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1.
《International Geology Review》2012,54(11):1750-1754
Examination of a large number of specimens of α-quartz, α-cristobalite, chalcedonies, opals, quartzines, and agates shows that the so-called amorphous forms of silica do not represent any particular specificities, but are simply amorphous mixtures, more often than not, for example, α-quartz with tridymite, on the α-quartz base (chalcedonies, opals). In chalcedonies the tridymitic constituent is somewhat larger than in opals. Another large group of opals is but an altered α-cristobalite, high in molecular water. The α-quartz opals characteristically contain far less water. — Authors. 相似文献
2.
埃塞俄比亚WOLLO地区产出的欧泊品种丰富,但火欧泊和水欧泊不稳定,易因外界温度或水分变化形成较多裂纹,严重影响其稳定性及加工性能。因此,本实验对埃塞俄比亚WOLLO地区产出的多裂纹火欧泊、水欧泊样品进行了充填处理,并对充填前、后的样品进行了显微放大观察和红外光谱、相对密度、紫外荧光的测试及分析,总结出了有机充填欧泊的一些鉴定特征。测试及分析结果显示,在2800-3100cm叫范围内红外吸收峰为有机充填欧泊的主要鉴定特征,表面及内部显微充填特征、偏小的相对密度、裂隙处的蠕虫状及空洞缺陷处的斑块状强蓝白色荧光可作为辅助鉴定特征。从样品的充填及测试分析结果可见,埃塞俄比亚WOLLO地区产出欧泊的有机充填方案可行,比较明显的开放裂隙易被充填。 相似文献
3.
应用XRF-SEM-XRD-FTIR等分析测试技术研究丽水蓝色类欧泊(蛋白石)的矿物学与光学特征 总被引：2，自引：2，他引：0
直至目前,我国相关欧泊的矿藏及其相应的矿物学特征鲜见报道,近期在浙江丽水缙云地区发现的蓝色类欧泊石引起了宝玉石科研工作者的广泛关注,但此矿物的相关研究至今尚未见论述。本文应用X射线荧光光谱(XRF)、场发射扫描电镜(FE-SEM)结合X射线粉晶衍射(XRD)与傅里叶变换红外光谱(FTIR)等多种综合检测技术首次对该类蓝色原矿的矿物学及光学变彩性质进行研究。结果表明:XRF分析显示蓝色原矿的主体化学组成为SiO2(质量含量95%),仅含极少量的Fe2O3与Al2O3等杂质。同时,蓝色原矿及其相应的热处理后样品局部区域具有明显的变彩特征,主体的化学组成与其光学特征与天然欧泊的组成及变彩效应类同。XRD分析显示原矿粉体的无机相的晶型为方石英相,衍射峰形锐化,该晶体的结构特征明显相异于天然欧泊即微晶类的蛋白石(Opal-CT)、Opal-C与非晶蛋白石类(Opal-A)。此外,样品的红外光谱与天然欧泊间存在一定的频率位移。鉴于此,初步将该类原矿归属为类欧泊,因蓝色原矿所在地丽水缙云地区属于中生代陆相火山岩的地质,因此进一步将该原矿命名为一类火山岩类的类欧泊石,而有关此类欧泊是否可以归属为广义上的欧泊有待再作商榷。同时基于对蓝色原矿有无变彩效应区域的FE-SEM测试结论,本文初步推测该类矿物的光学变彩特征与原矿表面的“叠瓦状”结构形貌有关。 相似文献
4.
近期国内珠宝市场上出现一种产自巴西的绿欧泊,该类绿欧泊表现出的宝石矿物学特征与传统的欧泊有着明显差异。采用常规宝石学测试手段,并结合电子探针、X射线粉末衍射、扫描电子显微镜、红外吸收光谱、紫外吸收光谱等测试分析方法,就其化学成分、物相、微结构、谱学特征及颜色成因等问题展开初步研究。结果表明,巴西绿欧泊的主要矿物组成为蛋白石,含不等量的α-方石英和α-鳞石英等次要矿物,整体呈不规则胶柬状结构,局部微波纹理发育;该类欧泊主要由直径约10～30nm的SiO2球粒聚集而成;由H2O和M—OH倍频振动致近红外吸收谱带位于7000cm-1处,由H2O合频振动致近红外吸收谱带分别位于5200,5612cm叫处,由M—OH与[SiO4]合频振动致近红外吸收谱带位于4600-4100cm-1范围内。笔者还对巴西绿欧泊的呈色机理一并给予了探讨。 相似文献
5.
帐篷构造是碳酸盐岩中的一种特殊沉积组构,因其倒“V”字形形态类似于帐篷(tepee)而得名,被认为是一种无成因意义的沉积组构。传统的帐篷构造在海相至陆相碳酸盐岩中都有发育,形态和胶结物的不同反映了沉积环境的变化,其成因为裂隙填充的胶结物结晶膨胀导致层面突起变形。新元古代帽碳酸盐岩中广泛发育有倒“V”字形的类似构造,但由于形态和成因上都和传统的帐篷构造有所区别,被称为“帐篷状构造”(te-pee-likestructure)。目前其成因解释主要有:“巨风暴潮波痕”、“甲烷气体渗漏”、“地下水侵位”和“晶体结晶”的假说。由于帐篷状构造的形成过程与机制和帽碳酸盐岩的成因密切相关,对帐篷状构造的进一步研究必将帮助我们对新元古代冰期结束机制的理解。 相似文献
6.
Kunwar Raghvendra Singh Rahul Dutta Ajay S. Kalamdhad Bimlesh Kumar 《Environmental Earth Sciences》2018,77(23):780
The present study centers on the investigation of surface water quality with the aid of quality indices and explores the application of a multi-objective decision-making method (TOPSIS) in arranging decisions for policy makers on the basis of overall ranking of the sampling locations. A case study has been performed on the Manas River, Assam (India). Water Quality Index (WQI) involving physico-chemical parameters, and heavy metal pollution index (HPI) and contamination index (CI) involving heavy metal influences were employed for water quality assessment. WQI graded two sampling locations “very poor” and all other locations “poor”. HPIs of all the locations were below the critical value of 100, but the CI depicted that two locations were “moderately contaminated”. Risk assessment to human health was done using hazard quotient and hazard index. Cluster analysis (CA) demonstrated site similarity by grouping the relatively more polluted and less polluted (LP) sites into two major clusters. However, there surfaced difficulty in discerning the overall water quality, as all the three quality indices included different parameters and contradicted each other. A multi-objective decision-making tool, TOPSIS was therefore employed for ranking the locations on the basis of their relative pollution levels. The novelty of the study reflects in the identification of the relatively more or relatively less polluted sites within the same cluster in CA by the application of TOPSIS. The study justifies the effectiveness of TOPSIS method in prioritizing decisions in complex scenarios for policy makers. 相似文献
7.
Distribution of the Period Four Transition Elements among Olivine, Calcic Clinopyroxene and Mafic Silicate Liquid: Experimental Results 总被引：5，自引：1，他引：5
The distribution of Ti4+, V3+, Cr3+, Mn2+, Fe(total), Co2+ andNi2+ among synthetic olivine, calcic clinopyroxene and maficsilicate liquid has been studied between 1125 and 1250 ?C underanhydrous conditions at 1 bar total pressure. The distributionof iron and magnesium among the three phases was concluded tobe independent of temperature and may be described by the twoequations
Titanium and vanadiumdid not enter olivine in significant amounts. The mean valueof the ratio (wt. per cent TiO2 in Cpx)/(wt. per cent TiO2 inL) was 0.29?0.04 for assemblages in which the liquid had botholivine and hypersthene in the norm but the ratio was greaterif the liquid was nepheline normative. Vanadium was concentratedin the pyroxene in some experiments and in the liquid in others,but it was not possible to conclude whether the change in distributionbehavior was due to varying temperature or changing liquid composition.Equilibrium partitioning of chromium was not achieved but theresults indicate that Cr2O3 was most strongly enriched in clinopyroxeneand showed a slight preference for olivine over the liquid.The divalent transition elements were each enriched in olivinerelative to clinopyroxene and the degree of enrichment increasedin the order predicted by crystal field theory. The mean (wt.per cent oxide in 01)/(wt. per cent oxide in Cpx) ratios were2.0 for MnO, 2.4 for FeO, 3.9 for CoO and 5.6 for NiO. Manganesewas enriched in olivine relative to the liquid and in the liquidrelative to the clinopyroxene. Cobalt and nickel were more concentratedin the crystalline phases than in the liquid but the degreeof enrichment was markedly less in the experiments in whichthe liquids were more mafic. 相似文献
8.
《International Geology Review》2012,54(1):78-83
Recent and detailed seismic studies in the U.S.S.R. have provided much information on the structure and revolution of the earth's crust. A review of this information indicates the following postulates: a) the thickness and constitution oft he crystalline layers (”basalt“ and ”granite“) change comparatively rapidly in Alpine provinces of pronounced tectonic movements (geosynclinal provinces and mobile zones), with but a slight lag behind these movements. b) Under platform areas, the crystalline complexes rebuild slowly with a lag of a few geologic periods behind the emergence of the structural elements. c) In both geosynclinal and platform areas the downwarping of the major segments is accompanied by an upward movement of the Mohorovi?i? surface. d) Block uplifts in geosynclinal provinces of mobile zones have absolute values, while in platform areas the uplifts usually represent blocks lagging behind their neighbors. e) Changes in thickness and composition of deeper layers within the crust usually lag behind the formation of corresponding structural elements. — J. R. Hayes 相似文献
9.
David C. Hurd 《Geochimica et cosmochimica acta》1973,37(10):2257-2282
The solution rate of biogenic opal in near-surface sediments in the Central Equatorial Pacific is three to eight orders of magnitude lower than similar acid-cleaned samples. Iron, magnesium and calcium aluminosilicates may be the minerals which are forming on the surface of the opal and reducing its solution rate. The scale height of the system studied suggests that diffusive and not advective processes are primarily responsible for the removal of dissolved silica in sediments. Solution budget calculations for this area suggest that 90–99 per cent of the biogenic opal produced in surface waters dissolves before reaching the sediment-water interface; an additional amount dissolves within the sediment and diffuses into bottom waters leaving 0.05–0.15 per cent of the original amount of opal produced by organisms in the sedimentary record. The relative solution potential of the upper 1000 m of the water column varies by more than an order of magnitude from the Antarctic to Equator and may have a pronounced effect on the accumulation rate of biogenic opal in underlying sediments. 相似文献
10.
As viewed from space remote-sensing images (e.g. Google Earth images) of South Guizhou and North Guangxi, the authors found that macroscopic karst landscape on the Earth’s surface is strongly controlled by the Conjugated shear joint of “X” type. Joints of this kind constitute a huge infiltration network and act as channel-ways for the permeation of meteoric waters from the surface, thus, leading to the dissolution of carbonate rocks nearby. As a result, the karst landscape is formed, which is dominated by linear karst valleys. An “X” karst valley network structure appears in the area where horizontal strata are distributed, and a feather-like network structure appears in the area where vertical strata are distributed, respectively. When the water permeates downwards to the underground-water level, it will flow horizontally along the strike of “X” joints toward the local base level of erosion to form an “X” network system of underground conduits in the area where horizontal strata are distributed, but it is relatively complex, because of the joining of other joints. This is the first time we have made use of Google Earth images to study the karst environment. Therefore, it has been successful in research on the Earth’s geomorphology, which could only rely on aerial photos and satellite photos in the past. Google Earth images provide low-cost and applicable imaging materials for the study of Earth’s geomorphology and karst rocky desertification and its control. 相似文献
11.
在富含水煤系或水力措施后的煤层中,受水溶液的浸泡,煤的孔隙结构及吸附特性发生改变,为了深入研究其变化规律,在实验室利用蒸馏水对2种不同变质程度煤样进行了长时间（60 d）浸泡,采用低温N2吸附实验和CO2吸附实验测试水浸前后煤样的孔隙结构变化规律,采用高压容量法测试水浸前后煤样的瓦斯吸附特性。结果表明,水浸干燥后煤体孔容和比表面积总体呈降低趋势。其中,低温N2吸附实验结果表明,煤体中大中孔的比表面积最高可降低48.9%;CO2吸附实验结果表明,水浸干燥后2种煤样的微孔孔容和比表面积也呈不同程度的降低趋势。将水浸煤样孔隙结构变化分为3个阶段,即矿物质溶出“增孔”阶段、煤基质局部膨胀变形“缩孔”阶段和煤基质整体溶胀变形“扩孔”阶段。此外,水浸干燥后煤对瓦斯的吸附能力下降,主要是由于水浸促使煤体产生膨胀变形,且导致微孔隙相互连通,从而降低了煤体微孔孔容和比表面积,降低瓦斯吸附能力。研究成果对进一步掌握富含水煤系或水力化措施后煤层的瓦斯抽采具有指导意义。 相似文献
12.
基于自制装置室内模拟试验和现场试验,研究了黏土体含水量变化及应力环境改变对采煤区地表拉张裂隙发育的影响,研究结果表明:在30%、35%、40%三种含水量情况下,随着黏土体含水量增高,土样表面拉张裂隙发育宽度和深度均明显降低,且拉张裂隙发育呈现时间上的滞后;当含水量增至40%时,土样表面不会产生拉张裂隙;在土样表面人为形成应力薄弱区,可以有效改变拉张裂隙发育位置;在孙疃煤矿1047工作面通过增湿试验地表“切眼裂隙”发育得到有效抑制;应力引导对地表“风机裂隙”的发育方向造成一定影响。 相似文献
13.
在上文阐明"五江一河"径流量的年际变化及各节点具体径流量要比"红旗河工程"构想少得多的基础上,本文依据前人资料和成果,进一步阐述这些河流的径流量,在年内分配的不均匀性与洪水特征,及其对跨流域调水量的制约作用。研究表明:"五江一河"在11月到翌年4月,径流量只占全年总径流量的12.09%~21.84%,月均只有2.01%~3.64%,为冬、春季枯水期。其径流量只比拟调水比例20%或21%的月均值1.67%或1.75%略多。如此之少的水量,只能维系流域内的生态、生产及生活用水,而不能跨流域调水。何况"红旗河"中、下游在冬季结冰期也难以进行调水。每年6月份到9月份的4个月,"五江一河"径流量占全年径流量的53.3%~88.3%,甚至8月份的月径流量可达全年总径流量的17.8%~29.6%,属于汛期。根据径流量的实际数据,一年当中可供调水时间段只有丰水与平水期的6个月或汛期的3~4个月,要比"红旗河工程"构想的全年调水的时间大大缩短。在可资跨流域调水的每年5—10月份的时间窗口中,如果按原构想的月均调水流量占年径流量的比例1.67%(按20%计)或1.75%(按21%计)进行调水,则"五江一河"的年调水总量仅为153.25×10^8m^3(按20%计)或161.50×10^8m^3(按21%计)。仅为原构想调水量600亿m^3的1/4,充其量不足27%。在丰水与平水期的6个月中实现年径流量20%或21%的年调水比例,就意味将月调水比例从占年径流量的1.67%或1.75%增加为3.33%或3.50%。这样,"五江一河"的年调水总量可达到306.50×10^8m^3或323.00×10^8 m^3。此调水方案,导致调水河道截面积或工程规模增加一倍,但调水量也只有原构想的大约一半或至多54%。如果将调水目标强行设定为600亿m^3,那么"五江一河"的调水比例将提高到占年径流量的27.1%(南水北调西线工程开展前),或除金沙江和雅砻江之外的其它调水河流的39.0%(南水北调西线工程完成后),"红旗河"的建设规模势必大大增加,这也意味着工程难度大大增加,意味着工程建设与运行成本大大增加,意味着洪水、地震与地质灾害的危险性大大增加。"五江一河"实际可调水量比"红旗河"构想严重减少,使人不禁会对"红旗河"工程立论的科学基础和科学依据提出质疑。 相似文献
14.
《Applied Geochemistry》2003,18(6):927-939
The formation of incrustations seriously affects the performance of wells, piezometers and drains. Their economic relevance must not be underestimated. Oxides of Fe(III) represent the most common incrustation type. Their formation via oxidation of dissolved Fe(II) is enhanced at zones of elevated flow velocities. The first, “amorphous” precipitates (ferrihydrite) are thermodynamically unstable and re-crystallise with time to form stable phases, mainly goethite (“ageing”). This transformation involves a decrease of surface area and a simultaneous decrease in reactivity and explains why older incrustations are harder to remove by chemical treatment. During formation, Fe oxide incrustations take up large amounts of trace elements from groundwater. Anions such as phosphate and arsenate dominate over cations. Anions are surface-bound and are mostly expelled with the decrease of surface area during ageing. Cations are probably bound in the crystal structure rather than as sorbed surface species. Only those with large ionic radius are mostly not expelled during ageing. Trace element concentrations influence the rate of transformation and the solubility of Fe oxide incrustations. 相似文献
15.
Classification of rivers based on water quality assessment using factor analysis in Taizi River basin, northeast China 总被引：2，自引：0，他引：2
A method for river classification based on water quality assessment (WQA) was introduced using factor analysis (FA) in this paper. Sixty-nine sampling sites and 20 water quality parameters in Taizi River basin were selected for monitoring and analysis. Five factors were determined in FA, denoted as general, hardness, trophic, nitrogen pollution, and physical factors. The total factor scores (TFSs) of the WQA results from all sampling sites were calculated by the eigenvalue and factor score of each factor. The TFSs of 69 sites were interpolated with the measure of inverse distance weighted in the river buffer zone generated by ArcGIS 9.2 software to form a continuous spatial distribution along river channels. All streams were divided into five classes marked “excellent”, “good”, “fair”, “poor”, and “seriously polluted”. The classification result showed that the water quality of Taizi River basin deteriorated gradually from the mountain area to the plain area. Sewage and intensive human activities contributed to the deterioration of water quality since towns and farmland were dotted densely along the river basin. 相似文献
16.
Macrozooplankton were sampled bi-weekly from October 1969 through May 1973 at 16 stations. Hydrological measurements, including water temperature and conductivity, accompanied each biological sample. Sampling sites and species were grouped by cluster analysis using Camberra-Metric measure of dissimilarity and flexible sorting. Two major seasons, based on taxon composition and abundance, were identified: A warm season (average water temperature above 22°C) dominated by larval and juvenile crustaceans, and a cool season with an abundance of larval fishes. Sites were more similar to each other within a year than they were between years. Differences between years correlated with variations in salinity and temperature. Community structure indices (Shannon-Weaver diversity, species richness and “evenness”) were applied to the seasonal data. Shannon diversity and “evenness” were positively correlated with each other, but richness values were often negatively correlated with the other two indices. 相似文献
17.
Micro- and non-crystalline opals, chalcedony and flint show diffuse small angle neutron scattering (SANS). Precious opals give rise to two additional intensity maxima at very small scattering angles which are due to Bragg reflections from the closest packed non-crystalline silica spheres. A small angle texture diagram reveals that the closest packing is faulty. Synthetic non-crystalline opals yield much less intense small angle scattering due to lower contrast between silica spheres and interstitial cement or particles; in this case intensity maxima were not observed. The outer part of the scattering curves of opal-CT and microcrystalline quartz deviates from Porod's law. The specific surface of natural non-crystalline opals ranges from 0.006 to 0.018 nm–1. In microcrystalline opals, the specific surface is about 10 times larger than in non-crystalline opals. 相似文献
18.
Natural titanites which have incurred radiation damage from the decay, over geologic time, of U and Th incorporated in the samples have been studied by powder X-ray diffraction, differential thermal analysis and infrared spectroscopy. In agreement with previous studies of ionirradiated synthetic titanite, X-ray diffraction indicated that titanite is two to three times more sensitive than zircon to damage from α-decay processes. Differential thermal analysis of samples which were deduced to have accumulated 10–30 percent of the α-fluence required to render the structure completely X-ray amorphous gave a series of exothermic peaks in the 200–800° C range of temperature. In such samples, X-ray and density measurement showed that atomic displacement damage anneals during heating periods of the order of one h in the temperature range 500–800° C. The density of titanite rendered X-ray amorphous by irradiation was estimated to be ～8 percent lower than that of crystalline titanite. 相似文献
19.
“Mallines” (wet-meadows) are Patagonian ecosystems that provide hydrological, biological and scenic resources. They develop in landscape locations that are favourable for water concentration. The area of each “mallín” is usually limited to a few, tens, or hundreds of hectares at most, but independently of their size, they present high variability in their internal physiographic characteristics. These are reflected on the vegetation distribution that basically responds to the space and time water distribution in the “mallín”, both at the surface as well as across the soil profile.We analyze the internal variability of a “mallín type” and present a conceptual map that illustrates the functional relationships established between four basic elements: geomorphology, hydrology, soils and vegetation, whose interrelationships allowed the differentiation of various situations, which may correspond both to different “mallines” and to subunits within the same “mallín”. 相似文献
20.
Groundwater resources in the semi-arid regions of southern India are under immense pressure due to large-scale groundwater abstraction vis-à-vis meager rainfall recharge. Therefore, understanding and evaluating the spatial distribution of groundwater is essential for viable utilization of the resource. Here, we assess groundwater potential at the watershed scale, in a semi-arid environment with crystalline aquifer system without a perennial surface water source using remote sensing, geophysical, and GIS-based integrated multi-parameter approach. GIS-based weighed overlay analysis is performed with input parameters, viz., geology, geomorphology, lineament density, land use, soil, drainage density, slope, and aquifer thickness. The watershed is categorized into four zones, namely, “very good” (GWP4), “good” (GWP3), “moderate” (GWP2), and “low” (GWP1) in terms of groundwater potential. Overall, ~?70% of the study area falls under moderate to low groundwater potential, indicating a serious threat to the future availability of the resource. Therefore, serious measures are required for maintaining aquifer resilience in this over-exploited aquifer (e.g., restricting groundwater withdrawal from GWP1 and GWP2 zones). Further, as the aquifer is under tremendous anthropogenic pressure, rainwater harvesting and artificial recharge during monsoon are advocated for sustainable aquifer management. Due to the direct dependence of crop production vis-à-vis farmer economy on groundwater, this study is an important step towards sustainable groundwater management and can be applied in diverse hydrological terrains. 相似文献