首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Fluorine-bearing minerals are uncommon in submarine exhalative ores, exhalites and associated alteration zones, probably because of the low solubility of CaF2. The Broken Hill (Australia) deposit contains fluorapatite and fluorite with one lens containing 1.35% F and greater than 3 volume % F-bearing minerals. The calcite-fluorite-fluorapatite assemblage at Broken Hill indicates that ore deposition was probably from hypersaline fluorine-bearing fluids which decreased in pH by base leaching reactions which released Ca2+ and mixing with seawater promoting the rapid and simultaneous precipitation of calcite, fluorite and fluorapatite as a result of temperature and salinity decrease and pH and [Ca2+] increase. The abundance of fluorine minerals in the Broken Hill ore and the association of F and B minerals with stratigraphically equivalent W- and Sn-bearing exhalites suggest that F complexes are important for ore transport in some exhalative systems. The Fe/Mn ratio decreases and the F/Cl ratio increases in fluorapatite in exhalites with increasing proximity to the Broken Hill deposit.  相似文献   

2.
Sixteen unpublished analyses of Broken Hill manganese silicates (two pyrox‐mangite, one rhodonite, four hedenbergite, and nine bustamite) from the papers of the late Dr W. T. Schaller are presented. They have been complemented with additional analyses by the electron microprobe to define the compositional fields of these minerals. Data are provided on the relationship of these minerals with tephroite and garnet. The occurrence of roepperite (zincian tephroite) at Broken Hill is discredited, and its validity is doubtful. Dannemorite from Broken Hill has a composition close to Mn2(Fe,Mg)5Si8O22(OH)2, and can be considered a valid amphibole subspecies.  相似文献   

3.

Nd isotope studies of the oldest metasedimentary rocks from the Wonominta Block, western New South Wales reveal that these samples have a model age (TDM) of 1780–2010 Ma, slightly younger than that of low‐grade Willyama Supergroup metasediments (1920–2160 Ma), and significantly younger than those ages previously reported from high‐grade rocks of the Broken Hill Block (2200–2300 Ma). These differences have important implications for tectonic reconstruction in this region and support a model of transitional tectonics from the Broken Hill to Wonominta Blocks, as suggested by earlier geochemical studies of mafic rocks. Those studies revealed that the mafic rocks from the basal sequence of the Wonominta Block may have formed in a back‐arc basin, developed from a propagating rifting, an environment contiguous to that in which Willyama Supergroup was deposited. These results also carry significant implications for tectonic reconstruction of eastern Australia.  相似文献   

4.
Phase compositions in pelitic and mafic gneisses place tight constraints on pressure (ranging from 3 up to 6 kb), and, to a lesser extent, on temperature (500° up to 800° C) during prograde regional metamorphism of the Willyama Complex, Broken Hill, SE Australia. These limits allow an evaluation of water activity across the terrain using various equilibria in pelitic and mafic gneisses. The stability of cummingtonite and biotite over much of the terrain places upper limits on temperature, and the presence of syn-metamorphic partial melts in the metasediments places lower limits on a(H2O). Garnet-biotitesillimanite-K feldspar-quartz relations combined with the partial melting data suggest a decrease in water activity from near 1.0 in the lower grade zones to 0.5±0.2 in the Broken Hill — Little Broken Hill part of the two pyroxene zone. This result is compatible with less precise hornblende-orthopyroxene-clinopyroxene-quartz relations.These P-T-a(H2O) data from the Willyama Complex support a continuum from amphibolite to granulite facies, as proposed by Binns (1964) and suggest that the higher grade assemblages are formed in response to both higher temperature and lower water activity. The formation of granulite facies terrains by prior crustal dehydration is unsubstantiated in the present example. Instead, the decrease from a(H2O)-1.0 in the andalusite/sillimanite-muscovite zones to a(H2O) < 1.0 found at higher grades, is likely to reflect buffering by partial melting and dehydration reactions in the volumetrically dominant metasediments.  相似文献   

5.
Three sheet‐like bodies of felsic gneiss containing abundant K‐feldspar megacrysts (megacrystic felsic gneiss, augen gneiss or granite gneiss) surrounding the Broken Hill Line of Lode in western New South Wales, Australia, are inferred to be pre‐ to syn‐D1 granitoids. We interpret the Feral gneiss to be a pre‐ to early syn‐D1 intrusion, as it contains S1 as its earliest foliation. However, it has no magmatic flow foliation. The Alma Gneiss, and the megacrystic portions of the Rasp Ridge Gneiss, northwest of the Line of Lode, both contain S1 parallel to a magmatic flow foliation, and are interpreted as having been magmatic during D1. Therefore, the Alma and Rasp Ridge Gneisses may have been intruded during D1, probably just after the Feral gneiss, as the Alma Gneiss intrudes the Feral gneiss. S1 in the augen gneisses and the wall rocks is defined by biotite, sillimanite, garnet and ribbon quartz, and indicates that high‐grade metamorphic conditions accompanied D1. Evidence suggesting that these rocks were originally granitoids includes: (i) the Alma Gneiss transecting and intricately intruding the Feral gneiss, the contacts being transected by S1; (ii) euhedral to subhedral K‐feldspar porphyroclasts (former phenocrysts), especially those with concentrically arranged inclusions; (iii) microgranitoid enclaves, particularly where megacrystic and relatively large; (iv) aplite dykes (most common in plutonic rocks and therefore reliable indicators); (v) metasedimentary xenoliths; (vi) magmatic flow foliations overprinted by parallel tectonic foliations; and (vii) chemical affinities with undoubted Australian Proterozoic granitoids. Therefore, felsic gneisses at Broken Hill should not be used for stratigraphic correlation, unless they can be definitely determined to be of volcanic flow or tuffaceous origin. The inferred intrusion of granitoids early in the tectonic history of the Broken Hill Block suggests that they may have contributed to the metamorphic and/or hydrothermal heat, and may have helped concentrate metals to form orebodies.  相似文献   

6.
The Redan Geophysical Zone forms a regional magnetic high in contrast to the regional magnetic low defined by the main part of the Broken Hill Block. The magnetic rocks are interpreted to dip below the remainder of the Broken Hill Block and there has been speculation that they are significantly older than the Early Proterozoic Willyama Supergroup.

Evaluation of lithological mapping and aeromagnetic data permitted interpretation of a stratigraphic sequence within the Redan Geophysical Zone, consisting of three new formations: the Redan Gneiss, Ednas Gneiss and Mulculca Formation, plus the Lady Brassey Formation, part of the Thackaringa Group. The rocks are considered to belong to the lower part of the Willyama Supergroup and are not an older basement.

Although the Redan Geophysical Zone contains some rock types not found elsewhere in the Broken Hill Block, there are some lithological similarities with the lower part of the Willyama Supergroup: an abundance of albite‐rich rocks, the presence of quartz‐magnetite rocks with Cu and trace Co, and abundant amphibolite/ basic granulite in the Lady Brassey Formation.

The boundary between the Redan Geophysical Zone and the remainder of the Broken Hill Block appears to be conformable, with no evidence of major faulting. Similarly no evidence of unconformities or major displacement of stratigraphic boundaries has been found within the Redan Geophysical Zone. Structural history, fold style and orientation, and metamorphic grade within the Redan Geophysical Zone are similar to adjacent areas of the Broken Hill Block.

It is concluded that the Broken Hill Block contains no outcropping equivalent of the first cycle of sedimentary/ igneous rocks recognized in the Early Proterozoic of northern Australia.

Albite‐quartz‐hornblende‐magnetite rocks unique to the Redan Geophysical Zone most likely comprised detritus derived directly from an intermediate volcanic suite. Some were altered considerably, while other rocks retained the dacite/andesite composition, except for the addition of Na, an increase in the oxidation state, and partial leaching of some of the more mobile elements. These modifications could have taken place in shallow alkaline evaporitic lakes.

The Redan Geophysical Zone contains some of the elements of a foreland basin adjacent to a continental volcanic arc: a thick stratigraphic sequence, oxidizing evaporitic conditions, and intermediate volcanic detritus. The change from intermediate‐acid volcanism in the earliest formations, to bimodal acid/basic volcanism in the Thackaringa and Broken Hill Groups could correspond with a change from initial continental arc volcanism into bimodal rift volcanism. The case for the arc volcanism is weakened, however, by the relative scarcity of rocks with andesitic compositions and the lack of basaltic andesite compositions. The alternative is that the intermediate to acid volcanism represents only a variation on the later bimodal rift volcanism.  相似文献   

7.
The Willyama Supergroup of the Broken Hill region in southern Australia consists of supracrustal sedimentary and magmatic rocks, formed between 1810 and 1600 Ma. A statistical analysis of nearly 2000 SHRIMP U–Pb zircon spot ages, compiled from published and unpublished sources, provides evidence for three distinct tectonostratigraphic successions and four magmatic events during this interval. Succession 1 includes Redan Geophysical Zone gneisses and the lower part of the Thackaringa Group (Cues Formation). These rocks were deposited after 1810 Ma and host granite sills of the first magmatic event (1710–1700 Ma). Succession 2 includes the upper Thackaringa Group (Himalaya Formation), the Broken Hill Group and the Sundown Group and was deposited between 1710 and 1660 Ma. These rocks all contain detrital zircons from the first magmatic event (1710–1700 Ma) and in some cases from the second magmatic event (1690–1680 Ma). The second magmatic event (1690–1680 Ma) was bimodal, resulted from crustal extension, and was coeval with deposition of the Broken Hill Group and deepening of the basin. With this event a mafic sill swarm focused in the Broken Hill Domain. Mafic sills lack any trace of inheritance, unlike the granitoids that commonly contain inherited zircons typical of the supracrustal sediments. Succession 3, the Paragon Group and equivalents were deposited after 1660 Ma, but before a regional metamorphic event at 1600 Ma. Metamorphism was closely followed by inversion of the succession into a fold‐and‐thrust belt, accompanied by a fourth late to post‐orogenic magmatic event (ca 1580 Ma) characterised by granite intrusion and regional acid volcanism (the local equivalents of the Gawler Range Volcanics in South Australia).  相似文献   

8.
The prograde pressure–temperature (P–T) path for the complexly polydeformed Proterozoic Broken Hill Block (Australia) has been reconstructed through detailed structural analysis in conjunction with calculation of compositionally specific P–T pseudosections of pelitic rock units within a high‐temperature shear zone that formed early in the tectonic evolution of the terrane. Whilst the overall P–T path for the Broken Hill Block has been interpreted to be anticlockwise, the prograde portion of this path has been unresolved. Our results have constrained part of this prograde path, showing an early heating event (M1) at P–T conditions of at least c. 600 °C and c. 2.8–4.2 kbar, associated with an elevated geothermal gradient (c. 41–61 °C km?1). This event is interpreted to be the result of rifting at c. 1.69–1.67 Ga, or at c. 1.64–1.61 in the Broken Hill Block. Early rifting was followed by an episode of lithospheric thermal relaxation and burial, during which time sag‐phase sediments of the upper Broken Hill stratigraphy (Paragon Group) were deposited. Following sedimentation, a second tectonothermal event (M2/D2) occurred. This event is associated with peak low‐pressure granulite facies metamorphism (c. 1.6 Ga) and attained conditions of at least 740 °C at c. 5 kbar. A regionally pervasive, high‐temperature fabric (S2) developed during the M2/D2 event, and deformation was accommodated along lithology‐parallel, high‐temperature shear zones. The larger‐scale deformation regime (extensional or shortening) of this event remains unresolved. The M2/D2 event was terminated by intense crustal shortening during the Olarian Orogeny, during which time the first mappable folds within the Broken Hill Block developed.  相似文献   

9.

A heavy mineral concentrate from the undeformed Mundi Mundi Granite N of Broken Hill yielded very few zircons. U‐Th‐Pb measurements on microgram fractions of those extracted showed no indication of the stock's true 1500–1600 Ma intrusive event but revealed something inherited and of an age probably greater than 2 Ga. These zircons, either survivors of those inherited from the magma source or accidental inclusions from the wall rocks, may either represent sedimentary accumulations in the lower Willyama Supergroup with an older craton source i.e. provenance, or indicate the presence of a pre‐Willyama Supergroup basement. Considerable loss of Pb from the zircons is deduced to have occurred at (1) the time of granite intrusion, (2) in the lower Palaeozoic, and, (3) in the case of 208Pb, probably right up to recent time.  相似文献   

10.
The Early‐Middle Proterozoic Broken Hill Block contains three types of W occurrences, which show close stratigraphic control. All three types occur within a relatively narrow stratigraphic interval (the ‘Mine Sequence’ Suite of Stevens et al., 1980) comprising a highly variable group of metamorphosed silicic and mafic volcanics, clastic sediments, and exhalative and chemical sediments containing base metals. The first type includes occurrences of W and base metals in bedded calc‐silicate rocks. In the second type, W occurs in layered to non‐layered calcsilicate rocks associated with amphibolite; these are intimately associated in a narrow stratigraphic interval containing abundant, small, Broken Hill type deposits. The third type comprises stratabound, W‐bearing pegmatites, which have been remobilised from quartz‐feldspar‐biotite gneiss and bedded quartz‐tourmaline rocks. Tungsten has been mined only from the third type and only in small quantities. The three types of tungsten deposits show a close spatial relationship with stratiform and stratabound Pb‐Zn mineralisation, including the Broken Hill type. The Pb‐Zn and W deposits are inferred to be genetically related.  相似文献   

11.
Uncertainty for elemental and isotopic measurements in calcite by LA‐ICP‐MS is largely controlled by the homogeneity of the reference materials (RMs) used for calibration and validation. In order to produce calcite RMs with homogeneous elemental and isotopic compositions, we incorporated elements including U, Pb and rare earth elements into calcite through heat‐ and pressure‐induced crystallisation from amorphous calcium carbonate that was precipitated from element‐doped reagent solution. X‐ray absorption spectra showed that U was present as U(VI) in the synthesised calcite, probably with a different local structure from that of aqueous uranyl ions. The uptake rate of U by our calcite was higher in comparison with synthetic calcite of previous studies. Variations of element mass fractions in the calcite were better than 12% 2RSD, mostly within 7%. The 207Pb/206Pb ratio in the calcite showed < 1% variations, while the 238U/206Pb ratio showed 3–24% variations depending on element mass fractions. Using the synthetic calcite as primary RMs, we could date a natural calcite RM, WC‐1, with analytical uncertainty as low as < 3%. The method presented can be useful to produce calcite with controlled and homogeneous element mass fractions and is a promising alternative to natural calcite RMs for U‐Pb geochronology.  相似文献   

12.
Aluminous, mafic, felsic, calcareous, and sulphide‐rich rocks have been involved in localized deformation and retrograde metamorphism at Broken Hill, western New South Wales, where retrograde schist‐zones intersect high‐grade, regional metamorphic rocks of the lower granulite facies (or the amphibolite‐granulite facies transition). Although technically retrograde, the schists contain mineral assemblages indicative of the lower amphibolite facies. The schist‐zones were formed by local folding, apparently as part of the third stage of deformation in the Broken Hill area.  相似文献   

13.
The replacement by ferroan calcite with preservation of the original structures can be used as a new criterion for identifying skeletons originally composed of high-magnesian calcite. This applies to bryozoa, rugose corals, echinoderms, many foraminifera, most ostracods, red algae, and serpulids. On the other hand, skeletons originally composed of low-magnesian calcite were never replaced by ferroan calcite, as shown by belemnites, brachiopods, and most of the pelecypods. Using this criterion, an original low-magnesian calcite composition is inferred for Tentaculites and some ostracods and foraminifera, whereas a previous high-magnesian calcite composition is inferred for trilobites, oligostegina and certain ooids. Chemical instability of high-magnesian calcite is suggested to be the driving force of the replacement by ferroan calcite. In most of the thirty-seven samples investigated, of Oligocene to Devonian age, the ferrous iron concentration of the interstitial fluid increased during diagenesis, as shown by well established sequences of cement A and B and fissure fill. This offers a relative time scale for diagenetic processes. Ferroan calcites contain up to 6 mol % FeCO3 and up to 5 mol % MgCO3. In this range of concentration, the distribution coefficients for Fe and Mg between calcite and solution at about 25°C are about 1 to 0-03, respectively, according to experiments. Possible sources of iron are iron oxides and hydroxides as well as clay minerals including glauconite. Though a submarine origin below the sediment surface is conceivable for ferroan calcite, there are serious limiting conditions such as low Eh and, at the same time, lack in sulphate-reducing bacteria. On the other hand, ferroan ‘dedolomite’, compositional zonality in individual ferroan calcite overgrowths, low δ18C and δ18O values, and low Mg concentrations point more to a meteoric-phreatic origin of many ferroan calcite occurrences.  相似文献   

14.
Twenty two samples of calcretes from seven depth-profiles in the Menindee catchment, Broken Hill region, Australia were analysed for their inorganic and organic carbon contents and inorganic carbon and oxygen isotopes. The organic carbon content is very low (from 0.06 to 0.31 wt.%) while inorganic carbon (carbonate) is up to 3.9 wt.%. Both δ13C and δ18O become more positive closer to the surface. Carbon isotopes vary from − 8.5‰ to −5.5‰ PDB. Oxygen isotopes vary from − 6‰ to − 1.8‰ V-PDB. Depth-related δ13C and δ18O variations correlate over at least 15 km and show no significant variation along the flow path. δ13C values increase by 3‰ and δ18O values increase by 4‰ with decreasing depth in a 1.40 m thick soil profile. The variation is interpreted to indicate an increasingly elevated air temperature, greater water stress and subsequently an aridification of the area through time. The Broken Hill calcrete data confirm that climatic evolution can be deduced from isotopic series and be applied successfully to the Broken Hill region.  相似文献   

15.
Granite plutons of the Whypalla Supersuite in the Butchers Hill — Helenvale region of north Queensland were intruded into the upper crust of the Hodgkinson Formation during contractional deformation associated with the Permian‐Triassic Hunter‐Bowen Orogeny. A four‐stage structural history has been resolved for the area, with fabric overprinting relationships, porphyroblast‐matrix microstructural geometries and isotopic ages being consistent with granite emplacement during D4 shortening at ca 274 Ma. Microstructural relationships suggest the possibility of a minor syn‐D3 phase of granite emplacement. The deformation‐emplacement history of the Butchers Hill — Helenvale area is consistent with that recognised regionally for the Hodgkinson Province, indicating province‐wide synchronous syntectonic granite intrusion during a major phase of contractional deformation. Intense syn‐emplacement deformation partitioning was ongoing in the country rocks during progressive D4 and was associated with upward translation of country rock from the microscale to the macroscale along D4 cleavages and shears. Kinematic indicators show that this progressive uplift, at the scale of the area examined, was east‐side‐up.  相似文献   

16.
《Applied Geochemistry》2005,20(4):767-787
The supergiant Pb–Zn–Ag Broken Hill orebody and numerous other minor mineral deposits occur within the limited outcrop of the Proterozoic Curnamona Province of Australia. The vast majority of this Province is concealed by up to 200 m of transported regolith, hampering conventional exploration strategies. Approximately 300 groundwater samples were collected over the southern Curnamona Province to test whether this medium could be helpful in the search for hidden mineral deposits. Sulphur, Sr and Pb isotope composition of the groundwaters were determined and S excess (SXS), i.e., the amount of S that can be ascribed neither to evaporation nor to mixing, was calculated. Many samples were recognised to have undergone an addition of 34S-depleted S, which can be attributed to oxidation of sulfides with a Broken Hill type δ34S signature (average ∼0‰ V-CDT). Furthermore, Sr isotopes identify the broad types of bedrock that the groundwater has been interacting with, from the less radiogenic Adelaidean rocks (and minerals) in the west (groundwater 87Sr/86Sr ratio as low as 0.708) to the highly radiogenic Willyama Supergroup in the east (87Sr/86Sr ratio up to 0.737). The groundwaters have 207Pb/204Pb and 206Pb/204Pb ratios comparable to, or intermediate between, various mineralisation types recognised in the area (Broken Hill, Rupee, Thackaringa, etc., types). The few samples taken in the vicinity of known mineralisation yield positive indicators (positive SXS, low δ34S, 87Sr/86Sr signature of bedrock type and Pb isotope fingerprinting of mineralisation type). This study also highlights several new locations under sedimentary cover where these indicators suggest interaction with mineralisation.  相似文献   

17.
In situ measured microprofiles of Ca2+, pCO2, pH and O2 were performed to quantify the CaCO3 dissolution and organic matter mineralization in marine sediments in the eastern South Atlantic. A numerical model simulating the organic matter decay with oxygen was used to estimate the calcite dissolution rate. From the oxygen microprofiles measured at four stations along a 1300-m isobath of the eastern African margin and one in front of the river Niger at a water depth of 2200 m the diffusive oxygen uptake (DOU) and oxygen penetration depth (OPD) was calculated. DOU rates were in the range of 0.3 to 3 mmol m−2 d−1 and showed a decrease with increasing water depth, corresponding to an increase in OPD. The calculated amount of degradated organic matter is in the range of 1 to 8.5 gC m−2 a−1. The metabolic CO2, released from mineralization of the organic matter drives calcite dissolution in these sediments overlain by calcite-supersaturated water. Fluxes across the sediment water interface calculated from the in situ Ca2+ microprofiles were 0.6 mmol m−2 d−1 for two stations at a water depth of 1300 m. The ratio of calcite dissolution flux and organic C degradation is 0.53 and 0.97, respectively. The microprofiles indicate that CO2 produced within the upper oxic sediment layer dissolves up to 85% of the calcite rain to the seafloor. Modeling our O2, pH and Ca2+ profiles from one station predicted a calcite dissolution rate constant for this calcite-poor site of 1000 mol kgw−1 a−1 (mol per kg water and year), which equals 95% d−1. This rate constant is at the upper end of reported in situ values.  相似文献   

18.
Two groups of perennial springs are observed in the Canadian High Arctic at Expedition Fjord on Axel Heiberg Island at Colour Peak and Gypsum Hill. Saline discharge (∼1.3–2.5 molal NaCl) produces a variety of calcite (travertine) and gypsum-rich precipitates. Saturation index calculations of the spring waters at Colour Peak suggest CO2 degassing from the waters causes calcite precipitation. Gypsum precipitation dominates at Gypsum Hill, where spring waters have lower alkalinity and higher SO4 concentrations. Mineral accumulations form both channel and rimstone pool morphologies as a result of varying slope conditions. At Colour Peak, confined flow in steep slope areas develop massive structures in contrast to more friable, porous accumulations in areas where waters fan out on shallower slopes; these morphological variations lead to corresponding varying apparent rates of mineral precipitation. Mineral precipitation at Gypsum Hill is far less notable as a result of lower discharge rates and annual degradation by icing formation. Microscopic observations and geochemical analyses of the channel precipitates at Colour Peak reveal alternating light (calcite spar) and dark (anhedral microcrystalline calcite combined with organic matter and non-carbonate minerals) laminae. Rimstone pools forming in lower sections of spring discharge are composed of accumulations of large euhedral calcite crystals interbedded with allochthonous inputs. High concentration of dissolved solids is responsible for slow travertine precipitation rates, which occurs during winter. This precipitation is further retarded during summer months by the introduction of crystal growth inhibitors such as Fe3+ and deposition of organic matter and soil sediments.  相似文献   

19.
《Applied Geochemistry》1998,13(2):177-184
Calcium carbonate is one of the most common and important scale-forming minerals in oilfield produced water, but the kinetics of CaCO3 precipitation has been ignored in most scale prediction models because of the lack of reliable precipitation rate model. There are none in the open literature for oilfield conditions (temperature > 100°C, pressure > 200 bar and salinity > 0.5 mol kg− 1). In this work the kinetics of calcite (CaCO3) precipitation from high salinity waters (up to 2 mol kg−1) have been studied by a pH-free-drift method in a closed water system. This method. is much easier to operate than the often used steady-state method. The experimental results indicate that the calcite precipitation rate is not only affected by the solution CaCO3 saturation level, but also by the solution pH, ionic strength and the concentration ratios of Ca to HCO3− ions (CCa2+/CHCO3−). When the concentration ratios of Ca to HCO3− ions are close to their chemical stoichiometric ratio of 0.5, the calcite growth from a supersaturated solution is believed to be surface reaction controlled. However, at higher CCa2+CHCO3− ratios, the transportation of the lattice ions to calcite crystal surface has to be considered.  相似文献   

20.
Abstract. Mineral assemblage, precipitation sequence and textures of the gold‐bearing veins from the Hishikari epithermal vein‐type deposits, southern Kyushu, Japan, were examined. In addition, fluid inclusion microthermometry and carbon and oxygen isotopic compositions of calcite were determined. Calcite, and that replaced by quartz, were commonly observed throughout the precipitation sequence of the veins. Thus, calcite must be a more common gangue constituent initially than observed presently. Association of calcite and electrum is observed immediately subsequent to columnar adularia in some vein samples. In addition, close association of electrum with pseudo‐acicular quartz, and electrum with truscottite were observed. The initial coprecipitation of electrum and calcite might be a common phenomenon in the gold‐bearing veins at the Hishikari deposits. The Th (homogenization temperature) data from the Honko‐Sanjin deposits are generally higher than those from the Yamada deposit. Samples that show association of calcite and electrum yielded higher Th (206–217°C, average) than the Th data from calcite associated with low‐grade Au ore or barren (180–204°C, average). The measured Tm (temperature of last melting point of ice) range from ‐0.4 to 0.0°C. The result suggests that the salinity of the hydrothermal solution was low during the precipitation both of calcite associated with Au mineralization and of barren calcite. Fluid inclusion evidence suggestive of boiling of hydrothermal solution for the precipitation of calcite was not recognized in the present work. The δ13C and δ18O values of calcite range from ‐10.8 to —4.7 % and from +3.2 to +15.2 %, respectively. The δ13C value of H2CO3 and the δ18O value of H2O in the hydrothermal fluids calculated assuming isotopic equilibrium with calcite using the temperature obtained by fluid inclusion microthermometry, range from ‐14.4 to ‐9.1 %, and from ‐6.2 to +5.5 %, respectively. Thus, the calculated δ18O values of H2O for calcite further confirm the presence of the 18O‐enriched ore fluids during the mineralization at the Hishikari deposits. The hydrothermal solution isotopically equilibrated with the sedimentary basement rocks was responsible for the gold mineralization associated with calcite.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号