope in springs was revealed, and then using this equation, theory foundation for deducing recharge source of spring was estimated. By applying the mass balance method, the annual mean groundwater recharge rate at the catchment was estimated. Based on the groundwater recharge analysis, combining the hydrogeological condition analysis, and comparing the rainfall-runoff coefficients from the 1960s to 1990s in the Huaisha River basin and those in the Chaobai River basin, part of the runoff in the Huaisha River basin is recharged outside of this basin, in other words, this basin is an un-enclosed basin. On the basis of synthetically analyses, combining the compositions of hydrogen and oxygen isotopes and hydrochemistry, geomorphology, geology, and watershed systems characteristics, the relative contributions between surface water and groundwater flow at the different areas at the catchments were evaluated, and the interaction between surface water and groundwater was re- vealed lastly.  相似文献   

16.
The Odra river flood of 1997 was a rare hydrological as well as an interesting sedimentological event. At Hohenwutzen (Lower Odra River) we observed the suspended particulate matter transport and the temporal development of water and solidsπ pollution with heavy metals and As. While the suspended particulate matter concentration decreased the trace element concentrations increased during the flood by fractionation of particles and solution processes. Because of a successive flooding of differently contaminated sedimentary sources and polluted regions the contents of heavy metals developed irregularly. Their median particulate concentrations did not exceed the values of older samples taken under mean discharge conditions between 1989 and 1995. The dissolved amounts correspond to those of the Elbe river in 1990. During the flood the dissolved share of all analyzed total element contents increased. The total loads increased 4fold (Cr) to 17fold (Cd).  相似文献   

17.
In contrast with biological processes in lacustrine environments, the physical characteristics of river waters greatly complicate the relationship between nutrient input and primary productivity. In this paper a new approach to quantify this relationship is developed, linking land use within the watershed to the bioavailability of nutrients in the receiving waters. It estimates by two different ways an enrichment index derived from N/P ratios. A load model links land-use within the watershed area to nutrient export, and allows the estimation of the potential enrichment index from the ratio of calculated annual exports of nitrogen and phosphorus. This index value correlates well with the real enrichment index representing the annual mean value of the corresponding measured ratios in running waters. The latter index can then be related to nutrient availability expressed by chl-a and the algal growth potential. This model, established from 7 sampling stations on the Yamaska-North river, allowed assessment of nutrient bioavailability in the river water as a function of hydrological (low or high water flow) as well as of seasonal (summer or winter) events.  相似文献   

18.
Norman E. Peters 《水文研究》2009,23(20):2860-2878
A long‐term stream water quality monitoring network was established in the city of Atlanta, Georgia during 2003 to assess baseline water quality conditions and the effects of urbanization on stream water quality. Routine hydrologically based manual stream sampling, including several concurrent manual point and equal width increment sampling, was conducted ～12 times annually at 21 stations, with drainage areas ranging from 3·7 to 232 km2. Eleven of the stations are real‐time (RT) stations having continuous measures of stream stage/discharge, pH, dissolved oxygen, specific conductance, water temperature and turbidity, and automatic samplers for stormwater collection. Samples were analyzed for field parameters, and a broad suite of water quality and sediment‐related constituents. Field parameters and concentrations of major ions, metals, nutrient species and coliform bacteria among stations were evaluated and with respect to watershed characteristics and plausible sources from 2003 through September 2007. Most constituent concentrations are much higher than nearby reference streams. Concentrations are statistically different among stations for several constituents, despite high variability both within and among stations. Routine manual sampling, automatic sampling during stormflows and RT water quality monitoring provided sufficient information about urban stream water quality variability to evaluate causes of water quality differences among streams. Fecal coliform bacteria concentrations of most samples exceeded Georgia's water quality standard for any water‐usage class. High chloride concentrations occur at three stations and are hypothesized to be associated with discharges of chlorinated combined sewer overflows, drainage of swimming pool(s) and dissolution and transport during rainstorms of CaCl2, a deicing salt applied to roads during winter storms. One stream was affected by dissolution and transport of ammonium alum [NH4Al(SO4)2] from an alum‐manufacturing plant; streamwater has low pH (<5), low alkalinity and high metals concentrations. Several trace metals exceed acute and chronic water quality standards and high concentrations are attributed to washoff from impervious surfaces. Published in 2009 by John Wiley & Sons, Ltd.  相似文献   

19.
如何表达流域复杂的系统结构是实现流域信息与模型集成,构建流域决策支持系统需要研究的首要问题.在分析现有流域数据库存在问题的基础上,以太湖流域西南部的西苕溪流域为研究区,采用面向对象的Geodatabase地理数据技术,通过分析流域系统的组成要素及过程,提出面向流域水文、水质应用需求的数据库信息组织体系;应用Arcgis的Archydro水文分析模块,基于国家基础地理数据库中的数字地形提取流域要素信息,构建了包括河流流线、集水区出水口、监测台站位置、湖库出口等要素的完整水文网络,并分析水文网络要素上下游关系,对流域集水区与河流的水力联系进行表达;通过分析流域监测台站空间信息、监测项目、时间序列的信息特征,设计Geodatabase的表结构和连接类,实现流域空间特征与状态序列的一体化表达,研究可以为流域数据库建设及流域决策支持系统信息平台构建提供一些技术参考.  相似文献   

20.
白洋淀沉积物-沉水植物-水系统重金属污染分布特征   总被引：6，自引：1，他引：5  
通过对白洋淀沉水植物及对应沉积物和水中Cd、Pb、As含量测定,以期揭示白洋淀沉积物-沉水植物-水系统中重金属污染状况及分布规律,明确不同沉水植物对重金属的富集能力.结果表明,地表水Cd、Pb、As浓度均符合我国地表水I类水质标准,不同采样区重金属浓度差异不显著.上覆水Pb浓度显著高于地表水和间隙水,间隙水As浓度显著高于地表水和上覆水;地积累指数法和潜在生态危害指数法评价结果表明,沉积物中重金属污染程度表现为Cd > Pb > As,Cd污染最严重,达到"轻度-偏重度"污染程度,"中等-极强"生态危害级别,As为清洁水平,不同采样区重金属污染程度表现为生活水产养殖区 > 纳污区 > 淀边缘区;沉水植物重金属富集能力表现为金鱼藻（Ceratophyllum demersum L.） > 菹草（Potamogeton crispus L.）和穗状狐尾藻（Myriophyllum spicatum L.） > 篦齿眼子菜（Potamogeton pectinatus L.）.植物体内重金属含量与体内氮、磷含量呈显著正相关,氮、磷营养盐影响沉水植物对重金属的富集.  相似文献   

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