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1.
The Baoshan Cu-polymetallic deposit is a recently discovered skarn deposit in the northern Lesser Xing’an Range, NE China. The orebodies are mainly hosted in the contact zone between granitic intrusions and Lower Cambrian dolomitic crystalline limestones or skarns. We present here zircon U–Pb and molybdenite Re–Os age data, whole-rock geochemistry, and zircon Hf isotopic data to constrain the geodynamic mechanisms of igneous activity and metallogenesis within the Baoshan Cu–polymetallic deposit. LA–ICP–MS zircon U–Pb dating suggests that a hornblende–quartz monzonite and porphyritic biotite granite were emplaced at 252.45 ± 0.70 Ma and 251.10 ± 0.98 Ma, respectively. Molybdenite separated from ore-bearing quartz veins or skarn-type ores yields a weighted mean model age of 250.3 ± 3.4 Ma, which coincide with the emplacement of the igneous rocks. These data suggest that the Late Permian-Early Triassic magmatic and mineralization event led to the formation of the Baoshan Cu–polymetallic deposit. Granitic intrusions are closely associated with this mineralization and have high contents of SiO2 (60.90–68.98 wt.%), Al2O3 (15.15–16.98 wt.%) and K2O (2.77–4.17 wt.%), with A/CNK ratios of 0.86–0.96. These granites are classified as metaluminous and high-K calc-alkaline I-type granites, and are enriched in Rb, Th, U, and K, and depleted in Nb, Ta, P, and Ti. Moreover, Moreover, the hornblende–quartz monzonite and porphyritic biotite granite have geochemical characteristics similar to adakites and island arc calc-alkaline rocks, respectively. In situ zircon Hf isotope data on the hornblende–quartz monzonite samples show εHf(t) values from +0.1 to +3.1, and porphyritic biotite granite samples exhibit heterogeneous εHf(t) values from −5.4 to +1.1. The geochemical and isotopic data for the Baoshan intrusions indicate that the Late Permian–Early Triassic continental–continental collision caused over thickening and delamination of the lower crust. Partial melting of delaminated lower crust formed the primary adakitic magmas, which may have reacted with surrounding mantle peridotite during ascent. Hornblende–quartz monzonite was formed by the emplacement of the adakitic magmas, whereas the formation of the porphyritic biotite granite was caused by the mixing of adakitic magmas with ancient crustal materials during ascent. Moreover, ore-forming materials were typically derived from the adakitic magmas with high oxygen fugacity, which incorporated significant amounts of ore-forming elements. Based on the regional geological history and the new geochemical and isotopic data from intrusions, we suggest that diagenesis and mineralization of the Baoshan Cu–polymetallic deposit took place in a transitional tectonic setting from collisional orogeny to extension, after collision of the North China Plate and Songnen Block, during the latter stages of the Xingmeng orogeny.  相似文献   

2.
The Southeast Anatolian Orogenic Belt (SAOB), the most extensive segment of the Alpine-Himalayan Orogenic Belt, resulted from the northward subduction of the southern branch of the Neotethys oceanic crust beneath the Anatolian micro-plate. We present new whole-rock geochemistry, zircon U–Pb ages, and Lu–Hf isotope data from the stocks and dykes with a length of up to tens of meters belonging to the Keban magmatic rocks, eastern Turkey. These rocks are represented by syenite and quartz monzonite intruded into the Keban metamorphic complex. The geochemistry data indicates that the samples bear mostly metaluminous, variably high alkalines (K2O + Na2O), Ga/Al ratios and zircon saturation temperature, and typically the A-type granite characters. According to the Y/Nb vs Yb/Ta diagram, the Keban magmatic rocks show A1-type geochemical signatures modified by crustal melts. Syenite and quartz monzonite samples from Keban magmatic rocks give zircon U–Pb ages of 77.4 ± 0.34 Ma, 76.3 ± 0.3 Ma and 76.36 ± 0.34 Ma, respectively. On the primitive mantle-normalised trace element patterns, the Keban magmatic rocks show enrichment in large-ion lithophile elements (LILEs) relative to high field strength elements (HFSEs). They are coupled with slightly negative Nb–Ta anomalies. Chondrite-normalised rare earth-element patterns show strong enrichment in LREEs relative to HREEs, a typical A-type granites feature. The zircons have negative εHf(t) values that vary from ?2.68 to ?0.41, and Hf model ages (TDM2) range from 1171.54 to 1329.26 Ma, indicating the enriched lithospheric mantle sources and crustal contribution. The sources and evolution of the alkaline magmas might be related to the post-collisional tectonic setting.  相似文献   

3.
Abstract

New zircon laser ablation inductively coupled plasma mass spectrometry and secondary ion mass spectroscopy U–Pb ages, and Hf isotope and whole-rock geochemical data are reported for Mesozoic igneous rocks from the eastern margin of the Songnen–Zhangguangcai Range Massif, Northeast China, in order to document the petrogenesis of the igneous rocks and reconstruct the early Mesozoic tectonic setting of the region. Zircons from five representative igneous rocks are euhedral–subhedral and display oscillatory growth zoning or striped absorption in cathodoluminescence images, suggesting a magmatic origin. The dating results indicate that granite, gabbro, and rhyolite from the eastern Songnen–Zhangguangcai Range Massif formed during Late Triassic (204–211 Ma). The Late Triassic granitoids and rhyolites have an affinity to A-type granites or rhyolites. Their zircon εHf(t) values and Hf two-stage model ages range from –3.8 to +3.8 and from 999 to 1485 Ma, respectively, indicating that their primary melts were derived from the partial melting of the Meso-Proterozoic crust. The geochemistry of coeval gabbros, which reflects primary magma composition, shows a significant large ion lithophile element (e.g. Ba and Sr) enrichment and high field strength element (i.e. Zr, Hf, Nb, Ta, and Ti) depletion. Based on zircon εHf(t) values (–4.2 to +2.8) and Hf single-stage model ages (746–1031 Ma), we conclude that the mafic magma is the product of partial melting of lithospheric mantle that was metasomatically enriched by fluids derived from the subducted oceanic crust. The Late Triassic magmatism along the eastern margin of the Eurasian continent has bimodal magma compositions, indicating an extensional setting after the final closure of the Palaeo-Asian Ocean rather than being related to subduction of the Palaeo-Pacific Plate beneath the Eurasian continent. The occurrence of Late Triassic igneous rocks on the eastern side of the Mudanjiang Fault suggests that this fault does not represent the suture zone between the Songnen–Zhangguangcai Range and Jiamusi massifs.  相似文献   

4.
ABSTRACT

The low Yangtze River metallogenic belt (LYRMB) is one of the most important poly-metal deposit belts in China. The Chuxian, Machang and Shangyaopu intrusions in the LYRMB are intermediate rock series, mainly composed of monzonite and quartz monzonite. In this study, bulk rock major and trace elements, zircon U–Pb dating and Hf isotope were analysed. Five ages have been obtained as (1) Chuxian, 121.8 ± 1.9 and 124.0 ± 1.4 Ma, respectively, (2) Machang intrusion, 123.1 ± 2.0 Ma and (3) Shangyaopu, 126.6 ± 1.8 and 123.4 ± 1.9 Ma, indicating that the regional igneous activity was in Early Cretaceous, being consistent with the massive Yanshanian magmatic events in eastern China. These three intrusions are identified as a high-Mg adakite, most of them showing geochemical features of high Si, high Na and low Sr, which can be interpreted as partial melting of subducted oceanic crust. High Mg# characteristics indicate the magmas reacted with the mantle. The negative zircon εHf values of these adakites suggest that the magmas have assimilation of old crustal material, e.g. Archaean continental crust, the basement of the south Tancheng–Lujiang (Tan–Lu) fault. Biotite Ti temperature result (about 700°C) shows that intrusive magma has a relatively low temperature. Petrogenesis and regional Cu–Au mineralization mechanism may be explained by Pacific plate subduction during about 125–180 million years subducted to southwest towards the LYRMB. Magmas formed by partial melting of subducted oceanic crust have systemically high Cu–Au contents, which are conducive to corresponding mineralization.  相似文献   

5.
This paper presents new SHRIMP zircon U–Pb chronology, major and trace element, and Sr–Nd–Hf isotopic data of two Early Paleozoic granitic plutons (Yierba and North Kudi) from the western Kunlun orogen, in attempt to further constrain the Proto-Tethys evolution. SHRIMP zircon U–Pb dating shows that the Yierba pluton was emplaced in the Middle Cambrian (513?±?7 Ma) and the North Kudi pluton was emplaced in the Late Silurian (420.6?±?6.3 Ma). The Yierba pluton consists of quartz monzodiorite, quartz monzonite and granodiorite. These granitoids are metaluminous and potassic, with initial 87Sr/86Sr ratios of 0.7072–0.7096, εNd (T) of ?0.2 to ?1.6 and εHf (T) (in-situ zircon) of ?1.2. Elemental and isotopic data suggest that they were formed by partial melting of subducted sediments, with subsequent melts interacting with the overlying mantle wedge in an oceanic island arc setting in response to the intra-oceanic subduction of Proto-Tethys. The North Kudi pluton consists of syenogranite and alkali-feldspar granite. These granites are metaluminous to weakly peraluminous and potassic. They show an affinity of A1 subtype granite, with initial 87Sr/86Sr ratios of 0.7077–0.7101, εNd (T) of ?3.5 to ?4.0 and εHf (T) (in-situ zircon) of ?3.9. Elemental and isotopic data suggest that they were formed by partial melting of the Precambrian metamorphic basement at a shallow depth (<30 km) during the post-orogenic regime caused by Proto-Tethyan oceanic slab break-off. Our new data suggest that the subduction of the Proto-Tethyan oceanic crust was as early as Middle Cambrian (～513 Ma) and the final closure of Proto-Tethys was not later than Late Silurian (～421 Ma), most probably in Middle Silurian.  相似文献   

6.
《International Geology Review》2012,54(13):1735-1754
Widespread granitic intrusions in the northeast part of the Wulonggou area were previously thought to be emplaced into the Palaeoproterozoic Jinshuikou Group during the Neoproterozoic. This contribution presents detailed LA-ICP-MS zircon U–Pb geochronology, major and trace element geochemistry, and zircon Hf isotope systematic on the Wulonggou Granodiorite and Xiaoyakou Granite from the Wulonggou area. Three granodiorite samples yielded U–Pb zircon ages of 247 ± 2, 248 ± 1, and 249 ± 1 Ma, and one granite sample yielded U–Pb zircon age of 246 ± 3 Ma. The granodiorite samples are metaluminous with an alumina saturation index of 0.90–0.96, as well as intermediate- to high-alkali contents of 5.49–6.14 wt.%, and low Zr+Nb+Ce+Y contents, and low Fe2O3T/MgO ratios, which suggest an I-type classical island arc magmatic source. The granite samples are peraluminous with an alumina saturation index of 1.02–1.03, Sr content of 305.00–374.00 ppm, Sr/Y ratios of between 17.68 and 28.77, (La/Yb)N values of 16.98–25.07, low HREEs (Yb = 1.10–2.00 ppm), and low Y (13.00–21.10 ppm), which suggest adakite-like rocks. All granodiorite samples have zircons εHf(t) values ranging from ?2.9 to +3.9, and granite samples have zircon εHf(t) values ranging from ?7.8 to +3.2. These Hf isotopic data suggest that the Early Triassic granites were derived from the partial melting of a mafic Mesoproterozoic lower crust, although the degree of ancient crustal assimilation may be higher for the Xiaoyakou Granite. It is suggested here that the ca. 246–248 Ma magma was generated during the northward subduction of the Palaeo-Tethys oceanic plate.  相似文献   

7.
The recently discovered Taolaituo porphyry Mo deposit and Aobaotu hydrothermal vein Pb–Zn deposit are both located in the Great Xing’an Range, Northeast China. Here we present new zircon U–Pb ages, whole-rock geochemical and Pb isotopic data, and molybdenite Re–Os ages for these two deposits. The Mo mineralization in the Taolaituo area occurred in quartz porphyry, which yields zircon U–Pb ages ranging from 138.5 ± 0.8 to 139.1 ± 0.5 Ma. Fine-grained granite representing pre-mineralization magmatic activity was formed at 145.2 ± 0.5 Ma. Molybdenite Re–Os dating indicates that Mo mineralization occurred at 133.8 ± 1.2 Ma. In the Aobaotu deposit, the ore-related granodioritic porphyry has a zircon U–Pb age of 140.0 ± 0.4 Ma. These geochronological data indicate that these magmatic and hydrothermal activities occurred during the Early Cretaceous. The mineralogical and geochemical features of the Taolaituo and Aobaotu granitoids suggest they can be classified as A1-type within-plate anorogenic granites and I-type granites, respectively. The Pb isotopic compositions suggest a mixed crust–mantle origin of the granitoids in these two deposits. The Taolaituo granitoids were formed by the partial melting of lower crust and crust–mantle interaction, with subsequent fractionation of apatite, feldspar, Ti-bearing phases and allanite or monazite. In contrast, the Aobaotu granites were derived primarily from lithospheric mantle that had been transformed or affected by the addition of subduction-related components. Combined with the regional geology, tectonic evolution and available age data from the literature, our results suggest that the Early Cretaceous (140–100 Ma) was likely to be the most important peak period for metallogenic mineralization in Northeast China. The Taolaituo and Aobaotu deposits formed under an extensional environment at an active continental margin in response to subduction of the Palaeo-Pacific oceanic plate.  相似文献   

8.
《International Geology Review》2012,54(12):1445-1461
We present zircon U–Pb ages, Hf isotopes, and whole-rock geochemistry of the Xiaochuan gneissic granite intrusion, SE China, to constrain its petrogenesis and provide insights into early crustal evolution of the Cathaysia Block. LA-ICP-MS zircon U–Pb dating of a representative sample yields a weighted mean 206Pb/207Pb age of 1839 ±16 Ma, interpreted as the emplacement age of the Xiaochuan granite. Zircons have ?Hf(t) values ranging from –8.1 to 2.7 and T DM2 model ages from 2.23 to 3.03 Ga. The granites are strongly peraluminious (A/CNK = 1.14–1.41), with relatively high FeOt, TiO2, and CaO/Na2O, and low CaO, Al2O3/TiO2, and Rb/Sr values. In addition, they show strongly negative Ba, Sr, Nb, and Ta and positive Th and Pb anomalies in the primitive mantle-normalized spider diagram, similar to other Cathaysia Palaeoproterozoic S-type granites. The geochemical and Hf isotopic signatures suggest that the Xiaochuan gneissic granites were generated by partial melting of Archaean crustal materials in an intraplate extensional setting. Our results, combined with existing geochronological data, further demonstrate that the Wuyishan terrane is underlain by Palaeoproterozoic crystalline basement.  相似文献   

9.
The geodynamic setting of Mesozoic magmatic rocks and associated mineralization in eastern Tianshan, Northwest China, are attracting increasing attention. The newly discovered giant Donggebi molybdenum deposit (0.508 Mt at 0.115% Mo) is located in the central part of eastern Tianshan, Xinjiang. The molybdenum mineralization was genetically associated with the Donggebi stock, comprised of porphyritic granite and granite porphyry. Secondary ion mass spectrometry (SIMS) zircon U–Pb dating constrains that the porphyritic granite and granite porphyry emplacement occurred at 233.8 ± 2.5 Ma and 231.7 ± 2.6 Ma, respectively. The Re–Os model ages of six molybdenite samples range from 235.2 to 237.0 Ma, with a weighted mean age of 236.1 ± 1.4 Ma, which is roughly consistent within errors with the zircon U–Pb ages, suggesting a Middle Triassic magmatic–mineralization event at Donggebi. Geochemically, the Donggebi granitoids are characterized by high SiO2 and K2O contents, with low MgO contents, belonging to high-K calc-alkaline granites. These rocks show pronounced enrichment in K, Rb, U, and Pb, and depletion in Sr, Ba, P, and Ti, with negative Eu anomalies (Eu/Eu* = 0.20–0.38). In situ Hf isotopic analyses of zircon from the porphyritic granite and granite porphyry yielded εHf(t) values ranging from +6.6 to +10.5, and from +5.5 to +10.1, respectively. The geochemical and isotopic data imply that the primary magmas of the Donggebi granitoids could have originated by partial melting of a juvenile lower crust that involved some mantle components. Combined with the regional geological history, geochemistry of the Donggebi granitoids, and new isotopic age data, we thus propose that the Donggebi molybdenum deposit was formed in the Middle Triassic, and occurred in an intracontinental extension setting in eastern Tianshan.  相似文献   

10.
沙麦钨矿床位于内蒙古东乌旗地区,是该区目前已探明的中型岩浆热液型钨矿床。矿体主要赋存在黑云母二长花岗岩和黑云母二长花岗斑岩中,对这两种花岗质岩石的岩相学、岩石地球化学和LA-ICP-MS锆石U-Pb年代学进行了研究。结果表明,黑云母二长花岗岩锆石U-Pb年龄为135.6±1.6 Ma和136.3±1.8 Ma,黑云母二长花岗斑岩锆石U-Pb年龄为138.6±1.1 Ma,二者侵位时间均为早白垩世。两种花岗质岩体具有富SiO2(73.73%～78.23%)、高钾钠(Na2O+K2O)(7.56%～8.89%)、贫MgO(0.09%～0.20%)、贫CaO(0.51%～0.89%)、贫TiO2(0.03%～0.12%)的特征,属于过铝质-高钾钙碱性系列;微量元素富集Rb、K、Th和U,相对亏损Sr、Ba、Nb、P和Ti元素,具有强烈的Eu负异常,具有较高的FeOT含量,较高的FeOT/MgO和FeOT/(FeOT+M...  相似文献   

11.
The Changfagou Cu deposit is a newly discovered porphyry deposit located in the southern Jilin Province of Northeastern China, on the northeastern margin of the North China Craton. To better understand the formation of the Cu deposit, we report the zircon U–Pb and molybdenite Re–Os dating, and Sr-, Nd-, and Hf- isotopic data of the granite porphyry. LA-ICP-MS dating of zircon grains from two mineral zones in the granite porphyry yield ages of 115.7 ± 0.8 and 115.3 ± 0.6 Ma, which is interpreted as the emplacement age of the granite porphyry. The molybdenite Re–Os model ages of 112.5 to 113.8 Ma, an isochron age of 113.3 ± 1.3 Ma, and a weighted mean model age of 113.0 ± 0.7 Ma, which represents the age of the Cu mineralization quite well. The Changfagou granite porphyry samples lack amphibole and muscovite, and are compositionally characterized by high SiO2, high Na2O+K2O, and low P2O5, enriched in some Rb, Th, U, and Pb, and depleted in Nb, Ta, Ti, P, and Eu. Mineralogical and geochemical features suggest that the Changfagou granite porphyry samples are slightly peraluminous and are of highly fractionated I-type granitoids. The granitic rocks also have relatively high (87Sr/86Sr)i (0.71199 to 0. 71422), and both low εNd(t) (?14.56 to ?13.19) and εHf(t) values (?14.916 to ?8.644), which suggest that Changfagou granite porphyry are derived from mixed sources of crustal and mantle, and diagenesis and mineralization were possibly related to the switch in subduction direction of the Palaeo-Pacific Plate in the late phase of Early Cretaceous.  相似文献   

12.
The Triassic (Indosinian) granites in the South China Block (SCB) have important tectonic significance for understanding the evolution of Eastern Asia. The Dengfuxian biotite granite in eastern Hunan Province, China, reported in this article, was recognized as Late Triassic (late Indosinian) weakly peraluminous A-type granite with a zircon laser ablation inductively coupled plasma mass spectrometry U–Pb age of 225.7 ± 1.6 Ma. It is enriched in F, Cs, Rb, Th, high field strength elements, and rare earth elements (REEs) and depleted in Ba, Sr, P, Ti, Nb, and Ta, with high Ga/Al ratios and zircon saturation temperatures. The Dengfuxian biotite granite shows high initial Sr isotope values (0.715932 to 0.716499) and negative ?Nd(t) (?10.46 to ?9.67) and ?Hf(t) (?9.92 to ?6.29) values, corresponding to the Nd model ages of 1.79 to 1.85 Ga and the Hf model ages of 1.65 to 1.88 Ga. It is proposed that the Dengfuxian biotite granite was derived from high-temperature partial melting of the Palaeoproterozoic lower crust undergoing granulitization. Some Late Triassic A-type granites were recently identified in the SCB with the ages between 202 and 232 Ma. These A-type granites have the same geochemical characteristics and petrogenesis as Dengfuxian A-type granite, and show A2-subtype granite affinity. The Late Triassic A-type granite formed a NE-trending granite belt, which is consistent with the main NE-trending faults in the SCB. The formation of these A-type granites was in response to the subduction of the palaeo-Pacific plate underneath the SCB, and indicates an extensional tectonic environment in the SCB. Combined with previous studies on tectonic evolution, we suggest that there may be a tectonic transition inside the SCB from compression to extension at least from 225 to 230 Ma.  相似文献   

13.
The granitic dykes in the Badu Group,Zhejiang Province,South China provide important insights on tectonic setting and crustal evolution of the South China Block(SCB) and the Indochina Block during Triassic.Here we report LA-ICP-MS U-Pb data of granitic rocks from the Hucun and Kengkou which show early Triassic ages of 242 ± 2 and 232 ± 3 Ma,respectively,representing their timing of emplacement.The dyke rocks are enriched in K,Al,LREE,Rb,Th.U,and Pb.and are depleted in Nb,Ta,Sr,and Ti.The rocks are characterized by highly fractionated REE patterns with(La/Yb)N ratios of 28.46-38.07 with strong negative Eu anomalies(Eu/Eu* = 0.65-0.73).In situ Hf isotopic analyses of zircons from the Hucun granite yielded ε_(Hf)(t) values of-13.9 to-6.4 and two-stage depleted mantle Hf model ages of 1.68-2.15 Ga,which indicate that the magma was formed by partial melting of the Paleoproterozoic metasedimentary protoliths in the Cathaysia Block.The zircons from the Kengkou granite have ε_(Hf)(t) values ranging from 40.7 to 31.5 and yield two-stage depleted mantle Hf model ages of 0.99-2.49 Ga,indicating magma origin from a mixed source.The Hucun and Kengkou dykes,together with the Triassic A-type granites in SE China were probably generated during magmatism associated with crust-mantle decoupling along the convergent plate boundary between SCB and the Indochina Block.  相似文献   

14.
ABSTRACT

Large-scale Cu–Au mineralization is associated with Late Mesozoic intrusive rocks in the Tongling region of eastern China, which mainly comprise pyroxene monzodiorite, quartz monzodiorite, and granodiorite. To constrain the petrogenesis of the intrusive rocks and Cu–Au mineralization, detailed analyses of the geochronology, apatite in situ geochemistry, whole-rock geochemistry, and zircon Hf isotopic compositions were performed. Magmatic zircons from pyroxene monzodiorites, quartz monzodiorites, and granodiorites yield U–Pb ages of 136–149 Ma, 136–146 Ma, and 138–152 Ma, respectively, indicating that their formation ages are contemporaneous. Quartz monzodiorites and granodiorites (SiO2 = 57.9–69.5 wt.%) are highly potassic calc-alkaline rocks with adakitic affinity and have low MgO and Y contents, low zircon εHf(t) values (?11.7 to ?39.0), high apatite Cl contents (>0.2 wt.%), and log fO2 values (?23.2 to ?8.23), indicating that they may have formed when metasomatized mantle-derived magmas mixed with slab-derived magmas before undergoing crustal assimilation and fractional crystallization. Pyroxene monzodiorites (SiO2 = 48.4–53.0 wt.%) are shoshonitic and record high MgO, P2O5, and Y contents, high zircon εHf(t) values (1.55 to ?7.87), high oxygen fugacity, low Nb and Ta contents, and low apatite Cl contents (mainly <0.2 wt.%), suggesting that they were primarily derived from a metasomatized lithospheric mantle-derived magma that experienced the assimilation of lower crustal materials. The results indicate that the intrusive rocks and associated large-scale Cu–Au mineralization of the Tongling region resulted from the partial melting of the subducted oceanic slab in an oxidizing environment.  相似文献   

15.
The Dashuang complex in Zhejiang Province of southeast China is composed of two distinct lithologies: syenite in the west and quartz monzonite in the east. They record similar zircon U–Pb ages of 224 ± 3 Ma (syenite), and 226 ± 2 Ma and 227 ± 1 Ma (quartz monzonite), respectively, but are notably different in petrography, magnetic susceptibility, whole-rock chemistry, zircon Hf isotope and zircon trace element characteristics. The west Dashuang syenitic pluton (the west body) has high modal alkali feldspar, high zircon saturation temperatures, high whole-rock and zircon MREE/HREE ratios, low Fe–Mg–Ti contents, and is depleted in Ba, Sr and Eu. It also has low magnetic susceptibilities, belongs to the ilmenite-series, and is a peraluminous and ferroan granitoid. The east Dashuang quartz monzonitic pluton (the east body) has abundant K-feldspar megacrysts, with hornblende, titanite and biotite being the major ferromagnesian minerals. In contrast to the west body, the east body has lower zircon saturation temperatures, lower whole-rock and zircon MREE/HREE ratios, higher Fe–Mg–Ti contents, and shows no depletion in Ba, Sr or Eu. The east body has higher magnetite contents, high magnetic susceptibilities and belongs to the magnetite-series. It is a metaluminous and magnesian granitoid of arc-affinity. Zircon Hf isotopic data reveal that both bodies were derived from partial melting of Paleoproterozoic igneous protoliths in the lower crust, but the east body possibly incorporated subducted terrigenous sediments. Both bodies have higher melting temperatures and pressures than adjacent Cretaceous granitoids, reflecting their origin in a thickened, hotter lower crust. The most feasible model to explain their differences is variations in water content during crustal melting, resulting in different melting and crystallization behaviors. Such melting in a Triassic thickened crust with variable water involvement, followed by Cretaceous magmatism in an extensional setting, is consistent with the flat-slab subduction model proposed for South China. The model involves crustal thickening and partial melting, with mantle and lower crustal metasomatism during flat-slab propagation in the Triassic–Early Jurassic, and crustal thinning and extension from the mid-Jurassic to the Cretaceous.  相似文献   

16.
《International Geology Review》2012,54(10):1294-1310
ABSTRACT

Palaeozoic intrusions in Eastern Tianshan are important for understanding the evolution of the Central Asian Orogenic Belt (CAOB). The Sanchakou intrusions situated in Eastern Tianshan (southern CAOB), are mainly quartz diorite and granodiorite. A comprehensive study of zircon U–Pb ages, zircon trace elements, whole-rock geochemistry, and Lu–Hf isotopes were carried out for the Sanchakou intrusive rocks. LA-ICP-MS zircon U–Pb dating yielded crystallization ages of 439.7 ± 2.5 Ma (MSWD = 0.63, n = 21) for the quartz diorite, and 430.9 ± 2.5 Ma (MSWD = 0.21, n = 21) and 425.5 ± 2.7 Ma (MSWD = 0.04; n = 20) for the granodiorites. These data, in combination with other Silurian ages reported for the intrusive suites from Eastern Tianshan, indicate an early Palaeozoic magmatic event in the orogen. In situ zircon Hf isotope data for the Sanchakou quartz diorite shows εHf(t) values of +11.2 to +19.6, and the two granodioritic samples exhibit similar εHf(t) values from +13.0 to +19.5. The Sanchakou plutons show metaluminous to weakly peraluminous, arc-type geochemical and low-K tholeiite affinities, and display trace element patterns characterized by enrichment in K, Ba, Sr, and Sm, and depletion in Nb, Ta, Pb, and Ti. The geochemical and isotopic signatures indicate that the Sanchakou dioritic and granodioritic magmas were sourced from a subducted oceanic slab, and subsequently underwent some interaction with peridotite in the mantle wedge. Combined with the regional geological history, we suggest the Sanchakou intrusions formed due to the northward subduction of the Palaeo-Tianshan Ocean beneath the Dananhu–Tousuquan arc during early Silurian time.  相似文献   

17.
ABSTRACT

We report new zircon U–Pb ages, Hf isotopic and geochemical results for the Tongling granitic plutons of Southeast China. SHRIMP U–Pb ages for the Miaojia quartz monzodiorite porphyrite,the Tianebaodan and Tongguanshan quartz monzodiorites, the Xinqiaotou granodiorite porphyry, and the Shatanjiao and Nanhongchong granodiorite are 143 ± 2, 141 ± 1 and 142 ± 1, 147 ± 1, and 145 ± 1 and 139 ± 1 Ma, respectively. Combined with previous geochronological data, our results indicate that the porphyritic rocks are older than rocks of the same type lacking porphyritic texture. Geochemically, these high-K calc-alkaline intrusive rocks are characterized by arc-like trace element distribution patterns, with significant enrichment in LILE and LREE but depletion in HFSE. Lu–Hf isotopic compositions of zircons from the high-K calc-alkaline (HKCA) rocks have εHf(t) values of magmatic 139–147 Ma zircons from ?8.1 to ?25.6, with two-stage model ages (tDM2) of 1.71–2.67 Ga, whereas εHf(t) values of inherited 582–844 Ma zircons range from 5.4 to ?9.5, with tDM2 of 1.39–2.22 Ma, younger than tDM2 values of igneous zircon, indicating that newly formed mantle material was added to the continental crust of the Yangtze Block. Moreover, εHf(t) values of inherited zircon cores older than 1000 Ma are from ?7.8 to ?26, similar to magmatic zircons, and the tDM2 values are all greater than 3.0 Ga (3.16–3.75 Ga), reflecting partial melting of ancient sialic material. We conclude that the plutonic melts were derived from both the enriched mantle and the ancient crust. The HKCA Tongling intrusions coincide temporally with the J3–K1 magmatic event that was widespread in Southeast China. This igneous activity may have accompanied sinistral slip along the Tan-Lu fault due to oblique subduction of the Palaeo-Pacific plate.  相似文献   

18.
《International Geology Review》2012,54(15):1835-1864
The Yinshan deposit is a large epithermal-porphyry polymetallic deposit, and the timing and petrogenesis of ore-hosting porphyries have been hotly debated. We present new results from geochemical, whole-rock Sr–Nd and zircon U–Pb–Hf–O isotopic investigations. Zircon U–Pb data demonstrate that the quartz porphyry, dacitic porphyry, and quartz dioritic porphyry formed at ?172.2 ± 0.4 Ma, ?171.7 ± 0.5 Ma, and ?170.9 ± 0.3 Ma, respectively. Inherited zircon cores show significant age spreads from ?730 to ?1390 Ma. Geochemically, they are high-K calc-alkaline or shoshonitic rocks with arc-like trace element patterns. They have similar whole-rock Nd and zircon Hf isotopic compositions, yet an increasing trend in ?Nd(t) and ?Hf(t) values typifies the suite. Older (inherited) zircons of the three porphyries display Hf compositions comparable to those of the Jiangnan Orogen basement rocks. In situ zircon oxygen isotopic analyses reveal that they have similar oxygen isotopic compositions, which are close to those of mantle zircons. Moreover, a decreasing trend of δ18O values is present. We propose that the ore-related porphyries of the Yinshan deposit were emplaced contemporaneously and derived from partial melting of Neoproterozoic arc-derived mafic (or ultra-mafic) rocks. Modelling suggests that the quartz porphyries, dacitic porphyries, and quartz dioritic porphyries experienced ?25%, ?10%, and ?10% crustal contaminations by Shuangqiaoshan rocks. Our study provides important constraints on mantle–crust interaction in the genesis of polymetallic mineralization associated with Mesozoic magmatism in southeastern China.  相似文献   

19.
The northwest Zhejiang Province is a key domain for providing deep insight into the crust–mantle interaction and tectonic evolution of the South China block. In this paper, we collect geochemical, geochronological, and isotopic data of the Jurassic porphyries in this region, and investigated the Huangbaikeng ore-bearing porphyry in the Tongcun Mo–Cu deposit, using it as an example to uncover the porphyry petrogenesis and evaluate their metallogenic potential. Two varieties of the Huangbaikeng porphyry were distinguished: the medium- to coarse-grained type and medium- to fine-grained type. Zircon Sensitive High-Resolution Ion Microprobe U–Pb dating indicates that they were emplaced at 161.8 ± 2.8 and 162.7 ± 3.5 Ma, respectively, which are consistent with the molybdenite Re–Os ages of 163.9–161.8 Ma. The inherited zircons age spectrum significantly recorded a series of geological events, for example, assembly and breakup of the Columbia and Rodinia supercontinent, and the Triassic collision of Yangtze and North China blocks. Whole rock Sr–Nd and Jurassic zircon Hf isotopic data yield mostly negative εHf(t) values (0.5 to ?8.4) and εNd(t) values (?0.79 to ?4.82). Besides the Huangbaikeng porphyry, all the Jurassic porphyries in the northwest Zhejiang Province have a wide range of SiO2 contents (76.78–60.91 wt.%). They do not contain typical aluminous minerals (e.g. cordierite and garnet), and are mainly metaluminous to weakly peraluminous with high Na2O, low FeOT/MgO, and Zr + Nb + Ce + Y concentrations in composition. They thus fit the I-type granite definition. Some major and trace elements show strong correlations with SiO2, possibly indicating extensive fractional crystallization during their magma evolution. Tectonic discriminations imply that these plutons were likely formed in a volcanic arc regime possibly related to subduction of the Palaeo-Pacific plate. Sr–Nd–Hf isotopic data suggest a mixed source of the Mesoproterozoic crust and 30–50% mantle components. Compared with the adjacent Dexing Cu-bearing porphyies, which have more positive εHf(t) and εNd(t) values with more significant mantle components (55–70%), the Jurassic porphyries in the northwest Zhejiang Province probably lack metallogenic potential to form a giant porphyry copper deposit as Dexing.  相似文献   

20.
The NS-treading Zhongdian Arc located in the southern part of the Yidun Arc is an important region to address the evolution and reconstruction of the Palaeo-Tethys Ocean and related mineralization. In this study, we investigate three barren intrusions in the Zhongdian Arc and present geochemical compositions, zircon U–Pb dating and Hf isotopic compositions. Zircons from the three intrusions yielded U–Pb ages of ~227.5, ~222.5, and ~230 Ma, with highly variable εHf(t) values (?20.5 to 4.3). These quartz monzonite porphyries show typical adakitic affinity, and it is inferred that these intrusions in the Zhongdian Arc, together with those in the northern Yidun Arc, were derived from the partial melting of mantle wedge and contaminated by minor lower crustal components during the westward subduction of the Ganzi-litang Ocean, which probably resulted from the Triassic continental collision between the south China and the north China blocks. In the Yidun Arc, the Triassic ore-bearing intrusions have εHf(t) values that cluster around zero, while the barren intrusions possess negative εHf(t) values, suggesting that the mantle lithospheric components played an important role in the Triassic ore-bearing porphyries.  相似文献   

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