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1.
A scheme of excitation, quenching, and energy transfer processes in the oxygen nightglow on the Earth, Venus, and Mars has been developed based on the observed nightglow intensities and vertical profiles, measured reaction rate coefficients, and photochemical models of the nighttime atmospheres of the Venus and Mars. The scheme involves improved radiative lifetimes of some band systems, calculated yields of the seven electronic states of O2 in termolecular association, and rate coefficients of seven processes of electronic quenching of the Herzberg states of O2, which are evaluated by fitting to the nightglow observations. Electronic quenching of the vibrationally excited Herzberg states by O2 and N2 in the Earth's nightglow is a quarter of total collisional removal of the O2(A, A′) states and a dominant branch for the O2(c) state. The scheme supports the conclusion by Steadman and Thrush (1994) that the green line is excited by energy transfer from the O2(A3Σu+, v≥6) molecules, and the inferred rate coefficient of this transfer is 1.5×10−11 cm3 s−1. The O2 bands at 762 nm and 1.27 μm are excited directly, by quenching of the Herzberg states, and by energy transfer from the O2(5Πg) state. Quenching of the O2 band at 762 nm excites the band at 1.27 μm as well. Effective yield of the O2(a1Δg) state in termolecular association on Venus and Mars is ∼0.7. Quantitative assessments of all these processes have been made. A possible reaction of O2(c1Σu−)+CO is a very minor branch of recombination of CO2 on Venus and Mars. Night airglow on Mars is calculated for typical conditions of the nighttime atmosphere. The calculated vertical intensity of the O2 band at 1.27 μm is 13 kR, far below the recently reported detections.  相似文献   

2.
Imaging spectrometers are highly effective instruments for investigation of planetary atmospheres. They present the advantage of coupling the compositional information to the spatial distribution, allowing simultaneous study of chemistry and dynamics in the atmospheres of Venus and Mars. In this work, we summarize recent results about the O2(a1Δg) night and day glows, respectively obtained by VIRTIS/Venus Express and OMEGA/Mars Express, the imaging spectrometers currently in orbit around Venus and Mars. The case of the O2(a1Δg - X3Σg−) IR emission at 1.27 μm on the night side of Venus and the day side of Mars is analyzed, pointing out dynamical aspects of these planets, like the detection of gravity waves in their atmospheres. The monitoring of seasonal and daily airglow variations provides hints about the photochemistry on these planets.  相似文献   

3.
Long-exposure spectroscopy of Mars and Venus with the Extreme Ultraviolet Explorer (EUVE) has revealed emissions of He 584 Å on both planets and He 537 Å/O+ 539 Å and He+ 304 Å on Venus. Our knowledge of the solar emission at 584 Å, eddy diffusion in Mars' upper atmosphere, electron energy distributions above Mars' ionopause, and hot oxygen densities in Mars' exosphere has been significantly improved since our analysis of the first EUVE observation of Mars [Krasnopolsky, Gladstone, 1996, Helium on Mars: EUVE and Phobos data and implications for Mars' evolution, J. Geophys. Res. 101, 15,765-15,772]. These new results and a more recent EUVE observation of Mars are the motivation for us to revisit the problem in this paper. We find that the abundance of helium in the upper atmosphere, where the main loss processes occur, is similar to that in the previous paper, though the mixing ratio in the lower and middle atmosphere is now better estimated at 10±6 ppm. Our estimate of the total loss of helium is almost unchanged at 8×1023 s−1, because a significant decrease in the loss by electron impact ionization above the ionopause is compensated by a higher loss in collisions with hot oxygen. We neglect the outgassing of helium produced by radioactive decay of U and Th because of the absence of current volcanism and a very low upper limit to the seepage of volcanic gases. The capture of solar wind α-particles is currently the only substantial source of helium on Mars, and its efficiency remains at 0.3. A similar analysis of EUV emissions from Venus results in a helium abundance in the upper atmosphere which is equal to the mean of the abundances measured previously with two optical and two mass spectrometers, and a derived helium mixing ratio in the middle and lower atmosphere of 9±6 ppm. Helium escape by ionization and sweeping out of helium ions by the solar wind above the ionopause is smaller than that calculated by Prather and McElroy [1983, Helium on Venus: implications for uranium and thorium, Science 220, 410-411] by a factor of 3. However, charge exchange of He+ ions with CO2 and N2 between the exobase and ionopause and collisions with hot oxygen ignored previously add to the total loss which appears to be at the level of 106 cm−2 s−1 predicted by Prather and McElroy [1983, Science 220, 410-411]. The loss of helium is compensated by outgassing of helium produced by radioactive decay of U and Th and by the capture of the solar wind α-particles with an efficiency of 0.1. We also compare our derived α-particle capture efficiencies for Mars and Venus with observed X-ray emissions resulting from the charge exchange of solar wind heavy ions with the extended atmospheres on both planets [Dennerl et al., 2002, Discovery of X-rays from Venus with Chandra, Astron. Astrophys. 386, 319-330; Dennerl, 2002, Discovery of X-rays from Mars with Chandra, Astron. Astrophys. 394, 1119-1128]. The emissions from both disk and halo on Mars agree with our calculated values; however, we do not see a reasonable explanation for the X-ray halo emission on Venus. The ratio of the charge exchange efficiencies derived from the disk X-ray emissions of Mars and Venus is similar to the ratio of the capture efficiencies for these planets. The surprisingly bright emission of He+ at 304 Å observed by EUVE and Venera 11 and 12 suggests that charge exchange in the flow of the solar wind α-particles around the ionopause is much stronger than in the flow of α-particles into the ionosphere.  相似文献   

4.
The excitation, energy transfer and quenching of O2 (A3 Σu+, C3 Δu, c1 Σu?) and O(1S) are discussed, taking into account laboratory measurements and observations on the airglow of the Earth, Venus and Mars. The excitation of O(1S) occurs by the Barth mechanism with O2(c) as a precursor: the rate coefficient is 2.5 × 10?12 cm3 s?1 for υ > 0 and 2.5 × 10?12 exp(?1100T) cm3 s?1for υ = 0. The O2(c) can be formed directly by recombination or by O2(A) and O2(C) colliding with other molecules; the O2(c) yield through quenching of these states is about 0.3 in air and about 1.0 in carbon dioxide. The rate coefficients of some processes that control the molecular oxygen bands and the atomic oxygen green line are estimated.  相似文献   

5.
We present absolute abundances and latitudinal variations of ozone and water in the atmosphere of Mars during its late northern spring (Ls=67.3°) shortly before aphelion. Long-slit maps of the a1Δg state of molecular oxygen (O2) and HDO, an isotopic form of water, were acquired on UT January 21.6 1997 using a high-resolution infrared spectrometer (CSHELL) at the NASA Infrared Telescope Facility. O2(a1Δg) is produced by ozone photolysis, and the ensuing dayglow emission at 1.27 μm is used as a tracer for ozone. Retrieved vertical column densities for ozone above ∼20 km ranged between 1.5 and 2.8 μm-atm at mid- to low latitudes (30°S-60°N) and decreased outside that region. A significant decrease in ozone density is seen near 30°N (close to the subsolar latitude of 23.5°N). The rotational temperatures retrieved from O2(a-X) emissions show a mean of 172±2.5 K, confirming that the sensed ozone lies in the middle atmosphere (∼24 km). The ν1 fundamental band of HDO near 3.67 μm was used as a proxy for H2O. The retrieved vertical column abundance of water varies from 3 precipitable microns (pr-μm) at ∼30°S to 24 pr-μm at ∼60°N. We compare these results with current photochemical models and with measurements obtained by other methods.  相似文献   

6.
The upper ionospheres of Mars and Venus are permeated by the magnetic fields induced by the solar wind. It is a long-standing question whether these fields can put the dense ionospheric plasma into motion. If so, the transterminator flow of the upper ionosphere could explain a significant part of the ion escape from the planets atmospheres. But it has been technically very challenging to measure the ion flow at energies below 20 eV. The only such measurements have been made by the ORPA instrument of the Pioneer Venus Orbiter reporting speeds of 1-5 km/s for O+ ions at Venus above 300 km altitude at the terminator ( [Knudsen et al., 1980] and [Knudsen et al., 1982]). At Venus the transterminator flow is sufficient to sustain a permanent nightside ionosphere, at Mars a nightside ionosphere is observed only sporadically. We here report on new measurements of the transterminator ion flow at Mars by the ASPERA-3 experiment on board Mars Express with support from the MARSIS radar experiment for some orbits with fortunate observation geometry. We observe a transterminator flow of O+ and O2+ ions with a super-sonic velocity of around 5 km/s and fluxes of 0.8×109/cm2 s. If we assume a symmetric flux around the terminator this corresponds to an ion flow of 3.1±0.5×1025/s half of which is expected to escape from the planet. This escape flux is significantly higher than previously observed on the tailside of Mars. A possible mechanism to generate this flux can be the ionospheric pressure gradient between dayside and nightside or momentum transfer from the solar wind via the induced magnetic field since the flow velocity is in the Alfvénic regime. We discuss the implication of these new observations for ion escape and possible extensions of the analysis to dayside observations which may allow us to infer the flow structure imposed by the induced magnetic field.  相似文献   

7.
Measurements of water vapor in the atmospheres of Venus or Mars by spectroscopic techniques in the infrared range are being made routinely by instruments onboard the Venus Express and the Mars Reconnaissance Orbiter. The interpretation of these measurements in the 2250-4450 cm−1 region is being complicated by the presence of HDO lines absorbing radiation in this region. These spectra cannot be modeled properly because line shape parameters for CO2 broadening (principal gas in these atmospheres) of HDO are not available. Here semi-classical line shape calculations for the HDO-CO2 collision system are made using the Robert-Bonamy formalism for some 2300 rotational band transitions of HDO. From these calculations, the half-width, its temperature dependence, and the line shift are determined to aid in the reduction of the measured spectra. These data will greatly reduce the uncertainty of the reduced profiles from the Venus and Mars measurements and will also allow better estimates of the D/H ratio on these planets.  相似文献   

8.
The absolute reaction cross sections and reaction rate coefficients as a function of photoionisation energy for 25 ion-molecule reactions (charge transfer reactions except for one) have been measured between the most abundant species present as ions or neutral in the Mars, Venus and Earth ionospheres: O2, N2, NO, CO, Ar and CO2.This study shows the strong influence of electronic as well as vibrational internal energy on most ion-molecule reactions. In particular endothermic charge transfer reactions are driven by electronic excitation of O2+ and NO+ ions in their a4Πu and a3Σ+ metastable states, respectively. Moreover, it is shown that lifetimes of these metastable states are sufficient to survive the mean free path in the lowest part of ionospheres and therefore express their enhanced reactivity. The reactions of O2+ with NO as well as the reactions of CO2+ with NO, O2, CO and to a less extent N2 are driven by vibrational excitation. N2+ and CO+ reactions vary much less with photon energy than the other ones, except for the case of reactions with Ar. The effects of the molecular ion internal energy content on their reactivity must be included in the ionospheric models for most of the reactions investigated in the present work. It is also the case for the effect of collision energy on the CO++M reactions as we expect that a significant proportion of these CO+ could be produced with translational energy by dissociation of doubly charged CO22+, in particular in the Mars ionosphere. Recommended effective rate constant values are given as a function of VUV photon energy.  相似文献   

9.
Recent spacecraft observations of Venus permit a detailed model of sulfur chemistry in the atmosphere-lithosphere system. Pioneer Venus experiments confirm that, as predicted, COS and H2S are dominant over SO2 in the lower atmosphere, and that the equilibrium concentrations of S2 and S3 are significant. Many criteria serve to bracket the oxidation state of the crust: it is nearly certain that the S22?/SO42? buffer regulates the oxygen fucagity, and that FeO is at least as abundant as Fe2O3 in crustal silicates. A highly oxidized crust (as, for example, would result from O2 absorption complementary to escape of vast amounts of H2) is incompatible with the gas-phase sulfur chemistry. If the Pioneer Venus mass spectrometer estimates of the abundance of sulfur gases are correct, Earth-like models for the bulk composition of Venus are seriously in error, and a far lower FeO content is required for Venus.  相似文献   

10.
In January of 1982 we measured a microwave spectrum of CO in the Martian atmosphere utilizing the rotational J = 1 → 2 transition of CO. We have analyzed data and reanalyzed the microwave spectra of R. K. Kakar, J. W. Waters, and W. J. Wilson, (Science196, 1090–1091, 1977, measured in 1975) and J. C. Good and F. P. Schloerb, (Icarus47, 166–172, 1981 measured in 1980) in order to constrain estimates of the temporal variability of CO abundance in the Martian atmosphere. Our values of CO column density from the data of Karar et al., Good and Schloerb, and our own are 1.7 ± 0.9 × 1020, 3.0 ± 1.0 × 1020, and 4.6 ± 2.0 × 1020cm?2, respectively. The most recent estimate of CO column density from the 1967 infrared spectra of J. Connes, P. Connes, and J.P. Maillard, (Atlas de Spectres Infarouges de Venus, Mars, Jupiter, et Saturne, Editions due Centre National de la Recherche Scientifique, Paris, 1969), is 2.0 ± 0.8 × 1020 cm?2 (L.D.G. Young and A.T. Young, Icarus30, 75–79, 1977). The large uncertainties given for the microwave measurements are due primarily to uncertainty in the difference between the continuum brightness temperature and atmospheric temperatures of Mars. We have accurately calculated the variation among the observations of the continuum (surface) brightness temperature of Mars, which is primaroly a function of the observed aspect of Mars. A more difficult problem to consider is variability of global atmospheric temperatures among the observations, particularly the effects of global dust storms and the ellipticity of the orbit of Mars. The large bars accompanying our estimates of CO column density from the three sets of microwave measurements are primarily caused by an assumed uncertainty of ±10°K in our atmospheric temperature model due to possible dust in the atmosphere. A qualitative consideration of seasonal variability of global atmospheric temperatures among the measurements suggests that there is not strong evidence for variability of the column abundance of CO on Mars, although variability of 0–100% over a time scale of several years is allowed by the data set. The implication for the variability of Mars O2 is, crudely, a factor of two less. We found that the altitude distribution of CO in the atmosphere of Mars was not well constrained by any of the spectra, although our spectrum was marginally better fitted by an altitude increasing profile of CO mixing ratios.  相似文献   

11.
There is a significant progress in the observational data relevant to Mars photochemistry in the current decade. These data are not covered by and sometimes disagree with the published models. Therefore we consider three types of models for Mars photochemistry. A steady-state model for global-mean conditions is currently the only way to calculate the abundances of long living species (H2, O2, and CO). However, our model does not fit the observed CO abundance using gas-phase chemistry and reasonable values of heterogeneous loss of odd hydrogen on the water ice aerosol. The second type of the calculated models is steady-state models for local conditions. The MGS/TES data on temperature profiles, H2O, and dust are input parameters for these models. The calculations have been made for nine seasonal points spread over the martian year and for twelve latitudes with a step of 10° for each season. The only adopted heterogeneous reaction is a weak loss of H2O2 on water ice with probability of 5×10−4. The results are in good agreement with the recent observations of the O2 dayglow at 1.27 μm and the O3 and H2O2 abundances. Global maps of the seasonal and latitudinal behavior of these species have been made. The third type of models is a time-dependent model for local conditions. These models show that odd hydrogen quickly converts to H2O2 at the nighttime and the chemistry is switched off while the association of O, the heterogeneous loss of H2O2, and eddy diffusion continue. This requires significant changes in the global-mean and local steady-state models discussed above, and these changes have been properly done. The calculated diurnal variations of Mars photochemistry are discussed. The martian photochemistry at low and middle latitudes is significantly different in the aphelion period at LS=10°-130° from that in the remaining part of the year.  相似文献   

12.
We have performed a numerical simulation to analyze the energy spectra of escaping planetary O+ and O2+ ions at Mars. The simulated time-energy spectrograms were generated along orbit no. 555 (June 27, 2004) of Mars Express when its Ion Mass Analyzer (IMA)/ASPERA-3 ion instrument detected escaping planetary ions. The simulated time-energy spectrograms are in general agreement with the hypothesis that planetary O+ and O2+ ions far from Mars are accelerated by the convective electric field. The HYB-Mars hybrid model simulation also shows that O+ ions originating from the ionized hot oxygen corona result in a high-energy (E>1 keV) O+ ion population that exists very close to Mars. In addition, the simulation also results in a low-energy (E<0.1 keV) planetary ion population near the pericenter. In the analyzed orbit, IMA did not observe a clear high-energy planetary ion or a clear low-energy planetary ion population near Mars. One possible source for this discrepancy may be the Martian magnetic crustal anomalies because MEX passed over a strong crustal field region near the pericenter, but the hybrid model does not include the magnetic crustal anomalies.  相似文献   

13.
Hydroxyl nightglow is intensively studied in the Earth atmosphere, due to its coupling to the ozone cycle. Recently, it was detected for the first time also in the Venus atmosphere, thanks to the VIRTIS-Venus Express observations. The main Δν=1, 2 emissions in the infrared spectral range, centred, respectively, at 2.81 and 1.46 μm (which correspond to the (1-0) and (2-0) transitions, respectively), were observed in limb geometry (Piccioni et al., 2008) with a mean emission rate of 880±90 and 100±40 kR (1R=106 photon cm−2 s−1 (4πster)−1), respectively, integrated along the line of sight. In this investigation, the Bates-Nicolet chemical reaction is reported to be the most probable mechanism for OH production on Venus, as in the case of Earth, but HO2 and O may still be not negligible as mechanism of production for OH, differently than Earth. The nightglow emission from OH provides a method to quantify O3, HO2, H and O, and to infer the mechanism of transport of the key species involved in the production. Very recently, an ozone layer was detected in the upper atmosphere of Venus by the SPICAV (Spectroscopy for Investigation of Characteristics of the Atmosphere of Venus) instrument onboard Venus Express (Montmessin et al., 2009); this discovery enhances the importance of ozone to the OH production in the upper atmosphere of Venus through the Bates-Nicolet mechanism. On Venus, OH airglow is observed only in the night side and no evidence has been found whether a similar emission exists also in the day side. On Mars it is expected to exist both on the day and night sides of the planet, because of the presence of ozone, though OH airglow has not yet been detected.In this paper, we review and compare the OH nightglow on Venus and Earth. The case of Mars is also briefly discussed for the sake of completeness. Similarities from a chemical and a dynamical point of view are listed, though visible OH emissions on Earth and IR OH emissions on Venus are compared.  相似文献   

14.
108 +/- 11 photons of the martian He 584-angstroms airglow detected by the Extreme Ultraviolet Explorer satellite during a 2-day exposure (January 22-23, 1993) correspond to the effective disk average intensity of 43 +/- 10 Rayleigh. Radiative transfer calculations, using a model atmosphere appropriate to the conditions of the observation and having an exospheric temperature of 210 +/- 20 K, result in a He mixing ratio of 1.1 +/- 0.4 ppm in the lower atmosphere. Nonthermal escape of helium is due to electron impact ionization and pickup of He+ by the solar wind, to collisions with hot oxygen atoms, and to charge exchange with molecular species with corresponding column loss rates of 1.4 x 10(5), 3 x 10(4), and 7 x 10(3) cm-2 sec-1, respectively. The lifetime of helium on Mars is 5 x 10(4) years. The He outgassing rate, coupled with the 40Ar atmospheric abundance and with the K:U:Th ratio measured in the surface rocks, is used as input to a single two-reservoir degassing model which is applied to Mars and then to Venus. A similar model with known abundances of K, U, and Th is applied to Earth. The models for Earth and Mars presume loss of all argon accumulated in the atmospheres during the first billion years by large-scale meteorite and planetesimal impacts. The models show that the degassing coefficients for all three planets may be approximated by function delta = delta (0)(t(0)/t)1/2 with delta (0) = 0/1, 0.04, and 0.0125 Byr-1 for Earth, Venus, and Mars, respectively. After a R2 correction this means that outgassing processes on Venus and Mars are weaker than on Earth by factors of 3 and 30, respectively. Mass ratios of U and Th are almost the same for all three planets, while potassium is depleted by a factor of 2 in Venus and Mars. Mass ratios of helium and argon are close to 5 x 10(-9) and 2 x 10(-8) g/g in the interiors of all three planets. The implications of these results are discussed.  相似文献   

15.
The processes of the kinetics and transport of hot oxygen atoms in the transition (between thermosphere and exosphere) region of the upper atmosphere of Mars are studied. The reaction of dissociative recombination of the main ionospheric ion O 2 + with thermal electrons in the ionosphere of Mars is considered as a source of hot oxygen atoms. The distribution of suprathermal oxygen atoms by kinetic energy is calculated. It is shown that the exosphere is populated by a considerable number of suprathermal oxygen atoms with kinetic energies just below the escape energy of 2 eV; that is, a hot oxygen corona of Mars is formed.  相似文献   

16.
The radiogenic and primordial noble gas content of the atmospheres of Venus, Earth, and Mars are compared with one another and with the noble gas content of other extraterrestial samples, especially meteorites. The fourfold depletion of 40Ar for Venus relative to the Earth is attributed to the outgassing rates and associated tectonics and volcanic styles for the two planets diverging significantly within the first billion or so years of their history, with the outgassing rate for Venus becoming much less than that for the Earth at subsequent times. This early divergence in the tectonic style of the two planets may be due to a corresponding early onset of the runaway greenhouse on Venus. The 16-fold depletion of 40Ar for Mars relative to the Earth may be due to a combination of a mild K depletion for Mars, a smaller fraction of its interior being outgassed, and to an early reduction in its outgassing rate. Venus has lost virtually all of its primordial He and some of its radiogenic He. The escape flux of He may have been quite substantial in Venus' early history, but much diminished at later times, with this time variation being perhaps strongly influenced by massive losses of H2 resulting from efficient H2O loss processes.Key trends in the primordial noble gas content of terrestial planetary atmospheres include (1) a several orders of magnitude decrease in 20Ne and 36Ar from Venus to Earth to Mars; (2) a nearly constant 20Ne/36Ar ratio which is comparable to that found in the more primitive carbonaceous chondrites and which is two orders of magnitude smaller than the solar ratio; (3) a sizable fractionation of Ar, Kr, and Xe from their solar ratios, although the degree of fractionation, especially for 36Ar/132Xe, seems to decrease systematically from carbonaceous chondrites to Mars to Earth to Venus; and (4) large differences in Ne and Xe isotopic ratios among Earth, meteorites, and the Sun. Explaining trends (2), (2) and (4), and (1) pose the biggest problems for the solar-wind implantation, primitive atmosphere, and late veneer hypotheses, respectively. It is suggested that the grain-accretion hypothesis can explain all four trends, although the assumptions needed to achieve this agreement are far from proven. In particular, trends (1), (2), (3), and (4) are attributed to large pressure but small temperature differences in various regions of the inner solar system at the times of noble gas incorporation by host phases; similar proportions of the host phases that incorporated most of the He and Ne on the one hand (X) and Ar, Kr, and Xe on the other hand (Q); a decrease in the degree of fractionation with increasing noble-gas partial pressure; and the presence of interstellar carriers containing isotopically anomalous noble gases.Our analysis also suggests that primordial noble gases were incorporated throughout the interior of the outer terrestial planets, i.e., homogeneous accretion is favored over inhomogeneous accretion. In accord with meteorite data, we propose that carbonaceous materials were key hosts for the primordial noble gases incorporated into planets and that they provided a major source of the planets' CO2 and N2.  相似文献   

17.
High-resolution spectra of Venus and Mars at the NO fundamental band at 5.3 μm with resolving power ν/δν=76,000 were acquired using the TEXES spectrograph at NASA IRTF on Mauna Kea, Hawaii. The observed spectrum of Venus covered three NO lines of the P-branch. One of the lines is strongly contaminated, and the other two lines reveal NO in the lower atmosphere at a detection level of 9 sigma. A simple photochemical model for NO and N at 50-112 km was coupled with a radiative transfer code to simulate the observed equivalent widths of the NO and some CO2 lines. The derived NO mixing ratio is 5.5±1.5 ppb below 60 km and its flux is . Predissociation of NO at the (0-0) 191 nm and (1-0) 183 nm bands of the δ-system and the reaction with N are the only important loss processes for NO in the lower atmosphere of Venus. The photochemical impact of the measured NO abundance is significant and should be taken into account in photochemical modeling of the Venus atmosphere. Lightning is the only known source of NO in the lower atmosphere of Venus, and the detection of NO is a convincing and independent proof of lightning on Venus. The required flux of NO is corrected for the production of NO and N by the cosmic ray ionization and corresponds to the lightning energy deposition of . For a flash energy on Venus similar to that on the Earth (∼109 J), the global flashing rate is ∼90 s−1 and ∼6 km−2 y−1 which is in reasonable agreement with the existing optical observations. The observed spectrum of Mars covered three NO lines of the R-branch. Two of these lines are contaminated by CO2 lines, and the line at 1900.076 cm−1 is clean and shows some excess over the continuum. Some photochemical reactions may result in a significant excitation of NO (v=1) in the lowest 20 km on Mars. However, quenching of NO (v=1) by CO2 is very effective below 40 km. Excitation of NO (v=1) in the collisions with atomic oxygen is weak because of the low temperature in the martian atmosphere, and we do not see any explanation of a possible emission of NO at 5.3 μm. Therefore the data are treated as the lack of absorption with a 2 sigma upper limit of 1.7 ppb to the NO abundance in the lower atmosphere of Mars. This limit is above the predictions of photochemical models by a factor of 3.  相似文献   

18.
The new ESA Venus Express orbiter is the first mission applying the probing technique of solar and stellar occultation to the atmosphere of Venus, with the SPICAV/SOIR instrument. SOIR is a new type of spectrometer used for solar occultations in the range 2.2-4.3 μm. Thanks to a high spectral resolving power R∼15,000-20,000 (unprecedented in planetary space exploration), a new gaseous absorption band was soon detected in the atmospheric transmission spectra around 2982 cm−1, showing a structure resembling an unresolved Q branch and a number of isolated lines with a regular wave number pattern. This absorption could not be matched to any species contained in HITRAN or GEISA databases, but was found very similar to an absorption pattern observed by a US team in the spectrum of solar light reflected by the ground of Mars [Villanueva, G.L., Mumma, M.J., Novak, R.E., Hewagama, T., 2008. Icarus 195 (1), 34-44]. This team then suggested to us that the absorption was due to an uncatalogued transition of the 16O12C18O molecule. The possible existence of this band was soon confirmed from theoretical considerations by Perevalov and Tashkun. Some SOIR observations of the atmospheric transmission are presented around 2982 cm−1, and rough calculations of line strengths of the Q branch are produced, based on the isotopic ratio measured earlier in the lower atmosphere of Venus. This discovery emphasizes the role of isotopologues of CO2 (as well as H2O and HDO) as important greenhouse gases in the atmosphere of Venus.  相似文献   

19.
T.Y. Kong  M.B. McElroy 《Icarus》1977,32(2):168-189
A variety of models are explored to study the photochemistry of CO2 in the Martian atmosphere with emphasis on reactions involving compounds of carbon, hydrogen, and oxygen. Acceptable models are constrained to account for measured concentrations of CO and O above 90 km, with an additional requirement that they should be in accord with observations of CO, O2, and O3 in the lower atmosphere. Dynamical mixing must be exceedingly rapid at altitudes above 90 km, with effective eddy diffusion coefficients in excess of 107 cm2 sec?1. If recombination of CO2 is to occur mainly by gas phase chemistry, catalyzed by trace quantities of H, OH, and HO2, mixing must be rapid over the altitude interval 30 to 40 km. The value implied for the diffusion coefficient in this region is a function of assumptions made regarding the rates for reaction of OH with HO2 to form H2O and of the rate for reaction of HO2 with itself to form H2O2. If rates for these reactions are taken to have values similar to rates used in current models for the Earth's stratosphere, the eddy diffusion coefficient at 40 km on Mars should be about 5 × 107 cm2 sec?1, consistent with Zurek's (1976) estimate for this parameter inferred from tidal theory. Surface chemistry could have an influence on the abundances of atmospheric CO and O2, but a major effect would imply sluggish mixing at all altitudes below 50 km and in addition would carry implications for the magnitude of the rates for reaction of OH with HO2 and HO2 with itself.  相似文献   

20.
This work presents model calculations of the diurnal airglow emissions from the OH Meinel bands and the O2 IR atmospheric band in the neutral atmosphere of Mars. A time-dependent photochemical model of the lower atmosphere below 80 km has been developed for this purpose. Special emphasis is placed on the nightglow emissions because of their potential to characterize the atomic oxygen profile in the 50-80 km region. Unlike on Earth, the OH Meinel emission rates are very sensitive to the details of the vibrational relaxation pathway. In the sudden death and collisional cascade limits, the maximum OH Meinel column intensities for emissions originating from a fixed upper vibrational level are calculated to be about 300 R, for transitions v′=9→v′?8, and 15,000 R, for transitions v′=1→v′=0, respectively. During the daytime the 1.27 μm emission from O2(), primarily formed from ozone photodissociation, is of the order of MegaRayleighs (MR). Due to the long radiative lifetime of O2(), a luminescent remnant of the dayglow extends to the dark side for about two hours. At night, excited molecular oxygen is expected to be produced through the three body reaction O + O + CO2. The column emission of this nighttime component of the airglow is estimated to amount to 25 kR. Both nightglow emissions, from the OH Meinel bands and the O2 IR atmospheric band, overlap in the 50-80 km region. Photodissociation of CO2 in the upper atmosphere and the subsequent transport of the atomic oxygen produced to the emitting layer are revealed as key factors in the nightglow emissions from these systems. The Mars 5 upper constraint for the product [H][O3] is revised on the basis of more recent values for the emission probabilities and collisional deactivation coefficients.  相似文献   

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