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再论蛇绿岩中豆荚状铬铁矿的成因——质疑岩石/熔体反应成矿说 总被引：9，自引：0，他引：9
着重论述了蛇绿岩地幔橄榄岩中豆荚状铬铁矿的成因,并对现今盛行的岩石/熔体反应成矿说提出了质疑。世界含铬铁矿的地幔橄榄岩均显示上部偏基性、下部偏酸性的垂直熔融分带,与蛇绿岩堆晶岩中上部偏酸性、下部偏基性的岩浆分异垂直层序恰恰相反。豆荚状铬铁矿与熔融剖面上部的纯橄岩或纯橄岩-方辉辉橄岩杂岩带紧密伴生。豆荚状铬铁矿是原始地幔岩高度熔融再造的产物,高铬型铬铁矿与PPG型蛇绿岩伴生,形成于岛弧或弧前盆地环境;高铝型铬铁矿与PTG型蛇绿岩伴生,形成于扩张脊（MOR）或弧后盆地环境。玻安岩（boninite）与高铬型豆荚状铬铁矿无成因关系,铬铁矿（或富铬矿浆）的形成反而为boninite提供了其形成所需的残余地幔;高铝型铬铁矿不是地幔橄榄岩/拉斑玄武质熔体反应形成的,而是富铬矿浆与基性熔体发生再平衡的产物。豆荚状铬铁矿中超高压矿物包体的出现为其地幔深部成因提供了佐证,而boninite形成于浅部较低压的条件;豆荚状铬铁矿中富集强相容元素IPGE（Os、Ir、Ru）合金,boninite富集不相容元素PPGE (Pt、Pd)硫（砷）化物, 而亏损IPGE,显示其形成较晚。因此,boninite与铬铁矿无生因关系,两者均受岛弧（或弧前盆地）环境的制约而在空间上相伴产出。 相似文献
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豆荚状铬铁矿床是工业上冶金级铬铁矿石的最主要来源,对于其成因研究依然是各国地质学家最为关注的热点之一。文章着重概述了近年来国内外地质学者对豆荚状铬铁矿床成因研究的现状和最新进展。最新研究表明,显生宙以来的豆荚状铬铁矿床具有一定的成矿专属性,主要赋存于蛇绿岩套底部(壳-幔边界,即岩石莫霍面)地幔橄榄岩中的一定层位中。世界上含矿的地幔橄榄岩普遍具有垂直熔融分带特征,即上部偏基性,下部偏酸性。豆荚状铬铁矿床与纯橄岩-方辉橄榄岩相密接相关,却很少见有豆荚状铬铁矿床产于二辉橄榄岩中。豆荚状铬铁矿的成矿作用经历了由洋中脊(MOR)扩张环境向岛弧体系俯冲环境的转变过程,而岛弧环境(岛弧、弧后盆地、弧前盆地等)是形成冶金级豆荚状铬铁矿的最为有利的构造环境。富铬铬铁矿与纯橄岩、玻安岩(Boninite)均为亏损地幔橄榄岩再次高度熔融的最终产物,而玻安岩普遍产于岛弧环境。虽然玻安岩不是铬的有效载体,但玻安岩的熔离促使铬铁矿达到进一步的富集。铬铁矿中的铬来自原始地幔,主要来自于地幔橄榄岩中两种辉石的不一致熔融及其对副矿物铬尖晶石的改造。随着部分熔融程度的增高,地幔橄榄岩逐渐向富镁方向演变,而对应的造矿铬尖晶石也逐渐向富镁、富铬方向演变。 相似文献
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豆荚状铬铁矿:古大洋岩石圈残片的重要证据 总被引：16，自引：2，他引：16
豆荚状铬铁矿为蛇绿岩的特征性矿产 ,保留了上地幔岩浆构造作用、高温变形以及岩石成因的重要信息。它们常见于方辉橄榄岩内 ,位于大洋岩石圈莫霍面下 1～ 2km的古深度范围内。豆荚状铬铁矿常被纯橄岩薄壳围限 ,保留特征的豆状、豆壳状等构造。豆荚状铬铁矿的TiO2 含量较低 ,铂族元素 (PGE)的分布模式显示特征的负斜率。普遍认为 ,豆荚状铬铁矿形成于部分熔融条件下 ,涉及原始地幔熔体与亏损地幔橄榄岩的相互作用 ,伴随复杂的岩浆混合及结晶过程。狭窄的上地幔岩浆通道或孔穴为豆荚状铬铁矿理想的堆积部位。超俯冲带 (弧后盆地、岛弧、弧前 )、大洋中脊、转换断层均可能是豆荚状铬铁矿形成的理想环境。其中 ,洋脊扩张模式及大洋上俯冲带模式较好地解释了豆荚状铬铁矿成因。对于经历高级变质及多期变形的华北大陆基底 ,豆荚状铬铁矿是研究古老蛇绿岩最直接而有效的地质标志 ,对于研究古大洋岩石圈增生过程 ,上地幔演化 ,探索早期板块构造意义重大。 相似文献
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The Troodos ophiolite of Cyprus hosts chromite deposits both as podiform bodies within the basal harzburgite and as lesser layers and schlieren within the overlying dunites and clinopyroxene dunites of the metacumulate sequence. All chromitite types have been studied from both field and mineralogical aspects, with particular emphasis on the chemistry of the ubiquitous silicate inclusions within chromite grains. Two distinct inclusion assemblages have been documented. Chromites from podiform bodies contain abundant hornblende, serpentine, ortho- and clinopyroxene and lesser olivine, while those from the metacumulates host pargasite, albite, serpentine and rare pyroxenes. This implies that no single silicate inclusion assemblage in chromite can be considered typically ophiolitic. The presence of an alkalirich fluid phase during chromite crystallization as evidenced by the unusual mineralogy of these inclusions has already been widely discussed in the literature. However, the marked stratigraphic control of inclusion types in chromite as reported here enables more complete modelling of the evolution of this phase to be made. 相似文献
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前人报道在西藏中生代和俄罗斯极地乌拉尔早古生代蛇绿岩地幔橄榄岩铬铁矿中发现了金刚石等深部地幔矿物,认为需重新考虑铬铁矿浅部成因的传统认识。为了查明不同造山带蛇绿岩的铬铁矿中金刚石等深部矿物的分布规律和豆荚状铬铁矿的成因,笔者开展了内蒙古贺根山晚古生代蛇绿岩中的铬铁矿床的人工重砂矿物学研究,本研究获得约2000 kg的内蒙古贺根山蛇绿岩铬铁矿石样品,对所采样品开展人工重砂选矿,表明该铬铁矿矿石样品中至少有金刚石、碳硅石及其他自然元素类、金属互化物类、氧化物类、硫化物类、硅酸盐类等30余种矿物。内蒙—大兴安岭造山带晚古生代的内蒙古贺根山蛇绿岩带铬铁矿石中,发现金刚石等深部地幔矿物表明,贺根山铬铁矿可能为深部成因。 相似文献
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关于冀东太古宙蛇绿岩的几个问题 总被引：8，自引：0，他引：8
最近美国学者Kusky博士和北京大学李江海教授在各种国际会议和Science等报章杂志上,报道他们在冀东发现了世界上最古老的25亿年的东湾子蛇绿岩以及遵化和辽西地区的蛇绿混杂岩和豆荚状铬铁矿。冀东是否存在蛇绿岩存在争论。我们的研究表明,所谓的太古宙东湾子蛇绿岩尚难成立。原因是他们所报道的蛇绿岩的所有组成岩石均多多少少存在问题:(1)东湾子蛇绿岩是否存在地幔橄榄岩还不能确定,Kusky和李江海等所说的地幔橄榄岩或方辉橄榄构造岩(harzburgite tectonite),经研究主要由富铁质的辉石岩和角闪石岩组成,且与辉长岩单元之间未直接接触,因此,上述超基性岩是否是太古宙的也不能肯定。(2)辉长岩的矿物组合中有少量原生黑云母出现,是蛇绿岩组合中罕见的。(3)席状岩墙群不成立,既无对称的冷凝边,也无不对称的冷凝边;所谓的岩墙群主要由辉石岩和角闪石岩组成,并非基性岩浆:辉石岩和角闪石岩的地球化学特征暗示其可能来自板块内部构造环境,也非蛇绿岩的特点。(4)与超基性岩伴生的铬铁矿富Fe和Cr,类似于产于古老地块的、与富铁质超基性岩有关的铬铁矿的特征,而非蛇绿岩的豆荚状铬铁矿。(5)缺少能够支持东湾子为蛇绿岩的详细和系统的地球化学资料。因此,根据目前的认识,冀东太古宙是否存在蛇绿岩仍然是一个不确? 相似文献
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中国铬铁矿资源的瓶颈状态已持续多年。最近,在西藏罗布莎蛇绿岩地幔橄榄岩的深部勘探发现200万t致密块状铬铁矿床,这是中国近50年来铬铁矿找矿的重大突破,对今后继续寻找同类型的铬铁矿床具有重要指导意义。蛇绿岩地幔橄榄岩中产出的豆荚状铬铁矿床是工业需求铬的重要来源。研究豆荚状铬铁矿的成矿作用和矿体围岩地幔橄榄岩地质特征,建立铬铁矿的成矿模型和找矿标志,是开展寻找同类型矿床的重要保证。随着近些年在豆荚状铬铁矿及围岩地幔橄榄岩中金刚石等深部矿物的不断发现和深入研究,人们对蛇绿岩型铬铁矿的物质来源和形成过程,有了新的认识,提出了铬铁矿的深部成因模式。研究认为深部成因铬铁矿床主要经历了4个阶段:(1)早期俯冲到地幔过渡带(410~660 km)的陆壳和洋壳物质被脱水和肢解,过渡带产生的热和流体促成了地幔的熔融和Cr的释放和汇聚;(2)铬铁矿浆在地幔柱驱动下,运移到过渡带顶部冷凝固结,并有强还原的流体进入,后者携带了深部形成的金刚石、斯石英等高压矿物,进入"塑性—半塑性地幔橄榄岩"中;(3)随着物质向上移动,深度降低,早期超高压相矿物发生相变,如斯石英转变成柯石英,高压相的铬铁矿中出溶成柯石英和单斜辉石;(4)在侵位过程和俯冲带环境下,含水熔体与方辉橄榄岩反应形成了不含超高压矿物的规模相对较小的浸染状铬铁矿及纯橄岩岩壳。进一步研究表明,同处雅鲁藏布江缝合带西段的几个大型地幔橄榄岩岩体与罗布莎岩体可以对比,经历了相同的构造背景和豆荚状铬铁矿的成矿作用,存在较大的找矿空间。 相似文献
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Songbai Peng T.M. Kusky X.F. Jiang L. Wang J.P. Wang H. Deng 《Gondwana Research》2012,21(2-3):577-594
We report the presence of a Grenvillian ophiolite on the northern margin of the Yangtze craton, drastically changing current ideas about South China's role in plate reconstructions of the Rodinia supercontinent. Strongly deformed amphibolites that locally show relict pillow lavas, isotropic and layered metagabbro, diabase dikes, serpentinized dunite and harzburgite with podiform chromite are dated at circa 1100–985 Ma (U–Pb zircon). The ophiolite is structurally dismembered and thrust over the Proterozoic shelf sequence that covers the north margin of the Yangtze craton, and overrode a flysch to conglomerate-wildflysch unit shed from the ophiolite and a magmatic arc terrane and deposited on the older Yangtze carbonate platform. The youngest clasts in the conglomerate are circa 861–813 Ma (U–Pb zircon), giving a maximum age for ophiolite emplacement. Fine-grained layered amphibolites exhibit slightly depleted-flat type REE curves with no obvious Eu anomalies, and are N-MORB type tholeiites. Metagabbro has typical cumulate textures, flat REE distributions and obvious positive Eu anomalies. The REE characteristics of serpentinized dunites show a U-shape of slight loss of middle REE, representing cumulates metasomatized by LREE slightly enriched mantle. All these features indicate that the metamafic–ultramafic rocks from the Proterozoic Miaowan Formation form a structurally dismembered ophiolite resting above an ophiolitic wildflysch, sitting on top of the Proterozoic shelf sequence on the Yangtze craton. The ophiolite is contemporaneous with an arc sequence preserved to the north on the edge of the Yangtze craton, suggesting that the entire ophiolitic forearc–arc was accreted to the Yangtze craton between 1000 and 850 Ma. Xenocrystic zircons in granite clasts in the basal wildflysch unit have ages consistent with Australian affinity, and detrital zircons in the arc sequence also show derivation from Australia, suggesting that the arc formed on the Australian segment of Rodinia before collision with the Yangtze craton. The discovery of the Proterozoic Miaowan ophiolite supplies important evidence for the existence of a Neoproterozoic oceanic basin on the north margin of the Yangtze craton, and demonstrates that the Yangtze craton first collided with Rodinia on its northern margin, with subsequent accretion of the Cathaysian block on the southern margin of the craton. 相似文献
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沿雅鲁藏布江缝合带分布的柳区砾岩是喜马拉雅造山作用过程中重要的沉积记录。然而,目前对该套地层的构造属性仍存在不同的认识,因为尚未发现来自冈底斯中酸性的火山岩砾石,部分学者认为其是在印度和洋内岛弧碰撞形成的。本次工作对柳区出露的柳区砾岩进行了详细的剖面实测、沉积学观察和物源区分析。地层由厚层的砾级到巨砾级的砾岩以及相对较薄层的砂岩和泥岩组成,砾石包括硅质岩、基性-超基性岩、石英砂岩、岩屑砂岩以及板岩和千枚岩。砾岩分选差,磨圆差,颗粒支撑和基质支撑均发育,根据岩相组合判断其形成于冲积扇和辫状河环境。较大的砾径以及极低的结构成熟度表示为近源堆积,暗示雅鲁藏布江蛇绿岩带为该套砾岩的重要源区,而特提斯喜马拉雅带为板岩和片岩的主要源区。岩屑砂岩的碎屑颗粒统计结果显示岩屑的含量为82%~85%,其中沉积岩屑为主(82%~95%),石英颗粒以单晶石英为主。碎屑锆石U-Pb年龄有453~579Ma和737~889Ma二个主要的范围,而缺少200~400Ma的锆石年龄。上述观测都说明日喀则弧前盆地、雅鲁藏布蛇绿岩带和特提斯喜马拉雅为柳区砾岩的重要物源区。由于柳区砾岩内部含有日喀则弧前盆地提供的物源,所以柳区砾岩是印度-欧亚板块碰撞之后沉积的。而柳区砾岩内各成分的变化反应源区对物源贡献的变化,同时记录了造山带隆升的历史,具体表现为印度-欧亚板块碰撞后,首先雅鲁藏布江蛇绿岩带和日喀则弧前盆地相对较快隆升,并遭受剥蚀,为柳区砾岩的沉积提供初始的物源,随着印度板块的俯冲,特提斯喜马拉雅带开始隆升,成为了柳区砾岩的物源,主要提供板岩和千枚岩。进一步的俯冲使得蛇绿岩带大幅度隆升而阻碍了日喀则弧前盆地和冈底斯继续提供物源,使得柳区砾岩上段石英砂岩中缺少火山岩石英和再旋回的石英颗粒。 相似文献
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铬铁矿是关键金属铬唯一可经济利用的自然资源,主要有层状铬铁矿和蛇绿岩中的豆荚状铬铁矿两种类型,其中豆荚状铬铁矿矿体规模小、发育不规律,是一个长期存在的勘探难题。由于铬铁矿特殊的经济战略地位,美国、欧洲、苏联和中国都非常重视铬铁矿地球物理勘探。铬铁矿地球物理探测技术发展始于20世纪30年代,至20世纪80年代,发展了以重力、磁法为主导的铬铁矿地球物理勘探技术,地震、电法也被应用。这一阶段在苏联乌拉尔肯皮尔赛等超大型蛇绿岩型隐伏铬铁矿勘探取得重大突破,在其他矿区取得一定的进展。自21世纪以来,高精度的便携式仪器和新兴地球物理技术逐渐运用到铬铁矿地球物理勘探,综合地球物理成为铬铁矿勘探的主流方法,在我国罗布莎等多个岩体隐伏铬铁矿勘探中取得突破,在印度、阿尔巴尼亚等国家也取得进展。本文回顾了铬铁矿地球物理勘探的发展历程,综述了铬铁矿岩石物理特征与测量方法、重磁勘探主要应用及存在问题、电磁法勘探的主要方法,并重点介绍了音频大地电磁测深在罗布莎铬铁矿的探测效果和电磁法勘探模式,展望了张量CSAMT技术、磁异常模量反演、高光谱遥感、高密度激电、无人机物探等有望在铬铁矿地球物理勘探中发挥重要作用的前沿... 相似文献
13.
Podiform Chromitites in the Luobusa Ophiolite (Southern Tibet): Implications for Melt-Rock Interaction and Chromite Segregation in the Upper Mantle 总被引：29，自引：0，他引：29
The Luobusa ophiolite in the Indus—Yarlung Zangbo sutureof southern Tibet hosts the largest known chromite deposit inChina. The podiform chromitites occur in a well-preserved mantlesequence consisting of harzburgite with abundant lenses of dunite.The harzburgites have relatively uniform bulk-rock compositionswith mg-numbers [100 Mg/(Mg + Fe)] ranging from 89 to 91 andshow flat, unfractionated, chondrite-normalized platinum groupelement (PGE) patterns. Their accessory chromite varies widelyin cr-number [100Cr/(Cr + Al)] (18–66). These rocks areessentially residua left after extraction of mid-ocean ridgebasalt (MORB)-type magmas. The podiform chromitites displaynodular, massive, disseminated and banded textures and typicallyhave dunite envelopes that grade into the surrounding harzburgiteand diopsidic harzburgite with increasing pyroxene contents.They consist of relatively uniform chromite with high cr-numbers(74–82), have strongly fractionated, chondrite-normalizedPGE patterns with enrichment in Os, Ir and Ru relative to Rh,Pt and Pt, and are believed to have formed from a boniniticmagma produced by a second stage of melting. Dunites containaccessory chromite intermediate in composition between thoseof harzburgite and chromitite and are believed to be the productsof reaction between new boninitic magmas and old MORB-type peridotites.The melt-rock reaction removed pyroxene from the peridotitesand precipitated oli-vine, forming dunite envelopes around thechromitite pods. The melts thus became more boninitic in compositionand chromite saturated, leading to precipitation of chromitealone. The interplay of melt-rock interaction, chromite fractionationand magma mixing should lead to many fluctuations in melt composition,producing both massive and disseminated chromitites and phaselayering within individual podiform bodies observed in the Luobusaophiolite. KEY WORDS: boninitic magmas; dunite envelope; melt—rock interaction; MORB peridotities; podiform chromitites
*Corresponding author. Present address: Department of Geology, Laurentian University, Sudbury, Ont, Canada P3E 2C6. 相似文献
14.
The Zedang and Luobusa ophiolites are located in the eastern section of the Yalung Zangbo ophiolite belt,and they share similar geological tectonic setting and age.Thus,an understanding of their origins is very important for discussion of the evolution of the Eastern Tethys Ocean.There is no complete ophiolite assemblage in the Zedang ophiolite.The Zedang ophiolite is mainly composed of mantle peridotite and a suite of volcanic rocks as well as siliceous rocks,with some blocks of olivinepyroxenite.The mantle peridotite mainly consists of Cpx-harzburgite,harzburgite,some lherzolite,and some dunite.A suite of volcanic rocks is mainly composed of caic-aikaline pyroclastic rocks and secondly of tholeiitic pillow lavas,basaltic andesites,and some boninitic rocks with a lower TiO2 content （TiO2 ＜ 0.6％）.The pyroclastic rocks have a LREE-enriched REE pattern and a LILE-enriched （compared to HFSE） spider diagram,demonstrating an island-arc origin.The tholeiitic volcanic rock has a LREE-depleted REE pattern and a LILE-depleted （compared to HFSE） spider diagram,indicative of an origin from MORB.The boninitic rock was generated from fore-arc extension.The Luobusa ophiolite consists of mantle peridotite and mafic-ultramaflc cumulate units,without dike swarms and volcanic rocks.The mantle peridotite mainly consists of dunite,harzburgite with low-Opx （Opx ＜ 25％）,and harzburgite （Opx ＞ 25％）,which can be divided into two facies belts.The upper is a dunite-harzburgite （Opx ＜ 25％） belt,containing many dunite lenses and a large-scale chromite deposit with high Cr203; the lower is a harzburgite （Opx ＞25％） belt with small amounts of dunite and lherzolite.The Luobusa mantle peridotite exhibits a distinctive vertical zonation of partial melting with high melting in the upper unit and low melting in the lower.Many mantle peridotites are highly depleted,with a characteristic U-shaped REE pattern peculiar to fore-arc peridotite.The Luobusa cumulates are composed of wehrlite and olivine-pyroxenite,of the P-P-G ophiolite series.This study indicates that the Luobusa ophiolite was formed in a fore-arc basin environment on the basis of the occurrence of highly depleted mantle peridotite,a high-Cr2O3 chromite deposit,and cumulates of the P-P-G ophiolite series.We conclude that the evolution of the Eastern Tethys Ocean involved three stages：the initial ocean stage （formation of MORB volcanic rock and dikes）,the forearc extension stage （formation of high-Cr203 chromite deposits and P-P-G cumulates）,and the islandarc stage （formation of caic-alkaline pyroclastic rocks）. 相似文献
15.
新特提斯缝合带中的铬铁矿带是全球最重要的豆荚状铬铁矿成矿带之一,尤其是新特提斯缝合带中段,即穆斯林巴赫-科希斯坦-雅鲁藏布江一带,自东向西发育罗布莎、马拉坎德、穆斯林巴赫等若干大型铬铁矿床。本文系统总结和梳理新特提斯缝合带中段蛇绿岩的时空分布特征以及典型豆荚状铬铁矿的矿床特征、赋存规律和控矿因素。研究表明,蛇绿岩形成时代主体为中侏罗世—晚白垩世,自东向西大致呈逐渐变新的趋势,构造侵位的时代相近,为古新世—始新世;马拉坎德、瓦济里斯坦、穆斯林巴赫及贝拉铬铁矿,与罗布莎矿床相似,均属于富铬型铬铁矿,产于SSZ相关构造背景下,显示良好的岩相分带,具有良好的成矿条件;提出下一步找矿方向是针对成矿条件优越的蛇绿岩,解析层序剖面,识别纯橄岩与方辉橄榄岩的岩相分带,确定有利赋矿岩相。 相似文献
16.
In the ophiolite series of N. Oman numerous small and large elongated podiform chromite deposits occur within the peridotite complex at a certain level of 100–200 meters below the layered zone, which grades into the overlying gabbro complex. The chromite grains were corroded after their deposition; their composition shows a large variation in Cr/Al ratio and a small variation in Cr/Fe ratio. The chromium is thought to have been liberated from clino-pyroxenes during partial melting of lherzolitic upper mantle material. Precipitation of large quantities of chromite at the specific level below the gabbro complex is related to the plagioclase- /spinel-lherzolite transition, but the influence of a change in oxygen fugacity is also considered. 相似文献
17.
《Journal of Asian Earth Sciences》1999,17(4):423-442
The Hegenshan ophiolite in Inner Mongolia is a remnant of oceanic lithosphere of probable Devonian age. The ophiolite consists of several blocks composed chiefly of serpentinized ultramafic rocks with lesser amounts of troctolite and gabbro, and sparse lavas and dikes. The ultramafic rocks consist chiefly of depleted harzburgite and minor dunite and are interpreted as mantle tectonites. In the Hegenshan block dunite is relatively abundant and is typically associated with podiform chromitite. Both the chromite ore and the residual chromites in this body are relatively aluminous with average Cr numbers of 44–54. A few small chromite bodies and some of the residual chromites have much higher Cr numbers (72–76). Several blocks have well-layered cumulate sequences of gabbro and troctolite. Sheeted dikes are absent but small mafic dikes are common in some of the ultramafic sections. Most of the mafic dikes have flat chondrite-normalized REE patterns and are strongly depleted in incompatible elements, similar to depleted tholeiites from immature island arcs. The basaltic lavas of the Hegenshan ophiolite have two distinctly different chemical signatures—one similar to the mafic dikes and one similar to ocean island basalts. The entire complex was probably formed within an island arc–marginal basin system that was later accreted to the southern margin of the Siberian Altaids. 相似文献
18.
藏南罗布莎铬铁矿床铬尖晶石矿物学与矿床成因研究 总被引：1，自引：1，他引：0
西藏罗布莎铬铁矿床是我国目前研究程度最高、规模最大、地幔橄榄岩相对新鲜的豆荚状铬铁矿床,主要工业矿体产于蛇绿岩壳-幔边界(即岩石莫霍面)以下方辉橄榄岩相带一定层位中,主要有块状、浸染状和豆状等矿石类型。罗布莎铬尖晶石成分变化范围大,依据铬尖晶石的化学成分与矿物学研究至少可识别出3个期次铬尖晶石:(1)成矿前期铬尖晶石,主要以熔蚀残斑晶、出溶晶及少量自形晶形式产于方辉橄榄岩中,以富Al2O3为特征,Cr#值变化范围大(17.19~66.30),且大部分小于60,并与Mg#值呈负相关关系,由出溶晶,残斑晶到自形晶铬尖晶石,总体表现向富Cr、Fe的方向演变;(2)成矿主期铬尖晶石,可分为早、晚2个阶段。早阶段铬尖晶石主要以它形晶产于不同类型铬铁矿石中,部分呈自形-半自形晶产于铬铁矿体的纯橄岩外壳中,主要以富铬为特征,矿石中Cr#值变化范围小(70.08~87.03),均大于60,其中块状铬铁矿具有最高的Cr#和Mg#,由纯橄岩外壳中副矿物铬尖晶石向豆状、浸染状矿石以及块状矿石演变过程中,铬尖晶石化学成分总体向更富Cr、富Mg方向演变;晚阶段铬尖晶石:主要以自形-半自形晶产于具堆晶结构的纯橄岩相带中,成份上以更加富而贫Al2O3,且具有最低Mg#(18.79~44.77)值为特征;(3)成矿晚期铬尖晶石,主要以网状集合体产于豆状-网脉状(眼眉状)矿石中,以更贫Al、富Fe为特征,具有最高的Cr#值和低的Mg#值。综合研究表明,罗布莎铬铁矿中的铬主要来自原始地幔岩本身,且主要来自于地幔橄榄岩中2种辉石的不一致熔融和对副矿物铬尖晶石的改造,原始富铬矿物可能来自地幔深部的八面体硅酸盐矿物。罗布莎豆荚状铬铁矿的成矿作用具有多期次、多成因、多种构造背景下成矿特征,成矿作用过程经历了由大洋中脊(MOR)扩张环境向岛弧体系俯冲环境的转变过程,洋内俯冲带之上(SSZ)的弧间盆地环境是形成冶金级豆荚状铬铁矿的最为有利构造环境。研究提出了罗布莎铬铁矿的"三阶段"成矿模式,即,经历了大洋中脊预富集阶段,俯冲带之上主成矿阶段及之后的构造抬升改造阶段。纯橄岩与方辉橄榄岩接触带之下的方辉橄榄岩相带是寻找较大规模铬铁矿床的有利地带。 相似文献
19.
The Zedong ophiolite is the largest ophiolite massif east of Dazhuqu in the Yarlung Zangbo Suture Zone in the southern Tibetan Plateau. However, its age, geodynamic setting and relationship to the Xigaze ophiolite remain controversial. New zircon U–Pb ages, whole-rock geochemical and Nd–Pb isotopic data from ophiolitic units provide constraints on the geodynamic and tectonic evolution of the Zedong ophiolite. U–Pb zircon geochronology of dolerite lavas and late gabbro–diabase dikes yield weighted mean ages of 153.9 ± 2.5 Ma and 149.2 ± 5.1 Ma, respectively. Strong positive εNd(t) and positive Δ7/4Pb and Δ8/4Pb values indicate derivation from a highly depleted mantle source with an isotopic composition similar to that of the Indian MORB-type mantle. The geochemistry of ophiolitic lavas and early dikes are analogous to typical island arc tholeiites whereas late dikes are similar to boninites. The geochemistry of these rock types suggests multi-stage partial melting of the mantle and gradually enhanced subduction influences to the mantle source through time. Combined with the MORB-like 162.9 ± 2.8 Ma Luobusha ophiolitic lavas, we suggest that the Luobusha lavas, Zedong lavas and early dikes originated in an infant proto-arc setting whereas late dikes in the Zedong ophiolite originated in a forearc setting. Together, they represent a Neo-Tethyan subduction initiation sequence. The Late Jurassic intra-oceanic proto-arc to forearc setting of the Zedong ophiolite contrasts with the continental margin forearc setting for the Xigaze ophiolite, which suggests a laterally complex geodynamic setting for ophiolites along the Yarlung Zangbo Suture Zone. 相似文献
20.
中国广泛分布有不同时期的蛇绿岩。相对于全球一些大型蛇绿岩铬铁矿床(如 Kempirsai,Bulquiza,Guleman 等), 我国同期蛇绿岩中赋存的铬铁矿床规模都较小(如萨尔托海,东巧,罗布莎等)。近年来的研究认识到绝大多数成矿的蛇绿 岩都形成于俯冲带上覆岩石圈。熔 - 岩反应是目前用来解释豆荚状铬铁矿成因的流行假说,但仍然不能解释铬元素的有效 富集过程——即铬铁矿矿床的形成过程。高铬含量是岛弧玄武岩原始岩浆的特征,但与成矿要求的铬含量相差甚远;岛弧 原始玄武岩浆结晶出富铬尖晶石,有利于成矿,但这个岩浆演化和相平衡过程仍然难以造就具有工业意义的矿体、矿床。 那么存在形成富铬熔体的机制吗?又如何运移这些富铬熔体并集中结晶成矿?这些仍然是豆荚状铬铁矿成因的关键问题, 有待于进一步思考研究。 相似文献