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1.
The notion of a dry Moon has recently been challenged by the discovery of high water contents in lunar apatites and in melt inclusions within olivine crystals from two pyroclastic glasses. The highest and most compelling water contents were found in pyroclastic glasses that are not very common on the lunar surface. To obtain more representative constraints on the volatile content of the lunar interior, we measured the Zn content, a moderately volatile element, of mineral and rock fragments in lunar soils collected during Apollo missions. We here confirm that the Moon is significantly more depleted in Zn than the Earth. Combining Zn with existing K and Rb data on similar rocks allows us to anchor a new volatility scale based on the bond energy of nonsiderophile elements in their condensed phases. Extrapolating the volatility curve to H shows that the bulk of the lunar interior must be dry (≤1 ppm). This contrasts with the water content of the mantle sources of pyroclastic glasses, inferred to contain up to approximately 40 ppm water based on H2O/Ce ratios. These observations are best reconciled if the pyroclastic glasses derive from localized water‐rich heterogeneities in a dominantly dry lunar interior. We argue that, although late addition of 0.015% of a chondritic veneer to the Moon seems required to explain the abundance of platinum group elements (Day et al. 2007), the volatile content of the added material was clearly heterogeneous.  相似文献   

2.
Endogeneous and exogeneous events resulting in the appearance of the large volumes of melted substance on the lunar surface should be accompanied by volatilization of some elements from melts in vacuum [1]. However, it is not clear up to now whether volatilization on the Moon has indeed occurred and how the lower (in comparison with the Earth) content of some elements (Na, K and others) in lunar soil can be explained. There are contradictory opinions on these problems in publications (O'Hara, Ringwood and others) [2]. The numerous laboratory investigations of the similar processes are insufficient [3–15; 36] for interpretation of the results for the lack of an adequate physical model and the theory of these processes and also due to the narrow range of the parameters used (T, p, τ) and the experimental regimes. In the present paper a physical model is developed, which is based on experimental data; together with a theory of the process of volatilization of the volatile components of rock melts in vacuum, taking into account an adsorption of the residual atmosphere gases; all these allow us to interpret such processes successfully. As a result, some preliminary conclusions have been drawn about such phenomena on the Moon and their laboratory simulation.  相似文献   

3.
Crystallization from the molten state has been an important process for the formation of rocks on the Moon; the phenomenon of fractional crystallization is therefore discussed. The principal chemical and mineralogical features of the Apollo 11, 12 and 14 basaltic crystalline rocks are described, and an account is given of other rock types and minerals which are represented among the coarser particles in the lunar soils. A comparison is made between the chemical compositions (major, minor and trace element concentrations) of rocks and soils.Based upon the above data, one possible model for the outer shell of the Moon is presented, which consists of an outer layer of Al-rich rocks underlain by a layer which is more ferromagnesian in character. Partial melting of the latter was probably responsible for the extrusion of lavas at the surface which spread to form the basalts (Apollo 11 and 12) of the non-circular maria. The Apollo 14 (Fra Mauro) basalts are relatively enriched in potassium, rare earth elements, zirconium, phosphorus and certain other elements and may derive from partial melting of the more aluminous upper layer.The separation of the outer Moon into two layers could have occurred through gravity-aided fractional crystallization at an early stage (first few hundred m yr) in lunar history.Paper presented to the NATO Advanced Study Institute on Lunar Studies, Patras, Greece, September 1971.  相似文献   

4.
The study of the elements and molecules of astrobiological interest on the Moon can be made with the Gas Analysis Package (GAP) and associated instruments developed for the Beagle 2 Mars Express Payload. The permanently shadowed polar regions of the Moon may offer a unique location for the “cold-trapping” of the light elements (i.e. H, C, N, O, etc.) and their simple compounds. Studies of the returned lunar samples have shown that lunar materials have undergone irradiation with the solar wind and adsorb volatiles from possible cometary and micrometeoroid impacts. The Beagle 2’s analytical instrument package including the sample processing facility and the GAP mass spectrometer can provide vital isotopic information that can distinguish whether the lunar volatiles are indigenous to the moon, solar wind derived, cometary in origin or from meteoroids impacting on the Moon. As future Lunar Landers are being considered, the suite of instruments developed for the Mars Beagle 2 lander can be consider as the baseline for any lunar volatile or resource instrument package.  相似文献   

5.
Abstract— Impact-induced comminution of planetary surfaces is pervasive throughout the solar system and occurs on submillimeter to global scales, resulting in comminution products that range from fine-grained surface soils, to massive, polymict ejecta deposits, to collisionally fragmented objects. Within this wide range of comminution products, we define regoliths in a narrow sense as materials that were processed by repetitive impacts to dimensional scales comparable to or smaller than that of component minerals of the progenitor rock(s). In this paper, we summarize a wide variety of impact experiments and other observations that were primarily intended to understand the evolution of regoliths on lunar basalt flows, and we discuss some of their implications for asteroidal surfaces. Cratering experiments in both rock and noncohesive materials, combined with photogeologic observations of the lunar surface, demonstrate that craters <500 m in diameter contribute most to the excavation of local bedrock for subsequent processing by micrometeorites. The overall excavation rate and, thus, growth rate of the debris layer decreases with time, because the increasingly thicker fragmental layer will prevent progressively larger projectiles from reaching bedrock. Typical growth rates for a 5 m thick lunar soil layer are initially (～≥3 Ga ago) a few mm/Ma and slowed to <1 mm/Ma at present. The coarse-grained crater ejecta are efficiently comminuted by collisional fragmentation processes, and the mean residence time of a 1 kg rock is typically 10 Ma. The actual comminution of either lithic or monomineralic detritus is highly mineral specific, with feldspar and mesostasis comminuting preferentially over pyroxene and olivine, thus resulting in mechanically fractionated fines, especially at grain sizes <20 μm. Such fractionated fines also participate preferentially in the shock melting of lunar soils, thus giving rise to “agglutinate” melts. As a consequence, agglutinate melts are systematically enriched in feldspar components relative to the bulk composition of their respective host soil(s). Compositionally homogeneous, impact derived glass beads in lunar soils seem to result from micrometeorite impacts on rock surfaces, reflecting lithic regolith components and associated mineral mixtures. Cumulatively, experimental and observational evidence from lunar mare soils suggests that regoliths derive substantially from the comminution of local bedrock; the addition of foreign, exotic components is not necessary to explain the modal and chemical compositions of diverse grain size fractions from typical lunar soils. Regoliths on asteroids are qualitatively different from those of the Moon. The modest impact velocities in the asteroid belt, some 5 km s?1, are barely sufficient to produce impact melts. Also, substantially more crater mass is being displaced on low-gravity asteroids compared to the Moon; collisional processing of surface boulders should therefore be more prominent in producing comminuted asteroid surfaces. These processes combine into asteroidal surface deposits that have suffered modest levels of shock metamorphism compared to the Moon. Impact melting does not seem to be a significant process under these conditions. However, the role of cometary particles encountering asteroid surfaces at presumably higher velocities has not been addressed in the past. Unfortunately, the asteroidal surface processes that seemingly modify the spectral properties of ordinary chondrites to match telescopically obtained spectra of S-type asteroids remain poorly understood at present, despite the extensive experimental and theoretical insights summarized in this report and our fairly mature understanding of lunar surface processes and regolith evolution.  相似文献   

6.
The nature of the ancient magnetic field of the Moon, in which lunar rocks acquired their remanent magnetism, has emerged as an important potential source of evidence, if somewhat controversial, for a lunar core which at a period in the Moon's history was the source of the magnetic field. Many of the lunar rocks possess a stable, primary remanence (NRM) with characteristics consistent with and indicative of thermo-remanent magnetization, acquired when the rocks cooled in an ambient magnetic field. Also present are secondary components of magnetization, one type of which appears to have been acquired between collection on the Moon and reception in the laboratory and others which were apparently acquired on the Moon.An important question to be answered is whether meteorite impacts play any part in lunar magnetism, either in modifying pre-existing magnetizations or by imparting a shock remanent magnetism (SRM) in a transient magnetic field associated with the impact. With current knowledge, SRM, in either a global lunar magnetic field of a transient field, and TRM cannot be distinguished, and in the paper the secondary magnetization characteristic of lunar rocks are examined to investigate whether their nature favours the presence of a permanent lunar magnetic field or whether they are consistent with an origin as a transient field-generated SRM.Besides terrestrial processes of secondary magnetization, such as viscous, chemical and partial thermoremanent magnetization, possible processes peculiar to the Moon are discussed and their likely importance assessed in relation to lunar sample history. The nature of the secondary magnetizations appear to be best explained on the assumption that they are due to one or more of the processes that require an ambient lunar field, namely viscous, partial thermoremanent and shock magnetization. When associated with other types of evidence obtained from lunar magnetism studies, investigations of lunar sample remanent magnetism now favours the existence of an ancient lunar magnetic field.  相似文献   

7.
The lunar atmosphere and magnetic field are very tenuous. The solar wind, therefore, interacts directly with the lunar surface material and the dominant nature of interaction is essentially complete absorption of solar-wind particles by the surface material resulting in no upstream bowshock, but a cavity downstream. The solar-wind nitrogen ion species induce and undergo a complex set of reactions with the elements of lunar material and the solar-wind-derived trapped elements. The nitrogen concentration indigeneous to the lunar surface material is practically nil. Therefore any nitrogen and nitrogen compounds found in the lunar surface material are due to the solar-wind implantation of nitrogen ions. The flux of the solar-wind nitrogen ion species is about 6×103 cm–2 s–1. Since there is no evidence for accumulation of nitrogen species in the lunar surface material, the outflux of nitrogen species from the lunar material to the atmosphere is the same as the solar-wind nitrogen ion flux. The species of the outflux are primarily NO and NH3, and their respective concentrations in the near surface lunar atmosphere are found by calculation to be 327 and 295 cm–3. The calculated concentration of NH3 seems to be consistent with the sunrise concentration results of the mass spectrometer implanted on the lunar surface. This is not the case for the concentration of NO. According to the presently calculated concentration value of NO, the mass spectrometer should have detected NO at sunrise, but no report was made for its detection. There is also discrepancy about the concentration of N2 which is explained in this paper. The concentrations of nitrogen species in the lunar material at the time of sample collection on the Moon remained about the same when the samples were analyzed on the Earth. However, no specific experiment was planned to detect the nitrogen species in the lunar material samples.  相似文献   

8.
Substantial indigenous abundances of siderophile elements have been found to be present in the lunar highlands. The abundances of 13 siderophile elements in the parental magma of the highlands crust were estimated by using a simple model whereby the Apollo 16 highlands were regarded as being a mixture of three components (i.e. cumulus plagioclase + intercumulus magma that was parentel to the highlands crust + meteoritic contamination by ordinary chondrites). The parental magma of the highlands was found to possess abundances of siderophile elements that were generally similar to the abundances of the unequivocally indigenous siderophile elements in primitive, low-Ti mare basalts. This striking similarity implies that these estimated abundances in the parental highlands magma are truly indigenous, and also supports the basic validity of our simple model.It is shown that metal/silicate fractionation within the Moon cannot have been the cause of the siderophile element abundances in the parental highlands magma and primitive, low-Ti mare basalts. The relative abundances of the indigenous siderophile elements in highland and mare samples seem, instead, to be the result of complex processes which operatedprior to the Moon's accretion.The abundances of the relatively involatile, siderophile elements in the parental highlands magma are strikingly similar to the abundances observed in terrestrial oceanic tholeiites. Furthermore, the abundances of the relatively volatile, siderophile elements in the parental highlands magma are also systematically related to the corresponding abundances in terrestrial oceanic tholeiites. In fact, the parental magma of the lunar highlands can be essentially regarded as having been a volatile-depleted, terrestrial oceanic tholeiite.The complex, siderophile element fractionations in the Earth's upper mantle are thought to be the result of core segregation. However, it is well-known that the siderophile element abundances do not correspond to expectations based solely upon equilibration of metal/silicate at low-pressures, as evidenced by the over-abundances of Au, Re, Ni, Co and Cu. Ringwood (1977a) has suggested that the siderophile element abundances in the Earth's upper mantle are the product of equilibration at very high-pressures between the mantle and a segregating core that contained substantial quantities of an element with a low atomic weight, such as oxygen. Comparable processes cannot have operated within the Moon due to its small internal pressures and the very small size of its possible core. Therefore, the fact that the Moon exhibits a systematic resemblance to the Earth's upper mantle is highly significant.The origin of the Moon is discussed in the context of these results. The possibility that depletion of siderophile elements occurred in an earlier generation of differentiated planetesimals similar to those which formed the basaltic achondrites, stony-irons, and irons is examined but can be dismissed on several grounds. It seems that the uniquely terrestrial siderophile signature within the Moon can be explained only if the Moon was derived from the Earth's mantle subsequent to core-formation.Paper dedicated to Professor Hannes Alfvén on the occasion of his 70th birthday, 30 May, 1978.  相似文献   

9.
New Trends in the Development of the Lunar Physical Libration Theory   总被引：4，自引：0，他引：4  
A review of the modern state of the lunar libration theory is presented. A significant progress in the lunar investigation is achieved due to the simultaneous processing of results of the satellite Doppler tracing and of the lunar laser ranging. The data evidencing existence of a small iron core in the Moon are discussed. In this connection, the further development of the theory of rotation of the Moon presents the study of internal structure and dynamics of a lunar body. A model of a two-layer Moon can have a very advanced application to explain some observed phenomena and to be as a first approach in the modelling of internal processes determining the lunar rotation.  相似文献   

10.
Crystal/liquid partition coefficients for Cr, V, Mn, and Fe have been determined experimentally between olivine, orthopyroxene, clinopyroxene and silicate melt possesing the composition of a primitive lunar green glass, at oxygen fugacities appropriate to the lunar interior. These species all behave essentially as compatible elements and possess crystal/liquid partition coefficients mostly between 0.3 and 0.9. Partition coefficients for Cr, V, and Mn are generally similar to those of Fe. This implies that crystal/liquid fractionation processes in the lunar interior which do not involve the participation of spinels would not have been effective in fractionating MnO, CrO, and VO from FeO. The well-known constancy of FeO/MnO ratios in nearly all lunar rocks is a reflection of this behaviour. It is shown that comparably strong correlations between CrO-;FeO and VO-;FeO exist for lunar highland breccias and soils from all sites and that these correlations extend to primitive lunar volcanic glasses associated with mare volcanism, strongly suggesting that the CrO/FeO and VO/FeO ratios so derived are of global importance. The observed ratios characterizing differentiated regions of the Moon can be combined with the corresponding ratios for residual refractory portions of the Moon, using measured partition coefficients for Fe, Mg, Cr, V, and Mn between olivine, orthopyroxene and liquid. Bulk Moon abundances for Cr and V have been calculated for a range of reasonable assumptions concerning the petrogenetic relationships between differentiated portions of the Moon and complementary refractory residua consisting of olivine and orthopyroxene mineralogies. Because of the small differences in crystal liquid partition coefficients between FeO, CrO, and VO, these estimates are insensitive to large variations in the models. The bulk Moon is accordingly estimated to contain 2190–2463 ppm Cr and 79–95 ppm V. These values are very similar to the Cr and V contents of the Earth's mantle, estimated as 3010 ppm Cr and 81 ppm V by Sun (1982). The geochemical implications of these similarities are discussed.  相似文献   

11.
For better insight into lunar radio emissions, observations of the Moon were made during the maximal Geminids meteor shower and during the lunar eclipse without external effects. Statistical processing of the obtained data was carried out. It was found that the lunar endogenous and exogenous processes are displayed in both the seismic-emission fields and lunar nonthermal electromagnetic emissions. Both types of signals demonstrate good correlation. The seismic and electromagnetic emission processes have common periodicities, some of which determine the internal structure of the Moon. Similar regularities are expected for other bodies of the Solar System.  相似文献   

12.
The disturbing function of the Moon (Sun) is expanded as a sum of products of two harmonic functions, one depending on the position of the satellite and the other on the position of the Moon (Sun). The harmonic functions depending on the position of the perturbing body are developed into trigonometric series with the ecliptic elementsl, l′, F, D and Γ of the lunar theory which are nearly linear with respect to time. Perturbation of elements are in the form of trigonometric series with the ecliptic lunar elements and the equatorial elements ω and Ω of the satellite so that analytic integration is simple and the results accurate over a long period of time.  相似文献   

13.
The processes of solar wind sputtering and meteoritic impact vaporization have created materials in the lunar regolith which were deposited from a vapor phase. Although the quantity of such exotic condensed substances should theoretically be comparable with that of materials which have been melted by impacts, their existence in the fines has not been generally recognized. We have investigated the physical and chemical properties of materials deposited from vapors generated by hydrogen-ion sputtering and thermal evaporation of lunar and artificial ferrosilicates. Both processes are highly reducing. The deposits are enriched in Fe, have large, nonselective, optical absorptivities, and contain abundant sub-microscopic, superparamagnetic grains of metallic Fe which exhibit the characteristicg=2.1 ESR resonance. The sputter-deposited films are enriched in heavy elements. Thus the hypothesis that the lunar fines contain several percent of materials deposited from the vapor phase accounts in a natural manner for many of the unusual optical, physical and chemical properties of lunar soils. The vapor-deposits are probably concentrated in the agglutinate particles of the regolith.  相似文献   

14.
Average data for igneous and/or metaigneous rocks and soils from seven lunar sites are presented. There are compositional similarities between Apollo 11 and Luna 16 eastern maria, Ap 12 and 15 western maria and between Ap 16 and L 20 highlands. Subtle differences do exist between the paired mare sites and the two highland sites and striking differences between the eastern and western maria. Chondritic normalized REE (rare earth element) patterns for igneous rocks and soils from all sites range from 7-350 generally with negative Eu anomalies. Anorthositic gabbroes to anorthosites, presumably highland material, exhibit a positive Eu anomaly. The REE patterns or Sr isotopic ratios suggest two lava flows each for the L 16 and Ap 14 sites, at least four lava flows for the Ap 11 and 12 site and about six for the Ap 15 site. Paucity of lunar andesites suggests rather limited lunar chemical differentiation. Norite-KREEP is a prominent component at Ap 12, 14 and 15, less at Ap 11 and 16 and L 16 and apparently very low at the L 20 highland site. Derivation of lunar soils can be best explained using multi-component mixing systems. Characterization of meteoritic impacting bodies is also observed in addition to a steady state veil of 1.9% carbonaceous Cl like material in soils. Interelement correlations impose constraints on the primitive composition of the Moon and on magmatic processes like selective volatilization.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.  相似文献   

15.
The principal rock types in the highlands are highland basalt (gabbroic anorthosite) with 28% Al2O3 and low K Fra Mauro basalt with 18% Al2O3. The chemistry of the highland soils and breccias can be represented by simple mixing models involving these rock types as major constituents. The mixing occurred during the intense highland cratering. Layering observed at the Apennine Front is interpreted as produced the Serenitatis basin collision. The plains-forming Cayley Formation and the Descartes Formation are not volcanic, but are derived from pre-existing highland crust.Although the overall chemical composition of the Moon has been affected by pre-accretion processes (e.g. loss of volatile elements), the composition of the highlands is mainly the result of postaccretion melting and element fractionation. Thus the individual rock types show involatile element distribution patterns, relative to primitive abundances, indicative of solid-liquid equilibria, evidence of post-accretion lunar igneous activity.The chemistry of the primitive green glass component (15426) indicates that the abundance of the involatile elements (REE, Ba, Zr, Hf, Th and U) in the source regions is at most only 2–3 times the abundances in chondrites.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.  相似文献   

16.
Three types of igneous rocks, all ultimately related to basaltic liquids, appear to be common on the lunar surface. They are: (1) iron-rich mare basalts, (2) U-, REE-, and Al-rich basalts (KREEP), and (3) plagioclase-rich or anorthositic rocks. All three rock types are depleted in elements more volatile than sodium and in the siderophile elements when relative element abundances are compared with those of carbonaceous chondrites. The chemistry and age relationships of these rocks suggest that they are derived from a feldspathic, refractory element-rich interior that becomes more pyroxenitic; that is, iron/magnesium-rich; with depth.It is suggested that the deeper parts of the lunar interior tend toward chondritic element abundances. The radial variation in mineralogy and bulk chemical composition inferred from the surface chemistry is probably a primitive feature of the Moon that reflects the accretion of refractory elementenriched materials late in the formation of the body.  相似文献   

17.
A summary of total sulfur abundances representative of the Apollo Missions is presented. Lunar crystalline rocks range from 0 to 3100μg S g−1. Lunar soils range from 310 to 1300μg S g−1. Rock mixing models evaluate the distribution of sulfur and define indigenous rock components and extralunar contributions of sulfur in lunar soils. Extralunar sulfur shows a positive correlation with a CC-1 like meteoritic component and solar wind derived total carbon content in the Apollo 16 and 17 lunar soils. Presented at the 25th International Geological Congress, Sydney, Australia, Section 15, Planetology. Contribution No. 105 from the Center for Meteorite Studies.  相似文献   

18.

Evidence for very recent emission of volatiles on the Moon is primarily of four types: (1) transient lunar optical events observed by Earth-based astronomers; (2) excursions on Apollo SIDE and mass spectrometer instruments; (3) localized Rn222/Po210 enhancements on the lunar surface detected by Apollo 15 and 16 orbital alpha spectrometers; (4) presence in lunar fines of retrapped Ar40 and other volatiles. Available evidence indicates that the release rate of volatile substances into the lunar atmosphere is not steady, but instead sporadic and episodic. Rn222/Po210 anomalies are at locations that are among those from which transient events have most often been reported (edges of maria, certain specific craters), and are probably related to them. Volatiles emitted at maria rims may originate in the Moon's fluid core, reaching the surface through deep cylindrical fault systems that ring the maria borders. The sources of volatiles emitted at craters such as Aristarchus or Tsiolkovsky, which possess floors which are cracked or filled with dark lava and possess central peaks, are more likely to be local pockets of magma or trapped gas at shallower depths. The volatiles are produced directly by radioactive decay (He4, Ar40, Rn) and by heating (other volatiles). The release by heating can occur either during melting or by ‘bakeout’ of unmelted materials. Release of gas into the lunar atmosphere is probably triggered by buildup of its own pressure. This may be assisted by tidal forces exerted on the Moon by the Earth. In addition to independent release, volatile emission is also expected to accompany other lunar activity, such as ash flows, if any lunar volcanism is presently active.

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19.
Possible models for the thermal evolution of the Moon are constrained by a wide assortment of lunar data. In this work, theoretical lunar temperature models are computed taking into account different initial conditions to represent possible accretion models and various abundances of heat sources to correspond to different compositions. Differentiation and convection are simulated in the numerical computational scheme.Models of the thermal evolution of the Moon that fit the chronology of igneous activity on the lunar surface, the stress history of the lunar lithosphere implied by the presence of mascons, and the surface concentrations of radioactive elements, involve extensive differentiation early in lunar history. This differentiation may be the result of rapid accretion and large-scale melting or of primary chemical layering during accretion. Differences in present-day temperatures for these two possibilities are significant only in the inner 1000 km of the Moon and are not resolvable with presently available data.If the Apollo 15 heat flow is a representative value, the average uranium concentration in the moon is 65±15 ppb. This is consistent with achondritic bulk composition (between howardites and eucrites) for the Moon.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.  相似文献   

20.
We find the lunar darkening process could be due neither to simple addition of impact-melted glass nor to addition of devitrified glass to crushed lunar rock. There is evidence that lunar soil grains have thin, very light-absorbing coatings that mask absorption bands, seen in the reflection spectra of freshly crushed lunar rock, in the same manner as they are masked in the spectra of lunar soils. We believe the processes that produce these coatings are (1) deposition of atoms sputtered from lunar soil grains by solar wind particles and (2) deposition of vapor species vaporized from lunar soil grains by micrometeorite impacts. Coatings produced in laboratory simulations of these processes owe their strong light-absorbing properties in large part to the presence of abundant metallic Fe grains smaller than 100 Å in diameter. Another process, which depends on implantation of solar wind protons in lunar soil grains and their later mobilization during micrometeorite impacts to produce metallic Fe in the impact glass, also seems reasonable but has not yet been demonstrated experimentally. As a result of impact vaporization the Moon would preferentially lose minor amounts of light elements, principally monatomic oxygen, and this would result in oxygen depletion in the vapor condensate. This type of fraction would be more extreme on airless bodies with lower escape velocities. Sputtering occurs at higher effective temperatures and this would cause loss of all common rock-forming elements in approximately equal amounts. There would be some bias in this process toward retention of very heavy trace elements— a characteristic that has been observed in the lunar soil. This bias would be less important for smaller airless bodies. We describe an apparent new type of fractionation that occurs during deposition of sputtered atoms. This fractionation favors retention of higher mass atoms over lower mass atoms, and appears to be a linear function of mass. This may explain observed isotopic fractionations in lunar soil, in which the heavier isotope always appears to be enriched relative to the lighter one. This “first bounce fractionation” process should operate on all airless bodies. Na and K apparently do not conform to this fractionation process and have a much greater tendency to escape. This may help explain the presence of high Na concentrations around Io.  相似文献   

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