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1.
On the basis of their mineral chemistry, podiform chromitites are divided into high-Al (Cr# = 20–60) (Cr# = 100 1 Cr/(Cr + Al)) and high-Cr (Cr# = 60–80) varieties. Typically, only one type occurs in a given peridotite massif, although some ophiolites contain several massifs that can have different chromitite compositions. We report here the occurrence of both high-Cr and high-Al chromitite in a single massif in China, the Dongbo mafic-ultramafic body in the western Yarlung-Zangbo suture zone of Tibet. This massif consists mainly of mantle peridotites, with lesser pyroxenite and gabbro. The mantle peridotites are mainly composed of harzburgites and minor lherzolites; a few dike-like bodies of dunite are also present. Seven small, lenticular bodies of chromitite ores have been found in the harzburgites, with ore textures ranging from massive through disseminated to sparsely disseminated; no nodular ore has been observed. Individual chromitite pods are 1–3 m long, 0.2–2 m wide and strike NW, parallel to the main trend of the peridotites. Chromitite pods 3, 4, and 5 consist of high-Al chromitite (Cr# = 12–47), whereas pods 1 and 2 are high-Cr varieties (Cr# = 73 to 77). In addition to chromian spinel, all of the pods contain minor olivine, amphibole and serpentine. Mineral structures show that the peridotites experienced plastic deformation and partial melting. The mineralogy and geochemistry of the Dongbo peridotites suggest that they formed originally at a mid-ocean ridge (MOR), and were later modified by suprasubduction zone (SSZ) melts/fluids. We interpret the high-Al chromitites as the products of early mid-ocean ridge basalt (MORB) or arc tholeiite magmas, whereas the high-Cr varieties are thought to have been generated by later SSZ melts.  相似文献   

2.
We report the finding of peridotite xenoliths in the Early Cretaceous Longmengou olivine-bearing diabase (138 Ma) in the Northern Taihang Mountains in the central North China Craton. Based on the modal proportions of olivine, clinopyroxene, amphibole and anorthite, these peridotite xenoliths can be divided into three zones: clinopyroxene-bearing olivine zone (COZ), olivine-clinopyroxene zone (OCZ), and amphibole-bearing anorthite-clinopyroxene zone (AACZ). The core of olivine grains in clinopyroxene-bearing olivine zone have higher Mg# (> 95), SiO2 (41.80–42.53 wt%) and lower CaO (< 0.07 wt%), FeO (3.91–4.54 wt%) than the rim (Mg# = 92.5–93.4, SiO2 = 41.27–41.98 wt%, CaO = 0.20–0.34 wt%, and FeO = 7.02–8.87 wt%), suggesting that rim is reaction product. The core of olivine grains with higher Mg# (> 95) and lower NiO content (< 0.04 wt%) in the clinopyroxene-bearing olivine zone was derived from ultra-depleted mantle subsequently altered by high Mg# melts/magma with low Ni. Two generations of olivine grains occur in the OCZ where the first generation shows exsolution of ilmenite and magnetite rods containing up to 0.35 wt% TiO2, and was likely derived from garnet peridotite hydrated by water. The second generation shows high Mg# (96.2–97.1) and cataclastic texture, and was possibly formed by decomposition of the COZ. The occurrence of aluminous spinel suggests the role of melts with extremely high Al and Mg. Clinopyroxene in the AACZ shows systematic core-rim compositional variation with CaO and SiO2 contents increasing towards the rim, and MgO and Fe2O3 concentrations decreasing from the core to the rim, indicating that the amphibole-bearing anorthite-clinopyroxene zone is a product of the reaction between mantle xenoliths and mafic magma. Plagioclase with high An value (92.0–99.95, average 97.79) indicates that the metasomatic melts have high Ca/Na and Al/Si ratios, possibly produced by the partial melting of ultra-depleted mantle under “wet” conditions. Combined with the data on other mantle xenoliths discovered in the NCC, our results suggest that the Mesozoic lithospheric mantle beneath the North Taihang Mountains within the central NCC is composed of ultra-depleted Archean and Paleoproterozoic peridotites and dunites modified by complex melts. We also propose that the destruction of eastern part of the NCC mainly occurred during Early Cretaceous, and that the boundary of the lithospheric destruction coincides with the Taihang Mountains.  相似文献   

3.
Anhydrous spinel peridotite xenoliths in Quaternary nepheline-basanite and melilite- or sodalite-bearing lavas of the Wau-en-Namus volcano in S Libya range from lherzolites to harzburgites recording melt extraction in a shallow setting (≤ 2 GPa). Primary clinopyroxenes have distinct trace element characteristics documenting LILE (large ion lithophile element) depletion or enrichment events predating the formation of glass pockets and veins in the xenoliths. These glasses are aluminous and alkali-rich, range in composition from ultrabasic to silicic (43–67 wt.% SiO2) and may contain empty vugs and micro-phenocrysts of olivine, clinopyroxene, spinel, plagioclase, sodalite, apatite that are similar in composition to phenocrysts in the host lavas. Reactions of infiltrating melt and xenolith minerals are documented by diffuse Fe–Ca-rich rims of olivine in contact with glass, and by spongy-textured reaction domains caused by incongruent dissolution of primary pyroxenes and spinel. Some glasses have trace element characteristics similar to that of the host Ne-basanite, suggesting they were derived from the same source during entrainment and transport to the surface. Incompatible element enrichment and Sr–Nd isotopic compositions of the analyzed host lava are similar to HIMU (high μ; μ = 238Pb/204Pb)-type magmas, but the Pb isotopic composition is less radiogenic compared to other intra-plate Neogene magmatic rocks from N Africa.  相似文献   

4.
The ultramafic member of the Variscan Ślęża Ophiolite (SW Poland) consists of heavily serpentinised, refractory harzburgites. Those located down to 1.5 km below paleo-Moho contain scarce grains or aggregates of olivine, clinopyroxene and spinel. Non-serpentine phases occur in various assemblages: M1—olivine (Fo 90.2–91.0%, NiO 0.38–0.47 wt.%) and rounded or amaeboidal aluminous chromite, rimmed by Al poor chromite and magnetite; M2—olivine (Fo 90.5–91.5, NiO 0.32–0.44 wt.%), olivine with magnetite inclusions (Fo 87.1–92.5, NiO 0.01–0.68 wt.%), rounded, cleavaged clinopyroxene I (Mg# 91.1–93.2, Al2O3 3.00–4.00 wt.%, Cr2O3 1.00–1.40 wt.%) and elongated clinopyroxene II and clinopyroxene from symplectites with magnetite (Mg# = 92.2–94.1, Al2O3 2.20–3.20 wt.% and Cr2O3 0.80–1.20 wt.%). Clinopyroxene is depleted in REEs relative to chondrite. The M3 assemblage consists of intergrown olivine (Fo 90.8–92.7, NiO 0.20–0.38 wt.%) and clinopyroxene (Mg# = 96.0–98.1, Al2O3 0.00–1.00 wt.% and Cr2O3 0.20–0.60 wt.%).The M1 assemblage contains chromite which records greenschist-facies metamorphism. Textural relationships and chemical composition of clinopyroxene occurring in the M2 assemblage are similar to those formed in oceanic spreading centres by LREE depleted basaltic melt percolation. Olivine occurring in M1 assemblage and part of that from M2 have composition typical of residual olivine from the abyssal harzburgites and of olivine formed in those rocks by melt percolation. The olivine with magnetite inclusions (M2 assemblage) and that from M3 record later deserpentinization event, which supposedly produced also M3 clinopyroxene. The non-serpentine phases from the Ślęża ophiolite mantle member, albeit very poorly preserved, document depleted basaltic melt percolation in the Variscan oceanic spreading centre.  相似文献   

5.
Relative to the North China Craton, the subcontinental lithospheric mantle (SCLM) beneath the Central Asian Orogenic Belt is little known. Mantle-derived peridotite xenoliths from the Cenozoic basalts in the Xilinhot region, Inner Mongolia, provide samples of the lithospheric mantle beneath the eastern part of the belt. The xenoliths are predominantly lherzolites with minor harzburgites, and can be subdivided into three groups, based on the REE patterns of clinopyroxenes. Group 1 peridotites (LREE-enriched), with low modal Cpx (3–7%), high Mg# in olivine (> 90.6) and Cr# in spinel (> 43.8), low whole-rock CaO + Al2O3 contents (1.62–3.22 wt.%) and estimated temperatures of 1043–1126 °C, represent moderately refractory SCLM that has experienced carbonatite-related metasomatism. Group 2 peridotites (LREE-depleted), with high modal Cpx (9–13%), low Mg# in olivine (< 90.6) and Cr# in spinel (< 20.0), high whole-rock CaO + Al2O3 contents (4.93–6.37 wt.%) and estimated temperatures of 814–970 °C, show affinity with Phanerozoic fertile SCLM that has undergone silicate-related metasomatism. Group 3 peridotites (convex-upward REE patterns), show wide ranges of olivine-Mg# (88.4–90.6), spinel-Cr# (11.5–47.6), and modal Cpx (3–14%) that overlap Groups 1 and 2. Their spinels have high TiO2 contents (> 0.41 wt.%), implying involvement of reactions between melt and peridotites. The estimated temperatures of Group 3 (1033–1156 °C) are similar to those of Group 1. We suggest that the pre-existing moderately refractory lithospheric mantle (i.e., Group 1) beneath the eastern part of the Central Asian Orogenic Belt was strongly penetrated by upwelling asthenospheric material, and the cooling of this material produced fertile lithospheric mantle (i.e., Group 2). The present lithospheric mantle of this area consists of interspersed volumes of younger fertile and older more refractory lithosphere, with the fertile type dominating the shallower levels of the mantle.  相似文献   

6.
Upper-mantle xenoliths in Cenozoic basalts of northwestern Spitsbergen are rocks of peridotite (spinel lherzolites) and pyroxenite (amphibole-containing garnet and garnet-free clinopyroxenites, garnet clinopyroxenites, and garnet and garnet-free websterites) series. The upper-mantle section in the depth range 50–100 km is composed of spinel peridotites; at depths of 80–100 km pyroxenites (probably, dikes or sills) appear. The equilibrium conditions of parageneses are as follows: in the peridotites—730–1180 °C, 13–27 kbar, and oxygen fugacity of − 1.5 to + 0.3 log. un.; in the pyroxenites—1100–1310 °C, 22–33 kbar. The pyroxenite minerals have been found to contain exsolved structures, such as orthopyroxene lamellae in clinopyroxene and, vice versa, clinopyroxene lamella in orthopyroxene. The formation temperatures of unexsolved phases in orthopyroxene and clinopyroxene are nearly 100–150 °C higher than the temperatures of the lamellae–matrix equilibrium and the equilibrium of minerals in the rock. The normal distribution of cations in the spinel structure and the equilibrium distribution of Fe2 + between the M1 and M2 sublattices in the orthopyroxenes point to the high rate of xenolith ascent from the rock crystallization zone to the surface. All studied Spitsbergen rock-forming minerals from mantle xenoliths contain volatiles in their structure: OH−, crystal hydrate water H2Ocryst, and molecules with characteristic CH and CO groups. The first two components are predominant, and the total content of water (OH– + H2Ocryst) increases in the series olivine → garnet → orthopyroxene → clinopyroxene. The presence of these volatiles in the nominally anhydrous minerals (NAM) crystallized at high temperatures and pressures in the peridotites and pyroxenites testifies to the high strength of the volatile–mineral bond. The possibility of preservation of volatiles is confirmed by the results of comprehensive thermal and mass-spectral analyses of olivines and clinopyroxene, whose structures retain these components up to 1300 °C. The composition of hypothetic C–O–H fluid in equilibrium (in the presence of free carbon) with the underlying mantle rocks varies from aqueous (> 80% H2O) to aqueous–carbonic (~ 60% H2O). The fluid becomes essentially aqueous when the oxygen activity in the system decreases. However, there is no strict dependence of the redox conditions on the depth of formation of xenoliths.  相似文献   

7.
The podiform chromite deposit of the Soghan mafic–ultramafic complex is one of the largest chromite deposits in south-east Iran (Esfandagheh area). The Soghan complex is composed mainly of dunite, harzburgite, lherzolite, pyroxenite, chromitite, wehrlite and gabbro. Olivine, orthopyroxene, and to a lesser extent clinopyroxene with highly refractory nature, are the primary silicates found in the harzburgites and dunites. The forsterite content of olivine is slightly higher in dunites (Fo94) than those in harzburgites (Fo92) and lherzolites (Fo89). Chromian spinel mainly occurs as massive chromitite pods and as thin massive chromitite bands together with minor disseminations in dunites and harzburgites. Chromian spinels in massive chromitites show very high Cr-numbers (80–83.6), Mg-numbers (62–69) and very low TiO2 content (averaging 0.17 wt.%) for which may reflect the crystallization of chromite from a boninitic magma. The Fe3 +-number is very low, down to < 0.04 wt.%, in the chromian spinel of chromitites and associated peridotites of the Soghan complex.PGE contents are variable and range from 80 to 153 pbb. Chromitites have strongly fractionated chondrite-normalized PGE patterns, which are characterized by enrichments in Os, Ir and Rh relative to Pt and Pd. Moreover, the Pd/Ir value which is an indicator of PGE fractionation ranges from < 0.08 to 0.24 in chromitite of the Soghan complex. These patterns and the low PGE abundances are typical of ophiolitic chromitites and indicating a high degree of partial melting (about 20–24%) of the mantle source. Moreover, the PdN/IrN ratios in dunites are unfractionated, averaging 1.2, whereas the harzburgites and lherzolites show slightly positive slopes PGE spidergrams, together with a small positive Ru and Pd anomaly, and their PdN/IrN ratio averages 1.98 and 2.15 respectively.The mineral chemistry data and PGE geochemistry, along with the calculated parental melts in equilibrium with chromian spinel of the Soghan chromitites indicate that the Soghan complex was generated from an arc-related magma with boninitic affinity above a supra-subduction zone setting.  相似文献   

8.
We present new, whole-rock major and trace element chemistry, including rare earth elements (REE), platinum-group elements (PGE), and Re–Os isotope data from the upper mantle peridotites of a Cretaceous Neo-Tethyan ophiolite in the Mu?la area in SW Turkey. We also report extensive mineral chemistry data for these peridotites in order to better constrain their petrogenesis and tectonic environment of formation. The Mu?la peridotites consist mainly of cpx-harzburgite, depleted harzburgite, and dunite. Cpx-harzburgites are characterized by their higher average CaO (2.27 wt.%), Al2O3 (2.07 wt.%), REE (53 ppb), and 187Os/188Os(i) ratios varying between 0.12497 and 0.12858. They contain Al-rich pyroxene with lower Cr content of coexisting spinel (Cr# = 13–22). In contrast, the depleted harzburgites and dunites are characterized by their lower average CaO (0.58 wt.%), Al2O3 (0.42 wt.%), and REE (1.24 ppb) values. Their clinopyroxenes are Al-poor and coexist with high-Cr spinel (Cr# = 33–83). The 187Os/188Os(i) ratios are in the range of 0.12078–0.12588 and are more unradiogenic compared to those of the cpx-harzburgites.Mineral chemistry and whole rock trace and PGE data indicate that formation of the Mu?la peridotites cannot be explained by a single stage melting event; at least two-stages of melting and refertilization processes are needed to explain their geochemical characteristics. Trace element compositions of the cpx-harzburgites can be modeled by up to ~ 10–16% closed-system dynamic melting of a primitive mantle source, whereas those of the depleted harzburgites and dunites can be reproduced by ~ 10–16% open-system melting of an already depleted (~ 16%) mantle. These models indicate that the cpx-harzburgites are the products of first-stage melting and low-degrees of melt–rock interaction that occurred in a mid-ocean ridge (MOR) environment. However, the depleted harzburgites and dunites are the product of second-stage melting and related refertilization which took place in a supra subduction zone (SSZ) environment. The Re–Os isotope systematics of the Mu?la peridotites gives model age clusters of ~ 250 Ma, ~ 400 Ma and ~ 750 Ma that may record major tectonic events associated with the geodynamic evolution of the Neo-Tethyan, Rheic, and Proto-Tethyan oceans, respectively. Furthermore, > 1000 Ma model ages can be interpreted as a result of an ancient melting event before the Proto-Tethys evolution.  相似文献   

9.
Mantle xenoliths hosted in Miocene-Quaternary mafic alkaline volcanic rocks from Sardinia have been investigated with electron microprobe, laser ablation microprobe-inductively coupled plasma-mass spectrometry and thermal ionization mass spectrometry techniques. The xenoliths are anhydrous clinopyroxene-poor lherzolites and harzburgites, plus very rare websterites and olivine-websterites. Glassy pods having thin subhedral to euhedral microlites of olivine, clinopyroxene and spinel have been found in harzburgites and websterites. Clinopyroxene shows trace element variability, with values of (La/Yb)N ranging from sub-chondritic (0.01) to supra-chondritic (8.6). The Sr–Nd isotopic ratios of the clinopyroxenes fall mostly in the field of the European lithospheric mantle xenoliths (87Sr/86Sr from 0.70385 to 0.70568 and 143Nd/144Nd ranging from 0.512557 to 0.512953). The geochemical characteristics of the Sardinian xenoliths testify to the variable degrees of earlier partial melt extraction, followed by metasomatic modification by alkaline melts or fluids. Websterites are considered to represent small lenses or veins of cumulitic (i.e. magmatic) origin within the mantle peridotite.  相似文献   

10.
The Saramta peridotite massif is located within the Sharyzhalgai complex, SW margin of the Siberian craton. The Saramta massif was formed in the Archean and then juxtaposed with granulites of crystalline basement of the Siberian craton. The Saramta harzburgites are highly refractory in terms of lack of residual clinopyroxene, olivine Mg-number (up to 0.937), and spinel Cr-number (∼0.5), suggesting high degree of partial melting. Detailed study of their microstructures shows that they have extensively reacted with a SiO2-rich melt, leading to the crystallization of orthopyroxene, clinopyroxene, amphibole and spinel at the expense of olivine. The major element compositions of the least reacted harzburgites are similar to the residues of refractory peridotites produced by the fractional melting (initial melting pressures >3 GPa and melt fractions ∼40%). Moreover, non-residual clinopyroxenes are highly depleted in Yb, Zr and Ti, but highly enriched in LREE. A two-stage history is proposed for the Saramta peridotite: (1) primitive mantle underwent depletion in the garnet stability field followed by melting in the spinel stability field; (2) refractory harzburgites underwent refertilization by SiO2-rich melt in supra-subduction zone. Rare Saramta lherzolites probably formed from more refractory harzburgites as a result of such a melt–rock reaction. The Saramta peridotites are similar to low-T coarse-grained peridotites of subcratonic mantle. Processes of their formation, as reflected by textures and composition of minerals of the Saramta peridotites, are characteristic of the early stages of subcratonic mantle formation.  相似文献   

11.
Post-collisional ultrapotassic magmatic rocks (15.2–18.8 Ma), containing mantle xenoliths, are extensively distributed in the Sailipu volcanic field of the Lhasa terrane in south Tibet. They could be subdivided into high-MgO and low-MgO subgroups based on their petrological and geochemical characteristics. The high-MgO subgroup has olivine-I (Fo87–92), phlogopite and clinopyroxene as phenocryst phases, while the low-MgO subgroup consists mainly of phlogopite, clinopyroxene and olivine-II (Fo77–89). These ultrapotassic magmatic rocks have high MgO (4.6–14.5 wt%), Ni (145–346 ppm), Cr (289–610 ppm) contents, and display enrichment in light rare earth element (REE) over heavy REE and enriched large ion lithophile elements (LILE) relative to high field strength elements (HFSE) with strongly negative Nb-Ta-Ti anomalies in primitive mantle-normalized trace element diagrams. They have extremely radiogenic (87Sr/86Sr)i (0.7167–0.7274) and unradiogenic (143Nd/144Nd)i (0.5118–0.5120), high (207Pb/204Pb)i (15.740–15.816) and (208Pb/204Pb)i (39.661–39.827) at a given (206Pb/204Pb)i (18.363–18.790) with high δ18O values (7.3–9.7‰). Strongly linear correlations between depleted mid-ocean ridge basalt-source mantle (DMM) and the Indian continental crust (HHCS) in Sr-Nd-Pb-O isotopic diagrams indicate that the geochemical features could result from reaction between mantle peridotite and enriched components (fluids and melts) released by the eclogitized Indian continental crust (HHCS) in the mantle wedge. The high-MgO (13.7–14.5 wt%) subgroup displays higher (143Nd/144Nd)i, lower (87Sr/86Sr)i and (206Pb/204Pb)i ratios and lower δ18O values compared with the low-MgO (4.6–8.8 wt%) subgroup. High Ni (850–4862 ppm) contents of olivine phenocrysts and high whole-rock SiO2, NiO, low CaO contents indicate that the low-MgO ultrapotassic magmatic rocks are derived from partial melting of olivine-poor mantle pyroxenite. However, lower Ni concentrations of olivine phenocryst and lower whole-rock SiO2, NiO, higher CaO contents of the high-MgO ultrapotassic rocks may indicate their peridotite mantle source. This could be attributed to different amounts of silicate-rich components added into the mantle sources of the parental magmas in the mantle wedge caused by the northward subduction of the Indian continental lithosphere. The reaction-formed websterite xenoliths, reported for the first time in this study, are made up of anhedral and interlocking clinopyroxene (45–65 vol%) and orthopyroxene (30–50 vol%) with minor phlogopite (< 3 vol%) and quartz (< 2 vol%) and are suggested to be formed by silicate metasomatism of the mantle peridotite. The harzburgites, another major type of mantle xenolith in south Tibet, have a mineral assemblage of olivine (60–75 vol%), orthopyroxene (20–35 vol%), clinopyroxene (< 3 vol%), phlogopite (< 2 vol%) and spinel (< 2 vol%) and may have experienced subduction-related metasomatism. Combined with two types of ultrapotassic magmas, we propose that compositions of mantle wedge beneath south Tibet may gradually evolve from harzburgite through lherzolite to websterite with strong metasomatism of silicate-rich components in their mantle source region. Partial melting of the enriched mantle sources could be triggered by rollback of Indian continental slab during 25–8 Ma in south Tibet.  相似文献   

12.
Mafic granulite and spinel lherzolite xenoliths from Cenozoic alkaline basalts near Al-Ashkhara, eastern Oman, have been selected for a systematic mineralogical, geochemical and Sr–Nd–Pb isotopic study. This is the only place in E Arabia where samples of both lower crust and upper mantle can be examined. Lower crustal xenoliths consist of two mineralogically and chemically distinct groups: gabbronorite (subequal abundances of ortho- and clino-pyroxene and plagioclase) and plagioclase pyroxenite (dominant pyroxene and subordinate plagioclase). Temperature estimates for lower crustal xenoliths using the two pyroxene geothermometer (T-Wells) yield 810–865 °C. The mineral assemblage (spinel–pyroxene–plagioclase) and Al content in pyroxene indicate that plagioclase-bearing xenoliths equilibrated at 5–8 kbar (13 and 30 km depth) in the lower crust. εNd and 87Sr/86Sr calculated at 700 Ma for Al-Ashkhara lower crustal xenoliths (+ 6.4 to + 6.6; 87Sr/86Sr = 0.7028 to 0.7039) are consistent with the interpretation that juvenile, mafic melts were added to the lower crust during Neoproterozoic time and that there was no discernible contribution from pre-Neoproterozoic crust. Upper mantle xenoliths consist of both dry and hydrous (phlogopite-bearing) lherzolites. These peridotites are more Fe-rich than expected for primitive mantle or melt residues and probably formed by pervasive circulation of melts that have refertilized pre-existing mantle peridotites. Mineral equilibration temperatures range from 990 to 1070 °C. Isotopic compositions calculated at 700 Ma are εNd = + 6.8 to + 7.8 and 87Sr/86Sr = 0.7016 to 0.7025, indicating depleted upper mantle. Pb isotopic compositions indicate that the metasomatism was relatively recent, perhaps related to Paleogene tectonics and basanite igneous activity. Nd model ages for the spinel peridotite xenoliths range between 0.59 and 0.65 Ga. The xenolith data suggest that eastern Arabian lower crust is of hotspot origin, in contrast to western Arabian lower crust, which mostly formed at a convergent plate margin. Geochemical and isotopic differences between lower crust and upper mantle indicate that these are unrelated, possibly because delamination replaced the E Arabian mantle root in Neoproterozoic time.  相似文献   

13.
《Gondwana Research》2014,25(3):1242-1262
Basal peridotites above the metamorphic sole outcropped around Wadi Sarami in the central Oman ophiolite give us an excellent opportunity to understand the spatial extent of the mantle heterogeneity and to examine peridotites−slab interactions. We recognized two types of basal lherzolites (Types I and II) that change upward to harzburgites. Their pyroxene and spinel compositions display severely variations at small scales over < 0.5 km, and encompass the entire abyssal peridotite trend; clinopyroxenes (Cpxs) show wide ranges of Al2O3, Na2O, Cr2O3 and TiO2 contents. Primary spinels show a large variation of Cr# [= Cr/(Cr + Al)] from 0.04 to 0.53, indicating various degrees of partial melting. Trace-element compositions of peridotites and their pyroxenes also show a large chemical heterogeneity in the base of the Oman mantle section. This heterogeneity mainly resulted from variations of partial-melting degrees due to the change of a mantle thermal regime and a distance from the spreading ridge or the mantle diapir. It was overlapped with subsolidus modification during cooling and fluid metasomatism prior and/or during emplacement. The studied peridotites are enriched in Rb, Cs, Ba, Sr and LREE due to fluid influx during detachment and emplacement stages. Chondrite (CI)-normalized REE patterns for pyroxenes are convex upward with strong LREE depletion due to their residual origin, similar to abyssal peridotites from a normal ridge segment. The Cpxs are enriched in fluid mobile elements (e.g., B, Li, Cs, Pb, Rb) and depleted in HFSE (Ta, Nb, Th, Zr) + LREE, suggesting no effect of melt refertilization. Their HREE contents, combined with spinel compositions, suggest two melting series with 1–5% melting for type II lherzolites, 3– < 10% melting for type I lherzolites and ~ 15% for harzburgites. Hornblendes are enriched in fluid-mobile elements relative to HFSE + U inherited from their precursor Cpx. The clinopyroxenite lens crosscuts the basal lherzolites, forming small-scale (< 5 cm) mineralogical and chemical heterogeneities. It was possibly formed from fractional crystallization of interstitial incremental melt that formed during decompression melting of a normal MORB mantle source. The studied peridotites possibly represent a chemical heterogeneity common to the mantle at an oceanic spreading center.  相似文献   

14.
The destruction (or reactivation) of the North China Craton (NCC) is one of the important issues related to the Phanerozoic evolution of eastern China, although the processes of destruction remain debated. Two main mechanisms – delamination and thermal/chemical erosion – have been proposed based on the geochemistry of Mesozoic–Cenozoic basalts and entrained deep–seated xenoliths. A key criterion in distinguishing between these mechanisms is the nature of the melt, derived from delaminated crust or the asthenosphere, that modified the lithospheric mantle. Here we investigate the mechanism of destruction of the NCC based on mineral compositions and oxygen isotopic data from olivines, and strontium isotopic data for clinopyroxenes within websterite xenoliths from the Early Cretaceous Feixian basalts in the eastern NCC. Olivines in websterite xenoliths have higher Mg# (86–86.4), Ni content (2187–2468 ppm), and lower Ca (983–1134 ppm), Ti (58.1–76.1 ppm), and Mn (1478–1639 ppm) contents than olivine phenocrysts (Mg# = 71.0–77.3, Ni = 233–1038 ppm, Ca = 1286–2857 ppm, Ti = 120–300 ppm, and Mn = 2092–4106 ppm) from Late Cretaceous basalts. Additionally, olivines in websterite xenolith have δ18O values of 7.10 ± 0.21‰ to 8.40 ± 0.21‰, evidently higher than those of typical mantle-derived olivines. Similarly, orthopyroxenes (Opx) and clinopyroxenes (Cpx) in the websterite xenoliths have much higher Mg# (86.3–89.2 and 87.5–90.3, respectively), and Ni contents (1097–1491 ppm and 581–809 ppm, respectively) than orthopyroxene- and clinopyroxene-phenocrysts (Opx: Mg# = 82.2–83.9, Ni = 730–798 ppm; Cpx: Mg# = 74.2–84.6, Ni = 117–277 ppm) from Late Cretaceous basalts. The 87Sr/86Sr ratios of clinopyroxenes in the websterite xenoliths range from 0.70862 to 0.70979, and are much higher than those of clinopyroxene grains from peridotite xenoliths and basalts. These data indicate that olivines are the residue of ancient lithospheric mantle that was modified intensively by a melt derived from recycled continental crust, and that the silicic and calcic metasomatic melt might have been derived from the partial melting of the subducted Yangtze slab and delaminated lower crust of the NCC. The existence of recycled continental crust in the Mesozoic lithospheric mantle implies that delamination was an important mechanism of destruction of the NCC.  相似文献   

15.
《Lithos》2007,93(1-2):175-198
The Neoproterozoic (∼ 820 Ma) Aries micaceous kimberlite intrudes the central Kimberley Basin, northern Western Australia, and has yielded a suite of 27 serpentinised ultramafic xenoliths, including spinel-bearing and rare, metasomatised, phlogopite–biotite and rutile-bearing types, along with minor granite xenoliths. Proton-microprobe trace-element analysis of pyrope and chromian spinel grains derived from heavy mineral concentrates from the kimberlite has been used to define a ∼ 35–40 mW/m2 Proterozoic geotherm for the central Kimberley Craton. Lherzolitic chromian pyrope highly depleted in Zr and Y, and Cr-rich magnesiochromite xenocrysts (class 1), probably were derived from depleted garnet peridotite mantle at ∼ 150 km depth. Sampling of shallower levels of the lithospheric mantle by kimberlite magmas in the north and north-extension lobes entrained high-Fe chromite xenocrysts (class 2), and aluminous spinel-bearing xenoliths, where both spinel compositions are anomalously Fe-rich for spinels from mantle xenoliths. This Fe-enrichment may have resulted from Fe–Mg exchange with olivine during slow cooling of the peridotite host rocks. Fine exsolution rods of aluminous spinel in diopside and zircon in rutile grains in spinel- and rutile-bearing serpentinised ultramafic xenoliths, respectively, suggest nearly isobaric cooling of host rocks in the lithospheric mantle, and indicate that at least some aluminous spinel in spinel-facies peridotites formed through exsolution from chromian diopside. Fe–Ti-rich metasomatism in the spinel-facies Kimberley mantle probably produced high-Ti phlogopite–biotite + rutile and Ti, V, Zn, Ni-enriched aluminous spinel ± ilmenite associations in several ultramafic xenoliths. U–Pb SHRIMP 207Pb/206Pb zircon ages for one granite (1851 ± 10 Ma) and two serpentinised ultramafic xenoliths (1845 ± 30 Ma; 1861 ± 31 Ma) indicate that the granitic basement and lower crust beneath the central Kimberley Basin are at least Palaeoproterozoic in age. However, Hf-isotope analyses of the zircons in the ultramafic xenoliths suggest that the underlying lithospheric mantle is at least late Archean in age.  相似文献   

16.
The Cenozoic Haoti kamafugite field (23 Ma) is situated at the western Qinling Orogen, Gansu Province in China, which is a conjunction region of the North China Craton, the Yangtze Craton and the Tibetan Plateau. Fresh peridotitic xenoliths entrained in these volcanic rocks provide an opportunity to study the nature and processes of the lithospheric mantle beneath the western Qinling. These xenoliths can be divided into two groups based on the petrological features and mineral compositions, type 1 and type 2. Type 1 xenoliths with strongly deformed texture have higher Fo (90–92.5) contents in olivines, Mg# (91–94) and Cr# (15–35) of clinopyroxenes, and Cr# (36–67) of spinels than the weakly deformed type 2 xenoliths, which have the corresponding values of 89–90, 89–91.5, 10–15 and 5–15 in minerals, respectively. CaO contents in fine-grained olivines are slightly higher than 0.10 wt% compared with coarse-grained ones (less than 0.10 wt%). Fine-grained clinopyroxenes have low Al2O3 + CaO contents (generally <23 wt%) relative to coarse-grained ones (>23 wt%). Fo contents in fine-grained olivines mainly in the melt pocket of the type 1 xenoliths are higher than those in coarse-grained ones, which is somewhat contrary to the type 2 xenoliths without melt pocket. Clinopyroxenes of the type 2 display higher Na2O contents (1.7–1.9 wt%) than those of the type 1 (<1.4 wt%). P–T estimations reveal that the type 1 xenoliths give temperature in range of 1106–1187 °C and pressure of 21–26 kbar and that relatively low temperature (907 and 1022 °C) and pressure (19.0 and 18.5 kbar) for the type 2 xenoliths. The type 1 xenoliths are characterized by depletion due to high degree of partial melting (>10%), modal metasomatic and deformed characteristics, and may represent the old refractory lithospheric mantle. In contrast, the type 2 peridotites show fertile features with low degree of partial melting (<5%) and may represent the newly-accreted lithospheric mantle. The lithospheric mantle beneath the western Qinling underwent partial melting, recrystallization, deformation and metasomatism due to asthenospheric upwelling and the latest decompression responding to the Cenozoic extensive tectonic environment. These processes perhaps are closely related to the evolution of Tibetan Plateau caused by the India-Asian collision.  相似文献   

17.
Ultrabasic xenoliths (pyroxenites, lherzolites, harzburgites) in recent (Neogene–Quaternary) volcanoes have been studied in three localities within Syria: Jubates (North), Mhailbeh (Center), Tel Thannoun (South). P–T conditions of mineral equilibration have been estimated by pyroxene thermometry (temperature) and maximum CO2 density in primary inclusions (minimum pressure). Pyroxenites equilibrate at significantly higher conditions (T about 1200 °C, P>15 kbar) than lherzolites and harzburgites (900<T<1100 °C, P between 10 and 15 kbar). All are within the spinel lherzolite field, whereas Cretaceous xenoliths originate within the garnet lherzolite field. To cite this article: A. Bilal, F. Sheleh, C. R. Geoscience 336 (2004).  相似文献   

18.
The basaltic maar of Youkou, situated in the Adamawa Volcanic Massif in the eastern branch of the continental segment of the Cameroon Volcanic Line, contains mantle-derived xenoliths of various types in pyroclastites. Spinel-bearing lherzolite xenoliths from the Youkou volcano generally exhibit protogranular textures with olivine (Fo89.4?90.5), enstatite (En89???91Fs8.7?9.8Wo0.82?1.13), clinopyroxene, spinel (Cr#Sp?=?9.4–13.8), and in some cases amphibole (Mg#?=?88.5–89.1). Mineral equilibration temperatures in the lherzolite xenoliths have been estimated from three–two pyroxene thermometers and range between 835 and 937 °C at pressures of 10–18 kbar, consistent with shallow mantle depths of around 32–58 km. Trends displayed by bulk-rock MgO correlate with Al2O3, indicating that the xenoliths are refractory mantle residues after partial melting. The degree of partial melting estimated from spinel compositions is less than 10%: evidences for much higher degrees of depletion are preserved in one sample, but overprinted by refertilization in others. Trace element compositions of the xenoliths are enriched in highly incompatible elements (LREE, Sr, Ba, and U), indicating that the spinel lherzolites underwent later cryptic metasomatic enrichment induced by plume-related hydrous silicate melts. The extreme fertility (Al2O3?=?6.07–6.56 wt% in clinopyroxene) and the low CaO/Al2O3 ratios in the spinel lherzolites suggest that they could not be a simple residue of partial melting of primitive mantle and must have experienced refertilization processes driven by the infiltration of carbonatite or carbonated silicate melts.  相似文献   

19.
The paper presents new petrographic, major element and Fourier transform infrared (FTIR) spectroscopy data and PT-estimates of whole-rock samples and minerals of a collection of 19 relatively fresh peridotite xenoliths from the Udachnaya kimberlite pipe, which were recovered from its deeper levels. The xenoliths are non-deformed (granular), medium-deformed and highly deformed (porphyroclastic, mosaic-porphyroclastic, mylonitic) lherzolites, harzburgite and dunite. The lherzolites yielded equilibration temperatures (T) and pressures (P) ranging from 913 to 1324 °C and from 4.6 to 6.3 GPa, respectively. The non-deformed and medium-deformed peridotites match the 35 mW/m2 conductive continental geotherm, whereas the highly deformed varieties match the 45 mW/m2 geotherm. The content of water spans 2 ± 1–95 ± 52 ppm in olivine, 1 ± 0.5–61 ± 9 ppm in orthopyroxene, and 7 ± 2–71 ± 30 ppm in clinopyroxene. The amount of water in garnets is negligible. Based on the modal proportions of mineral phases in the xenoliths, the water contents in peridotites were estimated to vary over a wide range from < 1 to 64 ppm. The amount of water in the mantle xenoliths is well correlated with the deformation degree: highly deformed peridotites show highest water contents (64 ppm) and those medium-deformed and non-deformed contain ca. 1 ppm of H2O. The high water contents in the deformed peridotites could be linked to metasomatism of relatively dry diamondiferous cratonic roots by hydrous and carbonatitic agents (fluids/melts), which may cause hydration and carbonation of peridotite and oxidation and dissolution of diamonds. The heterogeneous distribution of water in the cratonic mantle beneath the Udachnaya pipe is consistent with the models of mantle plume or veined mantle structures proposed based on a trace element study of similar xenolithic suits. Mantle metasomatism beneath the Siberian Craton and its triggered kimberlite magmatism could be induced by mantle enrichment in volatiles (H2O, CO2) supplied by numerous subduction zones which surrounded the Siberian continent in Neoproterozoic-Cambrian time.  相似文献   

20.
The concentrations of Rh, Au and other highly siderophile elements (HSE: Re, Os, Ir, Ru, Pt, Rh, Pd and Au), and 187Os/188Os isotope ratios have been determined for samples from peridotite massifs and xenoliths in order to further constrain HSE abundances in the Earth's mantle and to place constraints on the distributions processes accounting for observed HSE variations between fertile and depleted mantle lithologies. Concentrations of Re, Os, Ir, Ru, Pt and Pd were determined by isotope dilution ICP-MS and N-TIMS. The monoisotopic elements Rh and Au were quantified by standardization relative to the concentrations of Ru and Ir, respectively, and were determined from the same digestion aliquot as other HSE. The measurement precision of the concentration data under intermediate precision conditions, as inferred from repeated analyses of 2 g test portions of powdered samples, is estimated to be better than 10% for Rh and better than 15% for Au (1 s).Fertile lherzolites display non-systematic variation of Rh concentrations and constant Rh/Ir of 0.34 ± 0.03 (1 s, n = 57), indicating a Rh abundance for the primitive mantle of 1.2 ± 0.2 ng/g. The data also suggest that Rh behaves as a compatible element during low to moderate degrees of partial melting in the mantle or melt–mantle interaction, but may be depleted at higher degrees of melting. In contrast, Au concentrations and Au/Ir correlate with peridotite fertility, indicating incompatible behaviour of Au during magmatic processes in the mantle. Fertile lherzolites display Au/Ir ranging from 0.20 to 0.65, whereas residual harzburgites have Au/Ir < 0.20. Concentrations of Au and Re are correlated with each other and suggest similar compatibility of both elements. The primitive mantle abundance of Au calculated from correlations displayed by Au/Ir with Al2O3 and Au with Re is 1.7 ± 0.5 ng/g (1 s).The depletion of Pt, Pd, Re and Au relative to Os, Ir, Ru and Rh displayed by residual harzburgites, suggests HSE fractionation during partial melting. However, the HSE abundance variations of fertile and depleted peridotites cannot be explained by a simple fractionation process. Correlations displayed by Pd/Ir, Re/Ir and Au/Ir with Al2O3 may reflect refertilization of previously melt depleted mantle rocks due to reactive infiltration of silicate melts.Relative concentrations of Rh and Au inferred for the primitive mantle model composition are similar to values of ordinary and enstatite chondrites, but distinct from carbonaceous chondrites. The HSE pattern of the primitive mantle is inconsistent with compositions of known chondrite groups. The primitive mantle composition may be explained by late accretion of a mixture of chondritic with slightly suprachondritic materials, or alternatively, by meteoritic materials mixed into mantle with a HSE signature inherited from core formation.  相似文献   

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