共查询到19条相似文献，搜索用时 250 毫秒
1.
In this paper a thermogravimetry-differential thermal analysis method coupled with chromatography （TG-DTA-GC） has been adopted to simulate the generation of gaseous hydrocarbons from different hydrocarbon source rocks such as coals, mudstones, and carbonate rocks with different maturities. The temperature programming for thermal simulation experiment is 20℃/min from ambient temperature to 700℃. As viewed from the quantities and composition of generated gaseous hydrocarbons at different temperatures, it is shown that low-mature coal has experienced the strongest exothermic reaction and the highest loss of weight in which the first exothermic peak is relatively low. Low-mature coal samples have stronger capability of generating gaseous hydrocarbons than high-mature samples. The amounts and composition of gaseous hydrocarbons generated are closely related not only to the abundance of organic carbon in source rocks, but also to the type of kerogen in the source rocks, and their thermal maturity. In the present highly mature and over-mature rock samples organic carbon, probably, has already been exhausted, so the production of gaseous hydrocarbons in large amounts is impossible. The contents of heavy components in gaseous hydrocarbons from the source rocks containing type- Ⅰ and - Ⅱ kerogens are generally high ; those of light components such as methane and ethane in gaseous hydrocarbons from the source rocks with Ⅲ-type kerogens are high as well. In the course of thermal simulation of carbonate rock samples, large amounts of gaseous hydrocarbons were produced in a high temperature range. 相似文献
2.
Christopher BAIYEGUNHI Kuiwu LIU Nicola WAGNER Oswald GWAVAVA Temitope L. OLONINIYI 《《地质学报》英文版》2018,92(3):1193-1217
Shale gas has been the exploration focus for future energy supply in South Africa in recent time. Specifically, the Permian black shales of the Prince Albert, Whitehill, Collingham, Ripon and Fort Brown Formations are considered to be most prospective rocks for shale gas exploration. In this study,outcrop and core samples from the Ecca Group were analyzed to assess their total organic carbon(TOC), organic matter type, thermal maturity and hydrocarbon generation potential. These rocks have TOC ranging from 0.11 to 7.35 wt%. The genetic potential values vary from 0.09 to 0.53 mg HC/g,suggesting poor hydrocarbon generative potential. Most of the samples have Hydrogen Index(HI) values of less than 50 mg HC/g TOC, thus suggesting Type-Ⅳ kerogen. Tmax values range from 318℃ to601℃, perhaps indicating immature to over-maturity of the samples. The vitrinite reflectance values range from 2.22% to 3.93%, indicating over-maturity of samples. Binary plots of HI against Oxygen Index(OI), and HI versus Tmax show that the shales are of Type II and mixed Type Ⅱ-Ⅲ kerogen.Based on the geochemical data, the potential source rocks are inferred as immature to over-matured and having present-day potential to produce gas. 相似文献
3.
LIAO Zewen GENG AnsongThe State Key Laboratory of Organic Geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou Guangdong 《《地质学报》英文版》2000,74(3):680-684
It is a special petroleum geological phenomenon that Silurian oilsands are extensively distributed in the central and northeast Tarim basin. Some geochemical studies of the oilsands have been carried out, but there is still great controversy over the hydrocarbon-regenerating potential of oilsands and the possibility of Silurian oilsands as hydrocarbon source rocks. In this study, the kinetics of asphaltenes pyrolysis was directly used to simulate the potential of Silurian oilsands for regenerating hydrocarbons. According to the experimental results, combined with other related organic geochemical analysis, it is considered that Silurian oilsands in the Tarim basin have a high hydrocarbon-regenerating potential and are latent hydrocarbon source rocks. 相似文献
4.
Based on thermal simulation experiment, interactions between volcanic fluids and source rocks were studied. Gas generations in the dry system and fluid system under different temperatures were analyzed. The results showed that the various types of source rocks are similar in composition, containing gaseous C1-C5 hydrocarbons, H2 and CO2 whose gas yields increase with increasing temperature. The gas yield of source rocks of type I is the high- est, followed by type II, and that of source rocks of type III is the lowest, indicating that the yield of hydrocarbon gases is related to their hydrocarbon generating potential. Although the generating potential of type III is the lowest, it can still be regarded as a useful gas source when it is buried deeply enough. The basic volcanic fluid restrains the generation of gaseous hydrocarbons in different types of source rocks, but promotes the generation of inorganic gases. 相似文献
5.
The geochemical characteristics and oil-source rock correlation of oilshow from the Majiashan profile,Chaoxian County,South of Anhui Province 总被引：1，自引：1，他引：0
TANG Youjun WEN Zhigang ZAN Ling 《中国地球化学学报》2008,27(1):53-57
In the future time the exploration of marine oil and gas will be one of the significant domains in China. In this paper the biomarker assemblage characteristics of oilshow in the Nanlinghu Formation of the Majiashan profile, which is located in Chaoxian County, south of Anhui Province, are described in the light of gas chromatography/mass spectrometric （GCMS） analysis on the qualitative and quantitative basis. Based on the investigation of the biomarker assemblage characteristics of possible source rocks developed in the area studied, a conclusion is drawn that the oilshow was generated from the Nanlinghu Formation source rocks （abbreviated as Tin）, instead of the Qixia Formation source rocks （abbreviated as P1q）. It is pointed out that the Tin is of strong potential for future oil exploration, and therefore much attention should be paid to it. 相似文献
6.
Field and laboratory analyses of carbonate rock samples from the Qiangtang Basin,Tibet, indicate that carbonate source rocks are mainly developed in the Middle Jurassic Xiali Formation and Upper Jurassic Suowa Formation. Comprehensive studies showed that the Suowa Formation carbonate source rocks have a favorable hydrocarbon-generating potential. The abundance of organic matter in the carbonate rocks is controlled mainly by sedimentary environment and inorganic compounds in the rocks, which is higher in the restricted platform facies than in the open platform facies. Organic carbon contents decrease with increasing CaO contents in the source rocks. 相似文献
7.
Organic petrology is a marginal science that is quite practicable. At present, it has developed into a routine research tool that is widely applied in petroleum exploration and assessment. Based on several years‘ research of the authors, this paper presents the advances in organic petrological studies on immature source rocks, including the classification and characteristics of macerals, the composition of macerals and types of organic matter, the abundance and evolution of organic matter, oil-prone macerals, hydrocarbon generation and expulsion. All these results show that organic petrology is of considerable value pertaining to its application in the assessment of immature oil and gas. The immature source rocks consist of various macerals with obvious heterogeneity, contain different hydrocarbon-generating macerals with different oil thresholds and oil peaks, and show a two-staged evolutionary pattern of organic matter. 相似文献
8.
Five major froms(lamellar,banded,crack-like,dissceminated and segregated encrustation(of organic matter distribution in sourc rocks have been revealed under scanning electron microscope by using the heavy metal staining technique.The degree of organic impregnation is related to the amount of liquied hydrocarbons in the rocks,and from this relationship a rough estimation of organic matter can be made on the basis of electron microscopic observations.In conjunction with experimental studies it has been found that the distribution forms of organic matter are a function of its maturity in the process of thermal evolution and accordingly some microscopic criteria can be developed for the assessment of source rocks. 相似文献
9.
Quantitative Assessment of Hydrocarbon Expulsion of Petroleum Systems in the Niuzhuang Sag, Bohai Bay Basin, East China 总被引：1，自引：1，他引：0
PANG Xiongqi LI Sumei JIN Zhijun BAI Guoping Key Laboratory of Hydrocarbon Accumulation Ministry of Education Beijing E-mail: pangxq@bjpeu.edu.cnBasin & Reservoir Research Center University of Petroleum Beijing Sinopec Petroleum Exploration Exploitation Institute Beijing 《《地质学报》英文版》2004,78(3):615-625
Based on a detailed survey of the distribution and organic geochemical characteristics of potential source rocks in the South Slope of the Niuzhuang Sag, Bohai Bay Basin, eastern China, a new approach to assess the amount of hydrocarbons generated and expelled has been developed. The approach is applicable to evaluate hydrocarbons with different genetic mechanisms. The results show that the models for hydrocarbon generation and expulsion vary with potential source rocks, depending on thermal maturity, types of organic matter and paleoenvironment. Hydrocarbons are mostly generated and expelled from source rocks within the normal oil window. It was calculated that the special interval (algal-rich shales of the ES4 member formed in brackish environments) in 相似文献
10.
The geochemical characteristics and origin of crude oils in the Kekeya Oilfield,Xinjiang, China 总被引：2，自引：2，他引：0
GC/MS and GC/MS/MS techniques were employed to describe the characteristics of biomarker assemblages in two sets of hydrocarbon source rocks, Jurassic and Permian, in southwestern Tarim, and the parameters for the classification of the two sets of hydrocarbon source rocks have been established. It is found that diahopane and C30-unknown terpane are abundant in Permian samples, the contents of diahopane in Jurassic samples are relatively low, and terpenoids have been detected in Jurassic samples but not in Permian source rock samples. Kekeya crude oils are abundant in diahopane and C30-unknown terpane. The results of fine oil-rock correlation indicated that Kekeya crude oils were derived mainly from the Permian hydrocarbon source rocks. However, a small amount of diterpenoid was detected in the crude oils, indicating that the Jurassic hydrocarbon source rocks also made a certain contribution to Kekeya crude oils. 相似文献
11.
《International Geology Review》2012,54(13):1508-1521
Twenty Cretaceous shale samples from two wells in the Orange Basin of South Africa were evaluated for their source rock potential. They were sampled from within a 1400 m-thick sequence in boreholes drilled through Lower to Upper Cretaceous sediments. The samples exhibit total organic carbon (TOC) content of 1.06–2.17%; Rock-Eval S2 values of 0.08–2.27 mg HC/g; and petroleum source potential (SP), which is the sum of S1 and S2, of 0.10–2.61 mg HC/g, all indicating the presence of poor to fair hydrocarbon generative potential. Hydrogen index (HI) values vary from 7 to 128 mg HC/g organic carbon and oxygen index (OI) ranges from 37 to 195 mg CO2/g organic carbon, indicating predominantly Type III kerogen with perhaps minor amounts of Type IV kerogen. The maturity of the samples, as indicated by T max values of 428–446°C, ranges from immature to thermally mature with respect to oil generation. Measured vitrinite reflectance values (%Ro) of representative samples indicate that these samples vary from immature to mature, consistent with the thermal alteration index (TAI) (spore colour) and fluorescence data for these samples. Organic petrographic analysis also shows that amorphous organic matter is dominant in these samples. Framboidal pyrite is abundant and may be indicative of a marine influence during deposition. Although our Rock-Eval pyrolysis data indicate that gas-prone source rocks are prevalent in this part of the Orange Basin, the geochemical characteristics of samples from an Aptian unit at 3318 m in one of the wells suggest that better quality source rocks may exist deeper, in more distal depositional parts of the basin. 相似文献
12.
大杨树盆地中部甘河地区嫩江组烃源岩生烃潜力分析 总被引：1，自引：0，他引：1
通过岩石热解、总有机碳、镜质体反射率、饱和烃气相色谱-质谱等测试方法,系统分析大杨树盆地中部甘河地区嫩江组烃源岩有机地球化学、生物标志化合物特征,评价其生烃潜力。结果表明,大杨树盆地中部甘河地区嫩江组暗色泥岩有机质丰度较高,属于中等-好烃源岩,有机质类型主要为Ⅱ型干酪根,处于成熟阶段,是一套好的烃源岩。烃源岩形成于还原性的淡-微咸水的水体沉积环境中,有机质来源为混合来源,且以陆生高等植物来源贡献较大。总体显示大杨树盆地中部甘河地区嫩江组烃源岩具有一定的生烃潜力。 相似文献
13.
以往对鄂尔多斯盆地南部地区长7油层组(简称长7)中烃源岩生烃潜力的研究主要是采用静态地球化学指标进行的,目前尚无对生烃动态特征的系统评价,因而制约了对长7烃源岩生烃潜力和页岩油资源分布有利岩性的客观认识。为此,选取长7不同类型的烃源岩样品,通过开放和封闭热模拟实验,对比分析了不同类型烃源岩的动力学参数、生烃产物、产率特征及生烃演化规律。结果表明:(1)黑色页岩活化能分布范围比暗色泥岩更为集中,且主频活化能和频率因子均低于暗色泥岩,体现了快速生烃的特性;(2)在外推到地质条件下,黑色页岩主要生烃期对应的Ro值(0.70%~0.87%)低于暗色泥岩(1.06%~1.72%),且以生油为主;(3)Ro在0.9%~1.3%范围内,黑色页岩的总烃产率高于暗色泥岩,生油量高于暗色泥岩。结合研究区两类烃源岩的地球化学资料综合分析表明,黑色页岩是研究区页岩油资源形成与分布的有利烃源岩。 相似文献
14.
Omeid Rahmani Jafar Aali Radzuan Junin Hassan Mohseni Eswaran Padmanabhan Amin Azdarpour Sahar Zarza Mohsen Moayyed Parviz Ghazanfari 《International Journal of Earth Sciences》2013,102(5):1337-1355
The origin of the oil in Barremian–Hauterivian and Albian age source rock samples from two oil wells (SPO-2 and SPO-3) in the South Pars oil field has been investigated by analyzing the quantity of total organic carbon (TOC) and thermal maturity of organic matter (OM). The source rocks were found in the interval 1,000–1,044 m for the Kazhdumi Formation (Albian) and 1,157–1,230 m for the Gadvan Formation (Barremian–Hauterivian). Elemental analysis was carried out on 36 samples from the source rock candidates (Gadvan and Kazhdumi formations) of the Cretaceous succession of the South Pars Oil Layer (SPOL). This analysis indicated that the OM of the Barremian–Hauterivian and Albian samples in the SPOL was composed of kerogen Types II and II–III, respectively. The average TOC of analyzed samples is less than 1 wt%, suggesting that the Cretaceous source rocks are poor hydrocarbon (HC) producers. Thermal maturity and Ro values revealed that more than 90 % of oil samples are immature. The source of the analyzed samples taken from Gadvan and Kazhdumi formations most likely contained a content high in mixed plant and marine algal OM deposited under oxic to suboxic bottom water conditions. The Pristane/nC17 versus Phytane/nC18 diagram showed Type II–III kerogen of mixture environments for source rock samples from the SPOL. Burial history modeling indicates that at the end of the Cretaceous time, pre-Permian sediments remained immature in the Qatar Arch. Therefore, lateral migration of HC from the nearby Cretaceous source rock kitchens toward the north and south of the Qatar Arch is the most probable origin for the significant oils in the SPOL. 相似文献
15.
马朗凹陷低熟页岩油地球化学特征及成烃机理 总被引：1，自引：0，他引：1
勘探实践和研究表明,马朗凹陷二叠系芦草沟组源内油气为页岩油,该原油C29甾烷立体异构化参数w(20S)/w(20S+20R)、w(ββ)/w(αα+ββ)均为0.2~0.4,为典型低熟原油。通过对芦草沟组烃源岩地球化学和有机岩石学特征的综合研究,发现低熟页岩油的生烃母质为原生的富氢无定形体,这些无定形体在沉积早期经历过细菌的改造作用,致使其具有特殊的生烃演化模式,即低熟-成熟阶段早期（Ro为0.55%~0.75%）处于生油高峰,对应埋深为1 800~2 900 m,埋深大于或小于该主峰带,烃源岩生烃能力急剧降低。泥岩生烃模拟实验、热解、抽提等实验数据表明:芦草沟组低熟页岩油正是位于该主生带的源岩所生,处于生烃带的源岩区即为马朗凹陷低熟页岩油富集的有利地区。 相似文献
16.
Dhaou AKROUT Hassène AFFOURI Riadh AHMADI Eric MERCIER Mabrouk MONTACER 《Resource Geology》2011,61(3):270-280
This paper presents geochemical analysis of drilled cutting samples from the OMZ‐2 oil well located in southern Tunisia. A total of 35 drill‐cutting samples were analyzed for Rock‐Eval pyrolysis, total organic carbon (TOC), bitumens extraction and liquid chromatography. Most of the Ordovician, Silurian and Triassic samples contained high TOC contents, ranging from 1.00 to 4.75% with an average value of 2.07%. The amount of hydrocarbon yield (pyrolysable hydrocarbon: S2b) expelled during pyrolysis indicates a good generative potential of the source rocks. The plot of TOC versus S2b, indicates a good to very good generative potential for organic matter in the Ordovician, Silurian and Lower Triassic. However, the Upper Triassic and the Lower Jurassic samples indicate fair to good generative potential. From the Vankrevelen diagram, the organic matter in the Ordovician, Silurian and Lower Triassic samples is mainly of type II kerogen and the organic matter from the Upper Triassic and the Lower Jurassic is dominantly type III kerogen with minor contributions from Type I. The thermal maturity of the organic matter in the analyzed samples is also evaluated based on the Tmax of the S2b peak. The Ordovician and Lower Silurian formations are thermally matured. The Upper Silurian and Triassic deposits are early matured to matured. However, Jurassic formations are low in thermal maturity. The total bitumen extracts increase with depth from the interval 1800–3000 m. This enrichment indicates that the trapping in situ in the source rocks and relatively short distance vertical migration can be envisaged in the overlying reservoirs. During the vertical migration from source rocks to the reservoirs, these hydrocarbons are probably affected by natural choromatography and in lower proportion by biodegradation. 相似文献
17.
准噶尔盆地陆东-五彩湾地区石炭系具有良好的勘探前景,该地区石炭系烃源岩有机质丰度较高,成熟度范围宽,主要处于成熟-高成熟演化阶段,主要由Ⅲ型有机质组成。在对烃源岩样品进行常规评价的基础上,用开放体系进行了热解实验和动力学模拟,对陆东-五彩湾地区的生烃特征进行了研究,尝试了高成熟烃源岩生烃过程研究及Ⅲ型干酪根液态烃排烃时间的估计,并对石炭系地层产烃率进行了计算。结果显示,陆东-五彩湾地区石炭系最早在二叠纪（距今264 Ma左右）开始生烃,后期由于地层抬升,在古近纪早期（距今61 Ma左右）结束生烃。下石炭统产烃率大,液态烃排出时间估计在距今232~196 Ma之间;上石炭统产烃率较小,液态烃排出时间估计在距今196~178 Ma 之间,但天然气生成相对较晚,有利于天然气的保存。天然气可能主要来源于上石炭统烃源岩。 相似文献
18.
陆相低成熟烃源岩有机硫与热解成烃动力学关系初探 总被引：5，自引：0，他引：5
对陆相低成熟烃源岩（Ro≤ 0.5 %）有机硫与成烃动力学关系进行了研究。结果表明:①有机硫含量与镜质体反射率（Ro）之间呈负相关关系,即有机硫含量随成熟度提高而减少;②源岩的平均活化能（E）有随有机硫含量增大而减小的趋势;③有机硫含量与源岩活化能分布最小值（Emin）和经可溶有机质抽提后的活化能分布最小值（Emin）之间存在正相关关系;④活化能分布范围Emin～ESEmin（ESEmin＞Emin）内的可溶有机质生烃能力与有机硫含量具有一定的相关性;⑤综上结果推断东营凹陷南斜坡东段沙四段（Es4）源岩中的有机硫在成烃过程中可能起到了一定的作用。 相似文献
19.
“未熟油”与“未熟生烃”异议 总被引：16，自引：1，他引：15
有关专家认为,“未熟生烃”是我国新生代盆地广泛存在的地球化学现象,本文剖析了这一论点背后隐含的矛盾,并以苏北盆地部分断陷中存在的“不等深等温”“不等深等熟”,成熟度指标与埋深关系的“平行变浅”分布等资料为依据,提出此现象当源于“古大于今”埋深史这一特定地质背景（或称为退化受热史）若以恢复的最大古埋深重新勾画产经曲线,所谓“低温早熟”现象即可消除,既然未熟生烃现象不存在,也就不存在未熟的石油,同时指 相似文献