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1.
Springs are the point of origin for most headwater streams and are important regulators of their chemical composition. We analysed solute concentrations of water emerging from 57 springs within the 3 km2 Fool Creek catchment at the Fraser Experimental Forest and considered sources of spatial variation among them and their influence on the chemical composition of downstream water. On average, calcium and acid neutralizing capacity (bicarbonate-ANC) comprised 50 and 90% of the cation and anion charge respectively, in both spring and stream water. Variation in inorganic chemical composition among springs reflected distinct groundwater sources and catchment geology. Springs emerging through glacial deposits in the upper portion of the catchment were the most dilute and similar to snowmelt, whereas lower elevation springs were more concentrated in cations and ANC. Water emerging from a handful of springs in a geologically faulted portion of the catchment were more concentrated than all others and had a predominant effect on downstream ion concentrations. Chemical similarity indicated that these springs were linked along surface and subsurface flowpaths. This survey shows that springwater chemistry is influenced at nested spatial scales including broad geologic conditions, elevational and spatial attributes and isolated local features. Our results highlight the role of overlapping factors on solute export from headwater catchments.  相似文献   

2.
To evaluate the influence of hydrological processes on dissolved organic carbon (DOC) dynamics in a forested headwater catchment, DOC concentration was observed along the flow path from rainfall to stream water via throughfall, soil water, groundwater, and spring water for 4 years, and DOC flux through the catchment was calculated. The spatial and temporal variations in DOC concentration and flux were compared with physical hydrological observations and the mean residence time of water. In the upslope soil layer, DOC concentrations were not significantly correlated with water fluxes, suggesting that DOC concentrations were not strictly controlled by water fluxes. In the upslope perennial groundwater, DOC concentration was affected by the change in the amount of microbial degradation of DOC produced by changes in the mean residence time of water. In stream water, the temporal variation in DOC concentration was usually affected by changes in DOC concentration of the inflow component via vertical infiltration from above the perennial groundwater. During dry periods, however, the component from inflow via vertical infiltration was negligible and DOC in the upslope perennial groundwater became the major component of stream water DOC. The temporal variation in stream water DOC concentration during baseflow was affected by rainfall patterns over several preceding months. Therefore, records of rainfall over several preceding months are one of the most important factors for predicting changes in DOC concentration on a catchment scale. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

3.
Predicting inter-catchment groundwater flow (IGF) is essential because IGF greatly affects stream water discharge and water chemistry. However, methods for estimating sub-annual IGF and clarifying its mechanisms using minimal data are limited. Thus, we quantified the sub-annual IGF and elucidated its driving factors using the short-term water balance method (STWB) for three forest headwater catchments in Japan (named here catchment A, B and As). Our previous study using the chloride mass balance indicated that annual IGF of catchment A (49.0 ha) can be negligible. Therefore, we calculated the daily evapotranspiration (ET) rate using the Priestley–Taylor expression and the 5-year water balance in catchment A (2010–2014). The sub-annual IGF of the three catchments was then calculated by subtracting the ET rate from the difference between rainfall and stream discharge during the sub-annual water balance periods selected using the STWB. The IGF rates of catchment B (7.0 ha), which is adjacent to catchment A, were positive in most cases, indicating that more groundwater flowed out of the catchment than into it, and exhibited positive linear relationships with rainfall and stream discharge. This suggested that as the catchments became wetter, more groundwater flowed out of catchment B. Conversely, the IGF rates of catchment As (5.3 ha), included in catchment A, were negative in most cases, indicating that more groundwater flowed into the catchment than out from it, and exhibited negative linear relationships with rainfall and stream discharge. Given the topography of the catchments studied, infiltration into the bedrock was the probable reason for the IGF outflow from catchment B. We hypothesized that in catchment As, the discrepancy between the actual hydrological boundary and the surface topographic boundary could have caused an IGF inflow. This study provides a useful tool for determining an IGF model structure to be incorporated into rainfall-runoff models.  相似文献   

4.
Stream solute monitoring has produced many insights into ecosystem and Earth system functions. Although new sensors have provided novel information about the fine-scale temporal variation of some stream water solutes, we lack adequate sensor technology to gain the same insights for many other solutes. We used two machine learning algorithms – Support Vector Machine and Random Forest – to predict concentrations at 15-min resolution for 10 solutes, of which eight lack specific sensors. The algorithms were trained with data from intensive stream sensing and manual stream sampling (weekly) for four full years in a hydrologic reference stream within the Hubbard Brook Experimental Forest in New Hampshire, USA. The Random Forest algorithm was slightly better at predicting solute concentrations than the Support Vector Machine algorithm (Nash-Sutcliffe efficiencies ranged from 0.35 to 0.78 for Random Forest compared to 0.29 to 0.79 for Support Vector Machine). Solute predictions were most sensitive to the removal of fluorescent dissolved organic matter, pH and specific conductance as independent variables for both algorithms, and least sensitive to dissolved oxygen and turbidity. The predicted concentrations of calcium and monomeric aluminium were used to estimate catchment solute yield, which changed most dramatically for aluminium because it concentrates with stream discharge. These results show great promise for using a combined approach of stream sensing and intensive stream discrete sampling to build information about the high-frequency variation of solutes for which an appropriate sensor or proxy is not available.  相似文献   

5.
Uncertainty in the estimation of hydrologic export of solutes has never been fully evaluated at the scale of a small‐watershed ecosystem. We used data from the Gomadansan Experimental Forest, Japan, Hubbard Brook Experimental Forest, USA, and Coweeta Hydrologic Laboratory, USA, to evaluate many sources of uncertainty, including the precision and accuracy of measurements, selection of models, and spatial and temporal variation. Uncertainty in the analysis of stream chemistry samples was generally small but could be large in relative terms for solutes near detection limits, as is common for ammonium and phosphate in forested catchments. Instantaneous flow deviated from the theoretical curve relating height to discharge by up to 10% at Hubbard Brook, but the resulting corrections to the theoretical curve generally amounted to <0.5% of annual flows. Calibrations were limited to low flows; uncertainties at high flows were not evaluated because of the difficulties in performing calibrations during events. However, high flows likely contribute more uncertainty to annual flows because of the greater volume of water that is exported during these events. Uncertainty in catchment area was as much as 5%, based on a comparison of digital elevation maps with ground surveys. Three different interpolation methods are used at the three sites to combine periodic chemistry samples with streamflow to calculate fluxes. The three methods differed by <5% in annual export calculations for calcium, but up to 12% for nitrate exports, when applied to a stream at Hubbard Brook for 1997–2008; nitrate has higher weekly variation at this site. Natural variation was larger than most other sources of uncertainty. Specifically, coefficients of variation across streams or across years, within site, for runoff and weighted annual concentrations of calcium, magnesium, potassium, sodium, sulphate, chloride, and silicate ranged from 5 to 50% and were even higher for nitrate. Uncertainty analysis can be used to guide efforts to improve confidence in estimated stream fluxes and also to optimize design of monitoring programmes. © 2014 The Authors. Hydrological Processes published John Wiley & Sons, Ltd.  相似文献   

6.
Measurements of soil water potential and water table fluctuations suggest that morphologically distinct soils in a headwater catchment at the Hubbard Brook Experimental Forest in New Hampshire formed as a result of variations in saturated and unsaturated hydrologic fluxes in the mineral soil. Previous work showed that each group of these soils had distinct water table fluctuations in response to precipitation; however, observed variations in soil morphology also occurred above the maximum height of observed saturation. Variations in unsaturated fluxes have been hypothesized to explain differences in soil horizon thickness and presence/absence of specific horizons but have not been explicitly investigated. We examined tensiometer and shallow groundwater well records to identify differences in unsaturated water fluxes among podzols that show distinct morphological and chemical differences. The lack of vertical hydraulic gradients at the study sites suggests that lateral unsaturated flow occurs in several of the soil units. We propose that the variations in soil horizon thickness and presence/absence observed at the site are due in part to slope‐parallel water flux in the unsaturated portion of the solum. In addition, unsaturated flow may be involved in the translocation of spodic material that primes those areas to contribute water with distinct chemistry to the stream network and represents a potential source/sink of organometallic compounds in the landscape.  相似文献   

7.
Groundwater movements in volcanic mountains and their effects on streamflow discharge and representative elementary area (REA) have remained largely unclear. We surveyed the discharge and chemical composition of spring and stream water in two catchments: the Hontani river (NR) catchment (6.6 km2) and the Hosotani river (SR) catchment (4.0 km2) at the southern part of Daisen volcano, Japan. Daisen volcano is a young volcano (17 × 103 years) at an early stage of erosion. Our study indicated that deep groundwater that moved through thick lava and pyroclastic flows and that could not be explained by shallow movements controlled by surface topography contributed dominantly to streamflow at larger catchment areas. At the NR catchment, the deep groundwater contribution clearly increased at a catchment boundary defined by an area of 3.0 km2 and an elevation of 800 m. At the SR catchment, the contribution deep groundwater to the stream also increased suddenly at a boundary threshold of 2.0 and 700 m. Beyond these thresholds, the contributions of deep bedrock groundwater remained constant, indicating that the REA is between 2 and 3 km2 at the observed area. These results indicate that the hydrological conditions of base flow were controlled mainly by the deep bedrock groundwater that moved through thick lava and pyroclastic flows in the undissected volcanic body of the upper part of the catchment. Our study demonstrates that deep and long groundwater movements via a deep bedrock layer including thick deposits of volcanic materials at the two catchments on Daisen volcano strongly determined streamflow discharge instead of the mixing of small‐scale hydrological conditions. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

8.
The quantitative evaluation of the effects of bedrock groundwater discharge on spatial variability of stream dissolved organic carbon (DOC), dissolved inorganic nitrogen (DIN) and dissolved inorganic phosphorous (DIP) concentrations has still been insufficient. We examined the relationships between stream DOC, DIN and DIP concentrations and bedrock groundwater contribution to stream water in forest headwater catchments in warm-humid climate zones. We sampled stream water and bedrock springs at multiple points in September and December 2013 in a 5 km2 forest headwater catchment in Japan and sampled groundwater in soil layer in small hillslopes. We assumed that stream water consisted of four end members, groundwater in soil layer and three types of bedrock groundwater, and calculated the contributions of each end member to stream water from mineral-derived solute concentrations. DOC, DIN and DIP concentrations in stream water were compared with the calculated bedrock groundwater contribution. The bedrock groundwater contribution had significant negative linear correlation with stream DOC concentration, no significant correlation with stream DIN concentration, and significant positive linear correlation with stream DIP concentration. These results highlighted the importance of bedrock groundwater discharge in establishing stream DOC and DIP concentrations. In addition, stream DOC and DIP concentrations were higher and lower, respectively, than those expected from end member mixing of groundwater in soil layer and bedrock springs. Spatial heterogeneity of DOC and DIP concentrations in groundwater and/or in-stream DOC production and DIP uptake were the probable reasons for these discrepancies. Our results indicate that the relationships between spatial variability of stream DOC, DIN and DIP concentrations and bedrock groundwater contribution are useful for comparing the processes that affect stream DOC, DIN and DIP concentrations among catchments beyond the spatial heterogeneity of hydrological and biogeochemical processes within a catchment.  相似文献   

9.
Non-perennial streams comprise over half of the global stream network and impact downstream water quality. Although aridity is a primary driver of stream drying globally, surface flow permanence varies spatially and temporally within many headwater streams, suggesting that these complex drying patterns may be driven by topographic and subsurface factors. Indeed, these factors affect shallow groundwater flows in perennial systems, but there has been only limited characterisation of shallow groundwater residence times and groundwater contributions to intermittent streams. Here, we asked how groundwater residence times, shallow groundwater contributions to streamflow, and topography interact to control stream drying in headwater streams. We evaluated this overarching question in eight semi-arid headwater catchments based on surface flow observations during the low-flow period, coupled with tracer-based groundwater residence times. For one headwater catchment, we analysed stream drying during the seasonal flow recession and rewetting period using a sensor network that was interspersed between groundwater monitoring locations, and linked drying patterns to groundwater inputs and topography. We found a poor relationship between groundwater residence times and flowing network extent (R2 < 0.24). Although groundwater residence times indicated that old groundwater was present in all headwater streams, surface drying also occurred in each of them, suggesting old, deep flowpaths are insufficient to sustain surface flows. Indeed, the timing of stream drying at any given point typically coincided with a decrease in the contribution from near-surface sources and an increased relative contribution of groundwater to streamflow at that location, whereas the spatial pattern of drying within the stream network typically correlated with locations where groundwater inputs were most seasonally variable. Topographic metrics only explained ~30% of the variability in seasonal flow permanence, and surprisingly, we found no correlation with seasonal drying and down-valley subsurface storage area. Because we found complex spatial patterns, future studies should pair dense spatial observations of subsurface properties, such as hydraulic conductivity and transmissivity, to observations of seasonal flow permanence.  相似文献   

10.
There has been a great deal of research interest regarding changes in flow path/runoff source with increases in catchment area. However, there have been very few quantitative studies taking subscale variability and convergence of flow path/runoff source into account, especially in relation to headwater catchments. This study was performed to elucidate how the contributions and discharge rates of subsurface water (water in the soil layer) and groundwater (water in fractured bedrock) aggregate and change with catchment area increase, and to elucidate whether the spatial variability of the discharge rate of groundwater determines the spatial variability of stream discharge or groundwater contribution. The study area was a 5‐km2 forested headwater catchment in Japan. We measured stream discharge at 113 points and water chemistry at 159 points under base flow conditions. End‐member mixing analysis was used to separate stream water into subsurface water and groundwater. The contributions of both subsurface water and groundwater had large variability below 1 km2. The contribution of subsurface water decreased markedly, while that of groundwater increased markedly, with increases in catchment area. The specific discharge of subsurface water showed a large degree of variability and decreased with catchment area below 0.1 km2, becoming almost constant above 0.1 km2. The specific discharge of groundwater showed large variability below 1 km2 and increased with catchment area. These results indicated that the variabilities of stream discharge and groundwater contribution corresponded well with the variability of the discharge rate of groundwater. However, below 0.1 km2, it was necessary to consider variations in the discharge rates of both subsurface water and groundwater. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

11.
Understanding natural variation in stream phosphorus (P) concentrations over space and time is critical for understanding natural drivers of catchment behavior and establishing regulatory standards. Across minimally impacted benchmark streams (n = 81) in Florida, spatial variation in mean total P concentrations was large, indicating the importance of geologic controls on catchment solute dynamics. While this variation was significantly predicted by geographic regions, within regions we observed nearly comparable cross‐site variation, suggesting important finer‐scale heterogeneity in baseline catchment chemistry. Within‐site residual variation (unexplained by region or site) was as large as spatial variation, suggesting temporal variation in response to drivers such as flow may be critically important. To further explore timescales of P export variation, we collected long‐term, high‐frequency (subdaily) measurements of stream discharge (Q) and soluble reactive P (SRP) in 2 forested watersheds. We observed significant variation at annual, event, and diel timescales, all of which arise primarily from corresponding Q‐variation. Over the entire period of record, we generally observed a strong dilution signal, with SRP concentrations declining with increased Q. Despite significant SRP variation, flow variation was far larger and, thus, dominated temporal control on downstream flux. Within‐storm events, we observed strong and consistent clockwise SRP versus Q hysteresis, suggesting mobilization of proximal SRP stores. Diel variation exhibited mid‐afternoon concentration minima, Q‐controlled amplitude, and pronounced seasonal shifts in both magnitude and timing consistent with riparian evapotranspiration‐regulating lateral inputs of P‐rich groundwater. Such high‐resolution temporal signals allow identification of solute sources and provide insights into geologic and hydrologic drivers of solute variation.  相似文献   

12.
Conservative solute injections were conducted in three first-order montane streams of different geological composition to assess the influence of parent lithology and alluvial characteristics on the hydrological retention of nutrients. Three study sites were established: (1) Aspen Creek, in a sandstone–siltstone catchment with a fine-grained alluvium of low hydraulic conductivity (1·3×10−4 cm/s), (2) Rio Calaveras, which flows through volcanic tuff with alluvium of intermediate grain size and hydraulic conductivity (1·2×10−3 cm/s), and (3) Gallina Creek, located in a granite/gneiss catchment of coarse, poorly sorted alluvium with high hydraulic conductivity (4·1×10−3 cm/s). All sites were instrumented with networks of shallow groundwater wells to monitor interstitial solute transport. The rate and extent of groundwater–surface water exchange, determined by the solute response in wells, increased with increasing hydraulic conductivity. The direction of surface water–groundwater interaction within a stream was related to local variation in vertical and horizontal hydraulic gradients. Experimental tracer responses in the surface stream were simulated with a one-dimensional solute transport model with inflow and storage components (OTIS). Model-derived measures of hydrological retention showed a corresponding increase with increasing hydraulic conductivity. To assess the temporal variability of hydrological retention, solute injection experiments were conducted in Gallina Creek under four seasonal flow regimes during which surface discharge ranged from baseflow (0·75 l/s in October) to high (75 l/s during spring snowmelt). Model-derived hydrological retention decreased with increasing discharge. The results of our intersite comparison suggest that hydrological retention is strongly influenced by the geologic setting and alluvial characteristics of the stream catchment. Temporal variation in hydrological retention at Gallina Creek is related to seasonal changes in discharge, highlighting the need for temporal resolution in studies of the dynamics of surface water–groundwater interactions in stream ecosystems. © 1997 by John Wiley & Sons, Ltd.  相似文献   

13.
Stream chemistry is often used to infer catchment‐scale biogeochemical processes. However, biogeochemical cycling in the near‐stream zone or hydrologically connected areas may exert a stronger influence on stream chemistry compared with cycling processes occurring in more distal parts of the catchment, particularly in dry seasons and in dry years. In this study, we tested the hypotheses that near‐stream wetland proportion is a better predictor of seasonal (winter, spring, summer, and fall) stream chemistry compared with whole‐catchment averages and that these relationships are stronger in dryer periods with lower hydrologic connectivity. We evaluated relationships between catchment wetland proportion and 16‐year average seasonal flow‐weighted concentrations of both biogeochemically active nutrients, dissolved organic carbon (DOC), nitrate (NO3‐N), total phosphorus (TP), as well as weathering products, calcium (Ca), magnesium (Mg), at ten headwater (<200 ha) forested catchments in south‐central Ontario, Canada. Wetland proportion across the entire catchment was the best predictor of DOC and TP in all seasons and years, whereas predictions of NO3‐N concentrations improved when only the proportion of wetland within the near‐stream zone was considered. This was particularly the case during dry years and dry seasons such as summer. In contrast, Ca and Mg showed no relationship with catchment wetland proportion at any scale or in any season. In forested headwater catchments, variable hydrologic connectivity of source areas to streams alters the role of the near‐stream zone environment, particularly during dry periods. The results also suggest that extent of riparian zone control may vary under changing patterns of hydrological connectivity. Predictions of biogeochemically active nutrients, particularly NO3‐N, can be improved by including near‐stream zone catchment morphology in landscape models.  相似文献   

14.
Topography and landscape characteristics affect the storage and release of water and, thus, groundwater dynamics and chemistry. Quantification of catchment scale variability in groundwater chemistry and groundwater dynamics may therefore help to delineate different groundwater types and improve our understanding of which parts of the catchment contribute to streamflow. We sampled shallow groundwater from 34 to 47 wells and streamflow at seven locations in a 20‐ha steep mountainous catchment in the Swiss pre‐Alps, during nine baseflow snapshot campaigns. The spatial variability in electrical conductivity, stable water isotopic composition, and major and trace ion concentrations was large and for almost all parameters larger than the temporal variability. Concentrations of copper, zinc, and lead were highest at sites that were relatively dry, whereas concentrations of manganese and iron were highest at sites that had persistent shallow groundwater levels. The major cation and anion concentrations were only weakly correlated to individual topographic or hydrodynamic characteristics. However, we could distinguish four shallow groundwater types based on differences from the catchment average concentrations: riparian zone‐like groundwater, hillslopes and areas with small upslope contributing areas, deeper groundwater, and sites characterized by high magnesium and sulfate concentrations that likely reflect different bedrock material. Baseflow was not an equal mixture of the different groundwater types. For the majority of the campaigns, baseflow chemistry most strongly resembled riparian‐like groundwater for all but one subcatchment. However, the similarity to the hillslope‐type groundwater was larger shortly after snowmelt, reflecting differences in hydrologic connectivity. We expect that similar groundwater types can be found in other catchments with steep hillslopes and wet areas with shallow groundwater levels and recommend sampling of groundwater from all landscape elements to understand groundwater chemistry and groundwater contributions to streamflow.  相似文献   

15.
We examined how and why dominant peak-flow runoff-generation mechanisms differ among neighbouring headwater catchments. We monitored runoff and groundwater levels and performed terrain analyses in a granitic second-order catchment and its four neighbouring subcatchments in the Kiryu Experimental Watershed in Japan. Our analysis of lag times from peak rainfall to peak runoff suggests differences in the dominant peak-flow runoff-generation mechanisms among the five catchments. For two of the three zero-order catchments, with few perennial groundwater bodies, subsurface flow from hillslopes was the dominant mechanism at some events. However, the dominant mechanisms were channel precipitation and riparian runoff at almost all events in first- and second-order catchments and in the third zero-order catchment, which has a large perennial groundwater body over a bedrock depression in the riparian zone. In this zero-order catchment, the quick-flow ratio was the smallest of the five catchments because subsurface flow from the hillslope was buffered at the riparian zone. These facts suggest that the channel length, riparian buffering, and hillslope connectivity were the factors governing the different dominant peak-flow runoff-generation mechanisms among the catchments. Riparian buffering was affected, not only by surface topography, but also by bedrock topography and bedrock groundwater (BGW) dynamics. Our findings indicate that both of BGW dynamics and topography are important for catchment classification, and the relative importance of topography increases with the change from baseflow to stormflow. Furthermore, mismatching between a geographic source and a flow path resulted in different catchment classifications depending on the approach. Therefore, multiple approaches during both baseflow and stormflow periods are necessary for catchment classification to apply information obtained from one headwater catchment to other headwater catchments within the same region.  相似文献   

16.
R. L. BASSETT 《水文研究》1997,11(7):695-717
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17.
We examined the contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments by conducting detailed hydrochemical observations in five catchments that ranged from zero to second order. End‐member mixing analysis (EMMA) was performed to identify the geographical sources of stream water. Throughfall, hillslope groundwater, shallow bedrock groundwater, and deep bedrock groundwater were identified as end members. The contribution of each end member to storm runoff differed among the catchments because of the differing quantities of riparian groundwater, which was recharged by the bedrock groundwater prior to rainfall events. Among the five catchments, the contribution of throughfall was highest during both baseflow and storm flow in a zero‐order catchment with little contribution from the bedrock groundwater to the riparian reservoir. In zero‐order catchments with some contribution from bedrock groundwater, stream water was dominated by shallow bedrock groundwater during baseflow, but it was significantly influenced by hillslope groundwater during storms. In the first‐order catchment, stream water was dominated by shallow bedrock groundwater during storms as well as baseflow periods. In the second‐order catchment, deeper bedrock groundwater than that found in the zero‐order and first‐order catchments contributed to stream water in all periods, except during large storm events. These results suggest that bedrock groundwater influences the upscaling of storm‐runoff generation processes by affecting the linkages of geomorphic units such as hillslopes, riparian zones, and stream channels. Our results highlight the need for a three‐dimensional approach that considers bedrock groundwater flow when studying the upscaling of storm‐runoff generation processes. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

18.
The dominance of ‘old’ pre‐event water in headwater storm runoff has been recorded in numerous upland catchment studies; however, the mechanisms by which this pre‐event water enters the stream channel are poorly understood. Understanding these processes is fundamental to determining the controls on surface water quality and associated impacts on stream ecology. Previous studies in the upland forested catchment of the Afon Hafren (River Severn) at Plynlimon, mid‐Wales, identified an active bedrock groundwater system that was discharging into the stream channel during storm response. Detailed analysis showed that these discharges were small and could not account for the majority of pre‐event storm water response identified at this site; pre‐event storm runoff had to be sourced predominantly from further upstream. An intensive stream survey was used to determine the spatial nature of groundwater–surface water (GW–SW) interactions in the Hafren Catchment. Detailed physico‐chemical in‐stream profiling identified a marked change in water quality indicating a significant discrete point of bedrock groundwater discharge upstream of the Hafren Transect study site. The in‐stream profiling showed the importance of high spatial resolution sampling as a key to understanding processes of GW–SW interaction and how quick and cost‐effective measurements of specific electrical conductance of stream waters could be used to highlight in‐stream heterogeneity. This approach is recommended for use in headwater catchments for initial characterisation of the stream channel in order to better locate instrumentation and to determine more effective targeted sampling protocols in upland catchment research. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

19.
Josep Pi  ol  Anna   vila  Ferran Rod 《Journal of Hydrology》1992,140(1-4):119-141
Streamwater chemistry is described for three streams draining undisturbed, evergreen broad-leaved forested catchments on phyllites in NE Spain: two streams with no or negligible flow in summer are located in the Prades massif, and one perennial stream is in the wetter Montseny mountains. Weekly data for a study period of 2–4 years are provided to (1) describe the seasonal variations in streamwater chemistry, (2) analyse the relationship between stream discharge and solute concentrations using a two-component mixing model and (3) search for patterns of temporal variation in stream solute concentrations after discounting the effects of discharge. At Prades, concentrations of all analysed ions, except NO−3, showed marked seasonal variations in stream water, whereas at Montseny only ions related to mineral weathering (HCO−3, Na+, Ca2+ and Mg2+) showed strong seasonality. Ion concentrations were more closely dependent on instantaneous discharge at Montseny than at Prades. The residuals of the relationship between solute concentrations and discharge retained a strong seasonality at Prades, but not at Montseny. These differences are related to the major hydrochemical processes that determine the streamwater chemistry at each site. The same processes are probably operative in the three catchments, but are of varying relative importance. At Montseny, the mixing of waters of different chemical composition seems to be the major process controlling streamwater chemistry, although the soilwater end-member composition predicted by the mixing model applied did not match the measured soilwater chemistry. In the drier Prades catchments, the two major hydrochemical processes determining the seasonal variation of streamwater chemistry are (1) the restart of flow after the summer drought, which flushes out the solutes accumulated during the dry period, and (2) the seasonal changes in groundwater chemistry that result from the interplay of water residence time, temperature and CO2 partial pressure. In Mediterranean catchments with relatively high precipitation, such as Montseny, the seasonal variation in the streamwater chemistry is largely determined by the same processes as at humid-temperate sites, whereas in drier Mediterranean catchments, such as Prades, the major hydrochemical processes are clearly distinct.  相似文献   

20.
This data note describes the Biscuit Brook and Neversink Reservoir watershed long-term monitoring data that includes: 1) stream discharge, (1983–2020 for Biscuit Brook and 1937–2020 for the Neversink Reservoir watershed), 2) stream water chemistry, 1983–2020, at 4 stations, 3) fish survey data from 16 locations in the watershed 1990–2019, 4) soil chemistry data from 2 headwater sub-watersheds, 1993–2012 and 5) periodic stream water chemistry sampling data from 364 locations throughout the watershed, 1983–2020. The Neversink Reservoir watershed in the Catskill Mountains of New York, USA drains an area of 172.5 km2. The watershed feeds one of six reservoirs in New York City's West of Hudson water supply, which accounts for about 90% of the city's water supply. Biscuit Brook is a 9.63 km2 tributary sub-watershed within the Neversink Reservoir watershed.  相似文献   

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